|
RussianPatents.com
|
Method to decrease density of nitrate in products with the help of a gasifying agent. RU patent 2245844. |
|
|
FIELD: chemical and petrochemical industries. SUBSTANCE: the invention is dealt with a method to decrease of a density of ammonium nitrate in products. The method includes production of a gasifying agent in the form of a water-insoluble solid carbonaceous compound capable to help evolution of a gas at a chemical reaction, and production of a product out of ammonium nitrate. The water-insoluble solid substance having the average diameter of particles of no less than 40 micron is introduced in the ammonium nitrate product having the acid. At that the value of pH is between 2 and 5. At production of granules (pellets) from the ammonium nitrate product a granular product of an ammonium nitrate with the lowered density is formed. The invention also is dealt with granular products out of ammonium nitrate produced by this method and an explosive composition a containing a granular product out of the ammonium nitrate produced by this method. The offered method ensures an increase of volume of self-contained pores and accordingly a decrease of the volumetric bulk density. EFFECT: the invention ensures an increase of volume of self-contained pores and accordingly a decrease of the volumetric bulk density. 20 cl, 2 ex, 2 tbl
|
|
| Water-containing gunpowder explosive composition / 2243957 Invention relates to manufacture and application of industrial water-containing explosives based on gunpowder-sensitized gel-like oxidant solutions. Invention provides composition containing granulated pyroxylin gunpowder or mixture thereof with ground pyroxylin and/or ballistite artillery powders, or ballistite rocket powders; water-soluble metal nitrates or their mixture; organic fuel; polyacrylamide (thickener); aluminum sulfate (cross-linking agent); water; and ammonium nitrate. |
| Method to decrease density of nitrate in products with the help of a gasifying agent / 2245844 The invention is dealt with a method to decrease of a density of ammonium nitrate in products. The method includes production of a gasifying agent in the form of a water-insoluble solid carbonaceous compound capable to help evolution of a gas at a chemical reaction, and production of a product out of ammonium nitrate. The water-insoluble solid substance having the average diameter of particles of no less than 40 micron is introduced in the ammonium nitrate product having the acid. At that the value of pH is between 2 and 5. At production of granules (pellets) from the ammonium nitrate product a granular product of an ammonium nitrate with the lowered density is formed. The invention also is dealt with granular products out of ammonium nitrate produced by this method and an explosive composition a containing a granular product out of the ammonium nitrate produced by this method. The offered method ensures an increase of volume of self-contained pores and accordingly a decrease of the volumetric bulk density. |
Method of production of ammonium nitrate and a device for its realization / 2259319The invention is pertaining to the field of chemical industry, in particular, to processes of production of alkali liquors of ammonium nitrate. The method of production of ammonium nitrate includes neutralization of nitric acid by gaseous ammonia under an atmospheric pressure at the temperature of 130-140°C with an evaporation of the solution due to the heat of neutralization. The neutralization of the nitric acid is conducted in a stream with a solution of the ammonium nitrate by internal forced circulations with a parallel evaporation of the solution. The solution evaporation is conducted at rarefaction of 0.003-0.004 MPa. The device for production of the ammonium nitrate contains a cylindrical body with the bottom and unions for the solution withdrawal, gauging of its level and a pressure, a cover with an union for withdrawal of the juice vapor. Inside the body at some distance from the bottom the neutralization unit is mounted. It contains two concentrically mounted cylinders communicating with each other through two rows of holes located in the internal cylinder below at the bottom of the outer cylinder and above at the attachment flange of the internal cylinder. Above in the internal cylinder there is a tubular reactor made in the form of an ejector with unions for delivery of the nitric acid and the gaseous ammonia, the body of which is supplied with holes for the solution entry in the mixing chamber of the reactor; a separating funnel which is mounted without a backlash to the lower flange coupling and is fixed in the internal cylinder; and an assembly of an evaporation of the solution, containing two blind plates with the overflow edges installed one above another between the body of the device and the external cylinder of the neutralization assembly in such a manner, that the overflow edge of the upper plate is placed near to the body of the device and at the level of the axes of the upper holes in the internal cylinder of the assembly of neutralization, and the overflow edge of the lower plate - near to the external cylinder of the assembly of neutralization. At that the cylinders of the neutralization assembly inside and outside are supplied with longitudinal ribs. The technical result: the method of production of ammonium nitrate and the design of the device for its realization allow to conduct the process of the neutralization of the nitric acid by the gaseous ammonia with formation of alkali liquor of the ammonium nitrate in a safe mode, as the process is conducted without a pressure with a forced circulation of the solution of an ammonium nitrate due to a kinetic energy of gaseous ammonia, which is fed in the reactor and due to provision of a reliable heat-exchange between the circulating and evaporating alkali liquors, and also allows to reduce metal consumption and to simplify the layout of the equipment. |
Method of production of porous granulated ammonium nitrate / 2261226The invention is pertaining to the field of chemical industry, in particular, to the methods of production of the inorganic substances used in production of explosives, namely, to production of porous granulated ammonium nitrate used in production of the elementary explosives and emulsion explosives. The offered method of production of the porous granular ammonium nitrate provides for production of a solution of ammonium nitrate, injection in the produced solution of ammonium nitrate in terms of CaO in the end product of 0.5-3 mass % of calcium nitrate in the form of 40-70 % water solution, evaporation of the ammonium nitrate solution with production of a fusion cake, injection of a powder-shaped additive and a UF dispersant with the a subsequent granulation of the fusion cake. In the capacity of pore-forming additives use a high concentration solution containing potassium carbonates and-or sodium carbonates, and-or ammonium carbonates in a ratio of carbonate salts in terms of CO2 in respect to H2 O, equal to (0.06-0.9) : 1, in amount of 0.01-0.045 mass % in terms of CO2 in the fusion cake. The invention is intended for development of a method of production of a porous granulated ammonium nitrate with a capability to control oil absorption and strength of granules, which is stabilized against undesirable modification transformations and possesses the heightened thermostability. |
Method for preparing porous granulated ammonium nitrate / 2261842Invention relates to manufacturing explosive materials, namely, to manufacturing porous granulated ammonium nitrate used in manufacturing the simplest explosive substances and emulsion explosive substances. Invention proposes a method for preparing porous granulated ammonium nitrate involves preparing ammonium nitrate solution, addition of stabilizing additive consisting of magnesium and/or calcium nitrate to solution up to the concentration 2 wt.-% as measured for anhydrous product followed by evaporation of ammonium nitrate solution to obtain melt and addition pore-forming addition and disperser NS to it and the following granulation of product. Highly concentrated ammonium carbonate solution in ammonium nitrate is used as pore-forming additive in the amount 0.05-0.35 wt.-%, or mixture of carbamide with highly concentrated ammonium carbonate in ammonium nitrate in the amount 0.1-0.55 wt.-%. Pore-forming additive is mixed with disperser NS in melt or before their addition in melt. Invention provides the development of a method for preparing porous granulated ammonium nitrate of reduced caking and possibility for regulation of oil absorption and filled density. |
Porous ammonium nitrate for production of blasting explosives and a method of its production / 2265002The invention is pertaining to the field of making of special kinds of raw and processing methods of its production for making blasting explosives of a mix type. The invention offers a porous granulated ammonium nitrate for making the mix blasting explosives, which contains an additive modifying the space lattice of ammonium nitrate, the pores forming additives and the surface-active substance distributed on the bodies of the granules and also the conditioning seasoning additives on the surface of the granules. As the modifying additive it contains ferrous sulfite (III) and magnesium, calcium, potassium and sodium nitrates at the particular content of ions: Mg+2, Ca+2, Na+1, K+1, Fe+3, SO3 -2. And also the invention offers a method of production of the porous granulated ammonium nitrate. The technical result of the invention is production of the porous granulated ammonium nitrate with the developed homogeneous porosity space along the body and the surface of the granules, that allows to manufacture the stable explosive mixtures with the balanced contents of an oxidizing agent and a liquid oil product. |
| Ammonium nitrate phase stabilization method / 2298540 Invention relates to preparation of ammonium nitrate with structure resistant to temperature changes and provides an ammonium nitrate phase stabilization method involving addition of organic stabilizer selected from group of nitrogen-containing heterocycles with imine and carbonyl groups, which stabilizer is added to ammonium nitrate in amounts ranging from 4 to 34 wt %. Thus obtained combination is mixed and resulting mixture is ground into powder or heated to 130-160°C at stirring and cooled. Ammonium nitrate obtained by this method is resistant to repetitive changes in temperature within a range from -50 to +100°C, which allows it to be utilized, in particular, in gas-generation compositions for inflators in automobile safety bags. |
Methods for preparing water-resistant ammonium nitrate for manufacturing explosives / 2318726Invention is directed to creation of special types of starting material and its production technology for manufacturing explosives. Three variants of water-resistant ammonium nitrate preparation method are proposed. Method according to variant 1 comprises treatment of ammonium nitrate granules with mineral-organic emulsion consisting of (i) mineral phase, which contains iron alum and is obtained from ammonium nitrate, ferric sulfate solution, and sodium hydroxide solution; (ii) organic phase containing solid paraffin and natural stearin; and (iii) emulsion stabilizer, followed by drying and grinding. Method according to variant 2 comprises treatment of ammonium nitrate granules with iron alum solution obtained from ferric sulfate, ammonium nitrate, and sodium hydroxide and having pH 1.5 to 2.5, followed by drying, treatment of granules with organic waterproofing agent containing solid paraffin and natural stearin, subsequent drying and grinding. Method according to variant 3 comprises treatment of ammonium nitrate granules with mineral-organic mixture containing iron alum and obtained by mixing ammonium nitrate, ferric sulfate solution, sodium hydroxide solution, solid paraffin, and natural stearin followed by drying and grinding. |
| Method of colouring ammonium nitrate for technological purposes / 2353581 Invention relates to the method of colouring ammonium nitrate for technological purposes, used for making explosive materials, particularly, for the production of high-density and porous ammonium nitrate with a characteristic distinctive colouring of the granules. It can be used in the manufacture of ammonium nitrate, for making emulsion and basic explosives. Method of colouring ammonium nitrate for technological purposes lies in the fact, that granulation of molten ammonium nitrate is granulated in the presence of organic dyes, taken in the quantity 10-100 mg to 1 kg of the finished product. Dye is put into the molten ammonium nitrate directly before granulating into the composition of pore-forming agent or surfactant or in the form of an aqueous solution or suspension. Dyes which do not lose colour in molten ammonium nitrate at a temperature of 190°C are used as colouring agents. |
| Granulated or powdery crystalline product for production of industrial explosive substances / 2354635 Crystalline ammonium nitrate is proposed in granulated or powdery type for production of explosive substances. It has microstructure with size of unit domains from 20 to 120 nm and even density of dislocations distribution, at that density of dislocations distribution (P, cm) is determined according to the formula P=3/D3, where D is size of unit domains. Granules may be arranged as solid or porous. |
Method of water-resistant ammonium saltpeter preparation / 2355635Invention refers to chemical industry and can be used in the manufacture of the slow-release mineral fertilisers and water-resistant explosives on the base of ammonium saltpetre. The method of water-resistant ammonium saltpeter preparation consists in treatment of ammonium saltpeter with water repellent. The gel-like mixtures of mineral acids or its salts with liquid glass with mass ratio acid or salt to liquid glass equal 1:5-40 are used as water repellent. The treatment is carried out at mechanical stirring of the ammonium saltpeter and water repellent with its mass ratio equal 1 : 0.05 - 0.1 during the time enough for full granula coating but not less than 10 min with following dehumidification preferably not less than during 20 min at the temperature providing the stability of the gel, preferably not lower than 20°C. |
| Water-containing gunpowder explosive composition / 2243957 Invention relates to manufacture and application of industrial water-containing explosives based on gunpowder-sensitized gel-like oxidant solutions. Invention provides composition containing granulated pyroxylin gunpowder or mixture thereof with ground pyroxylin and/or ballistite artillery powders, or ballistite rocket powders; water-soluble metal nitrates or their mixture; organic fuel; polyacrylamide (thickener); aluminum sulfate (cross-linking agent); water; and ammonium nitrate. |
| Method to decrease density of nitrate in products with the help of a gasifying agent / 2245844 The invention is dealt with a method to decrease of a density of ammonium nitrate in products. The method includes production of a gasifying agent in the form of a water-insoluble solid carbonaceous compound capable to help evolution of a gas at a chemical reaction, and production of a product out of ammonium nitrate. The water-insoluble solid substance having the average diameter of particles of no less than 40 micron is introduced in the ammonium nitrate product having the acid. At that the value of pH is between 2 and 5. At production of granules (pellets) from the ammonium nitrate product a granular product of an ammonium nitrate with the lowered density is formed. The invention also is dealt with granular products out of ammonium nitrate produced by this method and an explosive composition a containing a granular product out of the ammonium nitrate produced by this method. The offered method ensures an increase of volume of self-contained pores and accordingly a decrease of the volumetric bulk density. |
Water-containing frost-resistant environmentally safe explosive / 2246473Invention relates to creation of safe water-gel industrial explosives for blasting operations in mining industry reusing overdue individual explosives, gunpowders, fuels, and their components. Claimed explosive contains ammonium nitrate, cryogenic additive, thickener, structure-forming agents, water, and a complex system: explosive sensitizer with chemical absorbent of halogen-containing toxic gases resulting from explosive conversion. |
Composition of emulsion explosive / 2252926The invention is pertaining to the field of shooting operations, in particular, to production of emulsion explosive substances (EES), which may be used on the earth surface with a manual and mechanized charging of the dry and encroached wells in hard, average, soft rocks and coals. The offered EES contains an emulsion of poremite, granulated ammonium nitrate, liquid oil products and a gas-generating additive. The EES may contain a porous granulated ammonium nitrate. The purpose of the invention is creation of an ecologically safe and safe in handling EES with explosive performances equal to a trinitrotoluol-containing blasting explosives. |
| Composition of emulsion blasting explosive / 2252927 The invention is pertaining to the field of mining shot firing operations, in particular, to the emulsion blasting explosives (EBE), which may be used on the earth surface with a manual or a mechanized charging of the dry boreholes in the hard, medium, weak rocks and coal. The offered EBE contains an emulsion of poremit, a granular ammonium nitrate and liquid oil products. The porous granular ammonium nitrate may be used in the given EBE. The purpose of the invention is development of a loose EBE, its safe production, transportation and use, that ensures a possibility of its delivery to the place of an explosion and charging of the boreholes by specialized machines for transportation of the explosives in the transportable loading pockets. |
Composition of emulsion blasting explosive / 2252928The invention is pertaining to the field of mining shot firing operations and may be used on the earth surface and in open cast mines, ore mines and coal pits, which are not gas- or dust-hazardous, using a manual and mechanical charging of the boreholes and blast-holes in the hard, medium, weak rocks and coal. The composition of the offered emulsion blasting explosive (EBE) contains a granular ammonium nitrate, oil products, an emulsion of poremit and powdered ferrosilicon. The porous granular ammonium nitrate may be used in the composition of the emulsion blasting explosive. The purpose of the invention is development of EBE safe for environment, safe at handling, transportation and storage. |
| Method of manufacturing charges of gel-like hydrogen-containing explosive composition / 2253642 Invention relates to hydrogen-containing industrial blasting substances based on gel-like matrix. Manufacture of charge of explosive composition comprises preparing aqueous solution of oxidants, adding polyacrylamide to form gelated solution of oxidants, adding structure-forming agent, adding sensitizer, filling envelop, and structuring charge. Structure-forming agent is constituted by two components, interaction of which with each other leads to formation trivalent ion functioning as structure-forming agent. One of the two components is added to aqueous solution of oxidants or to gelated solution of oxidants and the other component to gelated solution of oxidants before or during addition if sensitizer. Structuring of charge is performed at 20 to 90°C. |
Method to upgrade igdanit physical properties / 2257368The invention is pertaining to the field of mining, in particular, to industrial production of igdanit explosives and may be used at mining minerals on the ground and in mines not dangerous on the side of gas and dust. The invention presents a method of production of an industrial explosive composition of igdanit containing a diesel fuel and providing for an injection into the diesel fuel of an additive to upgrade its physical stability. In the capacity of the additive to upgrade its physical stability the invention offers to use organobentonite in amount of 4-5 % of the mass of the diesel fuel. The invention allows to upgrade the physical stability of igdanit composition. |
| Water-in-oil-type emulsion explosive composition / 2258055 Proposed water-in-oil-type explosive composition contains ammonium nitrate, mineral oil, water, and emulsifier. The latter is prepared by mixing poly(isobutylenesuccinic anhydride) or poly(isobutylene-bis-succinic anhydride) with product of its interaction with organic mono- or polyamine, adding, to continuously stirred mixture, esters of fatty acids with polyatomic alcohols, then adding Ca, K, Mg, Mo alkylbenzenesulfonate or mixture thereof in the form of 20-70% solution in industrial oil, mixing, and filtering resulting mixture. |
Method of production of porous granulated ammonium nitrate / 2261226The invention is pertaining to the field of chemical industry, in particular, to the methods of production of the inorganic substances used in production of explosives, namely, to production of porous granulated ammonium nitrate used in production of the elementary explosives and emulsion explosives. The offered method of production of the porous granular ammonium nitrate provides for production of a solution of ammonium nitrate, injection in the produced solution of ammonium nitrate in terms of CaO in the end product of 0.5-3 mass % of calcium nitrate in the form of 40-70 % water solution, evaporation of the ammonium nitrate solution with production of a fusion cake, injection of a powder-shaped additive and a UF dispersant with the a subsequent granulation of the fusion cake. In the capacity of pore-forming additives use a high concentration solution containing potassium carbonates and-or sodium carbonates, and-or ammonium carbonates in a ratio of carbonate salts in terms of CO2 in respect to H2 O, equal to (0.06-0.9) : 1, in amount of 0.01-0.045 mass % in terms of CO2 in the fusion cake. The invention is intended for development of a method of production of a porous granulated ammonium nitrate with a capability to control oil absorption and strength of granules, which is stabilized against undesirable modification transformations and possesses the heightened thermostability. |
| © 2013-2014 Russian business network RussianPatents.com - Special Russian commercial information project for world wide. Foreign filing in English. |