|
Hydrogen-oxygen mixture generator |
|
IPC classes for russian patent Hydrogen-oxygen mixture generator (RU 2252275):
Preparation of vanadium electrolyte with aid of asymmetric vanadium-reducing electrolyzer and use of asymmetric vanadium-reducing electrolyzer for reducing electrolyte charge state balance in operating reduction-oxidation vanadium battery / 2251763
Novelty is that acid vanadium electrolyte liquor that has in its composition V+3 and V+4 in desired concentration ratio introduced in electrolyte solution is produced from solid vanadium pentoxide by electrochemical method while at least partially reducing dissolved vanadium in acid electrolyte liquor; for the purpose electrolyte liquor is circulated through plurality of cascaded electrolyzers at least partially to V+3 degree; in this way reduced vanadium incorporating electrolyte liquor leaving the last of mentioned electrolyzers enters in reaction with stoichiometric amount of vanadium pentoxide to produce electrolyte liquor incorporating in effect vanadium in the V+3 form; acid and water are introduced to ensure definite molarity of liquor and the latter is continuously circulated through cascaded electrolyzers; stream of electrolyte liquor produced in the process that incorporates V+3 and V+4 in desired concentrations is discharged at outlet of one of electrolyzers of mentioned cascade. Each electrolyzer is distinguished by high degree of asymmetry and has cathode and anode of relevant surface morphology, geometry, and relative arrangement for setting current density on anode surface exceeding by 5 to 20 times that on projected cathode surface, oxygen being emitted from anode surface. Asymmetric electrolyzer of this type can be used in one of electrolyte circuits, positive or negative, of operating battery (cell) for reducing balance of respective oxidation degrees of their vanadium content.
Method of a ferric iron hydroxide hydrosol production / 2250914
The invention is intended for a chemical industry, an agriculture and pedology and may be used at production of solutions for soils reclamation. 0.5 l of a ferric chloride solution with concentration of 0.5 l/mole gram-molecule is poured into a pan. Carbon electrodes are put into the solution. Pass a current of 1А. Each 5-60 seconds polarity of the electrodes is changed. In a result of replacement of anions of the salt for ions of the hydroxyl obtain a stable hydrosol of the ferric iron hydroxide. The invention allows to produce such sols using a simple and a production-friendly method commercially.
Electrode, apparatus and method for electrolytic treatment of liquid, system for regenerating soil in situ and unit for performing reduction-oxidation reactions / 2247175
Electrode includes elongated, mainly hollow body made of porous material characterized by comparatively low electric conductivity, connector in the form of elongated electrically conducting member connected to power source. Connector passes along inner cavity of electrode body and it has contact with surface of inner wall of body in large number of places mutually spaced along length of body for distributing electric current supplied from power source practically uniformly along electrode.
Electrode, apparatus and method for electrolytic treatment of liquid, system for regenerating soil in situ and unit for performing reduction-oxidation reactions / 2247175
Electrode includes elongated, mainly hollow body made of porous material characterized by comparatively low electric conductivity, connector in the form of elongated electrically conducting member connected to power source. Connector passes along inner cavity of electrode body and it has contact with surface of inner wall of body in large number of places mutually spaced along length of body for distributing electric current supplied from power source practically uniformly along electrode.
Method of saturation of water with oxygen and plant for realization of this method / 2247081
Proposed method includes successive ejection-floatation mixing of plasma-chemotronic method of vapor-and-gas mixture H2O2+02 with water. Plant proposed for realization of this method includes two systems interconnected by means of vapor-and-gas pipe line: ejection-floatation system and vapor-and-gas producing system. Ejection-floatation system for saturation of water with oxygen is provided with pump, ejector and pressure floatation column interconnected by circulating pipe line. In its lower part column is connected to starting water pipe line and in upper part it is connected to oxygen-saturated water pipe line. Ejector is mounted in circulating pipe line between lower part of column and pump and is connected to vapor-and-gas mixture producing system by means of vapor-and-gas pipe line. Closed electrolyte circulating system for obtaining the vapor-and-gas mixture includes gas-and-liquid separator, electrolyte reservoir, plasma-chemotronic apparatus whose lower part is connected with air or oxygen supply pipe line through flow regulator.
Method and complex for preparing of bottled oxygen- saturated water / 2246882
Method involves producing oxygen-saturated water by ejection-floatation mixing of water with oxygen-containing gas; bottling oxygen-saturated water and capping, with gas-and-vapor H2O2+O2 mixture synthesized by plasma chemotronical method being used in all above operations. Complex of equipment comprises ejection-floatation unit for oxygen saturation of water and installation for supplying and bottling of oxygen-saturated water.
Method for the production of anode paste (options) / 2242538
The invention relates to the field of electrode production and can be used in the manufacture of anodes in aluminium electrolysis cells for the electrolytic production of aluminum
A method of manufacturing an electrode for electrochemical processes / 2241787
The invention relates to electrochemistry, in particular, to a technology of electrochemical productions, more specifically, to a technology for production of electrodes for electrochemical processes in the electrolysis, including chlorine and chlorate electrolysis, galvanic, in electro-membrane processes: electrodialysis, electroosmosis, electrophoresis, electrosynthesis
A method of manufacturing an electrode for electrochemical processes / 2241786
The invention relates to electrochemistry, in particular, to a technology of electrochemical productions, more specifically, to a technology for production of electrodes for electrochemical processes in the electrolysis, including chlorine and chlorate electrolysis, galvanic, in electro-membrane processes: electrodialysis, electroosmosis, electrophoresis, electrosynthesis
A method of manufacturing an electrode for electrochemical processes / 2241785
The invention relates to electrochemistry, in particular, the technology of electrochemical productions, more specifically, to a technology for production of electrodes for electrochemical processes in the electrolysis, including chlorine and chlorate electrolysis, galvanic, in electro-membrane processes: electrodialysis, electroosmosis, electrophoresis, electrosynthesis
Method and complex for preparing of bottled oxygen- saturated water / 2246882
Method involves producing oxygen-saturated water by ejection-floatation mixing of water with oxygen-containing gas; bottling oxygen-saturated water and capping, with gas-and-vapor H2O2+O2 mixture synthesized by plasma chemotronical method being used in all above operations. Complex of equipment comprises ejection-floatation unit for oxygen saturation of water and installation for supplying and bottling of oxygen-saturated water.
Method of saturation of water with oxygen and plant for realization of this method / 2247081
Proposed method includes successive ejection-floatation mixing of plasma-chemotronic method of vapor-and-gas mixture H2O2+02 with water. Plant proposed for realization of this method includes two systems interconnected by means of vapor-and-gas pipe line: ejection-floatation system and vapor-and-gas producing system. Ejection-floatation system for saturation of water with oxygen is provided with pump, ejector and pressure floatation column interconnected by circulating pipe line. In its lower part column is connected to starting water pipe line and in upper part it is connected to oxygen-saturated water pipe line. Ejector is mounted in circulating pipe line between lower part of column and pump and is connected to vapor-and-gas mixture producing system by means of vapor-and-gas pipe line. Closed electrolyte circulating system for obtaining the vapor-and-gas mixture includes gas-and-liquid separator, electrolyte reservoir, plasma-chemotronic apparatus whose lower part is connected with air or oxygen supply pipe line through flow regulator.
Electrode, apparatus and method for electrolytic treatment of liquid, system for regenerating soil in situ and unit for performing reduction-oxidation reactions / 2247175
Electrode includes elongated, mainly hollow body made of porous material characterized by comparatively low electric conductivity, connector in the form of elongated electrically conducting member connected to power source. Connector passes along inner cavity of electrode body and it has contact with surface of inner wall of body in large number of places mutually spaced along length of body for distributing electric current supplied from power source practically uniformly along electrode.
Electrode, apparatus and method for electrolytic treatment of liquid, system for regenerating soil in situ and unit for performing reduction-oxidation reactions / 2247175
Electrode includes elongated, mainly hollow body made of porous material characterized by comparatively low electric conductivity, connector in the form of elongated electrically conducting member connected to power source. Connector passes along inner cavity of electrode body and it has contact with surface of inner wall of body in large number of places mutually spaced along length of body for distributing electric current supplied from power source practically uniformly along electrode.
Method of a ferric iron hydroxide hydrosol production / 2250914
The invention is intended for a chemical industry, an agriculture and pedology and may be used at production of solutions for soils reclamation. 0.5 l of a ferric chloride solution with concentration of 0.5 l/mole gram-molecule is poured into a pan. Carbon electrodes are put into the solution. Pass a current of 1А. Each 5-60 seconds polarity of the electrodes is changed. In a result of replacement of anions of the salt for ions of the hydroxyl obtain a stable hydrosol of the ferric iron hydroxide. The invention allows to produce such sols using a simple and a production-friendly method commercially.
Preparation of vanadium electrolyte with aid of asymmetric vanadium-reducing electrolyzer and use of asymmetric vanadium-reducing electrolyzer for reducing electrolyte charge state balance in operating reduction-oxidation vanadium battery / 2251763
Novelty is that acid vanadium electrolyte liquor that has in its composition V+3 and V+4 in desired concentration ratio introduced in electrolyte solution is produced from solid vanadium pentoxide by electrochemical method while at least partially reducing dissolved vanadium in acid electrolyte liquor; for the purpose electrolyte liquor is circulated through plurality of cascaded electrolyzers at least partially to V+3 degree; in this way reduced vanadium incorporating electrolyte liquor leaving the last of mentioned electrolyzers enters in reaction with stoichiometric amount of vanadium pentoxide to produce electrolyte liquor incorporating in effect vanadium in the V+3 form; acid and water are introduced to ensure definite molarity of liquor and the latter is continuously circulated through cascaded electrolyzers; stream of electrolyte liquor produced in the process that incorporates V+3 and V+4 in desired concentrations is discharged at outlet of one of electrolyzers of mentioned cascade. Each electrolyzer is distinguished by high degree of asymmetry and has cathode and anode of relevant surface morphology, geometry, and relative arrangement for setting current density on anode surface exceeding by 5 to 20 times that on projected cathode surface, oxygen being emitted from anode surface. Asymmetric electrolyzer of this type can be used in one of electrolyte circuits, positive or negative, of operating battery (cell) for reducing balance of respective oxidation degrees of their vanadium content.
Hydrogen-oxygen mixture generator / 2252275
The invention is pertaining to technologies of electrochemical productions, in particular, to devices for electrolysis of water. The generator of a hydrogen-oxygen mixture contains at least one cylinder with a jacket of cooling, automatic inlet and outlet gates, a piston and a head of the cylinder forming a self-contained volume of the cylinder, a connecting rod gear linked wit a drive. The electrolyzer is made in a hermetic body with a cooling jacket with a capability of an easy passing through it of an electrolyte water solution. The electrolyzer is made in the form of two electrodes - half-blocks with a positive allowance entering each other. A device of the electrolyte cycle batch feeding into the electrolyzer is made in the form of a high-lift pump kinematically or through a control package is linked with the connecting rod gear and is supplied with the injector. The technical effect consists in an increase of productivity of the generator and its operating safety.
Electrolysis-water gaseous generator / 2252276
The invention is pertaining to the field of welding and may find application in devices of a gas-flame treatment of materials. The electrolysis-water gaseous generator contains a hermetic body made in the form of a rectangular container with a liquid, in the internal grooves of which there are two packages of metal plates shifted in respect to each other. At that the last and the first plates of the two packages are electrically connected. The generator contains a tight cylinder with a volume for automatic feeding of a liquid, a bubbler, a gas-mixer, an outlet connection pipe with a torch and a control circuit with the liquid level and pressure operated magnetic contacts located in a tight pipe, on the outer side of which there are a floater and a magnet. The length of the tight cylinder volume of automatic feeding of a liquid and its diameter are exceeding the length and width of the hermetic rectangular body accordingly. The shape of the upper part of the body is compatible with the cylindrical form of the volume of the automatic feeding, above which there are in series located a tight elastic dielectric spacer and the cylindrical volume of automatic feeding of a liquid. The height of the metal plates of the two packages does not exceed the height of the lower part of the cylindrical volume used for automatic feeding of a liquid, which similarly to the elastic dielectric spacer also has a through groove located in the area of displacement of the two packages of metal plates, which is ensuring formation of a gas cushion above a package of the metal plates and automatic feeding of a liquid. The technical effect is an essential simplification of the design of the device for the gas-flame treatment of materials.
Electrolysis-water gaseous generator / 2252276
The invention is pertaining to the field of welding and may find application in devices of a gas-flame treatment of materials. The electrolysis-water gaseous generator contains a hermetic body made in the form of a rectangular container with a liquid, in the internal grooves of which there are two packages of metal plates shifted in respect to each other. At that the last and the first plates of the two packages are electrically connected. The generator contains a tight cylinder with a volume for automatic feeding of a liquid, a bubbler, a gas-mixer, an outlet connection pipe with a torch and a control circuit with the liquid level and pressure operated magnetic contacts located in a tight pipe, on the outer side of which there are a floater and a magnet. The length of the tight cylinder volume of automatic feeding of a liquid and its diameter are exceeding the length and width of the hermetic rectangular body accordingly. The shape of the upper part of the body is compatible with the cylindrical form of the volume of the automatic feeding, above which there are in series located a tight elastic dielectric spacer and the cylindrical volume of automatic feeding of a liquid. The height of the metal plates of the two packages does not exceed the height of the lower part of the cylindrical volume used for automatic feeding of a liquid, which similarly to the elastic dielectric spacer also has a through groove located in the area of displacement of the two packages of metal plates, which is ensuring formation of a gas cushion above a package of the metal plates and automatic feeding of a liquid. The technical effect is an essential simplification of the design of the device for the gas-flame treatment of materials.
Electrolyzer / 2252921
Electrolyzer includes two electrodes (one electrode of stainless steel and other electrode of carbon); bridge type voltage rectifier; electric circuit plug; membrane; second doubled membrane - cover, for example of tracing paper or canvas; glass vessel; low-resistance voltage divider with taps; array of light emitting diodes with additional resistors whose number corresponds to that of taps; housing of electrolyzer. Plug is connected with inlets of bridge type voltage rectifier; negative outlet of voltage rectifier is connected with electrode of stainless steel. Second positive-polarity outlet of voltage rectifier is connected through low-resistance voltage divider with taps to carbon electrode arranged in second membrane-cover. All cathode ends of light emitting diodes with additional resistors are connected in parallel and they are connected with positive outlet of voltage rectifier; second ends of said diodes are connected with respective taps of low-resistance voltage divider.
|
FIELD: technologies of electrochemical productions. SUBSTANCE: the invention is pertaining to technologies of electrochemical productions, in particular, to devices for electrolysis of water. The generator of a hydrogen-oxygen mixture contains at least one cylinder with a jacket of cooling, automatic inlet and outlet gates, a piston and a head of the cylinder forming a self-contained volume of the cylinder, a connecting rod gear linked wit a drive. The electrolyzer is made in a hermetic body with a cooling jacket with a capability of an easy passing through it of an electrolyte water solution. The electrolyzer is made in the form of two electrodes - half-blocks with a positive allowance entering each other. A device of the electrolyte cycle batch feeding into the electrolyzer is made in the form of a high-lift pump kinematically or through a control package is linked with the connecting rod gear and is supplied with the injector. The technical effect consists in an increase of productivity of the generator and its operating safety. EFFECT: the invention ensures an increased productivity and operational safety of the generator. 3 cl, 4 dwg
The invention relates to the technology of electrochemical productions, namely, devices electrolysis of water, and can be widely used for the generation of clean fuel, mainly for heating of the population. Known used for the electrochemical decomposition of water electrolysis, comprises a cylindrical housing anode, a hollow cathode, mounted coaxially with the casing, the pipe to enter the electrolyte and the nozzle with a shut-off valve for the gas outlet and the constant current source [1]. The disadvantage of this cell is low productivity and low protection against explosions. The closest in technical essence of the present invention is a high pressure electrolyzer for receiving the detonating gas, comprises a cylindrical housing, separated by a check valve at the electrode and getnameinfo part where the electrode part is made with eyeliner power from the DC source to its electrodes, and gazonokosilka - with the possibility of removal of the gas under pressure [2]. A disadvantage of this device is the low productivity and high risk of explosion due to the need to accumulate gas in the cell to a high working pressure. The technical problem solved by the invention, Zack is udaetsya in improving the performance of the generator and its safety in operation. The problem is solved in that the generator hydrogen-oxygen mixture containing the cell made with the possibility of the liner supply from the constant current source, for example from a battery to its electrodes, according to the invention contains at least one cylinder with a cooling jacket, for example a liquid, a piston and a cylinder head forming a closed volume of the cylinder, check the intake and exhaust valves, a crank mechanism associated with the drive such as an electric motor, and a feeder of an aqueous solution of electrolyte such as aqueous potassium hydroxide, and the cylinder inlet connection in communication with the electrolyzer, posted in a sealed enclosure with a cooling jacket, for example a liquid, is made with the possibility of free passage through it of an aqueous solution of electrolyte and provided with outlet pipe with a shut-off valve, for example made in the form of a check valve, and a circulation path of the electrolyte in the electrolyzer, with pump and nozzle with cavitator, feeder aqueous solution of the electrolyte in the form of a high pressure pump such as a plunger, kinematically or through a control unit connected with a crank mechanism and provided with a nozzle, which can be cavitator made in view of the local constriction of the channel. When this nozzle circulation circuit has a cavitator, made in the form of the local constriction of the channel, the cell can be in the form of two electrodes-Polupanov, with a clearance fit into each other, in which any holes, for example, when you run them from a sheet of Nickel, or which are made of metal mesh, for example, of Nickel. The essence of the invention shown in the drawing, where: On 1 shows a schematic cross-section of the generator. Figure 2 shows a section of the cell along a-a in figure 1. Figure 3. A view along arrow B in figure 1. Figure 4. A schematic cross-section of the nozzle part of the cavitator. An example of implementation of the proposed solution. Generator hydrogen-oxygen mixture contains at least one cylinder 1 (1-3) with cooling jacket 2, self-acting inlet 3, an outlet 4 valves, the piston 5 and the cylinder head 6, forming a closed volume of the cylinder 7, a crank mechanism (8) connected to the actuator 9. Cylinder inlet connection 10 is in communication with the electrolyzer 11, made in a hermetically sealed housing 12 with a cooling jacket 13 with the possibility of free passage through it of an aqueous solution of electrolyte, equipped with a shut-off valve 14 in the form of a check valve in the outlet port 15 and the circulation path of the electrolyte 16, made in the form of pump 17 and the nozzle 18 with the cavitator 19 (figure 4) in the ideal narrowing 20 channel 21, cavitation zone 22. Feeder aqueous electrolyte, made in the form of a pump 23 high pressure, kinematically or through a control unit connected with a crank mechanism, and provided with a nozzle 24, which may have cavitator (figure 4, above). Thus the cell can be in the form of two electrodes-Polupanov 25 and 26, its elements 27 with a gap 28 fit into each other, in which or holes (perforation) or which are made of a metal grid electrodes-semiblocks dielectric spacer 29 are isolated from each other and from the housing, the power received from the source 30 DC, for example from the battery. In the electrolyzer made tube 31 for filling the cell with an aqueous solution of electrolyte and the valve 32 to control its level. Electrolytic tank 33 for storing an aqueous solution of electrolyte, the cutter 34 (hydraulic lock) on the line of the consumer, the consumer 35, for example, a boiler combustion chamber. Generator hydrogen-oxygen mixture is as follows. Before you begin electrolytic tank 33 (Fig.1-4) filled with an aqueous solution of electrolyte, such as aqueous solution of potassium hydroxide. Opening the valve 32 controls the level of the electrolyte in the electrolytic cell 11, if necessary, top up through the tube 31. The inclusion of, for example, b is the eye control electrodes semiblocks 25 and 26 serves the direct current from the source 30. Turns on the circulation loop 16 of the electrolyte, where the pump 17 takes away from the electrolyzer 11 aqueous electrolyte solution under pressure, for example, 5-10 ATM and through the nozzle 18 with the cavitator 19 feeds it back into the cell 11. In the local constriction 20 channel 21 of the nozzle 18, the speed of the circulating aqueous solution of the electrolyte increases, and the pressure drops to a critical value and the collapse formed in the cavitation zone 22 of bubbles leads to dissociation - the decomposition of water into hydrogen and oxygen, which increases the performance of the device. In the electrolytic cell 11 or expense made in the electrodes-polyblock 25 and 26 holes (perforation) and the gaps 28 between them or due to their vypolnennoi of metal mesh aqueous solution of the electrolyte has the opportunity to freely pass through the cell 11 and freely to contact with the entire surface of the electrodes-Polupanov 25 and 26. Then, when the flow of direct current from the source 30 through the aqueous electrolyte solution is electrolysis is the decomposition of water into hydrogen and oxygen. Enables the actuator 9 of the generator. The piston 5 moves from TDC to BDC, the exhaust check valve 4 is closed, the inlet 3 is open, the electrolyzer 11 vacuum is created, which intensifies the electrolysis of water and improves the device performance. Obtained in the electrolytic cell 1, the gas mixture through the outlet nozzle 15 with a shut-off valve 14 and then via the inlet pipe 10 are sucked into the cylinder 1. While the high-pressure pump 23 takes away from the electrolyte tank 33 cyclic dose of an aqueous solution of electrolyte under pressure, for example, 1-2 MPa (10-20 ATM), and through the injector 24 injects into the cell 11, where the cavitator 19 (4) of the nozzle 24 is above the decomposition of water into hydrogen and oxygen, which also increases the performance of the device. The piston 5 moves from BDC to TDC, the intake check valve 3 is closed, the outlet 4 is opened, the gas mixture from the cylinder 1 by the piston 5 under the discharge pressure through the cutter 34 (hydraulic lock) 35 is supplied to the consumer, for example in the combustion chamber of a boiler plant. And the cycles are repeated. When the explosions, the reverse shock in the generator actuates the cutter 14, the blast wave is extinguished in the cylinder 1 by the piston 5, which ensures safe operation of the device. The proposed generator hydrogen-oxygen mixture in the operation is completely safe and highly productive. Will give an opportunity to use the energy of water in the production of thermal energy for the population. Sources of information 1. RF patent №2034934, With 25 In 9/00, 1/02, 10.05.95. 2. As the USSR №1011730, With 25 In 1/12, prototype, 15.04.83. 1. Generator hydrogen-oxygen mixture containing the cell made with the possibility of the liner supply from the constant current source towardshis electrodes, characterized in that the generator comprises at least one cylinder with a cooling jacket, the piston and the cylinder head, forming a closed volume of the cylinder, check the intake and exhaust valves, a crank mechanism associated with the actuator, and a feeder of an aqueous solution of electrolyte, with the cylinder inlet connection communicates with the cell placed in a hermetically sealed enclosure with cooling jacket, made with the possibility of free passage through it of an aqueous solution of electrolyte and provided with outlet pipe with a shut-off valve and the circulation path of the electrolyte with the pump and the injector with the cavitator, feeder aqueous electrolyte solution is made in the form high-pressure pump, kinematically or through a control unit connected with a crank mechanism, and provided with a nozzle. 2. The generator according to claim 1, characterized in that the electrolytic cell has two electrodes-Polupanov, with a clearance fit into each other, in which either holes or hollow metal grid. 3. The generator according to claim 1, characterized in that the nozzle has a cavitator, made in the form of local narrowing of the channel.
|
© 2013-2015 Russian business network RussianPatents.com - Special Russian commercial information project for world wide. Foreign filing in English. |