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Method for near well-bore treatment with acid. RU patent 2490444.

IPC classes for russian patent Method for near well-bore treatment with acid. RU patent 2490444. (RU 2490444):

E21B43/27 - by use of eroding chemicals, e.g. acids
Another patents in same IPC classes:
Procedure for treatment of bottomhole zone of producer with two wellheads Procedure for treatment of bottomhole zone of producer with two wellheads / 2490443
In procedure for treatment of bottomhole zone with two wellheads in case of failure of an electric-centrifugal pump (ECP) with no apparent deviation in its operating parameters and in case of alkalinity growth for extracted product up to pH>7 the required volume of hydrogen chloride solution is calculated on the basis of a length and diameter of the well filtering part; the required volume of hydrogen chloride solution is selected to treat the whole volume of the strainer; the required volume of flush fluid is calculated for delivery of compounds into a slope wellhead. ECP is shutdown at the vertical wellhead before pumping of hydrogen chloride solution is started. The required volume of hydrogen chloride solution is carried out into tubular annulus from the side of the vertical wellhead. When pumping of hydrogen chloride solution is over extraction from the slope wellhead is increased and ECP is started from the vertical wellhead. ECP is stopped at the vertical wellhead and hydrogen chloride solution is overflushed by the flush fluid into filtering part of the well. After ECP startup in enlarged extraction rate from the slope wellhead samples are taken periodically in order to check pH value, monitor dynamics in changes of fluid supply from the slope wellhead. When pH value id recovered up to the normal value ECP is started into operation from the vertical wellhead and supply from the slope wellhead is returned back to normal operation mode.
Method for well completion / 2490442
In method for well completion including pumping of acid solution into open horizontal hole in the mode of jet impact such impact is attained due to a jet delivery by a jet nozzle at the end of a flexible flush-joint pipe. The nozzle is placed at the borehole bottom. The acid solution is pumped with circulation through the well mouth; while acid solution is circulating the flexible flush-joint pipe is lifted simultaneously from the well with the speed not exceeding speed of the borehole filling by the acid solution. When horizontal hole is filled with the acid solution, the solution is overflushed into the stratum with staged pressure build-up and exposure at each stage. The flexible flush-joint pipe with a nozzle is placed again at the borehole bottom and the operation of borehole filling and overflushing is repeated again. Soaking takes place so that acid solution could react with the rock. The flexible flush-joint pipe is lifted to the interval of inert gas pumping, an inert gas is pumped and a build-up curve is recorded. Cyclic well killing is carried out in the mode of water pumping - soaking - oil draining till complete oil drain; thereafter a submerged pump is run-in and the well is input into operation.
Device for treatment of bottomhole formation zone of a well and method for treatment of bottomhole formation zone of well Device for treatment of bottomhole formation zone of a well and method for treatment of bottomhole formation zone of well / 2487237
Device for treatment of bottomwhole formation zone contains an air chamber with atmosphere pressure and length of 20-50 m connected to the first additional perforated chamber with seal layer, solid heat generating compound A with flame igniter, combustible high-strength compound B and breakable calibrated membrane located inside; the first added perforated chamber by means of a coupling with holes is connected to the second added inlet chamber with combustible high-strength compound C, igniter and breakable calibrated membrane located inside; the second additional perforated chamber by means of a coupling with added air chamber with length of 1.5-3 m connected by means of a coupling and metal adapter with to inlet chamber that is made of elastic plastic material with seal layer, solid acid generating compound D with igniter located inside; in the metal adapter there are drilled holes; compound A generated heat and gas of the following components by wt %: ammonium nitrate 35; sodium bichromate 2; barium nitrate 15; aluminium ASD-1 1.5; iron-aluminium thermite 31; epoxide compound (mixture of ED-20 tar, EDOS plasticiser and AF-2M hardener) 15.5; compound B is made of the following components by wt %: ammonium nitrate 30-40, calcium carbonate 5-10, the above epoxide compound 50-65; inside the added inlet chamber there is a layer of glass sealant and solid gas generating compound E made of the following compounds by wt %: ammonium nitrate 70, sodium bichromate 1, the above epoxide compound 29; compound C is made of the same composition as compound B; compound D is made as thermal-gas-chemical solid fuel with a layer of glass sealant and a layer of epoxide compound on top of it; the above fuel consists of the following components by wt %: ammonium nitrate 12-16, lithium fluoride 1-3, barium nitrate 5-8, aluminium ASD-1 0.7-0.8, iron-aluminium thermite 14-16, hexachlorane 20-30, polytetrafluoroethylene 20-30, the above epoxide compound 5-10. The method for treatment of bottomhole zone (BHZ) includes delivery of the above device by a wireline, combustion of compound D and formation of maximum quantity of chemical agents, holding for the purpose of reaction of acids produced during combustion with BHZ formation, running with installation of the coupling with holes at the level of treated stratum, opening of the chamber with length of 20-50 m, actuation of breakable calibrated membrane in result of layer-by-layer combustion of compounds A and B with implosion treatment of BHZ, removal of impurities from bottomhole stratum; during holding thermal-gas-chemical impact acts on the stratum for 30 minutes ad pressure can be corrected due to availability of holes in the metal adapter at fixed position of the above fuel inside the inlet chamber due to the above layers of sealant and compound with formation of gases heated up to high temperatures at high pressure within treatment range; opening of the chamber with length of 1.5-3 m is carried out by sequential actuation of the igniter, compounds E and C and breakable calibrated membrane located in the second added inlet chamber; after hydraulic shock there's another holding of the process for 30 minutes; when the chamber with length of 20-50 m is opened combustion of compound A takes place with formation of gases heated up to high temperature at high pressure within treatment range.
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Method includes treatment of face area of oil bed by hydrophobic powder in organic and pushing oil away from collector with following delivery of oil from face-adjacent area of extraction well for processing of oil-containing terrigenic bed into organic solvent additionally inserted is copolymer of ethylene with vinylacetate, well treatment is performed with relation of components in percents of mass: said powder 0.05-2, said copolymer 0,05-2, organic solvent - the rest.
Method for range-wise treatment of productive layer through open horizontal well shaft and device for realization of said method Method for range-wise treatment of productive layer through open horizontal well shaft and device for realization of said method / 2247832
Method includes determining porosity, penetrability and oil saturation level of shaft-adjacent area along whole length of deflected shaft. On basis of these ranges with low penetrability are detected, caverns presence level and diameters of shaft on ends thereof are determined. With consideration of characteristics of detected ranges at surface a pipe assembly is assembled, at end of which a ring saddle is mounted for locking ball, on both ends - hydraulic packers. Between these in assembly pipe a radial through calibrated channel is made. Pipe assembly is fixed at end of pipes column and these are lowered into chamber to level of deflected shaft mouth. With unpacked packers straight and backward washing of shaft is performed. After that acid is pumped into well in amount, equal to amount of first treatment range. Locking ball is dropped, first from the face shaft range with low penetrability is packed and concurrently acid is pressed therein, after that well is left for reaction. Then both packers are unpacked, backward washing of shaft is performed. By raising pipe column, pipe assembly with packers is transferred in backward, from face, direction into area of second, from face, range with low penetrability and above-mentioned operations are repeated. In turns, operations with each treatment range are performed.
Method for acidic treatment of productive bed Method for acidic treatment of productive bed / 2247833
Method includes serial pumping of film-forming hydrocarbon liquid and hydrochloric acid with adding of salt-acidic corrosion inhibitor to these, as said inhibitor a special paraffin deposits inhibitor is used, in form of composition of surfactants and aromatic solvents, while hydrochloric acid with addition of inhibitor before pumping is dispersed with gas to receive foam.
Method for processing underground productive beds Method for processing underground productive beds / 2249097
Method includes injection of processing liquid into bed, which liquid contains solved or dispersed in water complicated ether and polymer destructor, selected from oxidizing destructor and ferment destructor in such a way, that complicated ether is hydrolyzed with production of organic acid for solution of material soluble in acid, present in filtering layer or adjacent to it or in other damage in productive bed, and polymer destructor destroys polymer material, present in filtering layer or bio-film in productive bed.

FIELD: oil and gas industry.

SUBSTANCE: method for near well-bore treatment with acid involves at the first stage pumping into the well of 10-15% aqueous solution of hydrogen chloride in a volume calculated on the basis of 0.25-0.5 m3 per 1 running metre of penetrated stratum depth; at the second stage - pumping of 10-15% aqueous solution of hydrogen chloride with a retarder of the acid reaction with rock in the volume of 2-5% of acid solution volume in total volume of pumping calculated on the basis of 1-1.5 m3 per 1 running metre of penetrated stratum depth at initial pressure equal to the final pressure value during pumping at the previous stage; overflushing by oil in volume of 5-15 m3 at initial pressure equal to the final pressure value during pumping at the previous stage; soaking during 16-48 hours and input of the well into operation.

EFFECT: improvement in efficiency of near-wellbore treatment.

3 ex

 

The invention relates to the oil industry and may be used in the acid treatment zone.

There is a method of acid treatment of bottom-hole zone of a petroleum layer, which includes the injection of a whipstock - hydrocarbon gel prepared with using «-N»activator «-N and diesel fuel and the subsequent processing at least one zone of formation of hydrochloric acid with concentration from 12 to 24%, while in case of repeated processing operations hydrochloric acid apply with decreasing concentration and the reduction of its volumes (RF Patent №2456444, publ. 20.07.2012).

The closest to the proposed invention is essentially a technical method of extraction of oil by injection acid composition, containing the acid, and composition containing surface-active agent (surfactant) and liquid hydrocarbon acid composition additionally contains retarder to the reservoir rock - or Zeolite, or crumb of synthetic zeolites, or concentrate syenite , or sodium lignosulfonates, or carboxymethylcellulose CMC, or CMC brand CMC-9, CMC-9S, or , or aluminum, in the following ratio of components, mass%: acid 97,5-99,9 specified moderator 0,1-2,5, injecting acid composition is carried out before or along with the song, containing surfactant and liquid hydrocarbons at a ratio Mac.%: Surfactants 5-16, liquid hydrocarbon 84-95, with a ratio of its volume to the volume of the acid composition from 2 to 4. And perform the injection of the components of both in production and injection wells (RF Patent №2295635, . 20.03.2007 - prototype).

General the disadvantage of this method is the low efficiency of processing, as expressed in a minor increase of well productivity after processing.

The proposed invention solves the problem of increase of efficiency of processing.

The task is solved by a method of acid zone, including at the first stage injection into the well 10-15%aqueous solution of hydrochloric acid from the calculation 0,25-0,5 m 3 1 m a perforated thickness of a seam, at the second stage pumping 10-15%solution of hydrochloric acid with the moderator reaction in the volume of 2-5% of the volume of the solution acid based 1.0 to 1.5 m 3 1 m a perforated capacity of the reservoir when the initial pressure equal to the end-pressure injection in the previous step, oil in the volume of 5-15 m 3 when the initial pressure equal to the end-pressure injection in the previous step, the technological holding during the 16-48 hours and putting well into operation.

The essence of the invention

Carbonate reservoirs are characterized by multidirectional fracturing, heterogeneity and a low coefficient of oil extraction.

In the case of a high viscosity of the oil produced after drainage of the collector, directly adjacent to the perforations well, there is a sharp drop in oil production rate, caused by the non-Newtonian properties of reservoir fluid. Existing technologies are not effective in these circumstances. The offered complex processing of carbonate reservoir aims to involve in the development of low-permeability and isolated zones of the layer. The consequence of this is to increase the production of the well and, ultimately, the oil recovery.

In the course of processing the increase permeability of the reservoir, improve reservoir properties of the layer through the use of hydrochloric acid, increase the coverage of acid stimulation by adding moderator acid reacts with the breed.

The important point is the continuity of performance of all works, i.e. injection components at a later stage of works with the initial pressure, equal to the final pressure on the previous stage.

The essential feature of the proposed invention is the ratio of injection solution of hydrochloric acid and hydrochloric acid solution with moderated as(0,25-0,5):(1,0-1,5). As the practice has shown precisely this correlation allows the greatest degree to increase well production as a result of processing.

The ratio of the components in solutions and volumes of injected components are defined from the practice as the most optimal solution. Going beyond the stated limits reduces the efficiency of processing.

As moderator of hydrochloric acid reaction with the breed use HCI-1, produced according to TU 2481-002-72650092-2009 or SNPH-8903 (specs 2458-314-05765670-2006 with MEAs. №1). Can be used classic retardants that are indicated when the description of the prototype.

Examples of specific performance

Example 1. Develop Deposit Bashkir tier. Collector - carbonate. The average well rate to 1.6 t/day., the average watercut of 11.6%. Plast has porosity of 13.2 percent, permeability 81,3 microns 2 * 10 -3 , oil saturation 82,4%, and the initial reservoir pressure 9 MPa, the depth of the soles of the reservoir 1041,5 m, reservoir temperature : 23 degrees C, viscosity oil in the reservoir conditions 292,5 MPa*s, the density of oil 937 kg/m 3 .

Through a stopped the oil well №1 in the layer with carbonate collector at the first stage pump 10%aqueous solution of hydrochloric acid in the amount of 3.5 m 3 (0.25 m 3 per 1 running meter perforated power) at initial pressure of 0.3 MPa and final pressure of 0.3 MPa, the second stage is injected 14 m 3 (1 m 3 1 p. m perforated layer thickness) 10%solution of hydrochloric acid with the moderator reaction HCI-1 in the amount of 2% from the volume of the acid solution at the initial pressure of 0.3 MPa and final pressure 0.5 MPa, produce oil in the volume of 5 m3 at home 0.5 MPa and final pressure of 1 MPa, conduct technological holding within 16 hours and impose the well into operation.

As a result of oil production increased from 1,8 to 4,5 m 3 /day.

Example 2. Perform as an example 1.

Through a stopped the oil well №2 in the reservoir with carbonate collector at the first stage pump 12%aqueous solution of hydrochloric acid in the volume of 10 m3 (0.4 m 3 per 1 running m perforated layer thickness) at initial pressure 0,25 MPa and final pressure 0,25 MPa, at the second stage pump 30 m 3 (1,2 m 3 per 1 running m perforated power formation) 12%solution of hydrochloric acid with the moderator reaction SNPH-8903 But in the quantity of 3.5% of acid solution at the initial pressure of 0.25 MPa and final pressure 0.5 MPa, produce oil in the volume of 10 m3 with the initial pressure of 0.5 MPa and final pressure 1.1 MPa, conduct the technological holding within 24 hours and impose the well into operation.

As a result of oil production increased from 1.8 to 4.8 m 3 /day.

Example 3. Perform as an example 1.

Through a stopped the oil well №3 in the reservoir with carbonate collector at the first stage pump 15%aqueous a solution of hydrochloric acid in the amount of 12 m 3 (0,5 m 3 per 1 running m perforated layer thickness) at initial pressure of 0,2 MPa and final pressure of 0,2 MPa, at the second stage pump 36 m 3 (1.5 m 3 per 1 running m perforated power layer) 15%solution of hydrochloric acid with the moderator reaction HCI-1 in the amount of 5% from volume of the acid solution at the initial pressure of 0,2 MPa and final pressure 1.6 MPa, produce oil in the volume of 15 m3 at the initial pressure of 1.6 MPa and final pressure 1.9 MPa, conduct technological holding within 48 hours and impose a well in operation.

As a result of oil production increased from 1.5 to 4.4 m 3 /day.

Application of the proposed method will allow to increase efficiency of processing zone.

Method of acid zone, including at the first stage injection into the well 10-15%aqueous solution hydrochloric acid in the amount of calculation 0,25-0,5 m 3 per 1 running m perforated thickness of a seam, at the second stage pumping 10-15%aqueous solution of hydrochloric acid with the moderator of acid reaction with the breed in the volume of 2-5% of the volume of the acid solution in the amount of downloads from the calculation of 1-1,5 m 3 per 1 running m perforated capacity of the reservoir when the initial pressure equal to the end-pressure injection in the previous step, oil in the volume of 5-15 m 3 when the initial pressure equal to the end-pressure injection in the previous step, the technological holding within 16-48 h and putting well into operation.

 

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