Gum arabic (1) replacement during encapsulation in confectionary products, in glues and coatings; (2) in food frames and during capsulation of taste substances (3), in lithography. RU patent 2504212.

FIELD: food industry.

SUBSTANCE: invention relates to a gum arabic replacer composition preparation for usage in various branches of industry (food, pharmaceutical and other). In the method implementation pattern for usage during encapsulation, coating application onto confectionary products, glazing or gluing of food products the method envisages sequential addition into a water solution of a strong film-forming agent of natural and/or modified polysaccharides (taken in an amount of 0.1% - 10% of the total weight of ingredients in the composition solvent), a low-viscosity cracking agent (in an amount of 88.9% - 55% of the total weight of ingredients in the composition solvent), a rapid crystallisation agent (in an amount of 10% - 25% the total weight of ingredients in the solvent) and an adhesiveness modifier (in an amount of 0.1% - 10% of the total weight of ingredients in the composition solvent). The produced composition has viscosity equal to approximately 10 - 2000 centipoise at a temperature of 25°C and a concentration of 35°-40° Brix.

EFFECT: invention allows to reduce dependence on gum arabic import due to usage of a locally available material as well as to enhance such functional properties as a lighter tone, fast drying-out during application and an improved film barrier preventing oxidation.

6 cl, 37 dwg, 10 tbl, 6 ex

This application is filed on the basis of the provisional patent application US 61/083,808, filed on July 25, 2008, which is included here as a reference for all contained here purposes.

This invention is mainly refers to the substitution of gum Arabic, but not limited to its use in three main categories of applications, including: (1) coating, confectionery, food/pharmaceutical adhesives and coatings; (2) encapsulation and spray drying aromatic substances and edible film; and (3) the enforcement in the field of printing, lithography or to achieve a variety of purposes, usually achieved by gum Arabic: (1) to bind and consolidation of the sugar shell chewing gum and the nut candy, chocolate or chewing balls; as a seal and oxygen barrier for centers of various nuts, chocolate malt balls; as textured modified hardener for pastilok and caramel; polishing shop were launched as a means to achieve a brilliant cover for drops, dry breakfasts, tablets and other products and as a glue record of granola, a group of Breakfast cereals and grains; (2) as an emulsifier and agent for oil, designed for spray drying, and as a foaming agent, which exfoliate small parts to get a shiny plastic wrap; and (3) as a wetting agent and and repulsive printing ink material used in lithography.

Gum Arabic - dry exudate obtained from various breeds of a tree acacia family Leguminosae, growing in tropical and subtropical areas of the world. Gum Arabic is widely used in food, pharmaceutical and manufacturing industries. At present there are two types of acacia, which are available on the market: Acacia Senegal (Senegal gum) and Acacia Seyal (red acacia) for the food and pharmaceutical applications. However, for industrial applications, specifically, in lithography, standard replacement becomes another exudate, namely, Combretum (red Magnolia). The main production of the country of production of these varieties are in Africa in the area South of the Sahara, including the Republic of the Sudan, Chad, Eritrea, Nigeria and neighbouring countries. Due to the political situation in this region of Africa in the other countries there is a shortage of gum Arabic.

Need for food and pharmaceutical applications is quite significant. Only for the coating of assessment international demand for gum Arabic - approximately 20 million pounds annually. In recent years, the supply of gum Arabic was very irregular and unpredictable due to political instability in Africa, where its sources. Accordingly, the risk of insufficient supplies of gum Arabic became all the more disturbing circumstance.

Gum Arabic - rich substance with a high molecular weight and extremely low viscosity and behaves like a Newtonian fluid, concentration up to 35%; it dissolves in the concentrations of 55%-60% and creates a thick syrup. This low viscosity caused by its structural branching, which makes it a spherical molecule. This branching prevents the formation of micelles, unlike linear resins, reducing to a minimum the intermolecular formation of hydrogen bond, when the gum Arabic is dissolved in water. As a result of gum Arabic forms a weak film. His solution becomes sticky at high concentrations, but gives texture after drying. When applied on the surface it forms a brilliant film which is split in a unique way. The material is the property of the emulsion in the presence of the protein, which is connected by covalent bond with some part of the faction, forming complex compounds, very rich in polysaccharides of high-molecular-weight exceeding 2 million daltons.

Gum Arabic is also used in solid nakatke in the manufacture of chewing gum and chocolate candy for communication and strengthening coatings shell, which consists of sugar or sugar alcohols. It is added to the syrup recipe for spraying or molding. Gum Arabic is used or only during the initial stages of coating process due to its high cost, or in all downloads syrup, in particular, in formulations to help create a solid layer of the shell around the centre of gum. Need a good binder component in covering and filling solutions is a direct result of the desire to use large baths with covering syrup to increase productivity, which requires large amounts of cleavage cover shell, when the centers over the bath. Many other examples of the packaging and transportation of the final product and when consumers shaken packaging occurs cracking of the product. Even during normal laying of sugar in the form of the necessity of hardening the shell in the coating process becomes important when using large machines for coating. Maltodextrin is a cheap substitute for binding sugar at normal syrup and can work satisfactorily, when the size of enrobing baths and a single boot are small; however, it cannot be used as a substitute of gum Arabic in large enrobing machines with large disposable loading due to the weaker and cracked crystals.

Acacia Senegal - first-class gum Arabic, which is a natural emulsifier used mainly in emulsions for preparation of drinks, dessert taste additives and flavorings spray drying; Acacia Seyal - brand of gum Arabic, which has limited emulsifying properties, but economically advantageous. Acacia Seyal replaces Acacia Senegal in many fields of application, where emulsification is a secondary or is not important. Substitutes Acacia Senegal in emulsions for drinks have been developed and commercialized in the form of various starches and Arabian gum, modified suktsinatom made from Acacia Seyal, as disclosed in U.S. patent 6 455 512. In encapsulated flavouring or spray dried flavoring used Acacia Seyal, mixtures containing Acacia Seyal, modified resin and mixtures containing emulsifying starches with maltodextrin, partially replacing Acacia Senegal. Examples of the application of the invention is different from these known substitutes composition of ingredients that have been evaluated and selected on the basis of their contribution to relevant key properties of gum Arabic in various fields of application, or in some cases improved functionality substitute for this gum Arabic while reducing cost or maintaining it at the same level.

In other applications, such as coating and manufacturing of confectionery products, the main substitute for gum Arabic is the use of Acacia Seyal instead of Acacia Senegal, is a practice that will not solve the problem of shortage of gum Arabic. Solid rolled coating or the edible or pharmaceutical compositions in which the sugar is used as sucrose, dextrose, fructose or glucose syrups, or used formulations containing maltitol, erythritol, sorbitol, xylitol, mannitol or hydrogenated products of hydrolysis of starch, almost always requires the use of gum Arabic for binding and hardening the shell or seals. The process of coating on the basis mainly consists of reset foundations (centres) in the dryer, rotating with a desirable speed at the right temperature, load coating components in liquid form and drying of the coating between the stages of the coating. Coating process is repeated until the shell reaches the desired thickness, approximately 30-33% of the weight of the product. Developed amendments to this process.

In practice, the application of the food film and glazes, where viscosity, transparency, the nature of the specific cracking and gluing of/exemption from the belt conveyor is very important, gum Arabic remains the only resin used for this purpose at the present time.

Due to the uniqueness of gum Arabic related technologies intended to replace it in different areas, such as the food industry and pharmaceutical industry, have not been sufficiently developed. Consequently, there remains a need for replacement of gum Arabic.

The invention relates to the replacement of gum Arabic, partial replacement or full replacement in various application fields, e.g. in the food industry, pharmaceutical industry and other sectors, which mainly addresses one or more of the problems associated with deficiencies and limitations known technologies.

The advantage of the invention consists in the replacement of gum Arabic, using locally available materials, which will reduce the dependence on imports of gum Arabic. Another advantage of the invention consists in the replacement of gum Arabic structure, which is competitive or cheaper than the gum Arabic.

Other advantages of the invention consist in increasing the functional properties in some areas of application, such as a lighter shade, quick drying when applying the product and superior film barrier, preventing oxidation.

Additional features and advantages of the invention will be described in the following description, and these benefits are partly will be obvious from the description or may be confirmed in practice of application of the invention. These signs and other advantages of the invention will be implemented and achieved structure described in the text of the description, the claims and the attached drawings.

Example of an embodiment of the invention refers to the method of preparation of a full substitute for gum Arabic, partial substitute or extended area of the use of the song when , candy, when and gluing. The method includes selection of durable (key) plenkoobrazovatelja of natural and/or modified polysaccharides, which in the total number of songs or in the final product include from about 0.1% to 10% of the amount of gum Arabic, which typically would be used, regardless of whether you are using gum Arabic in this case.

Another example of an embodiment of the invention refers to the usage of a substitute, partial substitute or an extended composition, as binding and hardening regimes of lathe tools sugar or sugar-alcohol coverage shell, centres containing o-oil, hardening of confectionery and gluing of grains and fragments of dry Breakfast. The method involves the application of water a substitute for gum Arabic, partial substitute or extended composition as a binder and hardening regimes of lathe tools sugar or sugar-alcohol coverage shell centres containing o-oil, hardening of confectionery and gluing together grains and fragments of dry Breakfast. The composition on this example of the incarnation includes durable (key) natural foaming agent and/or modified resin component from about 0.1% to 10% of the total number of compositions, or used by the target application at a level equivalent from about 0.1 to 10% of the amount of gum Arabic, which typically would be used, regardless of whether you are using gum Arabic in this case. Additionally composed of low viscosity cracking machines agent, modifier stickiness and/or agent rapid crystallization. For example, low viscosity cracking machines agent contains approximately 0% to 99,9% of the total number of songs or used by the target application at a rate equivalent to about 0 to 99.9% of the amount of gum Arabic, which typically would be used, regardless of whether you are using gum Arabic in this case. Modifier stickiness can range from about 0% to 10% of the total number of songs or used by the target application at a rate equivalent to about 0 to 10% of the amount of gum Arabic, which typically would be used, regardless of whether you are using gum Arabic in this case. Agent rapid crystallization can range from about 0% to 99.8% of the total number of songs or used by the target application at a rate equivalent to about 0 to 99.8% of the amount of gum Arabic, which typically would be used, regardless of whether you are using gum Arabic in this case.

Another example of an embodiment refers to the method of preparation of the substitute, a partial substitute or extended composition as agent for spray dried food additives or in the form of food film. The method includes selection of durable (key) plenkoobrazovatelja of natural and/or modified polysaccharide, which is from about 0.1% to 10% of the composition, or used by the target application at a level equivalent from 0.1 to 10% of the amount of gum Arabic, which typically would be used, regardless of whether you are using gum Arabic in this case. The method also includes the addition of natural and/or modified emulsifier, which provides a taste emulsion, stable for at least 4-6 hours after preparation, in which natural and/or modified emulsifier may be additional ingredient, replacing gum Arabic in the food glaze, in which such emulsifier is from about 0.1% to 25% of the total number of compositions, and in which the natural and/or modified emulsifier may be additional ingredient, replacing gum Arabic in the food glaze. Furthermore, the method involves adding polysaccharide of around 50% to 99.9% of the total number of songs, which song has a viscosity at concentrations of approximately 35-40 Celsius BRICs about 10 CP to 2000 centipoise at 25 deg C.

Another example of an embodiment of the invention refers to the usage of a substitute, partial substitute or extended composition in lithography and printing. The method includes selection of anionic polysaccharide of from about 0.1% to 10% of the total number of songs in which anionic polysaccharide is selected from the group consisting of xanthan gum, sodium carboxymethyl cellulose, alginate, gum ghatti, resin brown and their combinations. The method includes in addition to adding emulsifier and surface-adhesive modifier components from about 0.1% to 25% of the total composition. Emulsifier and surface-adhesive modifier selected from the group consisting of propylene glycol alginate; resins, modified suktsinatom; enriched emulsifier Arabian gum, modified suktsinatom; and their combinations. The method also includes the addition of sustainable to the solvent polysaccharide, selected from the group consisting of maltodextrine, larch resin, inulin, and their combinations, and which constitutes about 65% to 99.8% of the total composition. Compositions have a viscosity at a concentration of 14C Baume about 10 CP to 900 centipoise at 25 deg C.

It should be understood that the above is a General description and a subsequent detailed description are just examples and explanatory and provide additional information on the claimed invention.

The attached drawings provide additional understanding of the invention and an integral part of this description. They illustrate examples of the application of the invention and, together with a description explains the principles of the invention.

The drawings:

Figure 1A illustrates the composition of cracking film gum Arabic Acacia Seyal according to one example of the invention;

Figure 1B illustrates the composition of cracking film gum Arabic Acacia Senegal in another example of the invention;

Figure 2 illustrates the curve viscosity of compositions of gum Arabic, shown in figures 1A and 1B;

Figure 3A illustrates film carboxymethyl cellulose in another example of the invention;

Figure 3B illustrates the film of methylcellulose in another example of the invention;

Figure 3 illustrates film in another example of the invention;

Figure 3D illustrates film in another example the invention;

Figure 3E illustrates film of sodium alginate in another example of the invention;

Figure 3F illustrates film resin fruit of the carob tree in another example of the invention;

Figure 3G illustrates film xanthan gum in another example of the invention;

Figure 3 illustrates film in another example of the invention;

Figure 4A illustrates film in another example of the invention;

Figure 4B illustrates film larch resin in another example of the invention;

Figure 4 illustrates film starch according to another example of the invention;

Figure 4D illustrates film in another example of the invention;

Figure 5A illustrates the composition of cracking film standard substitute 1 in another example of the invention;

Figure 5B illustrates the composition of cracking film substitute 1 from natural substances, according to another example of the invention;

Figure 6 illustrates the curves of viscosity in another example of the invention;

Figure 7 illustrates three different films having different patterns scales in another example of the invention;

Figure 8A illustrates film Acacia gum Arabic Seyal, having the structure of cereals in another example of the invention;

Figure 8B illustrates a 50:50 mixture of film gum Arabic Acacia Seyal: Acacia Senegal, which has a structure of cereals in another example of the invention;

Figure 9B illustrates the profile of gum Arabic Acacia Senegal in different periods of time in another example of the invention;

Figure 9C illustrates profile substitute 2 with an emulsifier resin, modified suktsinatom, scanned device Turbistan at various time intervals in another example of the invention;

Figure 9D illustrates profile Turbiscan substitute 2 with an emulsifier starch, modified suktsinatom, at various time intervals in another example of the invention;

The figure of the 9TH illustrates the scanned device Turbiscan profile substitute for 2 with a natural emulsifier at various time intervals in another example of the invention;

Figure 9F illustrates the scanned device Turbiscan separately emulsion substitute 2 without emulsifier in different periods of time in another example of the invention;

Figure 10A illustrates food glaze Arabic gum Acacia Seyal according to the example of the invention;

Figure 10 illustrates the substitute 2 with food glaze, modified suktsinatom, in another example of the invention; and

Figure 10 illustrates the substitute 2 all natural food emulsifiers glaze in another example of the invention.

Examples of the application of the invention belong to skim for use in the three main areas of application: (1) coating on the confectionery, food, and pharmaceutical products; (2) encapsulation of food additives and spray dried aromatic substances and edible film; and (3) the field of lithography and printing. Of course, a complete replacement of gum Arabic, a partial substitute or extended composition can be used in many other areas, e.g. in the food, pharmaceutical and medical industry. Examples of the application also belong to the skim of gum Arabic from locally available materials for dry breakfasts and retail consumer products such as chewing gum, sweets, encapsulated aromatic substances, food film, and lithographic systems, thus minimizing problems of lack of gum Arabic and its cost.

By its composition, gum Arabic refers to materials, which can form a continuous film, and materials that could not form a continuous film. Examples of the application of the invention processing using the main components such as solid resins, crack agents, agents rapid crystallization and emulsifiers, ensure preparation of materials that are somewhere between these two ability of a layer formation materials.

Examples of the application of the invention also consider the parameters or characteristics of gum Arabic, such as ability, low viscosity, properties, influence of drying time, the nature of crystallization, viscosity level and crunch. Although these parameters or characteristics of gum Arabic provide a good job in finite fields of application, it is desirable to improve their specific characteristics, such as drying time, the strength of the casing, crunch and optimal viscosity. In addition, the issues related to cracking during transportation of end-products, create a requirement for the establishment of or substitutes.

The choice of the use of gum Arabic for sealing nut, chocolate, malt balls and the other containing oil centers intended to be coated, also stems from its unique low viscosity, which allows its use in 40% as covering syrup and, thanks to its property, use and as an oil barrier to seal oil, and as a barrier to oxygen, to prevent oxidation and rancidity. Gum Arabic at high concentrations also is viscous and sticky, making it suitable for gluing of grains, fragments of dry Breakfast plates of granola and other products. When used as a glaze for chocolates, tablets, it leaves a brilliant film. Gum Arabic is also used in and caramel to increase the strength and reduce the fragility crystallized confectionery.

Gum Arabic is also traditionally used for or spray drying flavor additives to protect aromatic oil from oxidation. Although it is not such a good foaming agent compared to most other polysaccharides, low viscosity of gum Arabic makes it ideal as a foaming agent in this field of application, because it allows you to create a recipe with solid particles (which means evaporation less water is drying) with a minimal increase in the viscosity of the emulsion drying spray. At the same time, theory of encapsulation requires that the optimal ratio of the material parts to oil in capsule was 4:1 and it makes the other resins much better properties of film formation unsuitable due to high viscosity, even with less than optimum 4:1.

When flavorings, there is another property of gum Arabic, which is required in addition to its related properties and low viscosity, namely: its emulsifying ability. Both varieties of gum Arabic. Acacia Seyal and Acacia Senegal, showed relatively the same performance characteristics in this field of application, confirming that even though Acacia Seyal the steady emulsifying ability for drinks, it is good enough to emulsify, flavour drying spray. Therefore, to replace the gum Arabic in this application, emulsifier is a necessary ingredient of the song that was not required in the above fields of application.

Fission structure of gum Arabic, when its 40% solution is bottled and dried on the surface (usually on the ribbon of stainless steel, suitable for its use to Shine in the edible film. Again, we note that a weak film and low viscosity are critical properties; in addition, in this area of application of such important qualitative characteristics of gum Arabic as transparency, Shine, bonding moist and easy release of the film after drying.

In lithography main function of a water solution of gum Arabic is to create the hydrophilic layer salts of calcium nitrate and gum Arabic in all parts of the surface where there is no image. Therefore, the properties of gum Arabic, which are important in lithography, include full solubility and stability in aqueous solution, sticking to the surface wetting and film formation.

Examples for implementing the invention relates to the preparation of the substitute of gum Arabic, partial substitute or extended compositions for use in various industries. Full or partial replacement of gum Arabic or extended composition is accompanied by two stages of the Protocol. This Protocol enables Stage 1 and Stage 2. Stage 1 is aimed at studying the properties of gum Arabic, such as viscosity, the characteristics of film forming, coating, Shine, crystallization, cracking and solubility. Stage 2 aims to test a substitute for gum Arabic, partial substitute or extended composition in a particular end-use, such as food industry, pharmaceutical industry and other industries.

In Stage 1 are the main study the properties of gum Arabic, including viscosity, film formation, coating, Shine, crystallization, cracking and solubility in water and thick syrup. Were prepared various concentrations of gum Arabic, including Acacia Seyal and Acacia Senegal with a content in the range of 10-50%, and was measured viscosity.

Figure 1A presents the structure of cracking film gum Arabic Acacia Seyal. Figure 1B illustrates the composition of cracking film gum Arabic Acacia Senegal. Figure 2 illustrates the curve viscosity of compositions of gum Arabic in figures 1A and 1B.

Figure 1A structure cracking formed emulsion gum Arabic Acacia Seyal. Composition contained approximately 35% of the water it was a syrup of gum Arabic Acacia Seyal. This composition was poured a glass plate with a thickness of 10 mm layer thickness of about 10-40 mm, dried, and occurred as crystallization and formation of cracks. The film has shaped structure cracking shown in figure 1A.

Figure 1B structure cracking formed emulsion gum Arabic Acacia Senegal. Composition had about 35% of water, that is, syrup gum Arabic Acacia Senegal. This composition was poured a glass plate with a thickness of 10 millimeters thick layer of 10-40 mm, dried and was observed in the process of crystallization and the formation of cracks. The film has shaped structure cracking shown in figure 1B.

When comparing the figures 1A and 1B significant differences between their structures, in particular, a different number of cracks and sizes flakes Seyal and Senegal, Seyal has numerous cracks and small number of flakes, a Senegal has only a small number of cracks and flakes of large size.

Figure 2 illustrates the curve viscosity of compositions of gum Arabic, shown in figures 1A and 1B. Figure 2 shows the hydration and viscosity of gum Arabic in water at various concentration, and curves Seyal and Senegal are well matched. Individual have also studied the film formation or cracking of the change of concentration as necessary, depending on the viscosity. Based on this study, it was decided that the one-component replacement of gum Arabic did not meet the indicators of gum Arabic in these estimates.

Figure 4A shows the film in another embodiment of the invention. Figure 4B shows the film larch resin in another incarnation. Figure 4C shows the film starch in another incarnation. Figure 4D shows film in another incarnation.

We now turn to the figures 3A-4D, on which you can see the various properties and features of the films. Thus, the figures 3A-3H are film-forming properties of polysaccharide resin food varieties with appropriate concentration for the spill, including film properties of maltodextrine and low viscose film from starch, as shown in the figures 4C and 4D, respectively.

From these results, it was found that depending on the application, neither the only material as a substitute (or substitutes) will not replace the gum Arabic, and for this purpose can be obtained only well-designed composition. In addition, in the course of the research it was found that the polysaccharides not form the film and turn into powder, as in the case of film (figure 4A) and film 15 DE (figure 4D), in contrast to those which form a sound and capable of adhesion of the film, which after application and drying of flakes in one piece, for example, the film of carboxymethylcellulose (figure 3A), the film of methylcellulose (figure 3B), pectin film (figure 3C), film (figure 3D), a film from sodium alginate (figure 3E), film resin fruit of the carob tree (figure 3F), film (figure 3G) and film (figure 3H) among others. It was discovered that the necessary elements for the replacement of gum Arabic Acacia Seyal or Acacia Senegal in various areas of application include: (1) durable (key) foaming agent, which is required in all applications at a minimum level, and supplements (2) ingredient and/or (3) emulsifier and/or (4) modifier stickiness and/or (5) ingredient rapid crystallization; each of them may be required depending on the ultimate purpose of the application.

Many of the compositions studied with regard to their competitiveness or cheaper than the gum Arabic, the end result came three different ways to replace that allow the composition of substitutes, which are functionally equivalent in three main categories of applications. These methods include: (1) method 1 replacement is aimed at the use of substitutes in causing diabetes and coverage, confectionery, applying for bonding and coating, but not limited to; (2) method 2 change is the replacement of gum Arabic are more suitable for encapsulation/drying spray flavouring substances, food film and brilliant coverage, although they will also work when and the manufacture of confectionery, and (3) method 3 change is the replacement of gum Arabic of more suitable materials for applications in lithography/printing, and that are functionally equivalent on the properties of wetting and repulsion of oil and ink, but is not limited to.

Method 1 forms the composition substitute as follows:

1. The choice of durable (key) agent from the list of natural and modified polysaccharides, including , pectin, alginate, 'gellan, agar-agar, , xanthan gum, guar, resin fruit of the carob tree, Tara, fenugreek, starch, carboxymethylcellulose, methylcellulose, HPMC (hydroxypropyl methylcellulose), propylene glycol alginate or combination of them-from 0,1% to 10%, replacing Arabic gum or using the end application at a level equivalent from about 0.1 to 10% of the amount of gum Arabic, which typically would be used (regardless of whether gum Arabic in this case or not) where these durable film formers may have different molecular weight and viscosity;

2. If you want to improve functionality, low viscosity is used cracking machines ingredient, which normalizes the viscosity changes crystallization and structure of cracking the key plenkoobrazovatelja according to paragraph 1 above, including, including, maltodextrin, monosaccharides, disaccharides, oligosaccharides, larch resin, or their combination, which is selected depending on the application sugar in the process or where an ingredient or a combination of them can be used at concentrations ranging from 0% to 99,9%;

3. If you want to improve the functionality of gum Arabic Acacia Seyal or, respectively. Acacia Senegal is added ingredient rapid crystallization, which may also play a role agent, consisting, among others, of inulin, , low maltodextrine DE, lactose or a combination of them in concentration from 0% to 99,9%; and

4. If you want to enhance the functionality while covering, modifier is added stickiness, consisting, including substances such as starch, guar gum, resin fruit of the carob tree or a combination thereof, from about 0% to 10%, where this ingredient can have a different molecular weight and viscosity.

Method 2 forms the composition of the substitute in the following stages:

1. The choice of durable agent from the list of natural and modified polysaccharides, including, including, , pectin, alginate, 'gellan, agar-agar, , xanthan gum, guar, resin fruit of the carob tree, containers, fenugreek, starch, carboxymethylcellulose, methylcellulose, HPMC (hydroxypropyl methylcellulose), propylene glycol alginate or combination of them-in number from about 0.1 to 10%, replacing Arabic gum or using the end application at a level equivalent from about 0.1 to 10% of the amount of gum Arabic, which typically would be used in this case (regardless of whether gum Arabic in this case), where such a rugged foaming agent can have a different molecular weight and viscosity;

2. Adding emulsifier, such as propylene glycol alginate; starch; resin, modified suktsinatom; mono - and diglycerides, lecithin soy proteins or their combinations, quantity from 0,1% to 25%; and

3. Adding polysaccharide, such as maltodextrin, larch resin, , inulin, or a combination thereof, used at concentrations ranging from 50% to 99.9%, to reach its use as gum Arabic or reducing the use of gum Arabic with the equivalent functionality in some important areas .

Method 3 forms the composition substitute as follows:

1. The choice of anionic polysaccharide, for example, xanthan gum, sodium carboxymethyl cellulose, , alginate, gum ghatti, resin brown or combinations thereof in a quantity from 0,1% to 10%;

2. Adding emulsifier and surface-adhesive modifier in the form of propylene glycol alginate; enriched emulsifier Arabian gum, modified suktsinatom; soy lecithin, or a combination thereof, in amount of 0.1% to 25%; and

3. Adding and sustainable to the solvent polysaccharide, such as maltodextrin, larch resin, inulin, , or a combination of about 65% to 99.8%.

Stage 2 comprises a test songs substitute for gum Arabic by specific end-uses: (1) composition substitute for method 1, called as a substitute standard 1, the corresponding Acacia Seyal, fast durable substitute 1 and substitute 1 from natural substances used in chewing gum, sealed and customary causing icing sugar on peanuts and lozenges; (2) the composition of the substitute method 2, called the substitute 2, have been tested food additives and applying a brilliant film; and (3) the composition of the substitute of the mode 3-called substitute 3, were tested for durability in the aqueous phase lithographic solution.

Table 1 illustrates the size of the flakes at 40 degrees brick for Acacia Seyal, Acacia Senegal, the mixture Seyal-Senegal and substitute of gum Arabic, obtained by the method 1 spill thickness of 5 and 10 mm on the surface of the plate.

Width, mm

Length, mm

Acacia Seyal, 100%

Acacia Seyal/Senegal, 50:50

Acacia Senegal, 100%

Substitute 1

Quick substitute 1

Quick substitute 1 from natural raw material

Example coating chewing gum:

In this example, gum Arabic compared with standard substitute 1 and fast substitute 1. Recipe syrup included 64,5% maltilol, 3.5% of binder (regulator or a substitute of gum Arabic) and 32% of water. Resin were first added to the water and were heated to about 82 o With before was added powdered maltitol. Then syrups were brought to a boil, brought up to 70 degrees Brix, 68° BRICs, 60 degree BRICs for measuring viscosity at 60 degrees C and 25 degrees C. Using the coating drum with a diameter of 18 inches, syrups 60° BRICs containing gum Arabic or substitutes used for coating and compared the characteristics of adhesion/stickiness and drying. Finished products coated chewing gum wrapper around from 32,4 to 32.6% were are in a state of equilibrium in a damp cell for about 16 hours at 35 C and 12% relative humidity and were tested on the strength of the casing, using THE analyzer XT Plux Texture Analyzer with a needle probe, with a speed test 1 mm/s at 50 parts of chewing gum as sampling.

Viscosity syrups - all match each other for gum Arabic and substitutes, as shown in table 2. Table 2 presents viscosity syrups maltilol containing gum Arabic and substitute at temperatures application of 25 C and 60 C and different values of degrees Brix. In addition, it was found that the higher the viscosity of the syrup can contribute to the bonding of the centers together and the appearance of uneven surface and, therefore, is undesirable. Therefore, different compositions substitutes have been standardized in order to issue the same viscosity and adhesion, as gum Arabic, except that in the fast substitute 1 stickiness was reduced to facilitate the application of coating.

Table 3 includes reports of an experimental batch application cover the chewing gum with 18-inch dryer coating (lot size 1000 g; powder-maltitol; rear syrup at a temperature of 60 Degrees; the size of the centre of 1,0 cm x 2.1cm; drying time after the free flow - 2.5 minutes).

Table 4 includes reports of an experimental batch application coverage of chewing gum with 18-inch dryer coating (lot size is 700 g; powder-maltitol; the size of the centre is 1.2 cm x 1.9 cm; drying time after the free flow of 2.5 minutes).

As shown in tables 3 and 4, Standard substitute 1 has the same drying time, and gum Arabic. Quick substitute 1, which contains the ingredient rapid crystallization, showed a more rapid drying of the coating of syrup, demonstrating that, if necessary, crystallization and drying covering syrup, based on the standard composition substitute, you can manage and improve compared with . In the process, as long as coating, it is recommended to reduce drying time, which experts estimate could be reduced by 5-10%, using the open car for coating. At the same time improving the color is achieved using substitutes, both of which have more bright white color. Gum Arabic has a natural brown color that goes into the shell cover, in particular, if the gum is covered with a transparent layer.

Table 5 presents comparative hardness sugar shell chewing gum gum Arabic (Acacia Seyal), standard substitute 1 and quick substitute 1. The hardness of the sugar shell chewing gum in table 5 shows a comparable or greater value of the destructive efforts to substitute compared with . Quick substitute 1, which contains the ingredient rapid crystallization, even when it is used in 2/3 parts of gum Arabic, shows strength, quite comparable with the strength of the shell basics №1. When used for the same purpose in the basis of chewing gum №2, quick substitute 1 shows a much higher destructive force compared with and standard substitute 1, improved functionality, which is achieved by adjusting the basic composition.

Maltitol-gum Arabic

Maltitol is a standard sample 1

Maltitol is a quick sample 1

Basics#1 [1,0 cm x 2.1 cm]

The average standard

Deviation

Base #2 [1,1 cm x 1.9 cm]

Standard. Deviation

* 2/3 of use in syrup

Example seals peanuts: in this example were tested for sealing peanut substitutes gum Arabic, providing oil barriers and oxygen, using syrup 40 degrees BRICs 3 download with and without means, but when drying a layer between the operations of the application of syrup. Viscosity of these syrups are shown in table 6, illustrating the viscosity syrup 40 degrees BRICs compared with and substitutes 1 and 2. These viscosity quite comparable with viscosity of Acacia Seyal and Acacia Senegal. Used tool was 50:50 mixture of cocoa and sugar powder. Compared drying time, and condensed peanut was subjected to sensory analysis after 2 months of storage in a sealed plastic vessel.

Resin (40 Degrees Brix

Medium viscosity at 25 C, in

Medium viscosity at 60 degrees C, in

Gum Arabic, Acacia Seyal

Gum Arabic, Acacia Senegal

Standard replacement 1

Quick substitute 11

Substitute 1 on the basis of the natural raw material

Table 7 compares the seal peanut and substitute 1, using batch weighing 1000 g; loading of syrup weight-10 g; mixture of flour and cocoa powder in a ratio of 50:50 weight-10, As shown in 7, drying times were comparable to the gum Arabic and standard substitute 1. However, the rapid replacement 1, containing the ingredient rapid crystallization, shows a much shorter drying times. In addition, he defended the peanuts from oxidation and rancidity as the best plenkoobrazovatelem.

Seal syrup

Download #

Time to flow, minutes

The drying up of the next boot, minutes

Average of the 3 tests

Average of the 3 tests

Syrup with 40% of gum Arabic

with means

with means

With means

The total number of

Without tools

Without tools

Without tools

The total number of

Touch sensation (after 2 months)

The rancid smell

standard sample 1 - 40% syrup

With means

With means

With means

The total number of

Without tools

Without tools

Without tools

The total number of

Touch sensation (after 2 months)

Small rancid smell

standard sample 1 - 40% faster syrup

With means

With means

With means

The total number of

Without tools

Without tools

Without tools

The total number of

Touch sensation (after 2 months)

Lack of rancidity smell

Example pastilles: in this example, the party of pastilles were prepared without gum, with (Acacia Seyal), with a standard substitute 1, fast substitute 1 and substitute 1 from natural raw materials used in the compositions below. Table 8 describes the compositions pastilles.

Regulation (without the gum Arabic)

With Acacia Seyal

Co standard pattern 1

With quick sample 1

Sample 1 from the natural raw material

Corn syrup

Citric acid

Malic acid

. connection

Resin system

In this example, water and corn syrup were first introduced in the dryer for coating. Sugar and resin as a dry mixture were added to the download with stirring. Then the mixture was heated to approximately 148 to 150 C, the heating was turned off, and were added acids and flavourings. Still liquid and hot confectionary syrup poured into the molds. When candy , they were placed in the camera on a wet night at about 12% relative humidity, Packed and chilled to prevent drying. Hardness of candy measured using the Texture Analyzer THE XT.

Standard substitute 1, quick substitute 1 and substitute 1 from natural raw materials increased hardness of candy on the same level or even slightly higher than gum Arabic (Acacia Seyal), compared with lollypops without resin. In terms of color gum Arabic seemed darker than substitutes. Table 9 includes the hardness values of the dice pastes produced with and with substitutes compared to control candy only with sugar; the average was solved 2 test and 6-20 repetitions in each test.

Hardness of candy from the point of view of efforts in grams necessary for splitting, is given in the table. As shown in table 9, control candies with only one sugar and gum Arabic have the lowest value of hardness. Lollipops with standard substitute 1 and fast substitute 1, showed comparable or slightly higher values of hardness in comparison with .

Samples lozenges

Distance 1

Control [no resins, only sugar]

Average value

11396±1552

With

Average value

12436±2098

With a standard substitute 1

Average value

12886±2173

With the rapid substitute 1

Average value

13336±2469

With substitute 1 from natural raw material

Average value

12904±2353

Table 10 includes emulsion orange oil for spray drying compared with and substitutes of gum Arabic with different emulsifiers. Thus, table 10 shows viscosity and type of emulsion prepared with the control , substitute 2 with suktsinatom-modified emulsifier, substitute 2 with starch and substitute 4 with natural emulsifier. All emulsion't had signs of separation. Profiles Turbiscan are presented in figures 9A-9F. These curves have confirmed that all of the samples were steady during the first 5-6 hours. None of them showed the separation of water, in contrast to the sharp reduction or shift of the refractive index on the chart with time the figure 9F at the bottom of the sample tubes (from 0 mm up to 10 mm). Similarly, there was no stratification, in contrast to figure 9F, which shows humps about 40 mm Significant shifts within 2 hours in curves emulsions Turbiscan with a modified suktsinatom resin and emulsifying starch, probably arose not because of oil, and thanks foaming or a collapse of bubbles. Up to 18 hours a control emulsion Acacia Seyal showed signs of a bundle, which is proved by a surge of up to 40 mm on the curve Turbiscan or top layer in a test tube; then as Acacia Senegal and substitutes for this are not shown. However, since spray drying occurs in approximately 4 hours, from a technical point of view, all emulsion using gum Arabic and various substitutes for 2 have withstood the test for resistance by the standards of the food industry.

Acacia Seyal

Acacia Senegal

Sample 2 with , suktsinatom-

Sample 2 with modified suktsinatom-starch-emulsifier

Sample 2 with natural emulsifiers

Directly determined viscosity (about 45 degrees)With CP

4-hour viscosity (25-27 OC), centipoise

Type of emulsion in 4 hours

No stratification

No stratification

No stratification

No stratification

No stratification

View emulsion 24 hours

The layer of water at the bottom

No stratification

No stratification

No stratification

No stratification

An example of a food film with a glossy coating; in this example were prepared edible film with a glossy coating. Made film with a glossy glaze included Arabic gum Acacia Seyal, and in recipe film with a glossy glaze used formulations substitute method 2, containing 40% of gum Arabic, or substitute compounds containing 0.8% of glycerin and 59.2% of water. Gum Arabic was dissolved in water and glycerine at room temperature for 1 hour, then the solution is poured thickness of 10 mil, dried in a drying case at adjustable humidity of the order of 12% relative humidity, layer removed scraper and Packed. Were also tested on a larger scale, using gum Arabic song substitute with the added potassium as a separating agent. Layers, applied in bulk, had similar patterns for cracking Acacia Seyal, substitute 2 with modified suktsinatom an emulsifier and a substitute 2 from natural raw materials.

Figure 10A shows the glossy food glaze Acacia Seyal according to one example of the incarnation. Figure 10 shows the substitute 2 with modified suktsinatom, for food glaze in another incarnation. Figure 10 shows emulsifier food glaze substitute 2 of mineral raw materials in another incarnation. The figures 10A-10C shows the final samples gloss coating, very similar to each other on the glitz and the size of the flakes. Testing on a larger scale also show the same technological properties of gum Arabic and substitutes.

Example lithography

In this example, the lithographic solution, gum Arabic [Acacia Seyal] and various compounds substitute for method 3 was compared, using two methods of Association: (1) adding a powder (7.58 percent) directly in the lithographic solution (92,42%), and (2), preparing of 14 deg solution Baume and adding it (28,6%) in the lithographic solution (71,4%). The solutions were tested for the division for 1-10 days.

Very few or polysaccharides are comparable or sustainable in the water solution or dampening solution, and within 1 day form colloidal layer either at the top or at the bottom of the container. The best resistance noticed when using anionic resins, such as xanthan gum and carboxymethylcellulose, compared with other negatively charged that contain emulsifiers modified suktsinatom resin. When you use method 3 was not noticed by any separation in part a substitute after 10 days irrespective of a way of mixing.

Although the present invention is described and illustrated with drawings with some degree of specificity, it is clear that the disclosure of the invention made an example only, and that the experts in this field can make numerous changes without leaving the essence and scope of the invention.

1. Method of preparation of compositions substitute gum Arabic, which in aqueous solution durable plenkoobrazovatelja, selected from the group consisting of carboxymethyl cellulose, hydroxypropyl methylcellulose, alginate, , pectin, agar-agar, xanthan gum resin, 'gellan, , fenugreek Greek, packagings and their combinations, quantity from 0,1 up to 10% of the total mass of the ingredients in a solvent composition, successively added: - low viscosity cracking machines agent, selected from the group consisting of maltodextrine, monosaccharides, oligosaccharides, resin larch, and combinations thereof, in amount from 88.9 to 55% of the total mass of the ingredients in a solvent composition - agent rapid crystallization, selected from the group consisting of inulin, , low maltodextrine DE and their combinations in the amount from 10 to 25% of the total mass of the ingredients in a solvent composition, and the modifier stickiness, selected from the group consisting of starch, guar gum powder resins, gums carob beans and their combinations, quantity from 0,1 up to 10% of the total mass of the ingredients in a solvent composition.

2. The method according to claim 1, characterized in that the composition of the substitute of gum Arabic adapted for use in the coating process for confectionery, when , when , during strengthening of candy when linking and strengthening of sugar or sugar-alcohol coverage shell centres containing o-oil, when gluing of products of food and has a viscosity at concentrations of approximately 35-40 Celsius BRICs about 10 to 2000 JV with 25 degrees C.

3. Method of preparation of compositions substitute gum Arabic, which in aqueous solution durable plenkoobrazovatelja, selected from the group consisting of carboxymethyl cellulose, hydroxypropyl methylcellulose, , pectin, agar-agar, xanthan gum resin, resin guar'gellan, , fenugreek Greek, Tara, gums carob beans and their combinations, quantity from 0,1 up to 10% of the total mass of the ingredients in a solvent composition, successively added: - emulsifier, selected from the group consisting of propylene glycol alginate; emulsifying starch; resins, modified suktsinatom; mono - and diglycerides; soy lecithin; proteins and their combinations, quantity from 0,1 up to 25% of the total mass ingredients in a solvent composition, and - low viscosity polysaccharide, selected from the group consisting of maltodextrine, larch resin, , inulin and their combinations in the amount of 99,8% to 65% of the total mass of the ingredients in a solvent composition.

4. The method of claim 3, wherein the received composition adapted for replacement of gum Arabic in the formation of a shiny coating and food film on the products of food and spray dried food additives and has a viscosity at concentrations of approximately 35-40 Celsius BRICs about 10 to 2000 JV with 25 degrees C.

5. Method of preparation of compositions substitute gum Arabic, which in aqueous solution durable plenkoobrazovatelja, selected from the group anionic polysaccharides composed of xanthan gum, sodium carboxymethyl cellulose, , gum ghatti, resin and punish them combinations, quantity from 0,1 up to 10% of the total mass of the ingredients in a solvent composition, successively added: - emulsifier and surface-adhesive modifier, selected from the group consisting of: propylene glycol alginate; enriched emulsifier Arabian gum, modified suktsinatom; soy lecithin; and their combinations in the amount of 0.1 to 25% of the total mass of the ingredients in a solvent composition, and - low viscosity polysaccharide, selected from the group consisting of: maltodextrin, larch resin, inulin, and combinations thereof, in an amount of 99,8 to 65% of the total mass of the ingredients in a solvent composition.

6. The method according to claim 5, wherein the received composition adapted to replace the gum Arabic during formation of films in and printing and has a viscosity at concentrations of approximately 14 deg Baume about 10 to 900 CPS at 25 deg C.