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Method borehole cil from deep lying placers and man-made mineral formations. RU patent 2504648.

IPC classes for russian patent Method borehole cil from deep lying placers and man-made mineral formations. RU patent 2504648. (RU 2504648):

E21B43/28 - Dissolving minerals other than hydrocarbons, e.g. by an alkaline or acid leaching agent (E21B0043241000 takes precedence);;
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FIELD: oil-and-gas industry.

SUBSTANCE: proposed CIL method comprises injection of activated leaching solution in producing bed via system of injection wells with subsequent extraction of gold. Said leaching solutions are injected via said system of injection wells in separate jets. First, hydrocarbonate-peroxide solution subjected to photo electrochemical processing is injected. Then after a pause, hydrochloric acid plus hydrogen peroxide subjected beforehand to UV radiation are injected. After detention of solution in producing bed till transition of the main portion of gold from mineral bulk into producing solution, perforated capsules with sorbent fitted with electrodes are placed into wells. Voltage is fed to said electrodes for direction diffusion of dissolved gold ions to sorbent and its sorption and extra leaching of gold remained in ore bed. Then sorbent saturated with gold is extracted to be recovered.

EFFECT: higher CIL efficiency.

 

The invention relates to the technology of underground leaching of noble metals, such as gold Sands of deep alluvial or from technogenic mineral formations (tails of enrichment of ores and dumps), and can be used in mining of placer deposits, mainly of the deep-seated by injection of solutions of leaching agents in the reservoir Sands through the system of injection wells and sorption extraction of gold from productive solutions.

Known hydrometallurgical way leaching of gold and silver in alkaline medium (pH=8-13) solution containing 12% chloride and 1% sodium hypochlorite. After cementation of gold and silver, zinc, Hypo-chlorite regenerate by the electrolysis of a solution and return to the leach (see U.S. patent N 4342592, 1982).

Recommended in the patent composition leaching reagent cannot be used for underground leaching for environmental reasons, because of the high content of chloride.

Closest to the claimed method is a method of leaching of metals, in particular gold and silver carried out in two stages. At the first stage of leaching use chlorine solution, and the supply of chlorine is adjusted to a solution had the pH of not less than 3. Surplus of active chlorine in pregnant solution restore before its refining and processing solution perform one of the known methods - sorption, cementation or electrolysis. At the second stage of refinement reservoir continue sodium thiosulfate. At the same time, there is a restoration of unreacted active chlorine and neutralization of water than are provided with ecological requirements to formation waters horizon (see RF patent №2074958, IPC 21 43/28, pub. 10.03.97,).

The disadvantage of this method is low metal recovery due to his loss with working solutions and on particles of clay minerals have sorption active properties.

The technical result of the proposed method is to increase the efficiency of leaching by reducing the loss of gold with working solutions and its on clay minerals.

Result is achieved by the method of leaching of gold from the deeper placers and technogenic mineral formations, including the filing of the productive layer of activated leaching solutions through a system of injection wells with the subsequent extraction of gold, differs in that the supply of leaching solutions through a system of injection wells produced by injection solution separate jets, while initially submit the hydro-peroxide solution subjected photoelectrochemical processing, then, after a pause, submit the solution of hydrochloric acid with the addition of hydrogen peroxide subjected before serving ultraviolet irradiation, after solution in the productive formation to the achievement of transition the main part of the gold from mineral mass in productive solution in wells placed perforated capsules with a sorbent, equipped with electrodes and serves on the electrode voltage to provide directional diffusion of ions dissolved gold to sorbent and its sorption and remaining in ore formation gold, then saturated with gold sorbent extract and undergo the process of regeneration.

The method is as follows.

Produce drilling, casing and injection wells. The casing of injection wells perform two coaxial perforated pipes, of which are external casing. Site of perforation of external and internal pipes connect the short pipes. Through internal pipe serves leachate solutions, initially hydro-peroxide-ended received reactor, then, after a pause, a solution of hydrochloric acid with the addition of hydrogen peroxide, with irradiation him before serving in the layer of UV rays. Solutions hydrocarbonate-peroxide compositions, with jet pulse filing into the reservoir, through subsequent diffusion processes ensure the spread of hydrocarbonate ions and active oxygen in the film of water, surrounding mineral particles, including sulphide minerals and magnetite with dispersed gold. It provides initial oxidation of minerals in the surface area and space, adjacent to the surface of cracks and pores, respectively, and a significant reduction of oxidants as part of the main solution. The main leaching solution containing complexing and oxidizer for gold, also through wells serves a few dozen hours after the original filing of hydro-peroxide solution. The main components of the solution also from areas of high initial concentration of diffusing distributed in the main volume of the reservoir. Due to the advanced surface formed after the processing of the active solution hydro-peroxide-ended high concentrations of components chloride peroxide solution relatively quickly oxidize and leached gold.

Due to the catalyzed by ultraviolet irradiation of reaction between hydrogen chloride and hydrogen peroxide mainly solution, formed active metastable hypochlorous acid, muriatic environment periodically and decaying on the atomic oxygen, chlorine and water 4 l - 4l*+2O*+2H 2 o Hypochlorous acid and formed by the reaction products react with gold with the release of complex anions type Au(OHCl) and Au(Cl) 4 - . Educated comprehensive gold ions in the electric field periodically dissociate into cations and anions, cations to recombination with chlorine anions and hydroxyl have time to migrate to the cathode and, consequently, to the sorbent that is placed in the well.

An example of a specific use of the method.

(more than 12 m on the roof of the stratum) placer gold, with a capacity of a layer of sand 3-3 .5 m mainly represented by small (up to 0.5 mm) and dispersed (adsorbed minerals, clays, included in the lattice of magnetite and other minerals) secretions metal.

The filtration coefficient in the Sands of 1.5 m/day.

Initially carry out drilling diameter 150 mm on the network 5*5 m, Casing of injection wells produce plastic pipes with a diameter of 150 mm and 100 mm, which perforate and place of perforation of these pipes connect the pipes in diameter of 50 mm The contour of block Buryat drainage wells network 10*10 and equip them airlifts for periodic pumping of water reservoir, which may decrease the concentration leaching agents.

Preparation of leaching solutions are in special (hydro-peroxide-ended) and photochemical (a solution of hydrochloric acid with the addition of hydrogen peroxide) reactors. Hydrocarbonate- solution prepared from a 5%solution of sodium carbonate by electrolysis, input 10 g/l 30%hydrogen peroxide and irradiation resulting suspension of ultraviolet lamp type DPT-230.

Solutions hydrocarbonate-peroxide-ended served in the reservoir through pipes, placed into wells in the jet pulse mode until reaching the designed T:G=50:1. After a pause 48 hours for which a solution diffuses into the main volume of the reservoir, in him the same way pumped solution is sodium peroxide composition, and prior to injection into the reservoir solution, is irradiated with UV lamp DT-230 for 10 minutes. After a pause in 72 hours during which the leaching of gold in the diffusion regime of oxidized at the first stage of minerals, pipe is extracted from wells and lowered capsules with electrodes, and anodes and cathodes are placed in individual wells and cathodes are placed in the ion-exchange resin And-100. After the filing of the electrodes voltage value 5-8, is leached chloride solution gold and its sorption resin. In addition, due to allocation on the anode chlorine and formation of new moving in an electric field chlorine-oxygen complexes, the leaching of remaining in the solid phase of gold intensified. Due to combination of processes leached at the first stage (when primary chloride peroxide solution) gold and its , the total time of its transfer into the solution and accumulation in areas on resin is 10 days when extracted from the solid 75-85%. After the process of sorption capsules with the resin extracted from the wells and pass on regeneration.

Method of leaching of gold from the deeper placers and technogenic mineral formations, including the filing of the productive layer of activated leaching solutions through the system injection wells with the subsequent extraction of gold, characterized in that the supply leaching solutions through a system of injection wells produced by the injection of a solution of separate jets, while initially submit the hydro-peroxide solution subjected photoelectrochemical processing, pause, and then submit the solution of hydrochloric acid with the addition of hydrogen peroxide subjected before serving ultraviolet irradiation, after solution in the productive formation to the achievement of transition the main part of the gold from mineral mass in pregnant solution in the wells is placed perforated capsules with a sorbent, equipped with electrodes and serves on the electrode voltage to provide directional diffusion of ions dissolved gold to sorbent and its sorption and remaining in ore formation gold, then saturated with gold sorbent extract and undergo the process of regeneration.

 

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