RussianPatents.com
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Superhard material. RU patent 2413699. |
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FIELD: chemistry. SUBSTANCE: invention relates to production of superhard material which contains CVD diamond and which can be used in making a wheel dressing tool, a cutting, drilling tool etc. The surface of the CVD diamond is partially or completely covered by a shell under high pressure and temperature, where the said shell has a frame made from polycrystalline diamond (PCD) or polycrystalline cubic boron nitride (PCBN) with a bond between diamond-diamond grains or cBN-cBN grains, between which an activating additive is placed. The surface area of the shell surrounding the CVD diamond is not less than 40% of the surface of the CVD diamond; said shell contains 70-95 wt % PCD or PCBN and 5-30 wt % activating additive. If the shell is made from polycrystalline material based on PCD, the activating additive contains silicon and/or at least one transition metal, and if made from polycrystalline material based on PCBN, the activating additive contains aluminium and/or nitrides, borides and/or salicides of group IlIa, IVa, IVb, Vb, VIb, VIIb and VIII metals. The CVD diamond component of the superhard material can be polycrystalline as well as monocrystalline and can have different shapes and dimensions. EFFECT: obtaining superhard material with high compression strength and thermal stability. 4 cl, 5 tbl, 2 dwg
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Structural material / 2348594 Structural material as per the invention is received from the charge material containing cilicide of carbon in the form of ultra fine fiber, ultra fine boron nitride and carbon fiber having periodically recurring internal volumes filled with helium at the following components ratio, volume %: boron nitride B11N15 30-94.6, carbon fiber 5-25, ultra fine cilicide of carbon 0.2-15, helium 0.2-30. Diamond - like layers are located in the contact spots of ultra fine fiber with carbon fiber, and cubic boron nitride layers are located in the contact spots with boron nitride. Helium and boron nitride have isotopic composition with light section of thermal neutron capture. |
Method of production of composite materials / 2266268 Proposed method includes molding the blanks from borazon powders followed by heat treatment of blanks in hydrocarbon medium and impregnation with liquid silicon at temperature of 1420-1700°C and pressure no less than 1000 mm Hg. Heat treatment in hydrocarbon medium is continued till increase of mass of blank by 3-25%. Borazon grains are bonded by silicon carbide matrix; proposed method excludes losses of superhard materials in forming silicon carbide due to diamond. |
Composite / 2243955 Claimed material is sintered under pressure and contains (mass %): hexagonal boron nitride 45-80 and second material 55-20. The second material represents solid aluminum oxide solution in silicium nitride containing 35 % or less of oxygen. |
Method for manufacturing of fibrous stock for production of parts from composite material of carbon/carbon type, including ceramic particles, and products produced by this method / 2407718 One or more than one two-dimensional fibrous fabric from carbon fibres or precursors of carbon fibres is impregnated with sol-gel by solution or colloid suspension, providing for possibility of dispersion of discrete ceramic particles to remain on fibrous fabric. Sol-gel solution contains precursor of oxide, and colloid suspension - oxide, selected from the following group: TiO2, ZrO2, HfO2, SiO2. Fibrous stock is made by means of application of layers formed of two-dimensional fabric made of carbon fibres or precursors of carbon fibres, besides, at least some of layers are at least partially formed of previously impregnated two-dimensional fabric. Layers are connected to each other, and thermal treatment is carried out at the temperature of 1400-1750°C, afterwards fibrous stock is sealed with carbon matrix. In process of thermal treatment particles of oxide are transformed into particles of carbide. |
Method for processing of fire-resistant products / 2356873 Invention is related to production of fire-resistant products and may be used in aviation and rocket engineering. Technical result is achieved by layerwise saturation of refractory material surface with carbon by means of fullerene solution impregnation in organic dissolvent. Product is placed above heating element so that temperature of saturated surface does not exceed 60-65°C, fullerene solution is supplied in organic dissolvent onto product surface so that complete surface is wetted, and impregnation is carried out for 30-45 minutes. |
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Heat-resistant composite diamond sintered article and the method of its production / 2312844 The invention is pertaining to the heat-resistant composite diamond sintered articles used in the capacity of the cutting tools, the tool used for the high-precision machining and to the jewelry branch. The diamond composite sintered article contains in the capacity of the article the diamond crystal and the very small amount of the non-diamond carbon and has the hardness according to Vickers of 85 GPa or more. The article is produced by the method providing for inclusion of the synthetic diamond powder having the average size of the grains of 200 nanometers or less, in the tantalum or molybdenum capsule, both heating and application of the pressure at usage of the apparatus for the synthesis under the super-high pressure in the thermodynamically stable conditions including the temperature of 2100°С or more and the pressure of 7.7 GPa or more. The technical result of the invention is production of the articles having the electric conductivity, the high thermal stability and having the brilliance and the glaze. |
Superfine-grained diamond sintered article of the high purity and the high hardness / 2312843 The invention is pertaining to the production of the superfine-grained diamond sintered articles of the high purity and high hardness, which is intended for usage in the capacity of the wear-resistant material capable to let the light go through it, and may be used in production of jewels. The article has the size of the grain equal to 100 nanometers or less. For its manufacture the superfine-grained natural diamond powder having the granulometric spread of values from null up to 0.1 microns is subjected to desiliconization, to sublimation drying in the solution, inclusion into the tantalum or molybdenum capsule without the sintering additive, heating and application of the excessive pressure to the capsule using the device for the synthesis at the super-high pressure at the temperature of 1700°С or more and under pressure of 8.5 GPa or more, which meet the conditions of the thermodynamic stability of the diamond. The technical result of the invention is realization of the synthesis of the diamond sintered article at the more low pressure, than in the standard method and without usage of any sintering additive. The article has hardness according to Vickers - 80 GPa and more and is excellent concerning resistance to the tear and wear and the thermal resistance. |
Method of production of the composite materials based on the ultra-hard particles for manufacture of the cutting tools / 2296727 The invention is pertaining to the field of the tool-and-die industry, in particular, to production of the composite materials for the cutting tools on the basis of the ultra-hard particles with their volumetric contents in the material of 75÷ 92 %. For production of the composite materials the method provides for preparation of the charge, which consists of the binding agent and the ultra-hard particles, at least, of two sizes, from which as one size the ultra-hard particles use the diamond, and as the ultra-hard particles of the other size use the cubic boron nitride of 8÷40 microns. At that they take diamond particles with the size equal to (5.1-8) sizes of the cubic boron nitride. The charge is subjected to the thermal pressing at the temperature of the binding agent melting. Besides, the charge is additionally introduced with the diamond particles of the size equal (4-6) sizes of the main diamond grains. At that the main diamonds grains are taken with the size of 81-320 microns. The method allows manufacture the composite material with the wide range of the operational characteristics. |
Initial refractory materials, the method of their production and the refractory products manufactured with their usage / 2294945 The invention is pertaining to production of the refractory products and may be used in building materials industry, metallurgy industry, other industries for production of the refractory materials and products. The refractory materials are produced by molding the composition, which contains the refractory filler and the initial refractory material with the graphite grains having the average size of 500 nanometers or less, or with the graphite grains produced by the graphitization of the carbonic carbon black. The graphite grains contain at least one component selected from the group consisting of metals, boron and silicon. The refractory materials alongside with the refractory filler may contain also the carbon grains (A), selected from the carbonic carbon black and the graphite grains produced by the graphitization of the carbonic carbon black and having absorption - DBP (x) 80 ml/100g or more; the carbon grains () selected from the carbonic carbon black and the graphite grains produced by the graphitization of carbonic carbon black, and having absorption -DBP (x) less than 80 ml/100g. The invention allows to improve the thermal impact stability of the refractory materials, their corrosion resistance and the oxidation resistance. |
Thermal-protective system with the variable density of the fibers / 2293718 The invention is pertaining to the thermal-protective materials used for the aerospace industry and may be applied for protection of the surface subjected to the action of the intensive heat loading. The thermal-protective system contains the fiber basis consisting of the woven or non-woven fiber layers composed in the form of the multilayer material, or the basis produced by the method of the three-dimensional canework. At that the fiber basis has the variable density of the fibers with the density increasing into the depth of the thermal-protective material from the outer surface to the inner surface. The basis is impregnated with the organic resin, subjected to the carbonization, then it is impregnated with the ablation resin based on silicone. In the basis there is perforation and it is connected to the insulating substrate. The technical result of the invention is achievement of the high strength and the high-degree protection against oxidization at the rather low cost. |
Heat-conducting material / 2270821 Invention relates to diamond-containing composites, which show high heat-conductivity and high temperature-conductivity for use in heat absorbers, heat distributors, and in other cases where heat-conducting materials are required. Material contains 55-81% diamond particles, 3-39% silicon carbide, and up to 41% silicon showing heat-conductivity at least 400 W/(m·K) and temperature-conductivity at least 2.1 cm2/sec. Diamond particles are made up of at least two fractions with different particle size, at least 50% of particles having diameter 80 μm and larger. |
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Heat-conducting material / 2270821 Invention relates to diamond-containing composites, which show high heat-conductivity and high temperature-conductivity for use in heat absorbers, heat distributors, and in other cases where heat-conducting materials are required. Material contains 55-81% diamond particles, 3-39% silicon carbide, and up to 41% silicon showing heat-conductivity at least 400 W/(m·K) and temperature-conductivity at least 2.1 cm2/sec. Diamond particles are made up of at least two fractions with different particle size, at least 50% of particles having diameter 80 μm and larger. |
Thermal-protective system with the variable density of the fibers / 2293718 The invention is pertaining to the thermal-protective materials used for the aerospace industry and may be applied for protection of the surface subjected to the action of the intensive heat loading. The thermal-protective system contains the fiber basis consisting of the woven or non-woven fiber layers composed in the form of the multilayer material, or the basis produced by the method of the three-dimensional canework. At that the fiber basis has the variable density of the fibers with the density increasing into the depth of the thermal-protective material from the outer surface to the inner surface. The basis is impregnated with the organic resin, subjected to the carbonization, then it is impregnated with the ablation resin based on silicone. In the basis there is perforation and it is connected to the insulating substrate. The technical result of the invention is achievement of the high strength and the high-degree protection against oxidization at the rather low cost. |
Initial refractory materials, the method of their production and the refractory products manufactured with their usage / 2294945 The invention is pertaining to production of the refractory products and may be used in building materials industry, metallurgy industry, other industries for production of the refractory materials and products. The refractory materials are produced by molding the composition, which contains the refractory filler and the initial refractory material with the graphite grains having the average size of 500 nanometers or less, or with the graphite grains produced by the graphitization of the carbonic carbon black. The graphite grains contain at least one component selected from the group consisting of metals, boron and silicon. The refractory materials alongside with the refractory filler may contain also the carbon grains (A), selected from the carbonic carbon black and the graphite grains produced by the graphitization of the carbonic carbon black and having absorption - DBP (x) 80 ml/100g or more; the carbon grains () selected from the carbonic carbon black and the graphite grains produced by the graphitization of carbonic carbon black, and having absorption -DBP (x) less than 80 ml/100g. The invention allows to improve the thermal impact stability of the refractory materials, their corrosion resistance and the oxidation resistance. |
Method of production of the composite materials based on the ultra-hard particles for manufacture of the cutting tools / 2296727 The invention is pertaining to the field of the tool-and-die industry, in particular, to production of the composite materials for the cutting tools on the basis of the ultra-hard particles with their volumetric contents in the material of 75÷ 92 %. For production of the composite materials the method provides for preparation of the charge, which consists of the binding agent and the ultra-hard particles, at least, of two sizes, from which as one size the ultra-hard particles use the diamond, and as the ultra-hard particles of the other size use the cubic boron nitride of 8÷40 microns. At that they take diamond particles with the size equal to (5.1-8) sizes of the cubic boron nitride. The charge is subjected to the thermal pressing at the temperature of the binding agent melting. Besides, the charge is additionally introduced with the diamond particles of the size equal (4-6) sizes of the main diamond grains. At that the main diamonds grains are taken with the size of 81-320 microns. The method allows manufacture the composite material with the wide range of the operational characteristics. |
Superfine-grained diamond sintered article of the high purity and the high hardness / 2312843 The invention is pertaining to the production of the superfine-grained diamond sintered articles of the high purity and high hardness, which is intended for usage in the capacity of the wear-resistant material capable to let the light go through it, and may be used in production of jewels. The article has the size of the grain equal to 100 nanometers or less. For its manufacture the superfine-grained natural diamond powder having the granulometric spread of values from null up to 0.1 microns is subjected to desiliconization, to sublimation drying in the solution, inclusion into the tantalum or molybdenum capsule without the sintering additive, heating and application of the excessive pressure to the capsule using the device for the synthesis at the super-high pressure at the temperature of 1700°С or more and under pressure of 8.5 GPa or more, which meet the conditions of the thermodynamic stability of the diamond. The technical result of the invention is realization of the synthesis of the diamond sintered article at the more low pressure, than in the standard method and without usage of any sintering additive. The article has hardness according to Vickers - 80 GPa and more and is excellent concerning resistance to the tear and wear and the thermal resistance. |
Heat-resistant composite diamond sintered article and the method of its production / 2312844 The invention is pertaining to the heat-resistant composite diamond sintered articles used in the capacity of the cutting tools, the tool used for the high-precision machining and to the jewelry branch. The diamond composite sintered article contains in the capacity of the article the diamond crystal and the very small amount of the non-diamond carbon and has the hardness according to Vickers of 85 GPa or more. The article is produced by the method providing for inclusion of the synthetic diamond powder having the average size of the grains of 200 nanometers or less, in the tantalum or molybdenum capsule, both heating and application of the pressure at usage of the apparatus for the synthesis under the super-high pressure in the thermodynamically stable conditions including the temperature of 2100°С or more and the pressure of 7.7 GPa or more. The technical result of the invention is production of the articles having the electric conductivity, the high thermal stability and having the brilliance and the glaze. |
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