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The method of producing foam

IPC classes for russian patent The method of producing foam (RU 2128675):
C08J9C08G18/12 -
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(57) Abstract:

The foam is designed to remove the imprint of the foot in the manufacture of orthopedic shoes. The foam is produced by interaction of MDI with a monofunctional alcohol and water at a ratio of 1-10:1, and oxypropylation product of sucrose (mol.m. 400-600 in the presence of a catalyst, a plasticizer, taken in an amount of 20-80 wt.h. on 122,3-125 wt.h. MDI. The resulting foam contributes to the conservation form of the impression after removal of the load.

The invention relates to orthopedics, in particular to the creation of the material used to make impressions of the foot and making the impression of a plaster positive in the manufacture of individual insoles and footwear.

For the manufacture of high-quality orthopedic footwear and individual orthopedic insoles is important to manufacture the exact replica of the stage.

Currently, for the manufacture of the mould stage of use of the vacuum installation /SU, 1653737/ special electronic installation /DE, the application 3835008/. However, these are expensive to install, difficult to operate and do not allow to serve people with disabilities at home.

Know the use of phenolformaldehyde not meet all the requirements of environmental safety and do not possess the required sanitary and hygienic properties.

Alternative phenol can be the polyurea foams.

Closest to the claimed method is a method of producing foam - penopolietelen interaction MDI /PIZ/ water in the presence of a catalyst and small amounts of monofunctional alcohol, 5-15% by weight PIZ /US patent 4454251/.

However, this foam has no creasing, necessary for the production of casts. Under creasing the present invention is the ability of the foam to deform under the influence of a certain load and save the deformation after removal of the load.

The purpose of the invention is the obtaining of the polyurea foam with improved creasing, i.e. the ability to retain the shape of the impression after removal of the load, suitable for removal of the cast of the foot in the manufacture of orthopedic shoes.

This objective is achieved in that impose additional product oxypropylation of sucrose (mol. weighing 400-600 and a plasticizer in an amount of 20-80 wt. hours 122,3-125 wt.h. MDI when the mass ratio of the monofunctional alcohol and water, is 1-10:1.

To determine sinemasi foam used is set steel ball with a diameter of 60-0,5 mm and is maintained in this position 120 C. Then the ball is gently removed and the line is measured with an accuracy of 1 mm diameter imprint of the ball.

Experimentally it was found that to get a good foot print must be set to sinemasi determined by the above method, from 20 to 32 mm At specified values of cinemati foam is easily deformed when pressed stages and is not destroyed by pouring in the plaster test it.

According to the invention using the following raw materials: the product oxypropylation of sucrose (mol.wt. 400-600, namely:
Polyethers Maro Laprol 404 - project SPECIFICATIONS. Laprol 564-TU 6 -55-221-990-88. Laprol 501-2-45 THE 6 - 05-221-835-85.

The polyisocyanate - TU 113-03-38-106-90
Foaming agent-Halocarbon 11-TU - 6-02-727-78
Monofunctional alcohols-ethanol - GOST 18300-87, methanol - GOST 2222-78 Butanol - GOST 17299-71 ethylhexanol-GOST 26624-85
Distilled water - GOS 6709-72
Foam controller silicone cap-2 - TU 6-02-813-73
The plasticizer is dioctylphthalate, dimethylphthalate, dibutyl phthalate, dioctyladipate - TU 6-05-1347-75.

The proposed method for the polyurea foam was tested in laboratory and pilot-scale conditions.

Prepare a mixture of 9 wt.h. ethanol, 5 wt.h lapola, 404,5 wt.h. water, 1.1 wt. including CEP-2, 65 wt.h. dioctylphthalate, 2.5 wt.h. dimethylethanolamine, 10 wt.h. halon 11, mix. After stirring 124 wt. including PIZ, again stirred for 15-20 C and poured into the form size HH mm for foaming and curing.

The density of the obtained foam 30 kg/cm3,
breaking stress in compressionSG- 0.16 kg/cm2,
Shimamoto - 25 mm

Example 2.

The ratio of alcohol:water 1.2:1
Prepare a mixture of 6 wt.h. methanol, 8 mass.h. lapola, 564,5 wt.h. water, 1.1 wt.h. The CEP is 2.80 wt.h. dibutyl phthalate, 2 wt.h. dimethylethanolamine, 10 wt. including halon 11 and mix. After stirring 125 wt.h. PIZ, again stirred for 15-20 C and poured into a mold to foaming and hardening. - 28 kg/cm3,SG- 0.16 kg/cm2Shimamoto - 20 mm

Example 3.

The ratio of alcohol:water is 2.9:1.

Prepare a mixture of 14.5 wt.h. butanol, 5 wt.h. water, 6 wt.h. lapola 564, 1.1 wt. CEP-2, 55 wt.h. dimethylphthalate, 2 wt. hours of dimethylethanolamine, 10 wt. including halon 11 and mix. To the mixture is added 123 wt. including PIZ, stirred for 15-20 C and poured into the m

Example 4.

The ratio of alcohol:water 5:1.

Prepare a mixture of 25 wt.h. 2 - ethylhexanol, 5 wt. water of 6.5 wt.h. lapola, 404,1,1 wt.h. CEP-2, 45 wt.h. dioctyladipate, 10 wt.h. halon - 11, 2.5 wt.h. dimethylethanolamine, mix, then add 124 wt. including PIZ, stirred for 15-20 C and poured into the form. After foaming and curing measure: - 22 kg/cm3,SG- 0,185 kg/cm2Shimamoto - 25 mm

Example 5.

The ratio of alcohol:water to 9.9:1.

Prepare a mixture of 4.5 ethanol, 45 wt.h. lapola 4 501-2-45, water, 5 wt., 5 wt. including lapola 564, 1 wt. dimethylethanolamine, 2 wt.h. CEP-2, 20 wt halon 11, 20 wt.h. dioctylphthalate, mix, then add 122,3 wt.h. PIZ, stirred for 15-20 C and poured into the form. After foaming and curing is measured to 25.4 kg/cm3,SG0.12 kg/cm2Shimamoto - 22 mm

Example 6 (control without plasticizer).

The ratio of alcohol:water to 1.8:1.

Prepare a mixture of 9 wt.h. ethanol, 5 wt.h. water, 0.7 wt. hours of dimethylethanolamine, 1 wt.h. CEP-2, 10 wt.h. halon, 11.5 wt.h. lapola 564, mix. To the mixture is added 110 wt.h. PIZ, stirred for 15-20 C and poured into the form. After foaming and curing Emini.

Example 7 (control without plasticizer and polyester).

The ratio of alcohol:water to 1.8:1
Prepare a mixture of 9 wt.h. ethanol, 5 wt.h. water, 0.7 wt.h. dimethylethanolamine, 1 wt.h cap-2.10 wt.h. halon 11, mix. To the mixture is added 110 wt.h. PIZ, stirred for 15-20 C and poured into the form. After foaming and curing measure - 9.9 kg/cm3,SG- 0.05 kg/cm2Shimamoto - 4,4 mm Foam crack under the strain, destroyed by pouring plaster test.

Example 8 (control with reduced alcohol content).

The ratio of alcohol:water is 0.9:1.

Prepare a mixture of 4.5 wt.h. ethanol, 5 wt.h. water, 0.7 wt.h. dimethylethanolamine, 1 wt. including CEP-2, 10 wt.h. halon -11,5 wt.h. lapola 546,65 wt.h. dioctylphthalate, mix. In the resulting mixture was added 120 wt.h. PIZ, stirred for 15-20 C and poured into the form. After foaming and curing measure - 22 kg/cm3,SG- 0.2 kg/cm2. After removal of the load, the foam does not retain the shape of the imprint.

Example 9 (prototype).

Prepare a mixture of 9 wt.h. water, 4 wt.h. of methanol, and 1.0 wt.h. the catalyst Polycat 17, surfactants 540 2 wt.h., mix and add the PIZ 100, 4 wt. hours after mixing, pour in the t imprint.

Remove the foam made according to this invention, has been tested and is recommended for industrial use on the prosthetic and orthopedic enterprise.

The method of producing foam MDI interaction with monofunctional alcohol and water in the presence of a catalyst, characterized in that in the interaction impose additional product oxypropylation of sucrose (mol. m 400 - 600 and the plasticizer in the amount of 20 to 80 wt.h. on 122,3 - 125 wt. including MDI when the mass ratio of the monofunctional alcohol and water 1 to 10 : 1.

 

 

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