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Ceramic mass for production of acid-resistant substances

IPC classes for russian patent Ceramic mass for production of acid-resistant substances (RU 2250884):
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FIELD: production of ceramic materials, mainly acid-resistant agents.

SUBSTANCE: ceramic mass has the following composition, mass-%: clay portion of tailings of gravitation of zirconium-ilmenite ores, 40-60; pyrophyllite, 35-45 and dump overburden rock of gold field, 5-15. Ceramic mass thus prepared makes it possible to obtain acid-resistant agents possessing high frost resistance and low water absorption.

EFFECT: enhanced ecological safety; extended field of application.

3 tbl

 

The invention relates to ceramic materials industry, mainly to AMIS to obtain acid-proof materials.

Known ceramic material for acid-proof materials of the following composition, wt.%: Jean-Daurian clay 50, pyrophyllite 50 [1].

The disadvantage of this structure are relatively low mechanical strength in compression, low frost and content in the charge scarce refractory clay.

Closest to the invention is a ceramic material for the manufacture of acid-proof materials [2], which includes the following components, wt.%: clay part of the “tails” of gravity zircon-ilmenite ores - 50 pyrophyllite - 40, feldspar concentrate - 10.

The disadvantage of the composition of the ceramic material are low resistance and relatively high water absorption.

The aim of the invention is to increase the frost resistance and reduced water absorption.

The objective is achieved due to the fact that the ceramic material, including clay part of the “tails” of gravity zircon-ilmenite ores and pyrophyllite, further comprises a conveyor overburden gold Deposit in the following ratio, wt.%:

clay part of the “tails” of gravity

zircon-ilmenite ores 40-60

pyrophyllite 35-45

final Stripping the cities of gold

field 5-15

As smoothly used final overburden gold Deposit. The resistance dumping overburden gold Deposit 1180-1250°C, particle size allows you to enter them in the ceramic material without pre-crushing and sieving: bulk density 1400-1450 kg/m3grains larger than 3 mm in the amount of 1-3%, the number of fine particles smaller than 0.1 mm does not exceed 20%. The chemical composition of the components shown in table 1.

Table 1
The chemical composition components
Component Oxide content, %
SiO2 Al2O3 CaO MgO Fe2About3 R2O PPP
Clay part of the “tails” of gravity zircon-ilmenite ORES 58,74 21,39 1,760 1,22 6,21 1,82 7,34
Pyrophyllite 52,85 34,88 0,22 0,1 0,4 0,09 7,88
Final overburden gold mine 58,2 to 19.9 6,2 1,71 2,5 8,42 2,23

Ceramic mass prepared plastic method with moisture 18-22%. Was formed square tile type PC-1, which was dried to a residual moisture content of not more than 5% and then fired at a temperature of 1250°C. table 2 shows the compositions of ceramic masses, and in table 3 - physical and mechanical properties of acid-proof tiles.

Table 2
The compositions of ceramic masses
Components Content, wt.%
1 2 3 4 5
Clay part of the “tails” of gravity zircon-ilmenite ores 60 55 50 45 40
Pyrophyllite 35 40 40 40 45
Final overburden gold mine 5 5 10 15 15
Table 3
Physico-mechanical parameters of acid-proof materials
Indicators Structures The placeholder
1 2 3 4 5
Frost resistance, cycles 152 150 180 201 190 Over 50
Water absorption, % 1,7 1,8 1,5 1,2 1,5 2,0
Acid, % 97,2 97,3 97,4 97,5 of 97.8 97,5
Shrinkage, % 8,8 8,5 9,2 9,8 9,5  
Thermal stability, thermal cyclings 3 5 6 7 8 7
The mechanical compressive strength, MPa 80 75 85 95 90  

As can be seen from table 3, acid resistant tiles of the proposed compositions have higher resistance and lower water absorption than the prototype.

SOURCES of INFORMATION

1. Abdrakhimov Y.S., Abdrakhimov the old Testament Kinetics of changes in patterns of porosity in the firing process of acid-proof materials. // Izvestiya vuzov. Construction. - 2000. No. 9. - Ñ.38-41.

2. Abdrakhimov Y.S., Abdrakhimov the old Testament Obtaining acid-resistant materials using waste products. // Building materials. - 2002. No. 2 - P.18-20.

Ceramic material for acid-proof materials, including clay part of the “tails” of gravity zircon-ilmenite ores and pyrophyllite, characterized in that, to increase frost resistance and lower water absorption, it includes the additional final overburden gold Deposit in the following ratio, wt. %:

Clay part of the “tails” of gravity

zircon-ilmenite R is d 40-60

Pyrophyllite 35-45

Final overburden gold Deposit 5-15

 

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