Method of producing complex stabilisers for chlorine-containing polymers |
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IPC classes for russian patent Method of producing complex stabilisers for chlorine-containing polymers (RU 2400496):
 
 Rubber mixture on the basis of the ethylenepropylenediene caoutchouck / 2307134
The invention is pertaining to the field of the rubber industry, in particular, to the development of the receipts of the rubber mixtures on the basis of the ethylenepropylenediene caoutchouck with the heightened adhesion strength, which may find application at manufacture of the composite materials. The rubber mixture on the basis of 100 mass shares of the ethylenepropylenediene caoutchouck includes (in mass shares): sulfure -2, captax - 0.5, a thiuram - 1.5, the stearic acid - 1, zinc oxide - 5, industrial carbon PM75 - 50, the modifying agent of adhesion - the basic salt of calcium methyphosphite of the formula:
 Composition for obtaining foam / 2213752
The invention relates to compositions for the preparation of foam operated at temperatures up to 150oWith the increased requirements to the vibration, which can find applications in mechanical and aeronautical engineering
 Thermoplastic composition / 2206583
The invention relates to thermoplastic compositions based on polypropylene
 Polymer composite material / 2144050
 Polymer composition / 2131894
The invention relates to stabilized polymeric compositions based on polyolefins (polyethylene and its copolymers), and can be used to obtain a dyed materials with high resistance to light aging
 The method of stabilization of organic phosphite and/or phosphonite from the effects of hydrolysis and stable composition / 2119493
The invention relates to a method of stabilizing organic phosphite and/or phosphonite from exposure to hydrolysis by adding them sterically constrained amine containing group of the formula (II) or (III) where G is hydrogen, methyl; G1and G2is hydrogen, methyl or both together represent = 0, in an amount to provide content in stable organic phosphite and/or phosphonite of 0.1 to 25.0 wt.% the amine in the calculation of the organic postit and/or phosphonic
 Thermoplastic polymer composition / 2115675
 Polymer composition / 2078779
The invention relates to the field of composite materials based on lapola
 Phosphite additives to polyolefins / 2388771
Invention relates to polyolefins, particularly to phosphite additives to polyolefins. Described is a composition containing the following: polyolefin, highly active phosphite - arylalkyldiphosphite of formula
Rubber mixture / 2383566
Rubber mixture contains the following, in pts. wt: unsaturated carbon-chain rubber - 100, technical rubber P-324 - 30-60, quinol ether EK-1 - 3-7, cadmium stearate - 1.0-6.5.5.
 Vulcanising agents based on bisaminophenyl and vulcanising agents and vulcanisation accelerators based on amidine for perfluoroelastomer compositions / 2380384
Method involves: (a) reacting organic perfluoroalkyl acid with alcohol to form perfluoroalkyl ester; (b) reacting perfluroalkyl ester with ammonia to form fluorine-containing alkyl carboxyamide; (c) reacting fluorine-containing alkyl carboxamide with a dehydrating agent to form fluorine-containing alkyl nitrile; and (d) reacting fluorine-containing alkyl nitrile with at least ammonia or amine to obtain fluorine-containing amidine - vulcanising agent. Also described is a method of producing a vulcanising agent based on bisaminophenol, where the bisaminophenol vulcanising agent can vulcanise a perfluoroelastomer composition, and a method of producing a vulcanising agent based on a diphenyl compound with formula (III):
 Method of producing granules from additives to polymers, which form small amount of dust / 2375389
Additives to polymers which form granules are mixed with each other. The mixture is converted to a mass which is suitable for processing and is forced through a channel. The moulded filament-like extruded mass is cooled and, while still in processing state, it is moulded into granules by rolling plastic material with crush rollers and moulding rollers, where the distance between the rollers is regulated and the least distance determines the size of the granules, die moulding, cooling and crushing.
 Phenolic antioxidants in crystal form / 2362764
Invention relates to improved method of preparing solid particles used as phenolic antioxidants and including in, in fact, crystal form compound of formula:
 Synergetic combination of uv-rays absorbent / 2337113
Stabilising composition is described, containing (A) compound of 2,4-bis-(4-phenylphenyl)-6-(2-hydroxyphenyl)-1,3,5-triazine series by formula (I), and (B) one or more compounds chosen from group, which include benzotriazoles by formula (IIa), 2-hydroxybenzophenones by formula (IIb), oxanilides by formula (IIc), 2-hydroxyphenyltriazines by formula (IId), cinnamates by formula (IIe), and benzoates by formula (IIf). There are also described: composition, containing stabiliser composition and organic material; method for organic material stabilisation; and application of stabiliser composition to organic material stabilisation.
Rubber-bitumen mastic / 2323231
Invention relates to rubber-bitumen mastic containing bitumen, rubber crumb, plasticizer, and extender and is characterized by that mastic further contains butadiene-nitrile rubber (92.5-4.0%) and maleic anhydride (2.0-2.5%) and by that, as plasticizer, liquid fraction of liptobiolite coal resin with boiling temperature above 230°C and, as extender, talc are used in concentrations 20.0-30.0% and 22.5-35.0%, respectively, while bitumen represents the rest of the mastic.
Thermoplastic elastomer composition and improved rubber granulation process / 2316569
Invention relates to thermoplastic elastomer composition for manufacturing products such as films, which composition contains dynamically curable mixture of (A) halogenated isobutylene/p-methylstyrene copolymer, (B) polyamide, and (C) antioxidant having melting point above 70°C and below 200°C, granulated elastomer (A) obtained by granulation in presence of antioxidant (C) as granulator being dispersed as a domain in the continuous phase of polyamide (B) and composition containing (A) and (B) components being dynamically cured. Thus obtained film is characterized by better stretching than film made from composition containing curing agent as granulator and by excellent durability and stability at low temperature as compared to film made from talc-containing composition.
Polymer composition / 2315789
Invention relates to polymer compositions based on unsaturated polyester resins utilized to obtain filling, impregnation, and molding materials widely employed in manufacture of products in electronic and radio industries, in automotive industry, in construction, and other areas. Composition according to invention contains, wt parts: unsaturated polyester resin 100, epoxide dian resin 50-100, aliphatic amine 18-20, and hexachloro-p-xylene 2.0-2.5. If needed, composition may further contain filler up to 250 wt parts and/or special-destination additives up to 10 wt parts.
 Polyvinyl chloride-base composition / 2313543
Invention proposes a composition comprising polyvinyl chloride, dioctyl phthalate as a plasticizing agent and 4,4'-di-(2,3-epoxypropoxy)-diphenyl as a stabilizing agent taken in the amount 0.3-0.5 mas. p. per 100 mas. p. p. of polyvinyl chloride. Using 4,4'-di-(2,3-epoxypropoxy)-diphenyl as a stabilizing agent allows enhancing stability of material made of this composition to effect of light and heat and to simplify the composition formula. Proposed composition can be used in preparing film materials and artificial skin.
Polyurethane coating composition / 2391362
Invention relates to polyurethane composition used as a protective coating. The composition contains the following in pts. wt: 770 - polytetramethylene etherglycol with molecular weight of 1950, 200 - 4,4'-diphenylmethanediisocyanate, 80-100 - dimethylformamide, 36 - hydroxyl-containing compound, 100-120 - methylphosphite borate and 15-18 - glycidalmethacrylate. A prepolymer is synthesised first as an initial component by reacting polytetramethylene etherglycol and 4,4'-diphenylmethanediisocyanate in molar ratio OH:NCO-groups equal to 1:2.
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FIELD: chemistry. SUBSTANCE: carboxylic acids are reacted with oxides and/or hydroxides of Zn and Ca metals in the presence of glycerin, ionol, epoxidated soya oil, epoxy resin, diphenylol propane, phosphite NF while heating, in which the complex stabiliser is obtained through reaction of carboxylic acids with oxides and/or hydroxides of Ca, Zn, Mg, Al in the presence of glycerin and additives selected from ionol, epoxidated soya oil, epoxy resin, diphenylol propane, phosphite NF, diphenyl-n-butylphosphite, PES-5 polyethylsiloxane liquid, Penta-1006 or Penta-1005 plastic modifier, calcium stearate while heating, in which the carboxylic acids used are oleic acid, 2-ethylhexane acid, α,α'-branched C10-C26 monocarboxylic acids. The carboxylic acids are first reacted with oxides and/or hydroxides of Zn, Ca, Mg, Al and glycerin at 140-180ºC to obtain a mixture consisting of salts of carboxylic acids and glycerin monoether of carboxylic acid, and an additive is added to the reaction mass only when acid number not greater than 5 mg KOH/g is reached. The process is carried out in the following ratio of components, wt %: carboxylic acids 6.3-60.4; oxides and/or hydroxides of metals 1.2-8.3; glycerin 8.5-20.4; additives - the rest. EFFECT: simplification of the technological process of producing complex stabilisers of chorine-containing polymers, cutting on the number of technological operations, higher environmental safety of the process owing to prevention of formation of wastes and wider range of non-toxic complex stabilisers of chlorine-containing polymers. 2 cl, 27 ex, 3 tbl
The invention relates to organic chemistry and chemistry of polymers, in particular an improved method for obtaining complex stabilizers for chlorine-containing polymers may be used in the processing compositions of chlorine-containing polymers such as polyvinyl chloride, chlorinated polyvinyl chloride, copolymers of vinyl chloride etc. in various products (film materials, cable compounds, building materials, pipes and so on). The main requirements to the above polymeric materials are sufficiently high thermal stability, high resistance to light aging, low initial yellowness products, good processability of the materials. It is known that for processing chlorine-containing polymers necessary stabilizers destruction. In the practice of stabilizing chlorine-containing polymers in the composition administered to five or more components, slowing decomposition and reporting PVC number of properties, in particular, for these purposes, use salts of carboxylic acids, epoxysilane, organic phosphites, antioxidants and other The ideal stabilizer for PVC shall perform the following functions: to connect eye-catching HCl to inhibit (inhibit) the oxidation reaction, stapling, to protect the double bond in the PVC chains, to absorb ultraviolet radiation. Realizalasa these functions can only be achieved through the use of complex stabilizers [K.S. K.S. Minsker, Fedoseeva G.T. Degradation and stabilization of PVC. M.: Chemistry, 1972, 424 S.]. A method of obtaining stabilizers of polyvinyl chloride interaction of stearic acid or synthetic fatty acids7-C21with metals or their oxides or hydroxides, or salts in the presence of plasticizer. According to this method can be obtained as individual metal salts of fatty acids and their mixtures [USSR Author's certificate No. 413854, CL. SS 53/24, publ. 1971]. However, are effective stabilizers consisting of a mixture of metal-containing stabilizers-salts of fatty monocarboxylic acids and additives: antioxidants, lubricants, light stabilizers and other A method of obtaining complex stabilizers chlorine-containing polymers [USSR Author's certificate No. 2084472, CL. C08L 27/04, SC 13/02, publ. 1997], including the organic compound on the basis of a carboxylic acid and an additive, where the carboxylic acid is used arilsulfonilglitsinov acid, selected from a range that includes benzosulfimide acid, toluensulfonate acid, kilonardodicaprio acid, chlorobenzalmalononitrile acid, and as an additive, a mixture of calcium oxide and zinc stearate, or a mixture of lead oxide and calcium stearate. Advanced integrated with habilitator contains 4-8 parts by weight of maleic anhydride per 100 parts by weight of a Complex stabilizer is obtained by mixing the components first in the mixer at a temperature of 90-95°C for 25-30 min, then the composition ekstragiruyut on extrusomes at 160-165°C. To obtain the integrated stabilizer are difficult, expensive carboxylic acid. A method of obtaining complex stabilizer for chlorine-containing polymer interaction zinc oxide and calcium hydroxide in the presence of water first with a synthetic fatty acid (FFA) fraction of C17-C25at a temperature of 45-55°C for 90-120 min, drying the formed soosazhdennykh salt and mix them with pentaerythritol, diphenylolpropane or xilitla and teenliterotica [USSR Author's certificate No. 1809600, CL. SS 51/41, SC 5/11, 1996.] The disadvantage of this method is the complexity, the complexity and the multi-stage process, the presence of a stage of drying the formed soosazhdennykh salts of fatty acids. Closest to the claimed is a method of obtaining complex stabilizers for polyvinyl chloride by reacting a mixture of oxides and/or hydroxides Cd, Ba, Pb, Ca, Zn with carboxylic acid fraction With7-C20or their anhydrides at a temperature of 60-140°C in the presence of additives, intensifying the process of Salobre the Finance, such as glycerin, triethylene glycol, cyclohexanone, acetic acid, dioctylphthalate, acrylate, ether, triethylene glycol phthalic and methacrylic acids, diphenylolpropane, BHT or water, or epoxydecane soybean oil, epoxy resin, 2-ethylhexyladipate, Tris(nonylphenyl)pofit or chalk, wax, titanium dioxide, pigment paste. [USSR author's certificate No. 601276, SS 51/52, C08L 27/06, publ. 23.03.1978,] The disadvantages of this method are: the use of a large number of activators salt formation, mainly various plasticizer is dioctylphthalate, ether, triethylene glycol and methacrylic acid, in which the synthesis conditions (heating, water availability) salts of carboxylic acids by the interaction of the acid with oxides and hydroxides are alkaline hydrolysis accompanied by the accumulation of acidic products, which certainly has a negative effect on thermal stability and initial color polymer products, the complexity of the technological process, the presence of multi-component download, interleaving multiple stages of heating and cooling, the use of compounds of toxic metals such as Cd, Ba, Pb, which are increasingly limit in the application for environmental reasons, to obtain a liquid stabilizer (example 5) using solvent is cyclohexanone, which is then distilled off by azeotrope with water, at the end of the synthesis of complex stabilizer emit from the precipitate by decantation, which together leads to the formation of waste products. The purpose of the invention is to simplify the technological process of production of complex stabilizers, improving quality, expanding the range of complex non-toxic stabilizers chlorine-containing polymers. The essence of the invention lies in the fact that the complex stabilizer is produced by the interaction of carboxylic acids with oxides and/or hydroxides of CA, Zn, Mg, and Al in the presence of glycerol and additives selected from BHT, epoxidizing soybean oil, epoxy resin, diphenylolpropane, phosphite NF, diphenyl-n-butylphosphate, polyethylsiloxane liquid brand PES-5, modifier plastics brand Penta-1006 or Penta-1005, calcium stearate, when heated, in which the carboxylic acids used oleic, 2-ethylhexanol, α,α'-branched monocarboxylic acid fractions With10-C26first carboxylic acid is subjected to interaction with oxides and/or hydroxides of Zn, CA, Mg, A1 and glycerin at a temperature of 140-180 ° C to obtain a mixture consisting of salts of carboxylic acids and monoether glycerin carboxylic acids, and acid number of the reaction mass does not exceed 5 m in the KOH/g in the reaction mass of injected additives, moreover, the process is carried out at the following ratio, wt.%:
As additives used epoxydecane soybean oil, epoxy resin grades: ED-20 ED-16 (GOST 10587-84), the epoxy resin chlorinated "Oxilan-6 (TU 6-02-1376-87), BHT, diphenylolpropane, tennispalatsi (postit NF), diphenyl-n-butylphosphate, calcium stearate, polyethylsiloxane liquid brand PES-5 according to GOST 13004-77, or modifiers plastic brands: Cat-1006, or Penta-1005 (TU 2257-204-40245042-2007). Penta-1006, Penta-1005 is a composition based polyorganosiloxane. PES-5 polyethylsiloxane liquid, a mixture of polymers predominantly linear structure, with a kinematic viscosity of from 200 to 500 cSt. Epoxy resin brand ED-16 is an oligomeric product on the basis of epichlorohydrin and diphenylolpropane, with mass fractions of epoxy groups of 16-18%. Epoxy resin brand ED-20 is the way the second oligomeric product on the basis of epichlorohydrin and diphenylolpropane, with a mass fraction of epoxy groups 20-22,5%. Oxilan-6 is an oligomeric product of polymerization of epichlorohydrin in the presence of glycerol and subsequent dehydrochlorination the hydrate of sodium oxide obtained polyester. For complete integrated stabilizer using α,α'-branched monocarboxylic acid fractions acids With10-C26on THE other 2431-200-00203312-2000. Feature of the proposed method to obtain complex stabilizer is that pre-receive a mixture consisting of salts of carboxylic acids and monoether glycerin carboxylic acid, by reacting oleic or 2-ethylhexanol or VIC fraction10-C26with mixtures of oxides and/or hydroxides of CA, Zn, Mg, Al and glycerin at a temperature of 140-180°C. and acid number of the reaction mass is not more than 5 mg KOH/g enter the additives contributing to the stabilizing and improving the complex distribution of the stabilizer in the compositions of chlorinated polymers. Use in the compositions and complex stabilizers of these components in specific amounts, helps to improve the overall properties of the compositions of chlorine-containing polymers, namely to improve thermal and svetostoyjkostj, melt. Suggested usage : the BA allows you to: to simplify the process of obtaining complex stabilizers chlorine-containing polymers, which consists in reducing the number of technological operations; - to improve the environmental safety of the process by eliminating waste; to expand the range of non-toxic complex stabilizers chlorine-containing polymers. The essence of the invention is illustrated by the following examples. Example 1 (invention) In a three-neck flask equipped with stirrer, thermometer, nozzle Dean-stark pipe for blowing nitrogen, placed in an oil bath, load 59.3 g of oleic acid, of 9.8 g of glycerin, 2.9 g of ZnO, 1.4 g of MgO. The process is conducted under stirring at a temperature of 160°C to reach an acid number of the reaction mass 2.4 mg KOH/g, then the reaction mass is then cooled to a temperature not higher than 100°C, added to 4.2 g of diphenylolpropane and 17.5 g of epoxy resin ED-16, 4.9 g of tennispalatsi. A lot intensively stirred. The finished product is unloaded. The product yield is 99%. Examples according to the invention 2-26 syntheses carried out, analogously to example 1, using all the techniques and operations, in the same sequence. The components of the stabilizer, the synthesis conditions, are shown in table 1. Complex stabilizers in appearance is a homogeneous W is dcost light brown color. To determine the effectiveness of integrated stabilizers prepare the polymer composition of the following composition, parts by weight: PVC - 100, integrated stabilizer - 5, are mixed in a laboratory mixer at a temperature of 80°C for 30 minutes, then get the film on a roll mill at 180°C for 5 minutes. The stabilizing effect of the received complex stabilizers appreciate the time thermal stability of the polymer films according to GOST 14041-80 at 160°C, and fade resistance - time before the appearance of the paint film at 180°C, assessed visually. The melt flow index (MFR) determined according to GOST 11645-73 (Plastics. Method of determining the melt flow index of thermoplastic) on the device IIRT-1M. The composition and test results are stable complex stabilizers chlorine-containing polymer compositions are presented in tables 2-3. For reference, here is the stabilizer obtained in example 4 prototype as more similar in composition to declared.
1. The method of obtaining complex stabilizers of polyvinyl chloride by reacting carboxylic acid with oxides and/or hydroxides of the metals Zn, Ca in the presence of glycerol, BHT, epoxidizing soybean oil, epoxy resin, diphenylolpropane, is Osvita NF when heated, characterized in that the complex stabilizer is produced by the interaction of carboxylic acids with oxides and/or hydroxides of Ca, Zn, Mg, and Al in the presence of glycerol and additives selected from BHT, epoxidizing soybean oil, epoxy resin, diphenylolpropane, phosphite NF, diphenyl-n-butylphosphate, polyethylsiloxane liquid brand PES-5, modifier plastics brand Penta-1006 or Penta-1005, calcium stearate, when heated, in which the carboxylic acids used oleic, 2-ethylhexanol, α,α'-branched monocarboxylic acid fraction10-C26first carboxylic acid is subjected to interaction with oxides and/or hydroxides of Zn, Ca, Mg, Al and glycerin at a temperature of 140-180°C to obtain a mixture consisting of salts of carboxylic acids and monoether glycerin carboxylic acids, and acid number of the reaction mass is not more than 5 mg KOH/g in the reaction mass of injected additives, and the process is carried out in the following ratio, wt.%:
2. The method according to claim 1, characterized in that as the epoxy resin used epoxy resin grade ED-20 or ED-16 or epoxy resin chlorinated "Oxilan-6".
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