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RussianPatents.com
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Method of production of porous granulated ammonium nitrate. RU patent 2261226. |
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FIELD: chemical industry; to the methods of production of the porous granulated ammonium nitrate. SUBSTANCE: the invention is pertaining to the field of chemical industry, in particular, to the methods of production of the inorganic substances used in production of explosives, namely, to production of porous granulated ammonium nitrate used in production of the elementary explosives and emulsion explosives. The offered method of production of the porous granular ammonium nitrate provides for production of a solution of ammonium nitrate, injection in the produced solution of ammonium nitrate in terms of CaO in the end product of 0.5-3 mass % of calcium nitrate in the form of 40-70 % water solution, evaporation of the ammonium nitrate solution with production of a fusion cake, injection of a powder-shaped additive and a UF dispersant with the a subsequent granulation of the fusion cake. In the capacity of pore-forming additives use a high concentration solution containing potassium carbonates and-or sodium carbonates, and-or ammonium carbonates in a ratio of carbonate salts in terms of CO2 in respect to H2 O, equal to (0.06-0.9) : 1, in amount of 0.01-0.045 mass % in terms of CO2 in the fusion cake. The invention is intended for development of a method of production of a porous granulated ammonium nitrate with a capability to control oil absorption and strength of granules, which is stabilized against undesirable modification transformations and possesses the heightened thermostability. EFFECT: the invention ensures production of a porous granulated ammonium nitrate with heightened thermostability and capability to control granules oil absorption and strength, resistance against undesirable modifying transformations. 3 cl, 1 ex
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| Water-in-oil-type emulsion explosive composition / 2258055 Proposed water-in-oil-type explosive composition contains ammonium nitrate, mineral oil, water, and emulsifier. The latter is prepared by mixing poly(isobutylenesuccinic anhydride) or poly(isobutylene-bis-succinic anhydride) with product of its interaction with organic mono- or polyamine, adding, to continuously stirred mixture, esters of fatty acids with polyatomic alcohols, then adding Ca, K, Mg, Mo alkylbenzenesulfonate or mixture thereof in the form of 20-70% solution in industrial oil, mixing, and filtering resulting mixture. |
Method to upgrade igdanit physical properties / 2257368The invention is pertaining to the field of mining, in particular, to industrial production of igdanit explosives and may be used at mining minerals on the ground and in mines not dangerous on the side of gas and dust. The invention presents a method of production of an industrial explosive composition of igdanit containing a diesel fuel and providing for an injection into the diesel fuel of an additive to upgrade its physical stability. In the capacity of the additive to upgrade its physical stability the invention offers to use organobentonite in amount of 4-5 % of the mass of the diesel fuel. The invention allows to upgrade the physical stability of igdanit composition. |
| Method of manufacturing charges of gel-like hydrogen-containing explosive composition / 2253642 Invention relates to hydrogen-containing industrial blasting substances based on gel-like matrix. Manufacture of charge of explosive composition comprises preparing aqueous solution of oxidants, adding polyacrylamide to form gelated solution of oxidants, adding structure-forming agent, adding sensitizer, filling envelop, and structuring charge. Structure-forming agent is constituted by two components, interaction of which with each other leads to formation trivalent ion functioning as structure-forming agent. One of the two components is added to aqueous solution of oxidants or to gelated solution of oxidants and the other component to gelated solution of oxidants before or during addition if sensitizer. Structuring of charge is performed at 20 to 90°C. |
Composition of emulsion blasting explosive / 2252928The invention is pertaining to the field of mining shot firing operations and may be used on the earth surface and in open cast mines, ore mines and coal pits, which are not gas- or dust-hazardous, using a manual and mechanical charging of the boreholes and blast-holes in the hard, medium, weak rocks and coal. The composition of the offered emulsion blasting explosive (EBE) contains a granular ammonium nitrate, oil products, an emulsion of poremit and powdered ferrosilicon. The porous granular ammonium nitrate may be used in the composition of the emulsion blasting explosive. The purpose of the invention is development of EBE safe for environment, safe at handling, transportation and storage. |
| Composition of emulsion blasting explosive / 2252927 The invention is pertaining to the field of mining shot firing operations, in particular, to the emulsion blasting explosives (EBE), which may be used on the earth surface with a manual or a mechanized charging of the dry boreholes in the hard, medium, weak rocks and coal. The offered EBE contains an emulsion of poremit, a granular ammonium nitrate and liquid oil products. The porous granular ammonium nitrate may be used in the given EBE. The purpose of the invention is development of a loose EBE, its safe production, transportation and use, that ensures a possibility of its delivery to the place of an explosion and charging of the boreholes by specialized machines for transportation of the explosives in the transportable loading pockets. |
Composition of emulsion explosive / 2252926The invention is pertaining to the field of shooting operations, in particular, to production of emulsion explosive substances (EES), which may be used on the earth surface with a manual and mechanized charging of the dry and encroached wells in hard, average, soft rocks and coals. The offered EES contains an emulsion of poremite, granulated ammonium nitrate, liquid oil products and a gas-generating additive. The EES may contain a porous granulated ammonium nitrate. The purpose of the invention is creation of an ecologically safe and safe in handling EES with explosive performances equal to a trinitrotoluol-containing blasting explosives. |
Water-containing frost-resistant environmentally safe explosive / 2246473Invention relates to creation of safe water-gel industrial explosives for blasting operations in mining industry reusing overdue individual explosives, gunpowders, fuels, and their components. Claimed explosive contains ammonium nitrate, cryogenic additive, thickener, structure-forming agents, water, and a complex system: explosive sensitizer with chemical absorbent of halogen-containing toxic gases resulting from explosive conversion. |
| Method to decrease density of nitrate in products with the help of a gasifying agent / 2245844 The invention is dealt with a method to decrease of a density of ammonium nitrate in products. The method includes production of a gasifying agent in the form of a water-insoluble solid carbonaceous compound capable to help evolution of a gas at a chemical reaction, and production of a product out of ammonium nitrate. The water-insoluble solid substance having the average diameter of particles of no less than 40 micron is introduced in the ammonium nitrate product having the acid. At that the value of pH is between 2 and 5. At production of granules (pellets) from the ammonium nitrate product a granular product of an ammonium nitrate with the lowered density is formed. The invention also is dealt with granular products out of ammonium nitrate produced by this method and an explosive composition a containing a granular product out of the ammonium nitrate produced by this method. The offered method ensures an increase of volume of self-contained pores and accordingly a decrease of the volumetric bulk density. |
| Water-containing gunpowder explosive composition / 2243957 Invention relates to manufacture and application of industrial water-containing explosives based on gunpowder-sensitized gel-like oxidant solutions. Invention provides composition containing granulated pyroxylin gunpowder or mixture thereof with ground pyroxylin and/or ballistite artillery powders, or ballistite rocket powders; water-soluble metal nitrates or their mixture; organic fuel; polyacrylamide (thickener); aluminum sulfate (cross-linking agent); water; and ammonium nitrate. |
| Method of manufacturing dibasic gunpowder / 2260574 Invention is dealing with dibasic gunpowder, which can be used for armoring cartridges for rifle, artillery, and mortar systems. Method of invention consists in mixing cellulose nitrates, nitroglycerine, and in-water chemical stabilizer to form powder mass, pressing powder mass to remove water, rolling powder mass while performing heat treatment of mass to plasticize cellulose nitrates with nitroglycerine, and molding powder elements. Method is characterized by that, after pressing water out of powder mass, 30-80% aqueous solution of diethylene glycol monomethyl ether is added to cellulose nitrate mass as supplementary plasticizer in amount of 44-133% of the weight the mass and that, when the powder elements are molded, this supplementary plasticizer is removed via extraction with water at 20-60°C. Thus manufactured gunpowder is superior to existing analogs in what concerns its ballistic characteristics. |
Paddle feeder / 2260178Device has hollow rotor with blades mounted on drive shaft, rotor blades are metallic. Surfaces of rotor and blade are faced with rubber or elastic polymer material. In the middle of blades in certain step along their width through openings are made, through which facing of both sides of blades is connected. On end walls of rotor along circle grooves are made in form of dovetail, filled with facing material. Feeder is provided with remote adjustment system for rotation frequency. |
Method of armoring charges of ballistite-type solid rocked fuel / 2259986Method consists in regulating temperature and time conditions for applying migration-resistant adhesive sublayer onto solid rocked fuel block. The latter operation is effected in container with process solution containing glue (called "Leikonat"), allyl alcohol, dibutyltin dilaurate, after which block is removed from solution and dried for 40 to 360 min at 15-35°C. Dried block is placed in press mold and charge is then armored with acetylcellulose-based armoring composition using injection casting technique. |
| Method of armoring solid rocket fuel charges / 2259985 Method comprises applying adhesive sublayer onto fuel block, drying sublayer, placing and centering fuel block in press mold, heating grained thermoplastic armoring material until fluidity state, and injecting the latter into gap between press mold and fuel block. In such case, armoring material is given up to 30% of process refuse of armoring composition disintegrated to characteristic size of armoring material grains. In particular, to starting armoring material having high fluidity factor, refuse material with lower fluidity factor is added and, vice versa, to starting armoring material having low fluidity factor, refuse material with higher fluidity factor is added. |
Method of mixing blasting composition components / 2259984Invention, in particular, relates to mixing gun powders and mixed solid rocked fuels. method of invention comprises preparing components, measuring out viscous-liquid components, curing agent, portionwise measuring out powdered components and mixing them. When preparing components, powderlike curing agent is preliminarily mixed in plasticizer to be included into explosive formula at curing agent/plasticizer ratio 1:(1.5-2.0). Resulting mixture is metered into mixer and stirred during 10-20 min before measuring out last portion of powdered components of the composition. |
| Method of manufacturing solid ballistite-type fuel charge for rockets / 2259983 Method comprises mixing components, pressing fuel mass, rolling tableting, drying, and feedthrough compaction of charge on press apparatus through shaping pressing tool. Thus prepared charge receives up to 40 wt % of fuel process refuses having the same composition either in the form of finely divided crumbs (during mixing operation) or in the form of coarsely divided crumbs (during rolling tableting operation), or yet in the form of fuel tablets prepared by rolling tableting (during drying operation). |
Method for mixing explosive composition components / 2259982Method comprises preparing viscous-liquid and powdered components, measuring out viscous-liquid components into mixer, measuring out powdered components into mixer portionwise, and mixing each portion of powdered components with viscous-liquid components, while simultaneously controlling loadings on the drive of mixer agitators. When preparing powdered components, they are packed up by portions according to dispersity of particles, during which operation fine particles are separated from coarse ones. When measuring out powdered components, first coarse-grain component portions and then fine-grain ones are measured out. Final mixing is effected until minimal stable loadings on the drive of mixer agitators as well as stabilization of their value deviations are attained. |
Method of armoring inserted charges of solid rocket fuels with armoring composition having viscosity 4000 poise and vitality up to 10 minutes / 2259981Invention relates to inserted charges of solid rocket fuels largely used in various-destination rocket systems. Method comprises pouring armoring composition into gap between charge to be armored and cartridge under the action of centrifugal force directed along annular gap and creating overload at the inlet of gap at last 60 g. Armoring composition constituents are continuously measured out, mixed, and conveyed to mold rotating together with disk, to which several such molds are peripherally attached. To facilitate armoring composition flow into the gap and to degas composition, mold is given vacillating motion with predetermined amplitude and frequency. |
Solid rocket fuel charge manufacture method / 2259980Manufacture procedure comprises centering rod-assisted formation of fuel elements bundle, filling engine chamber bottom with fixing composition, immersing one end of fuel elements bundle into fixing composition and pressing it up to the stop, and hardening fixing composition. In order to form fuel elements bundle, fuel elements are assembled around centering rod into peripherally charge-forming cardboard envelop rolled up in overlapping way and secured on its outer side with scotch tape, cardboard envelop height being 0.8-0.9 that of protruded part of fuel elements from chamber bottom. When manufacturing fuel charge according to proposed method, fixing compositions with vitality time at least 30 min under normal conditions but also rapidly hardening at elevated temperatures can be used. |
Method for armoring a hard rocket fuel charge / 2259919Method includes applying adhesive migration-resistive sub-layer on prepared charge and armoring it using press by extrusion method. As armor material armor material on basis of thermo-elastic modified by special resin is used. Adhesive sub-layer is made on basis of special glue. |
Method of production of ammonium nitrate and a device for its realization / 2259319The invention is pertaining to the field of chemical industry, in particular, to processes of production of alkali liquors of ammonium nitrate. The method of production of ammonium nitrate includes neutralization of nitric acid by gaseous ammonia under an atmospheric pressure at the temperature of 130-140°C with an evaporation of the solution due to the heat of neutralization. The neutralization of the nitric acid is conducted in a stream with a solution of the ammonium nitrate by internal forced circulations with a parallel evaporation of the solution. The solution evaporation is conducted at rarefaction of 0.003-0.004 MPa. The device for production of the ammonium nitrate contains a cylindrical body with the bottom and unions for the solution withdrawal, gauging of its level and a pressure, a cover with an union for withdrawal of the juice vapor. Inside the body at some distance from the bottom the neutralization unit is mounted. It contains two concentrically mounted cylinders communicating with each other through two rows of holes located in the internal cylinder below at the bottom of the outer cylinder and above at the attachment flange of the internal cylinder. Above in the internal cylinder there is a tubular reactor made in the form of an ejector with unions for delivery of the nitric acid and the gaseous ammonia, the body of which is supplied with holes for the solution entry in the mixing chamber of the reactor; a separating funnel which is mounted without a backlash to the lower flange coupling and is fixed in the internal cylinder; and an assembly of an evaporation of the solution, containing two blind plates with the overflow edges installed one above another between the body of the device and the external cylinder of the neutralization assembly in such a manner, that the overflow edge of the upper plate is placed near to the body of the device and at the level of the axes of the upper holes in the internal cylinder of the assembly of neutralization, and the overflow edge of the lower plate - near to the external cylinder of the assembly of neutralization. At that the cylinders of the neutralization assembly inside and outside are supplied with longitudinal ribs. The technical result: the method of production of ammonium nitrate and the design of the device for its realization allow to conduct the process of the neutralization of the nitric acid by the gaseous ammonia with formation of alkali liquor of the ammonium nitrate in a safe mode, as the process is conducted without a pressure with a forced circulation of the solution of an ammonium nitrate due to a kinetic energy of gaseous ammonia, which is fed in the reactor and due to provision of a reliable heat-exchange between the circulating and evaporating alkali liquors, and also allows to reduce metal consumption and to simplify the layout of the equipment. |
| Method to decrease density of nitrate in products with the help of a gasifying agent / 2245844 The invention is dealt with a method to decrease of a density of ammonium nitrate in products. The method includes production of a gasifying agent in the form of a water-insoluble solid carbonaceous compound capable to help evolution of a gas at a chemical reaction, and production of a product out of ammonium nitrate. The water-insoluble solid substance having the average diameter of particles of no less than 40 micron is introduced in the ammonium nitrate product having the acid. At that the value of pH is between 2 and 5. At production of granules (pellets) from the ammonium nitrate product a granular product of an ammonium nitrate with the lowered density is formed. The invention also is dealt with granular products out of ammonium nitrate produced by this method and an explosive composition a containing a granular product out of the ammonium nitrate produced by this method. The offered method ensures an increase of volume of self-contained pores and accordingly a decrease of the volumetric bulk density. |
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