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A method of obtaining a semi-rigid polyurethane foam |
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IPC classes for russian patent A method of obtaining a semi-rigid polyurethane foam (RU 2110530):
A method of obtaining a molded urethane elastomers / 2107073
The invention relates to methods for molding urethane elastomers with high strength properties and may find application in engineering, for example, for the manufacture of coating rolls of paper machines, rollers assemblies of sheet metal and other bulky items
Method of producing elastic polyurethane foam cold forming and activating the mixture for its implementation / 2103279
The invention relates to the field of technology for elastic monopolarity in the presence of a catalyst, and may find application in the manufacture of gaskets furniture and upholstered car seats
The way to obtain hydroxyl-containing component for the production of flexible molded polyurethane foam / 2101302
The way to obtain in closed form elastic polyurethane foam product and elastic polyurethane foam products / 2100383
The invention relates to the chemistry of polyurethanes and concerns a method for obtaining the closed form elastic polyurethane foam products used in the furniture industry, vehicles and so on
The method of producing polyurethane foams / 2098434
The invention relates to the production of polyurethane foams and concerns a method for obtaining polyurethane foam plastics, in which the foaming is produced using pure nitrogen as a pore-forming means
Polyol as one component of isocyanate foams with reduced flammability / 2098432
The invention relates to the production of foams with reduced Flammability based on isocyanates and can be used in the manufacture of thermal insulation in industrial and civil construction at the place of use
A method of obtaining a hard moulded polyurethane foam / 2080336
The invention relates to the field of production of rigid moulded polyurethane foam and can be used in various industries for manufacturing of large-sized products of variable thickness and complex configuration
The way to obtain hydroxyl-containing component for the production of flexible molded polyurethane foam / 2076877
The invention relates to polyurethane chemistry and relates to a method of obtaining a hydroxyl-containing component for the manufacture of flexible molded polyurethane foam (PUF), which can be used in the furniture and automotive industries
The method of producing polyurethane foam / 2076115
The invention relates to methods for producing a rigid polyurethane foam used in the manufacture of refrigeration equipment, construction, etc
Mixture for obtaining flexible polyurethane foam / 2326132
Invention pertains to the mixture for obtaining flexible polyurethane foam and can be used as mastic for hydro and thermal insulation of foundations, buildings, pipelines, as well as for filling cavities in building structures. The mixture contains defined ratios of the following components: a hydroxyl containing oligomer-copolymer of butadiene and piperylene with molecular mass of 2100 and containing 0.92% hydroxyl groups; isocyanate component - polymethylene polyphenyl isocyanate with 29-31% content of isocyanate groups; catalysts: dibutyl tin dilaurate and N,N,N- triethylamine; water; glycerine; polydimethyl siloxane and polydimethyl siloxane modified by a polyester in the form of foam stabilisers and extra bitumen. Use of bitumen considerably lowers moisture absorption of the material and increases viscosity of the foam systems. This also enables the material to retain the density attained during foaming. Use of defined foam stabilisers in the mixture enables formation of more fine cells, with high stability and attainment of low density of the polyurethane foam.
Polyurethane foam made of hydroxymethyl-containing polyesterpolyols / 2352593
Invention refers to method for making bulk, high resilience slabstock or moulded foam, used for upholstery, automobile seats and panel cushions, for packing, other applications to softening and energy management, for sealing and other applications. The presented method involves as follows. Organic polyisocyanate contacts with polyol compound containing high mass equivalent polyol or mixed polyols with foaming agent, gelling catalyst and surface-active substance added. At least 10 wt % of high mass equivalent polyol (polyols) represent one or more equivalent mass hydoxymethyl-containing polyesterpolyols at least 400 up to 15000 produced by interaction of hydoxymethyl group containing fatty acid with 12-26 carbon or this acid ester atoms and compound initiator polyol or polyamine, thereby polyesterpolyol contains as follows: [H-X](n-p)-R-[X-Z]p, where R is residual compound initiator, X is independent, -O-, -NH- or -NR'-, while Z- represents linear or branched chain containing one or more groups A, independently chosen of groups A1, A2, A3, A4 and A5, expressed by formulas (II), (III), (IV), (V) and (VI), respectively. Besides there is disclosed polyurethane foam made by the declared method. Declared method ensures making polyurethane foams with using polyol from renewable source.
Method of obtaining compounded foam polyurethane / 2355713
Invention concerns method of obtaining compounded foam polyurethanes for operation as shock, heat and sound absorbing layers. Compounded foam polyurethanes are obtained by interaction of 100 weight parts of polyol component and 20 weight parts of polyisocyanate component, where polyol component is mixed preliminarily with 70-100 weight parts of rubber chips, and reaction mix is foamed and solidified at 160°C or higher to component destruction temperature. Butadiene and piperylene copolymer with 1200-3200 molecular weight and 0.8-1.1% content of hydroxylic groups is used as polyol component, and polymethylenepolyphenylisocyanate with 29-31% content of isocyanate groups is used as polyisocyanate component.
Method for production of polyurethane foam / 2356915
Invention is related to method for production of polyurethane foam with application of secondary waste of polyethylene terephtalate, and may be used for production of hard polyurethane foams. Polyurethane foam is produced by interaction of polyisocyanate with polyol component containing secondary waste of polyethylene terephtalate dissolved in triethanolamine or in mixture of mono-, di-, trichloracetic acids, in amount of not more than 67 wt % from total weight of polyol component. At that interaction is carried out at the ratio of polyol component : polyisocyanate as 1:1 - 1:2. Prepared polyurethane foams have good consumer properties, such as compression strength, oil-, heat resistance and reduced inflammability.
Flexible polyurethane foam / 2376321
Polyurethane foam is obtained by mixing a pre-polymer with foaming ingredients, containing at least one multifunctional isocyanate and water, which react releasing carbon dioxide. The pre-polymer, which has terminal hydroxyl groups, is obtained by reacting at least one polyol with less than a theoretical amount of at least one multifunctional isocyanate. The pre-polymer which is stable during storage can be obtained with low or high viscosity by choosing the corresponding amount isocyanate, which reacts with polyol. Use of more viscous pre-polymer enables regulation and setting the size of cells of the obtained foam.
Method of producing rigid polyurethane foam / 2385330
Method involves reacting a composition based on organic polyisocyanates with a composition which reacts with isocyanates in the presence of a hydrocarbon as a foaming agent. The said composition which reacts with isocyanates contains a maximum of 20 wt % polyester-polyols obtained from secondary streams, wastes or residue from production of DMT and/or PET, between 30 wt % and 50 wt % polyether-polyol obtained by reacting propylene oxide with an aromatic amine as an initiator, and between 30 wt % and 50 wt % polyether-polyol which is not initiated by an aromatic amine, where amount is based on total amount of the compound which reacts with isocyanates. Rigid polyurethane foam or polyisocyanurate foam modified with urethane corresponding to this proposed invention has low lambda value especially at 10°C.
Fluoro-hydrocarbon compositions / 2395539
Present invention relates to compositions for foaming foam plastic used in insulation materials at low temperatures. The said composition ontains 1,1,1,3,3-pentafluorobutane (HFC - 365mfc) and 1,1,1,3,3-pentafluoropropane (HFC-245fa) with mass ratio HFC-365mfc/HFC-245fa between 65:35 and 73:27.The invention also relates to a premix for producing foamed polyurethane or modified foamed polyurethane which contains such a foaming composition, at least one polyol and a catalyst for reaction of isocyanates and polyols. The invention also describes a method of producing foamed polyurethane or modified foamed polyurethane using the disclosed foaming composition, as well as heat insulation material which contains foamed polyurethane or modified foamed polyurethane made using the said method. When prepared systems are used completely, the foaming composition does not have an ignition point, which provides safe production of (modified) foamed polyurethane.
Polyurethane system and method of making foamed low density shoe articles with solid coating / 2397996
Present invention relates to a liquid polyurethane reactive system for producing shoe articles with a solid coating, e.g. sole inserts, soles etc. This reactive system includes at least one polyol meant for reaction with at least one isocyanate prepolymer, an expansion agent, an additive which contains a catalyst and expanded microspheres. The polyol is selected from polyester polyols with molecular weight from 1500 to 3000. Amount of expanded microspheres ranges from 1.0 to 30 % of the weight of polyol and the additive. Amount of the expansion agent ranges from 0.5 to 3.5% of the weight of polyol and additive. The invention also relates to a method of producing foamed shoe articles with a solid coating using the said liquid polyurethane system, resulting in a foamed structure with spontaneous foam density between 0.05 and 0.22 g/ml, as well as to foamed polyurethane shoe components made using the said method, and to use of expanded microspheres in the said liquid reactive polyurethane system.
Foamed polyurethane / 2411254
Invention relates to polyurethane used, for example, as seat cushions, decorative elements for the inside of cars etc, and to methods of producing said polyurethane via radical-initiated cross-linking in the presence of at least one agent which produces radicals and under the effect of ionising radiation, respectively. According to the given method, at least one polyfunctional isocyanate, at least one polyol which is completely or mainly polyether polyol with molecular weight higher than 1500, and foaming ingredients are subjected to addition polymerisation and a foaming reaction in the presence of at least one component with a reactive double bond to obtain a foamed mass with a polyurethane matrix. The polyfunctional isocyanate is not 4,4'-diisocyanate diphenylmethane or does not contain 4,4'-diisocyanate diphenylmethane, and the foamed mass undergoes radical-initiated cross-linking with the component with the reactive double bond which is an acrylate or methacrylate polymer containing at least two hydroxyl groups which also react with the said isocyanate so as to be embedded into the polyurethane matrix.
Polymeric polyols and polymer dispersions obtained from hydroxyl-containing materials based on vegetable oil / 2412954
Invention relates to polymeric polyols obtained from hydroxyl-containing materials, as well as dispersions of polymer particles in the said material. The polyol has a continuous polyol phase and dispersion ethylene-unsaturated polymer particles grafted on at least one stabiliser. The polyol phase contains at least one hydroxymethyl-containing polyester polyol derived from a fatty acid or a fatty acid ester. The polyol is a product of reaction between 9(10)-hydroxymethyl stearate or its alkyl ester and polyether polyol, containing ethylene oxide or propylene oxide links. The dispersion particles are a vinylaromatic polymer, nitirle with ethylene unsaturation or a mixture of two or more of them. The stabiliser is an addition compound of polyether polyol and vinylmethoxy silane or isocyanate with ethylene unsaturation.
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(57) Abstract: Usage: to remove paraffin, rubbing ski lubricants, as a cleaning tool in everyday life. The inventive mixed complex polyetherpolyols with the content of hydroxyl groups 13,5 - 15,5%, surfactant (OL-7 or OL-10), triethylamine and water, add amorphous boron in an amount of 0.2 - 0.25.h. on 100 wt.h. the reaction mixture is stirred until a uniform distribution of boron and add dietandnutrition (GUDEG-2) with a content of NCO-groups 28 - 31%. The invention relates to the chemistry of the production of cellular plastics, namely the production is filled with polyurethane foam, which can be used, for example, to remove paraffin and rubbing ski lubricants, as a cleaning tool in everyday life. A method of obtaining polyurethane foam, when the hydroxyl-containing component is used a complex mixture of polyester diol, hydroxylaminopurine connection. In this method, the ratio of-NCO/-OH groups is 0.95 : 1 - 1,06 [1]. The reaction occurs in the presence of a catalyst and a blowing agent. The disadvantage of this method is the complexity of the process due to the complicated structure of the invasive properties when the abrasives are silicon carbide, aluminium oxide, cement and other [2] . But in such foams elasticity and abrasion properties tailored to very severe operating conditions. Closest to the proposed is a method for semi-rigid polyurethane foam in blocks by reacting diisocyanate with a mixture of polyols in the presence of catalysts, surfactants and blowing agent [3]. However, as the hydroxyl-containing component in this method uses a mixture of polyols of different molecular weight, which complicates the process. The abrasive properties of such semi-rigid polyurethane foam low. The aim of the invention is to simplify the process and obtaining a polyurethane foam having the desired combination of hardness and elasticity and abrasion. This objective is achieved in that for obtaining semi-rigid polyurethane foam use complex polyetherpolyols with the content of hydroxyl groups 13,5 - 15,5%, isocyanate content groups-NCO 28 - 31%. The complex polyester and isocyanate are mixed in a ratio of 1 : 0,9 - 1,1. To give polaczenie material - boron amorphous in amount of 0.2 - 0.25. including the reaction of the formation of foam takes place in the presence of a catalyst, a surfactant and a blowing agent. A comparison of the proposed solution with the prototype shows that the process of obtaining a semi-rigid polyurethane foam is easier, because as hydroxyl-containing component is used one substance is a complex polyetherpolyols, and in the prototype is a mixture of polyols of different molecular weight, which should be mixed from several polyols. The required rigidity and elasticity are not an application of a mixture of polyols of different molecular weights, and the corresponding ratio of complex polyetherpolyols and isocyanate. Thus, the claimed method meets the criteria of the invention of "novelty." A significant difference of the proposed method is that the semi-rigid polyurethane foam attached abrasive properties by adding boron amorphous. The proposed method for semi-rigid boron-containing polyurethane is implemented as follows. First, cook the mixture polyetherpolyols P-3 with a surface-active agent OP-10 (or OP-7), triethylamine ritilin - 0,26 - 0,31Water - 1,5 - 1,87 The mixture is intensively stirred for at least 5 minutes Directly before filling the form in which the curing of the polyurethane foam, the mixture of polyetherpolyols type amorphous boron in an amount of 0.2 - 0.25 g per 100 g of mixture. The mixture is stirred until a uniform distribution of boron. Then add to the mixture the product DODIG-2 90 - 110 g per 100 g of polyetherpolyols. The resulting mixture was intensively stirred for 20 - 30 seconds, then poured into a mold and stand in it to fully cure within 3 hours The proposed method for semi-rigid boron-containing polyurethane foam due to its simplicity and availability can be implemented in any production obtain foams. A method of obtaining a semi-rigid polyurethane foam by reacting hydroxyl-containing polyester, long catalyst, surfactant, water and isocyanatobenzene component, characterized in that as the hydroxyl-containing polyester use complex polyetherpolyols with the content of hydroxyl groups 13,5 - 15,5%, as surfactant - monoalkylphenol ether polietilentereftalata - the triethylamine as isocyanatobenzene component - dietandnutrition with a content of NCO-groups 28 - 31%, and before introduction into the reaction mixture dietadditionally enter amorphous boron in an amount of 0.2 - 0.25.h. on 100 wt.h. the reaction mixture, and complex polyetherpolyols and dietandnutrition use in their mass ratio of 1 to 0.9 : 1,1 respectively.
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