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Briquette used in manufacture of cast iron

IPC classes for russian patent Briquette used in manufacture of cast iron (RU 2247155):
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FIELD: ferrous metallurgy.

SUBSTANCE: briquette includes silicon-containing material, carbon-containing material, and cement as binder. Silicon-containing material includes metallurgical silicon carbide and carbon-containing material includes carbon-siliceous mixture.

EFFECT: improved process of manufacturing castings from synthetic cast irons thanks to simultaneous postcarbonization and modification.

4 cl, 2 tbl, 4 ex

 

The claimed invention (four options) relates to ferrous metallurgy, in particular to the production of alloys.

Claimed four options technical solution for each of the options is a solution of the same problem fundamentally the way that cannot be covered by one General claim.

Known formula for cast iron that contains carbon-containing material, silicon carbide, ferrosilicon and vanadium oxides in the following ratio, wt.%:

The carbonaceous material 10-30

Silicon carbide 1-5

The vanadium oxide 10-30

Ferrosilicon 75% else

(A.S. USSR №1169996, 22 S1/00. Bull. No. 28, 1985)

This mixture increases the resistance to wear of processed iron.

Known formula for machining cast irons containing 75% ferrosilicon, carbonaceous material and chromium oxides in the following ratio, wt.%:

The carbonaceous material 10-30

Silicon carbide 1-5

The chromium oxides 10-30

75% ferrosilicon else

(A.S. USSR №1266869, With 22 1/00. Bull. No. 40, 1986)

This mixture increases the hardness and corrosion resistance of cast iron.

Known for modifying the briquette containing aluminum, fluorspar, graphite, ferrosilicon and/or silimperi and binder in the following ratio comp is required, wt.%:

Aluminum 15-35

Fluorspar 2-10

Graphite 2-4

Ferrosilicon and/or

silimperi else

When this bond has the following composition, wt.%:

The bicarbonate magnesium 52,0-56,0

Chromic anhydride 2,6-2,9

The chromium oxide 11,2-11,9

Titanium dioxide 23,3-26,0

Water the rest

(A.S. USSR №1498792, With 21 1/08, With 22 35/00. Bull. No. 29, 1989)

This mixture increases the strength of the briquette and improves the mechanical properties of machined cast iron.

Known briquette for iron and steel production (Patent RF №2083681, IPC 21 5/06, 22, 1/24). This invention briquette for the production of iron and steel includes steel scale, carbonaceous material and a binder, and is used as a binder a mixture of silicon dioxide, calcium oxide, sodium oxide and aluminum oxide and the carbonaceous material - electrode battle.

Known briquette containing silicon-containing residues (options), and how to obtain it. The briquette according to this invention contains silicon remains as additives for metallurgical purposes, it is made by dry weight of 1-10% by weight cardboard fibers, 5-40% by weight of hydraulic cement, and the rest of silicon (Patent RF №2124058, IPC From 22 In 1/242).

The closest in technical essence and the achieved effect is modifying the briquettes desintations cast iron, containing ferrosilicon FC-75, a binder and a carburizer, as carburizer is coke, as a binder - 40% aqueous solution of sediment technical lignosulfonates in the following ratio, wt.%:

Ferrosilicon FS-75 5,0-8,0

Toxic 80,0-85,0

40% aqueous solution of a solid residue

technical lignosulfonates 10,0-12,0

(A.S. USSR №1574667, With 22 35/00. Bull. No. 24, 1990)

The composition of these briquettes provides only monogenoidea melt and reduce chill of thin-walled castings.

The technical objective of the invention is to achieve a qualitative improvement of the composition of the briquette by replacing ferrosilicon silicon carbide metallurgical under certain proportions of all components, resulting in higher technical results - improve the strength characteristics of alloys and improve the technological process of production of castings made of synthetic iron due to their simultaneous monogermane and modification.

Briquettes, claimed by the present invention (four options), can be used in the production of alloys, as well as gray and alloyed cast irons on the basis of synthetic melt, which has a low ability to graphitization.

The first is ariante the problem is solved in that the briquette to produce iron-carbon alloy comprising silicon-containing material, a carbonaceous material and a binder comprises a silicon-containing and carbon-containing materials, silicon carbide metallurgical and carbon - silicon mixture, the binder is cement in the following ratio, wt.%:

Silicon carbide metallurgical 59-62

Uglerodsesola mixture 21-25

Cement 13-20

In the second embodiment, the briquette to produce iron-carbon alloy includes silicon-containing material, a carbonaceous material and a binder comprises a silicon-containing and carbon-containing materials, silicon carbide metallurgical and uglerodistoi mixture as a binder cement in the following ratio, wt.%:

Silicon carbide metallurgical 44-48

Uglerodsesola mixture 36-39

Cement 13-20

In the third embodiment, the briquette to produce iron-carbon alloy includes silicon-containing material, a carbonaceous material and a binder comprises a silicon-containing and carbon-containing materials, silicon carbide metallurgical and uglerodistoi mixture as a binder cement in the following ratio, wt.%:

Silicon carbide metallurgical 18-21

Of plastics technology : turning & Kremnica mixture 62-66

Cement 13-20

In the fourth embodiment, the briquette to produce iron-carbon alloy includes silicon-containing material, a carbonaceous material and a binder comprises a silicon-containing and carbon-containing materials, silicon carbide metallurgical and uglerodistoi mixture as a binder cement in the following ratio, wt.%:

Silicon carbide metallurgical 1-5

Uglerodsesola mixture 79-82

Cement 13-20

The characteristic common to these for all variants of the claimed briquettes and the prototype is the presence of a silicon-containing material, a carbonaceous material and a binder.

The hallmark for the first variant is the content as a silicon-containing and carbon-containing materials, silicon carbide metallurgical and uglerodistoi mixture as a binder cement in the following ratio, wt.%:

Silicon carbide metallurgical 59-62

Uglerodsesola mixture 21-25

Cement 13-20

The hallmark for the second variant is the content as a silicon-containing and carbon-containing materials, silicon carbide metallurgical and uglerodistoi mixture as a binder cement in the following ratio, wt.%:

Silicon carbide IU the metallurgical 44-48

Uglerodsesola mixture 36-39

Cement 13-20

The hallmark for the third variant is the content as a silicon-containing and carbon-containing materials, silicon carbide metallurgical and uglerodistoi mixture as a binder cement in the following ratio, wt.%:

Silicon carbide metallurgical 18-21

Uglerodsesola mixture 62-66

Cement 13-20

The hallmark for the fourth option is the content as a silicon-containing and carbon-containing materials, silicon carbide metallurgical and uglerodistoi mixture as a binder cement in the following ratio, wt.%:

Silicon carbide metallurgical 1-5

Uglerodsesola mixture 79-82

Cement 13-20

Introduction the composition of the mixture of metallurgical silicon carbide provides replacement ferrosilicon. Silicon carbide is used as a component of the charge, providing the necessary content in the pig iron, silicon and partially of carbon. The use of silicon carbide metallurgical more economical in comparison with ferrosilicon and helps reduce the tendency of liquid iron to chill and also more uniform distribution of spherical inclusions of graphite in ductile iron and more stable silicon content in all cast iron, h is about significantly improves the technological characteristics of the iron-carbon melt and mechanical properties of cast iron.

The influence of silicon carbide metallurgical together with uglerodistoi mixture ensures the adequacy of the carburizing process. Silicon carbide contains fewer non-metallic inclusions and impurities of non-ferrous metals than ferrosilicon, a lower content of gases and promotes the release of elemental carbon, forms in the liquid melt centers graphitization.

Uglerodsesola mixture is a secondary product thermochemical reactions with the ratio SVAS.: Swab. = 1:7, provides the saturation of the melt particles of carbon, which are the active centers of graphitization and are also a source of silicon to form SiC.

Thus, in the present briquette combination of carbon-containing components provides graphitization cast iron due to the complex influence and at the same time provides a synergistic principle of their action.

The choice of cement as a binder allows you to produce briquettes of high strength, which substantially reduces the loss of components during storage and transportation.

The boundaries of the content components in the composition of the briquette in the first embodiment are justified as follows.

Silicon carbide (STF 002222-162-99). When the content within 59-62 wt.% provided Troubleshooting chill in the iron to provide the required content of the cream is Oia. When the content is less than 59 wt.% the silicon content in the pig iron is not responding vintage. When the content is more than 62 wt.% the time response of briquettes increases significantly at low danegerous effect (worsening of modifying the ability of the briquette, deteriorating the form of graphite and, as a consequence, the mechanical properties of castings).

Uglerodsesola mixture (TUU 322-00196204.005-99). The number uglerodistoi mixture into briquettes within 21 to 25 wt.% provides a stable carbonizing the ability of the briquettes. When the content in the briquette uglerodistoi mixtures of less than 21 wt.% carbonizing the ability of their insufficient, and when the content of her more than 25 wt.% you receive the excess carbon in comparison with grades.

Cement (GOST 30515-97), for example, grade M-400 provides the necessary strength of the briquettes. But when the content in the composition of the briquette less than 13 wt.% cement they have insufficient strength, increased litter. When the content is more than 20 wt.% deteriorate the mechanical properties of cast iron, increases the amount of slag.

The boundaries of the content components in the composition of the briquette according to the second option proved the following.

Silicon carbide (STF 002222-162-99). When the content within 44-48 wt.% provided Troubleshooting chill in cast iron, increasing the amount of ferrite in cast iron and are provided with appropriate content is silicon. When the content is less than 44 wt.% the silicon content in the pig iron is not responding vintage. When the content is more than 48 wt.% you receive an excess of silicon, resulting in reduced strength properties of cast iron due to the heterogeneity of the structure of the metal matrix.

Uglerodsesola mixture (TUU 322-00196204.005-99). The number uglerodistoi mixture into briquettes within 36-39 wt.% ensure high and stable carbonizing the ability of the briquettes. When the content in the briquette uglerodistoi mixture less than 36 wt.% carbonizing the ability of their low when the content of its more than 39 wt.% worse shape, size and distribution of inclusions of graphite, which degrades the quality of castings.

Cement (GOST 30515-97), for example, grade M-400. In the claimed number provides the necessary strength of the briquettes. But when the content in the composition of the briquette less than 13 wt.% cement they have insufficient strength, increased litter. When the content is more than 20 wt.% deteriorate the mechanical properties of cast iron, increases the amount of slag.

The boundaries of the content components in the composition of the briquette by the third variant is proved as follows.

Silicon carbide (STF 002222-162-99). When the content within 18-21 wt.% provide the required silicon content, the effect of standard modification that eliminates the chill. When the content of m is her 18 wt.% the silicon content in the pig iron is not responding vintage. When the content of more than 21 wt.% you receive an excess of silicon, resulting in reduced strength properties due to the heterogeneity of the structure of the metal matrix.

Uglerodsesola mixture (TUU 322-00196204.005-99). When the content within 62-66 wt.% ensures the sufficiency of the carburizing process. When the content in the briquette uglerodistoi mixture less than 62 wt.% not provided grades of cast iron to carbon, and when the content of her more than 66 wt.% worse shape, size and distribution of inclusions of graphite, which degrades the quality of castings.

Cement (GOST 30515-97), for example, grade M-400. In the claimed number provides the necessary strength of the briquettes. But when the content in the composition of the briquette less than 13 wt.% cement they have insufficient strength, increased litter. When the content is more than 20 wt.% deteriorate the mechanical properties of cast iron, increases the amount of slag.

The boundaries of the content components in the composition of the briquette according to the fourth variant justified as follows.

Silicon carbide (STF 002222-162-99). When the content is in the range of 1-5 wt.% to achieve the effect of standard modification, reducing the number of structurally free cementite. When the content is more than 5 wt.% in the iron you receive an excess of silicon, resulting in reduced strength properties due to the heterogeneity of the structure of the URS of the metal matrix.

Uglerodsesola mixture (TUU 322-00196204.005-99). When the content within 79-82 wt.% ensures the saturation of the melt particles of carbon, which are the active centers of graphitization. When the content in the briquette uglerodistoi mixture of less than 79 wt.% not provided a sufficient degree, and when the content of her more than 82 wt.% leads to the release of graphite with liquid iron in the form of sang, which degrades the quality of castings.

Cement (GOST 30515-97), for example, grade M-400. In the claimed number provides the necessary strength of the briquettes. But when the content in the composition of the briquette less than 13 wt.% cement they have insufficient strength, increased litter. When the content is more than 20 wt.% deteriorate the mechanical properties of cast iron, increases the amount of slag.

Conducted by the applicant search on scientific, technical and patent information sources and selected from the list of analogues prototype allows to detect the above-mentioned differences in the proposed technical solution.

So, the proposed solution “Cake for the production of iron-carbon alloy” (four options) meets the criteria of the invention is a novelty.

Further analysis of the known technical solutions for the determination of characteristics similar to the characteristics of the characterizing portion of the claims of the proposed technical R the solution, showed that these characteristics are not found among the known solutions.

Thus the claimed technical solution meets the criteria of the invention is an inventive step.

Examples of specific performance.

1. The briquettes in the first embodiment are used in the production of synthetic iron from a mixture consisting of 27% of steel scrap, 63% of cast or pig iron, 10% briquettes, by the present invention, for example, cast iron CSS (GOST 7769-82).

For comparative studies of briquettes for melting of cast iron as an object of research the iron CSS the following chemical composition, %: carbon 2,7-3,5; silicon 4,5-5,5; manganese ≤ 0.8; phosphorus ≤ 0,10; sulfur ≤ 0,03; chrome to 0.2; titanium 0.1 to 0.3; iron rest.

Melting synthetic iron were carried out in an induction furnace PCE-57 with acid lining. As metal mixture used 27% of steel scrap grade 1A (GOST 2787-88), 63% of pig iron brand PT2 (St SEV 3288-92). The melt is overheated to 1450°and has introduced 10% of the bricks.

Investigated the composition of the briquettes and the research results are summarized in table 1.

2. The briquettes according to the second variant used in the manufacture of synthetic iron from a mixture consisting of 45% of steel scrap, 45% of cast or pig iron, 10% briquettes, by the present invention, for example, cast iron SCH (GOST 1412-85), the ES-5 (GOST 1585-85).

For comparative studies of briquettes for melting of cast iron as an object of research the iron ASF-5 the following chemical composition, %: carbon 3,5-4,3; silicon 2,5-3,5; manganese 7,5-12,5; phosphorus : not more than 0.20, sulfur not more than 0,06; chrome to 0.2; iron rest.

Melting synthetic iron was carried out in an induction furnace PCE-57 with acid lining. As the charge used 45% of steel scrap grade 1A (GOST 2787-88), pig iron brand PT2 (St SEV 3288-92). The melt is overheated to 1450°and has introduced 10% of the bricks.

Investigated the composition of the briquettes and the research results are summarized in table 1.

3. The briquettes by the third variant used in the manufacture of synthetic iron from a mixture consisting of 63% of steel scrap, 27% of castings and pig iron, 10% briquettes, by the present invention, for example, cast iron MF 30-35 (GOST 1412-85), ASC-2 (GOST 1585-85).

For comparative studies of briquettes for melting of cast iron as an object of research the iron SO the following chemical composition, %: carbon 2,9-3,0; silicon 1,2-1,5; manganese 0,7-1,1; phosphorus ≤ 0,2; sulfur ≤ 0,12; iron rest.

Melting synthetic iron was carried out in an induction furnace PCE-57 with acid lining. As metal mixture used 63% of steel scrap grade 1A (GOST 2787-88), 27% of pig iron brand PT2 (the t CMEA 3288-92). The melt is overheated to 1450°and has introduced 10% of the briquettes by the present invention.

Investigated the composition of the briquettes and results are given in table 2.

4. The briquettes according to the fourth variant used in the manufacture of synthetic iron from a mixture consisting of 90% of steel scrap and 10% of the briquettes by the present invention, for example, cast iron CIS (GOST 7769-82).

For comparative studies of briquettes for melting of cast iron as an object of research the iron CS the following chemical composition, %: carbon 0.3 to 0.5; silicon 16,1-18,0; manganese ≤ 0.8; phosphorus ≤ 0,10; sulfur ≤ 0,07; iron rest.

Melting synthetic iron was carried out in an induction furnace PCE-57 with acid lining. As the charge used 90% of steel scrap grade 1A (GOST 2787-88). The melt is overheated to 1450°and has introduced 10% of the bricks.

Investigated the composition of the briquettes and results are given in table 2.

For all trunks:

Cast iron was kept for 10 min and brought to the required chemical composition of additives ferroalloys and necessary alloying elements.

After removal of the slag was poured technical standard samples ⊘ 30 mm for the study of the mechanical properties of cast iron, determination of the chemical composition of the metal.

As can be seen from tables 1, 2, proposed briquettes on the handle the containers increase the strength characteristics for 7-13% for the irons of their group, with more technological process of production of iron - simultaneous danaperino and modification.

The proposed composition of the briquettes can be easily reproduced and used for the production of high quality iron-carbon melts.

This obrazom, the claimed technical solution (four options) meets the criteria of the invention and industrial applicability.

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Table 1
Briquette for cast iron Beyond content ingredients The composition of the briquettes, wt.% The carbon content in the base melt, % The carbon content in cast iron after treatment with briquettes % The effect of monogermane Tensile strength cast iron tensile, MPA
Silicon carbide metallurgical Ferrosilicon Uglerodsesola mixture Binder GOST Experience
Known MF-25 Average   7,0 83,0 10,0 2,74 3,31 0,208 252 252
Bottom 59 - 21 13 1,9 2,7 0,421 290 316
Average of 60.5 - 23 16,5 1,9 3,1 0,631 290 316
Top 62 - 25 20 1,9 3,5 0,969 285 308
Below the bottom 58   20 12 1,9 2,1 0,105 310 347
Above top 63   26 21 1,9 the 3.8 1 270 289
We offer a briquette according to the second variant ACS GOST 1585-85 Bottom 44 - 36 13 1,5 3,5 1,33 100 109
Average 46 - 37,5 16,5 1,5 the 3.8 1,53 120 132
Top 48 39 20 1,5 4,3 1,87 128 140
Below the bottom 43   35 12 1,5 3,0 1 138 155
Above top 49   40 21 1,5 4,8 2,2 90 102

Table 2.
Briquette for cast iron Beyond content ingredients The composition of the briquettes, wt.% The carbon content in the base melt, % The carbon content in cast iron after treatment with briquettes % The effect of monogermane Tensile strength cast iron tensile, MPA
Silicon carbide metallurgical Ferrosilicon Uglerodsesola mixture Binder GOST Experience
Known MF-25 Average   7,0 83,0 10,0 2,74 3,31 0,208 252 252
We offer a briquette according to the third variant SC GOST 1412-85 Bottom 18 - 62 13 0,8 2,9 2,629 348 379
Average 19,5 - 64 16,5 0,8 2,95 2,687 350 395
Top 21 - 66 20 0,8 3,0 2,75 350 395
Below the bottom 17 - 61 12 0,8 2,8 2,5 305 335
Above top 22   67 21 0,8 3,2 3,0 310 338
We offer a briquette according to the fourth variant of ES-17 GOST 7769-82 Bottom 1 - 79 13 0,1 0,31 2,1 59,5 67
Average 3 - 80,5 16,5 0,1 0,45 3,5 60,0 67
Top 5 - 82 20 0,1 0,50 4,0 61,5 69,5
Below the bottom 0,5   78 12 0,1 0,28 1,8 55 of 60.5
Above top 6   83 21 0,1 0,55 4,5 54 59

1. The brick used in the production of cast iron, comprising a silicon-containing material, a carbonaceous material and a binder, characterized in that as the silicon-containing material contains a silicon carbide metallurgical, the carbonaceous material contains uglerodistoi mixture, and as the binder is cement in the following ratio, wt.%:

Silicon carbide metallurgical 59-62

Uglerodsesola mixture 21-25

Cement 13-20

2. The brick used in the production of cast iron, comprising a silicon-containing material, a carbonaceous material and a binder, characterized in that as the silicon-containing material the material it contains silicon carbide metallurgical, the carbonaceous material contains uglerodistoi mixture, and as the binder is cement in the following ratio, wt.%:

Silicon carbide metallurgical 44-48

Uglerodsesola mixture 36-39

Cement 13-20

3. The brick used in the production of cast iron, comprising a silicon-containing material, a carbonaceous material and a binder, characterized in that as the silicon-containing material contains a silicon carbide metallurgical, the carbonaceous material contains uglerodistoi mixture, and as the binder is cement in the following ratio, wt.%:

Silicon carbide metallurgical 18-21

Uglerodsesola mixture 62-66

Cement 13-20

4. The brick used in the production of cast iron, comprising a silicon-containing material, a carbonaceous material and a binder, characterized in that as the silicon-containing material contains a silicon carbide metallurgical, the carbonaceous material contains uglerodistoi mixture, and as the binder is cement in the following ratio, wt.%:

Silicon carbide metallurgical 1-5

Uglerodsesola mixture 79-82

Cement 13-20

 

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