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Method for elastic foam

Method for elastic foam
IPC classes for russian patent Method for elastic foam (RU 2130466):
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(57) Abstract:

The invention relates to a method for producing elastic foam cellular structure, which can be used in the automotive industry, housing construction and other industries, including the production of sports destination. The invention consists in the fact that Polyoxypropylenediamine content PSO-groups from 2.0 to 4.0 wt. % foamed in the presence of latex with a dry matter content of not less than 20 wt.% when the mass ratio of 80-20:20-80. The specified latex acts as a catalyst, emulsifier, foaming agent and polymer matrix. Obtained in this method, the foam has a high elasticity, tensile strength, resistance to long-term compression and cyclic compression. table 1.

The invention relates to a method for producing flexible foams of cellular structure that can be used in the automotive, housing, household and other industries, including the production of sports destination.

A known method of producing foam by foaming isocyanates canadapurchase product, a mixture of a polyhydric alcohol with a molecular mass of 2800-5600 and toluylene diisocyanate, as the catalyst used octoate tin and dimethylethanolamine or octoate tin, bis-(2-dimethylaminoethyl)-ether, triethylenediamine, or octoate zinc and dimethylethanolamine, or N,N-dimethylcyclohexylamine and N-ethylmorpholine, as emulsifier - silicone emulsifier, and as a blowing agent is water (see SU patent N 668615, IPC 08 J 9/02, 1976).

The disadvantages of the method are the complexity of the receipt of the foam through the use of a large number of components and the need for their accurate dosing, and the foam has poor physical and mechanical properties: elasticity, the nominal tensile strength, resistance to long-term and cyclic compression, which limits the range of its use.

The closest in technical essence and the achieved effect is a method of producing elastic foam by foaming isocyanatobenzene product in the presence of a catalyst, emulsifier and foaming agent, as isocyanatobenzene product, a mixture of a polyhydric alcohol with a diisocyanate, as catalyst, a mixture of 2,2,2-diazabicyclo and dimethylaminomethylphenol with ATA and advanced socialization - octoate tin, as an emulsifier - block copolymers of polyorganosiloxane and polyoxyalkylene, and as a blowing agent use water (see EN 1275018, IPC C 08 G 18/14, 1985).

The disadvantages of the method are the complexity of the receipt of the foam through the use of a large number of components and the need for accurate dosing, and the foam has poor elasticity, the nominal tensile strength, resistance to long-term and cyclic compression, which limits the range of its use.

The objective of the invention is to provide a less cumbersome method of obtaining a foam having a higher physical and mechanical properties: elasticity, the nominal tensile strength, resistance to long-term and cyclic compression.

The technical problem is solved by a method for elastic foam by foaming isocyanatobenzene product in the presence of a catalyst, emulsifier, foaming agent, which as isocyanatobenzene product use Polyoxypropylenediamine with a content of NCO-groups from 2.0 to 4.0 wt. %, and as a catalyst, emulsifier, foaming is when the mass ratio of latex to Polyoxypropylenediamine (20-80) : (80-20), it allows to increase the elasticity of the foam 3.5-14.5 times, conditional tensile strength 2.5 times, resistance to long-term compression 1.3-2.4 times, resistance to cyclic compression 1.3-2.1 times while reducing labor costs for obtaining foam through the use of fewer components.

Polyoxypropylenediamine (urethane prepolymer - see addition to the technical Regulation TR 104.43-89 NGO "Kazan synthetic rubber plant them. S. M. Kirov) is a product of the interaction polyoxypropyleneglycol (simple oligoether - Laprol - see the all-Union scientific research Institute of synthetic resins. Department of the research Institute of feasibility studies, Cherkasy. Simple and complex oligoesters. The catalogue. Cherkasy-1981) and the organic isocyanate (di - or polyisocyanate ľ see B. A., Tombrou. Polyurethanes. TRANS. from English. State scientific and technical publishing house of the chemical literature. Moscow, 1961.- S. 13-18).

In the method of producing elastic foam can be used both natural and synthetic and artificial latexes with a dry matter content of not less than 20 wt.%.

Natural, synthetic is either directly from the milky juice of plants (natural latex), or by the polymerization (copolymerization) of unsaturated hydrocarbons (synthetic latex), or by dispersion of the polymers in the aqueous phase (artificial latexes).

Example 1 (the prototype). Pre-cook the promoters I and II.

Activator I: mixed catalyst 2,2,2-diazobicyclo (0,132 wt.h. ) and 2-N,N-dimethylaminomethylphenol (0,093 wt.h.) with a blowing agent is water (2.8 wt. o'clock) and the emulsifier is a block copolymer of polyorganosiloxane and polyoxyalkylene (1.1 wt. o'clock) and intensively stirred.

Activator II: mixed polyhydric alcohol Laprol 3003 (3.8 wt.h.) and socialization - octoate tin (0.2 wt. hours).

Then the container is placed polyhydric alcohol - Laprol 3003 (96,2 wt. h) add the activator I and II, the resulting mixture was mixed thoroughly and add to 3.3 wt. hours of diisocyanate. The mixture is stirred, poured into a form and for a speedy setting is placed in a heat chamber and incubated for 15-20 min at 80oC, then a day at room temperature. The resulting foam is subjected to physico-mechanical tests.

Similarly carry out the method with other content components.

Example 2 (present method). In Salvia Laperla-3503 with a diisocyanate, a = content of NCO-groups to 2.8 wt. % with 50 synthetic butadiene-styrene latex SCS-With a dry matter content of 55 wt.% (THE 38.103230-85). Mixing lead for 3 min, then the mixture is then poured into the form and kept in a heating Cabinet at 80oC within 60 minutes After cooling from the form pull elastic foam. The resulting foam is subjected to physico-mechanical tests.

Examples 3-4 analogous to example 2. The ratio Polyoxypropylenediamine and latex SCS-S (wt.) 80:20 and 20:80, respectively.

The examples 5 and 6 is similar to example 2. As Polyoxypropylenediamine use the products of interaction of Laprol-4503 and Laperla-6003 with diisocyanate.

Examples 7-8 analogous to example 2. The content of NCO-groups in Polyoxypropylenediamine respectively 2.0 and 4.0 wt.%.

Example 9 same as example 2. As latex uses latex butadiene-vinylidenechloride DWHB-70 with a dry matter content of 27 wt.% according to OST 38.03204-80.

Example 10 same as example 2. As use latex natural latex with a dry matter content of 60 wt.%.

Example 11 same as example 2. As use synthetic latex water dispersion of polisar the ERU 2. As latex uses latex butadiene-styrene SCS-GP with a dry matter content of 35 wt.% according to GOST 10564-75.

Examples 13-14 analogous to example 2. As Polyoxypropylenediamine use the product of the interaction of Laprol-3503 with MDI (diphenylmethanediisocyanate) and PIZ (polyisocyanate) with a content of NCO-groups of 2.4 and 2.9 wt.% respectively.

The foams obtained in examples 2-14, were tested for elasticity, conditional tensile strength, residual strain in compression 50% resistance to long-term compression and fatigue under cyclic compression.

The apparent density of the material is determined according to GOST 409-68 relative sample mass to its volume.

The elastic rebound determine the share of energy returned by the sample, relative to the energy of free-falling pendulum. Use pendulum elastomer with brisk hemispherical shape with a radius of 15 mm and the distance from the axis of rotation of the pendulum to the center of the stroke 200 mm

Conditional tensile strength determined on samples cut from a billet thickness of 10 mm according to GOST 15873-70.

The residual deformation of the elastic foams under compression by measuring the C flexible molded polyurethane foam", assessing the relative residual deformation after 5000 cycles of compression at 75% strain.

Data on physical-mechanical indicators listed in the table (see the end of the description).

Thus, the claimed method of producing foam less time-consuming due to the use of a smaller number of components and the need for their accurate dosing. The foam obtained in this way has a 3.5-14.5 times greater elasticity, 2.5 times more conditional tensile strength, 1.3-2.4 times greater resistance to long-term compression and 1.3-2.1 times to cyclic compression compared to the prototype, which expands the area of its use.

Party foam by the present method obtained in NPF Tamerlan" and was successfully tested.

Method for elastic foam by foaming isocyanatobenzene product in the presence of a catalyst, emulsifier, foaming agent, characterized in that as isocyanatobenzene product use Polyoxypropylenediamine with a content of NCO-groups from 2.0 to 4.0 wt. %, and as a catalyst, emulsifier, foaming agent and, optionally, a polymeric matrix and openposition (20 - 80) : (80 - 20).

 

 

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