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Directional hardening of metal teemed in mould. RU patent 2520282.

Directional hardening of metal teemed in mould. RU patent 2520282.
IPC classes for russian patent Directional hardening of metal teemed in mould. RU patent 2520282. (RU 2520282):

B22D27/04 - Influencing the temperature of the metal, e.g. by heating or cooling the mould (cooling of open-ended moulds in continuous casting B22D0011055000)
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FIELD: metallurgy.

SUBSTANCE: proposed method comprises application of different-composition protective-separation coatings on the mould surface before teeming of fused metal. Coating, 0.1-0.2 mm thick, consisting of ultrafine powder of magnesium oxide in amount of 20-25 wt % and industrial oil in amount of 78-80 wt %. Coating, 0.2-0.3 mm thick, consisting of ultrafine powder of zirconium oxide in amount of 20-25 wt % and industrial oil in amount of 75-80 wt %. Coating, 0.3-0.4 mm thick, consisting of ultrafine powder of zirconium oxide in amount of 20-25 wt % and industrial oil in amount of 75-80 wt %.

EFFECT: directed crystallisation of metal, higher strength of casts.

1 dwg, 1 ex

 

The invention relates to the field of foundry production, namely the method of directional solidification filled in form of the metal.

The known method of directional solidification filled in the form (metal Buildover. Metallurgy is the same yesterday, today, tomorrow. Kiev: Naukova Dumka, 1990, str, RIS).

Its disadvantage is the difficulty of play of the results obtained from ingot to the bullion due to the lack of backward linkages, providing an opportunity of correction operational parameters of ingot solidification.

The known method of casting the disk and the ring blanks of heat-resistant hard alloys on a Nickel basis. The method includes the vacuum-induction smelting alloy with obtaining raw materials procurement, manufacturing ceramic forms, melting raw materials procurement heat-resistant alloy, fill melt in ceramic form and conduct directed crystallization in ceramic form. Ceramic mold made from the outer, the inner parts and the insertion of partitions. The inner part of the ceramic form installed at the bottom of the outer part. The space between the inner wall of the outer part and the outer wall of the internal parts in height inserts-partitions into parts, equal to the height of blanks. In boxes with holes, through which carry out the filling and feeding downstream blanks in the process of directional crystallization casting. Reduced complexity of manufacturing of details, increase the utilization of metal.

The disadvantages of this method are the limitations of using only a Nickel-based alloys, as well as complex and costly mold. The method may not be used without the need to readjust the equipment in standard conditions.

The known method of directional solidification filled in the form of metal (RF patent №2392092 from 02.07.2008). The method includes control of the process of crystallization in uniform, equipped with means of ensuring temperature difference in the direction crystallization of metal. Use a circular shape with a tapered inner surface. The temperature difference in the direction crystallization of metal is carried out by means of simultaneous cooling of annular shape from the bottom and its internal surface and heating metal in its upper part. Improved quality of castings.

The disadvantage of this method is complicated and expensive mold, as well as the inability to apply without readjustment of the equipment under standard conditions.

Closest to the claimed method is a method that is described in the patent №1680441 from 30.09.1991. The method consists in the fact that the pouring of molten metal produce in the mold coated with its internal surface coating thickness of 0.3-1.5 mm, short warmed up by means of an electric current with voltage 30-400 Century Floor consists of a mixture of graphite powder, alumina and gel SiO2 as a binder allocated from hydrolyzed solution of ethyl silicate, taken in the ratio,%: graphite 17-40, SiO 2 12-19, alumina else. The number of graphite coating changes within the specified limits, increasing from casting to supply parts of the Gating system. The electric current is led to the mold and poured the metal in the ladle.

The disadvantage of this method is the need for additional equipment and electric power for heating cover and chill mould, the need to prepare mixtures of different composition for different quantities of graphite in the floor in different parts of the mold.

The objective of the invention is a way to use without readjustment of the equipment under standard conditions.

The task is achieved by the fact that before pouring molten metal into the mold, on the part of its surfaces are applied protective-release covering various compositions. On the lower part of the walls of the mold coated, consisting of ultrafine powder of magnesium oxide 20-25% by weight and industrial oils 75-80% by weight the thickness of 0.1-0.2 mm In the middle part of the mold coated, consisting of ultrafine powder of zirconium oxide 20-25% by weight and industrial oils 75-80% by weight thickness of 0,2-0,3 mm On the top of the mold coated, consisting of ultrafine powder of zirconium oxide 20-25% by weight and industrial oils 75-80% by weight thickness of 0,3-0,4 mm

As a result, after pouring molten metal of the most intense heat goes through the bottom of the mold that is not coated. Less intense heat goes through the lower part of the walls of the mold coated, based on the powder of magnesium oxide. And the least intense heat goes through the middle and upper parts of the walls of the mold, where the coating based on zirconium oxide, as zirconium oxide has a lower thermal conductivity compared to magnesium oxide and thickness of coating layer Zirconia more. Thus, a directional heatsink on top of the casting to the bottom of the mold, this creates the necessary conditions for the directed crystallization of the melt.

The use of the proposed method of directional solidification of metal, ceteris paribus, can improve the quality alloyed and unalloyed metal, provides the possibility of reducing the consumption of alloying additives in metal for low-duty parts and high quality metal for the manufacture of critical parts.

Figure 1 shows: on the lower part surface of the mold 1 cause 2 floor, consisting of ultrafine powder of magnesium oxide 20-25% by weight and industrial oils 75-80% by weight the thickness of 0.1-0.2 mm In the middle part of the mold coated 3, consisting of ultrafine powder of zirconium oxide 20-25% by weight and industrial oils 75-80% by weight thickness of 0,2-0,3 mm On the top of the mold coated 4, consisting of ultrafine powder of zirconium oxide 20-25% by weight and industrial oils 75-80% by weight thickness of 0,3-0,4 mm

This ratio is explained by the fact that in a larger quantity of oil in the floor, it will not have sufficient strength and will run off with the coated surface, and with fewer oil coating is thicker in composition and will not ensure uniform application of the coating on the walls of the mold. Thickness of the applied coating is limited to the value of 0.5 mm, with a greater thickness of the coating will flow down from the walls of the form. Different coatings are necessary for the formation of directional crystallization front. The presence of three zones with different thickness of the coating is because fewer zones will be formed in front of directional crystallization and more areas will lead to the complication of technologies.

Summary of the invention consists in the following: applied to the surface of the mold protective separation layer prevents the direct contact of molten metal with metal form, reducing heat sink. The bottom of the mold is not covered with protective separation coated and will dissipate heat quickly. On the lower part of the mold coating on the basis of nanopowder magnesium oxide, it significantly reduces the heat sink. In the middle part of the mold is applied thicker layer coatings on the basis of nanopowder zirconium dioxide. Powder Zirconia has a much lower conductivity compared to powder magnesium oxide, it will lead to a significant reduction of the heat sink in the middle of the form. Minimum heat sink be at the top of the mold because of the presence of the coating on the basis of zirconium dioxide maximum thickness. Thus creates a directional heatsink from flooded metal to the bottom of the mold. This ensures directional crystallization of ingot and formation of high strength properties of castings.

Example.

On the lower part surface of the mold coated, consisting of ultrafine powder of magnesium oxide 20 wt.% and industrial oils 80% thickness of 0,15 mm At the middle part of the mold coated, consisting of ultrafine powder of zirconium oxide 22% and industrial oils 78% by weight thickness of 0,25 mm On top of the mold coated, consisting of ultrafine powder of zirconium oxide 22% and industrial oils 78% by weight thickness 0,35 mm, Then the mold is filled with molten alloy. The melt solidifies, mold cools, casting is pulled.

The method of directional solidification of metal into the mold with on its surface protective-dividing coverings with different composition that includes a fill in the mold of molten metal, wherein use a mold, on the lower part of the walls which are coated consisting of ultrafine powder of magnesium oxide 20-25% by weight and industrial oils 75-80% by weight the thickness of 0.1-0.2 mm at the middle part of the walls - floor, consisting of ultrafine powder of zirconium oxide 20-25% by weight and industrial oils 75-80% by weight thickness of 0,2-0,3 mm, and on the upper part of the walls - floor, consisting of ultrafine powder of zirconium oxide 20-25% by weight and industrial oils 75-80% by weight thickness of 0,3-0,4 mm

 

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