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Duplex-furnace for smelting of manganese alloys from ferrimanganese bases and concentrates and anthropogenic wastes of metallurgy

Duplex-furnace for smelting of manganese alloys from ferrimanganese bases and concentrates and anthropogenic wastes of metallurgy
IPC classes for russian patent Duplex-furnace for smelting of manganese alloys from ferrimanganese bases and concentrates and anthropogenic wastes of metallurgy (RU 2380633):
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Proposed method is used for converter processes such as AOD, MRP, AOD-L, MRP-L, CLU, ASM, Conars-Stainless steel, or vacuum processes such as VOD, SS-VOD, RH and RH with use of oxygen lance. Slag formed at the end of blowing and treatment in converter or vacuum plant is drained and removed in unreduced state; this slag is fed to electric furnace which is loaded with standard charge consisting of metal scrap and residual dust; then carbon is additionally fed and silicon if necessary; during melting, chromium oxide contained is slag is reduced by means of carbon and silicon.

FIELD: metallurgy.

SUBSTANCE: in arch of siphon there are implemented openings or windows for loading of carbon-bearing materials, partition with bottom window or windows for flow of melted slag into siphon is implemented in the form of common end wall for liquid-phase smelting shaft and siphon with electrode(s) and allows window or windows for fume extraction from under arch of siphon, located on level not higher than horizontal axis of top row of tuyeres of liquid-phase smelting shaft, siphon is outfitted by solid transverse partition, installed in its bottom part parallel to common end wall for liquid-phase smelting shaft and siphon at a distance enough for flow of required volume of slag melt from liquid-phase smelting shaft on surface of heated layer of carbon-bearing material, herewith solid transverse partition fully separates siphon from liquid-phase smelting shaft, and its top edge is located higher than horizontal axis of bottom row of tuyeres of liquid-phase smelting shaft.

EFFECT: invention provides decreasing of structure dimensions, utilising of all heat of effluent gas from siphon, decreasing of emissions amount of dioxide from siphon into environment.

1 dwg

 

The present invention relates to the production of high-quality manganese ferroalloys from poor concentrates (as, for example, ores, slag dump, sludge and dusts), and may also find its application for betaxolol poor processing of manganese ores and concentrates, as well as industrial wastes metallurgy (BOF dusts, oil sludge, nodules sea shelf etc).

Traditionally all over the world, for example, poor mn containing ores and industrial wastes on ferromanganese sequentially processed in a reverberatory furnace (design widely known in the art), then the slag is placed in an electric furnace, lined with carbon blocks (patent Australia CL No. 254219, 15.4 and RJ metallurgy, 1967, No. 3), which lead smelting reduction plants.

A disadvantage of the known equipment:

- the need to use three of furnaces, each of which maintained a certain temperature;

- high energy consumption due to heat loss during transportation melts and significant total area of the heat transfer surfaces of furnaces;

- low end-to-end use of manganese;

large emissions of harmful substances (dusts, dioxins, etc. in the environment.

Known the kiln for smelting of manganese ferroalloys, CA is Amy in metallurgy duplex oven. For example, in A.S. 1038366 (MKI: SS 5/52, publ. 30.08.83,, bull. No. 32) described sequential circuit: download poor mn containing materials in the first furnace, and then overload smelting products in the following furnace and subsequent melting. Because of the wide popularity of the design of electric furnaces, their description will not be repeated here.

The disadvantage of this technical solution:

- high power (up to 1000 kWh of electricity per tonne of pig manganese slag);

- increased loss of manganese associated with the metal (20%);

- low demand received associated metal;

- low degree of extraction of manganese from blast furnace slag in ferromanganese;

- high ratio of slag.

A common shortcoming of both known of furnaces is the fact that these units are able to operate satisfactorily (from the point of view of technical and economic indicators) only if the preliminary batch preparation (drying, sintering, briquetting, pelleting, etc.);

when precise coordination boot time, stay and discharge for each unit of the duplex process; the inclusion in the scheme of a complex system of gas-cleaning installations (because the process is associated with significant emissions of fine materials and dioxins in the environment).

Known furnace AG is egati for duplex processes, as, for example, for processing of fine oxidized poor Nickel ores. In these units eliminated the above-mentioned disadvantages, including the shortcomings of the above known duplex furnaces. The most advanced unit described in the patent of the Russian Federation No. 234888 on application No. 2006109262 from 24.03.2006, (authors Salikhov SG, Schetinin A.P., Ismestiev E.N.) "Vanyukov Furnace for the smelting of materials containing non-ferrous and ferrous metals".

This technical solution adopted for the prototype of the claimed invention as the most similar in purpose and achieve positive technical results.

The prototype essentially consists of serial connected or connecting two furnace units: Vanyukov furnace and electric arc furnace, minor design changes which may be required depending on the purpose of this type of duplex furnace and achieved positive results.

Vanyukov furnace prototype contains:

- liquid melting mine with caisson zones with upper and lower rows of tuyeres;

- pipes for loading of the charge and discharge of the flue gases at the roof and holes for drainage of liquid metal;

- inclined or stepped furnace hearth;

- wall with the bottom window or Windows for flow of the slag melt in the ladle;

- on the set of siphon fitted the h(s) electrode(s) can move;

channel(s) for release of the slag and metal components of the melt from the bottom of the siphon.

The disadvantages of the prototype are:

- large total surface area of the unit and the associated heat loss (sizes restorative camera is comparable or even larger than the melting chamber);

insufficient utilization of heat of oxidation gases, released during the operation of the siphon in the mode of an electric arc furnace (for modifying the viscosity of the slag on the border of the separation of metal and slag);

- a significant number of outliers (dioxide) from the siphon into the environment;

- needs carbonaceous material (coke or coal) upon receipt of pig manganese slag or ferromanganese;

- a large amount of unclaimed synthetic iron or requiring further processing obtained in the first stage of smelting of manganese ferroalloys.

The purpose of the invention: the creation of a kiln - duplex furnace for smelting of manganese ferroalloys from ferromanganese ores, concentrates and industrial waste metallurgy. A set of new signs of significant improvement of the prototype gives a positive effect : eliminates the disadvantages of furnaces for smelting of manganese ferroalloys.

The proposed duplex furnace issue is where it is refuelled manganese alloys contains liquid melting mine with caisson zones with upper and lower rows of tuyeres and with holes for exhaust gas discharge and loading of the charge and discharge of liquid metal, inclined or stepped furnace hearth, wall with the bottom window or Windows to release the slag melt in the ladle, in the firmament which set(s) electrode(s) to control the temperature of the melt, and the channel(s) for release of the slag and metal components of the melt from the bottom.

In her role end walls melting mine and siphon performs the partition wall, the upper edge of which rests on the arch of the melting shaft, and the lower on the furnace hearth, arch siphon, through the window(a) partitions made(data) for exhaust gases from under its arch, below the horizontal axis of the upper row of tuyeres liquid-phase melting shaft provided with a melting mine and contains sockets for download carbonaceous material (coke, coal and so on) in the combustion zone of the arc electrode(s), and in the lower part of the siphon is installed solid partition wall, the upper edge which ends above the horizontal axis of the bottom row of tuyeres, and the bottom edge rests on the furnace hearth siphon. Parallel mounted solid partition wall and a transverse partition with a Windows form a channel for flow of the melt from the melting zone to the surface layer of carbonaceous reductant in the siphon.

In addition, the duplex furnace for smelting of manganese alloys, the arch of her siphon through the window of a partition, which plays a role and a common end wall between p the operation of the mine and the siphon with the electrode(s), communicated with melting mine below the horizontal axis of the upper row of tuyeres, for example, 8-12 size of the mouth of the tuyere.

To confirm achieve the goal of obtaining a positive technical effects and evidence of the materiality of the distinctive features will present a description of the work proposed construction of the duplex furnaces in the smelting of manganese alloys from poor ores and industrial wastes.

Duplex furnace for smelting of manganese alloys of iron-manganese ores and concentrates and industrial waste metallurgy includes (see drawing): caisson liquid-phase melting pit - 1 and case - 2 (the case is not mentioned); tuyere bottom row - 3; lance top row - 4; REDD - 6 nozzles 7 to load the batch processing and the nozzles 8 for venting flue gases at the roof and the pipe 9 to drain the liquid metal, the furnace hearth - 10 (flat, inclined, stepped, or other form), siphon - 11 installed(and) his arch electrode(s) 12 for regulating the temperature of the melt and TV - 14 for the release of the slag and the metal component of the melt, the transverse wall 13, the upper edge of which rests on the arch 6 melting of mine - 1, and the lower on the furnace hearth - 10; set of siphon - 14 with holes for feeding carbonaceous coal or coke (not indicated)as of the end wall of the housing 2, plevel the Oh mine 1 and siphon 11 used partition 13, with the bottom(s) of the window or window - 15 and the window 16 for venting flue gases from under the arch of the siphon 11 in the lower zone of the upper row of tuyeres 4; end wall of the siphon 11 made in the form of a continuous transverse partition 17, the upper edge of which ends above the horizontal axis of the lower belt of the number of tuyeres 3, and the partition wall 17 is parallel to the transverse partition 13 with Windows 15 at a distance sufficient to overflow the total volume flow of the melt from the melting shaft 1 through the window 15 and the upper edge of the partition 17 to the surface layer of carbonaceous material in the siphon 11. Works duplex oven as follows.

Duplex oven heated to a certain temperature for a predetermined time schedule. Then load the molten slag (open hearth, blast or other easily fusible slag) caisson liquid-phase melting shaft 1 to set the level to the bottom row of tuyeres 3. After a warm-up set 6 through the pipe 7 gradually begin to load the mixture and coal, and oxygen-the air-gas mixture supplied through the bottom row of tuyeres 3 and starting the burner (not shown) creates a bubbling fluidised bed liquid-phase environment in the whole volume of the melting shaft 1. As ferromanganese raw materials (tailings and other), nefrackzionirovannam coal, flux (to provide the required melt viscosity) of the act is UPE mix, the heat from the combustion of coal (and methane) is spent on heating and melting of the charge, and products of incomplete combustion - carbon monoxide (CO) and H2used as reducing oxides, thermodynamic strength of which is lower than the oxide of manganese, i.e., those that can be restored with the help of carbon monoxide. The oxides of manganese in these conditions are not restored. Reduced iron and phosphorus are deposited on the furnace hearth furnace 10 and this alloy, high demand of metallurgists (90% Fe, 0.5 to 3.0% of Mn; 0.3 to 0.5% Si; 3,5-4,0%; 2,5-4,0% P) continuously emerges from the nozzle 9 of the melting shaft 1. Slag, freed from impurities (iron, phosphorus, non-ferrous metals) and containing mainly manganese oxides and iron oxides, whose thermodynamic strength higher than that of manganese oxide (oxides of silicon, calcium, magnesium, aluminum, barium and others), through the bottom(s) window(Windows) 15 transverse partitions 13 and the upper edge of the continuous partitions 17 continuously flows to the heated layer of carbon-containing reductant formed by downloading it through the boot nozzles 11 in the firmament of the siphon 11. Passing through the carbon-containing layer, the oxides of manganese and silicon are restored to varying degrees, depending on the desired range of ferrous alloys (carbon ferromanganese or silicomanganese), which is determined by temperature, layer thickness and the OS is ofmostly end of the slag in the siphon 11 (these options are supported by high-precision automation system - not shown). These products are produced from melting furnaces simultaneously and separately. By loading the mixture into the volume of the melting shaft 1, filled with fine "particles" of the melt, and "heap" (in the form of a dense flow) the flow of the mixture, followed by immersion in the melt in the absence of high velocity exhaust gases in Natsukawa space does not create conditions for the removal of dust from the liquid phase melting mine. This is confirmed by the practice of furnaces: liquid melting in the processing of fine materials reduces the removal of dust up to 30 times compared to mine, blast or reverberatory furnace(AMI). Because the downloadable mn containing the mixture is first immersed in a layer of molten slag, wetted, then the lances of the bottom row is discharged into the upper zone of the melting shaft 1, the reaction of reduction of iron is many times more intense than in other known furnace units, and the Department of CO and H2from the recovery process occurs in the upper zone of the mine and burnt by the lances of the top row of tuyeres. The heat released during the oxidation of CO and H2coming in contact with minute particles of metal and slag is returned back to the liquid-phase bubbling fluidised bed layer.

The resulting melt restored oxides in the siphon 1 is output from the nozzle (hole 14) siphon. The composition of this product melting: 70-75% Mn, 17-20% Si, 1.5 to 2.5% C, 0.1 to 0.3% of P, and the rest Fe. Eye-catching when you receive this product gases WITH continuously discharged through the window(s) 16 in the partition 13 and burn to CO2(i.e. disappears especially dangerous for ecology dioxide), and heat (approximately 30% of the heat of the melting zone of the furnace (this value can reduce the flow of heat transfer in the melting zone of the furnace, thus the total extent of the septum 13 is reduced to 1/4 the area of the vertical parts of the furnace and, consequently, on the same reduced heat loss to the environment) is passed to liquid-phase bubbling fluidised bed layer.

Thus, the set of new elements and their location can increase the extraction of Fe by 30-35%, manganese up to 15-25% and simultaneously utilize the heat of exhaust gases back into the processes of the duplex furnace, which reduces the energy consumption by 15-25%, and also allows you to get rid of, almost entirely from particularly harmful dioxins.

The proposed device duplex oven to implement the method of production of ferromanganese or silicomanganese can successfully be applied to produce other types of ferroalloys from poor ores, ferro-manganese concentrate and scrap of ferrous metals, without the use of coke and without preliminary preparation of raw materials processed with the loss of a valuable component of the s by 20-40% at this stage.

Duplex furnace for smelting of manganese alloys of iron-manganese ores and concentrates and industrial waste metallurgy containing liquid-phase melting mine with caisson zones with upper and lower rows of lances, nozzles for download of the charge and discharge of the flue gases on the roof and a hole for drainage of liquid metal, sloping or stepped furnace hearth, wall with the bottom window or Windows for flow of the slag melt in the ladle, in the firmament which set(s) electrode(s) to control the temperature of the melt and the channel(s) for release of the slag and metal components of the melt from the bottom of the siphon, characterized in that the set of siphon holes or window to load the carbonaceous materials, the partition with the bottom window or Windows for flow of the slag melt in the ladle made in the form of a common end wall for liquid-phase melting mine and siphon with the electrode(s) and has a window or Windows to exhaust gases from under the arch of the siphon, set(s) at a level not above the horizontal axis of the upper row of tuyeres liquid-phase melting of the mine, the siphon is provided with a continuous transverse partition, installed in the lower part thereof in parallel with a common end wall for liquid-phase melting mine and siphon at a distance sufficient to overflow the necessary volume of the mA molten slag from liquid-phase melting of the mine on the surface of the heated layer of carbon-containing material, when this solid transverse wall completely separates the siphon from the liquid phase melting of mine, and its upper edge is located above the horizontal axis of the bottom row of tuyeres liquid-phase melting mine.

 

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