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Procedure for thermal treatment of solid domestic and industrial waste

IPC classes for russian patent Procedure for thermal treatment of solid domestic and industrial waste (RU 2424334):
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FIELD: metallurgy.

SUBSTANCE: wastes are treated in Vanyukov's furnace with slag melting, supplying charge and oxygen containing gas through tuyeres into slag melting. Charge is melted and slag is generated at temperature 1250-1400°C. The procedure is implemented in the furnace wherein height of tuyeres can be changed. With growth of the lowest working heat-producing capacity of charge height of axis of tuyeres arrangement from a bottom of the furnace is increased. Value of ratio of blast of oxygen containing gas (nm3/hour per 1 m2 of cross section of a furnace) and the lowest working heat-producing capacity of charge (kJ/kg) is maintained within the ranges of 0.07-0.12 facilitating degree of carbon burning-out in charge to its residual content in slag at the level of 0.1-0.15%.

EFFECT: environmental safety of produced liquid and gaseous products of processing for their further utilisation, also maximal low combustible charge components under-burning for maximal utilisation of energy of processed waste.

1 tbl, 1 ex

 

The invention relates to pyrometallurgy - ways of recycling (waste, industrial products), containing different metals (lead, zinc, tin and others) and the carbon in the furnace with a slag melt, and can also be used for processing waste from other industries, such as housing and utilities (solid waste), chemical and petrochemical production (combustible waste), military-industrial complex and other

Known pyrometallurgical methods - analogues: the process of melting in the liquid bath - PGW (Likiernik M.M. and other slag Recycling of non-ferrous metallurgy. - M.: metallurgy, 1977, s and Vanyukov A. V., and others Melting in the liquid bath. - M.: metallurgy, 1988, s). These methods include loading recyclable materials containing lead, zinc and other metals, in caisson shaft type furnace, melting in barotraumas bath melt, the release of the melt drainage gazopylevogo from the oven. The process is conducted at a temperature of melt 1100-1200°C. the Disadvantages of these methods are large energy consumption when PGW costs of technological oxygen; low quality target product (Perevozchikov); low coefficients of teplooborudovanie from post-combustion flue gases; the malfunction of the blower devices without enrichment of blast oxygen furnaces PGW and other

Closest to the technical essence and the achieved effect to the claimed is a method of thermal processing of solid household and industrial waste in Vanyukov furnace with a slag melt, including the filing of the charge and the oxygen-containing gas through tuyeres in the slag melt and melting the mixture with the formation of slag temperature 1250-1400°C (EN 2079778, CL F23 5/00, 1997).

The known method provides for the loading of these wastes in Vanyukov furnace with a slag melt together with the carbon-containing fuel, which is used as carbon-containing solid waste or biogas solid waste landfills, in the molten slag bath and blowing oxygen-containing gas in the mixture gas diluent having a minimum content or not containing impurities of nitrogen and its compounds, through tuyeres with a certain intensity of the blast, and melting the mixture with the formation of slag temperature 1250-1400°C. the Disadvantages of this method is the inability to achieve constant temperature and the required phase composition of the slag in the furnace volume, the environmental security of the obtained liquid and gaseous food processing and the effectiveness of their subsequent disposal.

The objective of the invention is to achieve ecological security of the resulting liquid and gaseous conversion products for their further use in people's lives, as well as the lowest incomplete burning of combustible components of the charge for maximum energy recovery of waste.

T is khnicheskie the result is achieved by the method of thermal processing of solid household and industrial waste in Vanyukov furnace with a slag melt, including the filing of the charge and the oxygen-containing gas through tuyeres in the slag melt and melting the mixture with the formation of slag temperature 1250-1400°C, is carried out in a furnace, is made with the possibility of changing the height of the tuyeres, the height of the axis of the tuyere from the bottom of the furnace increases with the increase of the lower working calorific value of the charge, and the ratio of the intensity of the blast (nm3/h at 1 m2the cross-section of the furnace) and the lower working calorific value of the mixture (kJ/kg) maintained within the range 0,07-0,12 to provide the degree of burning of the carbon charge to its residual content in the slag at the level of 0.1-0.15%.

The above distinguishing features dictated the following.

Municipal solid waste composition (combustible components of carbon, hydrogen) provide the determined processing) due to its own calorific value with a corresponding oxygen enrichment of blast (i.e. achieved autogenous mode). Adding to municipal solid waste industrial waste with no calorific value, but containing non-ferrous and other metals (podshihtovkoj is from the point of view of utilization and improve efficiency% the SSA due to the extraction of precious metals in commercial product), the recycling process requires the introduction into the melting unit (in a bath of slag melt) additional fuel (gas, solid or liquid).

Studies show that the basic nitrogen and sulphur oxides are formed from the gas agents (air) and fuel (natural gas - content of up to 1% H2S, coal and fuel oil 3% S and more), and form of these elements in the waste formation and evolution in the gas phase oxides (NOxand SO2are less pronounced. Therefore, a more appropriate direction in improving environmental performance in this respect (reducing emissions) should be considered for addressing the causes (factors) pollution of exhaust gases emanating from the blast for more fuel and intake air in the working volume of the melting unit.

In existing methods of processing waste in barotraumas slag bath (including Vanyukov furnaces (PV)) melt blowing everywhere conduct air-oxygen mixture, and the regulation and fixation values required for the process of enrichment of the blast with oxygen is carried out by increasing or decreasing the flow of air as the diluent gas. The presence of high content of nitrogen in the feed air at normal process temperatures 1250-1450°C leads to the formation of harmful substances oxides AZ is in the process tail gases, cleaning which requires large capital and operating costs and are not always effective. Replacement air gases or vapours, not containing nitrogen (for example, carbon dioxide, water vapor), allows to solve the problem at the stage of melting waste (in my head). In the same direction operates the suction gas in the working volume (i.e. the free space above the slag bath melt) melting unit (usually the furnace RO operate at vacuum of-30-50 PA or more): the lower the vacuum, the lower the intake of ambient air (nitrogen) in the furnace space with high temperatures and therefore less possibility of pollution of exhaust gases oxides of nitrogen.

Recycling of different waste Vanyukov furnace with a slag melt and primarily carbonaceous combustible household and industrial waste has a number of advantages over other processing methods. The main advantages of this processing are:

1. Full environmental safety of the process due to the inability of education in the furnace primary and secondary toxic organic compounds, dioxins, furans, etc.

2. The minimum degree of incomplete combustion of combustible components of the processed charge, despite the fact that such wastes are essentially reconditio the fuel with low calorific value. This is due to the high oxidizing activity emulsion high temperature of the slag melt blown gaseous oxidant with an oxygen content of not less than 40%.

3. Easy regulation of the mineral composition, resulting from the recycling of slag due to the possibility feed directly into the furnace fluxing materials, which may be obtained slag required for use in the construction industry, including in the cement industry chemical and phase composition.

4. The possibility of achieving environmental security of the resulting gaseous and liquid products for further use in people's lives, as well as the lowest incomplete burning of combustible components of the charge for maximum energy recovery of waste, it is advisable to get the slag must have a minimum carbon content.

However, to obtain the necessary phase composition of the slag for further utilisation, in particular in the cement industry, as well as for the extraction of metals in the form of bottom phase and/or sublimates it is necessary to prevent saturation of the slag oxygen that can be achieved due to the presence of the slag residual carbon content.

From practice Vanyukov furnaces that use to maintain idle speed furnace p is ready hot downtime solid carbonaceous fuel, it is known that the residual carbon content in the slag to maintain its fluidity without pereokislenie, on the one hand, and ensure minimum underburning not more than 4% on the other hand, should be maintained in the range of 0.1-0.15%.

Special studies have found that maintaining a residual carbon content in the produced from the furnace slag is ensured by the adjustment of two parameters describing the geometry of the furnace and its mode of operation depending on the lowest working calorific value of the processed mixture.

It was proposed that the processing of solid domestic and industrial waste to be implemented in Vanyukov furnaces, made with the possibility of changing the height of the tuyeres, however, as the experiments showed, the height of the axis of the tuyere from the bottom of the furnace increases with the increase of the lower working calorific value of the charge, and the ratio of the intensity of the blast (nm3/h at 1 m2the cross-section of the furnace) and the lower working calorific value of the mixture (kJ/kg) maintained within the range 0,07-0,12. The degree of burning of the carbon charge to its residual content in the slag is provided at the level of 0.1-0.15%.

The mechanism of such control residual carbon content in the slag presumably consists in the following:

1. Changed the e to the height of tuyeres

When increasing the calorific value of the charge to save thermal stresses of the working space within the volume of the slag bath melt, while maintaining the specified performance of the furnace requires the increase of the slag melt in the furnace. The increase in the volume of the melt is achieved by increasing its height. So to save the amount of slag above the level of the tuyeres, it is necessary to increase the height of their location relative to the bottom.

2. Changes in the intensity of blast

The increase in calorific value of the charge under other equal conditions (heat stress workspace specified performance, the amount of slag. Located above the level of the tuyeres) requires in order to avoid local overheating of the reaction volume (especially in the near-wall region) for more uniform distribution of oxygen in nadvoresna volume that can be achieved only by increasing the intensity of the blast, referred to the cross-sectional area of the furnace in the region of the tuyeres.

A specific example of implementation of the proposed method

Examination of the claimed invention was carried out on pilot plant melting in the liquid bath Ryazan experimental plant Gintsvetmet (ROAMS) - Vanyukov furnace, made with the possibility of changing the height of lances from the bottom of the furnace. The processing of the design were subjected to various carbon-containing wastes with lower working calorific value from 5330 up 16960 kJ/kg.

The height (H) location lances from the bottom of the furnace and the intensity of the blast (I)supplied through the tuyeres installed depending on the values of the lower working calorific value of the processed charge (Qpn).

Determination of the residual carbon content in the slag was produced by sampling slag at release it from the oven, which were analyzed using infrared spectroscopy in the gas analyzer "LECO CS -300" with detection limits of 0.0004 to 3.5%.

Processing was subjected to zinc clinker production (Qpn=5330 kJ/kg). The height of the lances from the bottom of the furnace was 960 mm; the ratio of the intensity of the blast (nm3/h at 1 m2the cross-section of the furnace) and the lower working calorific value of the mixture (kJ/kg) supported within 0,07-0,12. The degree of burning of the carbon charge to its residual content in the slag was 0.1 to 0.15%.

In the processing of municipal solid waste (MSW) with a higher value of the lowest working calorific value of the charge (Qpn=6290 kJ/kg) the height of the axis of the tuyere from the bottom of the furnace was 1100 mm, the ratio of the intensity of the blast (nm3/h at 1 m2the cross-section of the furnace) and the lower working calorific value of the mixture (kJ/kg) supported within 0,07-0,12. The degree of burning of the carbon in the mixture prior to its residual content in the slag was 0.1 to 0.15%.

In the processing of low grade coals (Qpn=16960 kJ/kg) the height of the axis of the tuyere from the bottom of the furnace was 1500 mm, the ratio of the intensity of the blast (nm3/h at 1 m2the cross-section of the furnace) and the lower working calorific value of the mixture (kJ/kg) supported within 0,07-0,12. The degree of burning of the carbon charge to its residual content in the slag was 0.1 to 0.15%.

The research results are summarized in table 1.

The proposed method provides high ecological purity of the process, reduces operating costs smelting, increases the complexity of the use of waste can be achieved practically without waste and provides maximum closed loop recycling, increased involvement in processing a wide variety of industrial (including waste) waste with high efficiency.

Table 1
No PP The value of I/Qp The value of H/Qp The carbon content in the slag, wt.% Note
Processing concertinaed production
1 0,05 0,18 0,25
2 0,07 0,18 0,15 Optimal results
3 0,12 0,18 0,10 Optimal results
4 0,14 0,18 0,08
5 0,1 0,06 n/a
6 0,1 0,08 0.10 Optimal results
7 0,1 0,2 0,14 Optimal results
8 0.1 0,28 0,22
The recycling of solid waste
1 0,04 0,175 0,33
2 0,07 0,175 0,15 Optimal results
3 0,12 0,175 0,11 Optimal results
4 0,15 0,175 0,06
Processing of low grade coals
1 0,05 0,088 0,28
2 0,07 0,088 0,14 Optimal results
3 0,11 0,088 0.10 Optimal results
4 0,088 0,07

The method of thermal processing of solid household and industrial waste in Vanyukov furnace with a slag melt, including the filing of the charge and the oxygen-containing gas through tuyeres in the slag melt and melting the mixture with the formation of slag temperature 1250-1400°C, characterized in that it is carried out in the oven, made with the possibility of changing the height of the tuyeres, the height of the axis of the tuyere from the bottom of the furnace increases with the increase of the lower working calorific value of the charge, and the value of the ratio of the intensity of blowing oxygen-containing gas (nm3/h at 1 m2the cross-section of the furnace) and the lower working calorific value of the mixture (kJ/kg) maintained within the range 0,07-0,12 ensuring the degree of burning of the carbon charge to its residual content in the slag at the level of 0.1-0.15%.

 

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