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Method of controlling process of thermal destruction of petroleum residues in pipe furnace

Method of controlling process of thermal destruction of petroleum residues in pipe furnace
IPC classes for russian patent Method of controlling process of thermal destruction of petroleum residues in pipe furnace (RU 2318858):
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FIELD: petroleum processing.

SUBSTANCE: method according to invention determines pressure gradients at exit and entrance in each section of the furnace and real gradient is compared to projected gradient, after which, depending on disagreement value, this value is diminished via variation of fuel consumption in corresponding furnace burner. Projected gradient is calculated using formula: ΔPi=k(L1+b)n, wherein ΔPi is pressure gradient in i-th section of coil, %; k, b, n are coefficients depending on conversion value, nature of raw material, and projected quality of final thermal destruction products; and L1 reduced length of coil from its beginning to i-th measurement point, %.

EFFECT: decreased coking of furnace coil and increased operation cycle of plant, which incorporates the furnace.

3 cl, 3 tbl

 

The invention relates to the field of oil refining, in particular to a method of regulation of the process of thermal decomposition of petroleum residues in the multi-section tubular furnace.

A known method of regulating the heating process and the cracking temperature of the product at the exit of the furnace coil (Smidovich EV Technology of oil and gas processing, part 2-I, M, Chemistry, 1968, p.86-95).

The disadvantage of this method is the lack of control and regulation of the heat supply by the length of the coil (in sections), which causes the danger of coking of the furnace coil and reducing turnaround installation.

The closest to the technical nature of the claimed object is a method of regulation of the process of obtaining coke in the reactor delayed coking unit, including the measurement of the gradient between the two parameters at the inlet and outlet of each section of the furnace, comparing the actual gradient with the given and depending on the magnitude of the error decreases this value by changing the fuel to the burners of the relevant section of the furnace (A.S. No. 1778134, on. 30.11.92, BI No. 44).

The invention aims to increase productivity by improving the quality of regulation and exclusion of recirculate.

However, in the known method is not taken into account the following factors affecting zakocs ivanie coil furnace, such as:

- recirculate is not only cooled but also the stabilizer that improves aggregate stability of the loading coil of the furnace, and to exclude him from the process impractical;

- limit values are exceeded the conversion of the feedstock in a single pass coil furnace 1.5-3.8 times;

is not measured at the time of the product through coil sections of the furnace and, consequently, the conversion of raw materials as in sections and throughout the furnace;

when the coking internal heat transfer surfaces of the chimney, despite the availability of the automation system, raises the temperature of the pipe wall, which is accompanied by a spontaneous increase in the rate of coking process this section.

These weaknesses increase the risk of coking coil and shorten the duration of a continuous run of installation.

The technical result, which is aimed invention is to reduce coking of the furnace coil by improving the quality of regulation of the process of thermal decomposition of oil residue in the furnace coil when receiving products of the required quality.

This technical result is achieved in that in the method of regulation of the process of thermal decomposition of petroleum residues in the coil of the furnace, including the measurement of the gradient between the two parametreina the inlet and outlet of each section of the furnace, comparing the actual gradient with the given and depending on the magnitude of the error decreases this value by changing the fuel to the burners of the corresponding section, according to the invention as a gradient between the two parameters using the pressure gradient, and set the pressure gradient for each section of the coil is calculated by the formula

ΔPi=k·(Li+b)nwhere

ΔPi- pressure gradient at the i-th section of the coil, % of total pressure gradient across the coil of the furnace;

k, b, n are coefficients that depend on the magnitude of the conversion, the nature of the raw materials and the specified quality of the products of thermal decomposition;

Li- the length of the coil from its beginning to the i-th measuring points, % of total length of the coil.

It is advisable to measure the pressure gradient to use devmanager and system for measuring pressure gradient continuously feeding liquid separation-recirculate.

The gradient of pressure between inlet and outlet of each coil section of the furnace as measured indicator allows to control and regulate the process of thermal decomposition of petroleum residues in sections in accordance with the estimated profile of the pressure gradient along the length of the coil when receiving products of the required quality and thereby reduce the danger of coking is majevica oven.

The method of regulating thermal decomposition of oil residue in the furnace is as follows. After start-up and warm-up of the technical system at the starting gas in the multicell furnace instead of starting product is served raw material composition (a mixture of tar with thinners, turbulization) under pressure furnace pump, which takes place pipe camera convection and enters the pipe chamber radiation, where it is heated by radiation of the flame of the burning fuel mixture (fuel, air, steam)coming out of the burners located in the furnace. As you progress through the coil of the furnace temperature rises to the temperature of decomposition of the raw material (420-430°C)the volume of the vapor phase increases, increasing the flow rate increases the difference (gradient) of the pressure in this area (section) of the pipe, the flow structure inside the tube also changes and transitions from homogeneous (liquid) environment to a two-phase (gas - liquid).

When the temperature level flow 460-500°With the feedstock decomposes (Criciuma) more intensively with the formation of low molecular weight components (gas, gasoline, light and heavy gas oils), volume flow (fraction of the distillate) is increasing exponentially, increasing the flow rate increases the pressure drop n the current segment of the pipe. In this regard, the magnitude of the pressure difference (gradient) characterizes the performance of the processes of raw material inside the pipe, which is the result of heat to the flow on this section of the coil of the furnace. Actually measured value of the pressure gradient in the control system is compared with a given (estimated), and depending on the magnitude of the error, this value is reduced by changing the fuel to the burners of the relevant section of the coil. The control system must be implemented in hardware, such as programmable logic controllers.

The coking of the i-th section of the coil of the furnace accompanied by an increase in the pressure gradient in this section, which causes a corresponding reduction in fuel supply to burners of this section and, therefore, prevents further coking of this section. The last circumstance contributes to lowering the temperature of the flow and, consequently, the conversion in this area that the proposed method did not increase the fuel supply to the burners of the i-th section of the coil. This reduces the danger of coking of the furnace coil and increasing the duration of the continuous run of the installation.

The specified pressure gradient of each section of the furnace coil is calculated by the above formula is against the odds which set of pre-calculated experimentally. These coefficients depend on the nature of raw materials, given the conversion of raw materials and quality of products of thermal decomposition, as well as from the material design of the coil of the furnace. The absolute value of the differential pressure sections (MPa) is determined by multiplying the relative (%) pressure drop in the total pressure drop across the coil (MPa), which, in turn, completely correct as a General pressure gradient on the coil current installation.

The following are specific examples of implementation of the proposed method.

Raw tar with a density of 960 kg/m3, cocking behavior 10%, the nominal viscosity at 80°

The raw material is subjected to high temperature heating and cracking in laboratory flow-through installation, which includes: raw material tank, tank pad, gas oil, pump, furnace with coil for high temperature heating of the raw material, the valve-pressure regulator, reactor delayed coking unit with electric heating, refrigerating condenser, distillate receiver, gas watch, electrical equipment, control and measuring devices, in particular, at the inlet and outlet of the coil of the furnace and the reactor pressure gages are installed.

For option at the stage visbreaking cracking temperature in the furnace stood the sludge 480-490° With the pressure of 2 MPa. The reactor of the scheme off. Conversion of the raw material (decomposition) is determined by the sum of the output gas and gasoline as a percentage of raw materials.

For option delayed coking temperature in the furnace was 480-490°C, a pressure of 2 MPa in the reactor temperature 420-450°C, a pressure of 0.3 MPa.

According to the results of experiments data were obtained: ITC distillate, gas composition, material balance, conversion, quality, balance +180° (boiler fuel), the quality of coke (volatile substances)for which calculations were carried out industrial furnaces processes visbreaking and delayed coking units at various (specified) conversion of the feedstock in the furnace, with a recirculation ratio of 1.2 (Kp=1,2) upon receipt of the products of the specified quality. In table. 1, 2, 3 shows the experimental and calculated data.

From table. 1 (examples 1, 2, 3) shows that to improve the quality of balance (+180° (C) visbreaking by reducing the viscosity ofto standard boiler fuelit is necessary to increase the conversion of raw materials into the furnace coil from 2.8 to 5.5% (gas + gasoline), while the pressure gradient coil in the furnace will increase to 1.37 times. From table. 3 (columns 5, 6; examples 1, 2, 3) shows that in this case, when the application of the proposed method duration of continuous probematliki furnace is increased by 7-27% (relative) compared to the prototype (column 4).

From table. 1 (examples 4, 5, 6) also shows that to improve the quality of coke by reducing the content of volatile substances from 9-10 7-8%, it is necessary to increase the conversion of raw materials into the furnace coil from 6 to 10% (gas + gasoline), while the pressure gradient coil in the furnace will increase by 1.35 times. From table. 3 (columns 5, 6; examples 4, 5, 6) shows that in this case, when the application of the proposed method continuous run of a coil of the furnace is increased by 15-25% (relative) compared to the prototype (column 4).

Table 2 - Values of the coefficients in the formula for determining the specified pressure gradient along the coil sections of the furnace
№ p/p Process Conversion in the furnace, % (gas + gasoline) The magnitude of the coefficients of equations The pressure drop in the furnace associated with the conversion, % relates. ΔPi
k n b
1 2 3 4 5 6 7
1 Visbreaking (UVB) 2,8 4,07009·10-4 2,3146 25 100*
2 5,5 9,54591·10-6 3,12764 25 134*
3 11 4,3809·10-7 3,79551 25 173*
4 Delayed coking (DCU) 6 5,57475·10-5 2,7426 25 128*
5 8 5,00696·10-5 2,7712 25 152*
6 10 4,70756·10-5 2,78405 25 168*
* is determined by the formula

Discrepancies between the data presented in table 1 and calculated by the proposed formula with coefficients from table 2, do not exceed 5% (Rel.).

Table 3 - Duration of continuous mileage coil furnace in the process of thermal decomposition of oil residues
№ p/p Process Conversion in the furnace, % (gas + gasoline) Duration of continuous mileage furnace, %* The increased duration of the continuous run of the furnace, % (relative)
p is totip offer
1 2 3 4 5 6
1 Visbreaking (UVB) 2,8 100 107 7
2 5,5 95 109 15
3 11 83 105 27
4 Delayed coking (DCU) 6** 93 107 15
5 8 89 106 20
6 10 85 106 25
* The end of the run of the furnace is determined by increasing the pressure gradient in the coil by 20% from the initial value.
** Kp=1,2;

Thus, the proposed method of control of the process allows to minimize coking furnace coil in the processes of thermal decomposition of petroleum residues in obtaining products of the required quality and to increase the duration of continuous mileage furnace at 7-27% (relative) when visbreaking and 15-25% (relative) during coking.

1. The method of regulation of the process of thermal decomposition of petroleum residues in the coil is ECI, including the measurement of the gradient between the two parameters at the inlet and outlet of each section of the furnace, comparing the actual gradient with the given and, depending on the magnitude of the error, reducing this value by changing the fuel to the burners of the corresponding section, characterized in that as the gradient between the two parameters using the gradient of pressure and the predetermined pressure gradient for each section of the furnace coil is calculated by the formula

ΔPi=k·(Li+b)n,

where ΔPithe pressure gradient at the i-th section of the coil, %;

k, b, n are coefficients that depend on the magnitude of the conversion, the nature of the raw materials and the specified quality of the end product destruction;

Li- the length of the coil from its beginning to the i-th measuring points, %.

2. The method according to claim 1, characterized in that for measuring the actual pressure gradient use devmanager.

3. The method according to claim 1, characterized in that the measuring system pressure continuously serves release liquid-recirculate.

 

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