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Procedure for depletion of solid copper-zinc slag. RU patent 2398031. |
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FIELD: metallurgy. SUBSTANCE: invention refers to procedure for depletion of solid copper-zinc slag. The procedure consists in supply of charge containing solid copper-zinc slag and carbonic reducer at weight ratio of slag to solid carbonic reducer 1: (0.06-0.1) into heated furnace. Also charge in the heated furnace is blasted with oxygen containing oxidant by means of upper not-immersed blast; consumption of oxygen-containing oxidant is determined by contents of oxygen in it from condition of 60-110 kg per ton of slag. Further there is produced a rich with copper phase and zinc is transferred into a gas phase. EFFECT: simplification of process of solid copper-zinc slag depletion. 1 tbl, 1 ex
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Method of processing vanadium containing converter slag / 2385353 Method consists in crumbling, in oxidising annealing converter slag with production of ash, in leaching vanadium from ash with solutions of alkali and in extracting vanadium salts from vanadium solution. Converter slag containing reverse manganese additives over 20 % MnO, preferably 25-27 %, at ratio of manganese to vanadium equal to 1.5-1.7 is annealed during 1.0-1.5 hours at temperature 800-850°C, further vanadium is selectively leached from ash with solution of alkali at presence of carbon dioxide gas at mole ratio CO2: Na=0.5-1 or vanadium and manganese are collectively leached at pH 1.5-2.5 with sulphuric acid or spent electrolyte after production of electrolytic manganese dioxide and are extracted from solution of vanadium and manganese salts. |
Method of processing disintegrating metallurgical ladle slag / 2383635 Disintegrating metallurgical ladle slag treatment consists in extraction of metal inclusions out of disintegrated slag by method of magnet separation; upon extracting metal inclusions out of disintegrated slag particles of dimension over 5 mm are removed. The rest of slag is crumbled in a ball mill thereby producing particles of less 0.1 mm dimension; further, slag is pelletised interacting with water at amount 10-15% of slag mass. |
Reprocessing method of metallurgical slags and process line (versions) for its implementation / 2377324 Invention relates to ferrous metallurgy field, particularly to reprocessing of metallurgical slag, used in building industry, particularly in highway engineering, in concreting and others, to receiving or enrichment of magnetic iron-containing product, used in blast-furnace melting for changing of iron-ore raw material, in melting of steel and at manufacturing of agglomeration. |
Reprocessing method of manganous waste slags / 2374336 Invention relates to the ferrous metallurgy field, particularly to reprocessing of waste slags from manufacturing of manganese and siliceous ferroalloys for extraction from it of manganese and siliceous ferroalloys of high grade by content of phosphorus. In method there are mixed manganous waste slags and slag from manufacturing of ferrosilicon and is implemented reduction of oxides of manganese and silicon carbide, presenting in slag from manufacturing of ferrosilicon, herewith amount of silicon carbide in mixture of slags for 10-50% more than it is required by stoichiometry for total reduction of manganous oxide. |
Method of continuous or periodical receiving of metal or several metals from slag, containing specified metal or compound of specified metal / 2371490 Invention elates to method of continuous or periodic receiving of metal or several metals from slag, containing specified metal or compound of specified metal. Method includes heating and melting of liquid metallic slag in primary or secondary melting mill, implemented in the form of electric furnace of alternating current. From primary or secondary melting mill melt of slag is fed into electric furnace of direct current. In this furnace it is implemented electrolytic deposition of extracted metal. Additionally into primary or secondary melting mill it is fed and/or injected restorative in the form of silicocalcium (CaSi), calcium carbide (CaC2), ferrosilicon (FeSi), aluminium (Al) and/or gaseous restorative. |
Method of processing final tailings / 2370551 Final tailings are leached with circulating concentrated hydrochloric acid at boiling temperature of hydrochloric pulp of 103-109°C thereby producing gaseous mixture of water vapours, hydrogen chloride and hydrochloric acid solution containing titanium, vanadium, iron, chromium, manganese and cake. Produced cake is washed and dried; so final product is obtained in form of concentrate of silicon oxide. The following compositions of metals are extracted by selective sedimentation out of obtained hydrochloric acid solution in three stages: titanium hydroxide, hydrated vanadium pentaoxide, mixture of iron and chromium oxides and basic manganese carbonate. Vapour-gas mixture of water and hydrogen chloride formed in each stage of metal composition extraction is condensed producing circulating hydrochloric acid. The acid is used for washing sediments of metal compounds and for leaching of source final tailings. |
Method and installation for extraction of metal from slag containing this metal / 2368673 Extraction method of metal from slag containing this metal includes heating of liquefied metallic slag in the first furnace, implemented in the form of alternating-current electric furnace, and transfer of melt from the first furnace into the second furnace, implemented in the form of alternating-current electric furnace. Installation includes the first alternating-current electric furnace with submersible electrodes and the second alternating-current electric furnace with located horizontally in top and bottom field of melt by electrode plates, connected by means of melt transfer from one furnace into other, the second furnace is outfitted by electromagnets for providing of mixing of melt. |
Mobile installation for granulating slag breakage / 2366734 Mobile installation for granulating slag breakage consists of transported removable platform whereon there are assembled at least facility for selection of slag breakage located above feeding hopper, granulating devices fed with slag breakage from feeding hopper, reservoir-storage for granulating water phase feeding granulating devices with water phase, power source and means of control over said components. |
Method of recycling of steelmaking slag / 2365642 Invention relates to multipurpose use of the raw material in ferrous metallurgy, in particular to the methods of recycling of steelmaking slag. The method involves extraction of large pieces of scrap metal from the steelmaking slag, screening and seperation of nonmagnetic slag with size of 0-50 mm, sieving of the nonmagnetic slag with size of 0-5 mm, crushing of the oversised material followed by screening with size of 0-5 mm and pneumatic classification seperating the pieces by their sizes: large pieces are 5-0.5 mm, small pieces are 0.5-0.16 mm and dust is 0.16-0 mm followed by pneumatic classification of the large and small pieces and their dry magnetic seperation. |
Processing method of aluminium-containing slags / 2362819 Invention relates to processing methods of slag for aluminium smelting and its alloys, and also to production methods of construction materials and inorganic matters, particularly to technology of receiving of basic aluminium chloride. Processing method of aluminium-containing slag, containing aluminium nitride, includes water cleaning of soluble metals salt with regulation pH pulp. Additionally water cleaning is implemented with blowing of pulp by carbon dioxide up to receiving of meaning pH 7.0-7.5. |
Method of processing of iron-titanium concentrate / 2385962 Method includes formation of charge consisting of concentrate and sodium carbonate by means of intergrinding of components and reduction of charge components at presence of taken with excess carbonaceous reducing material at temperature 850-1300°C. Additionally batch material reduction is implemented up to providing of content of metallic iron in the range of particles dimensions 10-300 mcm not less than 80%. Received partly reduced conservative mass, consisting of metalise phase containing main part of iron and vanadium and oxide phase, containing main part of titanium and vanadium, it is grinned up to size not more than 300 mcm. Then it is implemented leaching of vanadium from reaction mass and leaching residue is separated from vanadate solution. After separation residue of leaching is subject to gravitational separation in water flow with separation of metalised and oxide phases. Metalised and oxide phases are separately subject to wet magnetic separation for receiving of metallic iron and titanium oxide concentrate. Additionally wet magnetic separation is implemented in the range of field intensity 20-300 E. |
Reduction method of metal and oxygen compositions / 2360982 At reduction of metal and oxygen composition effect as reducer, herewith at first stage gaseous CO is passed into reaction chamber, containing specified composition of metal and oxygen. In conditions, providing conversion of CO into solid carbon and carbon dioxide, formed solid carbon is introduced into metal and oxygen composition. At the second stage solid carbon, which is introduced into metal and oxygen composition at the first stage, reduces metal and oxygen composition. Additionally at the second stage it is, at least, the first material- promoter, conducive reduction of specified metal and oxygen composition. Additionally the first material- promoter contains the first metal- promoter and/or composition of the first metal- promoter. |
Method of tin manufacturing from cassiterite concentrate / 2333268 Invention concerns tin metallurgy field and can be used for tin manufacturing while treatment of cassiterite concentrates. Method of tin manufacturing from cassiterite concentrate with content of 35-50% SnO2 includes batch preparation by blending of tin concentrate with coal and flux additive. In the capacity of flux additive it is used sodium carbonate and sodium nitrate. Melting is implemented at temperature 850-1000°C during 2 hours. For mentioned concentrate it is kept up following mass ratio: concentrate : coal : sodium carbonate : sodium nitrate, equal to 1 : (0.2-0.25) : (0.12-0.15) : (0.06-0.08). It allows without concentrate pretreatment to provide tin manufacturing of 98% purity at less in comparison with tradition approach, temperature. |
Method of reduction of metal oxides / 2317342 Charge in form of mixture of oxides and reductant is fed to heated furnace and is mixed in way of temperature rise at passage of gas mixture through charge in way of temperature rise. Size of particles of oxides does not exceed 2-4 mm. Used as reductant are hydrocarbons and/or oxygen derivatives of hydrocarbons and/or their polymers. Reduction process is completed within range of temperatures of forming final product at preset phase state. |
Method of production of cleaned coal for metallurgical processes and method of production of reduced metal and slag containing oxidized non-ferrous metal with the use of this coal / 2302450 Proposed method is based on use of cleaned coal for production of high-quality reduced metal. Coal is first kept in organic solvent simultaneously with heating, thus obtaining cleaned coal suitable for metallurgy which possesses higher thermoplasticity as compared with starting coal. Then, mixture of cleaned coal and starting material is subjected to agglomeration in agglomerator and agglomerate thus obtained is reduced at heating in furnace provided with movable hearth; then, it is molten by further heating, thus obtaining reduced melt which is cooled and hardened in furnace provided with movable hearth, thus obtaining solid material, after which reduced solid material is withdrawn from furnace. Then, slag is removed with the use of screen and reduced metal is extracted. |
Method of production of cleaned coal for metallurgical processes and method of production of reduced metal and slag containing oxidized non-ferrous metal with the use of this coal / 2302450 Proposed method is based on use of cleaned coal for production of high-quality reduced metal. Coal is first kept in organic solvent simultaneously with heating, thus obtaining cleaned coal suitable for metallurgy which possesses higher thermoplasticity as compared with starting coal. Then, mixture of cleaned coal and starting material is subjected to agglomeration in agglomerator and agglomerate thus obtained is reduced at heating in furnace provided with movable hearth; then, it is molten by further heating, thus obtaining reduced melt which is cooled and hardened in furnace provided with movable hearth, thus obtaining solid material, after which reduced solid material is withdrawn from furnace. Then, slag is removed with the use of screen and reduced metal is extracted. |
Method of reduction of metal oxides / 2317342 Charge in form of mixture of oxides and reductant is fed to heated furnace and is mixed in way of temperature rise at passage of gas mixture through charge in way of temperature rise. Size of particles of oxides does not exceed 2-4 mm. Used as reductant are hydrocarbons and/or oxygen derivatives of hydrocarbons and/or their polymers. Reduction process is completed within range of temperatures of forming final product at preset phase state. |
Method of tin manufacturing from cassiterite concentrate / 2333268 Invention concerns tin metallurgy field and can be used for tin manufacturing while treatment of cassiterite concentrates. Method of tin manufacturing from cassiterite concentrate with content of 35-50% SnO2 includes batch preparation by blending of tin concentrate with coal and flux additive. In the capacity of flux additive it is used sodium carbonate and sodium nitrate. Melting is implemented at temperature 850-1000°C during 2 hours. For mentioned concentrate it is kept up following mass ratio: concentrate : coal : sodium carbonate : sodium nitrate, equal to 1 : (0.2-0.25) : (0.12-0.15) : (0.06-0.08). It allows without concentrate pretreatment to provide tin manufacturing of 98% purity at less in comparison with tradition approach, temperature. |
Reduction method of metal and oxygen compositions / 2360982 At reduction of metal and oxygen composition effect as reducer, herewith at first stage gaseous CO is passed into reaction chamber, containing specified composition of metal and oxygen. In conditions, providing conversion of CO into solid carbon and carbon dioxide, formed solid carbon is introduced into metal and oxygen composition. At the second stage solid carbon, which is introduced into metal and oxygen composition at the first stage, reduces metal and oxygen composition. Additionally at the second stage it is, at least, the first material- promoter, conducive reduction of specified metal and oxygen composition. Additionally the first material- promoter contains the first metal- promoter and/or composition of the first metal- promoter. |
Method of processing of iron-titanium concentrate / 2385962 Method includes formation of charge consisting of concentrate and sodium carbonate by means of intergrinding of components and reduction of charge components at presence of taken with excess carbonaceous reducing material at temperature 850-1300°C. Additionally batch material reduction is implemented up to providing of content of metallic iron in the range of particles dimensions 10-300 mcm not less than 80%. Received partly reduced conservative mass, consisting of metalise phase containing main part of iron and vanadium and oxide phase, containing main part of titanium and vanadium, it is grinned up to size not more than 300 mcm. Then it is implemented leaching of vanadium from reaction mass and leaching residue is separated from vanadate solution. After separation residue of leaching is subject to gravitational separation in water flow with separation of metalised and oxide phases. Metalised and oxide phases are separately subject to wet magnetic separation for receiving of metallic iron and titanium oxide concentrate. Additionally wet magnetic separation is implemented in the range of field intensity 20-300 E. |
Procedure for depletion of solid copper-zinc slag / 2398031 Invention refers to procedure for depletion of solid copper-zinc slag. The procedure consists in supply of charge containing solid copper-zinc slag and carbonic reducer at weight ratio of slag to solid carbonic reducer 1: (0.06-0.1) into heated furnace. Also charge in the heated furnace is blasted with oxygen containing oxidant by means of upper not-immersed blast; consumption of oxygen-containing oxidant is determined by contents of oxygen in it from condition of 60-110 kg per ton of slag. Further there is produced a rich with copper phase and zinc is transferred into a gas phase. |
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