Printing product and method of its manufacturing
The technical FIELD
The present invention relates to printed products and to methods of printing of these products. The invention in particular relates to products printed using ink palette, in which individual ink satisfy the required combinations.
The LEVEL of TECHNOLOGY
Printed products and printing methods are well known. Also known products made using multiple print and color palettes with different ink. To reduce and increase the intensity of the individual colors in the appearance of the finished product, uses tone grayscale and print. Also known combined image, which is obtained by a combination of colors from a limited palette of ink to get the color out of the palette. Ink is determined using either the color space of L-a-b or a value in the color space of the L-C-H, or the value in the color space of the L-C-H-a-b. Determine the magnitude of the color difference Delta e (dE) for each color of ink to provide such a color change that is acceptable for each color palette of the printed ink.
Delta-e (dE) for each color represents the magnitude of possible deviation of the color ink used from the reference color, specified in the map full color space. This deviation m is should be defined as the distance between the specified and actual colors. Delta e is defined as a scalar without direction. In this form of the characteristic colors of ink, the actual tolerance to change the color of the ink is represented by a sphere in a color space having a center at the position specified color and a radius equal to the Delta-that is, In practical applications where the color of the finished product are mixing the three basic colors palette, usually accumulating effects of changes in primary colors cause in the resulting composite colors exceeded the permissible level color deviations from the specified color composite. This tolerance level color deviations may result in the rejection of the finished product.
Thus, there is a need for a method of printing products, in which the specification of the color ink palette provides the appropriate ink, creating a printed color, which will have a valid level, color deviation from the specified color.
DISCLOSURE of INVENTIONS
In one embodiment of the invention, the printed product includes a substrate and a combination of printed ink. Ink include six different ink colors. Each color is defined in a specified color, with full tone of a given color and the grayscale of the selected color. Each of the six printed ink has the largest volume of the United color differences dE full tone L-C-H-a-b is not more than 2. Each of the six printed ink has a value combined color difference dE halftone no more than 3.
The inventive method of printing products includes the preparation of electronic data file of a given artwork, including the colors defined for the respective elements of the artistic image. Run a test print artwork, printing the data file using a digital printing device. The settings of the printing device combined with an electronic file of the artistic image. Provide many print copies of the combined settings of the printing device and an electronic data file of the artistic image. In many places print print copies of the product. Using the combined settings of the printing device and an electronic data file of the artistic image print copies of articles in many places print.
BRIEF DESCRIPTION of DRAWINGS
The figure schematically depicts an embodiment of the claimed invention.
The IMPLEMENTATION of the INVENTION
Printed article includes a substrate and an artistic image printed on the substrate. As products can be packaging materials, labels, packages, or other printed materials, known in the field. P is Delica can be any material, used in printing as a substrate. Substrates include polymeric films and other polymer materials, various types of paper ranging from thin tissue paper to corrugated cardboard, Kraft paper, coated folders. The substrate can also be used metallized films and metal foil. The main substrate may be coated with drugs known in the printing industry for printing artistic image. The product can receive a protective and decorative finish after art image is printed onto the substrate. The printed substrate may be further or processed during manufacture, packaging, or the processing ends printing.
Picture art image for printed products can be manufactured, configured, or simply stored in the electronic data file. Artistic image may include data relating to the desired or specified colors for the corresponding elements of the product. Specification of the artistic image and the color palette may include specification palette ink. Palette ink may include six individual specifications of colors, and may additionally include black ink. A limited palette of seven ink can be used, th is would get range from hundreds of multiple colors in the finished printed product. Each specification color in the palette ink may include the full value of the tone color in the color space of the L-C-H-a-b color space L-C-H or in the color space L-a-b. Color ink may be further defined by indicating the grayscale color model.
Specification palette, using values full tones and values halftone defines the color space. Artistic image can be created using the colors of a particular color space. To obtain a printed product, which accurately reproduce the drawings, the ink used in the printing process, should ensure that the reproduction is not only given full tone, but must also play the specified tones. The color of the finished printed product may include full tones and combinations of tones to obtain the colors of the entire color space.
The ink used by the printer must meet the appropriate specifications full color shades and halftones. In one embodiment of the invention it is necessary that the ink formulations were combined color difference dE full tone L-C-H-a-b, is less than or equal to 2. The person skilled in the art understands that the value of the combined dE full tone is simply a combination of dE values for each of the indicators L-C-H-a-b. Ink can be additionally is determined in accordance with the requirement, to 50% halftone had a joint dE no more than 3 in relation to 50% of the target halftone color.
The value of dE halftones can be determined, once the ink composition satisfies the requirement of dE full tone. A properly designed ink used to print the tonal range from 100% full tone to no tone at all. United dE halftones, preferably corresponding to 50% of the target halftone (best match is determined, as with figure L, is not greater than 1 relative to the target halftone), determined relative to the target tones. In one embodiment of the invention it is necessary that the combined dE was not more than 3. You may need to change the ink composition to satisfy the desired value of dE halftones. Ink with a changed composition should be tested to ensure that the desired value of dE full tone still satisfied.
The use of the compositions of the main ink that meet specifications full tone and 50% shading, reduces the likelihood of not processed composite color in the finished product.
Specification palette ink may optionally include the use of printer ink formulations, which contain no more than two pigment. This limitation can reduce the variability of the composition and reduce the possibility of color change is in response to the written ink.
Specification palette ink may also include the requirement of light fastness. The resistance is related to the stability of the color ink after exposure to radiant energy in a long time. Ink having a low degree of light fastness, can lose the appearance and fade even after exposure to light radiation of low intensity and low-energy spectrum.
Articles intended for use as a promotional product and product packaging, can be minimally acceptable levels of color light fastness, to ensure a stable and desirable appearance throughout the life cycle of the product. In one embodiment of the invention, the ink must have a lightfastness value of at least about 5. If the product is used under conditions of exposure to intense light radiation, the ink should have a value of light fastness 6, 7 or even 8.
To determine the light fastness of the ink composition can be used to test ISO 105-V, in accordance with which the ink is exposed to light of the xenon lamp. In this test, samples of the printed ink and standardized samples of woolen cloth of blue color, with increasing resistance to fading and numbered accordingly the degree of resistance 1 d is 8, are simultaneously exposed to light xenon lamps up until samples of the ink does not reach the color differences from the dark pattern corresponding to the gray scale value of 3. At the same time, samples of wool fabric, exposed to light compared with dark samples of woolen cloth. If a sample of wool fabric 5 has reached the color differences in the gray scale value of 3, suppose that the ink have a lightfastness scale blue woolen cloth (BWS) at least 5.
Palette ink may further determine that the ink formulations support color space standard systems trial printing. Standard system test printing KODAK™, NEC™ have a color space within systems that can perform the proofs of complex artistic image. The color space of the destination. The choice of ink formulations outside of the color space standard systems trial printing can cause the art, the image may not be adequate to that which was printed more expensive process multiple print the finished product. Specification, which indicates that the ink composition has a score of test printing 1, means that the ink can be successfully used for making prints using undertie proofing printers. Inks that have a metric of trial printing 0 cannot be used to generate fingerprints.
The choice of a specific color palette determines the appropriate color space or a color spectrum. Appropriate color space can be used to narrow or limit the color choices made when developing a picture or create an artistic image for the product. Many products are designed using conventional color space, allowing you to limit the selected color, and can subsequently be printed with a conventional ink set. When the product has a uniform substrate and the size of the print areas, it can be one printing device to print a variety of products with different artwork and different composite color art images without the need to change ink used in the printing process.
In one embodiment of the invention, the first product may be printed in the desired quantity and the second product containing artistic image that differs from the first product may be subsequently printed on the same printing device without the need to change ink or cleaning procedures that are required when changing ink colors.<> In one embodiment of the invention the color palette for printed products includes: the first ink, the color of which is set LCHab between about 61 and 64, 56 and 59, 224 and 227, -39 and -40, -39 and -42; second ink color which has values LCHab between about 53 and 56, 59 and 63, 358 and 4, 59 and 63, -1, and 4; the third ink color which has values LCHab between about 92 and 93, 87 and 88, 88 and 89, 2 and 3, 87 and 88; fourth ink color which has values LCHab between about 73 and 74, 80 and 81, 48 and 49, 53 and 54, and 60 and 61; the fifth ink whose color has a value LCHab between about 66 and 67, 64 and 65, 158, and 159 -60 and -61, 23 and 24; and the sixth ink whose color has a value LCHab between about 51 and 52, 49 and 50, 263 and 264, -5 and -6, -49 and-50.
Products can be printed using analog or digital print devices. The use of digital printing device allows to carry out trial printing products digital printing device from the electronic data file of the artistic image. After a successful trial printing products digital printing device between the settings of the printing device corresponding to the trial printing, and file data of the artistic image can be set to match. The data files of the artistic image and the settings of the printing device mouthbut passed in many print and can be used in many printing devices to obtain essentially identical products. The data files of the artistic image and the settings of the printing device can be transferred to many places print using any means known in the technical field related to the distribution of data.
Products can be printed using a combination of analog and digital print devices. Products can be printed using the methods of flexography or gravure printing. The product may include the proofs of rectangles, segments or spots. Each trial printed segment may consist of one color palette. In one embodiment of the invention, the segments include a composite color of the finished figure. The proofs of segments can be included in the final product or, as in the case of some of the labels can include the part of the intermediate forms of the product.
Products can be printed using partial color palette, by executing the printing multiple print devices. In one embodiment of the invention the product may include additional color ink stains to get the colors of the artwork outside the color space of the color palette.
The figure illustrates a product according to the invention. The article 100 includes a substrate 110, and the ink 115, 125, 135, 145, 155, 165 and 175, each of which is printed in the form of spots is detailed imprint, and all printed together in a composite image 180.
The dimensions and values disclosed in the description, should not be understood as being strictly limited to the above precise numeric values. On the contrary, unless otherwise specified, each such dimension is intended to refer to see value and a functionally equivalent range of this value. For example, the size, disclosed as "40 mm"mean "about 40 mm".
All documents cited in the detailed description of the invention, in relevant part, incorporated herein by reference; reference to any document should not be construed as a recognition of the fact that this document discloses the present invention. If there is any meaning or definition of the term in the description contradicts any meaning or definition of the same term in the document, included as reference information, the meaning or definition of the term given in the description, should be the determining factor.
Although specific embodiments of the and/or individual characteristics of the present invention have been described herein for persons having qualifications in this field, it will be obvious that various other changes and modifications can be made without departure from the essence and scope of the invention. Therefore, primogenital designed to cover all such changes and modifications that are within the scope of this invention.
The method of printing products containing phases in which: manufacture electronic data file containing a set of art images for printed products, make a test print art image by printing the data file is a digital printing device, establish a correspondence between the settings of the digital printing device and an electronic file of the artistic image, provide many print copies of the settings of the digital printing device and a data file of the artistic image, between which there is a correspondence, and printed copies of articles in many places print using the settings of the digital printing device and an electronic file of the artistic image, between which there is a match.
SUBSTANCE: conductive paste contains frit glass, a conductive material, an organic medium and one or more organometallic components which form metal oxides when burnt. The organometallic components are selected from a group comprising a metal carboxylate and a metal alkoxide, where the metal is boron, aluminium, silicon, bismuth, zinc or vanadium. When deposited on antireflecting coating on a substrate, the conductive paste is capable of penetrating the coating to form an ohmic contact with the substrate. Described also is a photovoltaic cell, having a semiconductor substrate, an antireflecting coating and lines of a conductive mesh formed from said conductive paste.
EFFECT: high efficiency of the photovoltaic cell, improved adhesion and ohmic contact between metallic elements and the substrate through antireflecting coatings.
10 cl, 1 tbl, 2 ex
SUBSTANCE: present invention relates to use of a composition which contains: a) 0.1-20 wt % binder which contains a polycarbonate derivative based on geminally disubstituted dihydroxydiphenyl cycloalkane, b) 30-99.9 wt % solvent, c) 0-10 wt %, with respect to dry mass, dye or mixture of dyes, d) 0-10 wt % functional material or mixture of functional materials, e) 0-30 wt % additives and/or auxiliary substances or a mixture thereof, as jet printing ink. The invention also relates to a method of producing a composite and a composite which contains a polymer layer on which there is a jet printing layer of said composition.
EFFECT: invention is aimed at producing agents which enable to use jet printing in making counterfeit protected documents and/or valuable documents based on polycarbonate layers, and which enable to deposit jet printing layers on layers which meet all optical requirements, which can be coloured, wherein lamination does not deteriorate optical properties of the layers and said layers do not act as a separating layer and facilitate formation of a monolithic composite.
31 cl, 2 tbl, 2 dwg, 8 ex
SUBSTANCE: invention relates to jet printing inks, particularly non-aqueous inks for jet printing. The ink for jet printing contains a pigment, binder, polyetheramide resin as a pigment dispersant, an organic solvent and an anti-corrosion agent from an imidazole group or a group of volatile anti-corrosion agents, preferably dicyclohexylamine or cyclohexylammonium cyclohexylcarbamate.
EFFECT: disclosed inks have high dispersion stability and prevent corrosion of print heads of jet printers and nozzle clogging.
8 cl, 8 tbl, 34 ex
FIELD: food industry.
SUBSTANCE: proposed print compound in the form of print ink or print varnish includes a binding substance with a resinous component and a solvent component. The binding substance solvent represents a one-component or multicomponent saturated resin solvent and a food product or food additive of a number of monoglycerides and/or diglycerides and/or triglycerides. Preferably, the binding substance solvent component includes acetylated or esterified monoglycerides and/or acetylated or esterified diglycerides and/or acetylated or esterified triglycerides.
EFFECT: print ink solvent migration degree reduction and treatment simplification in view of the possibility of the print compound drying-out by way of absorption and re-varnishing exclusion.
4 cl, 3 ex
FIELD: printing industry.
SUBSTANCE: proposed invention relates to a printing item comprising a substrate and a combination of printed inks including six colours. Each of colours is defined with a full tone and a half-tone of the specified colour, at the same time each ink has a value of colour difference dE of the combined full tone L-C-H-a-b, which is less than or equal to 2, and a value dE of the combined half-tone, which is less or equal to 3.
EFFECT: invention provides for production of printing items, which reproduce patterns with high accuracy.
7 cl, 1 dwg
FIELD: textiles and paper.
SUBSTANCE: non-woven fabric is proposed, on the visible surface of which the ink composition is applied comprising from about 40 wt % to about 80 wt % of the dry weight of the ink of linking agent - aziridine oligomer with at least two aziridine functional groups. Also an absorbing article is proposed comprising a liquid-permeable upper layer, an absorbing core and a liquid-impermeable lower layer that contains the specified non-woven fabric with the said applied ink composition. The application of ink on the non-woven fabric can be carried out by the method of flexography or a method of ink-jet printing.
EFFECT: printed non-woven fabric has high resistance to abrasion even in case of its contacting with fatty substance.
16 cl, 2 dwg, 2 tbl, 2 ex
FIELD: printing industry.
SUBSTANCE: waterless ink composition for inkjet printing contains a pigment, a polymer in an amount of 1 to 20 wt % in terms of total weight, dispersing of pigment, organic solvent, and alcohol containing an amino group in an amount of 0.01 to 3 wt % in terms of total weight. The alcohol containing an amino group is selected from the group consisting of 2-amino-1-butanol, 2-amino-2-methyl-1-propanol, 2-amino-2-methyl-1,3-propanediol, 2-amino-2-ethyl-1,3-propanediol and tris(hydroxymethyl) aminomethane. As the polymer the ink contains polyester, acrylic resin or polyvinyl chloride. The aqueous extract of the said waterless ink composition has pH ranging from 6.0 to 10.0.
EFFECT: increased stability of its pressure injection and the absence of clogging the nozzle of the print head with achievement of high quality printing.
7 cl, 1 tbl, 5 ex
SUBSTANCE: described is an activator of adhesion of ink to a substrate, containing a product of reaction of (a) a polymer solution or synthetic resin, (b) sulphonic acid or derivative thereof and (c) a metal compound selected from a group consisting of a metal halide, metal alkoxide, metal halide-alkoxide or a condensed metal alkoxide, where the metal is titanium or zirconium. The amount of sulphonic acid or sulphonic acid salt (b) and metal compound (c) corresponds to molar ratio of SO3X, where X is a H atom or a base residue, to Ti and Zr atoms ranging from 0.25:1 to 2:1. The invention also describes printing ink containing said adhesion activator.
EFFECT: reduced yellowing and smell of ink compared to ink which contains titanium acetyl acetonate as an adhesion activator while preserving effectiveness of the adhesion activator.
22 cl, 4 tbl, 15 ex
FIELD: technological processes.
SUBSTANCE: material marking method consists in the fact that there made is paint consisting of binding agent and fine microparticles and/or microencapsulated microdrops having diameter of approximately 40 to 80 mcm. Then, the mark having surface area of about one square centimetre and containing serial registration number is printed on the product by using the above paint. The above mark is lit with the light and chaotic character of distribution, shape and sizes of fine microparticles and/or microencapsulated microdrops are fully flashed; due to which non-reproducible and distinctive background card for the introduced mark is created. And data reads composed of the above background card are subject to filtration by using stop-down lens serving for neutralisation and suppression of any possible reflection of distortion of and damage to patterns, and then the above data reads subject to filtration are identified by means of optic-digital video camera interrelated with software, and view finder. At that, video camera has the possibility of transmitting the data to registration database for further comparison and confirmation of authenticity of the product marked in such a manner.
EFFECT: marking method allows high degree of protection of the product against false fabrication and copying.
10 cl, 2 dwg, 1 ex
FIELD: printing industry.
SUBSTANCE: ink that contains water, water-insoluble colour and multiple water-soluble organic dissolvents is applied onto a carrier. Specified dissolvents contain a good solvent for the specified colour (A) and a poor solvent for the specified colour (B) with the ratio of A to B, equal from 10:5 to 7:9. The water-soluble organic dissolvent that has maximum value Ka, identified by Bristow method, among all water-soluble organic dissolvents in the ink, relates to poor dissolvents.
EFFECT: high extent of surface coating and high density of OD image even with small quantity of ink.
3 cl, 16 dwg, 11 tbl, 16 ex
FIELD: protection coatings.
SUBSTANCE: invention aims at protecting bank notes and security papers against counterfeiting. Optically changing pigment contains interferential multilayer structure including light-transmitting dielectric layer having at least one luminescent material. Dielectric layer is selected from of rare-earth metal, bismuth, and principal group III element trifluorides; of principal group II element difluorides; mixtures thereof; organic or organometallic compounds. Luminescent material should be selected from organic or organometallic compounds containing transition or rare-earth metal ions. Above-defined structure may contain one or more semitransparent, partly reflecting layers, one or more nontransparent, fully reflecting layers, and one or more conducting layers. Pigment is prepared by a method including physical or chemical precipitation of the dielectric layer.
EFFECT: preserved proper properties of color shift, increased reliability of protection, and ensured identification simplicity at relatively low cost.
30 cl, 1 tbl, 9 ex
FIELD: ink-jet printing facilities and materials.
SUBSTANCE: invention relates to ink-jet printing on sheet-shaped substrates such as paper, films, and textiles. In particular, invention discloses a method for ink-jet printing on sheet-shaped substrates using aqueous ink including (i) at least one dye of formula (I): (I), wherein R1 and R2, each independently of the other, represents hydrogen atom or unsubstituted or substituted C1-C4-alkyl; R3 and R4, each independently of the other, represents unsubstituted or substituted C1-C4-alkyl; R5 and R6, each independently of the other, represents C1-C4-alkyl, C1-C4-alkoxy, halogen atom, hydroxyl, carboxyl, C2-C4-alkanoylamino, or sulfo group; X represents halogen atom, hydroxyl, C1-C4-alkoxy optionally substituted in alkyl residue, phenoxy optionally substituted in phenyl residue, C1-C4-alkylyhio optionally substituted in alkyl residue, phenylthio optionally substituted in phenyl ring, amino, C5-C7-cycloalkylamino optionally substituted in cycloalkyl residue, phenyl- or naphthylamino optionally substituted in aryl residue, N-C1-C4-alkyl-N-phenyl- or N-C1-C4-alkyl-N-naphthylamino optionally substituted in aryl residue, benzylamino optionally substituted in phenyl residue, morpholine, or pyperidin-1-yl; and n and m each is a number 0, 1, 2, or 3; and (ii) compound selected from polyethylene glycols with molecular mass from 150 to 400.
EFFECT: enabled producing light-resistant and moistureproof prints with elevated saturation of color.
12 cl, 1 tbl
FIELD: dyes, building materials.
SUBSTANCE: invention relates to sets of dye semifinished products used in preparing dyes of different designation. Invention describes the dye semifinished product with properties of fluidity and covering power that can be used in preparing a single-package latex dye stained with pigment wherein the volume content of dry matter is from about 30% to about 70% with the Schtormer viscosity value from about 50 to about 250 EK and comprising the following components: (I) at least one pigment conferring the covering power property; (II) at least one dispersing agent; (III) at least one thickening agent, and (IV) water wherein at least one dispersing agent and at least one thickening agent are compatible with at least one pigment and other dye components. Also, invention describes sets for dyes and dye lines comprising a latex polymeric binding agent. Some dyes for internal and external coating of different objects are prepared by using sets of dye semifinished products. Invention provides preparing the broad assortment of dyes of different quality for external and internal workings and with different levels of polishes and bases for carrying out the coloring from dye semifinished products and by using the minimal amount and types of the dye components. Proposed dye semifinished products can be used for architecture, industrial, polygraphic, elastomeric and non-cement coatings.
EFFECT: improved preparing method, valuable properties of dyes.
51 cl, 3 tbl, 63 ex
FIELD: printing technique.
SUBSTANCE: set and method of printing can be used for printing light-absorbing signs of protection of printed items. Set of printing ink for printing of light-absorbing signs has at least two dyes. Any dye has at least one dyeing matter, pigment of dye which absorbs visible light. Set of printing inks has first and second groups of dyes. Dyes from first group additionally have mark with preset spectral absorption characteristic, preferably with characteristic relating to absorption. Mark has absorption maximum within wavelength range of 700-900 nm, preferably, 780 nm, and the mark practically doesn't absorb light within visible spectrum of absorption. Dyes of second group has dyeing matter, dye or pigment, which absorbs light within visible light spectrum and they have the same maximum of absorption within IR-red spectrum at wavelength around 700 nm as spectral characteristic within IR-red range of mark, Method of printing signs, printed item and set of dyes, including four-color set of printing inks and IR-mark, are described.
EFFECT: reliability of identification of authenticity of item independently on color of signs.
15 cl, 5 dwg, 2 app
FIELD: printing arts; printing inks for securities; protection against falsification.
SUBSTANCE: proposed printing ink contains pigment possessing protective properties, binder and thinner; pigment contains ultra-dispersed powder of rare-earth ferrite-garnet selected from group including Y3Fe5O12, Ln3Fe5O12, YxLn3-xFe5O12, where Ln is rare-earth element, 0≤x≤3, Y3-xBixFe5O12, where 0≤x≤2 with sizes of crystallites not exceeding 100 nm in the amount not exceeding 85% of weight of ink. Optical characteristics are extended within 380-750 nm and infrared transparence is increased within 0.74-3.0 mcm.
EFFECT: enhanced identification due to magnetic properties.
8 dwg, 1 tbl, 3 ex
SUBSTANCE: invention relates to composition of aqueous dye used in stenciling, to a method for preparing indicated composition of stenciling, using indicated dying composition for stenciling and to securities printed using indicated dying composition. Invention describes composition of aqueous dye for stenciling containing the following components: (a) emulsion of acrylic or urethane-acrylic copolymer taken in the amount 30-70 wt-%, preferably in the amount 35-60 wt.-%, and more preferably in the amount 40-55 wt.-% of self-cross-linking emulsion of acrylic or urethane-acrylic copolymer as measured for the total mass of composition; (b) cross-linking agent taken in the amount 0.25-3 wt.-%, preferably in the amount 0.5-2 wt.-%, and more preferably in the amount 1-2 wt.-% of mass indicated cross-linking agent as measured for the total mass of composition; (c) optional catalyst; (d) optional pigments, and (e) optional additives and wherein indicated cross-linking agent comprises at least two different functional activity in a single molecule. The first functional activity is chosen by so manner to form a covalent bond with indicated polymer before printing and the second of indicated functional activities is chosen by so manner to carry out cross-linking indicated polymer for hardening printed dye. Emulsion of acrylic or urethane-acrylic copolymer is chosen from group possessing self-cross-linking property and wherein the composition shows pH from 7.0 to 8.5, preferably from 7.5 to 8.3 and more preferably from 7.5 to 8.0. Invention describes a method for preparing above said composition of aqueous dye for stenciling and comprising the following steps: (a) preparing emulsion of acrylic or urethane-acrylic copolymer; (b) optional preparing catalyst, optional pigments and optional additives; (c) preparing a cross-linking agent able to form a covalent bond under the first conditions with polymer prepared in (a), and cross-linking prepared polymer under the second conditions; (d) thorough mixing components prepared by points (a), (b) and (c) and providing interaction of polymer prepared by point (a) with a cross-linking agent prepared by point (c) under indicated first conditions; (e) regulation of pH value of the composition in the range from 7.0 to 8.5. Also, invention describes using the indicated composition of aqueous dye as a dye for stenciling and security document with signs printed by using indicated composition of aqueous dye. Proposed composition shows improved stability and improved toxicological properties in the combination and excellent stability of printed and hardened dye to chemical and physical effects.
EFFECT: improved properties of dye, improved preparing method.
14 cl, 6 ex
FIELD: chemical industry; polygraphy; methods of the stencil printing.
SUBSTANCE: the invention is pertaining to the paint suitable for the stencil printing inside the pressurized castings. The invention describes the paint suitable for the printing films made out of the transparent thermoplastic, consisting predominantly of: a) one or several pigments; b) the binding in the solution in c) the organic solvent or in the mixture of the organic solvents, d) the routine auxiliary materials, if it is desirable, at that as the binding use the copolymer of the poly-(metha)-acrylate containing (м1) from 50 up to 90 % to the mass of alkylmethacrtlate having from 1 up to 6 atoms of carbon in the ethereal radical; (м2) from 5 up to 25 % to the mass, at least, one vinylaromatic compound; (м3) from 1 up to 25 % to the mass of maleic anhydride, and if it is desirable, (м4) from 0 up to 5 % to the mass of the alkylacrylate having from 1 up to 6 atoms of carbon in the ethereal radical or the copolymer of the poly-(metha)-acrylamide containing polymethylmethacrylate with the degree of imidization from 65 up to 80 %, to 1 up to 15 mass % of methacrylic acid and from 1 up to 15 mass % of methacrylic anhydrade. At that the indicated copolymer has the softening temperature by VIKA (ISO 306 B) at least of 115°С. As the dissolvents use aliphatic, cycloaliphatic and aromatic hydrocarbons, ketones, esters, ethers, alcohols, phenoles or their mixtures. The invention also describes the film made out of the thermoplastic printed by the above described paint; the pressurized casting consisting of the film made out of the thermoplastic printed on the opposite side with the above described paint and supplied on this side with the layer of the thermoplastic coating. At that the indicated layer is applied by the operation of pressure die casting on the inside and at that the film and-or the plastic material for operation of the pressure die casting on the inside represents the copolymer of polymethylmethacrylate; and the method of production of the pressurized castings includes the following stages: a) stencil printing of the thermoplastic films by the above described method, b) the film molding, c) the pressurized castings on the inside on the stencil printed film side in the casting mould with the thermoplastic, and d) removal of the pressurized casting from the casting mould. The technical result of the invention: the paint is resistant to the action of the high pressures and temperatures during the operation of the pressurized casting on the inside, the image stencil printed by the paint has the stable color after long-term action of the atmospheric conditions.
EFFECT: the invention ensures, that the paint is resistant to the action of the high pressures and temperatures during the operation of the pressurized casting on the inside, the image stencil printed by the paint has the stable color after the long-term action of the atmospheric conditions.
6 cl, 1 tbl
FIELD: marking and identification of protected articles, such as bank-notes, service papers, labels, foil, fiber, card or industrial products.
SUBSTANCE: proposed printing ink contains dyes or pigments of expanded or hyperchromatic color space which is not reproduced by means of standard 4-color reproducing equipment. Identification of marking includes mathematical conversion of non-processed spectral information into statically independent hyperchromatic coordinates and comparison of selected hyperchromatic coordinates with respective standard magnitudes. Specification gives also description of printing inks and method of marking and identification of articles.
EFFECT: enhanced efficiency.
25 cl, 6 dwg, 2 tbl, 4 ex
FIELD: chemical industry; computer industry; methods of production of the pigments used in the coatings of the registering medium of ink-jet systems.
SUBSTANCE: the invention is pertaining to production of the pigments suitable for usage in the compositions of the registering mediums used for the ink jet printing. The invention provides, that the surface of the pigmental loose material is subjected to action of the water-soluble salt of the polyvalent metal in the aqueous medium. The treated surface of the particles gains the sizeable cationic surface charge. The salt represents the metal salt of the Group II or the Group III of Periodic table. The registering mediums for the ink-jet printing treated with the coating composition containing the indicated pigment ensure the high density fast-drying and anti-bleeding colorful images with the sufficient water-resistance. The compositions used for creation of the coating also have the advantage pertaining to the net cost and to the improved rheology at the more higher content of the pigment in the coating as compared with the coatings based on the siliceous pigments.
EFFECT: the invention ensures production of the coatings with the indicated pigment having the high density, fast-drying and anti-bleeding colorful images with the sufficient water-resistance at the low net cost, the improved rheology at the more higher content of the pigment in the coatings, as compared with the coatings based on the siliceous pigments.
30 cl, 5 dwg, 7 tbl, 7 ex
FIELD: printing engineering.
SUBSTANCE: invention, in particular, relates to a method of printing allowing protection of printing materials against counterfeit reprints, for instance in fabrication of banknotes, shares, checks, and other valuable paper documents. Invention provides printing liquid for printing through narrow nozzles onto objects, in particular when fabricating banknotes, shares, and checks, which liquid comprises carrying medium and nanoparticles of metal salts in the form of crystalline solid particles having average diameter less than 300 nm, which fluorescent and phosphorescent when excited by UV emission of the A, B, or C band, or visual light, while emitted fluorescent and phosphorescent waves do not lie in the visual light frequency region and excitation frequency region and emission frequency region are shifted in frequency scale. Nanoparticles contain enhancing additives of at least one type having excitation and emission frequency ranges corresponding to fluorescence and phosphorescence. Provided is also printing method including injecting of above-described liquid(s) through one or several narrow nozzles, which are regulated individually or by groups in relation to availability or lack of printing liquid and in relation to duration or intensity of flowing of printing liquid. Printing method is either piezoelectric method or jet printing one. Employment of proposed liquid for ink-pots and object marking, in particular when fabricating banknotes, shares, and checks involving printing equipment provided with one or several narrow nozzles is also described.
EFFECT: increased reliability of protection.
15 cl, 2 dwg