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Reagent dosing method and equipment for implementation

Reagent dosing method and equipment for implementation
IPC classes for russian patent Reagent dosing method and equipment for implementation (RU 2382813):
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Process of treating trapped persistent water-oil emulsions before processing Process of treating trapped persistent water-oil emulsions before processing / 2318865
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Method of preparing demulsifier for dehydration and desalting of oil emulsions Method of preparing demulsifier for dehydration and desalting of oil emulsions / 2310680
Demulsifier useful for destroying oil emulsions on crude oil treatment plants is prepared through polyether-tolylene diisocyanate reaction. In particular, tolylene diisocyanate dimer is used at polyether-to-tolylene diisocyanate dimer molar ratio between (n+1):0.5n and (n+3):0.5n, wherein n is integer from 1 to 6 and represents number of tolylene diisocyanate moles. Reaction is conducted at 20-25°C, after which temperature is raised to 50-60°C. Advantageously, demulsifier is dissolved in organic solvent, e.g. aromatic or non-aromatic water-soluble solvent, to concentration 30-65%.
Ethylene- and propylene oxide block copolymer based on pentaerythrite as deemulsifier of water-petroleum emulsion, method for production thereof and deemulsifier based on the same Ethylene- and propylene oxide block copolymer based on pentaerythrite as deemulsifier of water-petroleum emulsion, method for production thereof and deemulsifier based on the same / 2306322
Invention relates to synthesis of new block copolymer of ethylene- and propylene oxide based on pentaerythrite of general formulae C(CH2O-(C3H6O)m(C2H4O)nH)4, wherein 4n = 32-124; 4m = 24-96, and C(CH2O-(C3H6O)(C2H4O)n-(C3H6O)mH)4, wherein 4n = 32-124; 4m = 20-92. Method for production thereof includes component interaction in presence of dimethylsulphoxide and alcali catalyst under heating, wherein oxypropylated perpolymer in propylene oxide/pentaerythrite molar ratio 4 is obtained, then oxypropylation and oxyethylation or oxyethylation and oxypropylation are carried out. Claimed deemulsifier contains 10-90 mass % of said block copolymer, and balance: solvent up to 100 mass %.
Crude oil dehydration and desalting method Crude oil dehydration and desalting method / 2244733
To oil emulsion is added surface-active demulsifying additive containing (i) aqueous solution of surfactant based on sodium salt of oxyethylated isononylphenol carboxymethylate expressed by general formula C9H19-C6H4-O-(-CH2-CH2O)nCOONa, where n=10-12, (ii) self-emulsifying organosilicon compound, and (iii) sodium or calcium chloride salt.

FIELD: oil-and-gas industry.

SUBSTANCE: group of inventions related to oil industry, to dosing methods and equipment of reagents, such as demulsifying agents and corrosion inhibitors - oil development and preparation at fields and can be used at oil treatment and water preliminary discharge plants. Preliminary equalise pressure in a reagent tank and accompanying oil gas pipeline. Then regulate reagent flow rate, compare measured with flow metre reagent flow rate value in regulator with reagent flow rate target value, and according hose values difference create a control signal to a control valve, installed on pipe connecting nozzle to the tank. Device contains sealed tank with reagent, located over the pipeline top generating line. A section of a smaller diametre with nozzle mounted into the pipeline. The nozzle connected to the tank via pipeline, with reagent flow metre, connected to the regulator, reagent target flow rate signal transferred to the second end it, and outlet connected with control valve, installed on the pipe connecting nozzle to the tank. The reagent tank connected to the accompanying oil gas pipeline with equaliszing line.

EFFECT: simplification of reagent dosing into the pipeline, metal and power consumption decrease, ensuring reagent intense mixing with a total volume of pumped media.

2 cl, 1 dwg

 

Group of inventions relates to the oil industry, in particular to methods and devices for dispensing reagents demulsifiers and corrosion inhibitors - the collection and preparation of oil and water emulsions, and can be used on the oil treatment plants and preliminary water discharge, i.e. when the joint transport the produced oil and gas.

There is a method of dosing of chemicals (emulsion) in the collection and preparation of oil, namely, that the production from the wells flows into the container located inside the tank with a demulsifier, washes the tank. Then the dosing pump demulsifier served in the dispenser, through the holes which he uniformly across the cross-section of the vessel is introduced into the volume of the pumped boreholes. Mixed with demulsifier production wells re-enters the pipeline from production wells [RF Patent №2049519, CL 01D 17/04, publ. 1995.12.10].

The disadvantage of this method is the complexity of its implementation.

Known device for dosing of chemicals (emulsion) in the collection and preparation of oil, including the pipeline gathering system production wells, the reservoir for the chemical with the sockets for input and output of chemical and air release, dosing pump connected to the tank, while the plant is equipped with the capacity with the introduction and in the water pipes, connected to the pipeline gathering system production wells, and an annular perforated distributor connected to a dosing pump, and a reservoir for the chemical and the distributor is installed inside the tank [RF Patent №2049519, CL 01D 17/04, publ. 1995.12.10].

The disadvantage is the complexity of the layout of the installation, and the impossibility of accurate dosing of the chemical.

There is also known a method of dispensing reagents, namely, that in technological capacity, designed for the preparation and storage of reagent injected reagent. The level of the reagent is measured by the sensors. Further from the technological capacity of the reagent is supplied to the reception of a dosing pump. Alternate dosing of the reagent in the pipeline with the pumped medium or technological capacity is tripped [RF Patent №2171790, CL 02F 11/14, publ. 2001.08.10].

The disadvantage of this method is the complexity of the regulation of the SOS periodic dosing of the reagent, and that not by intensive mixing of the reagent with the pumped medium because after breaker flow becomes laminar character.

A device for dispensing reagents - block cooking chemicals block installations, including technological capacity chemical, pipeline re achiveve environment, the dosing pump, the output of which is connected through the circuit breaker, providing alternate connection of the output of the pump through the pipe strapping to the technological capacity of the reagent. Breaker periodic dosing of chemical reagent in the pipeline with the pumped liquid [RF Patent №2171790, CL 02F 11/14, publ. 2001.08.10].

The disadvantage of the block of preparation of chemical reagents is the presence of a dosing pump, which provides no flow control, the complexity of the regulation of the SOS periodic dosing of chemical reagent in the pipeline with the pumped liquid, because the breaker is made in the form of a valve device or a rotating rotor with slots and holes, does not provide a clear uninterrupted operation of the unit.

The closest way to the same destination to the claimed method in a group of inventions on the totality of symptoms is the way the dosage of the reagents, namely, that the reagent by gravity through the filter goes to the reception of a dosing pump, which regulates the flow rate of the reagent, and then fed into the pipeline with the pumped liquid. [Brochure "OZNA DISPENSER" joint stock company "OZNA", "Modification MDD performed with two dosing pumps, without spending capacity, without mixer", p.12-13 - Bashkort Republic of the mill, gontarski, street North, 60, see Appendix].

The disadvantage of this method is the complexity of the dosing of the reagent by regulating its flow by the dosing pump, which provides no change in dispensing of the reagent when the change in the flow rate of the pumped fluid. In addition, pump-dispenser reagent is served in the pumped flow in pulse mode, which leads to the interaction of the reagent with a certain portion of the reagent. In this part of the reagent is beyond the field of interaction with the reagent, i.e., not intense mixing of the reagent with the pumped medium.

The closest device to the same destination to the claimed device in the group of inventions on the totality of symptoms is the device - unit dosing of reagents, including technological capacity, intended for storage of the reagent. The unit contains a level sensor, temperature sensor and gauge, as well as the filter and the pump, carry out continuous volumetric dosing of reagents - liquid demulsifiers and corrosion inhibitors in the pipeline with the pumped liquid. This unit dosing of the reagent is performed in a block design. The equipment unit is mounted on a welded frame and is insulated room [brochure "OZNA DISPENSER" joint stock company "OZ IS A", "Modification of MDD performed with two dosing pumps, without spending capacity, without mixer", p.12-13 - the Republic of Bashkortostan, gontarski, oseira, 60, see Appendix].

Lack of unit dosing of reagents is the complexity of the structural design, the use of several expensive pumps, various devices, in particular the level sensor, temperature sensor and so on, which creates the complexity of regulation by dosing the reagent, as well as significant energy consumption. In addition, the dosing unit has a bulky design, placed on a welded frame, and must be insulated room.

The technical result is to facilitate the dispensing of the reagent in the pipeline with the pumped liquid due to the automatic regulation of the flow rate, simplifying the design, reducing the metal and energy consumption due to elimination of dosing pumps, hull and equipment unit mounted on a welded frame, as well as providing intensive mixing of the reagent with the entire volume of the medium pumped through the creation of turbulent flow during the passage of the fluid through the site of the narrowing.

Specified single technical result in the exercise of invention the object of the method is achieved by the reinforcement of the coherent method of dispensing reagents into the pipeline with the pumped liquid by regulating its flow, the peculiarity lies in the fact that pre-equalize the pressure in the vessel with reagent and gas associated gas, and then regulate the flow rate of the reagent, by comparing the measured flow of the reagent is the reagent consumption in the regulator with a set value of the flow rate of the reagent, and the difference between these two values is generated control signal to the regulating valve mounted on the pipe connection of the nozzle with the container.

Specified single technical result in the exercise of invention the device object is achieved in that in the known device dispensing reagents containing a container of reagent, the peculiarity lies in the fact that the container is airtight and is located above the top of pipe with the pumped medium in the pipeline built a pipeline of smaller diameter, in which is placed a nozzle, United pipeline capacity on pipeline connection nozzle with a capacity of installed flow sensor reagent, coupled to the controller, to the second end of which the signal of the set value of the flow rate of the reagent, and the output connected with a control valve on a pipeline connection nozzle capacity, in addition, the capacity of the surge line is connected to the gas associated gas.

The presence is Truboprovod with the pumped liquid pipeline of smaller diameter provides a greater rate of passage of the pumped fluid and turbulent hydrodynamic flow regime environment.

The placement of the nozzle pipe section of smaller diameter creates a vacuum, through which the reagent is sucked into the pipe with the pumped liquid and then intensively mixed with it.

Automated system for dispensing reagent provides an instant assessment of consumption and accurate dosing of reagent consumption.

The claimed group of inventions to meet the requirement of unity of invention, since the group of inventions forming a single General inventive concept, both group object of the invention is aimed at solving the same problem for a single technical result.

A method of dispensing reagent is as follows.

Pre-equalize the pressure in the tank 1 with the reagent in the pipeline 14 of associated petroleum gas. To do this, open the valves 12 and 13, then open the valves 9 and 10. Reagent from the tank 1 under the pressure of the gas from the pipeline 14 associated petroleum gas is fed into the pipe 2 with the pumped liquid - liquid-gas mixture (SHC). When this is included in the work of the nozzle 4. When the movement of the pumped fluid by a slim section of the pipeline in the position of the nozzle 4, a vacuum, which increases the pressure difference between the nozzle 4 and the tank 1, as a result of the supplied reagent is sucked into the pipe 2 with the switch is cinemoi environment and intensively mixed with it. The accuracy of the flow rate of the reagent is provided by the automatic regulation of the dispensing of the reagent, which is as follows. After pre-equalization of pressure in the tank 1 with the reagent and the pipeline 14 with associated petroleum gas, measure the flow rate of reactant flow sensor 6. Measured by the flow sensor 6 is the flow rate of the reagent in the controller 7 is compared with a set value of the flow rate of the reagent and the difference between these two values is generated control signal to the control valve 8.

The drawing shows a device for dispensing reagent.

Installation for dispensing reagent contains container 1 with the reagent and the pipe 2 with the pumped liquid, the container 1 is located above the top of pipe. In this pipe 2 is mounted to the pipe section 3 of smaller diameter, in which is placed the nozzle 4 connected by a pipe 5 with a capacity of 1, is airtight. On the pipe 5 connection nozzle 4 with a capacity of installed flow sensor reagent 6 connected to the controller 7, the second end of which the signal of the set value of the flow rate of the reagent, and the output is connected with the regulating valve 8 mounted on the pipe 5. On the pipe 5 posted by valves 9 and 10. In addition, capacity 1 surge line 11, where the valves 12 and 13, connected to the pipeline 14 of associated petroleum gas.

Device for dispensing reagents is as follows.

Pre-equalize the pressure in the vessel 1 and the gas 14, which open the valves 12 and 13. Then open the valves 9 and 10. Measured by the flow sensor reagent 6 is the flow rate of the reagent in the controller 7 is compared with a set value of the flow rate of the reagent and the difference between these two values at the output of the controller 7 is formed a control signal for the control valve 8 installed on the pipeline 5 connection nozzle 4 with a capacity of 1.

The proposed method and device for dispensing reagent are used for volumetric dosing of the reagents on the oil treatment plants and preliminary water at various oil fields.

1. A method of dispensing reagent into the pipeline with the pumped liquid by regulating its flow, wherein the pre-equalize the pressure in the vessel with reagent and pipeline associated petroleum gas, and then regulate the flow rate of the reagent, by comparing the measured flow value of the flow rate of the reagent in the controller with a set value of the flow rate of the reagent and the difference between these two values is generated control signal to the regulating valve mounted on the pipe connection of the nozzle with the container.

2. Device for dispensing reagent comprising a container of what eigentum, characterized in that the tank is airtight and is located above the top of pipe with the pumped medium in the last installed section of pipe of smaller diameter, in which is placed a nozzle, coupled with the capacity of the pipeline is installed flow sensor reagent, coupled to the controller, to the second end of which the signal of the set value of the flow rate of the reagent, and the output is connected with the regulating valve installed on the pipe connection nozzle with capacity, in addition, the capacity of the surge line is connected to the gas associated gas.

 

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