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Condensed surfactant system containing microfibre cellulose and method for preparing it

Condensed surfactant system containing microfibre cellulose and method for preparing it
IPC classes for russian patent Condensed surfactant system containing microfibre cellulose and method for preparing it (RU 2471476):
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FIELD: medicine.

SUBSTANCE: invention refers to chemical-pharmaceutical and cosmetic industry and represents an aqueous composition containing a system containing surfactants applicable in transparent surfactant products substantially consisting of water, microfibre cellulose in the concentration of approximately 0.05% to approximately 0.15% (wt/wt), a surfactant in the concentration of approximately 5% to approximately 50% (wt/wt of the active surfactant), suspended particles of inclusions, and optionally an excipient with the composition being transparent.

EFFECT: invention provides making the condensed system containing the surfactant which is transparent and contains suspended particles of inclusions.

15 cl, 5 ex, 5 dwg

 

PRIOR art

Products on the basis of surface-active substances, such as tools for body wash, shampoo, means for washing means for washing car and detergents, among other things often is infilled by using high concentrations of surface-active substances, through a combination of surface-active substances with a synergistic effect on the viscosity or by combining surface-active substances with small amounts of salts, for example sodium salts. Such compositions allow to obtain products with high viscosity, which look dense and homogeneous, but they have a limitation, which is that these products do not provide a sufficiently low shear viscosity to obtain a suspension of particles inclusions. Such particles inclusions can be additives that improve the aesthetic properties (decorative balls, tools, giving pearl glitter, bubbles, scented granules and the like), or active ingredients (insoluble enzymes encapsulated active substances, such as humectants, zeolites), exfoliating tools (e.g., alpha-hydroxy acid and/or glycolic acid or polyethylene beads), vitamins (e.g. vitamin E), etc. or a mix of both.

The standard will zapustit is whether and tools contributing to the formation of suspensions, such as xanthan gum, carboxymethylcellulose (CMC), hydroxyethylcellulose (NES), hypromellose (receiver array) and many types of polyacrylates, do not function well enough in thickened systems, surfactants and often lead to the loss of transparency due to the dimness, gelation and/or phase separation, or loss of sufficient suspendida properties. For example, xanthan gum has an excellent suspendresume properties in some compositions compositions for body wash with a low thickening of surface-active substances, but this gum is often loses its suspendresume properties in systems with high thickening of surface-active substances, which leads to muddy, impure mind and grainy or lumpy texture. Pulp products (CMC, BORE, receiver array, and others), which is another example of a standard thickeners provide unstable suspension and have significant limitations with respect to their compatibility with surfactants. Often use of acrylate systems, but these systems do not always provide a sufficient level of transparency, require high concentrations of the polymer and are not considered natural. Salt is often able to lower high shear viscosity in zag the breeding systems of surface-active substances, but they do not provide long suspendida properties.

So now for industries producing consumer goods, it is desirable to obtain a transparent gelled system surface-active substances suspended in their particle inclusions, as well as a means of facilitating the formation of a suspension, for use in systems with a high content of surface-active substances, where there exist several alternative thickeners.

It was found that microfiber cellulose (MFC), obtained using bacteria or other means can be used to obtain a suspension of particles inclusions in thickened systems, surface-active substances, as well as in compositions with high concentrations of surfactants. It was also found that the MFC can be used for this purpose with auxiliary means or without them. If you use the microfiber pulp obtained by bacteria, it is possible to remove cellular debris, which will provide transparent solutions at commonly used concentrations.

On the microfiber pulp, apparently, does not affect the formation of micelles of surfactants, and it supports a good quality of suspension in these systems. Microfiber cellulose possesses unique is through the ability to operate in these systems, largely because it is more dispersed than solubilizated, thereby provide good suspension properties in these compositions, which otherwise would occur turbidity and/or sedimentation, are often observed when using alternative solubilizing polymers.

The INVENTION

The described system of surface-active substances containing cellulose microfiber. The term "system of surface-active substances" includes, but is not limited to this dense system of surface-active substances and systems containing high concentrations of surfactants. Microfiber cellulose (MFC) includes MFC obtained by microbial fermentation, and MFC obtained by mechanical shredding/destruction of the cellulose fibers derived from grasses, wood or cotton. If you use the microfiber pulp obtained by bacteria, it is possible to remove cellular debris, which will provide transparent solutions at commonly used concentrations. In the present invention surfactants used to produce very thick (high viscosity) systems with high shear rates with particle inclusions suspended in them through the use of micro is lokniti pulp.

The concentration of surfactants in these systems varies from about 5% to about 50% (mass percent active surfactant), although the exact concentration depends on the product. Compositions for body wash usually contain from about 5 mass % to about 15 mass % of a surfactant, liquid, means for washing dishes usually contain from about 20 mass % to about 40 mass % surfactant (concentration equal to 40%, which is characteristic for ultraconservatives" product), and means for washing Laundry typically contain from about 15 mass % to about 50 mass % of a surfactant.

MFC is present in concentrations from about 0.05% to about 1.0%, but the concentration will depend on the desired product. For example, if the suspension of small pellets of alginate in compositions for washing the body, it is preferable to use about to 0.06 mass % MFC, the suspension of air bubbles in compositions for washing the body, it is preferable to use approximately of 0.075 mass % MFC, and for the suspension of air bubbles or balls in the system, containing about 40 mass % of a surfactant, it is preferable to use about 0,150 mass % MFC. In addition, the concentration of MFC can sootvetstvuyuschaya be adjusted, if it is desirable to obtain a system with high transparency. More specifically, very transparent composition for body wash at a concentration of active surfactant in the range from about 5 mass % to about 15 mass % can be obtained when the concentration of the MFC from about 0,055 mass % to approximately to 0.25 mass %.

Particle inclusions, to be suspendirovanie, can be a way of improving the aesthetic properties (decorative balls, tools, giving pearl glitter, bubbles, scented granules and the like). or active ingredients (insoluble enzymes encapsulated active substances, such as humectants, zeolites), exfoliating tools (e.g., alpha-hydroxy acid and/or glycolic acid or polyethylene beads), vitamins (e.g. vitamin E) and the like, or both. Specialist in the art will be apparent, other suitable particles.

The invention also relates to the use of assistive devices (substances) and/or tools that facilitate the process, such as CMC, xanthan and/or guar gum, together with microfiber cellulose systems surfactants described above. A mixture containing cellulose microfiber, are products of the microfiber pulp containing auxiliary materials the performance communications tools. Describes two mixtures: a mixture containing MFC, xanthan gum and CMC in the ratio 6:3:1, and the mixture containing MFC, guar gum and CMC in the ratio 3:1:1. These compounds provide the possibility of obtaining MFC in the form of a dry product that can "activate" high shear deformation or intensive mixing in water or other solutions based on water. "Activation" occurs when a mixture containing MFC, add in water and is hydrated AIDS/tools to ease the process. After hydration AIDS/tools to ease the process usually requires high shear deformation for the effective dispersion of the fibers of the microfiber pulp with obtaining three-dimensional functional network, which has a true yield stress. It was unexpectedly found that an adjuvant and/or a means of facilitating technological process, such as CMC, xanthan or guar gum present in such mixtures on the basis of the microfiber pulp remains solubilisation (after activation in water) in many compositions with a high content of surface-active substances, despite the usual lack of compatibility with systems with a high content of surfactants, that is likely due to low the mi levels in the concentrations of these polymers in the compositions, containing MFC.

The invention also relates to methods of producing the described systems surface-active agents, whether or not containing additives (substances) and/or tools that facilitate the process.

A BRIEF DESCRIPTION of GRAPHIC MATERIALS

The above invention will become clearer after reading the information, confirming the possibility of carrying out the invention, together with Figures 1-5.

INFORMATION CONFIRMING the POSSIBILITY of carrying out the INVENTION

Compositions compositions for washing the body, showing the properties of dense systems of surface-active substances and properties of the suspension, which used a mixture of MFC/xanthan gum/SMS (in the ratio 6:3:1) at a concentration of 0.125 per cent described in Examples 1 and 2. These compositions for body wash parallelt very good transparency and the ability to hold in suspension the air bubbles and balls.

Also described liquid detergent for washing dishes by hand and for washing clothes, which contain higher concentrations of surface-active substances, than in compositions for body wash. Liquid for washing dishes manually, containing suspended particles of alginate described in Example 3.

Liquid detergent for washing clothes containing suspended granules flavor is, described in Example 4.

The filter cake microfiber cellulose was used in Example 5 to obtain a system with a high content of surface-active substances containing concentrated liquid soap for washing clothes and suspended in the air bubbles.

DESCRIPTION of embodiments of the INVENTION

Example 1

There was prepared a liquid composition for washing the body with bubbles. The Figure 1 shows the transparency and suspension characteristics of the system. The obtained composition for washing the body on the basis of visual inspection found the rheological properties of very thick surfactants, possessed the ability to suspendirovanie air bubbles and the limiting shear stress, equal to about 3.4 PA (according to the results of measurement of the rheometer to determine the ultimate shear stress Brookfield®).

Stage A: Deionized water, 10%NaCl and Kathon®CG added to the container for mixing Oster®. The microfiber pulp (a mixture of MFC/xanthan gum/CMC in the ratio 6:3:1) was added on top of the water, and then attached a spatula for mixing Oster®and stirred the mixture at maximum speed for 5 minutes (the speed of "liquefaction").

Stage B: the Contents of the container is moved in a tall glass with a volume of 400 ml with shovels is Oh for mixing paint. Sodium Laureth sulphate (JEELATE®ES-3) was added to the solution described in Stage A, and stirred at 1000 rpm for 5 minutes. Then to the mixture was added sodium cocamidopropylbetaine (JEETERIC®CAB-LC) and was stirred for 5 minutes at 1000 rpm Then added flavoring.

Stage b: To the solution described in Stage B, added cocamide deja. As you add deja was thickening. Then added a 50%solution of citric acid to reduce the pH to the desired level (in this case up to pH 5.5). The contents were removed from the mixer. Air trapped during mixing, was stabilized by the presence of a mixture of MFC/xanthan gum/CMC in the ratio 6:3:1.

Gel for body wash in the shower
Stage of the process Ingredient % (wt./wt.) Grams
And Deionized water 54.775 219,10
Mixture on the basis of the microfiber pulp (a mixture of MFC/xanthan gum/CMC in the ratio 6:3:1) 0.125 0,50
And !0%NaCl solution 5,00 20,00
And Kathon CG 0,10 0,40
B Sodium cocamidopropylbetaine (JEETERIC® CAB-LC) 7,00 28,00
B Sodium Laureth sulphate (JEELATE® ES-3) 25,00 100,00
B Flavor 1,00 4,00
In Cocamide deja 7,00 28,00
In Citric acid (50%solution) On demand On demand
Only 100,00 400,00

Example 2

Composition for washing the body was prepared as described in Example 1, but instead of air bubbles contained a suspension of beads. At the end of the stage, were d is bauleni granules of alginate. A visual representation of this form of exercise can be seen in Figure 2.

Example 3

Systems with a high content of surfactants were prepared using the liquid for hand washing and detergent for washing clothes. The solutions were suspended granules of alginate or air bubbles. Soap for washing dishes Palmolive Ultra®was diluted two times to obtain the dishwashing "normal" concentrations. First, there was prepared a concentrate containing 0.25% of the mixture based on the microfiber pulp (a mixture of MFC/xanthan gum/CMC in the ratio 6:3:1) in deionized water. The concentrate was prepared by mixing the solution in the blender Oster®within 5 minutes at the speed of "liquefaction" (maximum speed). The mixture is then based on the microfiber pulp was diluted in the ratio 1:1 detergent Palmolive Ultra®or Dawn Ultra®(Palmolive® contained 0.1% triclosan) using blades for mixing paints or propeller stirrer. While stirring to a solution of the microfiber pulp was added to soap for washing dishes. As in samples containing detergent Palmolive Ultra®and in samples containing detergent Down Ultra®were received excellent transparency and excellent suspension puzyrko the air and/or alginate pellets. Microfiber cellulose was well diluted, despite the relatively low shear deformation created by the shovel for mixing paint or a propeller stirrer. The yield stress for these solutions was about 2.5 PA. The visual representation can be found in Figure 3.

Example 4

Systems with a high content of surfactants were prepared using the concentrated liquid soap for washing clothes. Was used detergent "All Small and Mighty®triple concentration. 0.25% of the mixture based on the microfiber pulp (a mixture of MFC/xanthan gum/CMC in the ratio 6:3:1) was activated in distilled water using a blender Oster®set the maximum speed (the speed of liquefaction). Mixing time was 5 minutes. The solution microfiber pulp was diluted in the ratio 1:1 by detergent "All Small and Mighty®triple concentration. Was obtained diluted solution with very high transparency and good properties of suspensions with yield strength equal to 0.62 PA. The detergent was placed in a thermostat at a temperature of 45°C to ensure thermal stability, and they showed excellent stability without loss of transparency or reduce the quality of suspension during the 4-week storage. The visual representation can the be seen on Figure 4.

Example 5

Systems with a high content of surfactants were prepared using filtered precipitate cellulose microfiber. Was used detergent "All Small and Mighty®triple concentration. The concentrate filter cake microfiber cellulose content MFC equal to 1.56%, activated in distilled water using a blender Oster®set the maximum speed (the speed of liquefaction). Mixing time was 5 minutes. Activity (%solids content) in the filtered sediment MFC was equal to about 16%, so that the concentration of the active MFC concentrate was approximately 0.25 per cent. The solution microfiber pulp was diluted in the ratio 1:1 by detergent "All Small and Mighty®triple concentration. Resulting dilution was received very good suspension with yield strength equal to 13 PA. The visual representation can be seen in Figure 5.

1. The water composition, comprising a system containing surfactant suitable for use in transparent products on the basis of surface-active substances, consisting essentially of water, microfiber cellulose in a concentration of from approximately 0.05% to approximately 0.15% (wt./wt.), surfactants in a concentration of from when is Erno 5% to about 50% (wt./wt. active surfactant), suspended particle inclusions and, optionally, auxiliary substances, and the composition is transparent.

2. The composition according to claim 1, wherein the microfiber cellulose is present at a concentration approximately equal to 0.06%.

3. The composition according to claim 1, wherein the microfiber cellulose is present at a concentration approximately equal to that of 0.075%.

4. The composition according to claim 1, wherein the microfiber cellulose is present at a concentration approximately equal to 0,09%.

5. The composition according to claim 2, characterized in that the surfactant is present in a concentration ranging from about 5% to about 15% (wt./wt. active surfactant).

6. The composition according to claim 5, characterized in that the particles inclusions contain air bubbles, granules or combinations thereof.

7. The aqueous composition according to claim 1, in which the microfiber pulp is present in the form of a mixture of cellulose microfiber with auxiliary substance containing microfiber cellulose, xanthan gum and carboxymethyl cellulose in the ratio 6:3:1.

8. The aqueous composition according to claim 7, in which the mixture of cellulose microfiber with the auxiliary substance is present in the aqueous composition at a concentration of component a 0.125% (wt./wt.).

9. DNA composition according to claim 1, in which the microfiber pulp is present in the form of a mixture of cellulose microfiber with auxiliary substance containing microfiber cellulose, guar gum and carboxymethyl cellulose in a ratio of 3:1:1.

10. The method of obtaining the aqueous composition according to any one of claims 1 to 6, including:
- combine powdered cellulose microfiber with water and mixing with a high shear deformation;
- adding a surfactant and subsequent mixing;
- add particle inclusions, followed by stirring;
moreover, microfiber cellulose is present in the aqueous compositions in concentrations of from approximately 0.05% to approximately 0.15% (wt./wt.), surfactant present in the aqueous composition at a concentration from about 5% to about 50% (wt./wt. active surfactant), and
thus formed composition is transparent, and the particles suspended in it.

11. The method according to claim 10, wherein the microfiber cellulose is present at a concentration approximately equal to 0.06%.

12. The method according to claim 10, characterized in that the cellulose microfiber is present in the aqueous composition at a concentration of that component of 0.075%.

13. The method according to claim 10, characterized in that the cellulose microfiber is present in the aqueous composition and concentration, component 0,09%.

14. The method according to claim 10, characterized in that the surfactant is present in a concentration ranging from about 5% to about 15% (wt./wt. active surfactant).

15. The method according to claim 10, characterized in that the particles inclusions contain air bubbles, granules or combinations thereof.

 

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