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Method to make decorative items with filler from amber and/or wastes of its processing (versions). RU patent 2452715.

Method to make decorative items with filler from amber and/or wastes of its processing (versions). RU patent 2452715.
IPC classes for russian patent Method to make decorative items with filler from amber and/or wastes of its processing (versions). RU patent 2452715. (RU 2452715):

C04B40 - Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability (by selecting active ingredients C04B0022000000-C04B0024000000; hardening of a well-defined composition C04B0026000000-C04B0028000000; making porous, cellular or lightening C04B0038000000)
C04B28/30 - containing magnesium cements (magnesium oxide cements C04B0028100000)
C04B18/04 - Waste materials; Refuse
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FIELD: construction.

SUBSTANCE: according to the first version, the method to make decorative items with a filler from amber and/or wastes of its processing with thickness of not more than 20 mm includes preparation of a moulding compound, at the ratio of components, wt %: caustic magnesite 20-25 filler - amber 10-15 magnesium chloride solution 20-25 filler - quartz sand balance, which is poured into a mould of the necessary size, compacted with vibration for 0.5 - 1 minute, dried at 13-30°C for 1-3 days, then taken out of the mould, ground, polished, final polishing is done, for instance, with a mixture from paraffin and wax for setting or, if required, coated with a varnish. The second and third versions are characterised for the method of making decorative items.

EFFECT: invention provides for strength, ecological safety of decorative items with a filler of amber or wastes of its processing at simultaneous simplification of the manufacturing method and reduced labour intensiveness, cheaper products.

3 cl, 5 dwg

 

The invention relates to the production of decorative items, which can be used for interior decoration, such as floors, walls, window sills, tabletops, mosaic decorative panels on the walls of buildings with the use of a filler of amber and/or amber waste production, especially those still not used.

The use of amber and amber waste for the production of decorative products known for a long time. The most famous work is the Amber room, which was created by the German and Danish masters for the Prussian king Friedrich 1. Masterpiece consisted of the amber panels, ornaments and pictures that were mounted on a wooden base (see http://ru.wikipedia.org).

Currently the products obtained known methods, are rare author's works, a very expensive and require constant care, because amber is a very fragile material.

In the Kaliningrad region on the Baltic sea is the largest Deposit of amber extraction and processing which is engaged in 1947, the Kaliningrad amber factory. In the 80-90-ies produced up to 700 tons of amber in the year, which were processed at amber plant. Ways of processing of amber allow you to get amber jewelry, amber oil, processed amber, molded amber, amber acid, and much more. However, there is no use as amber and its various waste in processing for manufacturing durable, cheap decorative items, for example, for the interior decoration of various premises.

The Kaliningrad amber plant for many years and have accumulated a variety of waste, some of them have not yet found an application. Consolidation of amber on the surface of the product is made difficult because of the characteristic properties of amber. No industrial production, for example, for the manufacture of decorative building products, such as floors, ceilings, walls, countertops, and more using as a filler amber and its various wastes, including unclaimed at the moment, which include slag, and other

The applicant considered all known ways of processing of amber for making decorative products using filler amber and waste processing. The problem of using amber and/or waste processing in the fragility of the filler. Amber difficult to pin on the surface of the product, as well as the manufacture to ensure that the surface of decorative articles with the filler made of amber had the strength in the long-term use, the product is environmentally friendly.

There is a method of manufacturing of decorative products made with the filler made of amber (patent RU 2151700, IPC 44 5/00, 04 28/18), by filling in the mold compositions on the basis of amber with the addition of polymer binder, accelerator and hardener. In the process of preparation of decorative composite material used as a filler amber low quality of the various factions and amber waste production without grinding, which at the stage of preparation are sorted by color and size, dividing into several groups. Then each group filler process gelcoat, determine the ratio of the mass of each of the groups of the filler and the polymer matrix. After that, prepare molding lay it in a special form and after that a composition in the following ratio , wt.%:

filler - amber

40-70 gelcoat 3-4

unsaturated essential resin

55-25 hardener 1-0,5

accelerator

1-0,5

The molding is carried out manually or vibration method for 20-40 minutes. After hardening, the product is removed from the mold and dried in a drying oven for 3-4 hours at a temperature of 50-70°N

The disadvantage of this method, limiting its application, is the considerable complexity of the process, including extracting casting out of shape due to the high adhesion of the composition to the material form, as well as a relatively low purity of the surface) of castings. To facilitate the removal of castings from the shape of the working surface of the wall is covered with a protective layer of gel coat or other materials referred to reduce adhesion. Used pigmented resin (gelcoat)that are related to harmful substances during manufacturing, and during the further use of finished products.

There is a method of production of end of the bezel (patent RU 2335391, IPC 27 3/04) for use in the interior of the premises: walls, floors, ceilings, countertops, etc. The method involves the processing of wooden dice composite, consisting of transparent polyester resin and filler in the form of powdered fraction of amber.

Disadvantage of this method is a complex, multistage, time-consuming manufacturing process, which allows you to produce small lots of products filled with amber flour. Use in the manufacture of polyester resins requires the observance of the work with harmful substances. Products manufactured in such a way is not strong, require special care and polyester resin can evaporate for a long time that violates the environment and harmful to the health of anyone who uses the products manufactured in this way.

There is a method of production of wooden inlaid amber (patent RU 2294843, IPC 44 1/28), which includes preliminary preparation of wood and amber, co-location in accordance with the sketch and impregnation of amber polymer resins. Amber different factions and color plates are made in accordance with the sketch cut out of items, and on the basis of wood through cut out fragments. Then, in accordance with the sketch assemble the product, which in the wooden basis instead of the cut pieces are equipped with a gap of amber items, the gap is filled polymeric compound composed of polyester resin.

Disadvantage of this method is a complex, multistage, time-consuming manufacturing process, which allows you to produce small batches. Use in the manufacture of polymer resins requires the observance of the work with harmful substances. Products manufactured in such a way is not strong, require special care and polymer resins may evaporate for a long time that violates the environment and harmful to the health of anyone who uses the products manufactured in this way.

Disadvantages of all the above methods are: the use for fixing amber polymer resins, compounds, polymers, gelcoats, complex multi-stage difficult technology of fastening of amber using a large amount of manual labor. Obtained by means of such a product does not have the strength, environmental safety, and require constant care.

Known methods of manufacturing of decorative products using mineral magnesia binder. For these methods are characterized by the absence of harmful substances in the process, simplicity and low cost, durability. Decorative products have the strength of environmental safety.

There is a method of manufacturing of facing and decorative products made of artificial stone (application EN 93031201, IPC 04 28/30) on the basis of a magnesia astringent. For obtaining of a decorative layer using pigments.

The disadvantages include the fact that the filler is not used amber and/or waste processing.

There is a method of manufacturing of construction products on binder (patent RU 2121987, IPC 04 28/30), which includes crossing of magnesia powder, mineral filler and water solution of magnesium chloride, forming products and their cure. Mineral filler activate joint grinding with chemical additive or mineral Supplement to the specific surface of particles 1000-3500 cm/g with a ratio of the components. The distinctive feature of this method is not just a joint application of mineral filler, mineral Supplement and/or chemical additives (superplasticizer), and the use of activated filler with polyfunctional effect.

Manufacturing of construction products on binder is the preparation, dosage and mixing of powder magnesia usta magnesite, filler with subsequent chloride of magnesium with mixing before reception of a homogeneous mixture, which then level, compact vibration (3), at 25 OC in within 10 hours, then the samples and stored under the same conditions 28 days.

Disadvantage of this method for the production of plates, panels, partitions, window sills, table tops, wall blocks, doors etc. is something that is used only mineral filler to improve strength and water resistance without the decorative surface of products.

There is a method of manufacturing of building materials on gypsum- binder (patent RU 2376260, IPC 04 28/30, 04 111/20), which involves mixing activated powder on the basis of a magnesia usta magnesite, magnesium chloride solution and filler. As a placeholder small (0-5 mm) and major (5-40 mm) can be used as inorganic (gravel, quartz sand, gravel, crushed marble, crushed brick, crushed slag, asbestos and others), and organic fillers (wood flour, sawdust, shavings, chopped straw, husks, waste paper and other).

Ratio components in a joint grinding is, wt.%:

powder caustic magnesia

40-70

tricalcium phosphate

1-8

3-12

methyl cellulose

0,04-0,6

plaster building

rest

And the ratio of the components in the total mixture is, weight.%:

Activated powder

10-18

Solution of magnesium chloride in water

density of 1.15-1.30 g/cm 3 )

10-18 Sand 10-25

Crushed stone

rest

Manufacturing of construction products on binder is in preparation, dosage and mixing of powder magnesia usta magnesite, filler with subsequent chloride of magnesium with stirring until a homogeneous mixture, which is then equalize, condense vibration (3), at 25 deg C for 10 hours, then the samples and stored under the same conditions 28 days.

Disadvantage of this method for the production of plates, panels, partitions, window sills, table tops, wall blocks, doors, etc. aimed at improving their strength and water resistance is the use of various mineral and organic fillers, including for obtaining of decorative properties of the products. Among the listed organic fillers do not specify a natural filler amber, and how you want to receive articles with the filler made of amber and/or waste processing according to their physical properties and characteristics.

The closest adopted for the prototype, is a method of manufacturing construction materials binder (patent RU 2222508, IPC 04 28/30), which includes a mixture of powder magnesia usta magnesite, mineral supplements, superplasticizer, aqueous solution of magnesium chloride and placeholder with the subsequent formation and solidification of the mixture. As placeholder (small: up to 5 mm and large 5-40 mm) can be used as inorganic (gravel, quartz sand, gravel, crushed marble, crushed brick, crushed slag, asbestos and others), and organic fillers (wood flour, sawdust, shavings, chopped straw, husks, waste paper and others). Particle size of the coarse aggregate shall not exceed 1/3 thickness of produced products.

Manufacturing of construction products on binder is in preparation, dosage and mixing of powder magnesia usta magnesite, filler with subsequent chloride of magnesium with mixing before reception of a homogeneous mixture, which then level, compact vibration (3), then at 20±2 degrees C for 10 hours, then the samples and stored under the same conditions 28 days.

A well-known object cannot be applied because it has disadvantages. The disadvantage of the production of plates, panels, partitions, window sills, table tops, wall blocks, doors, aimed at increasing their strength and water resistance as well as decorative properties of the products, is to use the various mineral and organic fillers, among which is not specified natural filler amber, and how to obtain durable products filled with amber and/or waste processing according to their physical properties and characteristics.

The invention created using the issue of creation of strong, ecologically safe and decorative articles with the filler made of amber and/or waste processing (, slag and others who previously were not used) while simplifying the method of manufacture and, accordingly, reduce complexity, and reduce the production cost.

The applicant offered three variants of solution of the task.

In the first option for obtaining products of a thickness not exceeding 20 mm, without specified in advance drawing on the surface of the product are the smallest waste processing of amber.

This problem is solved by the fact that in the known method after the preparation of the filler by sorting perform batch basic mixture molding material, which included caustic magnesite, solution of magnesium chloride, filler amber and/or its waste, quartz sand with the following component ratio, mass%:

caustic magnesite

20-25

filler, amber

10-15

solution of magnesium chloride

20-25

placeholder, quartz sand

rest

The obtained mixture is poured into a mold of the desired size, put on a vibrating table 0.5-1.0 minutes, then the shape is moved into the drying chamber where dried at a temperature of 13 to 30 OC for 1-3 days depending on the thickness of product. Then the product after hardening removed from the mold, processed by grinding with diamond abrasives and with materials.

Proposed method of manufacturing of decorative products filled with amber and/or waste processing (the first option), including the preparation of a molding material in the structure of magnesia usta magnesite, magnesium chloride solution, filler, the filler character (quartz sand) with the subsequent forming, sealing vibration, curing, drying, wherein as filler used amber and/or its waste, the ratio of the components molding material is, wt.%:

caustic magnesite

20-25

filler, amber

10-15

solution of magnesium chloride

20-25

placeholder, quartz sand

rest

Moulding mass is poured into forms of the necessary size, compact vibration during 0.5-1 minutes, then dried at a temperature of 13 to 30 OC for 1-3 days. Then the product after hardening removed from the mold, processed by grinding with diamond abrasives and with materials.

The proposed method is as follows (the first option).

A method of manufacturing of decorative products without the preset picture when used as a filler mainly waste processing of amber (slag, ) most of the fines includes the preparation of the filler, it is sorted, then the dough molding material, the composition of which includes caustic magnesite, solution of magnesium chloride, the sand, the ratio of the components molding material is, wt.%:

caustic magnesite

20-25

filler, amber

10-15

solution of magnesium chloride

20-25

placeholder, quartz sand

rest

Molding mass is poured into forms of the necessary size, compact vibration during 0.5-1 minutes, then dried at a temperature of 13 to 30 OC for 1-3 days.

Then do the work of extracting the product from the mold, its grinding, polishing, final polishing with a mixture of paraffin and wax pin or, if necessary, varnish.

The applicant may give specific examples of decorative items, received in accordance with the above principles.

1 shows a photograph of the tiles in the form of decorative products using as filler mainly waste processing of amber most small factions throughout the product's volume.

Figure 2 shows a photograph of the tiles in the form of decorative products using as filler mainly waste processing of amber () most small factions throughout the product's volume.

Decorative tile surface with amber turned out to be durable, environmentally safe, durable, cheap result in simplified manufacturing technology. It should also be noted that the used waste processing of amber, still not finding application in production.

Thus, the proposed method for decorative products filled with amber and/or waste processing allows you to get a cheap, environmentally friendly, cost-effective, safe decorative material for use in residential, public places, including schools, the hospitals.

In the second option for obtaining products without the specified image on the surface of the product, of a thickness exceeding 20 mm, used filler amber and/or waste processing of amber.

This problem is solved by the fact that in the known method depending on the thickness of the decorative products more than 20 mm to save the filler and lighten the weight of the products method of manufacturing of decorative products includes two stages. At the first stage performed all stages of a method of manufacturing of decorative products filled with amber according to the first variant, completing the dryer. The second stage includes preparation of moulding mass in the composition of the components in the same proportion with the use of sawdust instead of amber and/or waste it processing, then the form installed on the vibrating table 1-2 minutes to remove air bubbles and levelling filled masses, then perform drying in the drying chamber at a temperature below 16 C, With not less than two days, and then remove the product from the form, his grind, Polish, perform final polishing, for example, a mixture of paraffin and wax pin or, if necessary, varnish.

Proposed method of manufacturing of decorative products filled with amber (the second option), including the preparation of molding material, which included caustic Magnezit solution of magnesium chloride, filler, filler (quartz sand) with the subsequent forming, sealing vibration, curing, drying, wherein in the capacity of filler is used the amber and/or waste processing, method of manufacture includes two stages, the first stage perform all stages of the first option to complete drying, the ratio of the components molding material is, wt.%:

caustic magnesite

20-25

filler, amber

10-15

solution of magnesium chloride

20-25

placeholder, quartz sand

rest

At the second stage molding prepared with the same components, but instead of filler, which is used as amber and/or waste processing is enabled filler sawdust, pour on the first layer filled with amber and/or waste processing, after what condense vibration within 1-2 minutes, perform drying in the drying chamber at a temperature below 16 C, With not less than two days, and then do the work of extracting the product from the mold, its grinding, polishing, final polishing, for example a mixture of paraffin and wax to secure, or, if necessary, varnish.

The proposed method of manufacturing of decorative products filled with amber and/or waste processing is as follows.

The applicant may give specific examples of decorative items, received in accordance with the above principles (the second option).

Figure 2 - a photo of a table, the table-top which has a thickness over 20 mm, decorative items filled with amber, mainly waste production (slag, )in the upper layer of the product and filled with sawdust in the second layer of the product. Decorative surface countertops with amber and waste production was strong, environmentally safe, durable, cheap result in simplified manufacturing technology. It should also be noted that the used waste processing of amber, still not finding application in production.

Thus, the proposed method for decorative products filled with amber and/or waste production allows to get a cheap, ecologically clean, cost-effective, safe decorative material for use in residential, public places, including schools, hospitals.

The third option for obtaining products with a pre-defined pattern, for example, in the form of a mosaic on the surface of the product is used as filler amber and wastes of processing of amber.

This problem is solved by the fact that in the known method of manufacturing of decorative products with a filler in the form of pieces of amber is done according to a predetermined pattern, such as mosaic. According to a predetermined sketch selected and sorted amber and/or waste for the picture, which laid out small pieces of amber on the bottom of the preset sizes and thickness of product. Inlaid picture mosaic pour formulation, which includes caustic magnesite and solution of magnesium chloride in a ratio, mass%: 60-70 and 40-30 to cover completely the picture of a filler in the form of pieces of amber and leave for 5-6 hours. Then composition, the composition of which includes caustic Magnezit solution of magnesium chloride, sawdust, sand, in the ratio of components, molding material, mass%:

caustic magnesite

20-25

filler, sawdust

10-15

solution of magnesium chloride

20-25

placeholder, quartz sand

rest

pour on the first layer up to the height of the desired size, shape installed on the vibrating table to remove air bubbles and levelling filled masses for 1-2 minutes, then perform drying in the drying chamber at a temperature below 16 C, With not less than two days, after which the product is recovered from the form and subject grinding, for example by the diamond abrasives, until the surface of the image mosaic of amber, which is polished skins.

Proposed method of manufacturing of decorative products filled with amber and/or waste for decorative products (third option), including the preparation of molding material, which included caustic magnesite, solution of magnesium chloride, filler, filler (quartz sand), with the subsequent forming, sealing vibration, curing, drying, wherein in the capacity of filler is used the amber and/or waste it production, laid out by a predetermined pattern, for example in form of a mosaic, pour formulation, which includes caustic magnesite and solution of magnesium chloride in a ratio of the weight.%: 60-70 and 40-30 to cover completely the picture of the filler and leave for 5-6 hours, after that the moulding mass, composition of which is compiled in the ratio, mass%:

caustic magnesite

20-25

filler, sawdust

10-15

solution of magnesium chloride

20-25

placeholder, quartz sand

rest

pour on the first layer to the height of the desired size of the product and form installed on the vibrating table to remove air bubbles and levelling filled masses for 1-2 minutes, then perform drying in the drying chamber at a temperature below 16 C, With not less than two days, after which the product is recovered from the form and subject grinding, for example diamond abrasives, until the surface of the image mosaic of amber, which is polished skins.

The proposed method of manufacturing of decorative products filled with amber and/or waste processing is as follows.

Method of manufacturing of decorative products filled with amber and/or waste for decorative products, such as tiles on the surface, includes two stages. According to a predetermined sketch selected and sorted amber and/or waste for the picture, which laid out small pieces of amber on the bottom of the preset sizes and thickness of product. Inlaid picture mosaic pour formulation, which includes caustic magnesite and solution of magnesium chloride in a ratio, mass%: 60-70 and 40-30 to cover completely the picture of a filler in the form of pieces of amber and leave for 5-6 hours. Then composition, the composition of which includes caustic Magnezit solution of magnesium chloride, sawdust, sand in the ratio of components, molding material, mass%:

caustic magnesite

20-25

filler, sawdust

10-15

solution of magnesium chloride

20-25

placeholder, quartz sand

rest

pour on the first layer to the height of the desired size, shape installed on the vibrating table to remove air bubbles and levelling filled masses for 1-2 minutes, then perform drying in the drying chamber at a temperature below 16 C, With not less than two days, after which the product is recovered from the form and subject grinding, for example by the diamond abrasives, until the surface of the image mosaic of amber, which is polished skins.

The applicant may give specific examples of decorative items, received in accordance with the above principles.

Figure 4 shows a picture of the table, tabletop which is a decorative items filled with amber and production wastes in the form of mosaic in the upper layer.

Figure 5 shows a photograph of the panel (Firebird), which is also a decorative weapon in the form of a mosaic, made from amber and waste production.

Decorative surface countertops, and a panel with amber turned out to be durable, environmentally safe, durable, cheap result in simplified manufacturing technology.

Thus, the proposed method for decorative products filled with amber and/or waste production allows get a cheap, environmentally friendly, cost-effective, safe decorative material for use in residential, public places, including schools, hospitals.

Additionally it should be noted that the use of unclaimed waste processing of amber will not only get a variety of decorative products and complex to use amber without waste than it will also improved the ecological situation on the territory of the Kaliningrad amber plant and received additional profit.

1. Method of manufacturing of decorative products filled with amber and/or waste processing, including preparation of moulding mass consisting of magnesia usta magnesite, magnesium chloride solution, filler, filler - quartz sand, with the subsequent forming, sealing vibration, curing, drying, wherein in the capacity of filler used amber and/or its waste, molding prepared in a ratio of components, mass%:

caustic magnesite

20-25

filler - amber

10-15

solution of magnesium chloride

20-25

placeholder - quartz sand

the rest,

fill in the form the desired size, compact vibration during 0.5-1 min, dried at a temperature of 13 to 30 OC for 1-3 days, then remove from the form, grind, Polish, handle the final polishing, for example, a mixture of paraffin and wax pin or, if necessary, varnish.

2. Way manufacturing of decorative products filled with amber and/or waste processing, including preparation of moulding mass consisting of magnesia usta magnesite, magnesium chloride solution, filler, filler - quartz sand, with the subsequent forming, sealing vibration curing, drying, wherein in the capacity of filler is used the amber and/or its waste, method of manufacture includes two stages, the first stage perform all stages according to claim 1, including the completion of drying, in a ratio of components, molding material, mass%:

caustic magnesite

20-25

filler - amber

10-15

solution of magnesium chloride

20-25

placeholder - quartz sand

the rest,

at the second stage molding prepared with the same components, using as a filler sawdust, then molding pour on the first layer to the height of the desired product size, compact vibration within 1-2 minutes, perform drying in the drying chamber at a temperature below 16 C, With not less than two days, and then remove the product from the form, grind, Polish, handle the final polishing, for example, a mixture of paraffin and wax for fixing or, if necessary, varnish.

3. Method of manufacturing of decorative products filled with amber and/or waste processing, including preparation of moulding mass consisting of magnesia usta magnesite, magnesium chloride solution, filler, filler - quartz sand, with the subsequent forming, sealing vibration, curing, drying, wherein in the capacity of filler is used the amber and/or waste production, which is spread by a predetermined pattern, for example, in the form of a mosaic, pour band, which included caustic magnesite and solution of magnesium chloride in a ratio, mass%: 60-70 and 40-30 to cover completely the picture of the filler and leave for 5-6 hours, then molding mass ratio, mass%:

caustic magnesite

20-25

filler - sawdust

10-15

solution magnesium chloride

20-25

placeholder - quartz sand

the rest,

pour on the first layer to the height of the desired product size, compact vibration within 1-2 minutes, perform drying in the drying chamber at a temperature below 16 C, With not less than two days, and then remove the product from form, polished, for example, by the diamond abrasives, until the surface of the image mosaic of amber, which is polished skins.

 

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