Triethanolamine perchlorato (triflato)metal inner-complex coordination polymers as additives for synthetic polymers

IPC classes for russian patent Triethanolamine perchlorato (triflato)metal inner-complex coordination polymers as additives for synthetic polymers (RU 2398793):

C08L27/06 - Homopolymers or copolymers of vinyl chloride

C08L27/04 - containing chlorine atoms

C08K5/16 - Nitrogen-containing compounds

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FIELD: chemistry.

SUBSTANCE: invention discloses at least one triethanolamine perchlorato (triflato) metal inner-complex coordination polymer with monomer links of formula A system of stabilisers can also contain substituted cyanacetyl carbamides, 6-aminouracyls, 3-aminocrotonic acid esters, hydantoins, monomer or polymer dihydropyridines, hydroxides of alkali-earth metals, hydrotalcite, dawsonites, zeolites, glycidyl compounds, cyanamides, cyanguanidines and/or melamines, repectively. Phosphites and/or sterically hindered amines and/or NOR-HALS compounds can also be present, where Mt denotes lithium, sodium, potassium/magnesium, calcium, strontium, barium and zinc, An denotes OClO₃ or OS(O₂)CF₃ and q equals 1 or 2. The invention also relates to a composition for making films containing polyvinylchloride and the said system of stabilisers.

EFFECT: improved operating characteristics of the films.

12 cl, 14 tbl

The text descriptions are given in facsimile form.

1. The system stabilizers for synthetic polymers, with the holding of the coordination polymer chelate compound three-atenololpercocet(triflate)metal with Monomeric units of the formula (A)

in which
Mt means lithium, sodium, potassium, magnesium, calcium, strontium, barium and zinc,
'an means lO₃or OS(O₂CF₃and
q is 1 or 2.

2. The system stabilizers according to claim 1, characterized in that it further comprises linear and cyclic wreid selected from the group comprising substituted cancerigenic, substituted aminosalicilovu acid, substituted aminouracil, as, and/or an ester of 3-amino-crotonic acid and/or ester dihydropyrimidinase acid of formula (B-1), (2), (s-1) and (2):
and
and

and
,
in which
X denotes oxygen or sulfur,
Y represents CH₂CN,
Z denotes hydrogen, or
Y and Z form a bridge element of CH₂-C=NH, CR⁵=C-other⁶or R¹R²C, R¹, R²independently of one another denote hydrogen, alkyl with 1-22 carbon atoms, cyclohexyl, (meth)allyl, oleyl, phenyl, benzyl, phenylethyl, (tetrahydro)naphthyl, meth(or EB)oksipropil-(or ethyl), CH₂-CHOH-R^1aCH₂-CHOH-CH₂X R^1a,
X' represents oxygen or sulfur,
R^1adenotes hydrogen, alkyl with 1-22 carbon atoms, cyclohexyl, (meth)allyl, oleyl, phenyl, benzyl, phenylethyl, (tetrahydro)-naphthyl or IU is(or EB)oksipropil(or ethyl),
R³denotes unbranched or branched alkylene with 2-20 carbon atoms which may be interrupted by 1 to 4 atoms of oxygen or sulfur or/and substituted 1-4 hydroxyl groups, or dimethylcyclohexane-1,4-diyl, polyethylene(or propylene)glycol-α,ω-diyl ("poly" means preferably from "Tetra" to "DECA"), polyglyceryl-α,ω-diyl ("poly" means preferably from "Tetra" to "DECA") or glycerine, trimethylated(or propane)trial, PENTAERYTHRITE(or Tetra)Il bestemmelser(or propane)three(or Tetra)Il, diglyceride(or Tetra)Il, tetrahedral, triglyceride(or Tetra -, Penta)Il, penitential, dipentaerythritol(or hexa)silt and exitexit,
n represents 2, 3, 4, 5 or 6,
R⁵means hydrogen or (alkylidene)_1/2with 3-10 carbon atoms which may be interrupted by one or two oxygen atoms or may contain up to two substituents, independently selected from each other from the group comprising hydroxyl, phenyl and hydroxyphenyl,
R⁶means hydrogen, hydroxyalkyl with 2-4 carbon atoms, 3-alkoxy-2-hydroxypropyl with 1-10 carbon atoms in the alkoxy or substituted by 1-3 hydroxyl groups, phenyl, substituted by 1-3 alkyl groups with 1-4 carbon atoms in each phenyl or substituted by 1-3 alkoxygroup with 1-4 carbon atoms in each phenyl, allyl, phenyl with 1-3 substituents,
Rsup> 7, R^7'independently from each other mean a branched or unbranched alkyl with 1 to 4 carbon atoms, phenyl, cyclohexyl,
W means CO₂CH₃, CO₂With₂H₅, CO₂n-C₁₂H₂₅or CO₂C₂H₄-S-n-C₁₂H₂₅,
L, T denote unsubstituted alkyl with 1-12 carbon atoms,
m and n denote integers from 0 to 20, K is 0 or 1, and
R and R' independently of one another denote ethylene, propylene, butylene or alkyltrimethylenedi or cycloalkylcarbonyl group of type -(C_pH_2p-X-)_tC_pH_2p-, in which p denotes an integer from 2 to 8, t stands for an integer from 0 to 10 and X represents oxygen or sulphur.

3. The system stabilizers according to claim 1 or 2, characterized in that it further introduced the oxide or hydroxide of magnesium or calcium and/or magnesium or calcium soap and/or calcium/zinc stabilizer and/or optionally containing lithium or titanium hydrotalcite and/or davsonit and/or sodium zeolite a and/or hydroxyaromatic calcium-aluminum and/or goldirova connection and/or epoxydecane ester of fatty acid and/or melamine and/or ester of phosphorous acid and/or 2-naphthol and/or cyanamide of the formula (E)
,
in which
each R⁴independently of one another denotes hydrogen, nitri is, carbarnoyl,
R¹, R², R¹CO., R²CO., sodium, potassium, Mg_1/2and Ca_1/2or
(R⁴)₂means tetramethylene, pentamethylene or hexamethylene, and
means 1, 2 or 3.

4. The system stabilizers according to claim 1, characterized in that it added sterically hindered amine (HALS) and/or antioxidant and/or UV absorber (a derivative benzotriazole) and/or titanium dioxide and/or chalk.

5. The system stabilizers according to claim 4, characterized in that the sterically hindered amine (HALS) is a combination of NOR-HALS.

6. The system stabilizers according to claim 5, characterized in that the connection NOR-HALS is a compound based on triazine.

7. The system stabilizers according to claim 1 or 2, characterized in that it additionally contains a simple and/or ester of glycerol R⁸Och₂CH(OH)CH₂HE or R⁸CO₂CH₂CH(OH)CH₂OH and/or derived diethylaniline R⁹-[C(O)]_d-N(C₂H₄OH)₂or R⁸OCH₂CH(OH)CH₂-[C(O)]_d-N(C₂H₄OH)₂or R⁹-N(OH)(CH₂)₂(CH₂)₃-[C(O)]_d-N(C₂H₄OH)₂and/or parafinalia (or sulfonate)salt alkyl-(O)_d'-SO₃Na, Li, K with 12-18 carbon atoms in the alkyl and/or polyoxyalkylene formula (F)

each R⁸independently denotes hydrogen, alkyl with 1-2 carbon atoms, alkenyl with 2-24 carbon atoms, CH₂=CH-C(O) or CH₂=CLO₃-C(O), each R⁹independently mean alkyl with 1 to 24 carbon atoms, alkenyl with 2-24 carbon atoms, (CH₂)₂HE, CH₂-COOH or N(alkyl)₃Hal with 1-8 carbon atoms in the alkyl,
R¹⁰means hydrogen or CH₃,
Hal means chlorine, bromine or iodine,
a represents an integer from 2 to 20
b denotes an integer from 1 to 6, and
C, d, d', d" independently of one another denote 0 or 1.

8. Composition to obtain a film containing polyvinyl chloride and system stabilizers according to one of claims 1 to 7.

9. The composition according to claim 8, characterized in that it contains the polyvinyl chloride in the form of unplasticized, plasticized, suspension or emulsion PVC.

10. The composition of claim 8 or 9, characterized in that it contains from 0.001 to 1.0 parts by weight of chelate compounds (A) 100 parts by weight of polyvinyl chloride.

11. The composition of claim 8 or 9, characterized in that it contains from 0.01 to 10 parts by weight of sterically constrained amine and/or connection NOR-HALS and/or UV absorber and/or titanium dioxide.

12. The composition of claim 8 or 9, characterized in that the polyvinyl chloride contains plasticized PVC, and the system stabilizers contains simple 1,4-cyclohexyldimethylamine ether.