Agent, containing delivering particles, which produces favourable impact

FIELD: medicine.

SUBSTANCE: claimed invention relates to medicine and describes method of obtaining delivering particles of fragrance, containing core material and envelope, said envelope at least partially surrounds said core material and at least 75% of said delivering particles of fragrance are characterised by tensile strength from approximately 0.2 MPa to approximately 10 MPa, with particle size from approximately 1 micron to approximately 80 micron and thickness of particle walls from approximately 60 nm to approximately 250 nm; and said delivering particles of fragrance are characterised by release of fragrance from 0% to approximately 30%. In addition to creation of possibility to reduce number of agent which produces favourable impact, such particles make it possible to extend spectrum of applied agents which produce favourable impact.

EFFECT: in cases of application in compositions, for instance, detergents, or compositions for fabric care, such particles increase efficiency of delivery of agent which produces favourable impact, making it possible to use reduced amounts of agents which produce favourable impact.

11 cl, 9 tbl, 13 ex

 

The technical field

This invention relates to providing a beneficial effect to the agent containing the arriving particles, compositions containing such particles, and methods of making and using such particles and compositions.

Prior art

Have positive influence agents, such as perfumes, silicones, waxes, fragrances, vitamins and fabrics softeners are expensive and/or usually lose their effectiveness when used in consumer products in large quantities, for example, compositions for personal care, detergent compositions and compositions for the care of fabrics. As a result, there is a desire to maximize the efficiency of these have beneficial effects agents. One way of achieving this goal is to improve the efficiency of delivery of such which have a beneficial effect agents. Unfortunately, it is difficult to improve the efficiency of delivery which have a beneficial effect agents, as such agents may be lost because of a physical or chemical characteristics of the agent or such agents may be incompatible with other components of the compositions or the target area.

Accordingly, there is a need to have beneficial effects agent containing DOS is alaysia particles, provides improved efficiency of delivery agent, which have a beneficial effect.

The invention

The present invention relates to providing a beneficial effect to the agent, delivering containing particles comprising a core material and a wall material that at least partially surrounds the core material. The present invention also relates to compositions containing these particles, and methods of making and using such particles and compositions.

A detailed description of the invention

Definition

Used here the meaning of "consumer product" means the products or devices for child care, cosmetic care, to care for fabrics and home care, family care, feminine hygiene, Wellness destination, snacks and/or drinks, intended for use or consumption in the form in which they are sold, and not intended for further industrial production or modification. Such products include, without limitation, diapers, bibs, shawls; products designed for, and/or methods relating to hair care (people, dogs and/or cats), including bleaching, tinting, dyeing, conditioning, shampooing, styling; deodorants and antiperspirants; with whom estva personal hygiene; cosmetics; preparations for the care of skin, including the application of creams, lotions, and other products of local applications for consumer use; and means for shaving products designed for, and/or methods relating to the treatment of fabrics, hard surfaces and any other surfaces in the area of care for fabrics and home care, including: air fresheners air, car care products, dishwashing tools, air conditioning fabrics (including abating), detergents for washing, additives for washing and rinsing and/or to care for fabrics during washing, cleaning and/or processing of solid surfaces and other cleaning products for use by consumers or organizations; products and/or methods relating to bathing towels, napkins, facial, paper handkerchiefs, and/or paper towels; tampons, female sanitary napkins; products and/or methods relating to the means to care for the oral cavity, including toothpastes, tooth gels, tooth elixirs, denture adhesives, tools for teeth whitening; Wellness products sold without a prescription, including drugs for cough and cold, pain relievers, medicines, over-the-counter prescription (RX), funds for health care and nutrition of domestic animals and for acidimage; processed food products intended primarily for use in between regular meals or as food related products (non-limiting examples include potato chips, tortillas chips, popcorn, pretzels, corn chips, cereal bars, vegetable crisps or crisps, mixed snacks, mixed snacks for parties, chips from a mixture of cereals, snack crackers, cheese snacks, pork rinds, corn cereals, granular, Breakfast cereals, extruded Breakfast cereals and bagels); and coffee.

Used here is the term "detergent composition" includes, unless otherwise indicated, granular or powder-like universal or detergent for heavily contaminated products, especially cleaning products containing surfactants; liquid, gel or paste-like universal cleaning agents, especially the so-called liquid funds for heavily contaminated products; liquid detergent for delicate fabrics; means for washing dishes manually or means for washing lightly polluted dishes, especially heavily foamy; means for washing dishes in dish-washing machines, including the various tablet, granular, liquid and rinsing types means to use the education in the home and institutions; liquid cleaning and disinfecting agents, including antibacterial cleansers for manually lump detergents, liquid for rinsing the mouth, cleanser for the teeth and oral cavity, means for care of teeth, shampoo or tools for cleaning carpets, cleaning products for bathrooms; shampoos to wash your hair and conditioners for hair; shower gels and foam funds for baths and cleaning agents for metal; and an auxiliary cleaning products such as bleach additives and "pasted on the spot" means or means for pre-processing means on the media, such as wipes impregnated with a softener-antistatic, dry and wetted wipes and applicators, non-woven materials and sponges; as well as spray and aerosols.

Used here meaning the term "compositions for the care of tissue" includes, unless otherwise specified, a softener compositions, compositions for improving properties of tissues and structures for refreshment tissues, and combinations thereof.

Used here is the phrase "which have a beneficial effect agent, delivering containing particles comprises microcapsules, including microcapsules flavors.

Used here, the meaning of the terms "particle," "to provide a beneficial effect agent, delivering containing particles", "capsule" and"microcapsule" are synonyms.

Used here the value form of the singular (with the articles "a" and "an"), when used in the claims, should be understood as denoting one or more of the claimed or described objects.

Used here is the terms "include," "includes" and "including" are all used as a non-limiting.

Testing methods disclosed in Methods of testing this application should be used to determine the appropriate parameter values inventions applicants.

Unless otherwise noted, all content of the components or compositions belong to the active part of the component or composition, and do not take into account impurities, e.g., residual solvents or by-products that may be present in commercially available sources of such components or compositions.

All interest parts and ratios are calculated by weight, unless otherwise indicated. All interest parts and ratios are calculated with respect to the composition as a whole, unless otherwise noted.

It should be understood that each of the upper numerical limit specified in this description, includes all having smaller values of the numerical range, as if such lower numerical limits were explicitly specified here. Every lower numerical limit specified in this description, includes all of the available the large values of the numeric limits as if such a higher numerical limits were explicitly specified here. Each range of numeric values specified in this specification, includes all narrower ranges of numeric values that fall within this broader range of numeric values, as if such narrower numerical ranges of values were all explicitly specified here.

Delivering agent particles, which have a beneficial effect

Applicants have discovered that the problem of ensuring effective and efficient delivery of exerting a beneficial effect of an agent can be solved in a cost efficient way using which have a beneficial effect agent, delivering containing particles comprising a core material and a wall material that at least partially surrounds the specified core material and has a certain combination of physical and chemical characteristics. Such physical and chemical characteristics are strength, particle size, wall thickness of the particles and the release agent, creating a useful effect.

In the first aspect of the disclosed delivering particles which have a beneficial effect agent containing the core material and the shell, and this shell at least partially surrounds the specified core material. When conducting and the tests in accordance with these applicants are ways of testing at least 75%, 85% or even 90% of these delivers particles which have a beneficial effect agent have a tensile strength of from about 0.2 MPa to about 10 MPa, from about 0.4 MPa to about 5 MPa, from about 0.6 MPa to about 3.5 MPa, or even from about 0.7 MPa to about 3 MPa and magnitude of the release have beneficial effects agent from 0% to about 30%, from 0% to about 20%, or even from 0% to about 5%.

In one aspect, at least 75%, 85% or even 90% of these delivers particles which have a beneficial effect agent may have a particle size from about 1 micron to about 80 microns, from about 5 microns to 60 microns, from about 10 microns to about 50 microns or even from about 15 microns to about 40 microns.

In one aspect, at least 75%, 85% or even 90% of these delivers particles which have a beneficial effect agent may have a wall thickness of the particles is from about 30 nm to about 250 nm, from about 80 nm to about 180 nm, or even from about 100 nm to about 160 nm.

In one aspect, the core material delivering these particles have positive influence agent may contain a material selected from the group consisting of primary aromatic material, and/or optionally a material selected from the group consisting of vegetable oils, including what I diluted and/or mixed vegetable oil, including castor oil, coconut oil, cottonseed oil, grape seed oil, rapeseed oil, soybean oil, corn oil, palm oil, linseed oil, safflower oil, olive oil, peanut oil, coconut oil, palm kernel oil, castor oil, lemon oil, and mixtures thereof; esters of vegetable oils, including dibutylamine, dibutylphthalate, butylbenzylamine, benzylacrylamide, tricresylphosphate, trioctylphosphine esters and mixtures thereof; linear or branched hydrocarbons, including linear or branched hydrocarbons having a boiling point above about 80°C; partially hydrogenated terphenyls, diallylphthalate, alkylbiphenyls, including monoisopropylamine, alkilirovanny naphthalene, including depopulation, petroleum ethers, including kerosene, mineral oil and mixtures thereof; aromatic solvents including benzene, toluene, and mixtures thereof; silicone oils and mixtures thereof.

In one aspect, the material of the wall of delivering these particles have positive influence agent may contain suitable resin including the reaction product of the aldehyde and amine, and suitable aldehydes include formaldehyde. Suitable amines include melamine, urea, benzoguanamine, glycoluril and mixtures thereof. Suitable melamine include metromela is, methylated metropolin, erinomainen and mixtures thereof. Suitable urea include dimethylamino, the methylated dimethylamino, urea-resorcinol and mixtures thereof. Suitable materials for their manufacture can be obtained from one or more of the following companies Solutia Inc. (St.Louis, Missouri, USA), Cytec Industries (West Paterson, New Jersey, USA), Sigma-Aldrich (St.Louis, Missouri, USA).

In one aspect, the core material delivering these particles have positive influence agent may contain a material selected from the group consisting of:

a) composition of the flavor of importance Clog P (the logarithm of the distribution coefficient between phases of n-octanol and water) less than 4.5, less 4,25, less 4.0 or even less than 3.75;

b) a flavoring composition containing, in terms of the total weight of the flavoring composition, 60% or even 70% of flavouring materials having a Clog P less than 4,0;

c) a flavoring composition containing, in terms of the total weight of the flavoring composition, 35%, or 50%or even 60% of flavouring materials having a Clog p of less than 3.5;

d) a flavoring composition containing, in terms of the total weight of the flavoring composition, 40% of flavouring materials having a Clog P of less than 4.0 or even less than 3.5 and at least 1% flavoring materials having a Clog P of less than 2.0;

e) the composition of the flavor containing the th, in terms of the total weight of the flavoring composition, 40% of flavouring materials having a Clog P of less than 4.0 or even less than 3.5 and at least 15% flavoring materials having a Clog P less than 3,0;

f) a flavoring composition containing, in terms of the total weight of the flavoring composition, at least 1% or even 2% butanoate of ester and at least 1% pentanoate complex ether;

g) a flavoring composition containing, in terms of the total weight of the flavoring composition, of at least 2% or even 3% of ester containing allyl fragment, and at least 10%, 25% or even 30% other flavoring containing ester fragment.

h) a flavoring composition containing, in terms of the total weight of the flavoring composition, at least 1% or even 5% of the aldehyde containing fragment with alkyl chain;

i) a flavoring composition containing, in terms of the total weight of the flavoring composition, of at least 2% butanoate complex ether;

(j) a flavoring composition containing, in terms of the total weight of the flavoring composition, at least 1% pentanoate complex ether;

k) a flavoring composition containing, in terms of the total weight of the flavoring composition, at least 3% of ester containing allyl fragment, and 1% of the aldehyde, steriade what about the fragment with alkyl chain;

l) a flavoring composition containing, in terms of the total weight of the flavoring composition, at least 25% of aromatic compounds containing ester fragment, and 1% of the aldehyde containing fragment with alkyl chain;

m) of flavoring compositions containing, calculated on the total weight of the flavoring composition, of at least 2% or even 10% of material selected from Ivanov, such as 4-(2,6,6-trimethyl-1-cyclohexenyl)-3-butene-2-it, 4-(2,6,6-trimethyl-2-cyclohexenyl)-3-butene-2-it 3-methyl-4-(2,6,6-trimethyl-1-cyclohexen-2-yl)-3-butene-2-he mixtures thereof;

n) a flavoring composition containing, in terms of the total weight of the flavoring composition, of at least 0.1% or even 1% tridec-2-isonitrile and Mandarina (3,12-tridecanal) and mixtures thereof;

a) a flavoring composition containing, in terms of the total weight of the flavoring composition, of at least 2% or even 5% of a material selected from 3,7-dimethyl-6-octennial, 2-cyclohexylidene-2-phenylacetonitrile and mixtures thereof;

p) a flavoring composition containing, in terms of the total weight of the flavoring composition, of at least 80% of one or more aromatic compounds containing fragment selected from the group consisting of esters, aldehydes, Ivanov, NITRILES, ketones and combinations thereof;

q) a flavoring composition containing, p is Rescate on the total weight of the composition of the flavor at least 3% of ester containing allyl fragment; a flavoring composition containing, in terms of the total weight of the flavoring composition, of at least 20%, 30% or even 50% of a material selected from the group consisting of: 1-methylethyl-2-methylbutanoate; ethyl-2-methylpentanoate; 1,5-dimethyl-1-ethenylene-4-enolacetate; u-COP-1-ene-8-racette; 4-(2,6,6-trimethyl-2-cyclohexenyl)-3-butene-2-she; 4-acetoxy-3-methoxy-1-propenylbenzene; 2-propylcyclohexanone; 3-(1-methylethyl)ethyl ether complex bicyclo[2.2.1]hept-5-ene-2-carboxylic acid; bicyclo[2.2.1]heptane-2-ol, 1,7,7-trimethyl-, acetate; 1,5-dimethyl-1-Etoiles-4-enolacetate; hexyl-2-methylpropanoate; ethyl-2-methylbutanoate; 4-undecanone; 5-heptaldehyde-2(3h)-furanone; 1,6-nonadien-3-ol, 3,7-dimethyl-; 3,7-dimethylocta-1,6-Dien-3-ol; 3-cyclohexen-1-carboxaldehyde, dimethyl-; 3,7-dimethyl-6-octennial; 4-(2,6,6-trimethyl-1-cyclohexenyl)-3-butene-2-it; tridec-2-isonitrile; essential oils of patchouli; ateltico[5.2.1.0]decane-2-carboxylate; 2,2-dimethylcyclohexanone; hexadecanoate; 7-acetyl, 1,2,3,4,5,6,7,8-octahydro-1,1,6,7-tetramethylnaphthalene; arylcyclohexylamine; metalloelastase aldehyde; 1-Spiro[4,5]Dec-7-EN-7-yl-4-pentene-1-it; 7-octene-2-ol, 2-methyl-6-methylene-, dihydro; cyclohexanol, 2-(1,1-dimethylethyl)-, acetate; hexahydro-4,7-methanoindan-5(6)-improveverywhere-4,7-meta is onden-5(6)-ylpropionic; 2-methoxynaphthalene; 1-(2,6,6-trimethyl-3-cyclohexenyl)-2-butene-1-it; 1-(2,6,6-trimethyl-2-cyclohexenyl)-2-butene-1-it; 3,7-dimethyloctan-3-ol; 3-butene-2-it, 3-methyl-4-(2,6,6-trimethyl-1-cyclohexen-2-yl)-; hexanoic acid, 2-propilovogo of ester; (z)-non-6-EN-1-al; 1-decroly aldehyde; 1-octanal; 4-t-butyl-α-methylhydrocinnamic aldehyde, alpha-mexikoring aldehyde; ethyl-2,4-hexadiene; 2-propenyl-3-cyclohexylpropionate; and mixtures thereof;

d) a flavoring composition containing, in terms of the total weight of the flavoring composition, of at least 20%, 30% or even 50% of a material selected from the group consisting of: 1-methylethyl-2-methylbutanoate; ethyl-2-methylpentanoate; 1,5-dimethyl-1-Etoiles-4-enolacetate; u-COP-1-ene-8-racette; 4-(2,6,6-trimethyl-2-cyclohexenyl)-3-butene-2-it; 4-acetoxy-3-methoxy-1-propenylbenzene; 2-propylcyclohexanone; bicyclo[2.2.1]hept-5-ene-2-carboxylic acid, 3-(1-methylethyl)ethyl ether complex; bicyclo[2.2.1]heptane-2-ol, 1,7,7-trimethyl-, acetate; 1,5-dimethyl-1-Etoiles-4-enolacetate; hexyl-2-methylpropanoate; ethyl-2-methylbutanoate, 4-undecanone; 5-heptaldehyde-2(3h)-furanone; 5-hydroxydecanoic acid; decalactone; undecalactone; 1,6-nonadien-3-ol, 3,7-dimethyl-; 3,7-dimethylocta-1,6-Dien-3-ol; 3-cyclohexen-1-carboxaldehyde, dimethyl-; 3,7-dimethyl-6-octennial; 4-(2,6,6-trimethyl-1-cyclohexenyl)-3-butene--it; tridec-2-isonitrile; essential oils of patchouli; ateltico[5.2.1.0]decane-2-carboxylate; 2,2-dimethylcyclohexanone; arylcyclohexylamine; metalloelastase aldehyde; 1-Spiro[4,5]Dec-7-EN-7-yl-4-pentene-1-it; 7-octene-2-ol, 2-methyl-6-methylene-, dihydro, cyclohexanol, 2-(1,1-dimethylethyl)-, acetate; hexahydro-4,7-methanoindan-5(6)-improveverywhere-4,7-methanoindan-5(6)-ylpropionic; 2-methoxynaphthalene; 1-(2,6,6-trimethyl-3-cyclohexenyl)-2-butene-1-it; 1-(2,6,6-trimethyl-2-cyclohexenyl)-2-butene-1-it; 3,7-dimethyloctan-3-ol; 3-butene-2-it, 3-methyl-4-(2,6,6-trimethyl-1-cyclohexen-2-yl)-; hexanoic acid, 2-propilovogo of ester; (z)-non-6-EN-1-al; 1-delovogo aldehyde; 1-octanal; 4-t-butyl-α-methylhydrocinnamic aldehyde; ethyl-2,4-hexadiene; 2-propenyl-3-cyclohexylpropionate; and mixtures thereof;

s) composition of the flavor containing, calculated on the total weight of the flavoring composition, at least 5% of a material selected from the group consisting of 3-cyclohexen-1-carboxaldehyde, dimethyl-; 3-butene-2-it, 3-methyl-4-(2,6,6-trimethyl-1-cyclohexen-2-yl)-; essential oils of patchouli; hexanoic acid, 2-propilovogo of ester; 1-octanal; 1-delovogo aldehyde; (z)-non-6-EN-1-Ala; metalloelastase aldehyde; ethyl-2-methylbutanoate; 1-methylethyl-2-methylbutanoate; ethyl-2-methylpentanoate; 4-hydroxy-3-ethoxybenzaldehyde; 4-hydroxy-3-m is oxybenzaldehyde; 3-hydroxy-2-methyl-4-pyrone; 3-hydroxy-2-ethyl-4-pyrone and mixtures thereof;

t) a flavoring composition containing, in terms of the total weight of the flavoring composition, less than 10% or even 5% of flavoring materials having a Clog P greater than 5.0;

u) flavoring compositions containing geranylacetate; or

v) the composition of the flavor containing the first and, optionally, the second material and said first material has:

(i) a Clog P of at least 2, from about 2 to about 12, from about 2.5 to about 8, or even from about 2.5 to about 6;

(ii) a boiling point of less than about 280°C., from about 50°C. to less than about 280°C., from about 50°C. to less than about 265°C. or even from about 80°C. to less than about 250°C.; and

the second optional material, in case of its presence, has

(i) a Clog P of less than 2.5, or even from less than 2 up to about 0.1; and

(ii) ODT (detection limit of smell) is less than about 100 ppb, from about within 0.00001 ppb to less than about 100 ppb, from about within 0.00001 ppb to less than about 50 ppb or even from some within 0.00001 ppb to less than about 20 ppb.

In one aspect of delivering these particles have positive influence agent may contain, in terms of the total weight of the arriving particles which have a beneficial effect agent, at least 1 wt.%, from about 20 to about 95 wt.%, from about 50 to p is IMEMO 90% wt. or even from about 80 to about 85 wt.%. agent, providing a beneficial effect.

In one aspect, the core material delivering these particles have positive influence agent may contain, in terms of the total weight of the core material, at least about 20, from about 50 to about 70, or even from about 60 to about 100 wt.%, agent, providing a beneficial effect.

In one aspect of delivering these particles have positive influence agent may contain, in terms of the total weight of the particles, from about 20% wt. to about 95 wt.%, from about 50% wt. to about 90 wt.%, from about 70% wt. to about 85 wt.%. or even from about 80 wt.%. to about 85 wt.%. the composition of the flavoring.

In one aspect of delivering these particles have positive influence agent can be dried by spraying listed delivering agent particles, which have a beneficial effect.

In one aspect of delivering these particles have positive influence agent can be any combination of the above parameters listed in the above aspects.

Suitable materials for their manufacture can be supplied by one or more of the following companies: Firmenich (Geneva, Switzerland), Givauan (Argenteuil, France), IFF (Hazlet, New Jersey, USA), Quest (Mount Olive, New Jersey, USA), Bedoukian (Danbury, Connecticut, USA), Sigma Aldrich (St.Louis, Missouri, USA), Millennium Specialty Chemicals (Olympia Fields, Illinois, USA), Polarone International (Jersey City, New Jersey, USA), Fragrance Resources (Keyport, New Jersey, USA) and Aroma &Flavor Specialties (Danbury, Connecticut, USA) or synthesized in accordance with Example I, USP 5625205 with the replacement of succinic acid to palmitic acid or Example II USP 5652205 replacement laureillard on palmitoylated.

The method of obtaining delivers particles containing the agent, which have a beneficial effect

In one aspect of the disclosed method, including:

a) preparing a first solution containing, calculated on the total weight of the solution, from about 20% to about 90%, from about 40% to about 80%, or even from about 60% to about 80% water, the first emulsifier and the first resin, and the ratio of the specified first emulsifier and the first resin is from about 0.1:0 to about 10:0, from about 0.1:1 to about 10:1, from about 0.5:1 to about 3:1 or even from about 0.8:1 to about 1.1:1;

b) preparing a second solution containing, calculated on the total weight of the solution, from about 20% to about 95% water, a second emulsifier and a second resin, and the ratio of the specified second emulsifier and the second resin is from about 0:1 to about 3:1, from about 0.04 to:1 to approximately 0.2:1, or even from approximately 0.05:1 to primer is to 0.15:1;

c) the consolidation of the core material and specified the first solution with the formation of the first composition;

d) emulsification of the specified first composition;

e) the Union of the specified first composition and the second solution with the formation of the second composition and optionally combining any processing AIDS and the specified second composition, said first composition and said second solution can be combined in any order, but, in one aspect, the specified second solution is added to the specified first composition or the second solution and the first part of unite at the same time;

f) mixing the specified second composition for at least 15 minutes, at least 1 hour or even from about 4 hours to about 100 hours at a temperature of from about 25°to about 100°C., from about 45°to about 90°C. or even from about 50°to about 80°C. and optionally combining any processing AIDS with the specified second composition;

g) optionally combining any material absorber, amendment and/or antiglomerular agent with a specified second composition on the stage (f), or after it, such materials may be combined in any order, but, in one aspect, the material of the absorber admixed first, any amendment - second, and then use the more antiaglomerate agent; and

h) optionally spray drying the specified second part.

In one aspect of the above method specified core material includes raw fragrant material.

In one aspect, the core material delivering these particles have positive influence agent may contain a material selected from the group consisting of:

a) composition of the flavoring, having a Clog P less than 4.5, less 4,25, less 4.0 or even less than 3.75;

b) a flavoring composition containing, in terms of the total weight of the flavoring composition, 60% or even 70% of flavouring materials having a Clog P less than 4,0;

c) a flavoring composition containing, in terms of the total weight of the flavoring composition, 35% or 50% or even 60% of flavouring materials having a Clog p of less than 3.5;

d) a flavoring composition containing, in terms of the total weight of the flavoring composition, 40% of flavouring materials having a Clog P of less than 4.0 or even less than 3.5 and at least 1% flavoring materials having a Clog P of less than 2.0;

e) a flavoring composition containing, in terms of the total weight of the flavoring composition, 40% of flavouring materials having a Clog P of less than 4.0 or even less than 3.5 and at least 15% flavoring materials having a Clog P less than 3,0;

f) a flavoring composition containing, per the account on the total weight of the composition of the flavor at least 1% or even 2% butanoate of ester and at least 1% pentanoate complex ether;

g) a flavoring composition containing, in terms of the total weight of the flavoring composition, of at least 2% or even 3% of ester containing allyl fragment and at least 10%, 25% or even 30% of another aromatic compounds containing ester fragment.

h) a flavoring composition containing, in terms of the total weight of the flavoring composition, at least 1% or even 5% of the aldehyde containing fragment with alkyl chain;

i) a flavoring composition containing, in terms of the total weight of the flavoring composition, of at least 2% butanoate complex ether;

(j) a flavoring composition containing, in terms of the total weight of the flavoring composition, at least 1% pentanoate complex ether;

k) a flavoring composition containing, in terms of the total weight of the flavoring composition, at least 3% of ester containing allyl fragment, and 1% of the aldehyde containing fragment with alkyl chain;

l) a flavoring composition containing, in terms of the total weight of the flavoring composition, at least 25% of aromatic compounds containing ester fragment, and 1% of the aldehyde containing fragment with alkyl chain;

m) to the positions of flavors, containing, calculated on the total weight of the flavoring composition, of at least 2% or even 10% of material selected from Ivanov, such as 4-(2,6,6-trimethyl-1-cyclohexenyl)-3-butene-2-it, 4-(2,6,6-trimethyl-2-cyclohexenyl)-3-butene-2-he and 3-butene-2-it, 3-methyl-4-(2,6,6-trimethyl-1-cyclohexen-2-yl)- and mixtures thereof;

n) a flavoring composition containing, in terms of the total weight of the flavoring composition, of at least 0.1% or even 1% tridec-2-isonitrile and Mandela and mixtures thereof;

a) a flavoring composition containing, in terms of the total weight of the flavoring composition, of at least 2% or even 5% of a material selected from 3,7-dimethyl-6-octennial, 2-cyclohexylidene-2-phenylacetonitrile and mixtures thereof;

p) a flavoring composition containing, in terms of the total weight of the flavoring composition, of at least 80% of one or more aromatic compounds containing fragment selected from the group consisting of esters, aldehydes, Ivanov, NITRILES, ketones and combinations thereof;

q) a flavoring composition containing, in terms of the total weight of the flavoring composition, at least 3% of ester containing allyl fragment; a flavoring composition containing, in terms of the total weight of the flavoring composition, of at least 20%, 30% or even 50% of a material selected from the group consisting of: 1-methylethyl-methylbutanoate; ethyl-2-methylpentanoate; 1,5-dimethyl-1-ethenylene-4-enolacetate; u-COP-1-ene-8-racette; 4-(2,6,6-trimethyl-2-cyclohexenyl)-3-butene-2-it; 4-acetoxy-3-methoxy-1-propenylbenzene; 2-propylcyclohexanone; bicyclo[2.2.1]hept-5-ene-2-carboxylic acid, 3-(1-methylethyl)ethyl ether complex; bicyclo[2.2.1]heptane-2-ol, 1,7,7-trimethyl-, acetate; 1,5-dimethyl-1-Etoiles-4-enolacetate; hexyl-2-methylpropanoate; ethyl-2-methylbutanoate; 4-undecanone; 5-heptaldehyde-2(3h)-furanone; 1,6-nonadien-3-ol, 3,7-dimethyl-; 3,7-dimethylocta-1,6-Dien-3-ol; 3-cyclohexen-1-carboxaldehyde, dimethyl-; 3,7-dimethyl-6-octennial; 4-(2,6,6-trimethyl-1-cyclohexenyl)-3-butene-2-it; tridec-2-isonitrile; essential oils of patchouli; ateltico[5.2.1.0]decane-2-carboxylate; 2,2-dimethylcyclohexanone; hexadecanoate; 7-acetyl-1,2,3,4,5,6,7,8-octahydro-1,1,6,7-tetramethylnaphthalene; arylcyclohexylamine; metalloelastase aldehyde; 1-Spiro[4,5]Dec-7-EN-7-yl-4-pentene-1-it; 7-octene-2-ol, 2-methyl-6-methylene-, dihydro; cyclohexanol, 2-(1,1-dimethylethyl)-, acetate; hexahydro-4,7-methanoindan-5(6)-improveverywhere-4,7-methanoindan-5(6)-ylpropionic; 2-methoxynaphthalene; 1-(2,6,6-trimethyl-3-cyclohexenyl)-2-butene-1-it; 1-(2,6,6-trimethyl-2-cyclohexenyl)-2-butene-1-it; 3,7-dimethyloctan-3-ol; 3-butene-2-it, 3-methyl-4-(2,6,6-trimethyl-1-cyclohexen-2-yl)-; hexanoic acid, 2-propilovogo of ester; (z)-but the-6-EN-1-al; 1-delovogo aldehyde; 1-octanal; 4-t-butyl-α-methylhydrocinnamic aldehyde, alpha-mexikoring aldehyde; ethyl-2,4-hexadiene; 2-propenyl-3-cyclohexylpropionate; and mixtures thereof;

r) a flavoring composition containing, in terms of the total weight of the flavoring composition, of at least 20%, 30% or even 50% of a material selected from the group consisting of: 1-methylethyl-2-methylbutanoate; ethyl-2-methylpentanoate; 1,5-dimethyl-1-Etoiles-4-enolacetate; u-COP-1-ene-8-racette; 4-(2,6,6-trimethyl-2-cyclohexenyl)-3-butene-2-it; 4-acetoxy-3-methoxy-1-propenylbenzene; 2-propylcyclohexanone; bicyclo[2.2.1]hept-5-ene-2-carboxylic acid, 3-(1-methylethyl)-ethyl ether complex; bicyclo[2.2.1]heptane-2-ol, 1,7,7-trimethyl-, acetate; 1,5-dimethyl-1-Etoiles-4-enolacetate; hexyl-2-methylpropanoate; ethyl-2-methylbutanoate, 4-undecanone; 5-heptaldehyde-2(3h)-furanone; 5-hydroxydecanoic acid; decalactone; undecalactone; 1,6-nonadien-3-ol, 3,7-dimethyl-; 3,7-dimethylocta-1,6-Dien-3-ol; 3-cyclohexen-1-carboxaldehyde, dimethyl-; 3,7-dimethyl-6-octennial; 4-(2,6,6-trimethyl-1-cyclohexenyl)-3-butene-2-it; tridec-2-isonitrile; essential oils of patchouli; ateltico[5.2.1.0]decane-2-carboxylate; 2,2-dimethylcyclohexanone; arylcyclohexylamine; metalloelastase aldehyde; 1-Spiro[4,5]Dec-7-EN-7-yl-4-pentene-1-it; 7-octene-2-ol, 2-methyl-6-methyl is n, dihydro; cyclohexanol, 2-(1,1-dimethylethyl)-, acetate; hexahydro-4,7-methanoindan-5(6)-improveverywhere-4,7-methanoindan-5(6)-ylpropionic; 2-methoxynaphthalene; 1-(2,6,6-trimethyl-3-cyclohexenyl)-2-butene-1-it; 1-(2,6,6-trimethyl-2-cyclohexenyl)-2-butene-1-it; 3,7-dimethyloctan-3-ol; 3-butene-2-it, 3-methyl-4-(2,6,6-trimethyl-1-cyclohexen-2-yl)-; hexanoic acid, 2-propilovogo of ester; (z)-non-6-EN-1-al; 1-delovogo aldehyde; 1-octanal; 4-t-butyl-α-methylhydrocinnamic aldehyde; ethyl-2,4-hexadiene; 2-propenyl-3-cyclohexylpropionate; and mixtures thereof;

s) composition of the flavor containing, calculated on the total weight of the flavoring composition, at least 5% of a material selected from the group consisting of 3-cyclohexen-1-carboxaldehyde, dimethyl-; 3-butene-2-it, 3-methyl-4-(2,6,6-trimethyl-1-cyclohexen-2-yl)-; essential oils of patchouli; hexanoic acid, 2-propilovogo of ester; 1-octanal; 1-delovogo aldehyde; (z)-non-6-EN-1-Ala; metalloelastase aldehyde; ethyl-2-methylbutanoate; 1-methylethyl-2-methylbutanoate; ethyl-2-methylpentanoate; 4-hydroxy-3-ethoxybenzaldehyde; 4-hydroxy-3-methoxybenzaldehyde; 3-hydroxy-2-methyl-4-pyrone; 3-hydroxy-2-ethyl-4-pyrone and mixtures thereof;

t) a flavoring composition containing, in terms of the total weight of the flavoring composition, less than 10% or even 5% of flavoring materials having a Clog P bol is e 5,0;

u) flavoring compositions containing geranylacetate; or

v) the composition of the flavor containing the first and, optionally, the second material and said first material has:

(i) a Clog P of at least 2, from about 2 to about 12, from about 2.5 to about 8, or even from about 2.5 to about 6;

(ii) a boiling point of less than about 280°C., from about 50°C. to less than about 280°C., from about 50°C. to less than about 265°C. or even from about 80°C. to less than about 250°C.; and

the second optional material, in case of its presence, has

(i) a Clog P of less than 2.5, or even from less than 2 up to about 0.1; and

(ii) ODT less than about 100 ppb, from about within 0.00001 ppb to less than about 100 ppb, from about within 0.00001 ppb to less than about 50 ppb or even from some within 0.00001 ppb to less than about 20 ppb.

In one or more aspects of the way these first and second resins may contain a reaction product of the aldehyde and amine, and suitable aldehydes include formaldehyde. Suitable amines include melamine, urea, benzoguanamine, glycoluril and mixtures thereof. Suitable melamine include metropolin methylated metropolin, erinomainen and mixtures thereof. Suitable urea include dimethylamino, the methylated dimethylamino, urea-resorcinol and mixtures thereof.

In one or more aspects of the method are listed first and the second emulsifiers may contain a fragment, selected from the group consisting of carboxy, hydroxyl, thiol, amine, amide, and combinations thereof. In one aspect the specified emulsifier may have a pKa less than 5, preferably greater than 0 but less than 5. Emulsifiers include the copolymer of acrylic acid-alkylacrylate, poly(acrylic acid), esters polyoxyethylenesorbitan and fatty acids, polyalkylene-to-anhydrides of carboxylic acids, polyalkylene-to-anhydrides of maleic acid, poly(metilidinovy ether-co-maleic acid anhydride), poly(propylene-co-maleic acid anhydride), poly(butadiene-co-maleic acid anhydride) and poly(vinyl acetate-co-maleic acid anhydride), polyvinyl alcohols, polyalkylene glycols, polyoxyethyleneglycol and mixtures thereof.

In one or more aspects of the method specified core material may contain raw fragrant material and/or optionally a material selected from the group consisting of a material selected from the group consisting of vegetable oils, including undiluted and/or mixed vegetable oils, including castor oil, coconut oil, cottonseed oil, grape seed oil, rapeseed oil, soybean oil, corn oil, palm oil, linseed oil, safflower oil, olive oil, peanut oil, coconut oil, palm kernel oil, castor oil, lemon oil is a mixture of the; esters of vegetable oils, esters, including debutylation, dibutyl phthalate, butylbenzyl, benzylacrylamide, tricresylphosphate, trioctylphosphine and mixtures thereof; linear or branched hydrocarbons, including linear or branched hydrocarbons having a boiling point above about 80°C; partially hydrogenated terphenyls, diallylphthalate, alkylbiphenyls, including monoisopropylamine, alkilirovanny naphthalene, including depopulation, petroleum ethers, including kerosene, mineral oil and mixtures thereof; aromatic solvents including benzene, toluene, and mixtures thereof; silicone oils; and mixtures thereof.

In one or more aspects of the method, the pH of the first and second solutions can be controlled so that the pH of the specified first and second solutions ranged from about 3.0 to 7.0.

In one or more aspects of the method, at the stage f) from about 0% to about 10%, from about 1% to about 5% or even from about 2% to about 4%, calculated on the total weight of the second composition, the salt containing the anion and the cation, where the specified anion selected from the group consisting of chloride, sulfate, phosphate, nitrate, polyphosphate, citrate, maleate, fumarata and mixtures thereof; and the specified cation selected from the group consisting of an element of group IA of the Periodic system, the elements of group IIA Of the periodic system, cat whom she ammonium and mixtures thereof, preferably sodium sulfate, may be combined with the specified second composition.

In one or more aspects of the method can be combined with any of the above parameters treatment.

Suitable materials amendment that can be added to properly suspended delivering particles containing have beneficial effects agent include polysaccharides, for example, Gellan resin, starch, waxy corn, dent corn, octenylsuccinate starches, derivateservlet starches, such as gidroksietilirovanny or hydroxypropylamino starches, carrageenan, guar gum, pectin, xanthan gum and mixtures thereof; modified cellulose, such as hydrolyzed cellulose acetate, hydroxypropylcellulose, methylcellulose and mixtures thereof; modified proteins, such as gelatin; and hydrogenated dehydrogenation polyalkene and mixtures thereof; inorganic salts, such as magnesium chloride, calcium chloride, calcium formate, magnesium formate, aluminum chloride, potassium permanganate, Leonidova clay, bentonite clay, and mixtures thereof; polysaccharides in combination with inorganic salts; and stereoselectivity polymeric materials, for example, polyetheramines, alkyltrimethylammonium chlorides, divinecaroline is lore; the imidazoles; non-ionic polymers with a pKa less than 6,0, for example, polyethylenimine, polietilyenoksida; polyurethanes. Such materials can be obtained from firms WED Kelco Corp.(San Diego, California, USA); Degussa AG (Dusseldorf, Germany); BASF AG (Ludwigshafen, Germany); Rhodia Corp.(Cranbury, New Jersey, USA); Baker Hughes Corp.(Houston, Texas, USA); Hercules Corp.(Wilmington, Delaware, USA); Agrium Inc. (Calgary, Alberta, Canada), ISP (New Jersey, USA).

Suitable materials antiglomerular agent include divalent salts such as magnesium salts, for example, magnesium chloride, magnesium acetate, magnesium phosphate, magnesium formate, bored magnesium, magnesium titanate, magnesium sulfate heptahydrate; calcium salts, e.g. calcium chloride, calcium formate, calcium acetate, calcium bromide; trivalent salts such as aluminum salts, for example, aluminum sulfate, aluminum phosphate, a hydrate of aluminum chloride, and polymers capable of suspending anionic particles, such as suspension polymers, for example, polyethylenimine, alkoxysilane polyethylenimine, polyquaternium-6, polyquaternium-7.

In one aspect of the invention is made to deliver the particles containing which have a beneficial effect agent, and then cause them a coating of material to reduce the rate of release of particles which have a beneficial effect of the agent when the particles are exposed to the environment containing, for example, surface-Akti the substances, the polymers and solvents. Non-limiting examples of coating materials that can serve as barrier materials include materials selected from the group consisting of pyrrolidone polymers, such as polyvinylpyrrolidone homopolymer and its copolymers with styrene, vinyl acetate, imidazoles, monomers containing primary and secondary amines, polyethylenimine, including the ethoxylated polyethylenimine, methyl acrylate, polyvinylacetal; maleic anhydride; homopolymer polyvinyl alcohol and its copolymers with vinyl acetate, 2-acrylamide-2-methylpropanesulfonate, monomers containing primary and secondary amines, methyl acrylate; polyacrylamide; polyacrylic acids; polyethylenimine, of ethoxylated polyethylenimine; microcrystalline waxes; paraffin waxes; modified polysaccharides, such as starch, waxy maize and subatomnoy corn, octenylsuccinate starches, derivatizing starches, such as gidroksietilirovanny or hydroxypropylamino starches, carrageenan, guar gum, pectin, xanthan gum; modified cellulose, such as hydrolyzed acetylcellulose, hydroxypropylcellulose, methylcellulose and the like; modified proteins, such as gelatin; hydrogenated and n is hydrogenated polyalkenes; fatty acids; hardened shells, such as urea, crosslinked with formaldehyde, gelatin-polyphosphate, melamine-formaldehyde, polyvinyl alcohol, crosslinked with sodium tetraborate or glutaraldehyde; latexes of styrene-butadiene rubber, ethyl cellulose, inorganic materials such as clays, including silicates, magnesium aluminum silicates; silicates of sodium and the like; and mixtures thereof. Such materials can be obtained from firms WED Kelco Corp.(San Diego, California, USA); Degussa AG (Dusseldorf, Germany); BASF AG (Ludwigshafen, Germany); Rhodia Corp.(Cranbury, New Jersey, USA); Baker Hughes Corp.(Houston, Texas, USA); Hercules Corp.(Wilmington, Delaware, USA); Agrium Inc. (Calgary, Alberta, Canada), ISP (New Jersey USA). In one aspect, for example, if the particle is used in the composition for conditioning fabrics, the coating material comprises sodium silicate. Without limitation by theory, it is believed that the solubility of sodium silicate at high pH and low solubility at low pH makes it an ideal material for use on the particles, which can be used in the compositions produced at pH below 7, but used in an environment with a pH above or equal to 7. However, the aspect of the coating of the present invention is not limited to delivering particles of the present invention, containing which have a beneficial effect, the agent as coatings and coating processes disclosed here, can be useful for delivering any particles, the content is asih agent, providing a beneficial effect.

In one aspect of delivering particles containing exerting a beneficial effect of the agent can be combined with a formaldehyde scavenger. In one aspect of delivering such particles containing which have a beneficial effect, the agent may constitute delivering particles containing exerting a beneficial effect of the agent according to the present invention. Suitable formaldehyde scavengers include materials selected from the group consisting of sodium bisulfite, melamine, urea, etelemetry, cysteine, group probably facilitates lysine, glycine, serine, carnosine, histidine, glutathione, 3,4-diaminobenzoic acid, allantoin, glicorisa (glycouril), Anthranilic acid, methylanthranilate, methyl-4-aminobenzoate, ethylacetoacetate, acetoacetamide, malonamide, ascorbic acid, dimer of 1,3-dihydroxyacetone, biureta, oksamida, benzoguanamine, pyroglutamic acid, pyragollole, Mergellina, Etisalat, propylgallate, triethanolamine, succinamide, thiabendazole, benzotriazole, triazole indoline, sulfanilic acid, oksamida, sorbitol, glucose, cellulose, poly(vinyl alcohol), partially hydrolyzed poly(vinylformamide), poly(vinylamine), poly(etilenimina), poly(oxyalkylene), poly(vinyl alcohol)-co-poly(vinylamine is), poly(4-aminostyrene), poly(1-lysine), chitosan, hexanediol, Ethylenediamine-N,N'-besteducated, N-(2-ethylhexyl)acetoacetamide, 2-benzoylacetonitrile, N-(3-phenylpropyl)acetoacetamide, filiale (filial), gelinas (helional), melons (melonal), triples (triplal), 5,5-dimethyl-1,3-cyclohexandione, 2,4-dimethyl-3-cyclohexenecarboxaldehyde, 2,2-dimethyl-1,3-dioxane-4,6-dione, 2-pentanone, dibutylamine, Triethylenetetramine, ammonium hydroxide, benzylamine, hydroxycitronellal, cyclohexanone, 2-butanone, pentanedione, dehydracetic acid or mixtures thereof. Such formaldehyde scavengers may be obtained from Sigma/Aldrich/Fluka (St.Louis, Missouri, USA) or PolySciences, Inc. (Warrington, Pennsylvania, USA).

Such formaldehyde scavengers are typically combined with a suspension containing the specified delivering particles containing which have a beneficial effect agent, in an amount which shall be calculated on the total weight of the suspension, from about 2% wt. to about 18 wt.%, from about 3.5% wt. to about 14 wt.%. or even from about 5% wt. to about 13 wt.%.

In one aspect, such formaldehyde scavengers may be combined with the product, delivering containing particles containing okazyvayuschie favorable impact of the agent, and these sinks combine with the specified product in the amount which shall be calculated on the total weight of the product, elprimero of 0.005% to about 0.8%, alternatively, from about 0.03% to about 0.5%, alternatively, from about 0,065% to about 0.25 per cent, from the composition of the product.

In another aspect, such formaldehyde scavengers may be combined with a suspension containing the specified delivering particles containing which have a beneficial effect agent, in an amount which shall be calculated on the total weight of the suspension, from about 2% wt. to about 14 wt.%. from about 3.5% wt. to about 14 wt.%, or even from about 5% wt. to about 14 wt.%, and this suspension can be added to the matrix product, which are identical or different absorber may be added in an amount which shall be calculated on the total weight of the product, from roughly 0.005% to about 0.5%, alternatively from about 0.01% to about 0,25%, alternatively, from about 0.05% to approximately 0.15%of the composition of the product.

In one aspect, one or more of the above-mentioned formaldehyde scavengers may be combined with the liquid product to improve properties of fabrics containing delivers particles containing which have a beneficial effect agent, in an amount which shall be calculated on the total weight of the liquid product to improve properties of tissues, 0.005% to about 0.8%, alternatively from about 0.03% to about 0.4%, alternatively from about 0.06% to about 0.25 per cent, from the composition of the product.

p> In one aspect, such formaldehyde scavengers may be combined with a consumer product, for example, a liquid detergent for washing, delivering containing particles containing which have a beneficial effect agent, and these absorbers are selected from the group consisting of sodium bisulfite, melamine, urea, etelemetry, cysteine, group probably facilitates lysine, glycine, serine, carnosine, histidine, glutathione, 3,4-diaminobenzoic acid, allantoin, glicorisa, Anthranilic acid, methylanthranilate, methyl-4-aminobenzoate, ethylacetoacetate, acetoacetamide, malonamide, malonic acid, dimer of 1,3-dihydroxyacetone, biureta, oksamida, benzoguanamine, pyroglutamic acid, pyragollole, Mergellina, Etisalat, propylgallate, triethanolamine, succinamide, thiabendazole, benzotriazole, triazole, indoline, sulfanilic acid, oksamida, sorbitol, glucose, cellulose, poly(vinyl alcohol), partially hydrolyzed poly(vinylformamide), poly(vinylamine), poly(etilenimina), poly(oxyalkylene), poly(windowslogo alcohol)-co-poly(vinylamine), poly(4-aminostyrene), poly(1-lysine), chitosan, hexanediol, Ethylenediamine-N,N'-besteducated, N-(2-ethylhexyl)acetoacetamide, 2-benzoylacetonitrile, N-(3-phenylpropyl)acetoacetamide, lilies, gelinas, melons, triples, 5,5-dim the Teal-1,3-cyclohexandione, 2,4-dimethyl-3-cyclohexenecarboxaldehyde, 2,2-dimethyl-1,3-dioxane-4,6-dione, 2-pentanone, dibutylamine, Triethylenetetramine, ammonium hydroxide, benzylamine, hydroxycitronellal, cyclohexanone, 2-butanone, pentanedione, dehydracetic acid and mixtures thereof, and unite with the specified liquid detergent for washing in the amount which shall be calculated on the total weight of the liquid detergent for washing, from about 0,003% wt. to about 0.20% of dry wt., from about 0.03% of wt. to about 0.20% of wt. or even from about 0.06% of wt. to about 0.14% of wt.

In one aspect, such formaldehyde scavengers may be combined with means for conditioning the hair, delivering containing particles containing which have a beneficial effect agent, in an amount which shall be calculated on the total weight of the means for conditioning hair from about 0,003% wt. until approximately between 0.30 wt.%, from about 0.03% of wt. to about 0.20% of wt. or even from about 0.06% of wt. to about 0,14% wt., with the specified choice of sinks are identical to the list of sinks in the previous paragraph relating to liquid cleaning means for washing.

Suitable equipment for use in the disclosed here, the methods may include reactors continuous action in the tank with stirring, homogenizing, turbine mixers, recirculation on the wasps, paddle mixers, shear mixers steps lemasney blades, ribbon mixers, vertical granulators and drum mixers, configurations, both periodic and, in case of their availability, continuous operation, spray dryers and extruders. Such equipment can be purchased from companies Lodige GmbH (Paderbom, Germany), Littleford Day, Inc. (Florence, Kentucky, USA), Forberg AS (Larvik, Norway), Glatt Ingenieurtechnik GmbH (Weimar, Germany), Niro (Soeborg, Denmark), Hosokawa Bepex Corp.(Minneapolis, Minnesota, USA), Arde Barinco (New Jersey, USA).

Compositions comprising delivering particles containing the agent, which have a beneficial effect

Proposed by the applicants compositions include any embodiments of the particles disclosed in this application, including any options for implementation, provide a method of manufacturing a delivering agent particles, which have a beneficial effect described in this application. In one aspect the composition is a consumer product. Although the exact content of the used particles depends on the type and destination of the composition, the composition may contain from about 0.01 to about 10, from about 0.1 to about 10, or even from about 0.2 to about 5% wt. these particles are calculated on the total weight of the composition. In one aspect, the disclosed product containing from about 0,001% to about 25%, from the example is about 0,001% to about 10%, or from about 0.01% to about 3%, in terms of the total weight of the consumer product, the above delivering agent particles, which have a beneficial effect.

In one aspect of the disclosed composition cleaners containing from about 0,005% to about 10%, from about 0.01% to about 3% or from about 0.1% to about 1%, calculated on the total weight of the detergent composition, the aforementioned delivering agent particles, which have a beneficial effect.

In one aspect of the disclosed composition to care for fabrics, containing from about 0,005% to about 10%, from about 0.01% to about 3% or from about 0.1% to about 1%, calculated on the total weight of the composition for the care of fabrics, containing the aforementioned delivering agent particles, which have a beneficial effect.

In one aspect, if the above-mentioned composition of the particles used in the consumer product, such as a liquid consumer product, the composition of the particles can have a value of deposits equal to at least 10%, 20%, 30%, 40%, 50%, 60%, 70%, 80%, 90% or even 100%.

In one aspect, if the above-mentioned composition of the particles used in the consumer product, such as a liquid consumer product, the composition of the particles may have a degree of selection encapsulated provide a beneficial effect of the agent from the microcapsules of these particles in the specified needs of the research product is less than 50%, 40%, 30%, 20%, 10% or even 0%.

In one aspect, the detergent composition may contain from about 0.1 to about 1% wt. such particles, calculated on the total weight of the detergent composition containing such particles. In one aspect, the composition for treatment of tissue may contain, in terms of the total weight of the composition for treatment of fabrics, from about 0.01 to about 10% of such particles.

Aspects of the invention include the use of particles according to the present invention in detergents for washing (for example, TIDE™), tools for cleaning hard surfaces (for example, MR CLEAN™), liquid detergents for dishwashing machines (for example, CASCADE™), liquid agents for dish washing (for example, DAWN™) and detergent for floors (e.g., SWIFFER™). Non-limiting examples of formulations of detergents may include materials described in U.S. patents№4515705; 4537706; 4537707; 4550862; 4561998; 4597898; 4968451; 5565145; 5929022; 6294514 and 6376445. The detergent compositions disclosed here, is typically composed so that, when carrying out cleaning operations using water solutions, water to the washing solution will have a pH from about 6.5 to about 12 or from about 7.5 to 10.5. Liquid compositions of the products for washing dishes typically have a pH of from about 6.8 to about 9.0 in. Cleaning products are typically so that they had a pH of from about 7 to primer is 12. Techniques for controlling pH at recommended usage levels include the use of buffers, alkalis, acids, etc. and a well-known qualified personnel.

Compositions for textile treatment disclosed here, typically contain auxiliary materials for the improvement of consumer properties, such as active substances for bating tissues ("FSA"). Suitable active substances for bating tissues include, without limitation, the materials selected from the group consisting of stereoselectivity compounds (quats), amines, esters of fatty acids, esters of sucrose, silicones, dispersible polyolefins, clays, polysaccharides, fatty oils, polymer latexes and mixtures thereof.

Auxiliary materials for the improvement of consumer properties

Although it is not essential for the purposes of the present invention, non-limiting list of supporting materials, described below, is suitable for use in the compositions of the present invention and may be desirably incorporated in certain embodiments of the invention, for example, to improve or enhance performance, for treatment of the purified material or to modify the aesthetic characteristics of the compositions, as in the case of perfumes, pigments, dyes, etc. Assumes that such auxiliary materials and is used in addition to the components entered using the proposed applicants delivering particles, and FSA. The exact nature of these additional components, and levels of their inclusion will depend on the physical form of the composition and nature of the operations for which they should be used. Suitable support materials include, without limitation, polymers, for example cationic polymers, surfactants, components that enhance detergency, chelating agents, agents inhibiting the transfer of dyes, dispersants, enzymes, and enzyme stabilizers, catalytic materials, bleach activators, polymeric dispersing agents, agents remove dirt/prevents re-deposition, optical brighteners, defoamers, dyes, additional flavorings and delivery system of flavors, agents electification patterns, fabrics softeners, carriers, girotropnye substances, processing AIDS and/or pigments. In addition to the following description suitable examples of such other auxiliary materials and their applications are shown in U.S. patent No. 5576282, 6306812 B1 and 6326348 B1, which are incorporated here as reference.

As mentioned, the auxiliary ingredients are not essential for the proposed applicants compositions for cleaning and care of fabrics. So the m way certain embodiments of the proposed applicants compositions do not contain one or more of the following supporting materials: bleach activators, surfactants, components that enhance detergency, chelating agents, agents inhibiting the transfer of dyes, dispersants, enzymes, and enzyme stabilizers, catalytic metal complexes, polymeric dispersing agents, agents remove dirt/prevents re-deposition, optical brighteners, defoamers, dyes, additional flavorings and delivery systems flavorings, agents electification patterns, fabrics softeners, carriers, hydrotropic substances, additives and/or pigments. However, in the presence of one or more auxiliary materials may be present, such one or more additional materials, as described below.

Surfactants. The compositions in accordance with the present invention may contain a surfactant or surfactant, where the surfactant may be selected from nonionic and/or anionic and/or cationic surfactants and/or ampholytic and/or zwitterionic, and/or polupryamykh non-ionic on Ernesto-active substances. Surfactant is typically present in an amount of from about 0.1%, from about 1% or even from about 5% wt. compositions of detergents to about 99.9 percent, up to about 80%to about 35%, or even up to about 30 wt.%, from the compositions of detergents.

Components that enhance detergency. The compositions of the present invention may contain one or more components that enhance detergency, or systems of components that enhance detergency. In the present compositions will typically contain at least about 1% of a component that enhance detergency, or from about 5% or 10% to about 80%, 50% or even 30% wt. the specified component, enhancing the cleaning action. Components that enhance detergency, include, without limitation, polyphosphate salts of alkali metals, ammonium and alkanolamine, silicates of alkali metals, carbonates of alkaline earth and alkali metal aluminosilicate components that enhance detergency, polycarboxylate connection epigallocatechingallate, copolymers of maleic anhydride with ethylene or vinylmation ether, 1,3,5-trihydroxybenzene-2,4,6-trisulfonic acid and carboxymethylcysteine acid, various salts of alkali metals, ammonium and substituted ammonium polixeni acids, such as Ethylenediamine is araucana acid, nitrilotriacetic acid, and polycarboxylate, such as malletova acid, succinic acid, accidentally acid, primulina acid, benzene-1,3,5-tricarboxylic acid, carboxymethylcysteine acid and its soluble salts.

Chelating agents. The compositions of the present invention can also optionally contain one or more chelating agents, copper, iron and/or manganese. In the case of chelating agents will generally comprise from about 0.1% wt. compositions of the present invention up to about 15% or even from about 3.0% to about 15% wt. compositions of the present invention.

Agents that inhibit the transfer of dyes. The compositions of the present invention may also contain one or more agents, inhibiting the transfer of dyes. Suitable polymeric agents, inhibiting the transfer of dyes include, without limitation, polyvinylpyrrolidone polymers, polyamine N-oxide polymers, copolymers of N-vinylpyrrolidone and N-vinylimidazole, polivinilatsetatny and polyvinylimidazole or mixtures thereof. In the case of their presence in the compositions according to the present invention, agents that inhibit the transfer of dyes are used in amounts of from about 0,0001%, from about 0.01 percent, from approximately 0.05% wt. compositions of detergents to about 10%, about 2%, or even about 1% wt. compositions cleaners./p>

Dispersants. The compositions of the present invention can also contain dispersants. Suitable water-soluble organic materials are Homo - or copolymer acids or their salts in which the polycarboxylic acid may contain at least two carboxyl radicals separated by not more than two carbon atoms.

The enzymes. The compositions can contain one or more with action detergent enzymes which provide cleaning action and/or have a beneficial effect when caring for fabrics. Examples of suitable enzymes include, without limitation, hemicellulase, peroxidase, protease, cellulase, xylanase, lipase, phospholipase, esterase, cutinase, pectinase, keratinase, reductase, oxidase, peroxidase, lipoxygenase, ligninase, pullulanase, tannaz, pentosanase, Malagasy, β-glucanase, arabinosidases, hyaluronidase, chondroitinase, laccase, and amylases, or mixtures thereof. A typical combination is a cocktail generally applicable enzymes like protease, lipase, cutinase and/or cellulase in conjunction with amylase.

Stabilizers enzymes. Enzymes for use in the compositions, for example, detergents, can be stabilized in various ways. The enzymes used according to the present invention can be stabilized by the presence of water is soluble sources of calcium ions and/or magnesium in the finished compositions, that provide such ions to the enzymes.

The catalytic metal complexes. Proposed by the applicants, the compositions may include catalytic metal complexes. One type of metal-containing bleaching catalyst system is a catalyst containing a transition metal cation, with some whitening catalytic activity, such as the cations of copper, iron, titanium, ruthenium, tungsten, molybdenum or manganese, an auxiliary metal cation having little or not having the whitening catalytic activity, such as the cations of zinc or aluminum, and sequestrate having defined stability constants with respect to the catalytic and auxiliary metal cations, particularly ethylenediaminetetraacetic acid, ethylenediaminetetra(methylenephosphonate acid) and their soluble salts. Such catalysts are disclosed in U.S. patent 4430243.

Optionally, the compositions of the present invention can kataliziruetsa by the use of manganese compounds. Such compounds and levels of use are well known in the art and include, for example, catalysts based on manganese disclosed in U.S. patent 5576282.

Cobalt catalysts whitening suitable for use in the present invention are Izv the STN and described, for example, in U.S. patents 5597936 and 5595967. Such cobalt catalysts can easily be obtained by known methods, such as described, for example, in U.S. patents 5597936 and 5595967.

The compositions of the present invention can also fit to include a complex of the transition metal macrocyclic rigid ligand, abbreviated label "MRL". In practice, and without limitation, the compositions and cleaning methods of the present invention can provide at least about one part per hundred million parts which have a beneficial effect agent, MRL-materials in an aqueous detergent solution and can provide from about 0,005 ppm to about 25 ppm, from approximately 0.05 ppm to about 10 ppm, or even from about 0.1 ppm to about 5 ppm MRL in the washing solution.

Preferred transition metals in the catalyst whitening with the transition metal of the present invention include manganese, iron and chromium. Preferred MRL of the present invention are ligands highly rigid type with a cross-bridges, such as 5,12-diethyl-1,5,8,12-tetraazabicyclo[6.6.2]hexadecane.

Suitable MRL of transition metals can be easily obtained by known methods, such as described, for example, in WO 00/32601 and U.S. patent 6225464.

Methods of making compositions

The compositions according to the present izopet the tion may be made in any suitable shape and made way, the developer formulation, non-limiting examples of which are described in the documents U.S. 5879584; USA 5691297; USA 5574005; USA 5569645; USA 5565422; USA 5516448; USA 5489392; USA 5486303, which are all included here as a reference.

Method of use

Compositions comprising delivering particles which have a beneficial effect of an agent disclosed here can be used for cleaning or processing a certain area, including the surface or fabric. Typically, at least part of the site is put into contact with the embodiment proposed by the applicants of the composition, diluted or undiluted in a liquid, for example, the washing solution, and then the plot can be optionally subjected to washing and/or rinsing. In one aspect of the plot is optionally subjected to washing and/or rinsing, the introduction into contact with particles in accordance with the present invention or a composition containing the above particles, and then, optionally, washing and/or rinsing. For the purposes of the present invention washable includes, without limitation, cleaning brush and mechanical stirring. The fabric may represent practically any fabric suitable for washing or processing under normal conditions of use by the consumer. The solutions, which can contain the disclosed compositions can have a pH from about 3 to about 11.5. Such is ostavi typically used at concentrations in the solution is from about 500 ppm to about 15000 ppm. In cases where solvent cleaning solution is water, the water temperature typically ranges from about 5°to about 90°C and when the plot is a fabric, the ratio of water:fabric, typically, ranges from about 1:1 to about 30:1.

TESTING METHODS

Assume that the test methods disclosed in Methods of testing this application should be used to determine the appropriate values of the parameters of the applicants invention, which is described and claimed here.

(1) tensile strength

a) Put 1 gram of particles in 1 liter of distilled deionized (DI) water.

b) Leave particles in DI water for 10 minutes and then separated from the particles by filtration through a syringe filter 60 ml nitrocellulose filter of 1.2 μm (Millipore, diameter 25 mm).

c) Determine the breaking force for 50 individual particles. Destructive force of a particle is determined using the procedures Zhang, Z.; Sun, G; "Mechanical Properties of Melamine-Formaldehyde Microcapsules", J. Microencapsulation, vol.18, no. 5, pages 593-602, 2001. Then calculate the tensile strength of each particle by dividing the breaking force (in Newtons) on the cross-sectional area of the corresponding spherical particles (πr2where r denotes the radius of the particles prior to compression), and the cross-sectional area is determined by the SL is blowing follows: measure the size of each individual particle using the experimental device and method Zhang, Z.; Sun, G; " Mechanical Properties of Melamine-Formaldehyde Microcapsules", J. Microencapsulation, vol.18, no. 5, pages 593-602, 2001.

d) Using 50 independent measurements in stage (C) above and calculate the percentage of particles having a tensile strength in the claimed range of values of tensile strength.

(2) ClogP

The "calculated logP" (ClogP) is determined by the method of fragments of Hansch and Leo (cf., A. Leo, in Comprehensive Medicinal Chemistry, Vol.4, .Hansch, P.O.Sammens, J.B.Taylor and C.A.Ramsden, Eds. P.295, Pergamon Press, 1990, incorporated here by reference). The ClogP values can be calculated using the "CLOGP", available from the company Daylight Chemical Information Systems Inc. (Irvine, California, USA).

(3) boiling Point

The boiling point is measured in accordance with ASTM method D2887-04a, "Standard method of test for determining allocation limits boiling petroleum distillates by gas chromatography", ASTM International.

(4) the detection Limit of smell (ORT)

The limit of detection of the odor is determined using the Protocol described in U.S. patent 6869923 B1, column 3, line 39 to column 4, line 15.

(5) particle Size

a) Put 1 gram of particles in 1 liter of distilled deionized (DI) water.

b) Leave particles in DI water for 10 minutes and then emit particles by filtration through a syringe filter 60 ml nitrocellulose filter of 1.2 μm (Millipore, diameter 25 mm).

c) Determine the dimensions for 50 individual particles used with the eating of the experimental device and method Zhang, Z.; Sun, G; "Mechanical Properties of Melamine-Formaldehyde Microcapsules", J. Microencapsulation, vol 18, no. 5, pages 593-602, 2001.

d) Using 50 independent measurements from step (C) above and calculate the percentage of particles having a size in the claimed range of values.

(6) the Thickness of the particles

All references to firmoo Leica Microsystems belong to the company, the headquarters of which is located at:

Leica Microsystems GmbH

Emst-Leitz-Strasse 17-37

35578 Wetzlar

All references to the Drummond company belong to the company located at:

Drummond Scientific Company

500 Parkway, Box 700

Broomall, PA 19008

All references to the company Hitachi belong to the company headquarters, located at:

Hitachi High Technologies

24-14, Nishi-Shimbashi 1-chome, Minato-ku,

Tokyo 105-8717 Japan

All references to the company Gatan belong to the company headquarters, located at:

Gatan, Inc.

5933 Coronado Lane

Pleasanton, CA 94588

All references to the company Quartz relate to the company's office located at:

Quartz Imaging Corporation

Technology Enterprise Facility III

6190 Agronomy Rd., Suite 406

Vancouver, B.C. Canada V6T 1Z3

Materials:

Methylcyclohexane - Alfa Aesar, catalog number A or equivalent

Capillary pipettes - Drummond, catalog number 5-000-1005 or equivalent

A flat sample holder Leica Microsystems P/N 706897 or equivalent

Copper washers - Leica Microsystems P/N 706867 or equivalent

Flat boat for sample - Leica Microsystems P/N 706839 or EC is Valentia

Boot device for a flat sample holder Leica Microsystems P/N 706832 or equivalent

Torque wrench - Leica Microsystems P/N 870071 or equivalent

Hex head socket wrench, 2 mm Leica Microsystems P/N 870072 or equivalent

Tweezers - Leica Microsystems P/N 840105 or equivalent

Chuck company Gatan - Gatan P/N PEP5099

Tablet sample holder of the company Gatan - Gatan P/N PEP1395

Tools:

Scanning electron microscope (Hitachi Model S-5200 SEM/STEM or equivalent

Freezer high pressure Leica Microsystems Model 706802 EAT Pact or equivalent

Device for criteriathat - Gatan Model CT3500 or equivalent

System for criteriathat - Gatan Model CT2500 or equivalent

The temperature controller Gatan ITC - Gatan Model ITC502 or equivalent

Software for image analysis - Quartz PCI Version 5 or equivalent

Sample: Get a sample of microcapsules in accordance with procedure 1 above, entitled "tensile strength". You need 50 samples.

The test procedure

1) Include a high-pressure freezer Leica Microsystems (Leica Microsystems Model Number 706802).

2) Fill the container to methylcyclohexane freezer high pressure methylcyclohexanol (Alfa Aesar, Cat. #A16057 or equivalent).

3) Fill the liquid nitrogen Dewar freezer high pressure.

4) Filled with liquid nitrogen is Anna freezer high pressure.

5) When the tool is ready to use, on the front panel display freezer high pressure appears to Load the Sample.

6) turn the meter on a Hitachi Model S-5200 SEM/STEM and set accelerating voltage of 3.0 kV and emission current of 20 µa.

7) Fill the liquid nitrogen Dewar of anticontamination (anti-contaminator), located on the bottom right-hand column of the microscope (Hitachi Model S-5200 SEM/STEM.

8) Fill the liquid nitrogen Dewar system criteriathat Gatan Alto 2500 (Gatan Model CT2500). Pour liquid nitrogen until such time as the Dewar will not remain full. The device is ready for use when the temperature of the preparatory chamber reaches values below -190°C.

9) Put the copper washer (Leica Microsystems P/N 706867) flat on top of the sample holder so that the wiper opening coincided with the recess in the flat sample holder.

10) Take a glass capillary pipette (Drummond P/N 5-000-1005 or similar) and insert the provided wire the piston in one end of the pipette.

11) Lower the pipette into the dispersion of microcapsules and partially pull the plunger to gain some microlitres dispersion in the eyedropper.

12) Bring the tip of the pipette to the recess in the flat sample holder and push the piston in the pipette to squeeze a small amount of liquid, so that it slightly protrudes from the recess.

13) of Stable the t 2 mm hex nozzle (Leica Microsystems P/N 870072) torque wrench (Leica Microsystems P/N 870071).

14) using a torque wrench with a nozzle loosen the Phillips retaining screw flat pumps for sample (Leica Microsystems P/N 706839).

15) Place a flat sample holder and copper washer flat in the boat for a sample.

16) Use a torque wrench with a 2 mm hex cap for tightening the Phillips retaining screw flat boats for the sample on the sample to two clicks a torque wrench.

17) Attach the boot device for a flat sample holder (Leica Microsystems P/N 706832) to the flat boat for sample by screwing it to the protruding threaded sections crosswise locking screw.

18) Put the boot device for a flat sample holder with a flat boat for sample on it Pact of high-pressure freezer (Leica Microsystems P/N 706802) and stick it in the freezer high pressure.

19) Freeze the sample by using a high-pressure freezer.

20) is Transferred flat boat to sample at the discharge station and turn off the boot device for a flat sample holder, making sure that it remained immersed in a bath of liquid nitrogen.

21) using a torque wrench loosen Phillips retaining screw.

22) With tweezers, the ends of which are cooled in liquid nitrogen until then, until procratination liquid nitrogen, take out a flat sample holder from a flat pumps for sample and place it in a small container in a bath of liquid nitrogen.

23) Put the device to criteriathat Gatan CT3500 (Gatan Model Number CT3500) in the workstation for sample Gatan.

24) is Filled with liquid nitrogen Dewar device for criteriathat Gatan CT3500 and fill the Dewar workstation for sample Gatan, adding liquid nitrogen as necessary as long as you do not stop the rapid boiling of liquid nitrogen.

25) Carry a flat sample holder in a workstation for sample Gatan, keeping it in a container with liquid nitrogen.

26) using forceps cooled in liquid nitrogen until then, until it stops boiling liquid nitrogen, placed flat sample holder in the Chuck of the company Gatan (Gatan P/N PEP5099) and firmly pressed it down.

27) Put precast block from the stage 26 in tablet sample holder of the company Gatan (Gatan P/N PEP1395) and firmly pressed it down.

28) Push device for criteriathat Gatan ago workstation for sample Gatan.

29) using the supplied company Gatan 5 mm friction tool the shape Tool) spin tablet sample holder of the company Gatan in device for criteriathat Gatan.

30) Remove the device criteriathat Gatan from the workstation for sample Gatan and insert it into the system for cripe is ECOSOC Gatan Alto 2500.

31) Connect the temperature controller Gatan ITC (Gatan Model Number ITC502) to the device for criteriathat Gatan by attaching the outlet to measure the temperature from the controller Gatan ITC to the connector on top of the device for criteriathat Gatan.

32) control Gatan ITC raise the sample temperature to -120°C.

33) using the splitting knife tear copper washer, splitting the sample.

34) Reduce the sample temperature to values below -160°C.

35) When the voltage of 6 kV and the flow of gas specified to ensure current spray 10 mA, click spraying and when the current value reaches the value of 10 mA, include sputtering device for 60-90 seconds for application to the sample coating of gold/palladium.

36) Close protivomoroznyh screen device for criteriathat Gatan ST and transfer the sample in a Hitachi S-5200 SEM/STEM.

37) Wait until stabilized temperature device for criteriathat Gatan ST, typically between -170°C and -172°C.

38) Open protivomoroznyh screen device for criteriathat Gatan ST, turning counterclockwise control knob protivosudorozhnogo screen.

39) Moving the sample from side to side using the trackball table are divided microcapsule and set the amount of increase from 50000 to 150000×.

40) Govern fo the condition and management system stigmatura to obtain the best image.

41) Register the image of the cross section of the wall of the capsule.

Calculations

1) Select the line tool in the program Quartz PCI.

2) Bring the cursor to the edge of the wall of the microcapsules.

3) Press and hold the left mouse button, moving the mouse pointer to the opposite edge of the wall of the capsule, supporting the line perpendicular to the wall of the capsule wall thickness measurements.

4) Use 50 independent measurements (1 measurement for each capsule) to calculate the percentage of particles having a wall thickness in the claimed range of values.

(7) the Release agent, which have a beneficial effect

a) Receive 2 sample over one gram of the composition of the particles of the agent, which have a beneficial effect.

b) Add 1 gram (Sample 1) composition particles to 99 grams of a matrix product, which will use this particle, and for the second sample immediately move to the Stage d below,

c) carry out the aging matrix product containing particles (Sample 1) from stage a) above within 2 weeks at 35°C in a sealed glass jar.

d) Distinguish the particles of the composition of the particles from the matrix of the product from step C) (Sample 1 in the matrix product) and from the composition of the particles (Sample 2) above by filtering.

e) Process each sample particles from step (d) above solvent, which extracts all of anywaysi beneficial effect agent, of each particle samples,

f) Introducing a solvent containing which have a beneficial effect agent, of each sample from step (e) above, in the gas chromatograph and integrate the peak areas to determine the total number of which have a beneficial effect agent extracted from each sample,

(g) the Release of which have a beneficial effect of an agent is defined as:

The value from step (f) above for Sample 2 Is the Value from step (f) above for Sample 1.

EXAMPLES

Although there have been illustrated and described specific embodiments of the present invention, qualified specialists will know what can be done in various other changes and modifications without going beyond the nature and scope of the invention. Therefore, it is assumed that it covers in the appended claims all such changes and modifications are included in the scope of this invention.

EXAMPLE 1: Melamineformaldehyde (MF) capsule, 84% wt. core/16% wt. wall

Dissolve 25 grams of emulsifier on the basis of a copolymer of butyl acrylate-acrylic acid (Colloid C351, 25% solids, pka 4,5-4,7 (Kemira Chemicals, Inc., Kennesaw, Georgia, USA) and stirred in 200 grams of deionized water. Bring the pH of the solution to pH 4.0 with sodium hydroxide solution. To a solution of the emulsifier of primav Aut 8 grams of partially methylated methylaminophenol resin (Cymel 385, 80% dry matter (Cytec Industries, West Paterson, New Jersey, USA)). Add to the previous mixture of 200 grams of perfume oil by mechanical stirring and the temperature raised to 50°C. After stirring at high speed to obtain a stable emulsion to emulsion was added a second solution of 4 grams of salt is sodium sulfate. This second solution contains 10 grams of emulsifier is a copolymer of butyl acrylate-acrylic acid (Colloid C351, 25% solids, pka of 4.5 to 4.7, Kemira), 120 grams of distilled water, sodium hydroxide solution to establish a pH of 4.8, 25 grams of partially methylated methylaminophenol resin (Cymel 385, 80% solids, Cytec). This mixture is heated to 70°C and incubated overnight with continuous stirring to complete the process of encapsulation. Added to a suspension of 23 g acetoacetamide (Sigma-Aldrich, Saint Louis, Missouri, USA). Get the average size of the capsules is 30 μm, the results of the analysis using the device Model Accusizer 780.

EXAMPLE 2: Melamineformaldehyde capsule, 80% wt. core/20% wt. wall

Dissolve 18 g of a mixture of 50% of the emulsifier of a copolymer of butyl acrylate-acrylic acid (Colloid C351, 25% solids, pka of 4.5 to 4.7, Kemira) and 50% polyacrylic acid (35% solids, pKa of 1.5 to 2.5, Aldrich) and stirred in 200 grams of deionized water. Bring the pH of the solution to pH 3.5 with sodium hydroxide solution. PR is billaut to the solution of the emulsifier of 6.5 grams of partially methylated methylaminophenol resin (Cymel 385, 80% of dry matter, Cytec). Added to the previous mixture of 200 grams of perfume oil by mechanical stirring and the temperature was raised to 60°C. After stirring at high speed to obtain a stable emulsion to emulsion poured the second solution and 3.5 grams of salt is sodium sulfate. This second solution contains 10 grams of emulsifier is a copolymer of butyl acrylate-acrylic acid (Colloid C351, 25% solids, pKa of 4.5 to 4.7, Kemira), 120 grams of distilled water, sodium hydroxide solution to bring the pH to 4.6, 30 grams of partially methylated methylaminophenol resin (Cymel 385, 80%, Cytec). This mixture is heated to 75°C and incubated for 6 hours with continuous stirring to complete the process of encapsulation is added to a suspension of 23 g acetoacetamide (Sigma-Aldrich, Saint Louis, Missouri, USA).

EXAMPLE 3: Capsule 80% wt. core/20% wt. melamineformaldehyde wall

Dissolve 36 g of emulsifier is a copolymer of butyl acrylate-acrylic acid (Colloid C351, 25% solids, pKa of 4.5 to 4.7, Kemira) and stirred in 200 grams of deionized water. Bring the solution pH to pH 5.0 with sodium hydroxide solution. Added to a solution of the emulsifier 12 grams of partially methylated methylaminophenol resin (Cymel 385, 80% solids, Cytec). Add to the previous mixture of 200 grams of perfume oil by mechanical stirring and the temperature is raised to 65°C. After stirring at high speed to obtain a stable emulsion is added to the emulsion of the second solution and 5 grams of salt sodium sulfate. This second solution contains 12 grams of emulsifier is a copolymer of butyl acrylate-acrylic acid (Colloid C351, 25% solids, pKa of 4.5 to 4.7, Kemira), 120 grams of distilled water, sodium hydroxide solution to bring the pH to 5, 33 grams of partially methylated methylaminophenol resin (Cymel 385, 80% solids, Cytec). This mixture is heated to 65°C and incubated overnight with continuous stirring to complete the process of encapsulation. Added to a suspension of 23 g acetoacetamide (Sigma-Aldrich, Saint Louis, Missouri, USA).

EXAMPLE 4: Capsule 80% wt. core/20% wt. melamineformaldehyde wall

Dissolve 20 grams of emulsifier is a copolymer of butyl acrylate-acrylic acid (Colloid C351, 25% solids, pKa of 4.5 to 4.7, Kemira) and stirred in 200 grams of deionized water. Bring the pH of the solution to pH 5.5 with sodium hydroxide solution. Added to a solution of the emulsifier 6 grams of partially methylated methylaminophenol resin (Cymel 385, 80% solids, Cytec). Add to the previous mixture of 200 grams of perfume oil by mechanical stirring and the temperature was raised to 55°C. After stirring at high speed to obtain a stable emulsion is added to the emulsion of the second p is the target, and 9 grams of salt sodium sulfate. This second solution contains 8 grams of polyacrylic acid (35% solids, pKa of 1.5 to 2.5, Aldrich), 120 grams of distilled water, sodium hydroxide solution to bring the pH to 4.4, 35 grams of partially methylated methylaminophenol resin (Cymel 385, 80% solids, Cytec). This mixture is heated to 80°C and incubated for 4 hours with continuous stirring to complete the process of encapsulation. Added to a suspension of 23 g acetoacetamide (Sigma-Aldrich, Saint Louis, Missouri, USA).

EXAMPLE 5: Melamineformaldehyde capsule

The composition and procedure for preparation of the capsules are the same as the composition in Example 4, except as follows: Melamineformaldehyde resin is a mixture of 80% partially methylated methylaminophenol resin and 20% of the fully methylated melamine resin.

EXAMPLE 6. Melamineformaldehyde capsule

The procedure for fabrication of the capsules is the same as in Example 4, except for the following changes in the composition of the liquid to emulsify flavoring (first solution):

MaterialAndInDEFG
The copolymer poly (acrylic acid-butyl acrylate423102026180
Polyacrylic acid021291402227
20% NaOH2369277
Melamine resin19212184717
Aromatic oil265290246224220200204
Water95104103225159189237

The procedure for fabrication of the capsules is the same as in Example 4, except for the following changes in the composition of the second solution:

MaterialAndInDEFG
The copolymer poly (acrylic acid-butyl acrylate110150033
Polyacrylic acid1112049810
20% NaOH0,40,4 0,10,30,40,40,4
Melamine resin841613262329
Water11512643147524778

Then add acetoacetamide in an amount of 5 wt.%. from the weight of the lot.

EXAMPLE 7: Melamineformaldehyde capsule

The composition and procedure of manufacturing the capsules are the same as in Example 4, with the following exception: instead of acetoacetamide added to a suspension of 0.7% ammonium hydroxide.

EXAMPLE 8: Production of microcapsules by spray drying

Mixing 1200 g of a suspension of microcapsules flavoring containing one or more microcapsules disclosed in this application, with 700 g of water for 10 minutes using a mixer IKA Eurostar with a nozzle R1382 with a speed of 180 rpm./XB. The mixture was then transferred to a feed tank for spray drying device Niro Production Minor diameter is ω 1,2 m The suspension is fed into the tower using a peristaltic pump Watson-Marlow 504U and atomized by centrifugal atomizer 100 mm diameter, rotating at a speed of 18000 rpm./min., in parallel to the air flow for drying. The suspension is dried at the inlet temperature of 200°C and the outlet temperature 95°C with the formation of finely dispersed powder. Equipment used for spray drying, can be obtained from these providers: IKA Werke GmbH & Co. KG Janke & Kunkel - Str. 10, D79219 Staufen, Germany; Niro A/S Gladsaxevej 305, P.O. Box 45, 2860 Soeborg, Denmark and Watson-Marlow Bredel Pumps Limited, Falmouth, Cornwall, TR11 4RU, England.

EXAMPLE 9

Non-limiting examples of formulations of products containing microcapsules shown in the following table.

EXAMPLE 10. Microcapsules in dry formulations Laundry detergent

Componentwt.%. on the composition of the granular detergents for washing
AndInDEFG
Dodge0,10,1 0,10,20,10,20,1
Soap0,60,60,60,60,60,60,6
Ethylenediaminetetra acid0,10,10,10,10,10,10,1
Acrylate/malaty copolymer1,51,51,51,51,51,51,5
Hydroxyethane(methylenephosphonate acid)0,40,40,40,40,40,40,4
Mono-C12-14-alkyl, dimethyl, mono-hydroxyethyl Quaternary ammonium chloride0,50,50,50,50,50,5
Linear alkylbenzene0,10,10,20,10,10,20,1
Line Las10,3the 10.1to 19.914,710,31710,5
Magnesium sulfate0,40,40,40,40,40,40,4
Sodium carbonate19,519,2the 10.118,529,9the 10.116,8
The sodium sulfate29,6 29,838,815,124,419,719,1
Sodium chloride0,10,10,10,10,10,10,1
Zeolite9,69,48,1181013,2the 17.3
Particles fotoatelier0,10,10,20,10,20,10,2
Blue and red carbonate sequins1,81,81,81,81,81,81,8
Ethoxylated alcohol AA11 11111
Tetraacetylethylenediamine, agglomerate (92% wt. active in-VA)0,90,90,90,90,90,90,9
Citric acid1,41,41,41,41,41,41,4
Agglomerates PDMS/clay (9,5% wt. active PDMS)10,510,35155,17,310,2
The polyethylene oxide0,20,20,20,20,20,20,2
Enzymes, such as protease (84 mg/g active-VA), amylase (22 mg/g active-VA) 0,20,30,20,10,20,10,2
Antifoam, agglomerate (12,4% wt. active in-VA)0,20,20,20,20,20,20,2
Percarbonate sodium (containing from 12% to 15% of the active AvOx)7,27,1a 4.9of 5.46,919,313,1
Perfume oil0,50,50,50,50,50,50,5
The particulate flavoring0,400,40,40,40,40,6
ICRI is capsules flavors* 1,32,411,31,31,30,7
Water1,41,41,41,41,41,41,4
Various0,10,10,10,10,10,10,1
Only100100100100100100100
* Microcapsules added to the suspension with 35% of the active substance. The ratio of the core/wall may vary in the range from 80/20 to 90/10, and the average particle diameter may range from 5 μm to 50 μm

EXAMPLE 11. The compositions of liquid Laundry detergent (HDLs)

Ingredient HDL1HDL2HDL3HDL4HDL5HDL6
Alkylarylsulfonate0,000,50to 12.0to 12.06,07,0
Dodecylbenzensulfonate acid8,08,01,01,02,03,0
Ethoxylated alcohol8,06,05,07,05,03,0
Citric acid5,03,03,05,02,03,0
Fatty acid3,05,05,03,06,0 5,0
Ethoxysulfuron hexamethylenediamine were, and stereoselectivity1,91,21,52,01,01,0
Diethylenetriaminepentaacetic-phosphonic acid0,30,20,20,30,10,2
Enzymes1,200,8001,200,8
Dodge (desulfuromonas fluorescent bleach (FWA) on the basis of diaminostilbene)0,140,0900,140,010,09
Cationic hydroxyethylcellulose000,1000,2000,30
Poly(acrylamide-co-diallyldimethylammonium chloride)0000,500,100
The amendment based on hydrogenated castor oil0,500,440,20,20,30,3
Boric acid2,41,51,02,41,01,5
Ethanol0,501,02,02,01,01,0
1,2-propandiol2,03,01,01,00,010,01
Glutaric aldehyde0019 ppm 013 ppm0
Diethylene glycol (DEG)1,600000
2,3-Methyl-1,3-propandiol (MP diol)1,01,00000
Monoethanolamine1,00,50000
NaOH sufficient to provide a pH of the composition:pH 8pH 8pH 8pH 8pH 8pH 8
Coolcullen sodium (NaCS)2,0000000
Silicone (PDMS) emulsion0,003/td> 0,0030,0030,0030,0030,003
Flavor0,70,50,80,80,60,6
Polyethylenimine0,010,100,000,100,200,05
Microcapsules flavors*1,005,001,002,000,100,80
WaterUp to 100%Up to 100%Up to 100%Up to 100%Up to 100%Up to 100%
* Suspension of microcapsules flavors in accordance with the description of this application

EXAMPLE 12. Urea capsule

In a mixture of 89.5 grams of water, 5 grams of urea, 0.5 grams rez is rtina and 5 grams of a copolymer of alkylacrylate-acrylic acid, brought to pH 4.0, emuleret 90 grams of perfume oil. These compounds emuleret and the resulting mixture is placed in a container placed in a water bath to room temperature, under continuous stirring, 13.5 grams of a 37% solution of formaldehyde bath and heated to 55°C and maintained at this temperature throughout the night to initiate and complete encapsulation.

EXAMPLE 13

It was determined that the microcapsules flavors in Examples 1-7, tested in accordance with test methods of the present invention have tensile strengths from about 0.2 MPa to about 10 MPa, from about 0.4 MPa to about 5 MPa, from about 0.6 MPa to about 3.5 MPa, and even from about 0.7 MPa to about 3 MPa; the release of which have a beneficial effect agent, from 0% to about 30%, from 0% to about 20% and even of 0% to about 5%; the particle size from about 1 micron to about 80 microns from about 5 microns to 60 microns, from about 10 microns to about 50 microns or even from about 15 microns to about 40 microns; and the thickness of the particles is from about 60 nm to about 250 nm, from about 80 nm to about 180 nm, or even from about 100 nm to about 160 nm.

EXAMPLE 12

0,002tr>
Examples of liquid detergentA InD
C14-C15 alkylphenolethoxylate(8)6,254,006,256,25
C12-C14 alkylphenolethoxylate(7)0,400,300,400,40
C12-C14 alkylphenolethoxylate(3)sulfate, Na-saltor 10.60of 6.78or 10.60or 10.60
Linear alkylbenzenesulfonate acid0,191,160,790,79
Citric acid3,752,403,753,75
C12-C18 fatty acid4,002,56 7,027,02
Enzymes0,600,40,600,60
Boric acid2,41,51,251,25
TRANS-sulfirovannykh hexamethylenediamine were, quatern.1,110,711,111,11
Diethylenetriaminepentaacetate acid0,170,110,170,17
Fluorescent Brightener0,090,060,140,14
Hydrogenated castor oil0,050,3000,20 0,20
Ethanol2,501,002,502,50
1,2-propandiol1,140,71,141,14
Sodium hydroxidethe 3.82,64,604,60
Monoethanolamine0,80,5
Na-coolcullen
Silicone emulsion0,00300,00300,00300,0030
Dye0,0020,0020,002
Cloud (based on stirolakrilat)
Bentonite softening clay
Acrylamide/MARTHA (from the company Nalco Chemicals, Naperville, IL)0,400,40
Mirapol 550 (from the company Rhodia Chemie, France)
Polyquaternium 10 - cationic hydroxyethylcellulose
PP-5495 (silicone from Dow Coming Corporation, Midland, MI)
Pearlescent agent *0,2
Microcapsules flavoring (in terms of perfume oil)0,80,51,00,7
Flavor0,70,551,001,00
Polyethylenimine, MW 25000
Water100100100100
* Mica-TiO2 (Prestige Silk Silver Star from the company Eckart) or BiOCl (Biron Silver CO Merck) or precede the flax crystallized
* EGDS (Tegopearl N 100 from the company Degussa, in terms of pure EGDS)
Examples of liquid detergentEFGN
C14-C15 alkylphenolethoxylate(8)6,254,006,256,25
C12-C14 alkylphenolethoxylate(7)0,400,300,40
C12-C14 alkylphenolethoxylate(3)sulfate, Na-saltor 10.60of 6.78or 10.60or 10.60
Linear alkylbenzenesulfonate acid0,791,190,790,79
Citric acid3,752,403,753,75
C12-C18 fatty acid7,024,487,027,02
Enzymes0,601,00,60
Boric acid1,251,251,251,25
TRANS-sulfonated ethoxylated hexamethylenediamine were, quatern.1,110,711,111,11
Diethylenetriaminepentaacetate acid0,170,110,170,17
Fluorescent Brightener0,140,060,14
Hydrogenated castes the world oil 0,200,3000,200,20
Ethanol2,501,002,502,50
1,2-propandiol1,140,091,141,14
Sodium hydroxide4,603,014,604,60
Monoethanolamine
Na coolcullen
Silicone emulsion0,00300,00300,00300,0030
Dye0,0020,000840,000840,00084
Cloud (based on stirolakrilat)0,1
Bentonite softening clay
Acrylamide/MARTHA (from the company Nalco Chemicals, Naperville, IL)0,40
Mirapol 550 (from the company Rhodia Chemie, France)0,400,25
Polyquaternium 10-cationic hydroxyethylcellulose0,30
PP-5495 (silicone from Dow Corning Corporation, Midland, MI) 3,0
DC 1664 (silicone from Dow Corning Corporation, Midland, MI)3,03,0
Pearlescent agent *0,2
Microcapsules flavoring (in terms of perfume oil)0,90,30,51,2
Flavor1,000,651,001,00
Polyethylenimine, MW 25000
Water100100100 100

Examples of liquid detergentIJK
C14-C15 alkylphenolethoxylate(8)4,006,1
C12-C14 alkylphenolethoxylate(7)2,00
C12-C14 alkylphenolethoxylate(3)sulfate, Na-saltof 6.78
Linear alkylbenzenesulfonate acid1,197,815,0
Citric acid2,402,62,50
C12-C18 fatty acid4,482,611,4
Enzymes0,550,07
Boric acid1,25 1,501,3
TRANS-sulfirovannykh hexamethylenediamine were, quatern.0,711,20
Diethylenetriaminepentaacetate acid0,110,200,7
Fluorescent Brightener0,090,14
Hydrogenated castor oil0,3000,450,09
Ethanol1,001,400,7
1,2-propandiol0,093,306,7
Sodium hydroxide3,013,005,5
Monoethanolamine0,50
Na coolcullen 1,6
Silicone emulsion0,00300,00300,30
Dye0,000840,020,004
Cloud (based on stirolakrilat)
Bentonite softening clay3,40
Acrylamide/MARTHA (from the company Nalco Chemicals, Naperville, IL)
Mirapol 550 (from the company Rhodia Chemie, France)
Polyquaternium 10 - cationic hydroxyethylcellulose0,18
PP-5495 (silicone from Dow Corning Corporation, Midland, MI)
DC 1664 (silicone from Dow Corning Corporation, Midland, MI)3,0
Pearlescent agent *0,2
Microcapsules flavoring (in terms of perfume oil)0,20,450,75
Flavor0,650,51,0
Polyethylenimine, MW 250000,08
Water100100100

Examples of liquid detergentLM**N
C14-C15 alkylphenolethoxylate(8)3,720,7
C12-C14 alkylphenolethoxylate(7) 16,7
C12-C14 alkylphenolethoxylate(3)sulfate, Na-salt17,85,5
Linear alkylbenzenesulfonate acid12,522,913,5
Citric acida 3.91,7
C12-C18 fatty acid11,1185,1
Enzymes31,23
Boric acid0,50,5
TRANS-sulfonated ethoxylated hexamethylenediamine were, quatern.3,251,2
PEI 600 EO201,251,2
Diethylenetriaminepentaacetate acid or HEDP 1,60,85
Fluorescent Brightener0.20,30,14
Hydrogenated castor oil0,2
1,2-propandiol4,320,311,7
Sodium hydroxide1,0a 3.9
Monoethanolamine9,86,83,1
DyePresentPresentPresent
PDMS2,15
The potassium sulfite0,2
Microcapsules flavoring (in terms of perfume oil) 1,61,51,4
Flavor1,21,61,0
Formirovaniya (form.) phenylboronic acidPresent
Water100100100
** liquid detergent with low water content in a single package/bag of polyvinyl alcohol :

The dimensions and values disclosed here should not be construed as strictly limited to the exact given numerical values. Instead, unless otherwise specified, each such dimension shall be defined as the present value and a functionally equivalent range surrounding that value. For example, the size, disclosed as "40 mm"must mean "about 40 mm".

All documents referred to in the detailed description of the invention, in relevant part, included here as a reference; a reference to any document shall be construed as an admission that it is prior art referred by the th to the present invention. To the extent that any meaning or definition of a term in this document contradicts any meaning or definition of the same term in a document incorporated by reference, the dominant should be a value or definition given to this term in this document.

Although there have been illustrated and described specific embodiments of the present invention, qualified specialists will be clear that various other changes and modifications can be made without going beyond the nature and scope of the invention. Therefore, it is assumed that it covers in the appended claims all such changes and modifications are included in the scope of this invention.

1. The method of obtaining delivering particles of flavoring, containing the core material and the shell, and this shell at least partially surrounds the specified core material, while
i. at least 75% of these delivers particles of flavoring is characterized by a tensile strength of from about 0.2 MPa to about 10 MPa, particle size of from about 1 μm to about 80 μm and the thickness of the particles is from about 60 nm to about 250 nm; and
ii. these delivers particles of flavoring characterized by the release of flavor from 0% to about 30%;
while the criminal code of the above method includes a stage, are:
a) preparing a first solution containing, calculated on the total weight of the solution from about 20% to about 90% water, the first emulsifier and the first resin, and the ratio of the specified first emulsifier and the first resin is from about 0.1:1 to about 10:1;
b) preparing a second solution containing, calculated on the total weight of the solution from about 20% to about 95% water, a second emulsifier and a second resin, and the ratio of the specified second emulsifier and the second resin is from about 0:1 to about 3:1;
c) combine the core material and said first solution with the formation of the first composition;
d) emuleret said first composition;
e) combine said first composition and said second solution with the formation of the second composition and optionally combine any processing AIDS and said second composition;
f) mixing the specified second composition for at least 15 minutes at a temperature of from about 25°to about 100°C. and optionally combine any technological additives with the specified second composition;
g) optionally combine any material absorber, amendment and/or antiaglomerate agent with a specified second composition on stage
f) or after it;
h) optionally is subjected to spray drying specified second part.

2. SPO is about according to claim 1, in which the core material of these delivers particles of the flavoring includes raw fragrant material.

3. The method according to claim 1, characterized in that the core material includes:
a) the composition of the flavoring, having a Clog p of less than 4.5;
b) a flavoring composition containing, calculated on the total weight of the flavoring composition 60% flavouring materials having a Clog P less than 4,0;
c) a flavoring composition containing, calculated on the total weight of the flavoring composition 35% flavouring materials having a Clog p of less than 3.5;
d) a flavoring composition containing, calculated on the total weight of the flavoring composition of 40% fragrance materials having a Clog P less than about 4.0; and at least 1% flavoring materials having a Clog p of less than 2.0;
e) a flavoring composition containing, calculated on the total weight of the flavoring composition of 40% fragrance materials having a Clog P less than about 4.0, and at least 15% flavoring materials having a Clog P less than 3,0;
f) a flavoring composition containing, calculated on the total weight of the flavoring composition is at least 1% butanoate of ester and at least 1% pentanoate complex ether;
g) a flavoring composition containing, calculated on the total weight of the flavoring composition of at least 2% of ester containing all the local fragment, and at least 10% of another aromatic compounds containing ester fragment;
h) a flavoring composition containing, calculated on the total weight of the flavoring composition is at least 1% of the aldehyde containing fragment with alkyl chain;
i) a flavoring composition containing, calculated on the total weight of the flavoring composition of at least 2% butanoate complex ether;
(j) a flavoring composition containing, calculated on the total weight of the flavoring composition, at least 1% pentanoate complex ether;
k) a flavoring composition containing, calculated on the total weight of the flavoring composition of at least 3% of ester containing allyl fragment, and 1% of the aldehyde containing fragment with alkyl chain;
l) a flavoring composition containing, calculated on the total weight of the flavoring composition is at least 25% aromatic compounds containing ester fragment, and 1% of the aldehyde containing fragment with alkyl chain;
m) a flavoring composition containing, calculated on the total weight of the flavoring composition of at least 2% of a material selected from Ivanov, preferably, 4-(2,6,6-trimethyl-1-cyclohexenyl)-3-butene-2-it, 4-(2,6,6-trimethyl-2-cyclohexenyl)-3-butene-2-it 3-methyl-4-(2,6,6-trimethyl-1-cyclohexen-2-yl)-3-butene-2-it, and their mixtures;
n) HDMI is a function of the flavor containing, calculated on the total weight of the flavoring composition is at least 0.1% tridec-2-isonitrile and Mandela and mixtures thereof;
a) a flavoring composition containing, calculated on the total weight of the flavoring composition of at least 2% of a material selected from 3,7-dimethyl-6-octennial, 2-cyclohexylidene-2-phenylacetonitrile and mixtures thereof;
p) a flavoring composition containing, calculated on the total weight of the flavoring composition of at least 80% of one or more aromatic compounds containing fragment selected from the group consisting of esters, aldehydes, Ivanov, NITRILES, ketones and combinations thereof;
q) a flavoring composition containing, calculated on the total weight of the flavoring composition of at least 3% of ester containing allyl fragment; a flavoring composition containing, calculated on the total weight of the flavoring composition is at least 20% of a material selected from the group consisting of: 1-methylethyl-2-methylbutanoate; ethyl-2-methylpentanoate; 1,5-dimethyl-1-ethenylene-4-enolacetate; u-COP-1-ene-8-racette; 4-(2,6,6-trimethyl-2-cyclohexenyl)-3-butene-2-it; 4-acetoxy-3-methoxy-1-propenylbenzene; 2-propylcyclohexanone; bicyclo[2.2.1]hept-5-ene-2-carboxylic acid, 3-(1-methylethyl)ethyl ether complex; bicyclo[2.2.1]heptane-2-ol, 1,7,7-trimethyl-, acetate; 1,5-dimethyl-1-Aten Lex-4-enolacetate; hexyl-2-methylpropanoate; ethyl-2-methylbutanoate; 4-undecanone; 5-heptaldehyde-2(3n)-furanone; 1,6-nonadien-3-ol, 3,7-dimethyl-; 3,7-dimethylocta-1,6-Dien-3-ol; 3-cyclohexen-1-carboxaldehyde, dimethyl-; 3,7-dimethyl-6-octennial; 4-(2,6,6-trimethyl-1-cyclohexenyl)-3-butene-2-it; tridec-2-isonitrile; essential oils of patchouli; ateltico[5.2.1.0]decane-2-carboxylate; 2,2-dimethylcyclohexanone; hexadecanoate; 7-acetyl-1,2,3,4,5,6,7,8-octahydro-1,1,6,7-tetramethylnaphthalene; arylcyclohexylamine; metalloelastase aldehyde; 1-Spiro[4,5]Dec-7-EN-7-yl-4-pentene-1-it; 7-octene-2-ol, 2-methyl-6-methylene-, dihydro; cyclohexanol, 2-(1,1-dimethylethyl)-, acetate; hexahydro-4,7-methanoindan-5(6)-improveverywhere-4,7-methanoindan-5(6)-ylpropionic; 2-methoxynaphthalene; 1-(2,6,6-trimethyl-3-cyclohexenyl)-2-butene-1-it; 1-(2,6,6-trimethyl-2-cyclohexenyl)-2-butene-1-it; 3,7-dimethyloctan-3-ol; 3-butene-2-it, 3-methyl-4-(2,6,6-trimethyl-1-cyclohexen-2-yl)-; hexanoic acid, 2-propilovogo of ester; (z)-non-6-ene-1-a; 1-delovogo aldehyde; 1-octanal; 4-t-butyl-α-methylhydrocinnamic aldehyde, alpha-mexikoring aldehyde; ethyl-2,4-hexadiene; 2-propenyl-3-cyclohexylpropionate; and mixtures thereof;
d) a flavoring composition containing, calculated on the total weight of the flavoring composition is at least 20%, 30% or even 50% of a material selected from the group consisting of: 1-IU is ileti-2-methylbutanoate; ethyl-2-methylpentanoate; 1,5-dimethyl-1-Etoiles-4-enolacetate; u-COP-1-ene-8-racette; 4-(2)6(6-trimethyl-2-cyclohexenyl)-3-butene-2-it; 4-acetoxy-3-methoxy-1-propenylbenzene; 2-propylcyclohexanone; bicyclo[2.2.1]hept-5-ene-2-carboxylic acid, 3-(1-methylethyl)ethyl ether complex; bicyclo[2.2.1]heptane-2-ol; 1,7,7-trimethyl-, acetate; 1,5-dimethyl-1-Etoiles-4-enolacetate; hexyl-2-methylpropanoate; ethyl-2-methylbutanoate, 4-undecanone; 5-heptaldehyde-2(3P)-furanone; 5-hydroxydecanoic acid; decalactone; undecalactone; 1,6-nonadien-3-ol, 3,7-dimethyl-; 3,7-dimethylocta-1,6-Dien-3-ol; 3-cyclohexen-1-carboxaldehyde, dimethyl-; 3,7-dimethyl-6-octennial; 4-(2,6,6-trimethyl-1-cyclohexenyl)-3-butene-2-it; tridec-2-isonitrile; essential oils of patchouli; ateltico[5.2.1.0]decane-2-carboxylate; 2,2-dimethylcyclohexanone; arylcyclohexylamine; metalloelastase aldehyde; 1-Spiro[4,5]Dec-7-EN-7-yl-4-pentene-1-it; 7-octene-2-ol, 2-methyl-6-methylene-, dihydro, cyclohexanol, 2-(1,1-dimethylethyl)-, acetate; hexahydro-4,7-methanoindan-5(6)-improveverywhere-4,7-methanoindan-5(6)-ylpropionic; 2-methoxynaphthalene; 1-(2,6,6-trimethyl-3-cyclohexenyl)-2-butene-1-it; 1-(2,6,6-trimethyl-2-cyclohexenyl)-2-butene-1-it; 3,7-dimethyloctan-3-ol; 3-butene-2-it, 3-methyl-4-(2,6,6-trimethyl-1-cyclohexen-2-yl)-; hexanoic acid, 2-propilovogo of ester; (g)-non-6-ene-Ala; 1-delovogo aldehyde; 1-octanal; 4-t-butyl-a-methylhydrocinnamic aldehyde; ethyl-2,4-hexadiene; 2-propenyl-3-cyclohexylpropionate; and mixtures thereof;
s) composition of the flavor containing, calculated on the total weight of the flavoring composition is at least 5% of a material selected from the group consisting of 3-cyclohexen-1-carboxaldehyde, dimethyl-; 3-butene-2-it, 3-methyl-4-(2,6,6-trimethyl-1-cyclohexen-2-yl)-; essential oils of patchouli; hexanoic acid, 2-propilovogo of ester; 1-octanal; 1-delovogo aldehyde; (g)-non-6-EN-1-Ala; metalloelastase aldehyde; ethyl-2-methylbutanoate; 1-methylethyl-2-methylbutanoate; ethyl-2-methylpentanoate; 4-hydroxy-3-ethoxybenzaldehyde; 4-hydroxy-3-methoxybenzaldehyde; 3-hydroxy-2-methyl-4-pyrone; 3-hydroxy-2-ethyl-4-pyrone, and their mixtures;
t) a flavoring composition containing, calculated on the total weight of the flavoring composition is less than 10% flavoring, having a Clog P greater than 5.0;
u) a flavoring composition containing geranylacetate; or
v) the composition of the flavor containing the first and optional second material, and said first material has:
(i) a Clog P of at least 2;
(ii) a boiling point of less than about 280°C.; and the second optional material in case of its presence has (i) a Clog p of less than 2.5; and (ii) ODT less than about 100 billion-1.

4. The method according to claim 1, distinguished by the different topics the specified resin material includes the reaction product of an aldehyde with an amine, where the amine is chosen from the group consisting of melamine, urea, benzoguanamine, glycoluril and mixtures thereof.

5. The method according to claim 1, characterized in that the emulsifier contains a fragment selected from the group consisting of carboxy, hydroxyl, thiol, amine, amide, and combinations thereof, and the specified emulsifier has a pKa less than 5.

6. The method according to claim 1, characterized in that the core material includes a material selected from the group consisting of vegetable oils, esters of vegetable oils, esters, linear or branched hydrocarbons, partially hydrogenated terphenyls, diallylphthalate, alkylbiphenyls, alkylated naphthalene, petroleum ethers, aromatic solvents, silicone oils and mixtures thereof.

7. The method according to claim 1, characterized in that at any stage of the method, the pH of the first and second solutions is controlled so that the pH of the specified first and second solutions ranged from about 3.0 to 7.0.

8. The method according to claim 1, characterized in that in stage (f) from about 0% to about 10% based on the total weight of the second composition of the salt containing the anion and the cation, where the specified anion selected from the group consisting of chloride, sulfate, phosphate, nitrate, polyphosphate, citrate, maleate, fumarata and ismeca; and the specified cation selected from the group consisting of an element of group IA of the Periodic system, the group element ON the Periodic system, ammonium cation, and mixtures thereof, together with a specified second composition.

9. The method according to claim 1, wherein delivering these particles contain flavouring, calculated on the total weight of the arriving particles of flavoring at least 1 wt.% flavoring.

10. The method according to claim 1, characterized in that the core material of these delivers particles of the flavoring comprises, calculated on the total weight of the core material is at least about 20 wt.% flavoring.

11. The method according to claim 1, characterized in that the said flavoring composition includes flavoring, and these particles contain, calculated on the total weight of the particles from about 20 wt.% to about 95 wt.% the specified composition of the flavoring.



 

Same patents:

FIELD: chemistry.

SUBSTANCE: invention describes fabric softening compositions containing approximately from 0.01 to 50% cationic or nonionic softening compound; approximately from 0.01 to 5% fragrance component; and at least 0.001 wt % polymer material capable of holding ingredients of a volatile fragrance component, containing: at least approximately 0.001 wt % cross-linked polymer containing at least one vinyl monomer; and approximately from 5000 to 100000 ppm divinyl cross-linking agent. Also disclosed is a fabric softening method which involves bringing fabric into contact with the composition of a fabric softening agent in an effective amount, where contact takes place by sprinkling, rubbing or rinsing.

EFFECT: improved composition properties.

26 cl, 5 ex, 4 tbl

FIELD: chemistry.

SUBSTANCE: composition contains more than 5% anionic surfactant, less than 25% nonionic surfactant, a light-sensitive ingredient and an inorganic mother-of-pearl agent. The light-sensitive ingredient is selected from a group comprising enzymes, dyes, vitamins, aromatising agents and mixtures thereof.

EFFECT: inorganic mother-of-pearl agent improves stability of light-sensitive ingredients in the detergent composition.

20 cl, 14 ex

FIELD: chemistry.

SUBSTANCE: invention relates to oil-containing starch granules for delivering perfume oil as beneficial effect endowing additives to a substrate, containing: (a) starch in amount which forms an effective matrix for said granules; (b) perfume oil containing ingredients with Clog P equal to at least 3; and (c) an effective amount of an amidoamine compound for inhibiting migration of said oil to the surface of the said starch granules, said compound has the following structure: (I) or (II), where radicals are described in the claim separately for each structure. The invention also relates to a method of producing oil-containing starch granules, comprising the following steps: (a) preparing a dispersion of starch in water to form a starch suspension; (b) melting an effective amount of the amidoamine compound of structure (I) or (II) to obtain a molten amidoamine compound; (c) adding perfume oil to the molten amidoamine compound from step (b) to obtain a solution of the amidoamine compound in perfume oil; (d) adding the solution from step (c) to the starch suspension from step (a); (e) homogenisation of the obtained suspension by mixing to obtain a homogeneous mixture; and (f) spray drying the said homogeneous mixture to obtain oil-containing starch granules. The invention also relates to a method of washing fabric, comprising the following steps: (a) preparation of an aqueous solution containing an effective amount of the oil-containing starch granules in claim 1 or 2, and (b) bringing the fabric to be washed into contact with the aqueous solution from step (a). The invention also pertains to a laundry detergent composition containing: (a) at least one surfactant; and (b) an effective amount of oil-containing starch granules.

EFFECT: prolonged existence of the aromatising agent in the substrate owing to inhibition of migration of perfume oil to the surface during laundry.

7 cl, 5 tbl

FIELD: chemistry.

SUBSTANCE: system for delivering fragrant substances includes water-insoluble carrier particles contained at the surface of silanol groups. At least some of the said silanol groups are substituted with organic residues through inoculation of at least one organosilicon compound, and at least some of the said organic residues contain positively charged functional groups, including a positively charged alkylated nitrogen atom. The system also includes an aromatising agent adsorbed or absorbed in the said carrier particles. The carrier particles preferably include silicon dioxide, silicate, aluminium silicate or their mixture. Also described is a method of making a system for delivering fragrant substances. A fabric softening composition includes the system for delivering fragrant substances and one or more active quaternaryammonia compounds for softening fabrics. The washing composition contains the system for delivering fragrant substances and one more surfactants.

EFFECT: increased intensity and strength of fragrance with smaller amount of fragrant substances in the washing composition.

18 cl, 4 tbl, 14 ex

FIELD: chemistry.

SUBSTANCE: invention relates to systems for delivering fragrant substances. A system is proposed for delivering fragrant substances, containing water insoluble carrier particles, containing silanol groups on the surface, on which an organic-silicon compound is grafted, a polymer which contains positively charged functional groups, added to the said carrier particles, and a fragrant substance adsorbed on the said carrier particles or absorbed in the said carrier particles. A method is proposed for making the said system for delivering fragrant substances, as well as a fabric softening composition and washing agent, each of which includes the proposed delivery of fragrant substances.

EFFECT: design of an efficient system for delivering fragrant substances, which give fabrics, treated with compositions with the said delivery system, a strong fragrance.

20 cl, 2 tbl, 8 ex

FIELD: chemistry.

SUBSTANCE: invention concerns technical detergents, particularly pelletised car glass cleansing agent, mainly for windshields. Agent includes, wt %: sodium-(alpha)-olefin-sulfonate 15-25, citric acid monohydrate 15-25, oxidised sodium carbonate 25-45, ether oil or mix of ether oils 0.1-0.3, sodium sulfate is the rest.

EFFECT: enhanced cleaning effect, reduced consumption of detergent solution.

3 cl, 2 ex

FIELD: chemistry.

SUBSTANCE: invention pertains to a class of precursor compounds of aromatising agents, which consist of one or more compounds, obtained from reaction of X-OH and aldehyde or ketone. The above mentioned precursor compounds of aromatising agents have formula X-O-C(R)(R*)(OR**), in which R represents a C6-24alkyl group, C6-24arakyl group or C6-24alkaryl group; R* represents H or C6-24alkylene group, C6-24aralkyl group or C6-24alkaryl group; R** represents H or X; X-O represents a group, a derivative of X-OH, and where X-OH represents a fabric softener based on di(fatty)amidoamines. In the second aspect the invention pertains to the method of obtaining such precursors. The invention also relates to obtaining compositions and products, such as washing powder, fabric softeners, perfume additives or high quality aromatising agents, personal hygiene product and oral care product or product for caring for solid surfaces.

EFFECT: obtaining composition for production of precursor compounds of aromatising agents, with prolonged release of the aromatising agents.

20 cl, 2 ex, 11 dwg

FIELD: chemistry.

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EFFECT: improvement of composition fluidity, reduction of caking when storing.

4 cl, 3 tbl, 11 ex

FIELD: organic chemistry, perfumery.

SUBSTANCE: invention relates to an aromatizing composition containing at least compound of the formula (I): as an active component wherein values w, m, P, X, G, Q and n are given in claim 1 of the invention description, and one or more aromatizing component. Also, invention relates to a method for improving, enhancing or modifying odor, to a method for aromatizing surface, method for enhancing or prolonging the diffusion effect of component on surface and to novel compounds of the formula (I) with exception of compounds enumerated in claim 10 of the invention description and to invention relating to aromatizing article using compounds of the formula (I).

EFFECT: valuable cosmetic properties of compounds.

13 cl, 14 ex

FIELD: organic chemistry, cosmetics.

SUBSTANCE: invention relates to novel compounds of the formula (I) , wherein a dotted line means a bond or it absent and wherein R1 means: -when a dotted line as a bond is absent: -CHCH3OH or -CHCH3OCOR or -CHCH3XCH2CHOHR' or -CHCH3OCHR'CH2OH or ; -when a dotted line is absent: , -CHCH3OH, -CHCH3OCOR, -COCH3, -CHCH3XCH2CHOHR', -CH2CH2XCH2CHOHR', -CHCH3OCHR'CH2OH, -CHCHCOR', -CHCH2CHR'OH, -CH2CHCHR'OCOR, -CHCHCHOHR' or -CHCHCHR'OCOR wherein R means H, Me, Et, Pr, isoPr, But, isoBut, -CH3(CH2)4, -(CH3)2CHCH2, -CH2=CH or -(CH3)2C=CH; R' means H, Me or Et; X means O, N or S atoms. Owing to their odor proposed compounds can be used in perfume industry, cosmetics and care substances and can be used as aromatizing components for preparing atomatized composition or aromatized article.

EFFECT: valuable properties of compounds.

11 cl, 14 ex

FIELD: chemistry.

SUBSTANCE: invention relates to a powder coating composition obtained from aqueous dispersion containing polymer-encapsulated particles, said particles including particles encapsulated in a brittle polymer which can easily break up under ambient conditions. The invention also discloses a method of preparing an aqueous dispersion of particles encapsulated in a brittle polymer, a base which is at least partially coated with a coating deposited from said composition, a multilayer composite coating, a method of preparing a powder coating composition, a method of preparing an aqueous dispersion of particles encapsulated in a brittle polymer and a powder coating composition formed from said dispersion prepared using said method, as well as a reflecting surface which is at least partially coated with a layer which gives the colour of an uncovered coating deposited from disclosed powder coating compositions.

EFFECT: obtaining aqueous dispersion of particles encapsulated in a brittle polymer in which repeated agglomeration of particles is minimised and which enables to obtain a powder coating composition which contains multiple polymer-encapsulated particles having maximum turbidity so that the coating has absorption or reflection in the visible spectrum which is close to that of the given coating.

22 cl, 14 ex, 1 tbl

FIELD: process engineering.

SUBSTANCE: invention relates to production of minor spherical particles of active agent in sole liquid phase solution. Sole liquid phase comprises active agent, agent facilitating phase separation and first thinner. Phase separation is induced at controller rate in solution to cause separation active agent into "fluid-solid" and to form liquid and solid phases. Note here that inducing comprises solution cooling. Solid phase contains minor spherical particles of active agent. Liquid phase comprises agent facilitating phase separation and thinner. Minor spherical particles feature particle size varying from 0.01 mcm to about 200 mcm.

EFFECT: minor spherical particles of active agent in sole liquid phase solution.

77 cl, 49 dwg, 4 tbl, 36 ex

FIELD: process engineering.

SUBSTANCE: invention maybe used for efficient fire extinguishing, fast cooling of overheated structures and production of lower-flammability compounds. Microcapsules have a micro-sphere-like core containing water or water solution in gel state, main shell around said core to provide for core stable shape and composition and rule out water evaporation therefrom the core, and, additionally, comprises outer shell with lyophilic properties. Versions of proposed methods comprises producing aforesaid core via interaction of appropriate initial water solutions to be placed in microsphere and containing appropriate components of the shell with components of solutions to be precipitated and used for producing and cross-linking of gel, and producing additional lyophilic shell via interaction of components of initial solutions with appropriate components in organic medium.

EFFECT: high efficiency in fire extinguishing or fast cooling of overheated structures.

21 cl, 1 tbl, 10 ex

FIELD: chemistry.

SUBSTANCE: invention relates to use of polymer material, and specificaly to use of particulate polymer material as an active agent carrier. The polymer material is a polymer obtained from copolymerisation of pyrrole with quadratic or croconic acid or its derivative.

EFFECT: use in accordance with the invention enables to use polymer material as a composition in form of particles as an absorbent or prolonged release agent.

16 cl, 8 dwg, 1 tbl, 10 ex

FIELD: chemistry.

SUBSTANCE: invention relates to a solid re-dispersible emulsion which is a direct emulsion of fabric softener encapsulated in a polysaccharide shell which is stabilised by ions of polyvalent metals selected from Ca2+, Sr2+, Ba2+, Al3+, Cu2+, Zn2+, where the shell is initially insoluble in water but becomes soluble in water through ion donation. The polysaccharide is biodegradable and is selected from a group comprising alginates and carrageenans. Similar solid re-dispersible emulsions are primarily used in agents for washing or taking care of clothes. Powdered fabric softeners are easy to store, apportion and, if necessary, combine with powdered detergents during production.

EFFECT: invention enables production of fabric softeners previously produced as liquid compositions in solid powdered form.

14 cl, 2 ex

FIELD: chemistry.

SUBSTANCE: invention relates to capsular additives for rubber, obtained in form of microcapsules with a polymer wall and a nucleus, which contains at least one additive for rubber. The capsule wall is formed by at least one component from a reactive resin and at least one component from a polyelectrolyte or ionomer component. The reactive resin is melamine formaldehyde resin and/or polyurea resin. The invention also relates to a method of preparing such microcapsules. The proposed microcapsules are used for vulcanising natural and synthetic rubber. The microcapsules are thermally and mechanically stable in conditions for preparing and processing rubber compositions in kneading machines, manglers or twin-screw extruders at temperatures ranging from 120°C to 140°C.

EFFECT: microcapsular additives are uniformly distributed in rubber mixture and prevent formation of a heterogeneous rubber/additive system.

30 cl, 12 ex

Microcapsules // 2359662

FIELD: medicine, pharmaceutics.

SUBSTANCE: microcapsules, in which water droplet or droplets including the dissolved active ingredient are incapsulated in the hardened hydrophobic cover-matrix, are described. Also the methods of obtaining of the specified microcapsules and their application are described.

EFFECT: development of microcapsules which possess the improved stability and provide the adjustable and-or prolonged release of an active ingredient.

40 cl, 8 dwg, 4 tbl, 8 ex

FIELD: medicine; pharmacology.

SUBSTANCE: carrying out of treatment of disease, in particular, diabetes, by implantation of the encapsulated devices containing a covering and cells, thus density of cells makes 100000 cells/ml, and the covering contains acrylate polyethylene alcohol (PEG) high density with molecular mass from 900 to 3000 Dalton, and also a sulfonated comonomer.

EFFECT: minimisation of the tissue response, augmentation of concentration of cells and augmentation of time of viability of cells in the specified devices.

83 cl, 33 dwg, 8 tbl, 20 ex

FIELD: chemistry.

SUBSTANCE: composition is used for making hollow micro-spheres, which are used as a component of boring solutions when finding and producing oil, as low density filler in various composite materials, used in machine building, aviation and ship building, space technology, and when making heat insulation materials. The composition contains the following, in the given mass ratios: resol phenol-formaldehyde resin with relative viscosity of 5000-9000 cP - 100, porofor (5), polyether based on ethylene oxide copolymer and propylene oxide with molecular mass of 4000-6000 (2-3).

EFFECT: higher space factor of the boring solution micro-spheres, improved looseness of the micro-spheres, increased strength during hydrostatic compression.

1 tbl, 3 ex

FIELD: chemistry.

SUBSTANCE: group of invention covers the microcapsules consisting of at least one core which contains the rubber supplement, and the first polymeric coat of melamine-formaldehyde or phenol-formaldehyde resin; the second polymeric coat is applied upon the microcapsule and its content differs from that of the first one and consists of the low-molecular inorganic or organic compound as a sliding and wear layer to reduce the static friction.

EFFECT: method of preparation microcapsules and use in rubber vulcanisation.

20 cl, 14 ex, 2 tbl

FIELD: medicine.

SUBSTANCE: invention refers to peptides of general formula Rr-AA-R2 which can regulate neuron exocytosis, their mixtures and their cosmetically and pharmaceutically acceptable salts wherein AA represents a sequence of 6-40 neighbouring amino acids contained in the amino acid sequence of the protein SNAP-25 R1 is specified in a group consisting of H or acetyl, or saturated or unsaturated, linear, branched or cyclic C3-C24acyl, or a polyethylene glycol polymer; R2 is specified in a group consisting of amino, unsubstituted or substituted by saturated linear or branched, or cyclic C2-C24aliphatic groups provided when R1 represents H or acetyl, R2 is other tuhan unsubstituted amino. The invention also refers to cosmetic or pharmaceutical compositions containing such peptides, and use of such for treating the conditions which require regulation of neuron exocytosis, preferentially for skin treatment.

EFFECT: higher clinical effectiveness.

12 cl, 1 dwg, 8 ex

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