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Cleaning detergent for descaling of heating elements and internal surfaces of laundry washers |
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IPC classes for russian patent Cleaning detergent for descaling of heating elements and internal surfaces of laundry washers (RU 2334790):
Detergent for cleaning of metallic surface / 2326935
Invention is used in metallurgy industry for degreasing rolled metal products on the aggregates of continuous processing before application of different kinds of coatings (zinc, galvalume and etc.). The agent contains in g/l: sodium hydroxide 5.4-12.0, sodium carbonate 3.3-8.2, trisodium phosphate 0.6-1.25, sodium tripolyphosphate 1.0-2.5, hyrdroxyethylated alkylphenol on the basis of propylene trimer containing in a molecule 12 moles of ethylene epoxide 0.17-0.37, polyethyleneglycol esters of synthetic primary alcohol of C12-C14 fraction 0.14-0.23, alkylphenilpolyoxyethelenglycol acetal 0.11-0.28, chelate 0.02-0.075, defoaming agent 0.001-0.0025, water - 1 liter. Mass ratio of the blend of the organic and inorganic part of the composition to the blend of surfactants is 24.5:1. Chelate consists of disodium salt of tetrine, hydrous and trisodium salt of hydroxyetheledenediphosphonic.
Tool for cleaning hard surfaces / 2228951
The invention relates to means for cleaning metal and non-metal surfaces from oil, its vysokoudoynyh components and paraffins
The tool dezinficiruy-washing / 2194072
The invention relates to dezinficiruy-detergents intended for medical disinfection in case of bacterial, viral and fungal etiology in institutions of various types (medical, children, community and everyday life, and can also be used as a bactericide in the extraction of oil or fungicide in the fight against plant diseases
Cleaner / 2144062
The invention relates to cleaning tools and can be used for the purification of communication cables from the hydrophobic filler
Liquid composition for softening fabrics / 2134736
The invention relates to compositions for softening fabrics
Composition for softening fabrics / 2130522
Detergent-disinfectant for treatment of metallic surfaces / 2084498
The invention relates to the technical detergents for disinfection and cleaning of metal products from grease, oil, operational impurities and corrosion products and can be used in the maintenance and repair of machinery in various industries
The method of obtaining textile auxiliaries / 2079485
The invention relates to organic chemistry, namely the synthesis of textile auxiliaries (TBB), which is an ester of maleic acid polyoxyethyleneglycol derived fatty amine, which can be used as softener of textile materials in the processes of final finishes, including
Cleaner / 2054033
"sorti" detergent / 2330877
Invention can be applied in cleaning of hard surfaces, such as kitchen utensils, baths, sinks, glazed tile etc. The substance includes, mass %: active component 1.0-15.0; talc 2.5-5.0; odourant 0.05-0.2; calcium carbonate up to 100. The active component includes, mass %: sodium alkylbenzolsulfonate 12.0-16.0; sodium tripolyphosphate 14.0-18.0; liquid glass 3.0-7.0; sodium carbonate 13.0-17.0; sodium sulfate and water up to 100. Preferable calcium carbonate is milled marble. Additionally it contains 0.5 0.03-2.0 mass % of Tinolux domestic detergent.
Composition of purifying agent / 2323963
Composition, which contains one or several surface active substances (5-95 wt.%), 40 wt.% or more of all surface active substances being non-ionic, and one or several water-swellable polymers, which absorb water in amount exceeding their own weight (5-95 wt.%), is suggested. Weight ratio of surface active substances to water-swellable polymers is within 1:0.4 to 0.4:1. Water-swellable polymer is selected from the following compounds: polyacrylic acids, polyacrylates, cross-linked acrylates, guar gum and derivatives thereof, starch acrylic grafted copolymers, hydrolysates of starch acrylic grafted copolymers, cross-linked polyoxyethylene, cross-linked carboxymethyl cellulose, partially cross-linked water-swellable polymers, such as polyethylenoxide and polyacrylamide, isobutylene/maleic acid copolymers.
Toilet soap with peeling and moistening properties / 2311450
Composition of soft toilet soap contains 20-60 mass % of one or more synthetic surfactants, 10-50 % of moistening agent and peeling particles, wherein at least 20 % of particles have major axis length from 100 to 600 mum.
Cleansing paste to clean solid surface and cleansing paste production line / 2294358
Cleansing paste suitable to clean and sanify enamel and metallic kitchen dishes, sanitary ware such as washing stands, bathes, lavatory pans, gas burners and the like, marble and ceramic surfaces contains, wt %: sulfonol 3-5, soda ash 10-20, odorant 0.4-1.2, mineral sludge coming as waste from production of protein-vitamin concentrate 52-58, brine of naturally occurring bischofite mineral MgCl2·6h2O (density 1.2-1.3 t/m3) 4-6, and water the balance. Cleansing paste production line comprises sulfonol, soda ash, and odorant supply tanks, transportation means, mixer, vibrator for delivering finished produce, off-line and in-line tanks for finished produce, screw dispensing mechanism, finished produce packaging means, and conveyor for delivering packaged cleansing paste. The line is provided with receiving bin for above mineral sludge, drier, intermediate bin for dried sludge, crusher, sieve classifier, tanks for standard and non-standard sludge, cyclone, fan, hose filter to collect dust fraction of sludge, and sliding shutter. Upstream of mixer, bischofite brine and water tanks are disposed.
Solid surface cleaning composition and cleaning process / 2292386
Invention relates to liquid compositions for cleaning solid surfaces and is proved in the form of clear liquid gel with abrasive component and includes one or several cleaning surfactants, abrasive particles, thickening agent and, if necessary, optional components. Abrasive particles dispersed in liquid gel are macroscopic with average particle size between 0.5 and 2.5 mm, all particles having particle size deviation limits ±70% from average particle size.
Liquid abrasion detergent compositions / 2265044
Water alkaline abrasion detergent composition comprises, in mass %, 55-80 of abrasion agent, 0.15-0.40 of anion polymer, 0-0.4 of surface active agent and does not comprise thickening clays or thickening silicon dioxide. The detergent compositions can be ready for use or concentrated with at least 55% in mass of abrasion agent, which a consumer can be diluted up to the product ready for use without loss of long-term stability. The composition is allowed to be packed or canned.
Solid dispersed abrasive compositions and a method of production of liquid abrasive clearing compositions / 2256699
The invention is pertaining to the field of utilization of solid dispersed abrasive compositions for clearing solid surfaces. The dry composition contains a solid material abrasive and a suspending system eligible for production of a stable suspension at mixing with a liquid medium. It is preferable, that the dry composition should contain at least 65 % of solid abrasive and at least 0.1 % of a suspending system. The suitable suspending systems are based on a surfactant or a mixture of surfactants, which are capable to form a laminated micellar phase after mixing with a liquid medium, or on the basis of polymeric infilling systems. A preferential liquid medium is water. The dry abrasive composition is easily flowing and is easily dispersed in water by a consumer with formation of a liquid clearing composition ready for use.
Cleaner / 2235124
The invention relates to the field of household chemicals, namely, powdered tools for sanitary purposes, which can be used to remove dirt from hard surfaces
Cleaner / 2221846
The invention relates to cleaners for cleaning household appliances and can be used independently for cleaning hard surfaces: metal containers, Cutlery, window glass, pottery, porcelain, sinks, toilets, and in complex detergents for cleaning industrial equipment
Detergent for cleaning metal surfaces / 2216581
The invention relates to the technical detergents designed to clean metal surfaces of residual oil and solids, and can be used when cleaning tanks at refineries and rail ways
"sorti" detergent / 2330877
Invention can be applied in cleaning of hard surfaces, such as kitchen utensils, baths, sinks, glazed tile etc. The substance includes, mass %: active component 1.0-15.0; talc 2.5-5.0; odourant 0.05-0.2; calcium carbonate up to 100. The active component includes, mass %: sodium alkylbenzolsulfonate 12.0-16.0; sodium tripolyphosphate 14.0-18.0; liquid glass 3.0-7.0; sodium carbonate 13.0-17.0; sodium sulfate and water up to 100. Preferable calcium carbonate is milled marble. Additionally it contains 0.5 0.03-2.0 mass % of Tinolux domestic detergent.
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FIELD: chemistry. SUBSTANCE: detergent contains in mass %: sodium tripolyphosphate 39, sodium carbonate 42, sodium chloride 12, zeolite or bentonite 4, ethylene oxide mole ethoxylated 8-10 nonyl phenol 2, sodium salt of ethylenediaminetetraacetic acid 1. Single processing cycle provides descaling efficiency to 95-98 %. EFFECT: higher descaling efficiency of all internal surfaces and heating elements of laundry washers. 1 tbl, 3 ex
This invention relates to the field of washing and cleaning agents, in particular washing and cleaning agents for removing scale from the heating elements and the inner surfaces of washing machines. Water coming from natural sources in system domestic water contains hardness salts (mainly carbonates and bicarbonates of calcium and magnesium). Upon heating this water to high temperatures and especially when it is in contact with the surface of the heating elements is a selection of hardness salts with education on all surfaces washed by water, stubborn sludge - scale. The water supplied to industrial power plant such as boilers, are subjected to special treatment, which can remove a large part of hardness salts. In washing machines (household and industrial) uses tap water with salts of rigidity, which leads to the rapid formation of scale on all internal surfaces and especially on the surface of the heating elements. Scaling affects the heat transfer, which leads to failure of the heating elements. In addition, intensive contact erasable products with scale affects the texture of the tissues and reduces their strength. In this regard, the problem of removing scum no doubt. Submitting is shining most of the known washing and cleaning agents for removing scale presents acidic compounds with a low pH of their aqueous solutions. One of the earliest mentions of such media containing urea and hydrochloric acid or citric and maleic acids, refers to 1968 (Ajanovic. Chemical commodities, M., "Light industry", 1968, p.57-58). In the following patent publications available for descaling a number of washing and cleansing compositions based on various acids, in particular acetic and adipic acid (USSR Author's certificate No. 633896), sulfuric acid (USSR Author's certificate No. 768807 publ. 1978), organic dicarboxylic acids (USSR Author's certificate No. 697558 publ. 1979), phosphoric and organic phosphonic acids (Patent USSR No. 1829967, publ. 1993), sulfamic acid (Japanese patent No. 5050095, publ. 1993), phosphonic acid and organic dicarboxylic acids (Japanese patent No. 6154790, publ. 1994), formic acid and one or more carboxylic acids (U.S. Patent No. 5529637, publ. 1995), sulfuric and phosphoric acids in combination with ethylenediaminetetraacetic acid and sodium tripolyphosphate (Patent PRC No. 1144780, publ. 1997), ascorbic and ethylenediaminetetraacetic acid (Patent of Russia №2114215, publ. 1995), an organic acid in combination with hydrogen peroxide and surfactant (Canadian patent No. 2276165, publ. 1999), sulfuric acid, in combination with ethoxylated surfactants (French patent No. 2774371, publ. 199,), ethylenediaminetetraacetic acid and polimolekuly acid (Japanese patent No. 2000-154996, publ. 2000), hydrochloric acid (Patent of Russia №2265671, publ. 2005), sulfamic, nitrilotriethanol acids in combination with ammonium chloride and thiourea (Patent of Russia №2213069, publ. 2003). Above washing and cleaning agents when dissolved in water to form acidic solutions, well and quickly removes scum, but has a corrosive effect. High corrosive power of these resources excludes the possibility of their application for removal of limescale in washing machines. Publications related to washing and cleaning agents, which form when dissolved in water is neutral or slightly alkaline solutions, are able to remove the scum and do not attack the surface to be cleaned, very scarce. In particular, in the Patent PRC No. 1290741 (publ. 2001) offers a washing and cleaning agent for removing scale, which includes sodium hydroxide, sodium chloride, aluminum powder, sodium tripolyphosphate, and surfactant. The test composition proposed in this patent, showed that the process of removing scale from the interior surfaces of the washing machine requires a lot of time, and featured high norm makes it unprofitable. In the other Patent PRC No. 1546401 (publ. 2004) offers a washing and cleaning agent for removing scale, which consists of silica, sodium carbonate, sodium tripolyphosphate, salt of an alkali metal, in particular sodium chloride and alumina. Cost to use this composition is not suitable, because the authors recommend pre-listed components subjected to sintering at 1000-1500°C. The ideas contained in the above patents PRC, developed in the patent of Russia №2259392 (publ. 2005). Washing and cleaning agent described in this patent contains anionic surfactant, sodium tripolyphosphate, sodium carbonate, sodium chloride, sodium sulfate, ethoxylated Nonylphenol and some specific supplements are only necessary when washing clothes. We conducted tests of this tool (reproduced without specific additives) showed that solutions of this tool does not corrode any of the internal surfaces of the washing machine and well remove the scum. The only drawback of this tool, we have adopted as a prototype of this invention is that the efficiency of removing scale formed after three months of operation of the washing machine, not exceed (single treatment) 70%. To eliminate this drawback is proposed in composition among the STV, containing surfactant, sodium tripolyphosphate, sodium carbonate and sodium chloride, to enter the zeolite or bentonite and additionally sodium salt of ethylenediaminetetraacetic acid as a surfactant to use ethoxylated 8-10 moles of ethylene oxide Nonylphenol. Below is the proposed ratio of components, wt.%:
The technical result of the use of the proposed structure is in a significant increase of efficiency of scale removal from all internal surfaces and heating elements of washing machines. After a single processing cycle of the washing machine offered by the tool is removed up to 95-98% of the formed scale. The technical result is achieved by the fact that the washing and cleaning agent for removing scale from the heating elements and the inner surfaces of tyranny machines, containing surfactant, sodium tripolyphosphate, sodium carbonate and sodium chloride, further comprises a zeolite or bentonite and sodium salt of ethylenediaminetetraacetic acid as a surfactant is ethoxylated 8-10 moles of ethylene oxide Nonylphenol. Below is a brief description of zeolite and bentonite, the introduction of which into the composition of the proposed tools is its main distinguishing feature. Zeolite is a mineral of volcanic origin with high adsorption and ion exchange properties. All zeolites consist primarily of galantaminenoxide mixed with small amounts of clay and feldspar. When dehydration of zeolites form a fine crystal sponge with a pore volume of about 50% of the total volume of the mineral. Zeolites are thermally stable, chemically and mechanically hours, do not contain toxic compounds. Bentonite is dispersed clay with high binding and adsorption ability. Mineralogicheskii all bentonites include montmorillonite, salonic, napravit and baudelet. Origin is volcanic. Bentonites are good sorbents and capable of swelling in aqueous solutions. Does not contain toxic substances. Technology of preparation of the proposed means and means-FR the type shown in Example 1; methods of evaluating the effectiveness of removing scale in Example 2; the results of experiments on the removal of sludge in Example 3. Example 1. Technology of preparation of the proposed means of the prototype. The proposed tool and the tool prototype was prepared in an amount of 10 kg each in a laboratory drum mixer with a capacity of 20 kg Pre-method triturate preparing a mixture of parts of sodium tripolyphosphate ethoxylated with 8-10 moles of ethylene oxide with Nonylphenol (Neonol AF 8-10). The mixture was prepared manually in a porcelain bowl in the following way: 0.2 kg of neonols was mixed with 0.4 kg of sodium tripolyphosphate. To this mixture was added 0.6 kg of sodium tripolyphosphate and received 1.2 kg of the mixture was added 1.2 kg of sodium tripolyphosphate. After thorough mixing, the mixture containing 0.2 kg of neonols and 2.2 kg of sodium tripolyphosphate were loaded into the mixer. Then the mixer was consistently downloaded 2.8 kg of sodium tripolyphosphate, 3.0 kg of sodium carbonate, 1 kg of sodium chloride, 0.7 kg of zeolite or bentonite and 0.1 kg of sodium salt of ethylenediaminetetraacetic acid (trylon B). The tool prototype was prepared by the same technology in accordance with the recipe shown in the description of the Patent of Russia №2259392 taken as a prototype. In this process we used the following components: anionic surfactants, in particular alkylbenzoic Thonet sodium, sodium tripolyphosphate, sodium carbonate, sodium chloride, ethoxylated Nonylphenol (neonol AF 8-10), sodium sulfate and liquid glass. Other components (carboxymethylcellulose, polycarboxylate, optical Brightener and perfume), which is needed in the Laundry in the composition prepared means the prototype is not included. The duration of mixing upon receipt of the proposed means of the prototype was 2 hours. Example 2. Methods of evaluating the effectiveness of descaling For testing 20 samples prepared aluminum foil size 50×50 mm each, and 20 samples of stainless steel mesh sizes 20×20 mm hole size is approximately 2×2 mm Prepared samples foils and meshes separately weighed on an analytical balance with an accuracy up to the fourth digit, getting the total initial weight of the sample foil (Mof) and the total initial weight of the sample grid (Modwith). The weighted samples are artificially covered with scum. To do this, they were immersed in a glass heat-resistant glass, which was filled with a solution containing 0.5 DM3drinking water, 2.0 g of calcium carbonate, 2.0 g of magnesium carbonate and 0.2 g of iron sulfate. The solution was lowered and the stirrer at slow (30 min-1) stirring the solution was evaporated on a sand bath almost the DOS is and. Then the samples foil and mesh was transferred into a porcelain Cup and dried to constant weight in a drying Cabinet at 110°C. the Samples foil and mesh separately weighed to the fourth decimal getting a lot of samples with foil scale (Mfand a lot of samples with grid scale (Mwith). A lot of scum on the foil (Mnfand a lot of scale on grids (Mnwith) received by the formulas accordingly Mnf=Mf- Mofand Mnwith=Mwith- Mowith. To assess the effectiveness of removing scale in drum standard automatic washing machine was filled with 200 g of the proposed investment (in one case with the zeolite, the other with bentonite) or 200 g of product prototype. Then put on 20 samples of foil and grid scale. The car was launched in native mode (without linen) and the treatment was conducted at 90°after full testing program, samples of foil and mesh was removed from the car, washed with running tap water and dried in a drying Cabinet at 110°C to constant weight. In the weighing result received weight cleaned from scale samples foil and mesh respectively Mof 2and Mowith 2. The number of remaining samples on the scale was calculated by the formulas: for foil Bridgef=Mof 2- Mofand for a grid Bridgewith=M is with 2- Mowith. The removal efficiency of scale in % separately for foil (EF) and separately for the mesh (es) calculated by the formulas: and Example 3. The results of the evaluation of the effectiveness scale removal using the proposed tools (options with zeolite and bentonite) and using the prototype The procedure of applying and removing scale samples with foil and mesh, as well as the calculation of the efficiency of its removal was performed as described in example 2. The preparation of both versions of the proposed funds, and funds of the prototype was carried out as described in example 1. The results of the tests are presented in table 1. Results of experiments on the removal of scale
Washing and cleaning agent for removing scale from the heating elements and the inner surfaces of washing machines, containing surfactant, sodium tripolyphosphate, sodium carbonate and sodium chloride, characterized in that it further comprises a zeolite or bentonite and sodium salt of ethylenediaminetetraacetic acid as a surfactant is ethoxylated 8-10 moles of ethylene oxide Nonylphenol in the following ratio, wt.%:
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