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Dehydration method of carnallite raw materials and device for its implementation

Dehydration method of carnallite raw materials and device for its implementation
IPC classes for russian patent Dehydration method of carnallite raw materials and device for its implementation (RU 2359911):
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Method for dehydration of raw carnallite in fluidised bed three-cell furnace / 2323880
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Method of dehydration of the chlorine-magnesium feedstock and the device for its realization Method of dehydration of the chlorine-magnesium feedstock and the device for its realization / 2309896
The invention is pertaining to the field of the nonferrous metallurgy, in particular, to preparation of the chlorine-magnesium feedstock to the process of the electrolytic production of the magnesium out of the fused salts. The method of dehydration of the chlorine-magnesium feedstock in the multi-chamber furnaces melt layer provides for feeding of the raw material into the furnace, relocation of the feedstock from the chamber to the chamber at treatment of it with the flue-gases produced at burning of the natural gas, the air and chlorine in the hearth and fed through the angle bar into the layer, cooling by the air of the upper part of the angle bar over the horizontal partition, trapping of the outgoing gasses. The direction of the air movement in the upper part of the angle bar over the horizontal partition is exercised zigzagging by the air transition from one section into the following one. At that the air is fed into the upper part of the angle bar at the speed of 20-30 m\s. The device is made in the form of the multi-chamber furnace of the fluidized layer and includes: the body with the fitting pipes used for the feedstock inlet and the finished product outlet; the partition of the furnace; the gas-distribution tube plate with the holes, over which there is the gas-distribution angle bar rigidly connected to the gas-distribution tube plate by its ribs and separated by the horizontal partition for the upper and the lower parts; the windows for outlet of the flue-gases; the cyclones located on one axis to the holes and shifted concerning each other; the gas-trapping cyclones for trapping of the gases. The device is additionally supplied with the guiding angle bars, which are located in the upper part of the angle bar above the horizontal partition and form the sections. At that the guiding angle bars are mounted between the cap holes and are equally spaced from the axis of the cap and made in the form of the rectangular triangle rigidly connected alternately to each of sides of the angle bar. At that the hypothenuse is attached to the interior side of the angle bar, and one of legs - to the partition of the angle bar. The invention allows to increase the service life of the fluidized layer furnace, to improve the quality of the dehydrated carnallite.
Method of dehydration of magnesium chloride raw material / 2309895
Proposed method includes loading the raw material into multi-chamber fluidized-bed furnace and moving this material through row of horizontal chambers of furnace at conversion of crystalline hexahydrate into dihydrate in second chamber, thus obtaining dehydrated carnallite in third chamber at simultaneous treatment with flue gases containing hydrogen chloride. Crystalline dihydrate is mixed with solid salt of sodium chloride in second chamber of furnace, thus obtaining mixture of dehydrated carnallite and sodium chloride at mass content of water in mixture not exceeding 15-20%. Mixture thus obtained is dehydrated first at temperature of 180-190C and then at temperature of 190-360C.
Method of production of the enriched carnallite / 2308417
The invention presents the method of production of the enriched carnallite and is pertaining to the chemical technology of the inorganic substances, in particular, to the technology of production of the enriched carnallite from the natural ores in compliance with the halurgy technology and may be used at the chemical enterprises producing the enriched carnallite. The offered method of production of the enriched carnallite provides for dissolution the carnallite ore by the mother alkali liquor, clarification of the saturated mother alkali liquor, the vacuum-crystallization of the carnallite from the saturated mother alkali liquor, thickening and centrifuging of the carnallite. The sediment of the carnallite received after the stage of the centrifuging is treated with the carbamide solution in the quantity of 0.01÷1.00 % from the mass of the sediment. The invention allows to prevent reduction of the output of the enriched carnallite.
Method of reprocessing of the dust wastes formed at dehydration of the chlorine-magnesium raw materials / 2276101
The invention is pertaining to the field of non-ferrous metallurgy, namely, to dehydration of the chlorine-magnesium materials (carnallite) for the electrolytic production of magnesium, in particular, to reprocessing of the dust wastes trapped in the cyclones and gas ducts. The method of reprocessing of the dust wastes formed at the dehydration of the chlorine-magnesium materials provides for feeding of carnallite into the furnace boiling bed, its dehydration, the dust trapping in the cyclones, extraction of dust from the cyclones and its return to the stage of the dehydration, extraction of the dust waste from the pipe ducts. Dust wastes after extraction from the pipe ducts are wash out in the reactor by water, treat with the solution of sodium carbonate with production of the suspension the magnesium hydrocarbonate. The suspension is fractionated for the solid magnesium hydrocarbonate and the filtrate. The magnesium hydrocarbonate is annealed with production of the commercial magnesium oxide, and the filtrate is heated up to formation of the solution saturated with potassium and sodium chlorides. Crystallize it and dry with production of potassium chloride and sodium chloride. The invention allows to produce as the commercial products - potassium and sodium chlorides, alongside with the magnesium oxide.
Synthetic carnallite preparation method / 2262483
Invention is dealing with preparation of magnesium chloride feed for electrolytic production of magnesium and chlorine. In order to obtain synthetic carnallite, magnesium chloride is first mixed with potassium chloride-containing reagent including magnesium oxide followed by dehydration of resulting mixture. Novelty resides in additionally introducing aqueous hydrochloric acid when mixing the two solutions so that mixture contains at least 2 g hydrogen chloride per 1 g magnesium oxide.
Method of dehydrating solutions of calcium or magnesium chloride / 2259947
Method comprises dehydrating solutions of calcium chloride or magnesium chloride in fluidized bed apparatus by spraying the solution in the layer through nozzles with control of granulometric composition of the dehydrated product by means of control of the spraying intensity, separating a portion of the finishing product and its processing by means of initial solution to produce suspension. In order to processing the portion of the finishing product, the initial solution is used that is composed of admixture that is difficulty soluble in the concentrated solution of the finishing product, the suspension produced is separated to extract nonsoluble admixtures, and the solution is directed to the dehydration in the fluidized bed apparatus. In order to processing a portion of the finishing product, the initial solution is used that is composed of such compositions as sodium chloride, potassium chloride, calcium sulfate , and calcium or magnesium hydroxy acid.

FIELD: metallurgy.

SUBSTANCE: group of invention relates to non-ferrous metallurgy, particularly to method and device for preparation of carnallite raw materials to the process of electrolytic magnesium recieving. According to the method carnallite raw materials are loaded and dehydrated in the furnace by fuel gas, dehydrated carnallite is separated in dust cyclone from withdrawn gas and fed into the melting cyclone, where it is heated by fuel gas, received in burner by means of chlorine burning in natural gas, it is melted and heated up to the temperature 700-800°C. After overheating mixture of fuel gas and molten waterless carnallite is fed simultaneously in the melt collector, where gas is separated from the melt by means of collision with partition and fed into the furnace to dehydration stage, and waterless carnallite is discharged. Unit includes furnace with nozzles for loading of raw materials and gas mixture withdrawal with waterless carnallite, with nozzle for feeding of fuel gas, dust cyclone, connected to the furnace by gas pipe, melting cyclone, connected by pipeline to dust cyclone and melt pipe with melt collecto, outfitted by burner for burning of chlorine, collector of the melt with discharge nozzle for melt. It is also outfitted by gas flue, connecting melt collector with furnace and outfitted by device for gas feeding additionally melt collector is implemented in the form of tank with partition and outfitted by additional nozzle, connected to gas pipe.

EFFECT: group of inventions provides cost reduction for materials, electric power and equipment for dehydration of carnallite raw materials, to reduce raw materials losses and to increase productivity of unit operation.

9 cl, 1 dwg, 1 ex

 

The invention relates to ferrous metallurgy, in particular to a device for the preparation of carnallite raw materials to the process of electrolytic production of magnesium.

There is a method of dehydration of carnallite (Ed. mon. The USSR № 700445, publ. 30.11.1979, Bul), including the pre-dehydration dehydrated carnallite in the molten state at a temperature of 800-1000°C in an atmosphere of glorieuses agent into the cyclone chamber in a tangential entry of gases into the chamber with the speed of 40-150 m/s as glorieuses agent use hydrogen chloride, which is obtained by feeding gaseous chlorine into the flame of the burning fuel. In the torch burning chlorine, interacting with water vapor into hydrogen chloride. Exhaust gases are sent to a preliminary dehydration of carnallite in the solid state, and the resulting anhydrous carnallite flows into a mixer, where at a temperature of 700-800°To defend it from solids and sent to the electrolysis process.

The disadvantage of this method is that as the exhaust gases are served in the cyclone chamber at a high temperature, as in the upper part of the cyclone temperature of 1100-1200°C, and in the lower part of 800-900°C, then submit them directly to the stage of dehydration of carnallite is impractical because at this temperature the carnallite begins plavitsa to settle on the furnace hearth furnace, that does not allow the dehydration process. For this purpose, the gases must be cooled, which leads to additional cost and to high heat losses.

The known method and device for dewatering of carnallite (Ed. mon. The USSR № 1108318, publ. 15.08.1984, bull. 30). The method includes downloading a partially dehydrated carnallite in a fluidized bed furnace with a water content of 3-5%, dehydration him in the furnace of the fluidized bed to a water content of 1% flue gases coming from the burner into the furnace through the gas distribution grid, and through the tuyere zone. Dehydrated carnallite comes out of the oven COP as tangential inlet and cyclone dust on boot outlet in the melting cyclone. In the melting cyclone carnallite is melted by heat, overheat to a temperature of 750-800°C, resulting in receive molten anhydrous carnallite, which is sent to the receiver of the melt. The temperature of the heating gases flowing into the melting cyclone of the burner is reduced to 450-500°C and the exhaust pipe, they are fed into the tuyere zone of the furnace KS. Dehydration in an oven COP and in the melting cyclone is conducted to the atmosphere of the hydrogen chloride produced by the combustion of chlorine in the mixture of natural gas and air in the burner. The circulation of hydrogen chloride in the installation perform the regenerator, which is used to extract hydrogen chloride and dlego further circulation in the installation by returning the captured hydrogen chloride. In the regenerator receive hydrochloric acid of low concentration (21 wt.%), which is then saturated vapors of hydrogen chloride to a strong concentration (32 wt.%). Receive the molten anhydrous carnallite, wt.%: 50-51 MgCl2, MgO of 0.5.

Plant for dehydration of carnallite includes a fluidized bed furnace with the pipes for loading and unloading partially dehydrated carnallite, with the gas distribution grid of the tuyere zone, with a burner for combustion air. Dust cyclone is connected to the microwave CC and a melting cyclone. The melting cyclone is connected to the tuyere zone of the furnace of the fluidized bed, with a burner for the combustion of chlorine, with receiver melt and regenerator of hydrogen chloride containing absorption and distillation part. The receiver of the melt provided with a discharge pipe for removing melt. Installation can increase the degree of chlorine and improve working conditions.

The disadvantage of this method is that dehydration in the cyclone is subjected to pre-dehydrated carnallite, which leads to high costs of training materials. In addition, the installation includes the additional tuyere zone, a burner in the furnace fluidized bed regenerator hydrogen chloride - all this leads to additional material and energy costs dehydration of raw materials.

The known method and the moustache is the time for dehydrated carnallite raw materials (Ed. mon. The USSR № 945618, publ. 23.07.1982, bull. 27), the number of General characteristics adopted for the nearest equivalent prototype. The method includes downloading a partially dehydrated carnallite in a fluidized bed furnace with a water content of 3-5%, dehydration him in the furnace of the fluidized bed to a water content of 1% flue gases coming from the burner into the furnace through the gas distribution grid, and through the tuyere zone. Dehydrated carnallite comes out of the oven COP in the melting cyclone as tangential inlet and cyclone dust on boot outlet. In the melting cyclone carnallite is melted by heat, overheat to a temperature of 750-800°C, resulting in receive molten anhydrous carnallite, which is sent to the receiver of the melt. The temperature of the heating gases flowing into the melting cyclone of the burner is reduced to 450-500°C and the exhaust pipe, they are fed into the tuyere zone of the furnace KS. Dehydration in an oven COP and in the melting cyclone is conducted to the atmosphere of the hydrogen chloride produced by the combustion of chlorine in the mixture of natural gas and air in the burner. Exhaust gases together with the dust in the form of dehydrated carnallite from the furnace of the fluidized bed comes in a dust cyclone, in which gases are removed for gas purification and dust dehydrated carnallite in coaxial socket outlet is fed into the melting cyclone. As a result, the Euro is about getting anhydrous carnallite composition, wt.%: 30-51 MgCl2and 0.5 MgO, KCl + NaCl - rest. In addition, in the melting cyclone is a partial chlorination of the hydrolysis products formed during heating and melting of carnallite. The resulting melt flows from the melting cyclone in the receiver of the melt in the ladle is supplied to the electrolysis process.

For implementing the method proposed plant for dehydration carnallite raw materials, including fluidized bed furnace, with a feed pipe for loading partially dehydrated carnallite, tuyere zone, with the gas distribution grid, with the reactor for combustion of chlorine and air, and a dust cyclone. Dust cyclone is connected to the melting cyclone. The melting cyclone is connected to the tuyere zone, with oven COP, with a furnace for the combustion of chlorine and receiver melt. The receiver of the melt provided with a discharge pipe for removing melt. Method and installation help improve the quality of carnallite and improve the utilization of raw materials and fuel.

The disadvantage of this setup is the complexity of the design. So, the installation includes optional tuyere zone, a burner in the furnace of the fluidized bed - all this leads to additional costs for materials and equipment for dewatering of raw materials. In addition, the installation serves already partially dehydrated carnallite with a water content of 3-5%, which leads to updat the additional costs of pre-dehydrated carnallite raw materials. Dehydration is served a large amount of fuel supplied to the furnace COP through the gas distribution grid, and through the tuyere zone. The flow of exhaust gases from the melting cyclone in the tuyere zone requires high standards for seal installation, because the melting cyclone is under pressure.

The technical result is to eliminate the disadvantages of the prototype and allows you to reduce the cost of materials (air and natural gas for burners), electric power and dewatering equipment carnallite raw materials and to simplify the technological scheme of processing of raw materials to the process of electrolysis due to:

- exceptions may receive additional dehydrated carnallite raw materials;

exceptions to the additional submission of the flue gas through the tuyere zone of the furnace KS;

exceptions to the burner for supplying combustion gases directly into the oven for dehydration;

- exceptions in the furnace gas distribution grid,

- exceptions connection nipples located in the melting cyclone.

In addition, the proposed invention allows to reduce the loss of raw materials and increase the productivity of plants for dehydration carnallite raw materials.

The technical result is achieved by a method for dewatering carnallite raw materials, including download the ku carnallite raw materials and dehydration it in the furnace flue gases, Department of dehydrated carnallite in cyclone dust from the waste gases, the flow into the melting cyclone, heat and flue gases produced in the burner by the combustion of chlorine in natural gas, melting and overheating to a temperature of 700-800°C To produce anhydrous carnallite, loading it in the collection of the melt and unloading ready anhydrous carnallite, what's new is that after overheating the mixture of flue gases and molten anhydrous carnallite served simultaneously in the collection of the melt, where the gases are separated from the melt by the collision with the wall and served in the oven on a stage of dehydration.

In addition, the combustion gases serves on the stage of dehydration at a speed of 1.0-2.5 m/sec.

In addition, residual gases in the melting cyclone serves tangentially its conical surface.

In addition, the temperature of the flue gases at the outlet of the collection of the melt is 400-600°C.

For implementing the method proposed plant for dehydration carnallite raw materials, including stove with pipes for loading raw material and exhaust gas mixture with dehydrated carnallite, a pipe for supplying flue gases, dust cyclone, connected with the kiln gas duct, the melting cyclone is connected by a pipeline with a dust cyclone and rasplata with a collection of the melt and is equipped with a burner for the combustion of chlorine, proceedings of rspl the VA with inlet and outlet pipes to melt, what's new is that it is equipped with a flue connecting the collector of the melt from the furnace and provided with a device for gas supply, while the collector of the melt is made in the form of a vessel with septum and equipped with an additional pipe connected to the gas duct.

In addition, an additional tube is located in the upper part of the collection of the melt.

In addition, the furnace in the form of metal containers of cylindrical and conical parts.

In addition, a pipe for supplying a flow of gases is placed in a furnace axially.

In addition, the nozzle to the substrate and the nozzle for supplying flue gases are made in the lower conical part, and a pipe for draining the mixture of exhaust gas from dehydrated carnallite in the upper cylindrical part.

The proposed method is dehydrated carnallite raw materials allows to considerably simplify the technological scheme of preparation of raw materials for the electrolysis process by eliminating the stage for more dehydrated carnallite raw materials; supplementary feeding flue gas through the tuyere zone of the furnace KS; exceptions burners for supplying flue gases directly into the oven for dehydration; exceptions furnace gas distribution grid, exceptions connection nipples located in the melting cyclone.

The flow of the mixture of flue gases and molten is espagnola carnallite simultaneously in the collection of the melt, where the gases are separated from the melt by the collision with the wall and serves on the gas duct into the furnace at a stage of dehydration, can significantly reduce the cost of the dehydration of raw materials, to reduce the loss of raw materials. Placement of pipe to supply combustion gases axially into the furnace improves the performance of the operation of the plant for dehydration of carnallite raw materials.

The claimed group of inventions to meet the requirement of unity of invention, since the claimed method dehydrated carnallite materials and installation for its implementation constitute a single inventive concept.

Conducted by the applicant's analysis of the prior art, including searching by the patent and scientific and technical information sources and identify sources that contain information about the equivalents of the claimed invention, has allowed to establish that the applicant had not found the source, which is characterized by signs, identical all the essential features of the invention. The definition from the list of identified unique prototype as the most similar set of features analogue has allowed to establish the essential towards perceived by the applicant to the technical result of the distinctive features in the proposed method, obezvozhivaniya carnallite raw materials set forth in the claims izopet the deposits.

Therefore, the claimed invention meets the condition of "novelty."

To verify compliance of the claimed invention the term "inventive step", the applicant conducted an additional search of the known solutions to identify signs that match the distinctive features of the prototype of the characteristics of the claimed method. The stated signs are new and are not derived explicitly for the specialist, as in the prior art, a particular applicant identified the influence provided the essential features of the claimed invention transformations to achieve a technical result. Therefore, the claimed invention meets the condition of "inventive step".

The image is illustrated by a drawing.

Installation for dehydration carnallite raw material contains a furnace 1 for dewatering enriched carnallite, made of a cylindrical part 2 and the conical part 3, the pipe 4 to download carnallite raw materials into the furnace, the pipe 5 for exhaust gas mixture with dehydrated carnallite, pipe 6 for feeding into the furnace flue gases, the flue 7 connecting the furnace with a dust cyclone 8, pipe 9 for the flue, pipe 10 connecting the dust cyclone with a melting cyclone 11, the burner 12 for combustion of chlorine in the mixture of natural gas with air, rasplanirovan 13, connect the sequence of the melting cyclone with the collector of the melt 14. Proceedings of the melt is equipped with a nozzle for discharging the melt 16, the partition wall 17, a pipe connected to the gas duct 18, to supply chlorine-containing gases in the furnace with the help of the device 19.

Example operation of the method and installation for dehydrated carnallite raw materials.

Feedstock enriched carnallite composition, wt.%: 32 MgCl2, 24,5 KCl, 4,3 NaCl, 49.2 N2O density of 1.7 t/m3and an average particle size of 0,315 mm served in the furnace 1 dehydration in the solid state in the amount of 6.2 t/h. The oven 1 is a metal container made of two parts: a cylindrical 2 and cone 3, and provided with a socket 4 for the substrate and the nozzle 5 for removal of the mixture of exhaust gases and dehydrated carnallite, and a pipe 6 for supplying flue gases, placed axially in the furnace. When the pipe 2 to the substrate and the nozzle 6 for supplying flue gases are made in the lower conical portion 3 and the pipe 5 for removal of exhaust gas mixture with dehydrated carnallite in the upper cylindrical part 2. When the feed rate of the combustion gases 2.0 m/s in the lower conical part 3 of the furnace is formed with a weighted layer of carnallite, which is in contact with hot flue gases (500°C) is crushed. When reaching the particle density of carnallite 1.0-1.2 t/m3and particle size of 0.2 mm get dehydrated carnall is t, that is made together with the exhaust gases through the gas duct 7 in the dust cyclone 8. In the furnace 1 is dehydrated carnallite with getting 3.6 t/h, dehydrated carnallite following composition, wt.%: 48,1 MgCl2, 38,2 KCl, 7,9NaCl2, 1,4 MgO, 4.5 N2O. Dehydration conduct flue gases in the number 5060 nm3per hour, which lead from the collector of the melt 14 through the device 20 for supplying flue gases, such as a fan. Gases contain, wt.%: 5,8 CO2, 4,8 H2Oh, 10,9 HCl, 14,0 O2, 63,5 N2, 1,0 Ar. Contained in the gases hydrogen chloride obtained by burning chlorine in the burner 12 in the torch burning natural gas. In the burner 12 serves, nm3/h: natural gas - 188,0, primary blast (air) - 2719,1, secondary blast (air) - 834,8, anode chlorine gas (concentration of chlorine 91%) - 285,1. The temperature of the flue gases at the inlet into the melting cyclone 11 is 1030°C. In a dust cyclone 8 is supplied to 3.6 t/h dehydrated carnallite, while dehydrated carnallite in the amount of 3.5 tons/ hour catch and serves on the pipeline 10 in the melting cyclone 11. Part dehydrated carnallite together with the exhaust gases in an amount of 0.1 t/h enters through pipe 7 to the treatment plant, that is lost with the exhaust gases. In the melting cyclone 11 is heated, melting and overheating dehydrated carnallite due to heat Tabachnikov, get in the burner 12 by burning chlorine gas temperature at the outlet of the burner 12 and input into the melting cyclone 11 is equal 900-1300°C. the Composition of carnallite after dehydration in a melting cyclone 11 is equal wt.%: 51,8 MgCl2And 0.5 MgO, 39,5 KCl, 8,2 NaCl. The result is a mixture of gases and molten anhydrous carnallite, having a temperature of 700-800°C. the Mixture flows in the collector of the melt 14. In proceedings of the melt 14 gas is separated from the melt by the collision of the partition 17. The temperature of the gases in the collection of the melt 14 is reduced to 500°C and this temperature combustion gas flows through the gas duct 19 through the device 20, such as a fan in the lower conical part 3 of the furnace dehydration 1. Flue gases in the furnace 1 is carried away 0,017 t/hour of dust and 5060 nm3/h of flue gases. The composition of the gases entering the furnace, wt.%: 5,8 CO2, 4,8 H2O, 10,9 HCl, 14,0 About2, 63,5 N2, 1,0 Ar. From the collection of the melt 14 anhydrous carnallite periodically drained through the discharge pipe 16 and sent to electrolysis. The composition of the obtained anhydrous melt of carnallite, wt.%: 51,8 MgCl2and 0.5 MgO, 39,5 KCl, 8,2 NaCl vacuum bucket served in the electrolytic cells for the electrolysis process.

Thus, the invention allows to reduce the cost of materials (air and natural gas for burners), electric power and dewatering equipment to malitbog raw materials and to simplify the technological scheme of preparation of raw materials for the electrolysis process by eliminating the stage for more dehydrated carnallite raw materials; exceptions additional submission of the flue gas through the tuyere zone of the furnace KS; exceptions burners for supplying flue gases directly into the oven for dehydration; exceptions furnace gas distribution grid; exceptions connection nipples located in the melting cyclone.

In addition, the proposed invention allows to reduce the loss of raw materials and increase the productivity of plants for dehydration carnallite raw materials.

1. The method of dehydration of carnallite raw materials, including loading carnallite raw materials and dehydration it in the furnace flue gases, Department of dehydrated carnallite in cyclone dust from the waste gases, the flow into the melting cyclone, heat and flue gases produced in the burner by the combustion of chlorine in natural gas, melting and overheating to a temperature of 700-800°C To produce anhydrous carnallite, boot in the collection of the melt and unloading ready anhydrous carnallite, characterized in that after overheating the mixture of flue gases and molten anhydrous carnallite served simultaneously in the collection of the melt, where the gases are separated from the melt by the collision with the wall and serves in the oven on a stage of dehydration.

2. The method according to claim 1, characterized in that the flue gases serves on the stage of dehydration at a speed of 1.0-2.5 m/S.

3. The method according to claim 1, ex is different, however, that furnace gases in the melting cyclone serves tangentially its conical surface.

4. The method according to any one of claims 1 to 3, characterized in that the temperature of the flue gases at the outlet of the collection of the melt is 400-600°C.

5. Installation for dehydration carnallite raw materials, including stove with pipes for loading raw material and exhaust gas mixture with dehydrated carnallite, with a pipe for feeding flue gases, dust cyclone, connected with the kiln gas duct, the melting cyclone is connected by a pipeline with a dust cyclone and rasplata with a collection of the melt and is equipped with a burner for the combustion of chlorine, proceedings of the melt discharge pipe to melt, characterized in that it is equipped with a flue connecting the collector of the melt from the furnace and provided with a device for gas supply, while the collector of the melt is made in the form of a vessel with septum and equipped with an additional pipe connected with the flue.

6. Installation according to claim 5, characterized in that the additional tube is located in the upper part of the collection of the melt.

7. Installation according to claim 5, characterized in that the furnace is made in a metal container consisting of a cylindrical and conical parts.

8. Installation according to claim 5, characterized in that the nozzle for feeding flue gases is performed in a furnace axially.

9. Installation according to any one of PPI 7, characterized in that the nozzle to the substrate and the nozzle for supplying flue gases are made in the lower conical part of the furnace and the outlet for removal of exhaust gas mixture with dehydrated carnallite in the upper cylindrical part of the furnace.

 

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