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The method of obtaining the odorant

The method of obtaining the odorant
IPC classes for russian patent The method of obtaining the odorant (RU 2105597):
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(57) Abstract:

Usage: in the field of purification of gases, in particular processes for the production of odorants for hydrocarbons, the gas industry. The inventive method of producing odorant for natural gas, including extraction of mercaptans with an aqueous solution of alkali, the desorption of boiling mercaptans obtained mercaptides alkaline solution, the condensation of vapor-gas mixture with the release of the odorant, the odorant is subjected to adsorption drying with subsequent two-stage regeneration of the silica gel gas regeneration of zeolites and cooling of the adsorbent. The method provides high quality during storage. 1 C.p. f-crystals, 1 table.

The invention relates to the purification of gases, in particular to the processes of production of odorants for natural gas from mercaptoundecanoic hydrocarbons, and may find its application in the gas industry, including for sorbent regeneration.

A known method for separating low-boiling mercaptans from hydrocarbons used as an odorant for natural gas, including extraction of mercaptans 10-30% aqueous solution of alkali, the desorption of boiling mercaptans mercaptides alkaline rastut with a volumetric ratio of hydrocarbon extractant, equal (3-4):1, respectively, and the desorption is carried out in the presence of water in the amount of 20-50% by volume mercaptides alkaline solution.

The desorption process is carried out at a temperature 104-120oC and a pressure of 0.3 to 0.4 ATM [1]
The main disadvantage of this method is the presence of odour heavy mercaptans in the use and storage precipitated, which reduces the efficiency of the odorizing.

Closest to the present invention is a method of allocating natural mercaptans from hydrocarbons used as an odorant for natural gas, including extraction of mercaptans with an aqueous solution of alkali, the desorption of boiling mercaptans mercaptides alkaline solution, the condensation of vapor-gas mixture and the regeneration of the alkaline solution, in which the extraction is carried out at a molar ratio of mercaptan alkali equal to 1:(0,6-1,0), respectively [2]
The main disadvantage of this method is high moisture content in the bound form in the composition of the odour, which reduces the efficiency of the odorizing due to precipitation of heavy mercaptans during long-term storage of odour and reduce odor.

The objective of the invention is to establish the tx2">

The problem is solved by the method of obtaining the odorant for natural gas, including extraction of mercaptans from a raw material aqueous solution of alkali, the desorption of boiling mercaptans obtained mercaptides alkaline solution, the condensation of vapor-gas mixture with the release of odour, which highlighted the odorant is subjected to drying on silica gel with subsequent regeneration of the silica gel by feeding gas at elevated temperature and cooling of silica gel, and the regeneration is carried out by gas regeneration of zeolites in two stages: the first carried out by heating the silica to 100oC for 1 h when it is added to the gas from the regeneration of zeolites marketable natural gas; the second stage is carried out at 160-170oC for 4 h with subsequent cooling.

After regeneration of the silica gel was it cool for 2 h with regeneration gas with a temperature of 40-45oC.

Obtained by the proposed method the odorant consists mainly of 95 wt. from C2-C3that corresponds to THE 51-81-82.

Additional drying improves the quality of odour, which has a more intense and persistent odor. Due to the lack of water reduces the corrosion of the equipment, reduced commitment to the work, and it retains a high intensity and durability of the smell.

Example. Liquid hydrocarbon fraction, obtained by removal of the mercaptans mixture of sulfur natural gas and gas regeneration of zeolites taken to treatment in a volume ratio 6.8:1, after mixing with 10% alkali solution at a molar ratio of alkali hydrocarbon fraction equal to 1:8, is fed to the column.

The alkaline solution saturated with mercaptide having a higher density than the hydrocarbon fraction, is given cube columns in the tank for sludge and the treated liquid hydrocarbon fraction from the top of the columns displayed in the store.

Settled alkali solution after heating in the heater up to 90oComes with the second column, where the temperature of the top 116oWith Cuba, 120oWith the decomposition of mercaptides with the release of odour, which is in the vapor phase is shown with the top of the column to cooling and condensation in the cooler-condenser and then for sludge from water in the coagulator-sump with drain condensed odorant to the dewatering and water recovery in the second column for irrigation.

The odorant through the pipeline under pressure of 10 kg/cm2serves dunia odorant dissolved in water. The odorant through the layer of silica gel from top to bottom through filters designed to trap solids, is sent to the capacity of the drive is drained of odour.

After appearing after layer of adsorbent odorant dissolved in moisture higher than 0.1 mol. the adsorbers switch on regeneration. This next pair of adsorbers switch on drying.

Regeneration of the silica gel was carried out by gas regeneration of zeolites, supplied with the installation of gas cleaning and mercaptans. To adjust the temperature of the regeneration gas supplied to the silica gel, the pipeline of marketable natural gas and pipeline gas from the regeneration of the zeolite is selected the control valve.

The regeneration gas under pressure of 10 kg/cm2pipeline through the control valve serves to the bottom of the canister and carry out the regeneration of the silica gel in two stages. At the first stage within 1 h when open the valve, adding a sales gas pipeline gas recovery, gradually bring the temperature of the regeneration gas to 100oC. Then by closing the said valve to reduce the supply of marketable gas, and it will be a smooth rise of the gas temperature to 160-170oSince, at this temperature in tienta cold regeneration gas with a temperature of 40-45oC for 2 h regulate the temperature of the gas by opening the valve, allowing to increase the consumption of gas in the gas pipeline regeneration of zeolites.

After regeneration of the silica gel, the gas is sent to the air cooler where it is cooled to 80oC. Then, after passing annulus water fridge, the gas is cooled to 50oWith, into the separator, which separates the water and the pipe is fed into the gas pipeline stabilization. Separated in the separator water is diverted into the tank recovery.

Data on receipt of the odorant presented in the table.

Using the proposed method provides the following advantages: high output odorant per unit of feedstock; high quality reclaimed odour, when the content of mercaptans more than 95% of its conformity to THE-51-81-82.

1. The method of obtaining of odour, including extraction of mercaptans from a raw material aqueous solution of alkali, the desorption of boiling mercaptans obtained mercaptides alkaline solution, the condensation of vapor-gas mixture with the release of odour, characterized in that the selected odorant is subjected to drying on silica gel with Poslednyaya, the regeneration of the silica gel was carried out by gas regeneration of zeolites, and the regeneration is carried out in two stages: the first carried out by heating the silica to a temperature of 100oC for one hour when it is added to the regeneration gas zeolites marketable natural gas, and the second stage is carried out at a temperature of 160 170oC for 4 h and then cooled silica gel.

2. The method according to p. 1, characterized in that the cooling of the silica gel was carried out within two hours of the regeneration gas with a temperature of 40 45oC.

 

 

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