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Composition for arrangement of bases of road pavements and other structures. RU patent 2520118. |
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IPC classes for russian patent Composition for arrangement of bases of road pavements and other structures. RU patent 2520118. (RU 2520118):
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FIELD: construction. SUBSTANCE: invention relates to construction and utilisation of wastes of heat engineering, and namely to reinforced ground compositions (soil cements), which can be used for construction of structures, including in structures of bases of road pavements of automobile roads; in an earth bed of automobile roads and other structures; for backfilling, elimination and recultivation of developed soil banks and slurry ponds; for reinforcement of sides of roads, slopes and cavities. Composition for arrangement of bases of road pavements and structures, which includes cement, slurry of chemical water treatment of CHP, and when necessary, for assurance of required humidity (optimum for compacting), it additionally contains sand at the following component ratio, wt % (by solid phase): sand 57-82, cement 6-12, CHP chemical water treatment slurry (on a dry basis) 12-30. The invention is developed in a subclaim of the formula. EFFECT: accelerating strength gain. 2 cl, 4 ex, 5 tbl
The invention relates to the construction and utilization of waste heat power engineering, namely to the strengthened earth materials (songs) with use of waste, which can be applied for construction of facilities, including: - in the construction of the bases of road pavement of motor roads; - in earthen cloth roads and other structures; - for filling, liquidation and reclamation developed underground quarries and sludge pits; - to strengthen the road sides, slopes, cut-outs. This composition is a result of recycling of sludge chemical water treatment plants (SCHWA) in artificial cured material by processing astringent and mixing with active fillers and additives. SHUO as large-tonnage waste industry, related to the 4th class of hazard (low-hazardous waste), translated into secondary raw material used in the preparation of fortified compositions for construction. Famous songs - fortified soils (GOST 23558-94. A mixture of crushed stone and gravel-sand and soil treated with inorganic binders for road and airfield construction. Technical conditions.) The disadvantage of these compositions is the high cost, due to the high expense knitting - Portland cement and others to provide the required strength of the material, as well as high demand in industrial mineral soils. To reduce material consumption can be applied additive production waste. Also known (RU, patent №2303011) building material "Burola", including drilling sludge, cement and urea-formaldehyde foam, and it contains drilling sludge density from 1.3 to 1.8 kg/DM 3 , urea formaldehyde foam density of 10-30 kg/m 3 in the amount of 10-25% of the volume of drilling sludge, cement in the amount of 10-20% of the volume of drilling cuttings and advanced mineral filler with particle size from 2.7 to 3.1 mm, selected from the group consisting of sand and crushed granite, in the amount of 10-20% of the volume of drilling cuttings. It also contains calcium chloride in the amount of 2.0% from the mass of drill cuttings. The possibility of using cuttings is limited by the availability of this waste at the sites of education (oil and gas field). This waste - drilling cuttings and urea-formaldehyde foam (penoizol) are toxic and ecologically dangerous. "Burola" does not provide the necessary hardness, uniformity, water and other operating qualities required for material reasons road pavement and other critical structures, i.e. "Burola" not suitable for the construction of structures. The closest to the present invention, a similar composition (RU 2101413, "Composition for the device of automobile roads and surface facilities"), including mineral material, astringent and alkaline activator with pH of not less than 11, wherein it contains as knitting dispersed industrial waste with a total content of Cao+MgO, not less than 35%, and as mineral material solochek from burning garbage in the following ratio of components, mass%: solochek from burning garbage 40-85, dispersed industrial waste with a total content of Cao+MgO, not less than 35% 15-60, alkaline activator with a pH of at least 11 of the mass of the solid components 2-20. This composition can optionally contain the water in the quantity of providing the desired workability. Composition contains as alkaline Energizer lime or cement in the amount of 2-5% of the mass of solids or at least a component of the group: waste water production of epoxy resins paint and coatings industry; waste water finishing production of textile factories; waste coke production, formed at the stage of regeneration in vacuum solutions of coke gas purification; waste oil cracking, formed at the stage of flue gas cleaning; alkaline effluent produced at the stage of recovery of chlorine gas by using NaOH in the processes associated with the use of liquid or gaseous chlorine; limy milk chemical water treatment plants or the TES or any other strongly alkaline liquid, pasty or dry waste product, or product manufactured with a pH value not less than 11 in number 2-20% of the mass of solid components. The disadvantage of this arrangement is extended for the duration of the term of a set of durability of the material (90 days or more). In this composition the cement and lime at a very low dosage (2-5%) play the role of adjuvants, and curing takes place due to high content in the mixture of ash and slag/slurry active components (up to 85%). This circumstance has played a negative role in the case of songs with such a regime set of brand strength (as a result of elastic characteristics) for road construction due to the required high rate of construction and installation works, dictated by technological regulations, and also by the necessity of putting the object (roads) in the shortest possible time (usually due to excessive load of the road network and the need fast track roads in operation). In this case, factors such as high intensity of traffic, load and speed of movement of vehicles on the section of road where the base supports constructive layer of the song, not collected the brand strength of will affect premature destruction of road construction in General. Maintaining a technological break after the device grounds for up to 90 days for curing is problematic. Flaws in the song are the complexity of the composition and the difficulty of implementation, as used in the waste - Sololaki must be at least 35% of the active lime - CaO+MgO, but in case of use of chemical water treatment sludge TPP and TPP in the composition will be present only gidrirovaniya, i.e. loose the activity lime. The use of a large number of other components and wastes in this composition determines the feasibility of the complexity of the implementation in practice, as well as additional environmental risks in the use of industrial wastes, which include: - from solochek burning of waste generated at waste incineration plants; - knitting - dispersed industrial waste with a total content of CaO+MgO, not less than 35%, for example sludge chemical water treatment plants or the TPP, - crushed waste slag ferrous metallurgy, etc., alkaline activator with a pH of at least 11, which can be represented lime or cement or any other strongly alkaline products industries or waste, such as lime milk chemical water treatment sludge thermal power plants, wastewater production of epoxy resins paint industry, sewage finishing textile factories, waste coke production, formed at the stage of regeneration in vacuum solutions of coke gas purification, waste cracking of oil produced at the stage of flue gas cleaning and many others. The chemical compounds used in similar agents and additives are complex, multiple options, difficulty of identification. The objective of the invention consists in the creation through recycling waste heat power engineering, namely sludge HVO CHP in composition with soil and astringent, solid monolithic and homogeneous material - composition, suitable for the device of the bases of road pavement and other structures in construction. The main technical result obtained in the implementation of the claimed invention consists in utilization of industrial waste sludge HVO and to increase the strength composite material under compression, on Flexural for the material, the production of which provides for the reduction of consumption of the basic expensive knitting - Portland cement, as well as reducing the consumption of conditioned ground and a corresponding reduction in the cost of material in comparison with standard cementownia GOST 23558-94. In comparison with the similar offer composition differs accelerated curing after laying in a constructive element, as well as less complex structure without the use of a large number of toxic components. The problem is solved what is the composition for the device of the bases of road pavement and buildings, including cement, chemical water treatment sludge CHP and, if necessary, water to ensure the required humidity (optimal for seals), characterized in that it additionally contains sand, in the following ratio of components, mass% solid phase: sand 57-82; cement 6-12, chemical water treatment sludge CHP (dry) 12-30. To improve the physical-mechanical properties of the material composition optionally contains Supplement polymer-mineral complex "Nicobloc" in the amount of up to 1% of the mass of dry components. Sludge systems of chemical water treatment of enterprises in the energy sector is mainly represented by carbonates of calcium and magnesium, sulfate and calcium hydroxide. In the composition of the sludge may be present and organic impurities. The size of particles of mineral slurries HVO are heterogeneous colloidal dispersion system, in which the solid phase are fine gypsum, hydroxide or calcium carbonate, and also soluble and partially soluble salts of calcium, potassium, sodium and metal hydroxides. calcium carbonate 40-80magnesium carbonate 10-30ferric sulfate and other components 10-30This chemical composition allows to use SHUO for manufacture of building materials and reinforced with cement of soils, in particular, as a placeholder and additives, partially replacing astringent, either as activators of hardening cement binder. Slime fractions play the role not only of a filler, but the active component of the system that have significant impact on the formation of the active centres of crystallization. The presence of fine and clay-colloidal phase is one of the conditions of application of SHWO in compositions, as the specific content of fine phases contributes to a more optimal particle size distribution of soil fraction compared to a net natural and hydraulic deposition of sand, characterized by odnorazovojj composition. Supplement certain limited (optimal) the number of SHUO allows you to get a mixture of optimal number of plasticity. The strengthening of such material cement gives the best indicators of durability, water resistance, crack resistance, frost resistance compared with conventional tillage clean sand, when a fortified soil has a high porosity, permeability, low strength and frost resistance. Dosage increase binder in the standard cementarna or similar causes growth of hard crystallization relations and along with increasing strength increases the fragility and decreases the deformation and fracture resistance of the material. The basic properties of samples of SHUO, selected on the sludge ponds Tyumen TPP-2 in table 1. Table 1The basic properties of samples of SHUO Indicators Sample # 1 Sample # 2 United test in liquid form in thickened form in liquid form in thickened form in liquid form in thickened form The volume of water/sediment, ml 100/900 - 970/30 - 520/480 -The cake moisture, % - 23,8 - 24,6 - 24,1Bulk density in a dry condition, kg/m 3 615 621 619Optimum humidity, % - 46,1 - 45,8 - 46,0Maximum density, g/cm 3 1,62 1,63 1,62Besides SHUO, the composition may contain and improving additive. As an active additives in the claimed composition is applied PMK "Nicobloc", reagent domestic production, Saint-Petersburg (TU 5743-003-13881083-2006 "Additive firming for cementitious mortars and dry mixtures "Nicobloc"). Polymer-mineral composition (PMC) on the basis of the holder of powders and mineral fillers "Nicobloc" is a composition consisting of a distinctly selected minerals on a given chemical composition and activation, and polymers consisting of molecules, called "comb". This modification of polymer is a macromolecule with a long side chains. Since large chains are made of molecules of several types, each of which begins at a certain time. These chains have a specific speed absorbtsii and hydration (phase formation), which provides the necessary duration of their action in the mixture. The chemical composition of PMK "Nicobloc" presents the following components: - activated silica - 40%, calcium salts - 15%, sodium - 15%, polymers on the basis of lignins - 30%. "Nicobloc" it is a powder of grey color, different shades, bulk density 800-1260 kg/m3 , humidity not more than 2%, the residue on a sieve №0315 not more than 1%. More detailed data are specified in THE 5743-003-13881083-2006. PMC provides very high persistence mix, slow down the setting and accelerate the curing immediately after laying and compaction. When using the PMC is the activation of moisture in the soil optimal humidity, which affect the overall energy balance of the entire system strengthening mixtures, which in turn leads to additional activation of cement and, consequently, to the increase of durability on compression at equal and reduced quantities of cement to reinforce the soil. Experimentally confirmed that at strengthening sandy soils tensile strength at compression of samples in the age of 28 days with the introduction of additive SHWE and PMK "Nicobloc" will increase 1.5-2 times in comparison with a control sample, the coefficient of frost resistance will increase to 0.9-0,95. Also "Nicobloc" applies to all types of soils, suitable for the strengthening of cement, while there are no restrictions on the acidity of the soil, the presence of sulphates, chlorides, gypsum. This polymer-mineral complex (TMC) reduces the expense of cement on 15-30%, respectively transportation costs and the cost of cement and soil composition. The advantages of the road pavements and the structural layer, including fortified composition with SHWE and PMK "Nicobloc", include: - more long-lasting smoothness, especially in intensive soil heave roadbed; - significant improvement humidity curing composition, as the addition of SHUO or SHWO in combination with PMK "Nicobloc" increases the water retention capacity of the mixture in the process of the initial set of durability up to 7, 14 and 28 days. Developed specific surface of particles compositions and the presence of clay-colloidal phase ensures the cohesion of water molecules and prevent evaporation of laid the structural layer and its involvement in the processes of hydration of cement binding material. This simplifies care of the fresh layer does not require daily watering and bottling of film-forming; - decrease by 15-45% of the demand for scarce mineral materials and 1,5-3 times the number of vehicles; - reduction of labor costs and reduce the cost of construction. In the claimed composition perhaps the use of cement. The basic variant binder is Portland cement, slag Portland cement and Portland cement with mineral additives on the state standard 10178. Use of aluminous cements according to GOST 969, as well as: - cement gipsovoloknistyh expanding GOST 11052; - backfill cements according to GOST 1581; - sulfate and pozzolanic cements according to GOST 22266; - cement for the construction of solutions by GOST 25328. The basic requirement is to apply cement with normal (the beginning shvatyvanija should happen not earlier than 2 hours after mixing) terms of setting and drying. Examples of specific applications The research of the chair "Automobile roads and aerodromes" Tomaso the possibility of the application of additive SHUO at strengthening of soils. In particular, the introduction of up to 12-30% waste - chemical water treatment sludge CHP raise durability and resistance composition of polluting components of waste during this contact in the structure of consolidated mass. We have investigated the influence of SHUO Tyumen TPP-2 and additives "Nicobloc" on physical-mechanical parameters of construction of composite material on the basis of alluvial Sands, binding materials and waste. In our experiments we used a small and dusty Sands (GOST 25100-95) from a pile of hydraulic career Andreevsky with natural moisture content of 4%to 6%; Portland cement M-400 suholozhskogo plant (GOST 10178-85) and sludge HVO (integrated test) from the drive Tyumen TPP-2. Example 1. For the experimental confirmation of the possibility and effectiveness of application of SHUO, and together SHWE and PMK "Nicobloc was tested 3 series compositions: I - control series cementownia GOST 23558-94 containing 12% from weight of cement sand; II - composition containing sand (70%), 20% SHUO (dry residue) and 10% of binder; III - composition containing sand (59%), 30% of SHUO (on the dry rest) 10% of binder and additive "Nicobloc" in the amount of 1%. Cooked with optimal humidity of compounds I-III formalise samples-cylinders 5 x 5 cm using a small instrument Souzdornii and hydraulic press. Then the part of freshly prepared samples were sent to the ecologo-Toxicological studies, the basic amount (not less than 24 pieces) were placed in a desiccator to set strength in the air-wet conditions. Testing of the samples was carried out after 14 and 28 days extracts, water saturation within 48 hours (the first 6 hours - dive 1/3, then completely) according to GOST 23558-94 and GOST 10180-90. Weighed before and after water saturation samples were tested for durability at compression on a hydraulic press. The main results of the experiment are given in table 2. Table 2The results of the tests compositions of cementownia the number of series Number of samples 14 days 28 days In, %R SG , MPa Dov. the interval. In, %R SG , MPa Dov. the interval. I control, GOST 23558 9+9 9,5 1,92 +/-0,19 7.4 3,21 +/-0,27II composition of SHUO 9+9 4,5 2,45 +/-0,24 3,3 4,03 +/-0,34III composition with "Nikilika" 9+9 4,0 2,98 +/-0,21 2,9 4,82 +/-0,20Note: In - water absorption by weight; CSH - compressive strength. Thus, at identical quantity of binder, the strength of the composition (14 days) with SHUO significantly increased by 28%. Water absorption is reduced more than in 2 times, to III songs in a joint application of SHWE and Nikilika" strength is increased by 38%, water absorption is reduced by 2.6 times. These results confirm the efficiency of agent use (utilization) of SHWE and PMK "Nicobloc" when cooking fortified compositions for construction. These data indicate improvement of technical and economic indicators of the application of reinforced soil structures in garments of roads and industrial areas. Testing of standard 28 daily samples helped to determine the make of the proposed compositions with the use of SHWE and Nikilika" correspondingly the requirements to the materials by GOST 23558-94: I series - M 20 (3,21 MPa); II and III series - M 40 (4,03 and 4,82 MPa, respectively). Example 2. For further experimental determination of rational doses of SHUO, sand, cement and PMK "Nicobloc was tested 5 series compositions: I - composition containing sand (76%), 12% of SHUO (dry residue) and 12% of Portland cement; II - composition containing sand (75,7%), 12% of SHUO (on the dry rest), 12% of Portland cement and 0.3% PMK "Nicobloc"; III - composition containing sand (75,4%), 12% of SHUO (on the dry rest), 12% of Portland cement and 0.6% PMK "Nicobloc"; Table 3The results of the tests compositions of cementownia (example 2) the number of series Number of samples 14 days 28 days In, %R SG , MPa Dov. the interval. In, %R SG , MPa Dov. the interval. I 9+9 4,3 2,14 +/-0,18 4,1 3,90 +/-0,19 II 9+9 4,2 2,39 +/-0,22 3,6 4,12 +/-0,25 III 9+9 3,9 2,74 +/-0,21 2,9 4,28 +/-0,26 IV 9+9 3,2 3,06 +/-0,28 2,4 5,06 +/-0,17 V 9+9 3,2 a 3.87 +/-0,24 2,3 5,14 +/-0,29Testing of standard 28 daily samples helped to determine the make of the proposed compositions with the use of SHWE and Nikilika" correspondingly the requirements to the materials by GOST 23558-94: I series - M 20 (3,90 MPa); (II, III, IV, V series, M 40 (4,12, 4,28, 5,06 and 5,14 MPa, respectively). Rational dosage PMK - 0,6-1%, with no less effect, and most impractical for technical and economic reasons, as the strength growth slows down, and the cost increases. Example 3. Further, we investigated the following 2 series of compositions: I - composition containing sand (58%), 30% of SHUO (dry residue) and 12% of Portland cement; II - composition containing sand (57%), 30% of SHUO (on the dry rest), 12% of Portland cement and 1% PMK "Nicobloc". The main results of the experiment are given in table 4. Table 4The results of the tests compositions of cementownia (example 3) No.Number of samples 14 days 28 days B, %R SG , MPa DOV. the interval. In, %R SG , MPa DOV. the interval. I 9+9 3,9 2,73 +/-0,19 3,7with 4.64 +/-0,26 II 9+9 3,7 3,39 +/-0,29 3,2 6,47 +/-0,22Testing of standard 28 daily samples helped to determine the make of the proposed compositions with the use of SHWE and Nikilika" correspondingly the requirements to the materials by GOST 23558-94: I series - M 40 (With 4.64 MPa); II series - 60 M (6,47 MPa). Example 4. Further, we investigated the following 2 series of compositions: I - composition containing sand (82%), 12% of SHUO (dry residue) and 6% of Portland cement; II - composition containing sand (81%), 12% of SHUO (on the dry rest), 6% of Portland cement and 1% PMK "Nicobloc". The main results of the experiment are given in table 5. Table 5 - the results of the tests compositions of cementownia (example 4) the number of series Number of samples 14 days 28 days In, %R SG , MPa Dov. the interval. In,%R SG , MPa Dov. the interval. I 9+9 3,8 3,41 +/-0,18 3,4 3,70 +/-0,21 II 9+9 3,5 3,66 +/-0,30 2,6 4,93 +/-0,18Testing of standard 28 daily samples helped to determine the make of the proposed compositions with the use of SHWE and Nikilika" correspondingly the requirements to the materials by GOST 23558-94: I series - M 20 (3,70MPa); II series - M 40 (4,93 MPa). Amount of added water for optimum humidity mixtures, providing maximum density depends on the type and moisture content of the soil and the content and humidity, SHWE and varies between 0-19% by weight of dry components. The value of the optimal humidity for the specific of the compositions is determined in accordance with GOST 22733-2002. When the total moisture content is lower than the optimal humidity in the mixture is introduced the necessary amount of water. During the experiment were found to be optimal limits of doses of SHWO in the composition, namely 12-30% (dry). At a dose of the sludge in the amount of less than 12% not significant efficiency of utilization of the waste industry, and its Supplement of 30% or more practically does not entail increase strength composite material. Preparation of the composition in a production environment provides traditional methods of cooking earth mixtures, processed mineral knitting (in accordance with the regulations on technology for pavement construction and strengthening of soils). The main method is the mixture in the installation with the subsequent laying of the "in thing", compaction and care base. With the implementation of these compounds obtained materials with compression strength 3-6 MPa, suitable for construction of bearing grounds road pavement and other structures. The implementation of the composition is possible without using a PMC "Nicobloc", this ensures recycling of SHUO and the required strength of the composition. Additional introduction of the additive PMK "Nicobloc" (0,6-1%) provides improved physical-mechanical indicators and reducing the need mainly knitting - cement. The stated intervals of doses of the components in the composition allow, disposing of large-tonnage waste heat power - SHUO CHP, get monolithic dense, homogeneous and durable composite material corresponding to building norms and technical requirements. The quality of the songs is enhanced when combined with SHUO the introduction of supplements - PMK "Nicobloc". In this composition the required strength is provided at reduced in comparison with the similar list of additives, waste and chemicals, which reduces environmental risks. 1. A composition for the device of the bases of road pavement and buildings, including cement, chemical water treatment sludge CHP and, if necessary, water to ensure the required humidity (optimal for seals), characterized in that it additionally contains sand, in the following ratio of components, mass% solid phase: sand 57-82; cement 6-12, chemical water treatment sludge CHP (dry) 12-30. 2. The composition according to claim 1, characterized in that it additionally contains an additive PMK "Nicobloc" in the amount of up to 1% of the mass of dry components.
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