Metal lithium superdispersed deposited powder |
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IPC classes for russian patent Metal lithium superdispersed deposited powder (RU 2513987):
 Catalytic electrode for alcohol fuel elements / 2507640
Invention relates to a catalytic electrode for membrane-electrode blocks of alcohol (using methanol or ethanol as fuel) fuel elements, where the electric catalytic material is an electroconductive titanium dioxide alloyed with ruthenium oxide with the ruthenium to titanium ratio from 4 to 7 mol %, with platinum nanoparticles with size of 3-5 nm applied on the surface of the spherical particles of titanium oxide alloyed with ruthenium.
 Stiff compartment of negative electrode for metal-air battery and method of its manufacturing / 2503099
Invention relates to a precursor of a compartment of a negative electrode for rechargeable metal-air batteries, comprising a stiff body (1), at least one membrane (2) of solid electrolyte, a protective coating (5) fully covering the inner surface of the membrane (2) of solid electrolyte, a metal current collector (3), pressed to the inner surface of the protective coating (5), and also preferably a unit (4) of elastic material pressed to the current collector and substantially filling all internal space formed by walls of the rigid body and solid electrolyte (2), and also a flexible electronic conductor (6), tightly stretching via one of the walls of the stiff body. This invention also relates to a compartment of a negative electrode with a stiff body produced from the specified precursor, and to a battery comprising the specified compartment of the negative electrode. The suggested "precursor" corresponds to the empty compartment of the negative electrode, which is filled as a result of an electrochemical reaction and has sufficient mechanical strength.
 Method of producing carbon composite material / 2501128
Invention discloses a method of producing a carbon composite material, which includes a step of providing at least one nanostructured carbon composite material on the surface of LiFePO4 particles to obtain a LiFePO4/carbon nanostructured composite material. The nanostructured carbon composite material is obtained via synthesis of at least one nanostructured composite material in order to form a nanostructured carbon composite material.
 Negative electrode for lithium-ion secondary battery and battery with use of such electrode / 2501126
Invention suggests negative electrode for lithium-ion secondary battery that includes conducting substrate, a layer for active material of negative electrode that contains active material that is capable to absorb and desorb lithium ions and conducting element having less elastic modulus than elastic modulus of conducting substrate. At that at least part of active material for negative electrode is connected to conducting substrate through conducting element that contains conducting chained carbon material that has less elastic modulus than elastic modulus of conducting substrate. Lithium-ion secondary battery with such negative electrode is suggested.
 Material of positive electrode for electric device and electric device made with its usage / 2499333
Material of a positive electrode for an electric device is represented with the following formula: aLi[L1/3Mn2/3]O2×(1-a)Li[NixCoyMn1-x-y]O2 (where 0<a<1, 0<x<0.5 and 0<y<0.3) and meets the expression of the ratio 2x+y<1.
 Method to produce nanostructured multilayer 3d composite material for negative electrode of lithium-ion battery, composite material, negative electrode and lithium-ion battery / 2459319
At the first stage of the method realisation on a current-conducting substrate by a method of plasma-chemical synthesis from a gas phase in a plasma of an electric DC charge, a layer of a film of a nanocrystalline graphite is formed in the form of a 3D nanocarbon structure, and on the second stage a 3D composite material is formed, for this purpose the film grown on the first stage is conformally coated with at least one layer of active anode material, such as a silicon-containing material applied above the film in an even layer with thickness of 0.03-0.5 mcm.
 Anode active material of hull-kernel type for lithium secondary batteries, method to make such material and lithium secondary batteries containing such material / 2436201
Anode active material of hull-kernel type for lithium secondary batteries comprises a kernel of carbon-containing material by means of dry coating of a kernel from a carbon-containing material with a shell containing a material with PTC (positive temperature coefficient).
 Active cathode material for rechargeable lithium cells / 2430449
Proposed material comprises mixed lithium and transition metal oxide represented by the following formula containing surplus lithium and nickel with mean oxidation degree exceeding 2+ to display improved rate characteristics at high charge/discharge rates: Li1+aNi'bNi"cMndCoeO2 (I), where a, b, c, d and e are determined by equation 1.1 ≤(1+a)/(b+c+d+e)<1.3; mean oxidation degree of each said transition metal element id represented as follows: Ni'>2+, Ni"=3+, Mn=4+ and Co=3+; 0≤e≤0,1; 0.2<b+c≤0.55, 0.2<d≤0.55 and l(b+c)-d|≤0.1.
 Manufacturing method of active mass of cathode of lithium battery / 2424600
In manufacturing method of lithium-titanium phosphate, which consists in the fact that titanium oxide is mixed with ammonium dihydrogen phosphate and lithium hydroxide on dry basis with further mechanical activation and two-stage heat treatment at temperature of 400°C during 4 hours and at temperature of 800°C during 4 hours, according to invention at the first stage titanium oxide is mixed with ammonium dihydrogen phosphate and lithium hydroxide is added during mechanical activation by plastic flow at torsion at pressure of not less than 1.8 GPa and relative deformation values of 18-20.
 Manufacturing method of active mass of cathode of lithium current source / 2424599
In manufacturing method of lithium-ferrum phosphate, which consists in the fact that iron oxide is mixed with ammonium dihydrogen phosphate and lithium hydroxide on dry basis with further mechanical activation and two-stage heat treatment at temperature of 400°C during 4 hours, at temperature of 600°C during 4 hours, according to invention at the first stage iron oxide is mixed with ammonium dihydrogen phosphate and lithium hydroxide is added during plastic flow at torsion at pressure of not less than 2.0 GPa and relative deformation values of 20-22.
 Creation method of porous coating on metal electrically conducting carrier / 2499332
In a creation method of porous material, on electrically conducting metal carrier there formed for the purpose of increasing specific surface and porosity is a catalytic active layer on metal carrier by means of high-energy processes of gas-phase transfer, and namely by microplasma or cold gas-dynamic sputtering of composite powder mixture consisting of metal powder-base and pore agent; with that, the obtained coating as a result of sputtering is subject to heat treatment at the temperature of decomposition of pore agent into solid-phase and steam-gas components; as a result, gaseous component is removed through the coating, thus forming through pores, and solid-phase component is deposited on walls of pores, thus considerably increasing an integral specific coating surface.
 Electrode and its manufacturing method / 2497239
Electrode includes a conducting current collector having a resin layer and an active material layer, which is formed on the current collector. Active material layer includes an active material layer of positive electrode on one side of the conducting current collector and active material layer of negative electrode on opposite side of the conducting current collector. Resin layer of current collector is connected by means of connection through thermal fusion to active material layer.
 Manufacturing method of cathode of lithium current source / 2488196
Result is achieved due to increase in homogeneity of electrode active mass and increase of lithium diffusion coefficient; for this purpose in the suggested method active mass is mixed with electroconductive additive, the received mass is saturated with solution of polymer electrolyte, cathode mass is dried and grinded in ball crusher and press-fitted to current tap; at that after drying cathode mass is treated additionally in plastic yield process at torsion under pressure of at least 1.7 GPa and relative strain of 22-24.
 Chemical cell anode and method of making said anode / 2487441
Disclosed anode contains, wt %: magnesium 5-6, scandium 0.17-0.25, zirconium 0.05-0.12, beryllium 0.0001-0.005, copper 0.01-0.05, manganese 0.25-0.4, and inevitable impurities, including not more than 0.15 wt % iron and not more than 0.1 wt % silicon, having a structure which consists of grains of a solid solution having an elongated shape and thickness of 1-10 mcm, inclusions of aluminium-scandium-zirconium and aluminium-manganese-iron intermetallic phases and magnesium-silicon phases with size of 2-10 mcm and dispersed particles of the aluminium-scandium-zirconium phase with size of 2-10 nm. The disclosed method of making an anode of said composition involves melting an ingot of an alloy in form of a solid solution based on aluminium, with grain size and size of 30-90 mcm, with inclusion of intermetallic phases, homogenising annealing of the ingot, pressing the ingot into a strip, annealing the strip, straightening the strip by stretching and cutting an anode of given size.
 Method of producing cathode material with olivine structure for lithium self-contained power generation / 2482572
Invention can be used to produce cathode materials with an olivine structure for lithium self-contained power generation (hybrid transport, electric cars, buffer systems for energy storage etc). The method involves mixing a lithium salt Li2CO3, iron (III) oxide Fe2O3, citric acid and ammonium dihydrophosphate in stoichiometric ratio. Particles of the mixture are ground in ball mill in acetone medium and subsequent heat treatment is carried out at temperature of 350°C-650°C.
 Method to manufacture thin-film anode of lithium-ion accumulators based on films of nanostructured silicon coated with silicon dioxide / 2474011
Thin-film material is formed from nanosize clusters of silicon in a shell of silicon dioxide, which are produced in a single stage by magnetron sputtering of a silicon target in plasma containing argon and controlled additives of oxygen. The specified nanostructured films are produced in the plasma of the magnetron discharge, containing 1-3% of oxygen by volume in argon. Content of the silicon dioxide in the film is within 16-41 wt %, and the nanostructured silicon in the shell of silicon dioxide has a cluster structure with cluster size of 5-15 nm.
 Novel highly stable aqueous solution, nano-coated electrode for preparing said solution and method of making said electrode / 2472713
Invention relates to disinfectant compositions and specifically to a highly stable acidic aqueous solution, a method and apparatus for production thereof. The solution is prepared using a fluid medium treatment apparatus having at least one chamber (7), at least one anode (4) and at least one cathode (3) inside the chamber (7). The anode (4) and the cathode (3) are at least in part made from a first metallic material. At least one of said at least one cathode (3) and anode (4) have a coating with nanoparticles (5) of one or more metals.
 Method and device for drying of electrode material / 2435253
In the proposed method the sections of an electrode material containing a dissolvent are distanced from each other on a metal foil. An induction coil that provides for induction heating of the metal foil faces the metal foil. The amount of heat supplied to a non-coated section of the metal foil between the sections of the electrode material is reduced below the amount of heat supplied to the coated section of the metal foil, where the electrode material sections are arranged. Heating evaporates the dissolvent at the sections of the electrode material, making the metal foil release heat due to induction heating as the metal foil and the induction coil move relative to each other, in direction of location, i.e. in direction, where the sections of the electrode material are placed.
 Method of electrode production / 2402839
Electrode production method involves application of a coating onto a substrate by way of supersonic "cold" gas-dynamic spraying with the help of three simultaneously operating dispensers containing corundum, copper and a catalytic composition based on Ni-Al system intermetallides with subsequent etching and drying. The method provides for application of a catalytic layer onto the meal substrate surface being activated, smooth increase of the catalyst content from the substrate to the coating surface in linear fashion and development of porosity in the course of the concluding etching operation. The method increases the coating catalytic activity due to exclusion of partial decomposition of the catalyst during spraying and development of the coating porosity during etching.
 Electrode and method of making said electrode / 2391748
Electrode (30) has a plate (31) which has a main surface to which a separate relief template (32) was initially attached for directing deposition and/or holding electrolyte paste adjacent to the plate (31).
 Application method of thermal-protective nanostructured coating with plasma sputtering of powder / 2483140
Maintenance of dynamic vacuum in a chamber for coating application is performed and alternating sputtering of the coating layer with porosity of 0.1-0.2% is performed; it consists of fine particles and nanoparticles of the powder using an under-expanded plasma jet at maintaining the chamber dynamic vacuum with the pressure that is lower than static pressure in the plasma jet with sputtered powder at the chamber inlet, and then, sputtering of the coating layers is performed with porosity of 3.5-5.0%; it consists of plasticised powder particles using an over-expanded plasma jet at maintaining in the chamber of dynamic vacuum with the pressure that is higher than static pressure in the plasma jet with the sputtered powder at the chamber inlet. Alternating sputtering is performed till the required coating is obtained.
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FIELD: process engineering. SUBSTANCE: invention relates to super disperse deposition of metal lithium powder or thin lithium foil of substrate without solvents. Proposed method comprises deposition of metal lithium powder or thin lithium film of carrier. Said carrier is brought in contact with substrate of higher affinity to metal lithium powder compared with that of carrier to said powder. Said substrate in contact with carrier is subjected to conditions sufficient for transfer of deposited powder or film on said substrate. Carrier and substrate are separated to preserve said powder of film deposited on said substrate. EFFECT: ruled out reduction in lithium cell charge capacity. 12 cl, 2 dwg, 9 ex, 1 tbl
CROSS-REFERENCE TO RELATED APPLICATIONS [0001] This application claims the priority of provisional application U.S. serial number 61/266308, filed December 3, 2009, the contents of which are incorporated here by reference in its entirety. SCOPE AND BACKGROUND of the INVENTION [0002] the Present invention relates to a method of finely dispersed precipitation of lithium metal powder on the substrate. This tonkodispersnoe precipitated powder metal lithium can be used, for example, in the formation of the electrode for the primary or secondary (rechargeable) batteries. [0003] lithium and Lithium-ion secondary, or rechargeable, batteries have been used in certain areas, such as mobile phones, camcorders, and portable computers, and more recently even in devices with higher power, such as electric vehicles and hybrid electric vehicles. In these embodiments, the application preferably, the secondary battery had the highest specific capacity, but still provide safe conditions and good cycloramas so that a high specific capacity was maintained in subsequent cycles of discharging and charging. [0004] Although there are various designs of secondary batteries, each design includes a positive electrode (or Kato is), the negative electrode (or anode), a separator that separates the cathode and anode, and an electrolyte in electrochemical communication with the cathode and anode. In a secondary lithium ion battery, lithium ions migrate from the anode to the cathode through the electrolyte, when the secondary battery is discharged, that is used for its intended purpose. During the discharging process, the electrons are collected from the anode and pass through to the cathode through an external circuit. When the secondary battery charge or recharge, the lithium ions are transferred from the cathode to the anode through the electrolyte. [0005] Historically, the lithium secondary battery received with use as cathode active materials militiaman compounds with high specific capacity, such as TiS2, MoS2, MnO2and V2O5. These cathode active materials combined with the anode of metallic lithium. When the secondary battery is discharged, lithium ions were transferred from the lithium metal anode to the cathode through the electrolyte. Unfortunately, when Cycling metallic lithium was formed dendrites, which eventually led to dangerous conditions in the battery. As a result, the production of secondary batteries of these types in the early 1990-ies was discontinued in favor of lithium-ion batteries. [0006] lithium-ion batteries usually as a cathode active material used in the t of the oxides of lithium-metal such as LiCoO2and LiNiO2in combination with the anode on a carbon basis. In these batteries eliminated the formation of lithium dendrites on the anode, and thereby batteries are made safer. However, Li, "useful", the number of which determines the capacity of the battery, fully supplied from the cathode. This limits the choice of cathode active materials as active materials must contain recoverable lithium. In addition, deleteelement products formed during charging and over-charging, tend to be unstable. In particular, these deleteregvalue products tend to react with the electrolyte and to highlight the warmth that exacerbates the security problems. [0007] in Addition, the new lithium-ion cells or batteries are in a discharged state. During the first charge lithium-ion element lithium moves from the cathode material, such as LiCoO2or LiNiO2to the anode material, such as graphite. Passivation film, which is formed on the anode, called the solid electrolyte layer, or SEI (from the English. solid electrolyte interface). The SEI film occurs due to the electrochemical reduction of the substances present in the electrolyte at the electrode surface. Subsequent discharge of lithium consumed in the formation of the SEI does not return to the cathode. This causes the lithium-ion element, having smaller capacity compared to the original charging capacity, because some of the lithium was consumed in the formation of SEI. Irreversible expenditure of available lithium reduces the capacity Li-ion item. This phenomenon is called irreversible capacity and, as you know, absorbs about 10% to 20% of the capacity of conventional lithium-ion element. Thus, after the initial charge of lithium-ion element Li-ion cell loses approximately 10% to 20% of its capacity. [0008] One solution was the use of a powder of stabilized lithium metal ("SLMP®") for pre-litvinovna anode. For example, powder of lithium can be stabilized by surface passivation of metal powder by the action of CO2so, as described in U.S. patent No. 5567474, 5776369 and 5976403, the contents of which are included here by reference in its entirety. However passivated by the action of CO2the lithium metal powder can be applied only in the air with low humidity levels within a limited period of time before the content of metallic lithium will fall due to the reaction of metallic lithium with air. Another solution consists of applying a fluorinated coating on the lithium metal powder as described in U.S. patent No. 7588623, soda is the content of which is included here by reference in its entirety. Another solution is to create a wax layer, such as described in the publication U.S. No. 2009/A, the contents of which are incorporated here by reference in its entirety. However, there remains a need for improved methods of powder deposition of metallic lithium on a variety of substrates for forming a battery. The INVENTION [0009] the Present invention provides a method of finely dispersed precipitation of lithium metal powder or formed by powder lithium thin foil on a substrate, avoiding the use of solvent. The method includes the deposition of lithium metal powder on the carrier, bringing the carrier into contact with the substrate having a higher affinity for the metal powder of lithium compared with the affinity of the carrier for the powder metal lithium, the exposure of the substrate in contact with the carrier, the conditions sufficient to transfer deposited on the carrier powder of metallic lithium on a substrate, and the separation of the carrier and the substrate to retain the powder metal lithium tonkodispersnoe deposited on the substrate. Optionally, instead of lithium metal powder may be used formed by powder lithium thin foil. Also provides a battery comprising a substrate formed with the t is one method. BRIEF DESCRIPTION of DRAWINGS [0010] the Above objectives and advantages of the present invention will become clearer from the detailed description of the options for implementing the present invention involving accompanying drawings, in which: [0011] Figure 1 represents the voltage curve of the first cycle, corresponding to Example 7. [0012] Figure 2 is a curve of the voltage of the first cycle, corresponding to Example 8. DETAILED description of the INVENTION [0013] the terminology Used here is intended solely for the purpose of describing a particular implementation options and is not intended to limit the invention. Used herein, the term "and/or" includes any and all combinations of one or more of the associated listed items. Forms used here in the singular assumed also includes the plural, unless the context clearly indicates otherwise. In addition, it will be understood that the terms "includes" and/or "comprising", as used in this description, means the presence of these features, integers, steps, operations, elements and/or components, but do not preclude the presence or addition of one or more other features, integers, steps, operations, elements, components and/or groups. [0014] Unless otherwise noted, all used the s here, the terms (including technical and scientific terms have the same meaning as it is commonly understood by a person of ordinary skill in the art to which belongs the present invention. In addition, it will be understood that terms such as those defined in commonly used dictionaries, should be interpreted as having a meaning that is consistent with their meaning in the context of the relevant art and will not be interpreted in an idealized or overly formal sense unless it is not clearly defined here. [0015] In accordance with the present invention, the lithium metal powder tonkodispersnoe precipitated on a substrate without the use of solvent. The lithium metal powder is in the form of thin-dispersed powder. The lithium metal powder typically has an average particle size less than about 60 microns, and often less than about 40 microns. The lithium metal powder may be in the form of a powder of stabilized lithium metal ("SLMP®"), such as described, for example, in U.S. patent No. 5976403 and 6706447, the contents of which are included here by reference in its entirety. [0016] If used formed by powder lithium slim lithium foil, it will have a thickness of about 20 microns or less. [0017] the lithium metal Powder is first precipitated on the carrier. The media can be a synthetic is s or semi-synthetic amorphous solid polymer, cellulose, glass, metal (e.g., metal foil) or separator material (e.g. polypropylene, polyethylene or a laminate of them). For example, a sample of solid polymers include polypropylene film (for example, film InteToppTMType AA), polyethylene, or a complex of the polyester. Exemplary metal carriers include foil made of copper (Cu) or copper alloy. In one implementation, the surface of the carrier may include various additives to improve the processing performance, reduce cost, and to change the affinity of the carrier for the powder metal lithium. The carrier may be in the form of a film, foil, mesh or the like. The media often has a thickness of from 10 microns to 200 microns. The purpose of media is to deposition or migration of the lithium metal powder on the substrate. The carrier has an affinity for the metal powder of lithium; however, its affinity is lower than the affinity for the substrate, which must be precipitated powder of metallic lithium. If you use formed from a powder of lithium slim lithium foil, it may be printed or deposited using the same procedure as for the transfer of a powder of lithium, with the application of appropriate pressure. Alternatively, the carrier may be applied binder, such as EVA, SBR, wax, etc. Then n is Khabibullina can be electrostatically precipitated SLMP ®. [0018] the lithium metal Powder may be deposited on the carrier by the method of screening, spraying, coating, printing, painting, dipping, and the like, the choice of which will be within the competence of the specialist in this field of technology. It could also be precipitated using the technology of deposition in the stream of vapor high pressure settling in the gas flow and the like, which provide a very high deposition rate and the deposition without the use of solvent with the use of mechanical forces. [0019] the Substrate has a higher affinity for the metal powder of lithium compared with the affinity of the carrier for the powder metal lithium. Suitable substrates may include carbonaceous materials, Li4Ti5O12and other materials introduction lithium, Si, Sn, Cu, SiO, oxides of tin, alloys of tin, alloys of transition metals, nitrides of lithium-metal oxides, lithium metal, and their mixtures and composites, as well as Cu-th foil and other metal alloys. The substrate can be processed or brought into contact with the means to promote affinity of lithium metal powder to the substrate. Suitable stimulating affinity tools include a polymeric binder, such as vinyl acetate, butadiene-styrene rubber, butadiene rubber and the copolymer ethyl is a-propylene-diene monomer, natural waxes, such as 12-hydroxystearate acid, synthetic waxes such as polyethylene with a low molecular weight, petroleum waxes such as paraffin wax and microcrystalline wax. [0020] During operation, the media usually pripressovyvajut to the substrate under pressure, such as from 100 to 20000 psi (pounds per square inch). Using the affinity of lithium metal powder on the substrate to create non-continuous (intermittent) layer of lithium metal powder. Additionally, the lithium metal powder is deformed during its deposition. [0021] the Substrate may be in the form of the electrode surface. After the powder of the metallic lithium deposited, the carrier and the substrate can be separated in a way that is sufficient to preserve the lithium metal powder on the substrate. [0022] the Substrate can be used in a wide range of applications, in which the desirable properties of the lithium metal powder. For example, the substrate may be formed in the anode for the secondary battery, such as described in U.S. patent No. 6706447, the content of which is incorporated here by reference in its entirety. A typical secondary battery includes a positive electrode, or cathode, the negative electrode, or anode, a separator for separating the positive electrode and the negative electron is kind, and an electrolyte in electrochemical communication with the positive electrode and negative electrode. The secondary battery includes a current collector, which is in electrical contact with the cathode and the current collector, which is in electrical contact with the anode. The current collectors are in electrical contact with each other through an external circuit. The secondary battery may be any known in the art design, such as "jelly roll" (roll gel"), or batch design. [0023] the Cathode is formed of the active material, which is usually combined with the carbonaceous material and a polymeric binder. The active material used in the cathode, and preferably is a material that can be Litvinova when a suitable voltage (e.g., from 2.0 to 5.0 V relative to lithium). Preferably, the active material can be used deletirovanie materials, such as MnO2V2O5, MoS2, metal fluorides, or mixtures thereof, and more preferably used MnO2. However, it can also be applied lityeraturnyye materials such as LiMn2O4that may be additionally literaaly. Deletirovanie active materials are preferred because they generally have higher specific capacity, mengchu the cost and provide more choice, than lityeraturnyye active materials in this design, and thus can provide increased capacity, as compared with the secondary batteries that include lityeraturnyye active materials. In addition, since the anode includes lithium, as discussed below, for operation of the secondary battery is not necessary that the cathode included litigiously material. The amount of active material provided in the cathode, is preferably sufficient to receive the extracted metallic lithium present in the anode. [0024] the Anode is formed from a substrate capable of absorbing and decarbonate lithium in an electrochemical system. [0025] Other potential applications of the substrate include a current collector for primary batteries, the surface of the polypropylene high density, which could be used to manufacture parts of the neutron detector. [0026] the Following examples are only illustrative for the invention and not limit it. EXAMPLES Example 1 [0027] the polypropylene film InteToppTMType AA with an area of 50 cm2besieged 12 mg SLMP®. Then the film carrier SLMP slightly priateli using polypropylene cushion for jewelry work, so that the particles stuck to the film. Then the film carrier brought into contact with the carbon electrode of the battery with an area of 50 cm 2. Then the package of the film carrier and the electrode was pressed with a force of 1500 pounds. After pressing the tape was taken away millimetre from the electrode, having besieged approximately 8 mg of lithium (about 0.16 mg/cm2). Example 2 [0028] the polypropylene film InteToppTMType AA with an area of 284 cm2besieged 100 mg SLMP. Then the film carrier SLMP slightly priateli using polypropylene cushion for jewelry work, so that the particles stuck to the film. Then the film carrier brought into contact with the carbon electrode of the battery with an area of 284 cm2. Then the package of the film carrier and the electrode was pressed using a hand roller. After pressing the tape was taken away millimetre from the electrode, having besieged approximately 80 mg of lithium (about 0.4 mg/cm2). Example 3 [0029] the polypropylene film InteToppTMType AA, contains stimulating the adhesion of the EVA tool, napisali SLMP. Then the film carrier brought into contact with the negative electrode of the battery. Then the package of the film carrier and the electrode was pressed. After pressing the tape was taken away millimetre from the electrode, having besieged the layer of thin lithium foil negative electrode. Example 4 [0030] the polypropylene film InteToppTMType AA napisali SLMP with stimulating the adhesion of a coating of EVA. Then the film carrier brought into contact with the negative electrode of the battery. Then the package from plank the carrier and the electrode was pressed. After pressing the tape was taken away millimetre from the electrode, having besieged the layer of thin lithium foil negative electrode. Example 5 [0031] On the treated by corona discharge side of the plastic film of polypropylene InteToppTMType BA with an area of 249 cm2besieged 100 mg SLMP using suspension butadiene-styrene copolymer/BYK-P 104S in toluene in the ratio of SLMP:SBR:BYK = 100:10:5. After evaporation of the solvent the film carrier brought into contact with the copper foil. Then the package of the film carrier and the copper foil was subjected to calandrinia. After calendering polypropylene film was taken away millimetre from the copper foil, having besieged 26 mm layer of thin lithium foil. Example 6 [0032] On the treated by corona discharge side of the plastic film of polypropylene InteToppTMType BA with an area of 249 cm2besieged 48 mg SLMP using suspension butadiene-styrene copolymer/BYK in toluene. After evaporation of the solvent the film carrier brought into contact with the electrode of MCMB-25-28 (90%) + carbon black (3%) + PVdF (7%) with an area of 249 cm2. Then the package of the film carrier and the electrode was subjected to calandrinia. After calendering polypropylene film was taken away millimetre from the electrode, having besieged 47 mg layer thin lithium foil. Example 7 [0033] On the treated by corona discharge side of the plastic film of polypropylene InteToppTMType BA with whom the horse 49 cm 2besieged 5 mg SLMP using suspension butadiene-styrene copolymer/BYK in toluene. After evaporation of the solvent the film carrier brought into contact with the electrode of MCMB-25-28 (90%) + carbon black (3%) + PVdF (7%) with an area of 49 cm2. Then the package of the film carrier and the electrode was subjected to calandrinia. After calendering polypropylene film was taken away millimetre from the electrode, having besieged the layer of thin lithium foil. Then the electrode MCMB 2528 gathered in the item batch against the positive electrode of LiMn2O4(90%) + carbon black (5%) + PVdF (5%). The electrolyte used a 1M solution LiPF6/EC+DEC (1:1) from the firm Novolyte. For comparison, gathered basic elements with the same configuration that does not contain SLMP. After assembling the elements of the batch was tested on the device for Cycling Maccor series 4000. Used testing method was a CC 12 mA to 4.3 V, CV (constant voltage) with a time step equal to 10 hours. The discharge CC (constant current) at 12 mA to 3.0 Century Before the procedure, the Cycling of elements left to Mature for 5 hours, to allow time to complete the process prior litvinovna. Table 1 below summarizes the data for the base and containing SLMP elements in the case of Example 7. Figure 1 shows the voltage curve of the first cycle for the demonstrative base and containing SLMP ELEH the clients.
Example 8 [0034] the separator Celgard® 3501 with an area of 64 cm2besieged 5 mg SLMP using suspension butadiene-styrene copolymer/BYK in toluene. After evaporation of the solvent separator is brought into contact with the electrode of MCMB-2528 (90%) + carbon black (3%) + PVdF (7%) with an area of 49 cm2. Then the package from the separator and the electrode was subjected to calandrinia. After calendering the MCMB electrode 228 and the separator is collected in a batch item type against the positive electrode of LiMn 2O4(90%) + carbon black (5%) + PVdF (5%). The electrolyte used a 1M solution LiPF6/EC+DEC (1:1) from the firm Novolyte. For comparison, gathered basic elements with the same configuration that does not contain SLMP. After assembling the elements of the batch tested on the device for Cycling Maccor series 4000. Used testing method was a CC 12 mA to 4.3 V, CV with a time step equal to 10 hours. The CC discharge at 12 mA to 3.0 Century Before the procedure, the Cycling of elements left to Mature for 5 hours, to allow time to complete the process prior litvinovna. Figure 2 shows voltage traces of the first cycle for the base and containing SLMP elements. Example 9 [0035] On the copper foil with an area of 249 cm2besieged 100 mg SLMP using suspension butadiene-styrene copolymer/BYK in toluene. After evaporation of the solvent the copper foil was subjected to calandrinia, creating 26 mm layer of thin lithium foil on a copper foil. Then the copper current collector plus a thin lithium foil can be used as the negative electrode in the battery. [0036] Having described thus certain implementations of the present invention, it should be clear that the invention defined by the appended claims should not be limited to the specific Podrobnosti the mi, set forth in the above description as possible of its many obvious variations without deviating from the essence or scope, as stated next. 1. The deposition method of the metal powder of lithium on a substrate without the use of solvent, consisting of the following stages: 2. The method according to claim 1, the carrier is an amorphous solid polymer, cellulose or metal. 3. The method according to claim 1, the substrate is a material selected from the group consisting of carbon materials, Li4Ti5O12, Si, Sn, Cu, SiO, oxides of tin, tin alloys, metal foil, conductive polymers, conductive ceramics, oxides of transition metals, nitrides of lithium-metal oxides, lithium metal, and mixtures thereof is whether composites. 4. The method according to claim 1, stage (C) conditions sufficient to transfer the lithium metal powder include the crushing of the carrier and the substrate to each other. 5. The method according to claim 4, when the substrate is a material selected from the group consisting of carbon materials, Li4Ti5O12, Si, Sn, Cu, SiO, oxides of tin, tin alloys, metal foil, conductive polymers, conductive ceramics, oxides of transition metals, nitrides of lithium-metal oxides, lithium metal, and their mixtures or composites. 6. The deposition method of the metal powder of lithium on a substrate without the use of solvent, consisting of the following stages: 7. The method according to claim 6, while Sitel is an amorphous solid polymer, cellulose or metal. 8. The method according to claim 6, the substrate is a material selected from the group consisting of carbon materials, Li4Ti5O12, Si, Sn, Cu, SiO, oxides of tin, tin alloys, metal foil, conductive polymers, conductive ceramics, oxides of transition metals, nitrides of lithium-metal oxides, lithium metal, and their mixtures or composites. 9. The method according to claim 6, stage (C) conditions sufficient to transfer the foil of lithium metal powder include the crushing of the carrier and the substrate to each other. 10. Media for lithium deposition of powder stabilized lithium metal on a substrate without the use of solvent, and said media lithium includes media and besieged it powder metal lithium, and the affinity of the carrier for the powder metal lithium is less than the affinity of lithium metal powder to the substrate. 11. Media for lithium deposition of powder stabilized lithium metal on a substrate without the use of solvent, and said media lithium includes the carrier and deposited on a thin foil of metal lithium, and the affinity of the carrier to the metal lithium thin foil is less than the affinity of metal lit the I to the substrate. 12. Method of forming a battery, including:
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