Method of reducing creases using fabric care composition

FIELD: chemistry.

SUBSTANCE: present invention relates to a method of reducing creases when washing a garment made from heavy fabric, which includes steps of washing the garment and applying a fabric softener, which contains a quaternary ammonium fatty ester and a hydrolysed protein and polysiloxane copolymer, where the average molecular weight of the protein component ranges from 500 to 500000 Da, to the garment made from fabric weighing at least 250 g/m2. The present invention also relates to a fabric softener for reducing creases on garments made from heavy fabric, which contains: a) 0.5-50 wt % cationic softener, which contains a fatty acid ester of quaternary ammonium, b) 0.02-0.5 wt % hydrolysed protein and siloxane copolymer, where the average molecular weight of the protein component ranges from 500 to 500000 Da, c) a fragrant and d) water.

EFFECT: obtaining an efficient and cheap agent for removing or reducing creases on clothes during washing and drying.

13 cl, 3 ex, 4 tbl

 

CROSS-REFERENCE TO RELATED APPLICATIONS

This application claims priority in accordance with the provisional application for U.S. patent No. 61/224300 registered 9 July 2009, the contents of which is given here as a reference.

The LEVEL of TECHNOLOGY

In the process of washing and drying clothes folds. Although creases from clothes can be removed by pressing or Ironing, the Ironing process is time-consuming and requires effort. There have been many attempts to prevent the formation of folds during the washing process. Known attempts to reduce wrinkles by including reducing the folds of additives in synthetic detergents or softeners tissues. Such additives include aminosilicone and is capable of curing aminosilicone. However, each of these fillers has drawbacks. For example, aminosilicone can cause yellowing, and is capable of curing aminosilicone require a high temperature to reduce wrinkles.

Casual clothing such as jeans made of denim are often erased, in addition, the process of Ironing garments made from heavy fabrics, such as cotton, particularly laborious and time consuming. Therefore, the availability of funds to reduce wrinkles without Ironing is very gelatin is typical of such casual clothes. There is therefore a need for an effective and economical means for eliminating or reducing wrinkles of the clothes during washing and drying, especially for items of everyday clothing.

The INVENTION

Method of washing clothes for wrinkle reduction. The method includes the steps of washing clothes in a conventional way with the subsequent use of conditioner to the cloth to the washed clothes. Air conditioning for tissue contains fatty ester Quaternary ammonium and protein copolymer with silicone, used to reduce wrinkles in laundered garments, having a fabric weight of at least 250 g/m2(7.5 ounces per square yard) and up to 600 g/m2. It is desirable that the garment had less than 40%, preferably less than 30% of the surface area covered by more than one layer of fabric, stitched with stitches.

The invention further offers air conditioning for fabric that reduces or minimizes the amount of wrinkles in laundered garments, thus giving the clothes soft. Air conditioning for the fabric especially suitable for reducing wrinkles in garments, made of fabric, the weight of which is at least 250 g/m2and up to 600 g/m2.

Air conditioning for the fabric may contain from 0.5 to 50 wt.% fabric softener, such as fatty ester Quaternary ammonium compounds and from 0.1 to 2 wt.% FOSS is the iMER protein with silicone calculated on the total weight of the composition; the softener to the fabric may be ditalini (ditallow) W diethyl ammonium salt or ditalini the fluids dimethyl ammonium salt. It is desirable that the composition reduces formation of wrinkles in laundered the clothing item at least 50%, more preferably at least 60%, even more preferably at least 70%, compared with a garment-washed without the use of softening composition.

DETAILED description of the INVENTION

Used everywhere ranges are used to describe each value that is within range. Any value within the range can be selected as the boundary of the range. In addition, all references cited herein are, therefore, included in their entirety. In the event of a conflict in the definition of any term in this invention and the cited literature should be used in determining the present invention. Unless otherwise indicated, all percentages and numbers presented in this document and in other parts of the description should be understood as percentages by weight. Presents the number refer to the active mass of material, unless otherwise indicated.

The term "washing" includes any method of cleaning fabric. Typically, the fabric can be washed with water or in a washing machine, or hands, or brushing with assistance from the tava for cleaning using non-aqueous solvent.

The term "conditioning for fabric" refers to a composition that can improve the condition of the tissue. The term includes softeners for fabrics. Softeners for fabrics include materials that soften the fabric.

At refers to the active mass of the combined number of monasterace, descarcat and triternata.

This invention provides a method for reducing wrinkles, which may be formed when the garments are washed and dried. The method includes a stage of contact of clothing with a composition according to fabric care, such as air conditioning for the fabric, which contains Quaternary ammonium softener active and the protein copolymer with silicone. The method is especially focused on the reduction of wrinkles on garments made of heavy fabric. A heavy fabric suitable for clothing of the present invention and includes a fabric having a weight of at least 250 g/m2and up to 600 g/m2preferably from 270 g/m2to 550 g/m2, more preferably from 300 g/m2up to 500 g/m2.As a rule, heavy fabric is produced by the way the weave of obtaining such textures of fabrics like denim, tweed, hacks or canvas. The method is also directed to the processing of garments, having less than 40% of their surface area covered with overlapping of the oblasts, more than one layer of fabric, stitched with stitches. Sewn overlapping region is preferably from 5% to 30%, and more preferably from 10% to 25%. Mitigation fabric reduces wrinkling washed garments made of heavier fabric, at least 50%, more preferably at least 60%, even more preferably at least 70%, compared with a garment-washed without the use of imparting softness of the composition.

Composition for caring for a fabric, preferably a composition which imparts softness, contains the active cationic softener. Appropriate the cationic softener is a fatty ester Quaternary ammonium compound. Fatty ester Quaternary ammonium compound has the formula:

in which R4represents aliphatic hydrocarbon group having from 8 to 22 carbon atoms, R2and R3independently, represent (CH2)S-R5in which R5represents an alkoxy carbonyl group containing from 8 to 22 carbon atoms, benzyl, phenyl, (C1-C4) - alkyl substituted phenyl, OH or H; R1represents (CH2)tR6in which R6represents benzyl, phenyl, (C1-C4) - alkyl substituted phenyl, OH or H; q, s, and t each independently represents an integer is 1 to 3; and X-is compatible with the softener anion comprising halogen, for example chlorine, methyl sulfate or ethyl sulfate. Examples of Quaternary ammonium compounds include fluids dialkyl dimethyl ammonium salts such as ditalini fluids dimethyl ammonium chloride, and ditalini fluids dimethyl ammonium the methyl sulfate; W dialkyl diethyl ammonium salt, such as ditalini diethyl diethyl-the ammonium methyl sulfate, ditalini diethyl ethyl methyl the ammonium methyl sulfate, and mixtures thereof. The corresponding Quaternary ammonium compounds may also contain stereoselectivity mono - or three-hydrocarbon esters of alkanol-amine and mixtures thereof. Appropriate alkanol-Amin includes triethanol-amine and the corresponding Quaternary ammonium compounds include truefire fatty acids ethanol ammonium chloride, truefire fatty acids ethanol ammonium sulfate, monoether fatty acid diethyl ammonium chloride and monoether fatty acid diethanol ammonium sulfate. Also other suitable Quaternary ammonium compounds with a substituted or unsubstituted hydratability groups such as stearic, palmitic, myristic fatty acid groups which form an ester with alkanol-amine. Air conditioning for the fabric contains from 1 to 50 wt.%, calculated on the total weight of the composition, preferably from 2 to 35 wt.%,more preferably from 3 to 20 wt.%, even more preferably from 6 to 10 wt.%, most preferably from 8 to 9 wt.% cationic softener in the calculation of the active material weight.

Air conditioning for tissue contains protein copolymer with silicone. The term "protein"used herein refers to the hydrolized protein. The term "silicone"as used here, includes the silane or siloxane. The protein copolymer with silicone is a silicone component associated with the amine groups of the protein component. The copolymer can be obtained by covalent joining organofunctional Milanovich or siloxane compounds to protein amino groups with the formation of polymer molecules, including protein-silicone mesh structure. The average molecular mass of the protein component can be from 500 to 500,000 daltons, preferably from 1000 to 20000 daltons.

The corresponding model copolymers protein with silicone described in patent documents EP 540357 and WO03/078503.

Corresponding copolymers include copolymers of the General formula:

in which R is the residue hydrolyzed protein R-NH2; each R1is independently the residue organofunctional silane HR1-Si(R2')(R3')-OH, in which R2'and R3'are independently methyl-, hydroxy-, alkoxy having from 1 to 6 carbon atoms; R2 3are each independently methyl-, hydroxy-, alkoxy having from 1 to 6 carbon atoms, or a residue of a compound of formula (A) or (B):

in which R, R1, R2and R3each is independently as defined above, and n corresponds to the number of reacted amino groups, preferably in the range from 1 to 100, with from 0.1 to 0.4 molecules of silane on the reactivity of the amino group of the protein. R is preferably the residue hydrolyzed vegetable protein such as hydrolyzed protein, wheat or potatoes, especially protein wheat. The nature of the group R1which is the remnant of organofunctional silane used for the reaction with the protein component for the formation of the copolymer depends on the nature of the functional group originally present in organofunctional the silane. For example, when the functional group originally present in organofunctional the silane is Allgood, R1will, as a rule, contain a carbonyl group attached directly to the nitrogen atom of the protein residue. Similarly, when the functional group originally present in organofunctional the silane is sulfonyl halogen, R1will usually contain sulfonyl group associated neposredstvenno the nitrogen atom of the protein residue. The group R1preferably get a reaction organofunctional silane containing an epoxy group as a functional group. In this case, in the final copolymer connection, R1will take half of the formula-CH2-CH(OH)-, methylene part of which is linked directly to the nitrogen atom of the protein residue. Preferably the group R1is alkalinous group having from 1 to 10 carbon atoms which may be substituted by one or more oxygen atom, or one or more group selected from hydroxyl groups, halogen atoms, alkyl groups having from 1 to 6 carbon atoms, and alkoxygroup having 1 to 6 carbon atoms. The corresponding R1includes -(CH2)3-O-CH2-CHOH-CH2-or (CH2)3-CH(CH2-CO2H)-CO-.

The copolymer preferably includes a compound of formula (C):

where R is the residue hydrolyzed protein from wheat or potatoes; R2and R3each is other than methyl; and n has a value from 1 to 4, preferably 2. Corresponding copolymers protein with silicone in the present invention are commercially available, for example, from the company Croda Chemicals under the trademarks, COLTIDETMHis and CRODASONTMW. Particularly suitable COLTIDE HSi. Air conditioning for tissue contains about is 0.02 to 0.5 wt.% the total weight of the composition, preferably from 0.03 to 0.25 wt.%, more preferably from 0.04 to 0.2 wt.%, most preferably from 0.05 to 0.15 wt.% the protein copolymer with silicone. The mass of the protein copolymer with silicone refers to the mass.

In one embodiment, the composition contains 8.3 wt.% exterkate and 0.45 wt.% the protein copolymer with silicone. In another embodiment, the composition contains 2.8 wt.% exterkate and 0.8 wt.% the protein copolymer with silicone. In another embodiment, the composition contains 6.4 wt.% exterkate and 0.25 wt.% the protein copolymer with silicone. In another embodiment, the composition contains 6.4 wt.% exterkate and 0.45 wt.% the protein copolymer with silicone. In another embodiment, the composition comprises 10,67 wt.% exterkate and 0.45 wt.% the protein copolymer with silicone.

Air conditioning for tissue may further comprise a thickener. Appropriate thickener is a water-soluble cross-linked cationic vinyl polymer which is used as an agent for cross-linking defunctioning additional vinyl monomer at a level of from 70 to 300 ppm, preferably from 75 to 200 ppm and most preferably from 80 to 150 h/million These polymers are further described in the patent document U.S. Pat. No. 4806345, as well as other polymers that may be used is described in the patent is a document WO 90/12862. Typically, such polymers are manufactured in the form of emulsions of the type water-in-oil, in which the cross-linked polymers dispersed in mineral oil, which may contain a surfactant. When creating the finished product in contact with the aqueous phase emulsion is inverted, allowing the water-soluble polymer to swell. The preferred thickener for use in the present invention is a transverse cross-linked copolymer of acrylate Quaternary ammonium or methacrylate in combination with the co monomer acrylamide. Specified thickener in accordance with the present invention allows the air to the tissues, to show stability over a long period of time during storage and ensures the presence of relatively high levels of electrolytes, without affecting the stability of the composition. Additionally, the air to the tissues remain stable, even when accompanied by shearing force.

Air conditioning for tissue may optionally include chelate forming compound. Fit hepatoblastoma connections allow for the formation of chelates with metal ions at the level of at least 0.001 wt.% conditioning fabrics, preferably from 0.001% to 0.5%, and more preferably 0.005% to 0.25 wt.%. Hepatoblastoma compounds that are acidic in nature is e, may be present either in acid form or in the form of a complex salt with a suitable protivoatomnom, such as ion alkaline or alkaline-earth metal, or ammonium ion substituted ammonium or any mixtures. Hepatoblastoma compounds chosen among compounds aminocarbonyl acid and compounds organobentonites acid, and mixtures thereof. Suitable connections aminocarbonyl acid include: ethylendiamine tetraoxane acid (EDTA); N-hydroxyethylamino trioxane acid, nitrilotriacetic acid (NTA) and diethylenetriaminepentaacetic acid(DEPTA). Suitable connections organobentonites acid include: Ethylenediamine tetrakis (methylenephosphonate acid); 1-hydroxyethane, 1,1-diphosphonic acid (HEDP) and aminotri (methylenephosphonate acid).

Air conditioning for tissue may contain anti-foam agent is from 0.01% to 3%, preferably from 0.05% to 2%, more preferably from 0.1% to 1.5 wt.% of the composition. Suitable anti-foam agents include any known anti-foam compound, including, for example, the compounds of the silicone anti-foam, anti-foam alcohol compounds, like 2-alkylalcohol anti-foam compounds, fatty acids, paraffin anti-foam compounds and their mixtures. Especially preferred antiseepage connect what changes to apply here are silicone anti-foam compounds defined here as any anti-foam compound comprising a silicone component. Such silicone anti-foam compounds usually contain silicon component. The silicone component includes a variety of relatively high molecular weight polymers of siloxane components and hidrocarburos groups of various types, such as organopolysiloxane oils, for example, polydimethylsiloxane, dispersion or emulsion organosiloxane oils or resins, a combination of polyorganosiloxane with silicon particles, in which polyorganosiloxane hemosorbent or condense with silica. Anti-foam compounds are well known in the art, for example, described in patent documents U.S. Pat. No. 4265779, issued may 5, 1981 Gandolfo, etc., and European Patent Application No. 893078519 published February 7, 1990, by Starch, M. S. Other silicone anti-foam compounds described in the patent document U.S. Pat. No. 3455839, which discloses compositions and methods for antispyware aqueous solutions by introducing them in small quantities polydimethylsiloxane liquids. A mixture of silicones and silanirovannom silica described, for example, in patent document German Patent Application DOS 2124526. Examples of appropriate silicone anti-foam compounds are combinations of polyorganosiloxane with particles of Cremonese is a, commercially available from Dow Corning, Wacker Chemie and General Electric.

Air conditioning for the fabric of the present invention may further include a dispersant for suspension of the material in the rinse and obstacles to their decomposition on the washed fabrics.

The dispersant can be used in the compositions mainly at the level of from 0% to 7%, more preferably from 0.1% to 5% and most preferably from 0.2% to 3 wt.%. Suitable dispersing agents include non-ionic surfactants that contain more interaction products of ethylene oxide and optionally propylene oxide with fatty alcohols, fatty acids, fatty amines and the like. Here they are referred to amoxicillinum fatty alcohols, amoxicillinum fatty acids and amoxicillinum fatty amines. Any epoxydecane materials of a certain type, described below, can be used as nonionic surfactants. Such compounds are surface-active substances of General formula:

R5-Y-(C2H4O)z-C2H4OH,

in which R5selected from the group consisting of primary, secondary and branched chain alkyl and/or acyl-, and/or acyl hydrocarbonic groups; and primary, secondary and branched chain alkenyl hydrocarbonic groups, first is Chou, secondary and branched chain alkyl - and alkenyl-substituted phenolic hydrocarbonic groups; these hydrocarbonate group, have hidrocarburos chain length of from 8 to 20, preferably from 9 to 18 carbon atoms. In the General formula for epoxydecane surfactants Y is typically --O--, --C(O)O--, preferably-O--, R5when present, has value above and z has a value from 1 to 30, more preferably from 7 to 25.

Air conditioning for tissue may further comprise components that are usually included in the composition of the air conditioner, such as perfumes, surface-concentrated active substances, emulsifiers, dyes, preservatives, optical bishopshostel, natural and/or synthetic extracts, phosphors, hydrotropes, anti-settling, anti-shrink tool, remover of stains, corrosion protection agents, tools, giving draping properties, antistatic agents, auxiliaries for iron and mixtures thereof.

Air conditioning for the fabric of the present invention is very suitable for reducing wrinkling, washed and dried clothing, preferably of garments from heavy fabrics, such that every day can wear without Ironing.

EXAMPLES

Example 1: a fabric Softener.

Composers who AI fabric softener was used with the following components.

td align="center"> 8,1 (7,4)
Table 1
Track
1234567
C14-C15 alcohol
E:1
0,30,30,30,30,30,30,3
COLTDE TM His
The protein copolymer with silicone
0,45
(0,11)
0,25
(0,06)
00,45
(0,11)
0,45
(0,11)
0,25
(0,06)
0
Lactic acid0,060.60,060,060,060,060,06
Tetranyl L90 stereoselectivity fatty ether (active)9,1 (8,1)11,7 (10)9,2
(8,3)
7,1
(6,4)
7,1 (6,4)7,1 (6,4)
Perfume1111111
FlosolftTMDP-200 cationic acrylate thickener from
SNF Floerger
0,30,30,30,30,30,30,3
Simethicone
the non
0,40,40,40,40,40,40,4
Waterup to 100%up to 100%to
100%
to
100%
to
100%
up to 100%up to 100%

The method of obtaining softener.

Heat the water to 65°C and p and stirring phosphinic acid and protein copolymer with silicone. Separately heated with stirring katerinarosanna fatty ester ammonium to 65°C. Katerinarosanna ammonia is added slowly to a solution of the acid-water and stirred for 10 minutes. The mixture is cooled to 35°C and add lactic acid. Then with stirring, add the thickener. The mixture is additionally stirred for 10 minutes.

Example 2: Evaluation of the folds.

Jeans made from 100% cotton denim fabric having a mass of tissue from 400 to 500 g/m2and a long white shirt for evening dress (100% cotton), with a mass of tissue 190 g/m2washed in an automatic washing machine, using compositions 2 and 3 of example 1 in a cycle of softening fabrics. Commercial fabric softener is accompanied by instructions for use for dispensing a composition of fabric softener. For comparison, another set of the above garments are washed without adding variant composition of the present invention. The garments are removed from the washing machine and hang dry in ambient conditions. An expert group of six people are asked to visually estimate the number of folds formed on each dried the garment and give an opinion about the need for Ironing garments. A visual assessment of the folds of conduct, setting the number 1 for the minimum number of folds and the number 3 for the largest quantity is of folds. Table 2 shows the total of all assigned points for the washed garments.

Table 2
Visual assessment folds
GarmentComposition 2Composition 3 comparisonWithout treatment tissue
Jeans142521
The white shirt, the black tie151819

Table 3
The need for Ironing (answer - no need for Ironing, %)
GarmentComposition 2Composition 3 comparisonWithout treatment tissue
Jeans80%0%50%
White shirt for the evening is suit 0%10%0%

As you can see from the above, the composition for the care of the fabric of the present invention significantly reduces the formation of folds in garments made of heavy fabric. Composition on the fabric care significantly reduces the need for Ironing everyday clothing from heavy fabric, substantially reduces the tedious homework.

Example 3: the Folds in the fabric.

Prepare a sample size of 20 cm2and washed in an automatic washing machine, using composition 1 sample 1 in the cycle of softening fabrics. For comparison, another set of samples also washed, but without adding to the tissue variant composition of the present invention. Washing machine stop just before the last cycle of centrifugation, and the samples are removed from the washing machine. Each sample carefully fold in half along the length and manually squeezed to remove the water. Twisted sample take two corners and shaken out three times. Each dried sample is assessed visually on the number capable of perceiving folds within 6 cm circle in the center of the sample. For each composition tested forty-five samples of each tissue. In table 4

Table 4
Type of serviceFabric weight (g/m2)Composition 1 (the average number
folds)
No tissue processing (the average number of folds)Reduction
folds, %
Jeans
(100% cotton)
4666,025,776%
The military form (100% cotton)2526,319,468%

Example 3

Songs from 4 to 7 were evaluated by the expert group in an amount of from 30 to 32 members of the working group that deals with garments appearance of wrinkles. The clothing items were rated on a 5 point scale, 1 - no folds and 5 - very much. Members of the working group were approximately 1.5 metres from the garment in a well lit room. The results below are averages, referred to a particular type of clothing washed in various conditions. Jeans (100% cotton) and shirts (65% polyester and 35% cotton) washed and then treated with compositions from 4 to 7. Appreciate 192 pairs of jeans and 192 shirts. Half (92) shirts and jeans were dried beche the ke, and half (92) were dried in the drying apparatus. The data shown in the table below, based on the total assessments after 3 washing cycles. A lower number indicates a smaller number of creases.

In the first washing 1.8 kg garments are washed in an automatic washing machine front loading using 45 litres of water with a hardness of 100 ppm at 25°C, and 30 g of detergent Axion laundry from the firm's Mexico. The second washing is carried out under the same conditions, but without detergent. The third washing 2.8 kg of garments carried out using 66 liters of water at room temperature (approximately 23-25°C), 42.5 g of liquid detergent Tide from the U.S. and 110 ml of composition 4, 5, 6, or 7 (for comparison). Garments most dried in the drying apparatus within 60 minutes.

TrackWashing without softener
4567
Jeans total2,12,11,92,172,24
D is INSY drying on a string to 2.292,612,592,522,75
Jeans drying in the drying apparatus2,18to 1.861,492,082,03
Shirt total2,952,642,662,803,12
Shirt drying on a string3,863,453,283,53to 3.58
Shirt drying in the drying apparatus2,041,832,242,07to 2.67

Compositions 5, 6, and 7 are similar except for the values Coltide™ HSi copolymer protein with silicone. When drying in the drying apparatus adding Coltide™ HSi copolymer protein with silicone reduces the number of wrinkles on the clothing items.

1. A method of reducing wrinkles in the wash on the garment of heavy fabric, VK is uchumi stage washing of the garment and apply conditioner to the cloth, comprising the combination of a fatty ester Quaternary ammonium and a copolymer of hydrolyzed protein polysiloxane, where the average molecular weight of the protein component is from 500 to 500,000 daltons, garment fabric, having a mass of at least 250 g/m2.

2. The method according to claim 1, in which the conditioning of the fabric contains from 1 to 50 wt.% connection fatty ester Quaternary ammonium from 0.02 to 0.5 wt.% copolymer hydrolyzed protein with a polysiloxane in the total weight of the composition.

3. The method according to claim 1, in which the conditioning for the tissue used to clean clothing.

4. The method according to claim 2, in which the combination of a fatty ester Quaternary ammonium includes fluids ditallow diethyl ammonium salt or fluids ditallow dimethyl ammonium salt.

5. The method according to claim 2, in which the softening composition comprises from 6 to 10 wt.% connection fatty ester Quaternary ammonium compounds and from 0.05 to 0.15 wt.% copolymer hydrolyzed protein with silicone in the total weight of the composition.

6. The method according to any preceding paragraph, in which the washing process includes a step of washing and a separate stage rinsing, where the copolymer hydrolyzed protein with silicone used in stage rinsing.

7. The method according to claim 6, in which stage cleaning is performed in the automatic washing machine, and the stage opolskie the Oia is performed manually.

8. The method according to claim 6, in which the washing process is performed in the automatic washing machine, which has by cleaning stage and the stage of rinsing, where the conditioning for the tissue used in the stage rinsing.

9. The method according to claim 6, further comprising drying the set of clothes of heavy fabric in the drying apparatus.

10. Air conditioning to reduce creases in the garment of heavy fabric, including:
a) from 0.5% to 50 wt.% cationic softener containing compound ester of a fatty acid Quaternary ammonium,
b) from 0.02% to 0.5 wt.% copolymer hydrolyzed protein with silicone, where the average molecular weight of the protein component is from 500 to 500,000 daltons,
c) flavouring substance and
d) water.

11. The conditioning of claim 10, in which the softener includes gitarowy fluids diethyl ammonium salt or gitarowy fluids dimethyl ammonium salt.

12. The conditioning of claim 10, in which the copolymer hydrolyzed protein includes silicone copolymer having the formula:

in which R is the residue hydrolyzed protein R-NH2; each R1is independently the residue organofunctional silane HR1-Si(R2')(R3'HE is, in which R2'and R3'is independently methyl, hydroxy, alkoxy having from 1 to 6 carbon atoms;
R2and R3are not avisio methyl, hydroxy, alkoxy having from 1 to 6 carbon atoms, or a residue of a compound of formula (A) or (B):

in which R and R1, R2and R3are each independently as defined above; and n corresponds to the number of the reacted amine groups having from 0.1 to 0.4 molecules of silane on the reactivity of the amino group of the protein.

13. Air conditioning in p-12, in which the softening composition contains from 6 to 10 wt.% connection fatty ester Quaternary ammonium compounds and from 0.05 to 0.15 wt.% copolymer hydrolyzed protein with silicone calculated on the total weight of the composition.



 

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20 cl, 4 ex

FIELD: chemistry.

SUBSTANCE: disclosed are compounds of formula (I), where a is an integer from 0 to 200; b is an integer from 1 to 40; c is an integer from 1 to 40; n is an integer from 1 to 50; x is an integer from 0 to 21; and R corresponds to formula (II) or formula (III). Also disclosed are intermediate compounds which are formed when producing the disclosed compound of formula (I), a composition of a personal hygiene product and a composition of a household chemical, containing the disclosed alkyl quaternium silicone compound.

EFFECT: owing to their unique structure, the disclosed compounds enable to form unique microemulsions and provide unique hair conditioning properties.

31 cl, 6 tbl, 41 ex

FIELD: chemistry.

SUBSTANCE: personal hygiene composition contains a polymerised surfactant selected from a group consisting of poly(sodium allyldodecyl sulphosuccinate), poly(acrylic acid co-2-acrylamidododecyl sulphonic acid) and poly(sodium allyldodecyl sulphosuccinate-co-acrylic acid) and an ingredient which is usually used in personal hygiene compositions. Preferably, the composition has TEP of about 3 or higher. The composition can additionally contain at least one monomer surfactant.

EFFECT: reduced irritant effect on the skin and eyes, increased foaming.

10 cl, 14 tbl, 27 ex, 1 dwg

FIELD: medicine.

SUBSTANCE: invention refers to chemical-pharmaceutical and cosmetic industry and represents an aqueous composition containing a system containing surfactants applicable in transparent surfactant products substantially consisting of water, microfibre cellulose in the concentration of approximately 0.05% to approximately 0.15% (wt/wt), a surfactant in the concentration of approximately 5% to approximately 50% (wt/wt of the active surfactant), suspended particles of inclusions, and optionally an excipient with the composition being transparent.

EFFECT: invention provides making the condensed system containing the surfactant which is transparent and contains suspended particles of inclusions.

15 cl, 5 ex, 5 dwg

FIELD: chemistry.

SUBSTANCE: present invention relates to a laundry detergent composition containing glycosyl hydrolase, having enzyme activity with respect to both xyloglucan and amorphous cellulose substrates, where the glycosyl hydrolase is selected from GH 5, 12, 44 or 74 families; (ii) 0.05-10 wt % amphiphilic alkoxylated fat-removing polymer; and (iii) 2-50 wt % synthetic detergent. The present invention also relates to a laundry detergent composition containing: (i) glycosyl hydrolase, having enzyme activity with respect to both xyloglucan and amorphous cellulose substrates, where the glycolsyl hydrolase is selected from GH 5, 12, 44 or 74 families; (ii) a random graft polymer containing: (a) a hydrophilic backbone chain containing monomers selected from a group consisting of: alcohols, alkoxyl links and maleic anhydride; and (b) hydrophobic side chain(s) selected from a group consisting of: vinyl ester of saturated C1-C6 monocarboxylic acid, C1-C6 alkyl ester of acrylic or methacrylic acid; and (iii) 2-50 wt % synthetic detergent. The present invention also relates to a method of washing fabrics.

EFFECT: improved dirt-removing profile and whiteness retention profile with low content of surfactants.

20 cl, 28 ex

FIELD: chemistry.

SUBSTANCE: present invention relates to decontaminating, cleaning and degreasing surfaces. The foam consists of a dispersion of air bubbles in a foaming aqueous solution containing: 0.1-7 mol of one or more decontaminating, cleaning and/or degreasing reactant per litre of the solution, 0.01-25 wt % with respect to total weight of the solution of solid particles of the same type or mixtures of solid particles of different types, having foaming properties. The method of producing the foam involves mixing a decontaminating, cleaning and/or degreasing active agent, solid particles having foaming properties and, optionally, a surfactant, an oxidising agent, a complexing agent, a gelating agent and/or a solid foaming agent and/or solid particles having sorption properties before generating foam.

EFFECT: increasing foam life to 24 hours, which provides higher efficiency of decontaminating, cleaning and/or degreasing surfaces.

26 cl, 3 dwg, 2 ex

FIELD: chemistry.

SUBSTANCE: invention relates to a detergent or cleaning agent composition containing an amphiphilic water-soluble alkoxylated polyalkylene imine polymer which contains, in condensed form, repeating units of formulae (I), (II), (III) and (IV) and having an internal polyethylene oxide block containing 20-50 polyethylene oxide links and a terminal polypropylene oxide block containing 10-50 polyethylene links, and especially such alkoxylated polyalkylene imines in which the ratio of polyethylene oxide links to polypropylene oxide links is proportional to the square root of the number of polyalkylene imine links present in the backbone chain. The present invention also relates to a cleaning tool which contains a non-woven substrate and a detergent or cleaning agent composition.

EFFECT: improved properties of the composition.

15 cl, 12 ex

FIELD: chemistry.

SUBSTANCE: invention relates to compositions containing polymerised surfactants, particularly compositions of personal hygiene agents which contain a polymerised surfactant with low degree of polymerisation. Said composition has CMID of less than 90%. The polymerised surfactant is selected from a group consisting of allylalkyl sulphosuccinates EUAH, an anionic monomer and an amphiphilic monomer EUAC, and copolymers of maleic anhydride and long-chain α-olefins or alkyl vinyl ethers PPDA. The polymerised surfactant contains (a) 7-2000 amphiphilic repeating units on weighted average, and (b) the amphiphilic repeating units constitute at least 10 mol % of the polymerised surfactant. The composition contains at least one additional personal hygiene agent. The invention relates to a method cleaning the human body. The invention also relates to a method of producing the composition of the personal hygiene agent with a low irritant effect.

EFFECT: invention has relatively low irritant properties and the compositions have remarkably low content of small-sized micella as indicated by the CMID value.

FIELD: chemistry.

SUBSTANCE: invention relates to a composition for one-time packaging of a film-coated detergent in which the detergent composition is coated by a water-soluble or dispersible coating. The coating contains from at least 50% to 99% of a compound selected from (A1) protein or peptide, preferably gelatine or peptide(s) thereof, (A3) shellac or (B) amino acid(s) or a mixture of at least two of them. The coating also contains a plasticiser selected from monoalkyl ethers of alkylene glycol, glycerine, polystyrenes, propylene glycols, ethoxylated or propoxylated ethylene or propylene, glycerine esters, glycerine triacetate, polyethylene glycols, methyl esters and amides, and nonionic surfactants. The invention also relates to a method of producing said composition.

EFFECT: easy and safe to handle detergent composition.

11 cl, 1 ex

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