RussianPatents.com
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Method to develop structural ceramic material. RU patent 2450998. |
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FIELD: construction. SUBSTANCE: charge is prepared, containing the following components, mol. %: SiC - 53-62, BN - 3-7, Al - 35-40, at the same time the rated quantity of aluminium is introduced in it in full volume, doing mechanical activation. Primary stocks are shaped from the charge, dried, exposed to vacuum sintering and grinding. After the secondary shaping the stocks are dried, sintered in vacuum, nitrified at the temperature of 1050°C, and thermal treatment is carried out at 1400°C. Vacuum sintering is carried out at the temperature of 1150±2°C. The produced structural ceramic material is characterised by higher density and strength: withstands compression stress of at least 450 MPa, bending stress - of at least 130 MPa at high working temperatures of the material (at least 1400°C). Shrinkage at the stage of cermet conversion into ceramics - not more than 0.5%. EFFECT: reduced shrinkage.
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Refractory / 2448927 Invention relates to production of refractories, having high emissivity and prolonged use limiting temperature and can be used in metallurgical heat engineering, high-temperature equipment and combustion chambers. The ready mullite-silica refractory contains the following eutectic phases, wt %: mullite 3Al2O3·2SiO2 85-95, cristobalite 1-15 chromite FeO·Cr2O3 1-6. The refractory is obtained by melting raw materials - technical alumina, quartzite and chromite - in an arc furnace at temperature 2100°C. Chromite increases heat resistance and cristobalite increases emissivity of mullite at high temperatures. |
Proppant and production method thereof / 2447126 Invention relates to production of proppants used in oil and gas extraction using a penetrating fluid method. In the method of producing a proppant used when extracting oil and gas using a penetrating fluid method involves preparation of the starting mineral material, melting the material to obtain granules in a gas-discharge low-temperature plasma reactor, cooling the granules and screening said granules into commercial-grade fractions, the surface of the granules is cooled at a rate of more than 1.0-106 °C/s. The proppant, which is used when extracting oil and gas using a penetrating fluid method, obtained using said method in form of granules with diameter 100-2000 mcm and pycnometric density 1.0-3.5 g/cm3, from mineral material consisting of a core and cladding, where the cladding has an amorphous structure. The invention is developed in the dependent claims of the formula. |
Refractory article cast from melt / 2440953 Invention relates to refractory articles based on zirconium dioxide, which can be used in glass-melting tank furnaces and in steel-casting industry as vessels for continuous steel casting, as slide plates and as wearing components in zones under extra high load. The refractory article cast from melt consists of zirconium dioxide, whose crystals are stabilised with magnesium oxide and are surrounded by at least one magnesium oxide-containing crystalline phase. Magnesium oxide-containing crystalline phases and magnesium oxide account for 0.5-10 wt % and 1-10 wt % of the total weight of the refractory article, respectively. The magnesium oxide-containing crystalline phase is forsterite, enstatite, cordierite or spinel. |
Fused refractory material / 2431626 Fused refractory material has the following composition, wt %: 0.3-0.7 Na2O; 1.0-1.5 CaO; 1.0-2.0 Cr2O3; 0.5-1.0 MgO; 0.2-0.8 SiO2; Al2O3 - balance. Fused material has good compressibility and sintering ability, has high temperature of load softening start. |
Method of producing zirconia alumina / 2425009 Invention relates to production of zirconia alumina used in making an abrasive tool on a flexible base and grinding wheels on an organic bond. The method of producing zirconia alumina involves preparation of a mixture, loading said mixture into an electric melting furnace, melting and pouring the melt into a slit-type crystalliser for intense cooling of the melt. The alumina-containing component of the mixture used is high-alumina industrial wastes from natural gas processing, and the stabiliser and degasifying agent used is wastes from mechanical processing titanium metal. |
Boron suboxide-based composite material / 2424212 Invention relates to production of boron suboxide composite material which can be used as an abrasive. The composite material contains crushed or granulated boron suboxide, AlxByOz distributed in a binding phase, where x ranges from 4 to 8, y ranges from 2 to 4 and z ranges from 9 to 33. The amount of the binding phase is less than 30% of the mass of the composite material, preferably 3-15 wt %. In order to obtain the composite material, a coating of aluminium or aluminium compound is applied on the boron suboxide particles and then sintered at temperature higher than 1600°C and pressure lower than 300 MPa. |
Method of producing of heat resistant zircon-containing material / 2400451 Method for production of heat resistant zircon-containing material includes mixing powder of zircon and aluminium represented by powder with fraction of less than 80 micrometre, in ball mill in liquid glass for 1-3 hours, moulding initial stocks and sintering at the temperature of 1600°C. Components in charge are in the following ratio, wt %: zircon concentrate 80-90, aluminium powder 10-20. |
Method of making non-shrinking structural ceramic article / 2399601 Invention can be used to make articles from high-strength, non-shrinking ceramic materials working in high thermal-cycle loads in an oxidative, corrosive and aggressive atmosphere, and particularly in power generation installations. The starting material undergoes screening and deep cleaning. A mixture is prepared from components in the following ratio in mol %: boron nitride 12.5-17.5, aluminium 37-43, silicon carbide 42.5-46 and the mixture is mechanically activated. Primary workpieces are moulded from the mixture, dried and vacuum sintering is carried out at temperature between 1150 and 1250°C with residual pressure of 0.05 atm. The sintered workpieces are ground up and mechanically activated, after which articles are moulded and then vacuum sintered in conditions given above, mechanically processed, nitrogen hardened and oxidised. |
Method of producing al2o3-al composite material / 2398037 Invention relates to powder metallurgy, particularly to production of composite materials. It can be used for production of strong wear-resistant parts, abrasive tools and sealing elements. Billet is produced by pressing the burden that comprises aluminium powder that features plate-like shape of particles and binder, and sintering in SHS-conditions. Sintered product is placed in mould, heated to 600÷775°C and 9÷12 MPa pressure is applied thereto for 1÷30 minutes to product deformation of 1.18÷1.25. Then product is cooled under pressure to 590÷650°C at the rated of 5÷10°C/min. Now, pressure is removed and product is cooled to ambient temperatures at the rate of 2.5÷4°/min. |
Manufacturing method for beta-sialon / 2384546 Method is suggested for production of beta-sialon, in which thermal treatment of mixture of aluminium powder with specific surface area equal to 22.0-24.0 m2/g, and crystalline silicon powder with specific surface area of 0.2-0.3 m2/g, taken in the ratio of 1:1, is carried out by heating up to temperature of 1100-1200°C with heating rate of 10-12°/minute in air atmosphere. |
Method of producing aluminium nitride-based heat-conducting ceramic / 2433108 Invention relates to production of aluminium nitride-based heat-conducting ceramic which can be used in electronics and electrical engineering, particularly as substrate material for powerful microwave and power semiconductor devices, as well as other devices where there is need for good dielectric properties, strength and heat conductivity of the material. Powder of aluminium nitride with particle size less than 1 mcm, containing not less than 10% cubic phase of aluminium nitride with particle size less than 100 nm, and a technical additive selected from Y2O3, CaO, MgO in amount of not more than 6 wt % is used to prepare a mixture, with addition of not more than 65 vol. % organic component containing a solvent (mixture of methylethyl ketone with ethanol in ratio of 1:2), a dispersant (phosphate ether), binder (polyvinyl butyral) and a plasticiser (mixture of polyethylene glycol with dibutyl phthalate), followed by stirring with simultaneous deaeration for not less than 30 minutes rarefaction of air of not less than 0.15 atm. A belt is formed from the obtained slip, dried and cooled to room temperature. A plate is formed from the belt. The organic component is removed at temperature 150-500°C. The obtained half-finished product is sintered at pressure 0.1-1.0 MPa in the atmosphere of a nitrogen-containing gas at temperature 1650-1820°C for 1-3 hours and then cooled under given conditions. |
Method of producing moulded aluminium oxynitride in burning mode / 2370472 Invention relates to making heat resistant ceramic materials, particularly to methods of producing aluminium nitride in burning mode. The method of producing aluminium oxynitride involves preparation of a reaction mixture of initial components, containing chromium (VI) oxide, aluminium oxide, aluminium and aluminium nitride, putting the reaction mixture into an SHS reactor in form of heat resistant material, made from quartz, graphite or stainless steel, ignition of the mixture with subsequent reaction of its components in burning mode under 0.1-10 MPa pressure in a nitrogen medium, or mixture nitrogen and air, or mixture of nitrogen and argon. After synthesis of the end product in form of an ingot, aluminium oxynitride is separated from the chromium aluminide ingot. Components of the reaction mixture are in the following ratio, wt %: chromium (VI) oxide 37.3-41.0; aluminium 31.0-34.0; aluminium oxide 22.7-25.0; aluminium nitride up to 9.0. A functional layer of aluminium oxynitride powder can be put between the reaction mixture of components and the wall of the mould. |
Method of charge receiving containing aluminium nitride of cubic phase / 2361846 Method includes mixture preparation of superdispersed powders of aluminium and additions, burning of mixture on air up to achieving of maximal combustion temperature and quenching. In the capacity of addition it is used powder of tungsten or molybdenum at following correlation of components, wt %: superdispersed powder of aluminium - 97-98, superdispersed powder of tungsten or molybdenum - the rest. |
Method of production of a ceramic charge / 2268867 The invention is pertaining to the technology of production of the technical ceramics, in particular, to the technical ceramics resistant to the high temperatures and possessing a high thermal conductivity, which may be used in production of a charge for ceramic ware, including, the multilayered ceramic substrates, ceramic heaters, ceramic emitters and refractory structural materials. The offered development allows to form the charge with the required ratio of aluminum nitride and aluminum oxide by incineration of the ultradispersive powder of aluminum in a gas medium at the atmospheric pressure. The incineration of the aluminum powder is conducted in the chamber, which is connected by the free cross-flow to the gasholder filled with an artificial gaseous mixture of nitrogen and oxygen with the preset ratio. The technical result of the invention is the ratio control of an aluminum nitride and aluminum oxide in combustion materials by formation of the gases mixture with a preset amount of nitrogen and oxygen. |
Furnace charge for production of aluminum oxynitride / 2264997 The invention is pertaining to the field of production high-refractory ceramic materials, in particular, to production of aluminum oxynitride, which may be used as a component of ceramics and cermet for manufacture of cutting tools, heat-resistant and heat-conducting components of constructions, and also in thee oxidizing mediums instead of aluminum nitride and in a combination with it. The technical result of the invention is reduction of the end product cost price due to utilization of the more low-cost components. The premixed source charge consisting of an aluminum powder with the size of the specific surface area less than 0.01 m2/g with the content of the main substance of 79.4-99.8 mass % and a powder of aluminum oxide with the size of the specific surface less than 2.2 m2/g, burn in the air. The components are taken in the following ratio (in mass %): aluminum powder - 5-20, a dust of aluminum oxide - the rest. |
Method of producing ceramic armour material based on silicon carbide and boron carbide and ceramic armour material based on silicon carbide and boron carbide / 2440956 Invention relates to production of hard-alloy material, as well as to making protective equipment and can be used to produce armour ceramics. To produce composite material, a mixture is formed from grains of α-crystals of silicon carbide 50-100 mcm - 40-60 pts.wt, grains of boron carbide crystals ≤35 mcm - 40-60 pts.wt and a mixture of bakelite lacquer with isopropyl alcohol - 5-10 pts.wt; a workpiece is pressed and then heat treated to obtain pyrolytic carbon lying between grains of carbides; the workpiece is calcined in a vacuum at temperature 1450-1900°C. The workpiece undergoes silicification with 120-130 pts.wt metallic silicon per 100 pts.wt of the workpiece. During silicification, β-crystals of silicon carbide are deposited on the α-crystals of silicon carbide to 80-150 mcm grains with formation of bridges from β-crystals between silicon carbide grains, and on grains of boron carbide crystals - a shell of silicon, boron silicides and a solid solution of silicon carbide in boron carbide to form bridges from the latter. The obtained ceramic armour material is a double-crystal composite material from reaction bonded grains of α-crystals of silicon carbide, reaction bonded grains of boron carbide crystals and inter-grain silicon phase. |
Nanostructured functional-gradient composite material and method of producing said material / 2428395 Invention relates to engineering ceramics and particularly to ceramic-matrix composite material based on silicon carbide reinforced with carbon fibres. Disclosed is composite material which contains a matrix made from reaction bonded silicon carbide reinforced with bundles of carbon fibres and a working layer made from reaction bonded silicon carbide on at least one of its surfaces. The matrix and the working layer consist of 75-92 vol. % silicon carbide which is in form of primary grains and nanosized secondary grains, and 8-25 vol. % free silicon. The ratio of volume content of the matrix and reinforcing bundles of fibre increases from 25/75 to 60/40 in the direction towards the working layer. The method of producing the composite material involves steps for moulding a workpiece, hardening, carbonisation and silicon impregnation. Before moulding, reinforcing bundles of carbon fibre are treated with a suspension containing silicon carbide particles in amount of not more than 50 wt % and binder, and the carbon fibres for the working layer is treated with a suspension containing silicon carbide particles in amount of not more than 30 wt % and polymer binder in amount of not more than 20 wt %. When forming at least a set of thickness, reinforcing bundles of carbon fibre treated with a suspension with increasing content of silicon carbide particles in an interval from 30 to 50 wt % and/or with increasing average size of silicon carbide particles from 5 to 30 mcm are laid in the direction towards the working layer. The silicon impregnation step is carried out at temperature 1400-1450°C. |
Nanostructured ceramic matrix composite material and method of producing said material / 2415109 Invention relates to machine engineering ceramics, particularly ceramic matrix composite material based on silicon carbide and reinforced with carbon fibre. The composite material contains a matrix of reaction-sintered silicon carbide, reinforced with bundles of carbon filaments, separated from the matrix by a barrier layer. The filaments in the bundles are joined to each other by a dense sintered nanosize inter-filament phase which contains carbon, silicon, boron, nitrogen, as well as aluminium and yttrium oxide compounds. The barrier layer and the inter-filament phase do not contain free carbon. The method of producing the composite material involves pre-treatment of the bundles of carbon filaments with a suspension which contains polymer binder and nanoparticles of silicon nitride, aluminium and yttrium oxide compounds and at least one component selected from: boron, silicon, boron or silicon compound. After drying, the fibre mass is saturated with coke-forming binder which contains silicon carbide particles, the workpiece is moulded, the binder is cured, followed by a carbonisation step, synthesis and sintering of the inter-filament phase, and then a step for saturating the workpiece with solutions or melts of coke-forming polymers and silicification. |
Manufacturing method of moulded parts on basis of beta-sic for being used in corrosive media / 2375331 Manufacturing method of composite material on the basis of β-SiC, which involves: a) obtaining the mixture called "mixture-predecessor", which contains at least one predecessor β-SiC and at least one carbon-bearing heat-curable resin, b) forming the above mixture- predecessor in the form of granules, plates, tubes or bricks for manufacturing intermediate product, c) resin polymerisation, d) introduction of the above intermediate products to the capacity, e) closing the above capacity by means of the closing device allowing to avoid gas pressure increase, f) heat treatment of the above intermediate products at temperature of 1100°-1500°C for removing organic resin components and forming β-SiC in the end product. Products manufactured with the above method can be used as inner lining of electrolysis bath of fused salt or inner lining of incinerator. |
Carbon-containing composition for making silicicated components / 2370435 Invention relates to production of structural components based on carbon or graphite, particularly silicicated graphite. The composition contains carbon in form of powdered graphite with particle size of not more than 200 mcm in amount of 10-80 wt %, silicon carbide in amount of 10-60 wt % and binder - the rest. Carbon and silicon carbide are in inverse proportion and their total content in the composition is in the range 60-95 wt %. Density of the obtained material is 2.92-3.08 g/cm3, and ultimate compression strength is 4550-4970 kgf/cm2. |
Method of manufacturing antifriction parts from silicon carbide / 2314275 Invention relates to manufacturing silicon carbide parts via reaction caking procedure, especially concerning friction elements of end seals of pump-compressor and other equipment. Silicon carbide is ground to particle size 10 μm or less and mixed with carbon black ground to particle size 0.1 μm, while using, during both wet grinding and mixing operations, (i) isopropyl alcohol surfactant in amount 0.5-1.0% based on the volume of water medium present during grinding operation and (ii) aqueous cellulose solution added 15-20 min before the end of grinding. Dried mix is supplemented by paraffin dissolved in gasoline and rectification blanks are compacted at pressure 400-500 kg/cm2. Blanks are then treated in vacuum electric furnace at excessive pressures and consecutively applied temperatures: 100, 200, 300, and 400°C, during which operation temporary binder is removed. Reaction caking and impregnation of blanks are carried out in vacuum 10-3 mm Hg at 1500-1600°C. |
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