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Integrated high-temperature heat-retention material "itom" and a method for manufacture thereof

IPC classes for russian patent Integrated high-temperature heat-retention material "itom" and a method for manufacture thereof (RU 2246465):
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FIELD: manufacture of building materials.

SUBSTANCE: invention concerns manufacture of articles for heat-retention of furnace units and power equipment operated at surface temperatures up to 1100°C. Invention provides charge mixture containing, wt %: swollen vermiculite 20-60, refractory clay or kaolin 37-55, electrofilter dust 1-20, chamotte fraction below 0.063 mm 1-30, and structure-forming polyelectrolyte 3-5 (above 100%). Charge is moistened to form mass, which is aged in closed space for at least 24 h, molded into crude article, dried to residual moisture at most 5%, and fired at 1000-1100°C. Aforesaid polyelectrolyte is characterized by having carboxyl, amide, nitrile, and ester groups in polymer molecule.

EFFECT: reduced air and fire shrinkage and service deformations, raised softening point, simplified manufacture, and achieved absence of anisotropy of physicochemical and thermal characteristics with extremely low heat-conduction values.

2 cl, 1 tbl, 4 ex

 

The invention relates to the construction materials industry and can be used in the manufacture of products for thermal insulation of furnaces and power equipment with temperatures of up to 1100° C.

Known high-temperature thermal insulation material made from a mixture described in A.S. No. 1534038 consisting of expanded vermiculite, refractory clay, waste production of electrocorundum, waste coal, in the following ratio, wt.%: exfoliated vermiculite 26-42, fire clay 24-44, waste production of electrocorundum 9-34, waste coal 8-14. Known material has a number of disadvantages - low strength, high air and firing shrinkage, leading to deformation of the products, which require machining to make products of the exact size and shape.

A method of producing insulating ceramopaneley of the products described in A.S. No. 1583395, comprising preparing a clay slurry, the introduction part of the refractory filler in the amount of 25-45 parts by weight of the total content in the mass, mixing the mixture formed from exfoliated vermiculite and the remainder of the refractory filler, heated to 80-95° With, keeping weight within 1.5 to 2.0 h, molding, drying ibig, the dried crude product in an oven, preheated to a temperature of 1150° within 75-100 minutes. Disadvantages of the proposed method is expressed in its low processibility in the organization of mass production due to high moisture raw after molding, large air shrinkage of raw, high energy consumption for drying, large firing shrinkage, which leads to deformation of the products and the need for additional machining products.

The closest set of features (prototype) of the present invention is a high temperature insulating material made from a mixture described in the patent of Russian Federation № 2154042 consisting of expanded vermiculite, refractory clay, electrostatic dust, bentonite and polyelectrolyte amendment to the presence in the polymer molecule a carboxyl, amide, nitrile and ester groups, in the following ratio, wt.%: exfoliated vermiculite 35-60, fire clay or kaolin 36-43, dust from electrostatic 1-20, bentonite 1-3, the polyelectrolyte structure creators of 0.3 to 0.6. Use as the dispersed refractory filler alone dust from electrostatic prone to sintering, increases volumetric shrinkage changes of items during the operating temperature (1000°). Due to the presence the Oia low-melting bentonite maximum operating temperature of the material is reduced to 1000° C.

The closest set of features (prototype) for the proposed method is a production method of high-temperature insulation material described in the aforementioned patent RF № 2154042, including batching, mixing, wetting with an aqueous solution of polyelectrolyte amendment in the mixer component mass, consisting of a lightweight and dispersed refractory filler, refractory clay, processing it in the tape media, the pressing raw, drying and firing. The disadvantage of this method is the complexity of the operation of pressing the workpiece on the tape media from a mixture of exfoliated vermiculite having a high elastic aftereffect, which leads to the discontinuity of raw and receiving defective products. In addition, the products obtained by pressing on the tape media, have anisotropy of physical-mechanical properties (strength, thermal conductivity, thermal expansion), which affects the durability of products.

We offer insulation material in comparison with analogues is minimal (less than 1% of the exposure for 8 hours) volume changes during temperature service, a higher temperature at which softening (>1100° (C)that improves its performance and resource characteristics in the service, and blah is odara small and uniform linear and volumetric shrinkage (air 2,0-2,4%, fire to 2.2-2.3%) no deformation occurs products in drying and after firing. This technical effect is achieved in that the heat-insulating refractory material made from a mixture comprising expanded vermiculite as a lightweight filler, refractory clay or kaolin, polyelectrolyte, the amendment to the presence in the polymer molecule a carboxyl, amide, nitrile and ester groups and dispersed refractory filler, including dust from electrostatic rotary kilns for the production of clay and the clay fraction less 0,063 mm in the following ratio, wt.%:

Exfoliated vermiculite 20-60

Refractory clay or kaolin 37-55

Dust from electrostatic 1-20

The clay fraction less 0,063 mm 1-30

Polyelectrolyte structure-former 3-5 (above 100%)

as the number of input polyelectrolyte amendment is 9% by weight of fireclay or kaolin.

In the proposed method, in comparison with the prototype, fixed operation preliminary pressing of the workpiece tape pressure, which simplifies the forming raw, greatly reducing the number of defective workpieces that does not require the preparation and use of aqueous polyelectrolyte, creates isotropic integrated product structure in a matrix formed of refractory m the materials (refractory clay or kaolin, the clay and dust from the electrostatic precipitators), integrated particles, the lightweight filler is vermiculite, not having a directional orientation. Due to this structure eliminates the anisotropy of physical-chemical and thermo-physical properties of the products characteristic of the products have passed the stage of preliminary pressing on the tape media in which the particles of vermiculite receive orientation along the axis of extrusion. This technical result is achieved by the fact that when implementing the proposed method of production of heat-insulating refractory material including dosing, mixing and moistening in the mixer component mixture consisting of expanded vermiculite as a lightweight filler, refractory clay or kaolin and dispersed refractory filler, in the form of dust from electrostatic rotary kilns for the production of clay and the clay fraction less 0,063 mm, extrusion raw, its drying and firing, and in the preparation of mass it is added 3-5 wt.% (over 100%) powdered polyelectrolyte amendment to the presence in the polymer molecule a carboxyl, amide, nitrile and ester groups and the aging cooked mass in a closed container for at least 24 hours.

Dust from the electrostatic precipitators is a waste of clay during firing of refractory clays of the kaolin in rotary kilns. It presents a spherical particle with an internal cavity partially digidratirovannogo clay mineral is kaolinite. Dust neoplastica, its chemical composition, wt.%: Al2O335,4-42,2, Fe2About31,28-is 3.08, SiO252,0-60,2, CaO 0.3 to 0.5, MgO 0.2 to 0.5, PA2O+K2About 0.1 to 0.5; weight loss during calcination of 2-8, and granulometric composition, wt.%: fraction > 200 μm 0,3-4,3, fraction of 50-200 μm 40,3-54,1, fraction of 10-50 μm to 10.5 to 14.4, the fraction of 5-10 μm, 14,3-15,5, fraction of 1-5 μm 1,3-5,8, fraction <1 μm 10,3-20,4.

The use of the dust from the electrostatic allows due to the presence of an internal cavity in its particles to reduce the density of both raw and finished products than facilitates obtaining products with a low density (0.4-0.6 g/cm3) and extremely low thermal conductivity (λ =0.1 to 0.2 W/(m· K)) and high strength (σSG=1,0-2,5 N/mm2).

Add in the weight of dispersed clay (particles less than 0,063 mm) contributes to the reduction of volume shrinkage (air 2,0-2,4%, the firing of about 2.2-2.3%), preserving the exact geometric shape and size of the products after drying and firing.

Introduction to mass polyelectrolyte amendment in the form of dry solid powder can reduce its moisture content. Limit the number of polyelectrolyte amendment may reach 9% by weight of refractory clay (kaolin).

The increase in the content of the vermiculite in the charge leads to a decrease in apparent density and strength, the increase in total content of clay and dust from the electrostatic precipitators at a constant content of vermiculite leads to higher apparent density, reduce air and firing shrinkage, increased content of refractory clay (kaolin) increases the density and strength of products.

EXAMPLE 1. For the production of heat-insulating refractory materials using a mixture of the following composition, wt.%:

Plastic kaolin 37

Exfoliated vermiculite 58

The clay fraction less 0,063 mm 1

Dust from the electrostatic precipitators 1

Polyelectrolyte structure-former 3 (above 100%)

The proposed method consists of the following: weighting method in a predetermined ratio dosed components of the charge (refractory clay or kaolin, exfoliated vermiculite, dust from the electrostatic precipitators, the clay fraction less 0,063 mm, the polyelectrolyte structure-former), loadconsistently in the mixer (Z-shaped mixer or twin-shaft mixer) and mix thoroughly, then produce hydration water, stirred until a homogeneous granular mass which is discharged into a closed container and vylizyvaut at least 24 hours. When holding water affects the polyelectrolyte structure-former, causing swelling and plasticization, thereby increasing plastic mass properties and connectivity. After Valiev the tion of the mass of the molded product, which are dried natural or forced drying to a residual moisture content of not more than 5%, the dried product is calcined at a temperature of 1000-1100° C.

EXAMPLE 2. Differs from example 1 only by the composition of the charge, wt.%:

Plastic kaolin 50

Exfoliated vermiculite 48

The clay fraction less 0,063 mm 1

Dust from the electrostatic precipitators 1

Polyelectrolyte structure-former 4,5 (over 100%)

EXAMPLE 3. Differs from example 1 only by the composition of the charge, wt.%:

Plastic kaolin 40

Exfoliated vermiculite 20

The clay fraction less 0,063 mm 25

The dust precipitator 15

Polyelectrolyte structure-former - 4 (over 100%).

EXAMPLE 4. Differs from example 1 only by the composition of the charge, wt.%:

Plastic kaolin 45

Exfoliated vermiculite 25

The clay fraction less 0,063 mm 10

Dust from the electrostatic filter 20

Polyelectrolyte structure-former 4,5 (over 100%)

Properties of insulating refractory materials described in examples 1-4, are shown in table 1.

td align="center"> 8,68
Table 1.
Main technical characteristics of ITEM.
№p/p Name of indicator Values for sample
No. 1 No. 2 No. 3 No. 4
1. Apparent density, kg/m3 420-500 600-640 850-900 1000-1100
2. The limit of compressive strength, N/mm2 0,9-1,0 1,0-1,4 1,4-1,7 2,0-2,4
3 The open porosity, % 80-82 75-78 65-68 62-65
4. Additional linear shrinkage at 1150°,% 1,4-1,5 1,2-1,4 of 1.1-1.3 1,0-1,2
5. The onset temperature softening,°
Under a load of 0.05 N/mm2 1109 1119 1135 1140
Under load of 0.04 N/mm2 1120 - - -
Under load of 0.06 N/mm2 - 1118 - -
Under load 0,08 N/mm2 - - 1117 -
Under a load of 0.1 N/mm2 - - 1108
6. TCLE (α20-900°-the C-1×106 9,48 a 7.62 7,02
7. Coefficient of thermal conductivity, W/(m×)
  At an average temperature of 200° 0,090 0,120 0,183 0,230
  The average temperature 380° 0,120 0,139 0,194 0,250
8. Thermal stability, thermal cycles (1000°-air) >100 >100 >100 >100

1. Heat-insulating refractory material made from a mixture comprising expanded vermiculite, refractory clay or kaolin, polyelectrolyte, the amendment to the presence in the polymer molecule a carboxyl, amide, nitrile and ester groups and dispersed refractory filler, characterized in that the mixture contains as dispersed refractory filler dust from electrostatic rotary kilns for the production of clay and the clay fraction less 0,063 mm in the following ratio, wt.%:

exfoliated vermiculite 20-60,

refractory clay or kaolin 37-55,

dust from electrostatic 1-20,

the clay fraction less 0,063 mm 1-30,

polyelectrolyte structure-former 3-5 (above 100%),/p>

the amount of polyelectrolyte is 9% by weight of fireclay or kaolin.

2. Method of manufacturing heat-insulating refractory material including dosing, mixing and moistening in the mixer components of the charge: expanded vermiculite, refractory clay or kaolin and dispersed refractory filler, molding raw, its drying and firing, characterized in that in the preparation of mass is used as the dispersed refractory filler dust from electrostatic rotary kilns for the production of clay and the clay fraction less 0,063 mm and an additional 3-5 wt.% (over 100%) powdered polyelectrolyte amendment to the presence in the polymer molecule a carboxyl, amide, nitrile and ester groups, and after moistening the prepared weight vylizyvaut in closed containers for at least 24 hours

 

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