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Method of removing heavy metals and their salts of fish raw materials

IPC classes for russian patent Method of removing heavy metals and their salts of fish raw materials (RU 2166860):
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Method of raw milk purification from toxic metals / 2441397

FIELD: food industry.

SUBSTANCE: this invention covers method of raw milk purification from toxic metals and includes adding of a sorbent agent, purification from sorbent agent, herewith raw milk intoxicated with metals in (1.1…4.0)±0.1 MAC concentration undergoes purification. Purification is performed until 0.5 MAC ratio is reached; contact with a sorbent agent is performed at 6°C, 5 minutes with mixing. Purification from a sorbent agent is performed by a centrifugal method at the separator-milk purifier for cold purification, herewith grapheme powder of 0.1:1000 ratio is used as a sorbent agent.

EFFECT: decrease of toxic metals concentration in raw milk to (95…97)±1% degree of purification.

1 dwg, 2 tbl, 2 ex

(57) Abstract:

The invention can be used for removal of the fish raw material of heavy metals and their salts, mainly mercury. For the removal of heavy metals raw materials immersed in a solution of pectin concentration of 0.01% when the ratio of solution and raw materials 1:1. The extraction time is 5 minutes to the Invention will make it possible to extract heavy metals from raw materials with a minimum duration of the process. 1 C.p. f-crystals.

The present invention relates to the field of processing of water bodies, in particular to the problem of removal of fish raw materials heavy metals and their salts.

The known method of removing mercury from meat, coal fish, cut in pieces, by immersing the substrate in a solution of testingground with a concentration of 1% solution and keeping it in solution within 72 hours (Teeny F. M., Hall, A. S. , Gauglitz E. J. Reduction of mercury in sablefish, anoplopoma fimbria, and the use of the treated fish in smoked products. Marine fish. Rev. 1974, 36, N 5, 15-19, i 11, tabe Bibliogr. 5 ref.)
The disadvantages of this method include duration of soaking raw material, which adversely affects its quality, as it promotes the removal with heavy metals and valuable nutrients.

Isela in the solution of cysteine long time. This method allows to reduce the mercury content in fish from 40% to 20% depending on the concentration of hydrochloric acid and the exposure time of the substrate in solution (Spinelly J., Steinberg, M. A., Miller R., Hall, A. L. Zerman Reduction of mercury with cysteine in comminuted halibut and hake protein concentrate "J. Agr. And food Chem." 1973, 21, N 2, 264-268).

The disadvantages of this method include the low quality of the product due to partial denaturation of protein due to the impact of raw materials hydrochloric acid, and a low percentage removal of mercury (reduced from 40% to 20%).

The known method of removing heavy metals from fish or raw meat through the use of pectin (Tolstoguzov B. C. Artificial food. - M.: Nauka, 1978, S. 43,49).

The disadvantages of this method include the lack of best practices and settings that would allow display of raw material the maximum number of heavy metals and their salts.

For tasks that have set themselves the authors of this solution is the improvement of the quality of the food by increasing the amount of extractable heavy metals, the use of the extractant, safe for human health and for reducing the time of the extraction.

Delivered price is a thief with a concentration of 0.01% and immersed in a fish raw materials.

The ratio of the solution of pectin and fish should be 1:1. The exposure time in solution of raw materials in the form of chopped pieces of fish thickness of about 1 cm should be 5 minutes. This period of time is the best, because it is the time from raw materials derived 84,69% mercury and its compounds. With a longer shutter speed (up to 20 minutes) percent of the output of mercury was reduced to 62,82%.

The increase in the concentration of pectin in the solution of 0.03% at the exposure time of 5 minutes was reduced up to 69.9% in the number of output mercury. Using 1 kg of pectin (manufactured by) allows you to associate in raw materials 85 g of mercury, 89 g of lead, 48 g of cadmium assuming full replacement of the hydrogen of the free carboxyl groups on metal ion.

Especially good complexing agents pectin manifests itself in an alkaline environment, because in parallel with the flowing dimethoxypropane additionally exempt carboxyl groups required for binding of metal ions.

The advantages of using pectin as a means for removing heavy metals are its wide application in the food industry for other purposes, the safety delovogo extraction of heavy metals with a minimum duration of exposure to the product.

An example of the method.

Take 1 kg of meat fish (big-eyed tuna, swordfish, shark-Mako), mercury content which exceeds the permitted limit or approaching it, making 0,94 mg/kg. Cut the fish into pieces 1 cm thick and place in a pre-prepared solution with a concentration of 0.01%. The extraction time is 5 minutes. The ratio of the solution and the fish should be 1:1.

As shown by subsequent analyses, the number of derived mercury after treatment was on average 85% of original condition. The amount of mercury was determined by flameless atomic adsorption using mercury analyzer MASS-50 firms "Coleman".

1. Method of removing heavy metals and their salts of fish raw materials through the use of pectin, wherein preparing the solution of pectin concentration of 0.01% and immersed in the raw material, the ratio of the solution and the raw material is 1 : 1.

2. The method according to p. 1, characterized in that before the immersion of fish raw material in a solution of fish cut into pieces, and the extraction time is 5 minutes

 

 

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