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"sorti" detergent

IPC classes for russian patent "sorti" detergent (RU 2330877):
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Granulated synthetic detergent bi 10 (options) / 2329297
Invention pertains to compositions of granulated synthetic detergents, meant for manual and machine washing (in any type of machine) and soaking all types of textiles, including coloured and other household needs. The detergent contains the following components in the given % mass: anionic surface active agent sodium alkylbenzenesulfonate 9-12; non-ionic surfactant 2-5; sodium tripolyphosphate 15-30; dispergator 0.3-1.2; carboxymethyl cellulose 0.3-0.7; sodium silicate 3-6; modified polyalkylene glycol 0.2-0.6; enzyme 0.3-0.8; sodium carbonate 6-12; photo-bleaching agent 0.003-0.020; optical brightener 0.05-0.20; fragrance component 0.1-0.3; sodium sulphate and water up to 100. The non-ionic surfactant preferably contains oxyethylated monoalkylphenols based on propylene trimers or oxyethylated fatty alcohols. The dispergator used is sodium polyacrylate or sodium salt of a copolymer of maleic or acrylic acid or a sodium salt of a copolymer of acrylic, methacrylic and maleic acid. Alternatives of the synthetic detergent are also described.

FIELD: chemistry.

SUBSTANCE: invention can be applied in cleaning of hard surfaces, such as kitchen utensils, baths, sinks, glazed tile etc. The substance includes, mass %: active component 1.0-15.0; talc 2.5-5.0; odourant 0.05-0.2; calcium carbonate up to 100. The active component includes, mass %: sodium alkylbenzolsulfonate 12.0-16.0; sodium tripolyphosphate 14.0-18.0; liquid glass 3.0-7.0; sodium carbonate 13.0-17.0; sodium sulfate and water up to 100. Preferable calcium carbonate is milled marble. Additionally it contains 0.5 0.03-2.0 mass % of Tinolux domestic detergent.

EFFECT: obtaining of a detergent with excellent consumer properties, such as high cleaning capacity and stain removal efficiency, as well as reduced slumping tendency.

4 cl, 2 tbl

 

The invention relates to the chemical industry, namely the composition of household chemicals for cleaning hard surfaces - kitchen utensils, tubs, sinks, tile, etc.

One of the largest, important appointment and on a wide range of groups household is a group of cleaners.

Known means for cleaning hard surfaces, containing surfactant, peroksoborat sodium, soda ash, sodium tripolyphosphate, sodium silicate, odorant, abrasive. (SU 1286622 A1, 30.01.1987, C11D 3/14).

Lack of funds is low cleaning ability 78-83%, whitening ability 70-73%.

Known means for cleaning hard surfaces, containing in wt.%:

Surfactant 4-5
Soda ash 4-5
Sodium tripolyphosphate 8-10
Alumina 15-20
Perfume 0,1-0,2
Gypsum up to 100.

Additionally contains liquid sodium glass (EN 2016058 C1, 15.07.1994, C11D 3/14).

The disadvantage of this tool is not sufficiently high cleaning ability.

The closest technical solution is a cleaning cf is the rotary, containing in wt.%:

Calcium carbonate (marble) 65,0-80,0
Oxalic acid 10,0-16,0
Sodium carbonate and/or hydroxide of potassium or sodium 3,0-10,0
Talc 1,0-5,0
The sodium sulfate up to 100.

Additionally contains a surfactant of the anionic or nonionic type. (EN 2235124 C1, 27.08.2004, C11D 3/14).

However, the tool when it is in powdered form, is sensitive to moisture, since its presence may be the reaction between oxalic acid and calcium carbonate, which leads to caking detergent.

The objective of the invention is to provide cleaning products with high consumer properties - high cleaning ability, high efficiency for the removal of contaminants, as well as a reduced tendency to caking.

This is achieved in that the cleaning agent of the present invention contains the following components in wt.%:

12,0-16,0
Active component 1,0-15,0
includes:
Las sodium
Sodium tripolyphosphate 14,0-18,0
Liquid glass 3,0-7,0
Sodium carbonate 13,0-of 17.0
The sodium sulfate and water 100
Talc 2,5-5,0
Perfume of 0.05-0.2
Calcium carbonate up to 100.

In addition, the active component may additionally contain Cinelux BMS in the amount of 0.5-2.0 wt.%.

Thus, the totality of the members of the funds ingredients taken in the above quantitative limits, provides high cleaning power tool in relation to various kinds of pollution. The tool does not cake and preserves the stability properties when stored.

The active component of the cleaning agent contains as a surfactant Las sodium (sulfonic acid). Also contains sodium Tripolyphosphate and sodium carbonate (soda ash), which are introduced to increase the cleaning capacity of the facility and as logomachy components. Soda ash, also amylee fatty pollution, complements and enhances the cleaning effect of the surfactant. Sodium tripolyphosphate shows the inhibitory effect due to the absorption on the surface of the articles is s and create a protective film, and removing the aqueous solution. Liquid glass enhances the effect of sodium tripolyphosphate on the process of cleaning products, as it eliminates the harmful influence of natural water hardness, suspenseful and peptizyme impurities and prevents their re settling on the surface to be cleaned, amplifies the effect of soda ash to neutralize acidic pollution. The sodium sulfate is used in medicine as filler.

According to the invention the detergent may contain a small amount of cyan dye, which allows to further increase the degree of purification and white, as well as to give granules turquoise color. Particularly suitable dye is Cinelux BMS (trading company Ciba-Geigy).

When testing different formulations of the active component revealed that the best qualities of the active component, having the following composition, wt.%:

Las sodium 12,0-16,0
Sodium tripolyphosphate 14,0-18,0
Liquid glass 3,0-7,0
Sodium carbonate 13,0-of 17.0
The sodium sulfate and water up to 100.

Used in cleaning products as an abrasive calcium carbonate provides effective is mehanicheskoe remove dirt from the surface being cleaned.

Calcium carbonate can be used, in particular, in the form of chalk or crushed marble. It is preferable to use calcium carbonate in the form of crushed marble, because it has a high bulk density compared to chalk that allows you to use a more compact package.

Fundamentally important is the use in formula talc. As shown by the authors of the experimental study, talc adsorb iron ions, thereby increasing the efficiency of rust removal. Talc also performs in the claimed composition of functions abrasive and filler. In addition, as the test showed, thanks to the introduction of talc declare the tool does not cake during storage.

As odorants use lemon Twist (Lemon Power) 419641, Apfel (Apfel) 765247, Aqua Fresh (Aqua Fresh) 139438, mint (Mint) 158127. Perfume is introduced into the composition to give the vehicle a pleasant smell, to mask the odor of raw materials, while reducing the content of odorants less than 0.05% poorly masked the smell of raw material during the storage means, when increased above 0.2% of the smell is too intense.

Cleaning agent of the present invention is obtained by mixing ingredients in its composition, in a typical industrial mixer.

To clean the tool with the piece of cloth put on VL is the author contaminated surface. Rubbed across a contaminated surface and spend cleaning it with a subsequent water wash. After cleaning the dishes gets a nice clean look.

The possibility of implementing the claimed invention shown in the examples of specific performance, without limiting its scope.

Table 1
Components CMC Content in wt.%
1 2 3 4
The active component 1,0 5,0 8,0 to 12.0
Las sodium 15,0 to 12.0 14,0 13,0
Sodium tripolyphosphate 13,0 15,0 16,0 to 12.0
Liquid glass 5,0 3,0 4,0 6,0
Sodium carbonate to 12.0 11,0 15,0 13,0
Cinelux BMS 1,5 - 1,5 -
The sodium sulfate and water 100 100 100 100
Talc 2,5 4,0 3,0 5,0
Perfume
Lemon Power 419641 0,1 - - -
The Apfel 765247 - 0,1 - -
Aqua Fresh 139438 - - 0,1 -
Mint 158127 - - - 0,1
Calcium carbonate marble crushed 100 100 100
Calcium carbonate - chalk - - - 100

The cleaning ability is determined on the cleaning device through a uniform abrasion cleaner film pollutant with the subsequent measurement of white plates on photovoltaic blastomere FB-2. Using the color comparator type FCCS define whiteness before washing and after washing.

Caking means was determined by keeping a portion of the funds in a humid atmosphere (in a desiccator with water) for 2 weeks. Caking was assessed visually by the presence of stone-like conglomerates in the mass of the test tools. The absence of these conglomerates indicates nelieve the barb means.

Table 2
Example No. Cleaning ability, % Caking
1 99,0 no
2 99,0 no
3 100,0 no
4 99,8 no
EN 2230104 98,0 no

The results are given for samples obtained in industrial conditions.

Ready detergent is a powder of white colour with turquoise or white granules and has a pleasant smell of lemon, Apple, sea freshness or mint.

Based on data presented, we can conclude that the claimed detergent allows you to extend the range of high quality cleaners, high cleaning ability. When cleaning household appliances offer cleaning agent on the surface of the objects do not appear cracks. Ware has a high percentage of white after washing composition prepared funds. Also this tool provides a high cleaning ability against various contaminants. The tool h is compressed and preserves the stability properties when stored.

1. Cleaning agent, containing the following components, wt%:

active component 1,0-15,0
including: Las sodium 12,0-16,0
sodium tripolyphosphate 14,0-18,0
liquid glass 3,0-7,0
sodium carbonate 13,0-of 17.0
the sodium sulfate and water 100
talc 2,5-5,0
perfume of 0.05-0.2
calcium carbonate 100

2. Cleaning agent according to claim 1, characterized in that it contains calcium carbonate in the form of crushed marble.

3. Cleaning agent according to claim 1, characterized in that it further comprises Cinelux BMS, in the amount of 0.5-2.0 wt.%.

4. Cleaning agent according to claim 1, characterized in that as odorants contains lemon Power 419641, or Apfel 765247, or Aqua Fresh 139438 or mint 158127.

 

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