RussianPatents.com
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Method of treating bottom zone of low-permeable oil reservoirs. RU patent 2244111. |
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FIELD: oil and gas production. SUBSTANCE: invention aims at increasing productivity of oil- and gas-producing and injecting wells exposing high-temperature low-permeable oil reservoirs. In the treatment method according to invention including forcing enzyme substrate and separate enzyme into formation and creating conditions to enzymatically convert substrate into acid, geologic and productive characteristics for each interval of bottom zone are determined in order to pick out low-permeable intervals of oil reservoir for treatment, whereupon properties of enzyme substrate and separate enzyme as well as conditions for their pumping are chosen. Substrate utilized in the method is head fraction of methyl- and/or ethyl-, and/or butyl acetate production, to which aliphatic alcohols are added, and enzyme is an acid solution. Substrate is pumped simultaneously and/or before, and/or after pumping of enzyme, after which well is closed for some time and then opened and placed under predetermined operational conditions. EFFECT: enhanced efficiency of acid treatment due to increased phase permeability for oil and deepness of active acid-treated zone of low-permeable oil reservoirs. 25 cl, 1 tbl, 3 ex
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Oil pool development method / 2244110 Invention provides a method of developing oil pool allowing production of oil from water-rich oil reservoir under difficult geological-tectonic conditions in the last development stage. In the method, neutral salt of carbonic acid and acid solution are forced into formation through injecting well with water generated in gas-liquid fringe created in formation. After pumping of neutral salt of carbonic acid, acid solution is pumped by portions alternating with water pumping. Before pumping of acid solution portions beginning by at least second portion, selective insulation of high-permeable formation intervals is performed. Aforesaid neutral salt of carbonic acid utilized is sodium carbonate aqueous solution or aqueous suspension of calcium carbonate and aforesaid acid solution is aqueous hydrochloric acid solution. Selective insulation of high-permeable formation intervals involves use of freshly prepared controllable viscoelastic composition containing water-soluble acrylic polymer, cross-linking agent, thermal stabilizer, surfactant, and water. Summary concentration of acid solution is determined from concentration of neutral salt of carbonic acid on the base of stoichiometric proportions. |
Oil pool development method / 2244110 Invention provides a method of developing oil pool allowing production of oil from water-rich oil reservoir under difficult geological-tectonic conditions in the last development stage. In the method, neutral salt of carbonic acid and acid solution are forced into formation through injecting well with water generated in gas-liquid fringe created in formation. After pumping of neutral salt of carbonic acid, acid solution is pumped by portions alternating with water pumping. Before pumping of acid solution portions beginning by at least second portion, selective insulation of high-permeable formation intervals is performed. Aforesaid neutral salt of carbonic acid utilized is sodium carbonate aqueous solution or aqueous suspension of calcium carbonate and aforesaid acid solution is aqueous hydrochloric acid solution. Selective insulation of high-permeable formation intervals involves use of freshly prepared controllable viscoelastic composition containing water-soluble acrylic polymer, cross-linking agent, thermal stabilizer, surfactant, and water. Summary concentration of acid solution is determined from concentration of neutral salt of carbonic acid on the base of stoichiometric proportions. |
Method of treating bottom zone of low-permeable oil reservoirs / 2244111 Invention aims at increasing productivity of oil- and gas-producing and injecting wells exposing high-temperature low-permeable oil reservoirs. In the treatment method according to invention including forcing enzyme substrate and separate enzyme into formation and creating conditions to enzymatically convert substrate into acid, geologic and productive characteristics for each interval of bottom zone are determined in order to pick out low-permeable intervals of oil reservoir for treatment, whereupon properties of enzyme substrate and separate enzyme as well as conditions for their pumping are chosen. Substrate utilized in the method is head fraction of methyl- and/or ethyl-, and/or butyl acetate production, to which aliphatic alcohols are added, and enzyme is an acid solution. Substrate is pumped simultaneously and/or before, and/or after pumping of enzyme, after which well is closed for some time and then opened and placed under predetermined operational conditions. |
Oil recovery composition / 2244809 Invention is intended for use during development of oil pools at different waterflooding phase for intensifying functioning of producing wells and increasing current oil recovery of formation. Composition contains, wt %: liquid hydrocarbon 10.0-20.0, oil-soluble surfactant 0.3-5.0, water-soluble or water-oil-soluble surfactant 0.1-1.0, superfine hydrophobic material 0.1-2.0, and water (the rest). Composition may further contain 0.3-5.0% calcium chloride. Oil recovery is increased owing to hydrophobization of formation structure, reduction of surface tension in water/rock/oil phase boundary, increase in detergent power of polluted surface, increase in composition viscosity, and increase of relative permeability of the formation for hydrocarbon phase as compared with water phase. |
Formation bottom area treatment composition / 2244810 Composition contains 0.05-2.5% of hydrophobic power, 0.05-10% of ethylene/vinyl acetate copolymer, and organic solvent. Composition intensifies oil production owing to increased effective radius of formation bottom area treatment, prevention of moistening inversion effect upon fall of hydrophobic agent concentration, and, consequently, decreased volume of simultaneously produced water. |
Method for extracting hydrocarbons deposits / 2244811 Method includes drilling product and force wells, forcing gas and water through force wells into separate zones of productive bed and extraction of hydrocarbons from product wells, forming separate gas, water and hydrocarbon saturated areas with major contents of respectively gas, collected therein for later use, water and hydrocarbons, periodical pumping of collected gas from formed gas saturated zones to water saturated zones, periodical pumping of water to gas saturated zones is performed. It is possible to pump collected gas to water saturated zones in form of gas-water mixture. It is possible to pump in passing gas of current deposit. It is possible to pump hydrocarbon or non-hydrocarbon gas from other sources. It is possible to pump water with admixture of specifically selected chemical reagents or compositions thereof. When gas content in water saturated zones reaches from 0.1 to 28% from water content in water saturated zones it is reasonable to generate resilient waves with frequency within range from 0.0001 to 45 KHz and amplitude within range from 0.02 to 2.8 MPa. It is reasonable to pump gas and water to separate areas of productive bed with concurrent generation of resilient waves in there with frequency within range from 0.0001 to 45 KHz and amplitude within limits from 0.02 to 2.8 MPa. |
Method for oil bed extraction / 2244812 Method includes pumping of Sulfacella water dispersion into bed through force well and extraction of oil through extracting well, said dispersion additionally containing non-ionogenic surfactant AF9-12 with following ratio of components, in percents of mass: Sulfacella 0.5-1, AF9-12 0.01-0.1, water- the rest, while, before pumping of said dispersion mineralized water is pumped with total mineralization until 290 g/l in amount of 10% from volume of said dispersion, when pumping said dispersion prepared in fresh water, drain water is previously pumped, and when pumping said dispersion made from drain or bed water, bed water is previously pumped. For preparation of said dispersion fresh, drain or bed water is used with mineralization till 290 g/l. |
Method for operation of gas-condensate deposit / 2245997 Method includes examination of operation well for gas-condensation and periodical cleaning of face-adjacent well area from precipitating hydrocarbon condensate by pumping hydrocarbon condensate solvent into bed, exposure of well for period of condensate dissolution and following removal of received solution from face-adjacent area during well launch, as solvent binary mixture is used with unlimited mutual solubility of components, while at least one of them has unlimited mutual solubility with hydrocarbon condensate, and relation of binary mixture components is determined from previously built phase diagram of three-component system, formed during dissolution of hydrocarbon condensate. As binary mixture with unlimited mutual solubility of components a mixture of acetone and methanol is used, or chloroform and methanol, or chloroform and aniline, or chloroform and acetone. |
Method for preserving collecting properties of face-adjacent area of productive bed of oil-extractive well / 2245998 Method includes placing water solution of carnallite ore, either modified, concentrated, or mixtures thereof, said solution is used at maximal for well temperature conditions concentration and is pumped in amount, necessary and enough for forming a hydraulic column in well shaft above ceiling of productive bed and along remaining shaft height well is filled with water up to mouth. Carnallite ore used has composition, in percents of mass: potassium chloride 20.5-21.5; sodium chloride 19.5-22.5; magnesium chloride 24.0-27.0; crystallization water 29.5-30.5. Modified ore has composition, in percents of mass: potassium chloride 23.0-29.5; magnesium chloride 31.8-46.0; crystallization water - the rest. Said water solution is prepared by dissolving ore in fresh technical water, drained from oil preparation plants, or in bed water. In case of dissolving in bed water, the latter is pumped from well at temperature 60-90°C. During perforation of well, value of technological liquid hydraulic column above productive bed ceiling is taken equal to (1.03-1.07)-(1.05-1.1)Pb, where Pb - productive bed pressure. Water solution of carnallite ore is used at density 1.23-1.37 t/m3. During use of said solution as working body of force wells it is used at density 1.05-1.20 t/m3, and solution also contains swelling inhibitor for argillaceous component of oil and gas bearing bed, like oxyethylenedendiphosphone acid, in amount 0.05-0.15% of used dissolved ore mass. |
Oil extraction method / 2247231 Method includes treatment of face area of oil bed by hydrophobic agent in organic solvent and pressing oil from collector with following delivery of oil from face area of product well for treatment of oil terrigenic bed, in form of hydrophobic agent solution of ethylene copolymer with vinylacetate in ethylbenzol or fraction thereof is used in relation 1:1 - 10, treatment of face area is performed with following ratio of components, in percents of mass: ethylene copolymer with vinylacetate 0.05-2.0, ethylbenzol or fraction 0.05-20.0, organic solvent - the rest. |
Coal processing method / 2248398 Coal is affected by methanogenic consortium of microorganisms with culture medium utilizing continuous pumping of culture medium through wells and tank wherein methanogenic consortium of microorganisms with culture medium is placed. Tank is installed on the surface above wells and pumping of culture medium from the bottom of tank through methanogenic consortium of microorganisms. Process produces biogas and coal-water fuel. |
Method of treating bottom zone of low-permeable oil reservoirs / 2244111 Invention aims at increasing productivity of oil- and gas-producing and injecting wells exposing high-temperature low-permeable oil reservoirs. In the treatment method according to invention including forcing enzyme substrate and separate enzyme into formation and creating conditions to enzymatically convert substrate into acid, geologic and productive characteristics for each interval of bottom zone are determined in order to pick out low-permeable intervals of oil reservoir for treatment, whereupon properties of enzyme substrate and separate enzyme as well as conditions for their pumping are chosen. Substrate utilized in the method is head fraction of methyl- and/or ethyl-, and/or butyl acetate production, to which aliphatic alcohols are added, and enzyme is an acid solution. Substrate is pumped simultaneously and/or before, and/or after pumping of enzyme, after which well is closed for some time and then opened and placed under predetermined operational conditions. |
Device for treating well walls within range of productive bed / 2244112 Device has pipe-like body with detachable upper and lower sleeves. Concentrically to body, with possible rotation relatively to it, a cover is mounted with blades with scrapers placed spirally on its surface. To lower sleeve a reactive end piece is connected with slit apertures. End piece hollow is filled with granulated material engaging in exothermal reaction with acid. Lower portion of end piece is provided with check valve. Upper sleeve is provided with check valve having locking element in form of sphere with shelf and centering elements, to be dropped from well mouth. Base of saddle of check valve is made in form of disc having diameter equal to diameter of body. Pass aperture of saddle in lower portion is overlapped with easily destructible and easily removed element. Length of sphere shelf is greater than height of pass aperture of saddle of check valve of upper sleeve. |
Composition for treating bottom zones of wells / 2244114 Invention relates to compositions used for intensifying wells owing to increasing permeability of rocks forming well bottom zones. Composition of invention contains 7.0 to 30.0% ethanol, 0.1 to 0.3% cupric chloride, 0.1 to 0.5% alkylbenzenesulfonate, and trichloroacetic acid (to 100%). |
Acid composition for treating terrigenous oil reservoirs and a method for acid treatment of bottom area of formation / 2244816 Invention provides composition that can be used to intensify oil inflow and to develop well by means of acid treatment of terrigenous oil reservoir as well as to intensify oil inflow and to increase oil recovery of formations with the aid of hydraulic rupture of formation assisted by acid solutions. Composition contains borohydrofluoric acid needed to create borosilicate films prohibiting migration of particles during acid treatment. In addition, composition is characterized by lowered rate of reaction with rock at formation temperature in order to extend coverage of formation by treatment and to diminish deposit formation risk, low surface tension, low corrosion rate, and compatibility with inhibitors added to commercial acid, which will enhance efficiency of acid treatment using composition of invention. Composition is made up of, wt %: inhibited hydrochloric acid 8.0-15.0, fluorine-containing reagent (hydrofluoric acid, ammonium bifluoride, or ammonium fluoride) 1.5-10.0, boric acid 1.0-3.0, additionally isopropyl alcohol 5.0-10.0, and "Alkylfosfat-Khimeko" or "Efiroks-7", or "Fosfol-10" 0.5-2.0, and fresh water to 100%. In a method of acid treatment of the bottom area of terrigenous formation comprising consecutively pumping flushing fluid and acid composition into borehole, forcing the latter into formation by the aid of flushing fluid, giving time (up to 8 h) for reaction and subsequent removal of reaction products. Acid composition is used as it is or in the form of aqueous solution obtained by diluting composition with fresh water at water-to-composition ratio (1-5):1 in amount corresponding to 0.5-2.0 m3 per 1 m of perforated thickness of the formation. As flushing fluid, 1.5-3.0% ammonium chloride solution is used in amount 0.5-1.5 m3/m before pumping of acid composition or in amount 1.0-5.0 m3/m when used to force acid composition. |
Composition for declaying of bottom-hole formation zone / 2246612 Declaying composition contains clay dispersing reagent, peroxide compound and water, wherein as peroxide compound potassium fluoride peroxysolvate in activated form, comprising 1-3 mass % of oxalic or salicylic acid; and includes two sequential technological solutions. More specifically claimed composition contains (mass %): technological solutions 1: potassium fluoride peroxysolvate 1-2.5; hydrochloric acid as clay dispersing reagent 3-8.0; and balance: water; technological solutions 2: potassium fluoride peroxysolvate 1-2.5; sodium hydroxide as clay dispersing reagent 4-6.0; and balance: water. In addition said solution contain 0.1-1.0 mass % of water soluble surfactant. After treatment with disclosed solutions and well exposure dispersed reaction products are removed from bottom-hole formation zone. |
Method for increasing productiveness of oil and gas wells / 2247234 Method includes acidic treatment of bed, calculation of hardness decrease and pressure of rocks tearing and pressure for pressing working solution into bed, completion of well and the actual hydraulic tear. Pressure for pressing is determined from formula Pht=(2μ·Pm/(1-μ)+(1-3μ)·Pb/(1-μ), where Pht - rocks tear pressure, Pm - mountain pressure, Pb - bed pressure, μ - Poisson coefficient. |
Oil extraction methods / 2247235 Method includes treatment of face area of oil bed by hydrophobic powder in organic and pushing oil away from collector with following delivery of oil from face-adjacent area of extraction well for processing of oil-containing terrigenic bed into organic solvent additionally inserted is copolymer of ethylene with vinylacetate, well treatment is performed with relation of components in percents of mass: said powder 0.05-2, said copolymer 0,05-2, organic solvent - the rest. |
Method for range-wise treatment of productive layer through open horizontal well shaft and device for realization of said method / 2247832 Method includes determining porosity, penetrability and oil saturation level of shaft-adjacent area along whole length of deflected shaft. On basis of these ranges with low penetrability are detected, caverns presence level and diameters of shaft on ends thereof are determined. With consideration of characteristics of detected ranges at surface a pipe assembly is assembled, at end of which a ring saddle is mounted for locking ball, on both ends - hydraulic packers. Between these in assembly pipe a radial through calibrated channel is made. Pipe assembly is fixed at end of pipes column and these are lowered into chamber to level of deflected shaft mouth. With unpacked packers straight and backward washing of shaft is performed. After that acid is pumped into well in amount, equal to amount of first treatment range. Locking ball is dropped, first from the face shaft range with low penetrability is packed and concurrently acid is pressed therein, after that well is left for reaction. Then both packers are unpacked, backward washing of shaft is performed. By raising pipe column, pipe assembly with packers is transferred in backward, from face, direction into area of second, from face, range with low penetrability and above-mentioned operations are repeated. In turns, operations with each treatment range are performed. |
Method for acidic treatment of productive bed / 2247833 Method includes serial pumping of film-forming hydrocarbon liquid and hydrochloric acid with adding of salt-acidic corrosion inhibitor to these, as said inhibitor a special paraffin deposits inhibitor is used, in form of composition of surfactants and aromatic solvents, while hydrochloric acid with addition of inhibitor before pumping is dispersed with gas to receive foam. |
Method for processing underground productive beds / 2249097 Method includes injection of processing liquid into bed, which liquid contains solved or dispersed in water complicated ether and polymer destructor, selected from oxidizing destructor and ferment destructor in such a way, that complicated ether is hydrolyzed with production of organic acid for solution of material soluble in acid, present in filtering layer or adjacent to it or in other damage in productive bed, and polymer destructor destroys polymer material, present in filtering layer or bio-film in productive bed. |
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