Cleaning composition containing organic catalyst with improved compatibility with enzymes

FIELD: chemistry.

SUBSTANCE: cleaning compositions contain organic catalysts having the formula (i), (ii) given in the formula of invention, or mixtures thereof. In the formula G is selected from -O-, -CH2O-, -(CH2)2- and -CH2-, R1 is selected from H or C1-C4 alkyl, each R2 is independently selected from C4-C8 alkyl, benzyl, 2-methylbenzyl, 3-methylbenzyl, 4-methylbenzyl, 4-ethylbenzyl, 4-isopropylbenzyl and 4-tert-butylbenzyl.

EFFECT: improved compatibility of organic catalysts with enzymes.

18 cl, 18 ex

 

The technical field to which the invention relates.

The present invention relates to cleaning compositions containing organic catalysts, and to methods of producing and using such cleaning products.

The level of technology

Oxygen bleaches such as hydrogen peroxide, commonly used to facilitate the removal of stains and dirt from clothes and various surfaces. Unfortunately, these brighteners have extreme dependence on temperature. As a result, when the application of such brighteners in colder solutions, whitening effect of such solutions is significantly reduced.

In an effort to solve the aforementioned problem of efficiency, the industry developed a class of materials known as "bleach activators". However, since such materials would quickly lose their effectiveness in solution at temperatures less than 40°C, developed new organic catalysts, such as the internal salt of 3,4-dihydro-2-[2-(sulfoxy)decyl]skinline. In General, although such catalysts current level of technology is effective in conditions of low temperature water, they can inactivate certain enzymes. Since most of the compositions for washing and cleaning compositions are produced with enzymes, making cleaning products such catalysts which may be problematic.

Thus, there is a need for inexpensive cleaning compositions containing an organic catalyst that can provide the combined effect of the universality of the composition, the efficiency of bleaching at low water temperatures and compatibility with enzymes.

The invention

The present invention relates to cleaning compositions containing organic catalysts having improved compatibility with enzymes, and to methods for their preparation and use.

Detailed description of the invention

Definition

As used in this application, the term "cleaning composition" includes, unless otherwise indicated, granular or powder form generic or "heavy duty" detergents, especially detergents for Laundry use; liquid, gel or paste-form of the universal or "heavy duty" detergents, especially the so-called heavy-duty liquid types; liquid detergents for fine fabrics; compositions for hand dishwashing and light compositions for washing dishes, especially compounds with a rich foaming; compositions for machine dishwashing, including the various tablet, granular, liquid species and with the addition of rinse for domestic and industrial use; liquid cleaning and disinfecting compositions, on the tea antibacterial face wash, detergent bars, liquid for rinsing the mouth, cleanser for the teeth, shampoos for vehicles and carpet cleaning products for baths; shampoos and conditioners for the hair; shower gels and foam baths and metal cleaners surfaces; and an auxiliary cleaning agents such as bleach additives and cleaners such as alcohol or substance for pre-processing.

As used in this application, the phrase "independently selected from the group consisting of..." means that the parts or elements that are selected from a specified Markush formula, may be the same or different represent any mixture of elements.

To determine the appropriate values of the parameters of the inventions of the applicant must use the test methods disclosed in the section "testing" of this application.

Unless otherwise stated, all of the components or contents of the compositions are given in the calculation of active content data components or compositions and do not include impurities such as residual amounts of solvents or by-products that may be present in commercially available products.

All percentages and ratios are by weight, unless otherwise indicated. All percentages and ratios are calculated on the entire composition, unless otherwise indicated.

<> It should be understood that every maximum numerical limitation given in this description, includes any smaller the numerical value, as if such lower values would be specified. Each minimum numerical limitation given in the framework of the present description, will include any more numerical limitation, as if such greater restrictions would be specified. Any numerical range described in the present description, will include any narrower range, enter into it, as if such narrower ranges were specified.

All cited documents, in relevant part, incorporated into the present application by reference; the citation of any source cannot be considered as recognition of his relating to the prior art relative to the present invention.

Cleaning compositions containing an organic catalyst

The applicant has found that thoughtful selection of fragments R1and R2organic catalyst of the present invention results in improved compatibility with enzymes. Not communicating with theory, the applicant believes that this is due to the favorable decomposition catalyst in aqueous media as a result of the foregoing deliberate choice KJV is anutech fragments.

One object of the invention detergent compositions contain organic catalyst having the value of compatibility with enzymes 70 or more, or even 80 or more.

One object of the invention detergent compositions contain organic catalyst having the value of compatibility with the enzyme 70 or more, and one or more ancillary compounds.

One object of the invention detergent compositions contain organic catalyst having the value of compatibility with the enzyme 80 or more, and the composition contains the following additional ingredients: activated source barkisland, enzyme and surfactant.

One object of the invention detergent compositions contain organic catalyst represented by formula 1 or formula 2, or a mixture thereof.

where G is selected from-O-, -CH2O-, -(CH2)2- and-CH2-. R1selected from N or C1-C4the alkyl. Suitable1-C4alkyl fragments include, but are not limited to,methyl, ethyl, isopropyl and tertbutyl. Each R2independently selected from C4-C8of alkyl, benzyl, 2-methylbenzyl, 3-methylbenzyl, 4-methylbenzyl, 4-ethylbenzyl, 4-isopropylbenzyl and 4-tertbutylbenzene. Suitable4-C8alkyl fragm the options include, but not limited to, n-butyl, n-pentyl, cyclopentyl, n-hexyl, cyclohexyl, cyclohexylmethyl, n-heptyl and octyl.

One object of the present invention G is selected from-O - and-CH2-. R1selected from H, methyl, ethyl, isopropyl and tertbutyl. Each R2independently selected from C4-C6of alkyl, benzyl, 2-methylbenzyl, 3-methylbenzyl and 4-methylbenzyl.

Another object of the present invention G is a-CH2-, R1represents H, and each R2independently selected from n-butyl, n-pentile, n-hexyl, benzyl, 2-methylbenzyl, 3-methylbenzyl and 4-methylbenzyl.

Part of the above detergent compositions, any object, is brought to balance (to 100%) using one or more auxiliary materials.

Methods of obtaining suitable organic catalysts

Suitable organic catalysts can be obtained using different reaction reactors and processes, including periodic, paliperidone and continuous process. Suitable ministeria modification of the catalyst (formula 1) can be obtained in accordance with the General Protocol described in the examples and references. Modification of the specified catalyst containing oxaziridine ring, can be obtained by contacting ministeriosa modify the purpose of this catalyst carrier of oxygen, for example peroxycarbonates acid or proximodorsal acid. Such substances can be formed and used without purification.

Cleaning compositions and additives to detergent compositions containing organic catalysts of the applicant

The cleaning composition of the present invention can be used, for example, when washing clothes, cleaning hard surfaces, in automatic dishwashing machines, as well as in cosmetic use, such as dentures, teeth, hair and skin. However, due to unique advantages such as improved efficiency at lower temperatures of the solution, and excellent compatibility with enzymes, organic catalysts of the present invention are ideal for use in washing, for example in the bleaching of fabrics using a detergent that contains bleach or washing additives containing bleach. In addition, the organic catalysts of the present invention can be used both in granular and liquid formulations.

The organic catalysts of the present invention can also be applied in the cleaning additives. Detergent additive comprising an organic catalysts of the present invention, is ideally suited for introduction into the washing process in the case of the AE, if it is desirable to achieve additional bleaching effectiveness, for example, but not limited to, when cleaning in solution at low temperature. In its simplest form, this additive may be an organic catalyst of the applicant. Preferably, the additive may be packaged in a unit dosage form to be added to the cleaning process where the source is used percolated and it is desirable to increase the efficiency of bleaching. Such unit dosage form can contain a pill, tablet, measured with a gel or another individual dosage unit, such as a pre-measured powders or liquids. To increase the amount of such a composition may include a filler or carrier. Suitable material carrier or excipient includes, but is not limited to, various salts of sulfate, carbonate and silicate, and talc, alumina and the like. The materials of the carrier or filler for liquid compositions may be water or a low molecular weight primary or secondary alcohols, including diols and polyols. Examples of such alcohols include, but are not limited to, methanol, ethanol, propanol and isopropanol. The composition can contain from about 5% to about 90% of such materials. To lower the pH can be used acid fillers. Alternatively, brushing the traveler additive may include activated source barkisland, defined hereinafter, or auxiliary ingredients, as fully defined below.

Cleaning compositions and cleaning additives applicant require a catalytically effective amount of the organic catalyst of the applicant. The required level of such a catalyst can be achieved by adding one or more substances of the organic catalyst of the applicant. Practically but not to limit, the compositions and cleaning methods disclosed herein may contain of the order of at least 0.001 parts per million (h/mn)from about 0,001 h/m to about 500 h/mn, from about 0,005 h/m to approximately 150 hours/million, or even from approximately 0.05 h/m to about 50 hours/million organic catalyst of the applicant in the scrubbing liquid. To obtain such levels in the scrubbing liquid is considered typical compositions can contain from about is 0.0002% to about 5%, or even from about 0,001% to about 1.5% organic catalyst by weight of the cleaning compositions.

When the organic catalyst of the applicant is used in granular compositions, it may be desirable that the organic catalyst of the applicant had the appearance of an encapsulated particle to protect the organic catalyst of the applicant from moisture and (or) other components of the granular composition during storage. In addition, encapsulation is also the only means of controlling the availability of the organic catalyst of the applicant in the cleaning process and may enhance the effectiveness of the bleaching of the organic catalyst of the applicant. In this regard, the organic catalyst of the applicant may be encapsulated by any known encapsulating material.

The encapsulating material typically encapsulates at least part, and preferably all organic catalyst of the applicant. Typically, the encapsulating material is water-soluble and (or) water-dispersible material. The encapsulating material may have a glass transition temperature (Tg) 0°C or higher.

Preferably, the encapsulating material is selected from the group consisting of carbohydrates, natural or synthetic resins, chitin and chitosan, cellulose and its derivatives, silicates, phosphates, borates, polyvinyl alcohol, polyethylene glycol, paraffin waxes, and combinations thereof. Preferably, the encapsulating material is a carbohydrate, usually selected from the group consisting of monosaccharides, oligosaccharides, polysaccharides, and combinations thereof. More preferably, the encapsulating material is a starch. Preferred starches are described in EP 0922499, US 4.977.252, US 5.354.559 and US 5.935.826.

The encapsulating material may be a microspheres made from plastics, such as thermoplastics, Acrylonitrile, Methacrylonitrile, polyacrylonitrile, polymethacrylates and mixtures thereof; commercially available microspheres that are supplied under the brand Expance® from Expancel of Stockviksverken, Sweden, and microspheres supplied under the brands PM 6545, PM 6550, PM 7220, PM 7228, Extendospheres®, Luxsil®, Q-cel® and Sphericel® from PQ Corp., Valley Forge, Pennsylvania, USA.

The cleaning compositions of the present invention are preferably made so that during use in aqueous medium pH was between about 6.5 and about 11, or even between about 7.5 and 10.5. Liquid compositions for washing dishes can have a pH between about 6.8 and about to 9.0. Products for washing usually have a pH from about 9 to about 11. Methods of regulating the pH within the recommended range of use include the use of buffers, alkalis, acids, etc. and is well-known to specialists in this field.

Auxiliary materials

Although for the purposes of the present invention it is not essential, the following non-limiting list of excipients, which are suitable for use in the compositions of the present invention and may, if desired, be included in some embodiments of the invention, for example, to facilitate or enhance the cleaning effect, for processing to be cleaned of the substrate or to change the aesthetic component of the cleaning composition, as is the case with perfumes, dyes, coloring agents and the like, the Precise nature of these additional components, and levels of their content will be is dependent on the physical form of the composition and nature of cleaning operations, in which they are used. Suitable support materials include, but are not limited to, surfactants, core components, chelating agents, inhibitors of migration painting, dispersants, enzymes, and enzyme stabilizers, catalytic materials, bleach activators, hydrogen peroxide, sources of hydrogen peroxide, pre-formed percolate, polymeric dispersing agents, preventing re-deposition agents removal of the mineral soil pollution, bishopshostel, defoamers, dyes, perfumes, agents for elasticity patterns, fabric softeners, carriers, hydrotropes improving machinability additives, solvents and / or pigments. In addition to those described below, suitable examples of other such auxiliary substances and the levels of their use are given in U.S. patent No. 5.576.282, 6.306.812 B1 and 6.326.348 B1, which are incorporated here by reference.

As mentioned previously, the auxiliary ingredients are not required for the compositions of the applicant. Therefore, some embodiments of the compositions of the applicant do not contain one or more of the following supporting materials: surfactants, main components, chelating agents, inhibitors of migration painting, dispersant, which can and stabilizers, enzymes, catalytic materials, bleach activators, hydrogen peroxide, sources of hydrogen peroxide, pre-formed perkiset, polymeric dispersing agents, preventing re-deposition agents removal of the mineral soil pollution, bishopapostles, defoamers, dyes, perfumes, agents for elasticity patterns, fabric softeners, carriers, hydrotropes improving machinability additives, solvents and / or pigments. However, when one or more auxiliary materials are present, such one or more auxiliary materials may be submitted as described below.

Bleach: cleaning compositions of the present invention can contain one or more bleach. Suitable bleaches, other than the bleach catalysts include fotoatelier, bleach activators, hydrogen peroxide, sources of hydrogen peroxide, pre-formed percolate and mixtures thereof. In General, when using bleach compositions of the present invention can contain from about 0.1% to about 50% or even from about 0.1% to about 25% bleach from the masses consider cleaning composition. Examples of suitable brighteners include:

(1) fotoatelier, for example Sultonov the natural zinc phthalocyanine;

(2) pre-formed percolate. Suitable pre-formed percolate selected from the group consisting of percarbonic acids and salts, peroralnyh acids and salts, perekidnyh acids and salts, peroxymonosulfuric acids and salts, for example Oxzone®, and mixtures thereof. Suitable percarbonate acids include hydrophobic and hydrophilic percolate having the formula R-(C=O)o-O-M, where R represents an alkyl group, optionally branched, having, when percolate hydrophobic, from 6 to 14 carbon atoms, or from 8 to 12 carbon atoms, and if percolate hydrophilic, less than 6 carbon atoms or even less than 4 carbon atoms; and M is a counterion, such as sodium, potassium or hydrogen;

(3) sources of hydrogen peroxide, for example, inorganic perrykaty, including alkali metal salts, such as perborate sodium (usually mono - or tetrahydrate), percarbonates, persulfates, perphosphate, prsilikat and mixtures thereof. One object of the invention inorganic perrykaty selected from the group consisting of sodium salts of perborate, percarbonate and mixtures thereof. Usually, inorganic perrykaty are used in quantities of from 0.05 to 40 wt.%, or 1 to 30 wt.% by weight of the total composition and, as a rule, included in such compositions in the form of a crystalline solid phase, which may be caused to the coating is. Suitable coatings include inorganic salts such as silicates, carbonates or borates of alkali metals or mixtures thereof, or organic materials, for example, water-soluble or water-dispersible polymers, waxes, oils or fatty soap; and

(4) the bleaching activators, with R-(C=O)-L, where R is an alkyl group, optionally branched, having, when the bleaching activator is hydrophobic, from 6 to 14 carbon atoms, or from 8 to 12 carbon atoms, and if the bleaching activator hydrophilic, less than 6 carbon atoms or even less than 4 carbon atoms; and L is a leaving group. Examples of suitable leaving groups are benzoic acid and its derivatives, especially bansilalpet. Suitable bleach activators include sulfonate dodecanoate, sulfonate decanolactone, technologiesin acid and its salts, sulfonate 3,5,5-trimethylhexanoate, tetraacetyl diamine (TAED) and sulfonate nonenvironmental (NOBS). Suitable bleach activators are disclosed in the publication WO 98/17767. Although it is allowed to use any bleach activators, one object of the present invention under consideration, the cleaning compositions can contain NOBS, TAED or mixtures thereof.

Percolate and (or) a bleaching activator, if any, generally are present in the composition in amount the t of about 0.1 to about 60 wt.%, from about 0.5 to about 40 wt.%, or even from about 0.6 to about 10 wt.% in the calculation of the composition. One or more hydrophobic perkiset or their precursors can be used in combination with one or more hydrophilic percolate, or their predecessor.

Number source of hydrogen peroxide and percolate or bleaching activator may be selected so that the molar ratio of available oxygen (peroxide source) to percolate is from 1:1 to 35:1, or even 2:1 to 10:1.

Surface-active substances (surfactants): cleaning compositions in accordance with the present invention may contain a surfactant or surfactants, and surfactants may be selected from nonionic, anionic, cationic, ampholytic, zwitterionic, polupryamykh nonionic surfactants and mixtures thereof. If present, the surfactant is typically present in amount from about 0.1% to about 60%, from about 1% to about 50% or even from about 5% to about 40% by weight of the considered composition.

The main components of the cleaning compositions of the present invention may contain one or more major components or major systems of detergents. When using the main component of its content in the composition is typically at least about 1%, from about 5% to approx the RNO 60%, or even from about 10% to about 40% by weight of the considered composition.

Major components include, but are not limited to, salts of alkali metals, ammonium and alkanolammonium salts of polyphosphates, alkali metal silicates, carbonates, alkaline earth and alkali metal aluminosilicate components and polycarboxylate compounds, ethers of hydroxypolycarboxylic, copolymers of maleic anhydride with ethylene or vinylmation ether, 1,3,5-trihydroxybenzene-2,4,6-trisulphonate, and carboxymethylcysteine acid, salts of various alkali metal, ammonium and substituted ammonium salts polixeni acids, such as ethylenediaminetetraacetic acid and microtrusses acid, as well as such polycarboxylate as malletova acid, succinic acid, citric acid, accidentally acid, primulina acid, benzene-1,3,5-tricarboxylic acid, carboxymethylcysteine acid, and soluble salts.

Chelating agents: consider the cleaning composition may contain a chelating agent. Suitable chelating agents include chelating agents, copper, iron and / or manganese, and mixtures thereof. When using a chelating agent, its content in the composition can range from about 0,005% to about 15%, or even from when is Erno 3.0% to about 10% by weight of the composition.

Preventing migration of the dye agents: consider cleaning compositions can also include one or more of preventing migration of the dye agents. Suitable polymeric agents include, but are not limited to, polymers, polyvinylpyrrolidone, polymers of N-oxindolimine, copolymers of N-vinylpyrrolidone and N-vinylimidazole, polivinilatsetatny and polyvinylimidazole, and mixtures thereof. When using preventing migration of the dye agents, their content in the composition can range from about 0,0001% to about 10%, from about 0.01% to about 5%, or even from about 0.1% to about 3% by weight of the composition.

Bishopshostel: consider the cleaning compositions of the present invention may also contain additional components that modify the intensity of the color of cleaned products, for example, fluorescent bishopshostel. Levels of suitable fluorescent bishopapostles include lower limits from a maximum of approximately to 0.01, from about 0.05 to about 0.1 wt.%, or even from about 0.2 wt.% to an upper limit of 0.5 or even 0.75 wt.%.

Dispergator: composition of the present invention can also contain dispersants. Suitable water-soluble organic materials include Homo - or copolymer to the slots or their salts, in which the polycarboxylic acid comprises at least two carboxyl radicals separated from each other by no more than two carbon atoms.

Enzymes: cleaning compositions can contain one or more enzymes which provide cleaning effect and / or benefits in fabric care. Examples of suitable enzymes include, but are not limited to, hemicellulase, peroxidase, protease, cellulase, xylanase, lipase, phospholipase, esterase, cutinase, pectinase, mannanase, pectin-LiAZ, keratinase, reductase, oxidase, peroxidase, lipoxygenase, ligninase, pullulanase, tannaz, pentosanase, Malagasy, β-glucanase, arabinosidases, hyaluronidase, chondroitinase, laccase, amylases, and mixtures thereof. The usual combination is a mixture of enzymes, which may contain, for example, protease and lipase in combination with amylase. If the above enzymes are present in the cleaning composition, the protein content of the above-mentioned enzymes may be from about 0.00001% to about 2%, from 0.0001% to about 1%, or even from about 0,001% to about 0.5% by weight of the composition.

Stabilizers enzymes for use in detergents enzymes can be stabilized by various techniques. Used in the present invention, the enzymes can be stabilized in the presence of vocarstvo imih sources of calcium ions and / or magnesium in the final compositions, containing these ions. In the case of aqueous compositions, containing a protease, for additional stability can be added reversible protease inhibitor, for example, boron compound.

The catalytic metal complexes: cleaning compositions of the applicant may include catalytic metal complexes. One type of metal-containing catalysts whitening is a catalytic system containing a transition metal cation with a particular bleaching activity, for example, copper, iron, titanium, ruthenium, tungsten, molybdenum, or manganese cations auxiliary metal having a small whitening activity or not having it at all, for example, the cation of zinc or aluminum, and a binder having defined stability constants for the catalytic and auxiliary metal cations, particularly ethylenediaminetetraacetic acid, ethylenediaminetetra(methylenephosphonic acid and their water soluble salts. Such catalysts are described in U.S. patent No. 4.430.243.

If desired, the compositions of the present invention can be catalyzed by manganese compounds. Such compounds and levels of their content are well known in the art and include, for example, catalysts based on manganese, described in U.S. patent No. 5.576.282.

Known Koba is towie catalysts whitening suitable for the present invention, and are described, for example, in U.S. patent No. 5.597.936 and 5.595.967. Such cobalt catalysts are readily obtained by known procedures, as for example shown in U.S. patent No. 5.597.936 and 5.595.967.

The compositions of the present invention can also include a complex of the transition metal with ligands, as bispinosa (see WO 05/042532 A1), and (or) macrocyclic rigid ligands, referred to as "MRL". In practice - but not by limiting compositions and methods of the present invention can be adjusted to contain at least one part per million of the active MRL-component in the washing water, and generally provide from about 0,005 h/m to about 25 hours/million, from approximately 0.05 h/m to about 10 hours/million, or even from about 0.1 h/m to about 5 hours/million MRL in the washing solution.

Suitable transition metals in the bleach catalysts of the present invention include, for example, manganese, iron and chromium. Suitable MRL include 5,12-diethyl-1,5,8,12-tetraazabicyclo-[6.6.2]hexadecane.

Suitable MRL with transition metal are easily derived using well-known procedures, e.g. as described in WO 00/32601 and US 6.225.464.

Solvents: suitable solvents include water and other solvents, such as lipophilic fluid. Note the market suitable lipophilic fluids include siloxanes, other silicones, hydrocarbons, glycol ethers, derivatives of glycerol, such as esters of glycerine, perfluorinated amines, perfluorinated and hydrotherapie solvents, low-volatile non-fluorinated organic solvents, diol solvents, and other eco-friendly solvents, and mixture.

Methods of making the cleaning compositions and / or compositions for processing

The cleaning compositions of the present invention can be prepared in any suitable form and obtained by any method chosen by the experimenter; non-limiting examples of such methods are given in the examples of the applicant and in U.S. patent No. 5.879.584, 5.691.297, 5.574.005, 5.569.645, 5.565.422, 5.516.448, 5.489.392, 5.486.303, which are all incorporated here by reference.

Method of use

The present invention includes a method of cleaning including land surface or fabric. This method includes the steps at which contact the cleaning composition of the applicant, in pure form or in the form of a diluted aqueous solution with at least part of a surface or fabric, and then optionally rinsed specified surface or fabric. Surface or the fabric may be subjected to a washing step up to the specified stage rinsing. For the purposes of the present invention flushing includes - but is not limited to this processing, the Otti is a W and mechanical agitation. As will be appreciated by the person skilled in the art, the cleaning compositions of the present invention is ideal for washing clothes. Accordingly, the present invention includes a method of washing fabric. This method includes the steps where: contact to be washing the fabric with the said cleaning washing solution containing at least one variant of implementation of the cleaning compositions of the applicant, the cleaning additive of the applicant or their mixture. The fabric can contain almost any fabric capable of washing in the normal user conditions. The solution preferably has a pH from about 8 to about 10.5V. Song data can be used at concentrations in the solution is from about 500 h/m to about 15000 hours/million water Temperature is usually in the range from 5°C to 90°C. the Ratio of water/fabric typically ranges from about 1:1 to about 30:1.

Test the compatibility of the organic catalyst and enzyme

The following test uses the test activity of alpha-amylase to measure the impact of organic catalyst on the enzyme.

Equipment: spectrophotometer UV/visible range, capable of measuring at 415 nm; magnetic stirrer, heated to 40°C, 5 ml syringe with Swarovski nozzle and filters (Acrodisc 0.45 μm), pH meter and a scale (analytical, 4 digits).

Reagents: n the boron amylase from Merck (Merck Eurolab, part No. 1.19718.0001); Trizma base (Sigma, cat no.T-1503 or equivalent); two-water calcium chloride (Sigma, cat no.C-5080 or equivalent); pytevodniy sodium thiosulfate (Sigma, cat no.S-6672 or equivalent); hydrochloric acid (VWR cat no.JT9535-0 or equivalent); solution rigidity (group CTC, 3.00 g/cm3or equivalent); percarbonate sodium; peracetic acid (Aldrich, cat no.26933-6 or equivalent); the enzymes amylase: termamyl, natalise and durabil (Novozymes, Denmark); the matrix of granular detergent that does not contain enzymes, organic catalysts or bleaching agents.

1) preparation of the solution:

a) Test the TRIS buffer. Prepare 1 l of 0.1 M TRIS-buffer, 0,5% sodium thiosulfate (wt./vol.), 0,11% calcium chloride (wt./about.) at pH 8.3.

b) Control the detergent solution. Prepare 1 l of 0.5% enzyme and does not contain bleach granulated detergent in deionized water (wt./vol.), which is a 250 h/m H2About2(0,77 g percarbonate), and stiffness 10 gpg (rigidity 880 U1).

C) the Supply of termamyl, Urmila and natality. Prepare 100 ml of solutions containing 0,1633 mg active termamyl per ml TRIS-buffer, 0,1159 mg active natality per ml TRIS-buffer, and 0,1596 mg active duramale per ml of TRIS buffer.

g) Inventories organic catalyst. Prepare 500 hours/million in a solution of methanol in µm.

d) Supply of peracetic acid is you. Prepare a solution 3955 hours/million peracetic acid in deionized water.

(e) amylase Reagent. Follow the instructions set by Merck for the preparation of vials 1 and 2 use the vial 3, followed by stirring vials 1 and 2 by the end of the reagent used in the analysis of amylase activity.

2) Analysis of samples:

a) Analysis of the sample containing only the enzyme: add 100 ml of control solution of the detergent in 150 ml measuring Cup. Place the beaker on the hot mixer and bring the temperature up to 40°C under stirring. In a glass add Y ál of stock enzyme, where Y=612 μl duramale, 306 μl of termamyl or 918 ál natality. Mark only the desired enzyme. Mix the sample for 1 minute. Start the timer. After 7 min 45 sec remove the sample and filtered using 0.45 μm syringe filter (5 ml syringe). Mix 6 ál of the filtered sample with 250 μl of amylase reagent in the cuvette and place the cuvette in a UV/view. spectrophotometer and see the changes in absorbance at 415 nm. Determine with precision the length of time (tErequired to obtain the reference absorption of 1.0 for each enzyme. Use the tEfor each enzyme in stages 2B and 2C, are shown below.

b) Analysis of the sample only to the enzyme and peracetic acid. Repeat e is AP 2A) except after adding the enzyme solution allow to mix for 1 minute, then add 127 μl stock peracetic acid and start the timer. Remove the sample after 7 min 45 sec, as in step 2A). When the sample and the reagent are mixed, record the absorbance at tEfor the corresponding enzyme. This absorption indicate Ab.

in the Analysis of the sample with the enzyme, peracetic acid and an organic catalyst. Repeat step 2A) except that after adding the enzyme solution was left to mix for 1 minute, then add stock 127 ál of peracetic acid and a stock of 100 µl of the organic catalyst and include a timer. After 7 min 45 sec sample is removed, as in step 2A). Mixing the sample and reagent, record the absorbance at tEfor the corresponding enzyme. Denote this absorption as awith.

3) Calculate the magnitude of the compatibility of the enzyme (ECV):

a) Calculation of ECV for each specific enzyme: termamyl (ECVter), duramale (ECVdurand natality (ECVnat). Value ECV for any particular enzyme is (Awith/Ab)×100, where awithand Ab- the values defined in stages 2B and 2B), respectively, for a given enzyme.

b) ECV for selected organic catalyst is the average of the individual values ECV d is I the three enzymes. Therefore, ECV=(ECVter+ECVdur+ECVnat)/3.

EXAMPLES

Unless otherwise specified, the materials can be obtained from the firm Aldrich, P.O. Box 2060, Milwaukee, WI53201, USA.

Example 1: retrieving internal salt of 3,4-dihydro-4,4-dibenzyl-2-(3-sulfopropyl)skinline

Step 1. Obtaining α,α-dibutylaminoethanol (2): calcined three-neck round bottom flask with a capacity of 500 ml, equipped with a feed inlet for dry argon, magnetic michaelem and thermometer, add 5.0 g (0,043 mol) of benzylcyanide (1) and 100 ml of tetrahydrofuran. React slowly, over hours, injected 7.2 g (0,1075 mol) of sodium hydride (60% in oil). After the addition was finished the reaction mixture was stirred at room temperature for 1 hour. To the reaction mixture of 18.4 g (0,043 mol) of benzylbromide and stirred at 50°C for 18 hours. The mixture is evaporated to dryness, the residue dissolved in toluene and washed with 1N HCl. The organic phase is dried over Na2SO4, filtered and evaporated to obtain α,α-dibutylaminoethanol (2), the output of 7.7 g (65%).

Step 2. Obtain 1-amino-2,2-dibutil-2-phenylethane (3): 7 g (0,0237 mol) of α,α-dibutylaminoethanol (2) is dissolved in 1.1 equiv. complex, borane-THF at room temperature for 18 hours. At the end of the interaction add 50 ml of ethanol and the mixture is evaporated to dryness. After evaporation of the people headed the remainder are suspended in 100 ml of 1N HCl and the suspension evaporated to dryness on a rotary evaporator. This procedure was repeated three times. After the last evaporation a white residue is dissolved in 100 ml 1N NaOH and extracted with diethyl ether (2×150 ml). The extracts are combined, dried over Na2SO4, filtered and evaporated to dryness to obtain 6.4 g of 1-amino-2,2-dibutil-2-phenylethane (3) (yield 90%).

Step 3. Obtaining 3,4-dihydro-4,4-dibenzoylethylene (5): calcined three-neck round bottom flask with a capacity of 100 ml, equipped with an additional funnel, an inlet for dry argon, magnetic michaelem, a thermometer, a trap Dean-stark and heating bath, add 5.0 g (0,0166 mol) of 1-amino-2,2-dibutil-2-phenylethane (3) and 25 ml of toluene. In an additional funnel add 5.0 g of formic acid. Formic acid was added to stir the reaction mixture slowly, over 60 minutes, thereby forming a solid substance. After complete addition, the reaction mixture is subjected to distillation with reflux condenser and using traps Dean-stark water is removed. Upon completion of the reaction remove the toluene and obtain 4.9 g of N-formyl-β,β-dibutil-β-phenethylamine (4) (yield 90%). Formamid (4) then leads in the interaction with 30 g of polyphosphoric acid/6 g phosphorus pentoxide, using conditions Bichler-Napieralski, for 18 hours at 170°C. Then the reaction mixture was neutralized with an aqueous solution of NaOH, keeping the temperature between 60 and 0°C. After neutralization, the product is extracted with toluene to obtain 3,4-dihydro-4,4-dibenzoylethylene (5). Further product can be purified on silica gel.

Step 4. Get the internal salt of 3,4-dihydro-4,4-dibenzyl-2-(3-sulfopropyl)skinline (6): calcined three-neck round bottom flask with a capacity of 100 ml add 3.0 g (0,010 mol) of 3,4-dihydro-4,4-dibenzoylethylene (5) and 25 ml of acetonitrile. The solution was stirred at room temperature in an argon atmosphere and the solution is added to 1.34 g (to 0.011 mol) of 1,2-oxathiolane-2,2-dioxide. The mixture is heated to 50°C. and stirred for 18 hours. The reaction mixture is cooled to room temperature and left overnight at room temperature. The formed solid substance was separated by filtration and washed with cold acetonitrile, receiving 3,4-dihydro-4,4-dibenzyl-2-(3-sulfopropyl)skinline (6).

Example 2: retrieving internal salt of 3,4-dihydro-4,4-dipentyl-2-(3-sulfopropyl)skinline

The desired product is obtained in accordance with Example 1, replacing in stage 1 benzylchloride pantellaria.

Example 3: retrieving internal salt of 3,4-dihydro-4,4-dihexyl-2-(3-sulfopropyl)skinline

The desired product is obtained in accordance with Example 1, replacing in stage 1 benzylchloride vexillaria.

Example 4: obtaining internal salt of 3,4-dihydro-4,4-dibutil-2-(3-solopr who drank)skinline

The desired product is obtained in accordance with Example 1, replacing in stage 1 benzylchloride butyl chloride.

Example 5: receiving the internal salt of 3,4-dihydro-4,4-di(2-methylphenylethyl)-2-(3-sulfopropyl)skinline

The desired product is obtained in accordance with Example 1, replacing in stage 1 benzylchloride 2-methylbenzylamino.

Example 6: get the internal salt of 3,4-dihydro-4,4-di(3-methylphenylethyl)-2-(3-sulfopropyl)skinline

The desired product is obtained in accordance with Example 1, replacing in stage 1 benzylchloride 3-methylbenzylamino.

Example 7: get the internal salt of 3,4-dihydro-4,4-di(4-methylphenylethyl-2-(3-sulfopropyl)skinline

The desired product is obtained in accordance with Example 1, replacing in stage 1 benzylchloride 4-methylbenzylamino.

Example 8: get the internal salt of 3,4-dihydro-4,4-di(cyclohexylmethyl)-2-(3-sulfopropyl)skinline

The desired product is obtained in accordance with Example 1, replacing in stage 1 benzylchloride chloromethylketone (obtained from cyclohexanemethanol according Soy et al., Polyhedron 1992, 11(24), pp.3123-8).

Example 9: getting internal salt of 3,4-dihydro-4,4-di(phenylmethyl)-2-(3-sulfobutyl)skinline

The desired product is obtained in accordance with Example 1, replacing in stage 4 1,2-oxathiane-2,2-dioxide, 1,2-oxathiolane-2,2-dioxide.

Example 10:getting internal salt of 3,4-dihydro-4,4-di(phenylmethyl)-2-[3-(sulfoxy)ethyl]skinline

The desired product is obtained in accordance with Example 1, replacing in stage 4 1,3,2-dioxathion-2,2-dioxide, 1,2-oxathiolane-2,2-dioxide.

Example 11: obtain internal salt of 3,4-dihydro-4,4-di(phenylmethyl)-2-[3-(sulfoxy)propyl]skinline

The desired product is obtained in accordance with Example 1, replacing in stage 4 1,3,2-dioxathion-2,2-dioxide, 1,2-oxathiolane-2,2-dioxide.

Example 12: getting internal salt of 3,4-dihydro-4,4-di(4-methylphenylethyl)-7-methyl-2-(3-sulfopropyl)of isoquinoline

Step 1: Obtain 4-methyl-α-(4-were)-α-[(4-were)methyl]-benzoylpropionate.

Part A. Obtaining a silica-containing catalyst: silicon oxide (MKS-500, the specific surface area of 497 m2/g, from Nikki Chemical) activate the processing of 6N HCl and dried in vacuum at 120°C. a Mixture of 7.0 g of activated silica gel and 80 ml of toluene are placed in a flask and stirred for 1 hour. Then the syringe is injected 25 ml of N-(2-amino-ethyl)-3-aminopropyltrimethoxysilane (SH-6020, by Troy Silicone) and the resulting mixture is distilled under reflux on an oil bath for 8 hours. After cooling, the silica gel is filtered off and washed with benzene in a Soxhlet within 12 hours. The purified silicon oxide even 3 times washed with diethyl ether and left overnight in the air. One gram of purified silicon dioxide is then suspended in 1.5 ml of dioxane for 8 the Asses, then add 4.3 ml of 1,10-dibromodecane and the mixture was stirred at 80°C overnight on an oil bath. Then filtered silicon oxide on a glass filter and washed with dioxane, acetone and 1% NH4OH, and then sequentially washed with acetone and diethyl ether. Thus obtained silicon oxide is dried at 50°C under reduced pressure overnight.

Part B. Getting 4-methyl-α-(4-were)-α-[(4-were)methyl]-benzoylpropionate. Into a flask containing 1.0 g (2 mmol) of sodium cyanide (95%), dissolved in 5 ml of 50% aqueous NaOH solution, contribute 0.3 g of a catalyst based on oxides of silicon, then to 6.8 mmol chloride 4-methylbenzyl and 1 ml of toluene. The flask is put in an oil bath and heated for 48 h at 40°C under stirring, then add 10 ml of toluene. Filtered organic layer, and the filtrate is evaporated to obtain 4-methyl-α-(4-were)-α-[(4-were)methyl]-benzoylpropionate.

Step 2. Getting 4-methyl-α-(4-were)-α-[(4-were)methyl]-benzoylpropionate: the desired product is obtained in accordance with example 1, step 2, substituting α,α-dibutylaminoethanol 4-methyl-α-(4-were)-α-[(4-were)methyl] -benzoylpropionate.

Step 3. Obtaining 3,4-dihydro-4,4-di(4-methylphenylethyl)-7-methyl-isoquinoline: the desired product is obtained in accordance with example 1, stage 3, C is changing 1-amino-2,2-dibutil-2-Penilaian 4-methyl-α-(4-were)-α-[(4-were)methyl]-benzoylpropionate.

Step 4. Get the internal salt of 3,4-dihydro-4,4-di(4-methylphenylethyl)-7-methyl-2-(3-sulfopropyl)of isoquinoline: the desired product is obtained in accordance with example 1, step 4, substituting 3,4-dihydro-4,4-dibenzyl-isoquinoline 3,4-dihydro-4,4-di(4-methylphenylethyl)-7-methylisoquinoline.

Example 13: retrieving internal salt of 3,4-dihydro-4,4-di(4-isopropylphenyl)-7-isopropyl-2-(3-sulfopropyl)of isoquinoline

The desired product is obtained in accordance with Example 1, replacing chloride 4-methylbenzyl chloride 4-isopropylbenzyl.

Example 14: simultaneous production of a mixture of organic catalyst containing catalysts of formula 3, where R1independently represents H, methyl, ethyl and mixtures thereof

The desired mixture is formed according to example 12 when replacing chloride 4-methylbenzyl mixture benzylchloride (source for R1=N), chloride 4-methylbenzyl (source R1=methyl) and chloride 4-ethylbenzyl (Oakwood Products Inc., West Columbia, SC 29172, USA; source for R1=ethyl). This leads to a mixture of 18 compounds, various organic catalysts.

Example 15

Bleaching detergent compositions having the form of a granulated washing detergent is represented by the following structures:

td align="center"> In
AndDEF
Line Las202220152020
With12dimethylhydroxylamine chloride0,7110,60,00,7
AE3S0,90,00,90,00,00,9
AE0,00,50,0131
Sodium tripolyphosphate233023171223
Zeolite And0,0 0,00,00,0100,0
1.6 has been released Silicate777777
Sodium carbonate151415181515
Polyacrylate MW 450010,0111,51
Carboxymethylcellulose111111
Savinase 32,89 mg/g0,10,070,10,10,10,1
Natalise 8,65 mg/g0,1 0,10,10,00,10,1
Bishopshostel 150,060,00,060,180,060,06
Bishopshostel 490,10,060,10,00,10,1
Diethylenetriaminepentaacetic acid0,60,30,60,250,60,6
MgSO41110,511
Percarbonate sodium0,05,20,10,00,00,0
Fotoatelier 0,00300,00150,00150,00200,00450,0010
The perborate monohydrate sodium4,40,03,852,090,783,63
NOBS1,91,91,661,770,330,75
TAED0,580,580,510,00,0150,28
Organic catalyst*0,01850,01850,01620,01620,01110,0074
Sulfate/wetup to 100%up to 100%up to 100%up to 100%up to 100%up to 100%
* Organic catalyst obtained in accordance with Examples 1 to 14, or mixtures thereof

Any of the above composition is used for washing fabrics at a concentration in the water 3500 hours/million, 25°C and the ratio of water:clothing 25:1. Usually the pH is about 10, but can be adjusted by changing the ratio of acid to Las in the form of Na-salt.

Example 16

Bleaching detergent compositions having the form of a granulated washing detergent is represented by the following structures:

AndInD
Line Las87,176,5
AE3S04,805,2
Alkylsulfate1010
AE2,203,2 0,1
With10-12dimethylhydroxylamine chloride0,750,940,980,98
Crystalline layered silicate (δ-Na2Si2O5)4,104,80
Zeolite And200170
Citric acid3534
Sodium carbonate15201420
Silicate 2R (SiO2:Na2O in the ratio 2:1)0,0800,110
Dirt repellent agent0,750,720,710,72
Copolymer of acrylic acid is/maleic acid 1,13,71,03,7
Carboxymethylcellulose0,151,40,21,4
Protease (56,00 mg active substance/g)0,370,40,40,4
Amylase (21,55 mg active substance/g)0,30,30,30,3
Lipase (11,00 mg active substance/g)00,700,7
Tetraacetylethylenediamine (TAED)3,64,03,64,0
Percarbonate1313,21313,2
Organic catalyst*0,040,02 0,010,06
Na-salt ethylendiamine-N,N'-dinternal acid, (S,S-isomer) (EDDS)0,20,20,20,2
Hydroxyethylphosphonate (HEDP)0,20,20,20,2
MgSO40,420,420,420,42
Perfume0,50,60,50,6
Sinter suppressor foam0,050,10,050,1
Soap0,450,450,450,45
The sodium sulfate22332430
From sulphonated phthalocyanine zinc 0,070,120,070,12
Fotoatelier0,00140,0020,00140,001
Inclusions0,030,050,030,05
Water, etc.up to 100%up to 100%up to 100%up to 100%
* Organic catalyst obtained in accordance with Examples 1 to 14, or mixtures thereof

Any of the above composition is used for washing fabrics at a concentration in water of 10,000 hours/million, 20-90°C and the ratio of water:clothing 5:1. Usually the pH is about 10, but can be adjusted by changing the ratio of acid to Las in the form of Na-salt.

Example 17

Bleaching detergent compositions having the form of a granulated washing detergent is represented by the following structures:

0,30
AndInWith DEF
Line Las19,015,020,019,018,0of 17.5
Alkylsulfate1D1,00,81,01,11,2
AE3S0,30,20,0ML0,30,5
Polyacrylic acid, partially neutralized6,05,57,57,05,86,0
Ecological sodium*1,51,92,01,71,51,0
PEG 40000,3 0,250,350,150,20,10
Bishopshostel 49000,320,040,040,16
Bishopshostel 15000,680,080,080,32
Moisture2,502,002,902,202,401,80
Sodium carbonate20,0of 17.521,020,219,018,0
The sodium sulfate0,200,300,500,300,450,10
Sodium silicate 0,250,550,300,250,10
Crystalline layered silicate of formula δ-Na2Si2O52,73,02,23,71,51,0
Zeolite And11,011,012,510,29,58,0
Protease0,200,501,00,150,400,0
Silicone foam suppressor0,400,351,000,600,500,00
Lumpy sulfatea 21.523,021,021,020,0 18,5
The reaction product amine containing δ-Damascan****0,400,250,100,350,600,00
Perfume0,100,300,200,200,400,50
Percarbonate sodium2,84,52,00the 4.77,410,0
Traditional activator (NOBS)2,103,71,003,05,010,0
Organic catalyst**0,0050,101,000,250,050,05
Potenital***0,500,201,000,100,00
Fillerup to 100%up to 100%up to 100%up to 100%up to 100%up to 100%
*Can also be used other hydrotropes, such as toluensulfonate
**Organic catalyst obtained in accordance with Examples 1 to 14, or mixtures thereof
***Such as Ultramarine Blue or Azo-CM-Cellulose (Megazyme, Bray, Co. Wicklow, Ireland)
****Received in accordance with WO 00/02991

Any of the above composition is used for washing fabrics at a concentration in the water 500-1500 hours/million, 5-25°C and the ratio of water:clothes 15:1-25:1. Usually the pH is about 9.5 to 10, but can be adjusted by changing the ratio of acid to Las in the form of Na-salt.

Example 18

Listed below are organic catalysts tested in accordance with test compatibility of the organic catalyst of the present invention and the enzyme using: [peracetic acid] = 5,0 h/m; [organic catalyst] = 0.5 hours/million, with the receipt of the trail is proposed results:

Position***Fragments of catalyst R2; GThe value of compatibility with enzyme
ECVterECVdurECVnatECV
1No data51865865
2No data54905767
3Benzyl; -O-101100103101
4Benzyl; CH2-10299104102
54-Methyl-benzyl; -CH2-1039999 100
*Positions 1 and 2 - internal salt of mono-[2-(3,4-dihydroisoquinoline-2-yl)-1-((1,1-dimethylmethoxy)methyl)ethyl]ether sulfuric acid and the internal salt of mono-[2-(3,4-dihydroisoquinoline-2-yl)-1-(2-ethylhexyloxymethyl)-ethyl]ester of sulfuric acid, respectively, which are not covered by Formulas 1 and 2 of the applicant
**R1represents H for items 3-5

For professionals it is obvious that the described and illustrated private embodiments of the present invention can be changed and modified without departing from the essence and scope of the present invention. Therefore, all such changes and modifications are included in the scope of the present invention, attached covered by the following claims.

1. A cleaning composition containing:
a) an organic catalyst selected from the group consisting of organic catalysts having the following formula:
(i)
(ii)
(iii) and mixtures thereof;
where G is selected from-O-, -CH2O-, -(CH2)2- and-CH2-, R1selected from N or C1-C4of alkyl, each R2independently selected from C4-C8of alkyl, benzyl, 2-methylbenzyl, 3-methylbenzyl, 4-methylbenzyl, 4-ethylbenzyl, 4-isopropylbenzyl and 4-tert-butylbenzyl; the
b) one or more accessory ingredients.

2. The cleaning composition according to claim 1, wherein G is selected from-O - and-CH2-; R1selected from H, methyl, ethyl, isopropyl and tert-butyl; and each R2independently selected from C4-C6of alkyl, benzyl, 2-methylbenzyl, 3-methylbenzyl and 4-methylbenzyl.

3. The cleaning composition according to claim 2, wherein G represents-CH2-; R1represents H; and each R2independently selected from n-butyl, n-pentile, n-hexyl, benzyl, 2-methylbenzyl, 3-methylbenzyl and 4-methylbenzyl.

4. The cleaning composition according to claim 1, characterized in that it contains an organic catalyst having the following formula:

where G is selected from-O-, -CH2O-, -(CH2)2- and-CH2-, R1selected from N or C1-C4of alkyl, each R2independently selected from C4-C8of alkyl, benzyl, 2-methylbenzyl, 3-methylbenzyl, 4-methylbenzyl, 4-ethylbenzyl, 4-isopropylbenzyl and 4-tert-butylbenzyl.

5. The cleaning composition according to claim 4, wherein G is selected from-O - and - CH2-; R1selected from H, methyl, ethyl, isopropyl and tert-butyl; and each R2independently selected from C4-C6of alkyl, benzyl, 2-methylbenzyl, 3-methylbenzyl and 4-methylbenzyl.

6. The cleaning composition according to claim 5, characterized in that G represents-CH 2-; R1represents H; and each R2independently selected from n-butyl, n-pentile, n-hexyl, benzyl, 2-methylbenzyl, 3-methylbenzyl and 4-methylbenzyl.

7. The cleaning composition according to claim 1, characterized in that it contains an organic catalyst having the following formula:

where G is selected from-O-, -CH2O-, -(CH2)2- and-CH2-, R1selected from N or C1-C4of alkyl, each R2independently selected from C4-C8of alkyl, benzyl, 2-methylbenzyl, 3-methylbenzyl, 4-methylbenzyl, 4-ethylbenzyl, 4-isopropylbenzyl and 4-tert-butylbenzyl.

8. The cleaning composition according to claim 7, wherein G is selected from-O - and - CH2-; R1selected from H, methyl, ethyl, isopropyl and tert-butyl; and each R2independently selected from C4-C6of alkyl, benzyl, 2-methylbenzyl, 3-methylbenzyl and 4-methylbenzyl.

9. The cleaning composition of claim 8, wherein G represents-CH2-; R1represents H; and each R2independently selected from n-butyl, n-pentile, n-hexyl, benzyl, 2-methylbenzyl, 3-methylbenzyl and 4-methylbenzyl.

10. The cleaning composition according to claim 1, characterized in that at least one of the above-mentioned one or more additional ingredients selected from activated sources barkisland, the enzyme surface is chestno-active agents and mixtures thereof.

11. The cleaning composition according to claim 4, characterized in that at least one of the above-mentioned one or more additional ingredients selected from activated sources barkisland, enzyme, surfactant, and mixtures thereof.

12. The cleaning composition according to claim 7, characterized in that at least one of the above-mentioned one or more additional ingredients selected from activated sources barkisland, enzyme, surfactant, and mixtures thereof.

13. The cleaning composition according to claim 1, characterized in that it contains the following additional ingredients: activated source barkisland, enzyme and surfactant.

14. The cleaning composition according to claim 4, characterized in that it contains the following additional ingredients: activated source barkisland, enzyme and surfactant.

15. The cleaning composition according to claim 7, characterized in that it contains the following additional ingredients: activated source barkisland, enzyme and surfactant.

16. The cleaning composition according to claim 1, wherein G represents-CH2-; R1represents H; and each R2independently selected from n-butyl, n-pentile, n-hexyl, benzyl, 2-methylbenzyl, 3-methylbenzyl and 4-methylbenzyl, as mentioned composition contains the following additional ingredients: activated light source is to barkisland, enzyme and surfactant.

17. The cleaning composition according to claim 1, characterized in that the said catalyst has a value compatible with the enzyme 70 or more and one or more ancillary compounds.

18. The cleaning composition according to 17, characterized in that it contains an organic catalyst having the value of compatibility with the enzyme 80 or more, with the said composition comprises the following additional ingredients: activated source barkisland, enzyme and surfactant.



 

Same patents:

FIELD: chemistry.

SUBSTANCE: described is an aqueous liquid bleaching composition which contains a hypochlorite salt in amount sufficient for providing 0.0014-1.4 mol/l of hypochlorite ions, and an N-chloro-compound with pH higher than 7, which is selected from N-chloroarylsulfonamides and N-chlorimidodisulphate salt, where the composition contains at least one surfactant. Also described is a container which contains the said composition and a method of treating a solid surface using the said composition.

EFFECT: prolonged antibacterial activity on a solid surface.

11 cl, 3 tbl, 5 ex

FIELD: textile industry.

SUBSTANCE: method includes stage of article washing with detergent solution, which contains organic polymer, having spinnability, with average molecular weight of 1500000 or more, and where 60 mol % or more of its component monomers contain sulfonic acid group, or form of its salt, or sulfuric acid group, or form of its salt, provided that polyethylene oxide is unavailable. Invention also describes the following: method of hand washing, including stage of hand washing of laundry item with specified detergent solution, or washing solution produced by dissolution of detergent solution with more than 1-1000-multiple amount of water; and versions of detergents. Suggested washing solution may be used for hand washing.

EFFECT: improved smoothness of articles in process of washing and hand care, reduced unfavorable factors of squeaking, rough texture and physical fatigue in process of hand washing.

19 cl, 2 tbl, 11 ex

FIELD: chemistry.

SUBSTANCE: invention refers to sodium percarbonate particles. According to the invention the coated sodium percarbonate particles possessing the inner shell layer including as basic component at least one inorganic hydrate-forming salt and outer shell layer including alkali metal thiosulphate, alkali-earth metal thiosulphate and/or ammonium thiosulphate are described. The method of such sodium percarbonate particles preparation and application of these particles as bleaching agent in detergents and cleansers are also the subjects of an invention.

EFFECT: increasing of stability of sodium percarbonate particles in detergents and cleansers during storage.

23 cl, 4 dwg, 4 tbl

FIELD: chemistry.

SUBSTANCE: detergent contains the components as follows, wt %: anionic surface active agent (SAG) - alkylbenzol sodium sulphonate 10-16; nonionic SAG - oxyethylated fatty alcohols or oxyethylated alkylphenol 2-5; sodium tripolyphosphate 15-25; organophosphonate compound - sodium salt 1-hydroxyethylidene of phosphonic acid or sodium diethylentriaminopentaxys-(methylene phosphonate) 0.2-0.6; polycarboxylate 0.5-1.5; carboxymethyl cellulose 0.3-0.6; modified polyalkylene glycol 0.2-0.6; optical bleaching agent 0.05-0.3; soda ash 3-6; liquid glass 3.5-6.0; enzyme 0.4-0.7; defoaming agent 0.05-1.5; aromatiser 0.15-0.3; sodium sulphate and water to 100.

EFFECT: higher efficiency of bleaching detergent, all type decontamination with additional softening of fabric and without irritation of hand skin during manual washing, lower temperature modes of washing, reduced damage effect on metal parts of washing machines.

10 cl, 2 tbl, 5 ex

FIELD: chemistry.

SUBSTANCE: invention is meant for soaking, washing and bleaching all types of textile articles, except articles from natural silk and wool, in any kind of machine, and also hand wash. Substance contains in % mass: an anionic surfactant 7-15, nonionic surfactant oxyethylated fatty alcohol 2-5, sodium tripolyphosphate 15-25, sodium ethylene-diaminotetraacetate (versene) 0.3-1, polycarboxylate, containing monomers of acrylic acid 0.2-0.6, carboxymethyl cellulose (CMC) (in terms of 100% of the share of the main substance) 0.4-0.6, sodium silicate (in terms of SiO2) - 2-5, sodium perborate or sodium percarbonate (in terms of activated oxygen) 1.5-4, tetraacetylethylenediamine (TAED) 0.5-3, enzymes 0.4-1, caustic ash 5-15, mixture of sodium carbonate and amorphous sodium silicate 2-5, optical brightener 0.05-0.4, perfume 0.1-0.3, sodium sulphate and water till 100.

EFFECT: increase in the effectiveness of the detergent with a whitening effect, removal of all kinds of dirt while adding extra softness without an irritating effect on the skin during hand washing, reducing the temperature regimes of washing, reduction in the harmful effect to the metallic part of the washing machine.

9 cl, 2 tbl

FIELD: chemistry.

SUBSTANCE: invention concerns chemical bleaches applied in cleansers and detergents. Invention claims sodium percarbonate granules with coating of high storage endurance, including a) core obtained by dispersion granulation in pseudoliquefied layer with sodium percarbonate as main component, b) internal coating layer with non-organic hydrate-forming salt as main component, selected out of group including sodium sulfate, sodium carbonate, sodium bicarbonate, magnesium sulfate and mixes or mixed salts of these compounds, and c) outer coating layer with surfactant containing sulfate or sulfonate groups in the form of alkaline metal, alkaline-earth of ammonium salt, as main component.

EFFECT: enhanced storage endurance, high stability and active oxygen content in percarbonate granules.

22 cl, 1 ex

FIELD: chemistry.

SUBSTANCE: sodium percarbonate particles have bleaching effect, their surface contain hydrophobized superfine silica in proportion 0.01-1 wt %. Method for proposed particles production consists in mixing of sodium percarbonate particles, preferably being dried, and 0.01-1 wt % of hydrophobized superfine silica. Particles of the invention have high stability during storage, permit handling and storage without dust formation and agglutination; they are dispersed in water readily and completely.

EFFECT: simplification of particles obtaining technology, and reducing equipment needed.

17 cl, 21 ex, 7 tbl, 2 dwg

FIELD: chemistry.

SUBSTANCE: particles contain inner coating layer that consist of at least one hydrate-forming mineral salt, and outer coating layer, including 0.2-3 wt % alkali metal silicate with module more than 2.5, particularly 3 to 5. Outer layer is obtained using alkali metal silicate solution with alkali metal silicate concentration 2 to 20 wt %. Dissolution time can be extended by alkali metal silicate concentration lowering in solution used, coating material amount being the same. Dissolution time can be extended significantly according to coating layers sequence and solution concentration with low quantity of alkali metal silicate.

EFFECT: extension of dissolution time.

18 cl, 7 tbl, 18 ex

FIELD: chemistry.

SUBSTANCE: invention concerns liquid detergent compositions with high stability during long-term storage. The liquid detergent composition includes fluid medium with water content up to 15 mass % and coated bleaching powder suspended in it. Dissolution time of the bleach is not less than 5 minutes; the bleach coating has at least two layers: inner layer includes one or more hydrate-forming non-organic salts as the main component, and outer layer comprises 0.2 to 5% of bleach and includes an alkali metal silicate with module of SiO2 to M2O (M is an alkali metal atom) over 2.5 as the main component. Preferable compositions include sodium percarbonate with an inner layer consisting mainly of sodium sulfate and an outer layer consisting mainly of 0.5 to 1.5 mass % of sodium silicate (with module of 3.2 to 4.2) as a bleach.

EFFECT: improved detergent efficiency and stability of the claimed composition.

14 cl, 3 tbl, 12 ex

FIELD: chemistry.

SUBSTANCE: invention pertains to compositions of granulated synthetic detergents, meant for manual and machine washing (in any type of machine) and soaking all types of textiles, including coloured and other household needs. The detergent contains the following components in the given % mass: anionic surface active agent sodium alkylbenzenesulfonate 9-12; non-ionic surfactant 2-5; sodium tripolyphosphate 15-30; dispergator 0.3-1.2; carboxymethyl cellulose 0.3-0.7; sodium silicate 3-6; modified polyalkylene glycol 0.2-0.6; enzyme 0.3-0.8; sodium carbonate 6-12; photo-bleaching agent 0.003-0.020; optical brightener 0.05-0.20; fragrance component 0.1-0.3; sodium sulphate and water up to 100. The non-ionic surfactant preferably contains oxyethylated monoalkylphenols based on propylene trimers or oxyethylated fatty alcohols. The dispergator used is sodium polyacrylate or sodium salt of a copolymer of maleic or acrylic acid or a sodium salt of a copolymer of acrylic, methacrylic and maleic acid. Alternatives of the synthetic detergent are also described.

EFFECT: increased effectiveness of the detergent, bleaching effect after washing, wider assortment of high quality granulated synthetic detergents.

7 cl, 1 tbl

FIELD: chemistry.

SUBSTANCE: invention relates to a method of drying sulphonol. Sulphonol containing 38-52% dry substances is pre-foamed. The foam is deposited on a flat carrier using a uniform rod with diametre of 4-6 mm at atmospheric pressure. The foam layer rod is dried with infrared energy input with heat flow density of 2.92-3.23 kW/m2.

EFFECT: increased output of dry sulphonol.

1 cl, 5 ex

The invention relates to the field of sanitation and hygiene and can be used for cleaning and disinfection of surfaces in premises, sanitary-technical equipment, linen and utensils in health care institutions, public services, public catering and trade, on the railway transport objects and people in everyday life

-ketosulfones or their salts as surfactants for the processes occurring in aqueous media, and method of production thereof" target="_blank">

The invention relates to the production of fluorine-containing sulfonic acids, namely new fluorinated-ketosulfones and their salts of General formula I

RFCOCH2SO2OZ, (I) where RFtakes the values CnF2n+1when n = 5-8; C - C6H11, CF3O(CF2CF2O)mCF2- if m = 1-3;

C3F7O(CF2O)- when x = 0,1,2;

Z = H or a salt of ammonium, alkali or alkaline-earth metal or primary, secondary or tertiary amine

FIELD: chemistry.

SUBSTANCE: invention relates to bleaching compositions, which in fact do not contain peroxide bleaches, for bleaching of fabrics. Described is liquid bleaching composition with pH 10 or lower, which contains: (a) complex compound of transitional metal as catalyst of bleaching in air, (b) from 0.001 for 3 wt/wt % of odorant.

EFFECT: obtaining composition, whose bleaching activity is more, than 10 times higher as compared with bleaching activity of composition, containing as odorant molar equivalent of citronellal.

5 cl, 3 tbl, 62 ex

The invention relates to a method for producing nonionic surfactants and can be used in petrochemical, chemical, chemical, etc
Detergent // 2144946
The invention relates to detergents for cleaning of various contaminants, including petroleum products

The invention relates to detergent compositions containing alkylalkoxysilane and polyxenida fatty acids

FIELD: chemistry.

SUBSTANCE: invention relates to bleaching compositions, which in fact do not contain peroxide bleaches, for bleaching of fabrics. Described is liquid bleaching composition with pH 10 or lower, which contains: (a) complex compound of transitional metal as catalyst of bleaching in air, (b) from 0.001 for 3 wt/wt % of odorant.

EFFECT: obtaining composition, whose bleaching activity is more, than 10 times higher as compared with bleaching activity of composition, containing as odorant molar equivalent of citronellal.

5 cl, 3 tbl, 62 ex

FIELD: chemistry.

SUBSTANCE: cleaning compositions contain organic catalysts having the formula (i), (ii) given in the formula of invention, or mixtures thereof. In the formula G is selected from -O-, -CH2O-, -(CH2)2- and -CH2-, R1 is selected from H or C1-C4 alkyl, each R2 is independently selected from C4-C8 alkyl, benzyl, 2-methylbenzyl, 3-methylbenzyl, 4-methylbenzyl, 4-ethylbenzyl, 4-isopropylbenzyl and 4-tert-butylbenzyl.

EFFECT: improved compatibility of organic catalysts with enzymes.

18 cl, 18 ex

FIELD: chemistry.

SUBSTANCE: present invention relates to a method of reducing creases when washing a garment made from heavy fabric, which includes steps of washing the garment and applying a fabric softener, which contains a quaternary ammonium fatty ester and a hydrolysed protein and polysiloxane copolymer, where the average molecular weight of the protein component ranges from 500 to 500000 Da, to the garment made from fabric weighing at least 250 g/m2. The present invention also relates to a fabric softener for reducing creases on garments made from heavy fabric, which contains: a) 0.5-50 wt % cationic softener, which contains a fatty acid ester of quaternary ammonium, b) 0.02-0.5 wt % hydrolysed protein and siloxane copolymer, where the average molecular weight of the protein component ranges from 500 to 500000 Da, c) a fragrant and d) water.

EFFECT: obtaining an efficient and cheap agent for removing or reducing creases on clothes during washing and drying.

13 cl, 3 ex, 4 tbl

Up!