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Composition for microporous material krasavicaaaaa

Composition for microporous material krasavicaaaaa
IPC classes for russian patent Composition for microporous material krasavicaaaaa (RU 2057150):
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(57) Abstract:

The use of the invention: microporous krestovidnaya materials. The inventive composition comprises, by weight.h.: polyvinyl chloride 100; butylbenzylphthalate or its mixture with diethylphthalate 80 - 120; triethylene glycol 35 - 70; polyoxyalkylene alcohol 20 - 40 and dye 7 - 20. table 1.

The invention relates to the production of PVC plastisols with coloured compounds, which serve as the basis for the manufacture of krasavitsa materials in the form of various rollers of printing machines, stamp pad, marking stamps, etc.

A method of obtaining krishnapatnam PVC-plastisol and the printing material based on it [1] Separately prepare a pigment solution containing 100 wt.h. solvent (glycerylmonostearate or ethylhexanediol) and 5 wt. including dye methylfolate and PVC-plastisol, comprising 50 wt. including polyvinyl chloride, 50 wt.h. plasticizer (dioctylphthalate, tricresylphosphate) and 5 wt.h. thermo stabilizer trehosnovnogo sulphate of lead. Then these two compositions are mixed and get nerastraivaisya for a long time Krasnapolsky PVC plastisol, which by termouprugogo of this method is the possibility of obtaining print products only one color.

Known composition for microporous printing material [2] includes the following components, wt.h. Polyvinyl chloride 31,7-39,9 Plasticizers 17-21 Dye 4,4-9,9 Phenoxyethanol 20-24
Ectopically Alka - nirantara acids 8,1-10,4
As plasticizers are used butylbenzylphthalate, and dyes may be dyes belonging to different classes. For example, fat-soluble and soluble nigrosine, basic violet K, a fat-soluble violet, eosin, etc. with sufficient solubility in a mixture of Phenoxyethanol and octagenerian alchemistry acids. Prepared krasnokamennuyu composition thermoablative forms at a temperature of 130-160aboutC for 20 to 100 minutes

The invention allows to expand the color gamut and to improve the clarity of the prints print products, but one of them is abundant spontaneous selection of the coloring composition (wypadanie), which need to be removed within a few days after production. This prevents the widespread adoption of this technology.

Closest to the invention is a method whereby to obtain kraskoraspylitelemmetodom in their mass ratio from 1.00-1.67 to 1,00-1,60 fat-soluble dye purple K (W.R. F. K) in the amount of 13.0 to 35.0 wt. or the fat-soluble dye nigrosine (W.R. N.) from 9.7 to 20.0 wt. [3] In the obtained color formulations, respectively, purple and black colors after cooling to room temperature, add with stirring polyvinyl chloride in an amount of from 16 to 35% based on the total weight of the composition. Made of PVC plastisol is poured into metal molds of different sizes subjected to appropriate heat treatment and remove the finished product, print purple or black.

The advantage of [3] is to use only one solvent for the dye enough tonnage of triethylene glycol, and its drawback is a very limited color range of printing products that preclude their use in some areas of technology, in particular, when creating a multi-color printing devices.

The aim of the invention is the expansion of the color gamut microporous printing materials on the basis of available solvents for dyes through the use of additional types of dyes.

This is achieved by a composition comprising polyvinyl chloride, butylbenzylphthalate or its mixture with diethylphthalate, triethyleneglycol now, wt.h. Polyvinyl chloride 100
Butylbenzylphthalate or its mixture with diethylphthalate 80-120 triethylene glycol 35-70 Polyoxyalkylene amerosport 20-40 Dye 7-20
As polyvinyl chloride can be used paste brand, for example, PVC EP, PVC EP-C (GOST 14039-78) or PVC MS-(TU 6-01-1265-81).

The plasticizers of butylbenzylphthalate (BBF) and diethylphthalate(DEF) produced respectively by THE 6-05-1347-75 and GOST 8728-77. Triethylene glycol (TEG) is made by THE 6-01-864-78. As polyoxyalkylene of amerosport use tetracaprylate the Ethylenediamine produced under industrial name Lupranol 294 (TU 6-05-1681-80). You can also use a similar less viscous products, the synthesis of which part of the propylene oxide is replaced by ethylene oxide. These substances have already produced or are preparing to release under the brands of Lupranol M (TU 6-05-221-823-85) or Lupranol 354-2-20.

In the present invention the dyes are rhodamine 4C (TU 6-36-0204192-207-88), fat-soluble nigrosine (TU 6-14-376-76), fat-soluble purple K for ink pastes (TU 6-14-110-80), soluble yellow "C" (THE 6-14-814-77) alcohol-bright red With for pastes ballpoint pens (TU 6-14-815-78), spitroast is with each other.

Yaroslavakot krishnapatnam PVC plastisol, which is a required prerequisite for receiving quality printed products, in patents [1] and [2] is achieved by using the composition are compatible at room temperature plasticizers and solvents for the dye, as in the patent [3] by introducing into the system incompatible plasticizers and solvents some dyes that perform at certain concentrations function of its homogenizers.

In the present invention are incompatible at room temperature plasticizer BBF (or its mixture with WEF) and good solvent different dyes non-deficient TAG, as well as relatively poor solvent for dyes polyoxyalkylene amerosport. This product has found a property homogenized at room temperature the above components and to ensure proslaivaet krishnapatnam plastisol in General. In addition, after heat treatment, the PVC plastisol polyoxyalkylene amerosport together with the TAG and diluted dyes fill the interparticle space of plasticized PVC, form a complex microporous structure and benefit the Noah selection of the coloring composition to the surface of the material obtained, i.e. its a good printing properties.

The positive effect achieved by the introduction to the recipe krishnapatnam PVC-plastisol triethylene glycol and polyoxyalkylene of amerosport obtained experimentally and is not clear from the current level of technology. From this we can conclude that under the present invention, the criterion of "inventive step".

See technical solution can be widely used in the production of multi-colored stamps, stamps, stamp pad, various dye multicolor elements of printing and marking devices, etc.

The composition is prepared as follows. Under stirring and heated from 80 to 140aboutTo prepare a solution of the dye (or dyes) in a mixture of plasticizer, triethylene glycol and polyoxyalkylene of amerosport. (Some dyes, it is advisable to dissolve only in the triethylene glycol and then adding these components). After complete dissolution of the composition is cooled to room temperature and injected into it under stirring paste PVC. Homogeneous Krasnapolsky plastisol, which after removal pusherman at 120-150aboutC. warm-up Time is selected in each case depending on the composition, product weight, number of forms, etc.

P R I m e R 1. At a temperature of from 80 to 140aboutC and stirring prepare a coloring composition comprising the following components, wt.h. BBF 80 TAG 60 Lupranol 294 20 Rhodamine 4C 20
After dissolution of the dye and cooling the composition to room temperature in the mixing portions add 100 wt.h. PVC. Prepared homogeneous PVC-plastisol vacuum to remove air bubbles and poured into metal molds with engraving. After heat treatment of the composition in 120-150aboutC and subsequent cooling to room temperature form of extract microporous stamps, capable of long-term high quality printing crimson.

P R I m m e R 2. In accordance with the description in example 1 is prepared Krasnapolsky PVC plastisol of the following composition, wt.h. Polyvinyl chloride 100 BBF 80 TAG 60 Lupranol M 25 fat-Soluble nigrosine 20
After processing as in example 1 receive microporous stamps giving a large number of clear prints black.

P R I m e R 3. Analogously to example 1 is prepared krishnamani aremy name-
violet K for ink pastes 20
After heat treatment at 120-150aboutWith the song, drenched in a flat metal forms, get a quality stamp pillow purple color, providing tens of thousands of prints.

P R I m e R 4. According to example 1 is prepared Krasnapolsky PVC plastisol of the following composition, wt.h. Polyvinyl chloride 100 BBF 80 TAG 35 Lupranol 294 20 Rhodamine 4C 7
Soluble yellow "C" 8
After thermoforming the composition of example 3 receive ink pads in red, capable of prolonged operation.

P R I m e R 5. According to example 1 is prepared Krasnapolsky PVC-plastisol according to the following formulation, by weight.h. Polyvinyl chloride 100 BBF 80 DEF 20 TAG 51 Lupranol 294 20 Soluble blue phtalocyanines 9
After processing as in example 1 receive microporous stamps, giving a large number of clear blue prints.

P R I m e R 6. According to example 1 is prepared Krasnapolsky PVC plastisol of the following composition, wt.h. Polyvinyl chloride 100 BBF 80 TEG 40 Lupranol 354-2-20 20
Alcohol
bright red With for pastes ballpoint pens 20
The composition is poured into a cylindrical metal mold with iswow print is bright red in color.

P R I m e R 7. According to example 1 is prepared Krasnapolsky PVC plastisol of the following composition, wt.h. Polyvinyl chloride 100 BBF 50 DEF 50 TAG 42 Lupranol 294 40 Soluble blue phtalocyanines 6 Soluble yellow "C" 1
After processing as in example 1 receive microporous stamps, giving a large number of clear prints green.

P R I m e R 8. According to example 1 is prepared Krasnapolsky PVC plastisol of the following composition, wt.h. Polyvinyl chloride 100 BBF 80 TAG 35 Lupranol 294 10 Rhodamine 4C 7 Soluble yellow "C" 8
The composition is unstable in time and splits after 1-3 h, and stamp cushion on its basis have weak krasnoarmiys ability. This experience shows that the introduction of polyoxyalkylene alcohol in quantity is less than the offer leads to technological difficulties and poor quality products.

P R I m e R 9. According to example 1 is prepared Krasnapolsky PVC plastisol of the following composition, wt.h. Polyvinyl chloride 100 BBF 80 TAG 35 Lupranol 294 50 Rhodamine 4C 7
Soluble yellow "C" 8
The compositions are stable in time, but after thermoforming according to example 3 is sticky stamp cushion with high craccato alcohol in amounts greater than the offer leads to poor quality products.

P R I m e R 10. According to example 1 is prepared traceability PVC plastisol of the following composition, wt.h. Polyvinyl chloride 100 BBF 100 TAG 40 Lupranol 294 20 fat-Soluble nigrosine 20
The composition is stable in time and does not separate for a long time. After thermoforming according to example 3 is obtained stamp pillow, giving a large number of quality prints in black.

P R I m e R 11 (the prototype). According to example 1 is prepared Krasnapolsky PVC plastisol of the following composition, wt.h. Polyvinyl chloride 100 BBF 100 TAG 60 Soluble blue phtalocyanines 30
The concentration of dye in the mixture of plasticizer and solvent is 15.8 wt. including Coloring solution and PVC-plastisol based on it quickly exfoliate, making it unsuitable for processing in high-quality print products.

P R I m e R 12 (the prototype). According to example 1 is prepared Krasnapolsky PVC plastisol of the following composition, wt.h. Polyvinyl chloride 100 BBF 80 TAG 55 Rhodamine 4C 7 Soluble yellow "C" 8
The concentration of dyes in the mixture of plasticizer and solvent is 10.0 wt. Coloring solution and PVC-plastisol based on it quickly splits, making it unsuitable for pererabotki-plastisols and qualitative characteristics derived from these products are presented in the table. The compositions of examples 1-7, 10 made in accordance with the invention. In examples 8 and 9 polyoxyalkylene amerosport taken in quantity, respectively, below the lower and above the upper limit of the proposed composition, resulting in poor quality printing products. Examples 11 and 12 made in accordance with the prototype.

COMPOSITION FOR MICROPOROUS KRASAVICAAAAA MATERIAL including polyvinyl chloride, butylbenzylphthalate or its mixture with diethylphthalate, triethylene glycol and dye, characterized in that it further comprises polyoxyalkylene amerosport when asking it the ratio of components, wt.h.:
Polyvinyl chloride - 100
Butylbenzylphthalate or its mixture with diethylphthalate - 80 - 120
Triethylene glycol - 35 - 70
Polyoxyalkylene amerosport - 20 - 40
Dye - 7 - 20

 

 

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