Cosmetic composition containing two polyesters

FIELD: medicine.

SUBSTANCE: invention refers to cosmetology and represents a cosmetic composition for lips, containing at least one first polyester which can be produced by reaction of at least one polyol, containing 3 to 12 carbon atoms and 3 to 6 hydroxyl groups, at least one nonaromatic branched monocarboxyl acid chosen from the group, at least one aromatic monocarboxylic acid, chosen from the group and at least one polycarboxyl acid containing at least 2 carboxyl groups COOH, and/or cyclic anhydride of such polycarboxyl acid containing 3 to 18 carbon atoms; and at least one second polyester which can be produced by reaction of at least one polyol, containing 3 to 12 carbon atoms and 3 to 6 hydroxyl groups, at least one nonaromatic linear monocarboxyl acid chosen from the group, at least one aromatic monocarboxyl acid, chosen from the group and at least one polycarboxyl acid containing at least 2 carboxyl groups COOH, and/or cyclic anhydride of such polycarboxyl acid containing 3 to 18 carbon atoms. The first and second polyesters are in the composition in certain mass ratio.

EFFECT: invention provides stability and improved shine of deposited film.

10 cl, 9 ex, 3 tbl

 

The present invention relates to cosmetic compositions comprising two different complex of the polyester, as well as to their use, in particular in lipsticks.

Compositions according to the invention can be applied to such keratin surface skin of the face or body, lips, hair, eyelashes, eyebrows and nails.

There are numerous cosmetic compositions, in which the desirable properties of glitter deposited film after application to the skin, the lips, for example, lipsticks, lipsticks or even some hair tools.

In order to achieve such a result, it is possible to combine the specific source of the substance with the so-called oil for Shine, such as polybutene, which, however, have a high viscosity; or esters of fatty acid or fatty alcohol, the number of carbon atoms is high; or some vegetable oil; or else esters obtained by partial or complete esterification gidrauxilirovannogo aliphatic compounds with aromatic acid, as described in the application for the European patent 1097699.

You can also combine lanoline with complex polyesters obtained by the sequential presentation of the interaction of castor oil with ezoterikovou acid, then with succinic acid, such as described is " in U.S. patent 6342527.

To improve the brilliance of the deposited film, as well as its sustainability, also proposed the use of esters obtained from the condensation reaction of a polyol with a carboxylic acid of type "neo", in particular, according to the French patent 2838049.

You can also call the European patent 1457201 that describes the composition, combining a complex polyester triglycerides hydroxycarboxylic acids and oil with a small molecular weight, choose among polybutylenes, hydrogenated products of polyisobutylene, hydrogenated or no polydecene, copolymers of vinylpyrrolidone, esters of linear fatty acids, hydroxylated esters, branched esters of fatty alcohols or fatty acids with C24-C28, silicone oils and/or oils of vegetable origin.

In the application for the European patent 0792637 describes the composition, combining aromatic ester and a polymer polybutene or polyisobutene type.

In the application for the European patent 1155687 describes a method consisting in incorporating in the oil phase formed cosmetically acceptable oil, organopolysiloxane containing at least 2 groups that can form hydrogen bonds.

However, these compositions and combinations, even if they significantly increase the Shine, still have shortcomings with the points of view of the prolonged stability of the Shine in time.

The polymers used in the present invention, preferably are alkyd resins, which form a special class of polyesters, representing the reaction product of polyols and polycarboxylic acids, usually modified unsaturated fatty acids such as oleic acid, unsaturated oils, such as soybean oil or castor oil.

The prior art describes cosmetic compositions comprising polyesters. It is possible, in particular, to call French patent 2562793, which describes the use of sucrose benzoate in combination with toluensulfonate resins; or the Japan patent 61246113, which describes the use of sucrose benzoate in combination with alkyd resins, modified complex ester glycidylester. You can also call the International patent application WO 2002/243676, which describes the use of polyester resin on the basis of neopentylglycolester in combination with alkylacrylate and alkylmethacrylamide copolymers. Known the Japan patent 58023614, which describes the use of the modified complex of the polyester obtained by the condensation reaction of pentaerythritol with CIS-4-cyclohexene-1,2-dicarboxylic acid and fatty acids of castor oil, then reaction with dioxirane the new connection type epoxy resin; or even the Japan patent 54011244, which describes the use of the modified complex of the polyester obtained by the condensation reaction of dipentaerythritol with cyclohexane-1,2-dicarboxylic acid and fatty acids of castor oil, then reaction with dioxiranes connection type epoxy resin.

Polyesters used in the present invention have a structure different from the known polyesters. In addition, when combined with special ingredients, they can achieve cosmetic properties, equal, even the best properties already received when using the known polyesters.

The aim of the present invention to provide cosmetic compositions, Shine and resilience Shine in time which is improved in comparison with the compositions according to the prior art, including other polyesters.

The applicant has unexpectedly found that two particular complex polyester lead to cosmetic compositions, the stability of gloss are improved.

The object of the present invention is therefore a cosmetic composition containing:

- at least one complex of the polyester, which can be obtained by reaction:

- at least one polyol containing from 3 to 6 hydroxyl groups;

at least one NEA is omatically branched monocarboxylic acid;

- at least one aromatic monocarboxylic acid and

at least one polycarboxylic acid containing at least 2 carboxyl groups COOH and/or a cyclic anhydride of such a polycarboxylic acid;

- at least one complex of the polyester, which can be obtained by reaction:

- at least one polyol containing from 3 to 6 hydroxyl groups;

at least one nonaromatic linear monocarboxylic acids;

- at least one aromatic monocarboxylic acid and

at least one polycarboxylic acid containing at least 2 carboxyl groups COOH and/or a cyclic anhydride of such a polycarboxylic acid.

The composition according to the present invention may be in the form of pastes, solids, more or less viscous cream. It can be an emulsion of oil-in-water or water-in-oil, solid or soft gel. Preferably, it is in the form applied by pouring from a tube or Cup, and, in particular, in the form of a solid anhydrous gel, in particular in the form of an anhydrous cosmetic pencil.

According to another of its aspects, the object of the present invention is a cosmetic composition, including:

the first polymer based on benzoic acid and optlevel acid/ezoterikovou acid/pentaerythritol, and

the second polymer on the basis of benzoic acid/isophthalic acid/stearic acid/pentaerythritol.

The mass ratio of the first polymer and the second polymer is preferably from 50:1 to 2:1, for example from 30:1 to 20:1.

The term "hydrocarbon" refers to a radical or connection established(Noah) essentially, even with(her), atoms(s) of carbon and hydrogen, and possibly atoms(s), oxygen, nitrogen, sulfur, phosphorus, and does not contain(General) the silicon atom or fluorine. This radical or compound may contain alcohol groups, ether groups, carboxyl groups, amino groups and/or amide groups. Preferably, the adjective "hydrocarbon" means a radical or connection established(Noah) only atoms of carbon and hydrogen and oxygen.

The term "branched" understand the connection comprising at least one branching. Generally speaking, the amount of branching of the molecules corresponds to the number of side groups containing at least one carbon atom and is attached to the main chain of the molecule, the main chain corresponds to the longest carbon chain of the molecule (see S.H.Pine "Organic Chemistry", fifth edition; Mc Graw-Hill, Chapter 3).

Polyesters (or polycondensate)

Polyesters (also called subsequently polycondensate) Ave the property is produced by the interaction of the polyol, polycarboxylic acids, non-aromatic, linear or branched monocarboxylic acid and aromatic monocarboxylic acid.

The first polymer can be obtained by reacting polyol, polycarboxylic acid, nonaromatic branched monocarboxylic acid and aromatic monocarboxylic acid.

The second polymer is mainly produced by the interaction of Alila, polycarboxylic acid nonaromatic linear monocarboxylic acid and aromatic monocarboxylic acid.

According to one variant of implementation, the content of non-aromatic monocarboxylic acid is from 5 wt.% up to 80 wt.%, preferably, from 20 wt.% up to 70 wt.%, for example, from 25 wt.% to 65 wt.%, with respect to the total mass of polycondensate.

According to another variant implementation of the polyesters mainly produced by interaction of the polyol, polycarboxylic acid and at least one non-aromatic monocarboxylic acid, and the above-mentioned monocarboxylic acid is found in significant quantity.

Polycondensate can be obtained by the reaction of esterification/polycondensation nigeoplachivaemoy components in accordance with methods known to the expert in this field.

One of the components required to obtain polycondensates according from what retenu, is a polyol containing, preferably, from 3 to 6 hydroxyl groups, in particular from 3 to 4 hydroxyl groups. Can certainly use a mixture of such polyols.

The above polyol may constitute, in particular, carbon-containing, in particular, hydrocarbon, linear, branched or cyclic, saturated or unsaturated compound containing 3-18 carbon atoms, in particular 3 to 12 carbon atoms, even 4-10 carbon atoms and 3-6 hydroxyl groups (OH), and which may include, in addition, one or more oxygen atoms in the circuit (a simple ester or oxygraph).

The above polyol is preferably a saturated, linear or branched, hydrocarbon compound containing 3-18 carbon atoms, especially 3 to 12 carbon atoms, even 4-10 carbon atoms and 3-6 hydroxyl groups (OH).

It can be selected individually or as a mixture, of:

- triolo, such as butane-1,2,4-triol, hexane-1,2,6-triol, trimethylacetyl, trimethylolpropane, glycerin;

- tetraols, such as pentaerythritol (tetramethyllead), aritra, diglycerin or detromethorphan;

- pentalow, such as xylitol;

- hexalot, such as sorbitol and mannitol; or else dipentaerythritol or triglycerin.

Preferably, the polyol is chosen from among glycerin, pentair the TRITA, diglycerin, sorbitol and mixtures thereof; and, even better, the polyol is tetraol as pentaerythritol.

The polyol or mixture of polyols is preferably from 10 wt.% up to 30 wt.%, in particular, from 12 wt.% up to 25 wt.%, and, better, from 14 wt.% to 22 wt.%, in relation to the total weight of the final polycondensate.

Another component necessary for obtaining the first complex of the polyester according to the invention, is nonaromatic branched monocarboxylic acid. Nonaromatic branched monocarboxylic acid may be saturated or unsaturated, including 6-32 carbon atoms, especially 8-28 carbon atoms and better still from 10 to 24 carbon atoms, even 12-20 carbon atoms. Undoubtedly, you can use a mixture of such non-aromatic monocarboxylic acids.

The term "nonaromatic branched monocarboxylic acid" is understood a compound of the formula RCOOH, in which R is branched, saturated or unsaturated, hydrocarbon radical containing 5-31 carbon atoms, in particular, 7-27 carbon atoms and better still from 9 to 23 carbon atoms, even 11-19 carbon atoms.

Preferably, the radical R is saturated. Even better, the above radical R is branched, with a number of carbon atoms 5-31, even 11-21.

According to one particular variant of the invention, the non-aromatic R is Svetlana monocarboxylic acid has a melting point above or equal to 25°C, in particular, higher than or equal to 28°C, 30°C, it was found that when using such an acid, in particular, in large numbers, can, on the one hand, to achieve a good Shine and resilience Shine above, and, on the other hand, to reduce the amount of waxes usually present in the composition.

From nonaromatic branched monocarboxylic acids that may be used include, individually or in the form of a mixture, isoheptane acid, 4-ethylpentane acid, 2-ethylhexanoyl acid, 4,5-dimethylhexanoic acid, 2-heptylate acid, 3,5,5-trimethylhexanoic acid, isooctanol acid, isononanoic acid, isostearoyl acid.

Preferably, you can use 2-ethylhexanoyl acid, isooctanol acid, isoheptane acid, isononanoic acid, isostearoyl acid and mixtures thereof, and, even better, isostearoyl acid.

The above nonaromatic branched monocarboxylic acid, or a mixture of the above acids is preferably from 30 wt.% up to 80 wt.%, in particular, from 40 wt.% up to 75 wt.%, even from 45 wt.% up to 70 wt.%, and, better, from 50 wt.% to 65 wt.%, in relation to the total weight of the final polycondensate.

Another component necessary to obtain a second complex of the polyester according to the invention, has the nonaromatic linear monocarboxylic acid. Non-aromatic monocarboxylic acid may be saturated or unsaturated, including 6-32 carbon atoms, in particular, 8-28 carbon atoms and better still from 10 to 24 carbon atoms, even 12-20 carbon atoms. Undoubtedly, you can use a mixture of such non-aromatic monocarboxylic acids.

The term "non-aromatic monocarboxylic acid" is understood a compound of the formula RCOOH, in which R denotes a linear, saturated or unsaturated, hydrocarbon radical containing 5-31 carbon atoms, in particular, 7-27 carbon atoms and better still from 9 to 23 carbon atoms, even 11-19 carbon atoms.

Preferably, the radical R is saturated. Even better, the above radical R is a linear or branched, and preferably the number of carbon atoms 5-31, even 11-21.

According to one particular variant of the invention, non-aromatic monocarboxylic acid has a melting point above or equal to 25°C., in particular higher than or equal to 28°C, 30°C, it was found that when using such an acid, in particular, in large numbers, can, on the one hand, to achieve a good Shine and resilience Shine above, and, on the other hand, to reduce the amount of waxes usually present in the composition.

From nonaromatic linear monocarboxylic acids, is the quiet can be used, you can call, individually or as a mixture:

unsaturated monocarboxylic acids such as Caproic acid, Caprylic acid, octanoic acid, novanova acid, cekanova acid, lauric acid, tridecanoate acid, myristic acid, palmitic acid, stearic acid, arachnid acid, Bekenova acid, zerotinova (hexacosanol) acid; cyclopentanecarbonyl acid, cyclopentadecane acid, 3-cyclopentylpropionic acid, cyclohexanecarbonyl acid, cyclohexyloxy acid, 4-cyclohexylmethanol acid;

unsaturated but non-aromatic monocarboxylic acid, such as caproleuna acid, obtusiloba acid, undecylenoyl acid, dolezelova acid, lingeriea acid, Mirandolina acid, physeteridae acid, Tsurikova acid, palmitoleic acid, oleic acid, petrolina acid, Aksenova acid, elaidic acid, Godunova acid, gadolinia acid, erucic acid, catolina acid, Neronova acid, linoleic acid, arachidonic acid.

From the above-mentioned non-aromatic linear monocarboxylic acids with a melting point above or equal to 25°C can be called individually or as a mixture:

among the saturated monocarboxylic acids: dekanovu (to prinova) acid, lauric acid, tridecane acid, myristic acid, palmitic acid, stearic acid, arachnid acid, beenbuy acid, arotinolol (hexacosanol) acid;

among the unsaturated but non-aromatic monocarboxylic acids: Petroselinum acid, vaccinology acid, elaidic acid, londonbuy acid, gadolinium acid, erucic acid, Neronova acid.

Preferably, you can use lauric acid, myristic acid, nonanoyl acid, palmitic acid, stearic acid, beenbuy acid and mixtures thereof, and, even better, one stearic acid.

The above-mentioned non-aromatic linear monocarboxylic acid, or a mixture of the above acids is preferably from 30 wt.% up to 80 wt.%, in particular, from 40 wt.% up to 75 wt.%, even from 45 wt.% up to 70 wt.%, and, better, from 50 wt.% to 65 wt.%, in relation to the total weight of the final polycondensate.

Another component necessary to obtain polycondensates according to the invention is an aromatic monocarboxylic acid. This acid may include 7-11 carbon atoms may, in addition, may be substituted by 1-3 saturated or unsaturated, linear, branched and/or cyclic alkyl radicals which contain 1-32 carbon atoms, in particular 2 to 12 carbon atoms,even 3-8 carbon atoms.

Undoubtedly, you can use a mixture of such aromatic monocarboxylic acids.

Under aromatic monocarboxylic acid to understand the connection of the formula R COOH, in which R' represents an aromatic hydrocarbon radical comprising from 6 to 10 carbon atoms, and, in particular, benzoic and naphthoic radicals.

The abovementioned radical R', in addition, may be substituted by 1-3 saturated or unsaturated, linear, branched and/or cyclic alkyl radicals containing 1-32 carbon atoms, in particular 2 to 12 carbon atoms, and even of 3-8 carbon atoms; and select, in particular, among methyl, ethyl, propyl, isopropyl, butyl, isobutyl, tert-butyl, penttila, isopentyl, neopentyl, cyclopentyl, hexyl, cyclohexyl, heptyl, isoheptyl, octile or isooctyl.

From aromatic monocarbonic acids that may be used include, individually or in a mixture of benzoic acid, o-Truelove acid, m-Truelove acid, p-Truelove acid, 1-naphthoic acid, 2-naphthoic acid, 4-tert-butylbenzoic acid, 1-methyl-2-naphthoic acid, 2-isopropyl-1-naphthoic acid.

Preferably, you can use benzoic acid, 4-tert-butylbenzoic acid, o-Truelove acid, m-Truelove acid, 1-naphthoic acid, individually or as mixtures; and, l is CSE, one benzoic acid.

The above aromatic monocarboxylic acid, or a mixture of the above acids is preferably from 0.1 wt.% up to 10 wt.%, in particular, from 0.5 wt.% to 9.95 wt.%, preferably, from 1 wt.% up to 9.5 wt.%, and even from 1.5 wt.% up to 8 wt.%, in relation to the total weight of the final polycondensate.

Complex polyester can be produced from non-aromatic, saturated or unsaturated, branched monocarboxylic acids, including 10-32 carbon atoms, in particular, 12-28 carbon atoms, and better still, 12-24 carbon atoms; and having a melting point above or equal to 25°C., in particular higher than or equal to 28°C and 30°C. it is Certainly possible to use a mixture of such non-aromatic monocarboxylic acids.

Found that when using this acid in these quantities, it is possible, on the one hand, to achieve a good Shine and resilience Shine above, and, on the other hand, reduce the amount of waxes, usually present in the provided compositions.

Under nonaromatic branched monocarboxylic acid understand the connection of the formula RCOOH, in which R denotes a saturated or unsaturated hydrocarbon radical, including 9-31 carbon atoms, in particular, 11-27 carbon atoms and better still, 11-23 carbon atoms.

Preferably, the radical R is on Ishenim. Even better, the above radical R is linear or branched and preferably the number of carbon atoms 11-21.

The above nonaromatic branched monocarboxylic acid with a melting point above or equal to 25°C., or a mixture of the above acids is preferably from 22 wt.% up to 80 wt.%, in particular, from 25 wt.% up to 75 wt.%, and even from 27 wt.% up to 70 wt.%, and, better, from 28 wt.% to 65 wt.%, in relation to the total weight of the final polycondensate.

Complex polyester can be produced from non-aromatic, saturated or unsaturated, branched monocarboxylic acids, including 6-32 carbon atoms, in particular, 8-28 carbon atoms, and better still 10 to 20 carbon atoms, and even 12 to 18 carbon atoms, which may have a melting point of strictly below 25°C, in particular below 20°C, and even 15°Snisarenko, you can use a mixture of such non-aromatic monocarboxylic acids.

Under nonaromatic branched monocarboxylic acid understand the connection of the formula RCOOH, in which R denotes a saturated or unsaturated, linear, branched and/or cyclic hydrocarbon radical, including 5-31 carbon atoms, in particular, 7-27 carbon atoms and better still, 9-19 carbon atoms, and even 11-17 carbon atoms.

Preferably, the radical R is saturated. Even better, you ukazanny radical R is linear or branched and preferably, the number of carbon atoms 5-31.

Of the non-aromatic monocarboxylic acid, having a melting point below 25°C, which can be used include, individually or as a mixture:

among the saturated monocarboxylic acids: isoheptane acid, 4-ethylpentane acid, 2-ethylhexanoyl acid, 4,5-dimethylhexanoic acid, 2-heptylate acid, 3,5,5-trimethylhexanoic acid, isooctanol acid, isononanoic acid, isostearoyl acid.

Preferably, you can use isooctanol acid, isononanoic acid, isostearoyl acid and mixtures thereof, and, even better, one isostearoyl acid.

The above nonaromatic branched monocarboxylic acid with a melting point below 25°C., or a mixture of the above acids is preferably from 0.1 wt.% up to 35 wt.%, in particular, from 0.5 wt.% up to 32 wt.%, even from 1 wt.% up to 30 wt.%, and, better, from 2 wt.% up to 28 wt.%, in relation to the total weight of the final polycondensate.

Another component necessary to obtain polycondensate according to the invention, is saturated or unsaturated, even aromatic, linear, branched and/or cyclic polycarboxylic acid comprising at least 2 carboxyl groups COOH, in particular 2 to 4 COOH group; and/or cyclizes the th anhydride of such a polycarboxylic acid. Undoubtedly, you can use a mixture of such polycarboxylic acids and/or anhydrides.

The above polycarboxylic acid may be selected from among a linear, branched and/or cyclic, saturated or unsaturated, even aromatic, polycarboxylic acids, including 3-50, in particular, 3-40, carbon atoms, in particular, 3-36, even 3-18 and, even better, 4-12 carbon atoms, and even 4 to 10 carbon atoms.

The above acid includes at least two carboxyl groups COOH, preferably 2 to 4 COOH group.

Preferably, the above-mentioned polycarboxylic acid is aliphatic and includes 3-36 carbon atoms, in particular, 3-18 carbon atoms, and even 4-12 carbon atoms; or the above-mentioned polycarboxylic acid is aromatic and includes 8-12 carbon atoms. It contains, preferably, 2 to 4 COOH group.

Cyclic anhydride of such a polycarboxylic acid, in particular, can meet one of the following formulas:

in which the groups a and b, independently from each other, means:

is a hydrogen atom;

is saturated or unsaturated, linear, branched and/or cyclic aliphatic carbon-containing radical, or aromatic carbon-based radical, containing 1-16 carbon atoms, particularly 2 to 10 the volume of carbon and even 4-8 carbon atoms, in particular methyl or ethyl;

or a and b taken together form a saturated or unsaturated, even aromatic cycle, which includes, in General, 5-7, in particular 6, carbon atoms.

Preferably, a and b denote a hydrogen atom or together form an aromatic cycle, which includes, in General, to 6 carbon atoms.

From polycarboxylic acids or their anhydrides which may be used include, individually or as a mixture:

- dicarboxylic acids, such as decandia acid, dodecandioic acid, cyclopropanecarbonyl acid, cyclohexanecarbonyl acid, cyclobutanecarbonyl acid, naphthalene-1,4-dicarboxylic acid, naphthalene-2,3-dicarboxylic acid, naphthalene-2,6-dicarboxylic acid, subernova acid, oxalic acid, malonic acid, succinic acid, phthalic acid, terephthalic acid, isophthalic acid, tetrahydrophtalic acid, hexahydrophthalic acid, Emelyanova acid, sabotinova acid, azelaic acid, glutaric acid, adipic acid, fumaric acid, maleic acid, taconova acid, dimer fatty acids (in particular with 30 carbon atoms), such as the products sold under the names Pripol 1006, 1009, 1013 and 1017 by the company Uniqema;

- tricarboxylic acid, such as cyclohexanecarboxylate, trimellitate acid, benzene-1,2,3-tricarboxylic acid, benzene-1,3,5-tricarboxylic acid;

- tetracarbonyl acid, such as butanetetracarboxylic acid and pyromellitate acid;

cyclic anhydrides of these acids and, in particular, phthalic anhydride, trimellitic anhydride, maleic anhydride and succinic anhydride.

Preferably, you can use adipic acid, phthalic anhydride and/or isophthalic acid and, even better, one isophthalic acid.

The above polycarboxylic acid and/or its cyclic anhydride is preferably from 5 wt.% up to 40 wt.%, in particular, from 10 wt.% up to 30 wt.%, and, best of all, 14 wt.% up to 25 wt.%, in relation to the total weight of the final polycondensate.

Polycondensate, in addition, may include silicone with hydroxyl group (OH) and/or carboxyl group (COOH).

The silicone may contain 1-3 hydroxyl groups and/or carboxyl groups and, preferably, contains two hydroxyl groups or two carboxyl groups.

These groups can be at the end of the chain or in the chain, but mainly at the end of the chain.

Preferably use silicones, having a mass-average molecular mass (MW), a component of from 300 to 20,000, in particular from 400 to 10,000, and even from 800 to 4000.

This silicone can correspond to the formula:

in which:

- W and W'are, independently from each other, means HE or COOH; preferably, W=W';

p and q, independently from each other 0 or 1;

R and R', independently of one another, mean a divalent carbon-containing, in particular, hydrocarbon, saturated or unsaturated, even aromatic, linear, branched and/or cyclic radical comprising 1 to 12 carbon atoms, especially 2 to 8 carbon atoms, and possibly comprising, in addition, 1 or more heteroatoms chosen among O, S and N, in particular, On (a simple ether);

in particular, R and/or R' can answer the formula -(CH2)and-where a=1-12, and, in particular, means methylene, ethylene, propylene, phenylene;

or the formula[(CH2)xO]z-where x=1, 2, or 3 and z=1-10; in particular, x=2 or 3 and z=1-4; and, best of all, x=3 and z=1;

- R1-R6, independently from each other represent a linear, branched and/or cyclic, saturated or unsaturated, or even aromatic, carbon-based radical containing 1-20 carbon atoms, especially 2 to 12 carbon atoms; preferably, R1-R6 are saturated or aromatic and may be selected, in particular, among the alkyl radicals, in particular methyl, ethyl, propyl, isopropyl, butyl, penttila, hexyl, Attila, decyl, dodecyl and octadecyl; cycloalkyl radicals, especially cyclohexyl; the radicals rolnych, in particular phenyl and naphthyl; arylalkyl radicals, in particular benzyl and phenylethyl; and talila and csilla;

- m and n, independently of one another, denote integers from 1 to 140 and are such that the mass-average molecular mass (MW) silicone ranges from 300 to 20,000, in particular from 400 to 10,000, and even from 800 to 4000.

In particular, can be called α,ω-valpolicellas or α,ω-dicarboxylicacid, and, in particular, α,ω-dialogeditselected and α,ω-dicarboxylicacid-siloxanes; α,ω-dualpolarization or α,ω-dicarboxyl-polyacrilamide, and, in particular, α,ω-diapositivas or α,ω-dicarboxyphenoxy; polyacrilamide with silanol groups, such as polyphenylsiloxane; polyalkyloxy with silanol groups, such as polydimethylsiloxane; polyaryl/alkylsilane with silanol groups, such as polyphenyl/methylsiloxane or even polyphenyl/propylsilane.

In particular the use of α,ω-dialogeditselected with mass-average molecular mass (MW), a component of from 400 to 10,000, even from 500 to 5000, and in particular from 800 to 4000.

When present, the above silicone may range preferably from 0.1 wt.% up to 15 wt.%, in particular, from 1 wt.% up to 10 wt.%, and even from 2 wt.% up to 8 wt.%, in relation to the weight of policemen the ATA.

According to one variant of implementation, the first complex of the polyester can be obtained by reacting:

- at least one polyol comprising 3-6 hydroxyl groups;

at least one nonaromatic branched monocarboxylic acid comprising 6-32 hydrogen atoms;

- at least one aromatic monocarboxylic acid comprising 7 to 11 carbon atoms;

at least one polycarboxylic acid comprising at least 2 carboxyl groups COOH and/or a cyclic anhydride of such a polycarboxylic acid.

According to one variant of implementation, the second complex of the polyester can be obtained by reacting:

- at least one polyol comprising 3-6 hydroxyl groups;

at least one nonaromatic linear monocarboxylic acid, including 6-32 hydrogen atoms;

- at least one aromatic monocarboxylic acid comprising 7 to 11 carbon atoms;

at least one polycarboxylic acid comprising at least 2 carboxyl groups COOH and/or a cyclic anhydride of such a polycarboxylic acid.

Preferably, the non-aromatic monocarboxylic acid does not contain a free group HE.

According to one variant of implementation, polycondensate can be obtained in which aimogasta:

- 10-30 wt.%, with respect to the total mass of polycondensate at least one polyol comprising 3-6 hydroxyl groups;

- 30-80 wt.%, with respect to the total mass of polycondensate at least one non-aromatic, saturated or unsaturated, linear or branched, depending on a complex of the polyester, which wish to receive) monocarboxylic acids, including 6-32 carbon atoms;

the 0.1 - 10 wt.%, with respect to the total mass of polycondensate at least one aromatic monocarboxylic acid comprising 7 to 11 carbon atoms, which may additionally substituted by 1-3 saturated or unsaturated, linear, branched and/or cyclic alkyl radicals comprising 1-32 carbon atoms;

- 5-40 wt.%, with respect to the total mass of polycondensate at least one saturated or unsaturated, even aromatic, linear, branched and/or cyclic polycarboxylic acid comprising at least 2 carboxyl groups COOH, in particular 2 to 4 COOH group and/or a cyclic anhydride of such a polycarboxylic acid.

According to one variant of implementation of the above polycondensate can be obtained by reacting:

- 15-30 wt.%, with respect to the total mass of polycondensate at least one polyol comprising 3-6 hydroxyl groups;

5-40 wt.%, with respect to the total mass of polycondensate at least one non-aromatic, saturated or unsaturated, linear or branched, depending on a complex of the polyester, which wish to receive) monocarboxylic acids, including 6-32 carbon atoms;

- 10-55 wt.%, with respect to the total mass of polycondensate at least one aromatic monocarboxylic acid comprising 7 to 11 carbon atoms, which may additionally substituted by 1-3 saturated or unsaturated, linear, branched and/or cyclic alkyl radicals comprising 1-32 carbon atoms;

- 10-25 wt.%, with respect to the total mass of polycondensate at least one saturated or unsaturated, even aromatic, linear, branched and/or cyclic polycarboxylic acid comprising at least 2 carboxyl groups COOH, in particular 2 to 4 COOH group and/or a cyclic anhydride of such a polycarboxylic acid.

Preferably, the first complex of the polyester can be obtained by reacting:

- at least one polyol chosen, individually or in the form of a mixture, among hexane-1,2,6-triol, trimethanolamine, trimethylolpropane, glycerol, pentaerythritol, eritria, diglycerin, detromethorphan, xylitol, sorbitol, mannitol, dipentaerythritol and/or triglyceride; in number is the number, preferably 10-30 wt.%, in particular, 12-25 wt.%, and, best of all, 14-22 wt.%, in relation to the total weight of the final polycondensate;

at least one nonaromatic branched monocarboxylic acid chosen, individually or in the form of a mixture, among isoheptane acid, 4-ethylpentane acid, 2-ethylhexanoic acid, 4,5-dimethylhexanoic acid, 2-heptylate acid, 3,5,5-trimethylhexanoic acid, isooctanol acid, isononanoic acid, ezoterikovou acid; in number, preferably 30-80 wt.%, in particular, 40-75 wt.%, and, best of all, 45-70 wt.%, in relation to the total weight of the final polycondensate;

- at least one aromatic monocarboxylic acid chosen, individually or in the form of a mixture, among benzoic acid, o-Truelove acid, m-Truelove acid, p-Truelove acid, 1-naphthoic acid, 2-naphthoic acid, 4-tert-butylbenzoic acid, 1-methyl-2-naphthoic acid, 2-isopropyl-1-naphthoic acid; in the amount of, preferably, 0.1 to 10 wt.%, in particular, 1-9,5 wt.%, and even 1.5 to 8 wt.%, in relation to the total weight of the final polycondensate; and

at least one polycarboxylic acid or one of its anhydrides chosen(ICDO), individually or in the form of a mixture, among sabatinovka acid, dodecandioic acid, cyclopropane the oil acid, cyclohexanedicarboxylic acid, cyclobutanedicarboxylic acid, naphthalene-1,4-dicarboxylic acid, naphthalene-2,3-dicarboxylic acid, naphthalene-2,6-dicarboxylic acid, subernova acid, oxalic acid, malonic acid, succinic acid, phthalic acid, terephthalic acid, isophthalic acid, pipelinewall acid, sabatinovka acid, azelaic acid, glutaric acid, adipic acid, fumaric acid, maleic acid, cyclohexanecarboxylic acid, trimellitic acid, benzene-1,2,3-tricarboxylic acid, benzene-1,3,5-tricarboxylic acid, butanetetracarboxylic acid, pyromellitic acid, phthalic anhydride, anhydride trimellitic, maleic anhydride and succinic anhydride; situated (located) in an amount of, preferably 5-40 wt.%, in particular, 10-30 wt.%, and, best of all, 14-25 wt.%, in relation to the total weight of the final polycondensate.

Preferably, the second complex of the polyester can be obtained by reacting:

- at least one polyol chosen, individually or in the form of a mixture, among hexane-1,2,6-triol, trimethylol-ethane, trimethylolpropane, glycerol, pentaerythritol, eritria, diglycerin, detromethorphan, xylitol, sorbitol, mannitol, dipentaerythritol and/or triglyceride; in number, preferably 10-30 wt.%, in the osobennosti, 12-25 wt.%, and, best of all, 14-22 wt.%, in relation to the total weight of the final polycondensate;

at least one nonaromatic linear monocarboxylic acid chosen, individually or in the form of a mixture, among Caproic acid, Caprylic acid, octanoic acid, nonnovel acid, decanoas acid, lauric acid, tridecanoic acid, myristic acid, palmitic acid, stearic acid, arachnid acid, beganovi acid, arotinolol (hexacosanol) acid; in number, preferably 30-80 wt.%, in particular, 40-75 wt.%, and, best of all, 45-70 wt.%, in relation to the total weight of the final polycondensate;

- at least one aromatic monocarboxylic acid chosen, individually or in the form of a mixture, among benzoic acid, o-Truelove acid, m-Truelove acid, p-Truelove acid, 1-naphthoic acid, 2-naphthoic acid, 4-tert-butylbenzoic acid, 1-methyl-2-naphthoic acid, 2-isopropyl-1-naphthoic acid; in the amount of, preferably, 0.1 to 10 wt.%, in particular, 1-9,5 wt.%, and even 1.5 to 8 wt.%, in relation to the total weight of the final polycondensate; and

at least one polycarboxylic acid or one of its anhydrides chosen(ICDO), individually or in the form of a mixture, among decandiol acid, dodecandioic acid, cyclopropane is karbonovoi acid, cyclohexanedicarboxylic acid, cyclobutanedicarboxylic acid, naphthalene-1,4-dicarboxylic acid, naphthalene-2,3-dicarboxylic acid, naphthalene-2,6-dicarboxylic acid, subernova acid, oxalic acid, malonic acid, succinic acid, phthalic acid, Tere-phthalic acid, isophthalic acid, pipelinewall acid, sabatinovka acid, azelaic acid, glutaric acid, adipic acid, fumaric acid, maleic acid, cyclohexanecarboxylic acid, trimellitic acid, benzene-1,2,3-tricarboxylic acid, benzene-1,3,5-tricarboxylic acid, butanetetracarboxylic acid, pyromellitic acid, phthalic anhydride, trimellitate anhydride, maleic anhydride and succinic anhydride; situated(located) in an amount of, preferably 5-40 wt.%, in particular, 10-30 wt.%, and, best of all, 14-25 wt.%, in relation to the total weight of the final polycondensate.

According to another variant implementation of the first polycondensate and second polycondensate, both can be obtained by reacting:

- 10-30 wt.%, with respect to the total mass of polycondensate at least one polyol comprising 3-6 hydroxyl groups;

- 22-80 wt.%, with respect to the total mass of polycondensate at least one non-aromatic, saturated or unsaturated, branched monocarboxylate, includes 10-32 carbon atoms and having a melting point above or equal to 25°C;

- 0.1 to 35 wt.%, with respect to the total mass of polycondensate at least one non-aromatic, saturated or unsaturated, linear monocarboxylic acid, including 6-32 carbon atoms and having a melting point strictly below 25°C;

the 0.1 - 10 wt.%, with respect to the total mass of polycondensate at least one aromatic monocarboxylic acid comprising 7 to 11 carbon atoms, which may additionally substituted by 1-3 saturated or unsaturated, linear, branched and/or cyclic alkyl radicals comprising 1-32 carbon atoms;

- 5-40 wt.%, with respect to the total mass of polycondensate at least one saturated or unsaturated, even aromatic, linear, branched and/or cyclic polycarboxylic acid comprising at least 2 carboxyl groups COOH, in particular 2 to 4 COOH group and/or a cyclic anhydride of such a polycarboxylic acid.

Preferably, the first polycondensate can be obtained by reacting:

- at least one polyol chosen, individually or as mixtures, include glycerol, pentaerythritol, sorbitol and mixtures thereof, and, even better, one of pentaerythritol; in the amount of 10-30 wt.%, in particular, 12-25 wt.%, and l is CSE, 14-22 wt.%, in relation to the total weight of the final polycondensate;

at least one nonaromatic branched monocarboxylic acid chosen, individually or in a mixture of 2-ethylhexanoic acid, isooctanol acid, lauric acid, palmitic acid, ezoterikovou acid, isononanoic acid, stearic acid, beganovi acid and mixtures thereof, and, even better, one ezoterikovou acid or one of stearic acid; in the amount of 30-80 wt.%, in particular, 40-75 wt.%, and, best of all, 45-70 wt.%, in relation to the total weight of the final polycondensate;

- at least one aromatic monocarboxylic acid chosen, individually or in the form of a mixture, among benzoic acid, o-Truelove acid, m-Truelove acid, 1-naphthoic acid, and, even better, one benzoic acid; in an amount of 0.1-10 wt.%, in particular, 1-9,5 wt.%, and even 1.5 to 8 wt.%, in relation to the total weight of the final polycondensate; and

at least one polycarboxylic acid or one of its anhydrides chosen(ICDO), individually or in the form of a mixture, among phthalic anhydride and isophthalic acid, and, even better, one isophthalic acid; situated(located) in an amount of, preferably 5-40 wt.%, in particular, 10-30 wt.%, and, best of all, 14-25 wt.%, with respect to the total mass to echnolo of polycondensate.

Preferably, the first and/or second polycondensate have:

acid number, expressed in mg of potassium hydroxide per g of polycondensate, higher than or equal to 1; in particular comprising from 2 to 30 and, even better, of 2.5 to 15; and/or

- hydroxyl value, expressed in mg of potassium hydroxide per g of polycondensate, above or equal to 40; in particular comprising from 40 to 120 and, even better, of 45 to 80.

These acid and hydroxyl number can be easily determined by a person skilled in the field of conventional analytical methods.

Preferably, the first and/or second polycondensate has a mass-average molecular mass (MW), component from 1,500 to 300,000, even from 2,000 to 200,000 and in particular from 3000 to 100000.

The mass-average molecular weight can be determined by gel permeation chromatography or light diffusing depending on the solubility of the considered polymer.

Preferably, the first and/or second polycondensate has a viscosity, measured at a temperature of 110°C., comprising from 20 MPa·s to 4000 MPa·s, in particular from 30 MPa·s to 3500 MPa·s, even from 40 MPa·s to 3,000 MPa·s and, preferably, from 50 MPa·s to 2500 MPa·satu viscosity measure described before example method.

The first and/or second polycondensate can be obtained by means of esterification/polycondensation, usually is used by the person skilled in the art. As an illustration, a common way to obtain is:

in the mixture of polyol and aromatic and non-aromatic monocarboxylic acids,

in the heated mixture, in an inert atmosphere, first up to the melting temperature (usually 100-130°C) and then to a temperature in the range from 150°C to 220°C until complete consumption of monocarboxylic acids (achieved when the acid number of less than or equal to 1), preferably, gradually driving the formed water, then,

- if necessary, cooling the mixture to a temperature in the range from 90°C to 150°C,

- adding a polycarboxylic acid and/or a cyclic anhydride and optionally a silicone with hydroxyl or carboxyl groups, at one time or sequentially, then

- in heated again to a temperature below or equal to 220°C., in particular in the range from 170°C to 220°C, preferably while continuing to remove water formed, until the required characteristics in relation to the acid number, viscosity, hydroxyl number and solubility.

You can add the usual catalysts for the esterification reaction, such as sulfonic acids (in particular, the mass concentration of from 1% to 10%) or type titanate (in particular, the mass concentration of from 5 hours/million to 100 hours/million).

The reaction can also be carried out, wholly or partly, in an inert Rast is oricale, such as xylene, and/or under reduced pressure, to facilitate the removal of water. Preimushestvenno, do not use any catalyst or solvent.

The above method of obtaining may include, in addition, the stage adding to the reaction medium, at least one antioxidant in particular, the mass concentration of from 0.01% to 1%, relative to the total weight of the monomers, with the aim of limiting the possible destruction associated with prolonged heating.

The antioxidant may be the primary type secondary type and may be selected among spatial difficult phenols, secondary aromatic amines, phosphorus compounds, sulfur-containing compounds, lactones, activepanel and mixtures thereof.

Particularly preferred antioxidants include, in particular, BHT, BHA, TBHQ, 1,3,5-trimethyl-2,4,6-Tris(3,5-di-tert-butyl-4-hydroxybenzyl)benzene, octadecyl-3,5-di-tert-butyl-4-hydroxycinnamic, metanarrative-3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate, 2,5-di-tert-butylhydroquinone-octadecyl-3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate, 2,2-methylbis(4-methyl-6-tert-butylphenol), 2,2-Methylenebis(4-ethyl-6-tert-butylphenol), 4,4-butylidene(6-tert-butyl-m-cresol), N,N-hexamethylenebis(3,5-di-tert-butyl-4-hydroxyhydrocinnamate-amide); pentaerithrityl(3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate), and the hour of the activity, one, manufactured by CIBA under the name IRGANOX 1010; octadecyl-3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate, in particular, one manufactured by CIBA under the name IRGANOX 1076; 1,3,5-Tris(3,5-di-tert-butyl-4-hydroxybenzyl)-1,3,5-triazine-2,4,6-(1H,3H,5H)Trion, in particular, one manufactured by Mayzo of Norcross, Ga, under the name BNX 3114; di(stearyl)-pentaerythrityl; Tris(2,4-di-tert-butylphenyl)FOSFA, in particular, one manufactured by CIBA under the name IRGAFOS 168; delayintolerant, in particular, one manufactured by CIBA under the name IRGANOX PS800; bis(2,4-di-tert-butyl)pentaerithritol, in particular, one manufactured by CIBA under the name IRGAFOS 126; bis(2,4-bis)[2-phenylpropane-2-yl]phenyl)pentaerythrityl; triphenylphosphite; (2,4-di-tert-butylphenyl)pentaerythrityl, in particular, such manufactured by GE Specialty Chemicals under the name ULTRANOX 626; Tris(nonylphenyl)FOSFA, in particular, one manufactured by CIBA under the name IRGAFOS TNPP; a mixture in the ratio of 1:1 N,N-hexamethylenebis(3,5-di-tert-butyl-4-hydroxyhydrocinnamate) and Tris(2,4-di-tert-butylphenyl)-phosphate, in particular, such, manufactured by CIBA under the name IRGANOX B 1171; tetrakis(2,4-di-tert-butylphenyl)FOSFA, in particular, one manufactured by CIBA under the name IRGAFOS P-EPQ; distearyldimonium, in particular, one manufactured by CIBA under the name IRGNOX PS802; 2,4-bis(actitioner)-o-cresol, in particular, one manufactured by CIBA under the name IRGANOX 1520; 4,6-bis(dodecylthiomethyl)-o-cresol, in particular, one manufactured by CIBA under the name IRGANOX 1726.

The first complex of the polyester can mainly be in the total amount of 1 wt.% up to 50 wt.%, particularly, from 10 wt.% up to 45 wt.%, and even from 10 wt.% up to 20 wt.%, in relation to the weight of the composition.

The second complex of the polyester can mainly be in the total quantity of 0.1 wt.% up to 20 wt.%, particularly, from 0.2 wt.% up to 10 wt.%, and even from 0.5 wt.% up to 2 wt.%, in relation to the weight of the composition.

The total number of polyesters, located in the compositions depends, of course, on the type of composition and the desired properties and may vary within a very wide range usually from 0.1 wt.% up to 70 wt.%, preferably, from 1 wt.% up to 50 wt.%, in particular, from 10 wt.% up to 45 wt.%, even from 20 wt.% up to 40 wt.%, and, better, from 25 wt.% up to 35 wt.%, in relation to the weight of the cosmetic compositions.

According to one variant of implementation of the total number of polycondensate is from 10 wt.% up to 20 wt.%.

Non-volatile oil

The composition according to the present invention mainly includes non-volatile oil. Non-volatile oil may be from 1 wt.% up to 90 wt.% the composition, in particular from 5 wt.% up to 75 wt.%, the particular from 10 wt.% up to 60 wt.%, even from 25 wt.% up to 55 wt.%, in relation to the total weight of the composition.

According to one variant of implementation of the non-volatile oil may be from 35 wt.% up to 60 wt.%.

In the sense of the present invention, the term "non-volatile oil" means the oil has a vapor pressure below of 0.13 PA. Non-volatile oil may be a hydrocarbon oils, silicone oils, fluorinated oils or mixtures thereof.

In the sense of the present invention, the term "silicone oil" means the oil comprising at least one silicon atom and, in particular, at least one group Si-O.

The term "hydrocarbon oil" means the oil containing mainly hydrogen atoms and carbon atoms and possibly oxygen, nitrogen, sulfur and/or phosphorus.

The term "hydrocarbon" means the oil containing only atoms of hydrogen and carbon.

Non-volatile oils may be chosen, in particular, among hydrocarbon oils, if necessary, fluorinated and/or non-volatile silicone oils.

As non-volatile hydrocarbon oils can, in particular, include:

hydrocarbon oils of vegetable origin, such as phytosterolemia esters, such as phytosterolemia, phytosterolaemia and lauroyl/octyldodecyl/phytosteryl-glutamate (AJINOMOTO; ELDEW PS203); triglycer the water, formed by esters of fatty acids and of glycerol, the fatty acids of which can have a length of chain, changing from C4to C24and these latter can be linear or branched, saturated or unsaturated; these oils are, in particular, heptane or octane triglycerides; wheatgerm oil, sunflower oil, grape seed oil, sesame oil, corn oil, apricot oil, castor oil, tallow tree oil, avocado oil, olive oil, soybean oil, sweet almond oil, palm oil, rapeseed oil, cottonseed oil, peanut oil, Australian nut, oil str, oil, alfalfa oil, poppy oil from Chinese pumpkin, pumpkin oil, blackcurrant oil from evening primrose oil from millet oil, barley oil, quinoa oil, rye, safflower oil, Tung oil Molucca, passifloraceae oil, rose Muscat; oil tallow tree; or more triglycerides of Caprylic/capric acids, such as manufactured by the company STEARINERIES DUBOIS or those manufactured by DYNAMIT NOBEL under the names MIGLYOL 810®, 812®and 818®;

- synthetic ethers, containing 10-40 carbon atoms;

- linear or branched, mineral or synthetic origin, hydrocarbons such as vaseline, polydecene, hydrogenated polyisobutene, such as Parleam®, squalane, and mixtures thereof, and, in particular, hydrogenated polyisobutene;

- synthetic esters, such as oils of formula R1COOR2in which R1means the residue of a linear or branched acid containing 1 to 40 carbon atoms, and R2means a hydrocarbon chain, especially branched, containing 1 to 40 carbon atoms, provided that the sum of R1+R2is ≥10.

Esters may be chosen, in particular, among the esters, in particular fatty acids, as, for example, chemosterilant; esters of isopropyl alcohol, such as isopropylmyristate, isopropyl, Etisalat, 2-ethylhexylamine, isopropylene or isopropyltoluene, zosterisessor, attrstart; gidroksilirovanii esters, as isostearate, activitiesthat, diisopropylamide; heptanoate, and, especially, isostearate, octanoate, decanoate or ricinoleate alcohols or polyols, as propilenglikolmonostearata, tetrachromat, tridecylamine, 4-diheptanoate and 2-ethylhexylamine, alkylbenzoic, polietilenglikolmonostearat, propylene glycol-2-diethylhexanoate and mixtures thereof; benzoate alcohols with C12-C15, exellent, esters neopentanoate acid, as istallment is not, isotretinoinsee, isostearate, octyldodecanol; esters of isononanoic acid, as isononylphenol, isotridecyl-isononanoate, octyldodecanol; gidroksilirovanii esters, as isostearate, diisostearate;

- esters of polyols and esters of pentaerythritol, as dipentaerythritol/tetraisostearate;

liquid at room temperature alcohols with branched and/or unsaturated carbon chain with 12-26 carbon atoms such as 2-octyldodecanol, isostearoyl alcohol, oleic alcohol, 2-hexyldecanol, 2-butyloctyl and 2-underinternational;

higher fatty acids such as oleic acid, linoleic acid, linolenic acid and mixtures thereof; and

- diallylmalonate, and the 2 alkyl chains may be identical or different, such as disabilitant manufactured by the company COGNIS under the name CETIOL CC®.

Used in the composition of non-volatile silicone oil may be a non-volatile polydimethylsiloxane (PDMS); polydimethylsiloxane, including side and/or on the ends of the silicone chain alkyl or CNS group, and groups, each contains 2-24 carbon atoms; phenylaziridine silicones, as penultimately, penultimately, phenyltrimethoxysilane, difenidol the icons, divinyltetramethyldisiloxane and 2-phenylethylenediamine, Dimethicone or penultimately with a viscosity of less than or equal to 100 cSt, and mixtures thereof.

According to another variant implementation of the silicone oil corresponds to the formula:

in which groups R represent independently of each other, methyl or phenyl. Preferably, according to this formula, the above organopolysiloxane includes at least three phenyl groups, for example, at least four or at least five phenyl groups. Can be used the above mixture containing phenyl groups organopolysiloxanes.

As examples of the mixture of organopolysiloxanes with three, four or five phenyl groups.

According to another variant implementation of the silicone oil corresponds to the formula:

in which Me denotes methyl and Ph denotes phenyl. This forsterei silicone, in particular, is issued by the company Dow Corning under the name Dow Corning 555 Cosmetic Fluid (named according to the nomenclature of the Association for perfume and cosmetic products and fragrances (INCI): trimethylenetrinitramine). Can also be used the designation Dow Corning 555 Cosmetic Fluid.

Non-volatile oil is preferably non-polar in the sense that its argument races is foremost Delta is equal to 0.

Wax

The composition may contain a wax. Under the wax, in the sense of the present invention, see lipophilic compound, solid at room temperature (25°C), with a reversible change of state solid/liquid having a melting point above or equal to 30°C, which can reach up to 120°C.

The melting point of the wax may be determined using a differential scanning calorimeter (D.S.C.), such as a calorimeter, manufactured by METTLER under the name DSC 30.

The waxes may be hydrocarbon, fluorinated and/or silicone. In particular, the waxes have a melting point above 25°C or better above 45°C.

As the wax used as the primary, can be called a linear hydrocarbon waxes. Their melting point is preferably above 35°C, for example, above 55°C, preferably above 80°C.

Linear hydrocarbon waxes mainly choose among substituted linear alkanes, unsubstituted linear alkanes, unsubstituted linear alkenes, substituted linear alkenes, and unsubstituted connection represents a connection of only carbon and hydrogen. The above substituents do not contain carbon atoms.

Linear hydrocarbon waxes include polymers and copolymers of ethylene with a molecular weight of from 400 to 800, for example, Polywax 500 is whether Polywax 400, manufactured by the company New Phase Technologies.

Linear hydrocarbon waxes include waxes on the basis of linear paraffins, as paraffins S&P 206, S&P 173 and S&P 434 manufactured by the company Strahl &Pitsch.

Linear hydrocarbon waxes include linear alcohols with long chain, like products, comprising a mixture of polyethylene and alcohols with the number of carbon atoms is from 20 to 50, in particular, Performacol 425 or Performacol 550 (mixture in ratio 20/80), produced by the company New Phase Technologies.

Examples of silicone waxes are, for example,

- C20-24-alkylation,24-28-alkyldimethyl,20-24-alkyldimethyl,24-28-alkyldimethyl manufactured by Archimica Fine Chemicals called SilCare 41M40, SilCare 41M50, SilCare 41M70 and SilCare 41M80;

- sterilisation called SilCare 41M65 manufactured by Archimica, or sterilisation called DC-2503, manufactured by Dow-Corning;

- starextremely, marketed under the name SilCare 1M71 or DC-580;

products ABIL WAX 9810, 9800 or 2440, manufactured by Wacker-Chemie GmbH;30-45-alkylation manufactured by Dow-Corning under the name AMS-C30 Wax, just as With30-45-alkyldimethyl, marketed under the name SF-1642 or SF-1632 by the company General Electric.

The amount of wax in the composition according to the invention may range from 5 wt.% up to 70 wt.%, in relation to the total weight of the composition, preferably from 5 wt.% up to 40 wt%, and, better, from 10 wt.% up to 30 wt.%.

Dye

The composition according to the invention may contain a dye in an amount of from 0.5 wt.% up to 50 wt.% the coloring matter, preferably from 2 wt.% up to 40 wt.% and, better, from 5 wt.% up to 30 wt.%, in relation to the total weight of the composition.

Dye may be any inorganic and/or organic compound which has absorption in the wavelength range of 350-700 nm or capable of generating optical effect, as, for example, reflection of incident light or interference.

Dyes usable according to the present invention, is chosen among all known in the art of organic and/or inorganic pigments, in particular, those that describe the Kirk-Othmer in "encyclopedia of chemical technology" and Ullmann in "encyclopedia of industrial chemistry".

As examples of inorganic pigments can be called a processed or unprocessed on the surface of titanium dioxide, zinc oxide, oxides of zirconium or cerium, iron oxides or chromium, manganese violet, ultramarine blue, chromium hydrate and ferrous sulfate. For example, can be used the following inorganic pigments: TA2About5, Ti3O5, Ti2O3, TiO, ZrO2in the form of a mixture of TiO2, ZrO2, Nb2O5 CeO2, ZnS.

As examples of organic pigments can be called a nitroso, nitro, azo compounds, xanthene, quinoline, anthraquinone, phthalocyanine, type metal complex, isoindoline, isoindoline, chinagreen, perinon, fixed, diketopiperazines, thioindigo, dioxazine, triphenylmethane, chieftain.

In particular, the dyes can be selected among Carmine, (gas) carbon black, aniline black, azo yellow, chinagreen, phthalocyaninato blue, sorghum red, the blue pigments codified in the Color Index under the designations CI 42090, 69800, 69825, 73000, 74100, 74160; the yellow pigments codified in the Color Index under the designations CI 11680, 11710, 15985, 19140, 20040, 21100, 21108, 47000, 47005; green pigments codified in the Color Index under the designations CI 61565, 61570, 74260; orange pigments, codified in the Color Index under the designations CI 11725, 15510, 45370, 71105; red pigments codified in the Color Index under the designations CI 12085, 12120, 12370, 12420, 12490, 14700, 15525, 15580, 15620, 15630, 15800, 15850, 15865, 15880, 17200, 26100, 45380, 45410, 58000, 73360, 73915, 75470; the pigments obtained by oxidative polymerization of indole derivatives, phenol derivatives, such as described in French patent 2679771.

The pigments according to the invention can also be in the form of composite pigments, such as those described in European patent 1184426. These composite pig the coefficients can be formed particles, comprising an inorganic core at least one binder, providing fixation of the organic pigments to the core, and at least one organic pigment at least partially covering the core.

Dyes can be selected from among dyes, paints or pigments.

The dyes are, for example, fat-soluble dyes, although there may be used water-soluble dyes. The liposoluble dyes are, for example, Sudan red, D&C red 17, D&C green 6, β-carotene, soybean oil, Sudan brown, D&C yellow 11, D&C violet 2, D&C orange 5, quinoline yellow, annatto. They can be from 0 wt.% up to 20 wt.%, and, better, from 0.1 wt.% up to 6 wt.%, in relation to the weight of the composition. Water-soluble dyes are, in particular, beetroot juice, methylene blue and can range from 0.1 wt.% up to 6 wt.% in relation to the weight of the composition (if present).

Under varnish understand adsorbiruyuschee on insoluble particles, dyes, and thus the resulting set of remains insoluble during use. Inorganic substrates, on which the adsorbed dyes are, for example, aluminum oxide, silicon dioxide, calculateresult or calceolariaceae and aluminum. From the organic to the of asiala can be called cochineal Carmine.

As examples of varnishes can be called the products known under the following names: D&C red 21 (CI 45380), D&C orange 5 (CI 45370), D&C red 27 (CI 45410), D&C orange 10 (CI 45425), D&C red 3 (CI 45430), D&C red 7 (CI 15850:1), D&C red 4 (CI 15510), D&C red 33 (CI 17200), D&C yellow 5 (CI 19140), D&C yellow 6 (CI 15985), D&C green (CI 61570), D&C yellow 1 (CI 77002), D&C green 3 (CI 42053), D&C blue 1 (CI 42090).

Under the pigments need to understand white or colored, inorganic or organic particles intended to color and/or imparting opacity of the composition. The pigments according to the invention can be selected, for example, among white or colored pigments, pigments with special effects, such as parametry reflecting pigments or interference pigments.

As pigments used according to the invention include oxides of titanium, zirconium or cerium, as well as oxides of zinc, iron or chromium, and iron sulfate. Organic pigments used according to the invention, can be called (gas) carbon black and barium lacquer, strontium lacquer, calcium varnish (D&C red No. 7), aluminum lacquer.

Parametry may be present in the composition in amounts of 0.001-20% relative to the total weight of the composition, preferably in an amount of about 1-15%. Used according to the invention basecoat can nazvat the mica, covered with titanium oxide, with iron oxide, with natural pigment or with bismuth oxychloride, such as colored Taanilinna mica.

The pigments may be present in the compositions in amounts of 0.05-30% relative to the weight of the final composition, and preferably in the amount of 2-20%.

The variety of pigments which can be used according to the present invention allows to obtain a rich palette of colors, as well as to achieve special optical effects such as metallic or interference effects.

Under the pigments with special effects understand the pigments, which, as a rule, create a colored appearance (characterized by a certain tone, a certain brightness and a certain lightness), heterogeneous and iridescent depending on observation conditions (light, temperature, angles). They are the opposite of also white or colored pigments, which provide a homogeneous opaque, translucent or transparent classic hue.

As examples of pigments with special effects can be called white pearlescent pigments, such as titanium or with bismuth oxychloride, mica, colored pearlescent pigments, such as titanium and iron oxides, mica coated with titanium and, especially, iron sulphate is m or chromium oxide, mica, titanium and an organic pigment such as specified above, mica and pearlescent pigments based on bismuth oxychloride. As pearlescent pigments can be called parametry Cellini, manufactured by Engelhard (Lac mica-TiO2), Prestige, manufactured by Eckart (mica-TiO2), Colorana manufactured by Merck (mica-TiO2-Fe2O3).

You can also call the pigments with an interference effect, not fixed on the substrate as liquid crystals (Helicones HC, Wacker), interference holographic flake crystals (geometric pigments or Spectra f/x, the firm Spectratek). Pigments with special effects also include fluorescent pigments, which are fluorescent in daylight or substance which generate ultraviolet fluorescence, phosphorescent pigments, photochromic pigments and thermochromic pigments.

Composition mainly contains goniochromism pigments, such as multilayer interference pigments and/or reflecting pigments. These two types of pigments are described in the patent application France 0209246, the contents of which are incorporated into the present application by reference.

The composition may contain reflective pigments that can be goniochromism or no interference or not.

Their size is ovestin with the manifestation of specular reflection of visible light (400-700 nm) of sufficient intensity considering the average gloss of the composition, to create a degree of excessive Shine. This size may vary depending on the chemical nature of the particles, their shape and their ability to specular reflection of visible light.

Reflecting particles preferably have a size of at least 10 μm, for example, in the range from about 20 microns to about 50 microns.

The term "size" means the amount determined by the statistical particle size distribution to half of the population, the so-called D50. The size of the reflecting particles may depend on the state of their surface. The more pigment is reflecting the less, a priori, should be the size, and Vice versa.

Reflecting particles used according to the invention, with a metal or white glare can reflect light in the case of all components of the visible part of the spectrum without absorption significantly in relation to one or more wavelengths. The spectral reflectance of these reflective particles may be, for example, above 70% in the range of 400-700 nm, and better, at least 80%, even 90% or even 95%.

Reflecting particles, whatever their form, can be layered or no structure and, in the case of a multilayer structure, for example, can have at least one layer of a uniform thickness, in particular, reflect the its material, which covers the substrate.

The substrate may be selected from among glass, ceramics, graphite, metal oxides, alumina, silica, silicates, in particular aluminosilicates and borosilicates, and synthetic mica, and this list is not exhaustive.

The reflective material may include a metal layer or metal link.

The metal layer or metal link may or not fully cover the substrate and the metal layer may at least partially be overlapped by a layer of another material, for example, a transparent material. It may be preferable that the metal layer or metal link covers the substrate completely, directly or indirectly, that is, with the interposition of at least intermediate, metal or not, of the layer.

The metal may be selected among, for example, Ag, Au, Cu, Al, Ni, Sn, Mg, Cr, Mo, Ti, Pt, Va, Rb, W, Zn, Ge, Te, Se, and their alloys. Highly preferred are Ag, Au, Al, Zn, Ni, Mo, Cr, Cu and their alloys (such as bronze and brass).

In the case, in particular, particles coated with silver or gold substrate, a metal layer may be in the amount of, for example, 0.1 to 50 wt.%, even 1-20 wt.%, with respect to the total mass of particles.

Particles of glass coated with a metal layer, are described in particular in patent applications Japan JP-A-09188830, JP-A-10158450, JP-A-10158541, JP-A-I JP-A-05017710.

Particles of the substrate made of glass, coated with silver, in the form of plates, are issued by the company TOYAL under the name MICROGLASS METASHINE REFSX 2025 PS. Particles of the substrate made of glass, coated with an alloy of Nickel/chromium/molybdenum produced by the same company under the name CRYSTAL STAR GF 550, GF 25255.

Reflecting particles, whatever their form, can also be selected among the particles of the synthetic substrate coated at least partially, at least one layer, at least one compound of a metal, particularly a metal oxide selected among, for example, oxides of titanium, in particular, TiO2iron, in particular Fe2O3, tin, chromium, barium sulfate and the following compounds: MgF2CrF3, ZnS, ZnSe, SiO2, Al2O3, MgO, Y2O3SeO3, SiO, HfO2, ZrO2CeO2, Nb2O5Ta2O5, MoS2and their mixtures or alloys.

As examples of such particles include, for example, particles consisting of a substrate of synthetic mica coated with titanium dioxide, or particles of glass coated with either brown micaceous iron dye, or titanium oxide, tin oxide or mixtures thereof, as such, issued by the company ENGELHARD under the name REFLECKS®.

According to the invention is also suitable pigments range METASHINE 1080R, manufactured by NIPPON SHEET GLASS CO. LTD. These pigments, bol is e specifically described in the patent application of Japan 2001-11340, are shards of glass C-GLASS, including 65-72% SiO2covered with a layer of titanium oxide of rutile (TiO2). These shards of glass have an average thickness of 1 μm and an average size of 80 microns, or the ratio of the average size: average thickness is 80. They have blue, green, yellow glares or reflections silver tone depending on the thickness of TiO2.

You can still be called a particle size of from 80 μm to 100 μm, consisting of a substrate of synthetic mica (perflogger), coated with titanium dioxide, comprising 12 wt.% with respect to the total mass of the particles, manufactured by NIHON KOKEN called PROMINENCE.

The reflective particles may be selected among the particles formed by the set of at least two layers with different refractive indices. These layers can be polymeric or metallic nature and, in particular, include at least one polymer layer. Such particles are described, in particular, in the International application WO 99/36477, U.S. patents 6299979 and 6387498. To illustrate materials, which may consist of different layers of the multilayer structure include, but not exhaustively, polyethylenterephthalat (PEN) and isomers, polyalkylacrylate and polyimides. Reflecting particles, consisting of a set of at least two polymeric layers, the release is available from 3M company under the name MIRROR GLITTER. These particles include layers of 2,6-PEN and polymethyl methacrylate in a weight ratio of 80:20. Such particles are described in U.S. patent 5825643.

The composition may contain one or more goniochromism pigments.

Goniochromism the dye can be selected among, for example, multilayer interference structures and liquid dyes.

In the case of a multilayer structure, it may include at least two layers, each layer, independently or not from the other layers (other layers)is performed, for example, from at least one material selected from the group consisting of the following materials: MgF2, CeF3, ZnS, ZnSe, Si, SiO2, Ge, Te, Fe2O3, Pt, Va, Al2O3, MgO, Y2O3, S2O3, SiO, HfO2, ZrO2CeO2, Nb2O5Ta2O5, TiO2, Ag, Al, Au, Cu, Rb, Ti, Ta, W, Zn, MoS2, cryolite, alloys, polymers and combinations thereof.

The multilayer structure may have or not, with respect to the Central layer, the symmetry at the level of the chemical nature superimposed on each layer.

Examples of symmetric interference multilayer structures used according to the invention are, for example, the following structures: Al/SiO2/Al/SiO2/Al, and pigments having this structure, produced by DUPONT DE NEMOURS; Cr/gF 2/Al/MgF2/Cr, and pigments having this structure, produced by the firm FLEX under the name CHROMAFLAIR; MoS2/SiO2/Al/SiO2/MoS2; Fe2O3/SiO2/Al/SiO2/Fe2O3and Fe2O3/SiO2/Fe2O3/SiO2/Fe2O3moreover , pigments having these structures, produced by BASF under the name SICOPEARL; MoS2/SiO2/mica-oxide/SiO2/MoS2; Fe2O3/SiO2/mica-oxide/SiO2/Fe2O3; TiO2/SiO2/TiO2and TiO2/Al2O3/TiO2, SnO/TiO2/SiO2/SnO; Fe2O3/SiO2/Fe2O3; SnO/mica/TiO2/SiO2/TiO2/mica/SnO, and pigments having these structures, are produced by the company MERCK (Darmstadt) under the name XIRONA. As an example, these pigments can be a pigment patterns of silica/titanium oxide/tin oxide, produced by the company MERCK under the name XIRONA MAGIC, pigments patterns silica/brown micaceous iron dye manufactured by the company MERCK under the name XIRONA INDIAN SUMMER, and the pigments of the structure of silica/titanium oxide/mica/tin oxide, produced by the company MERCK under the name XIRONA CARIBBEAN BLUE. You can still call pigments INFINITE COLORS company SHISEIDO. Depending on the thickness and nature of the various layers achieve different effects. So, in the case of the structure of e 2O3/SiO2/Al/SiO2/Fe2O3receive from Golden-green to grey-red layer of SiO2at 320-350 nm; from red to Golden for layers of SiO2when 380-400 nm; from violet to green for layers of SiO2at 410-420 nm; from copper to red for layers of SiO2at 430-440 nm.

You can still use goniochromism dyes with a multilayer structure comprising alternating polymeric layers, for example, type polyethylenterephtalate and polyethylene terephthalate. Such dyes are described, in particular, in International applications WO-A-96/19347 and WO-A-99/36478.

As examples, the pigments with a polymeric multilayer structure pigments manufactured by the 3M company under the name COLOR GLITTER.

Liquid dyes include, for example, silicones or ethers of cellulose, to which is grafted mesomorphic group.

As the liquid crystal goniochromism particles can be used, for example, those manufactured by CHENIX, and also manufactured by the company WACKER under the name HELICONE®.

Compositions according to the invention can be in any reasonable and customary for cosmetic compositions form.

The expert can select the appropriate herbal form, and how it is received, on the basis of his General knowledge in this field, taking into account, od the first side, the nature of the used components, in particular their solubility in the base, and, on the other hand, envisaged for the composition of the application.

Compositions according to the invention can be used for cosmetic care or makeup such keratin surfaces, such as hair, skin, eyelashes, eyebrows, nails, lips, hair (of the skull) and, more specifically, makeup lips, eyelashes and/or faces.

Therefore, they can be in the form of funds for cosmetic care and/or makeup of the skin of the body or of the face, lips, eyelashes, eyebrows, hair, hairline (skull) or nails; tanning or fake tan preparations; hair, in particular, for dyeing, conditioning the hair and/or hair care; they are mainly in the form of mascara, lipstick, lip gloss (Shine), blush or eyeshadow, tonal resources.

The object of the present invention is also the use of two different polycondensates, such as described in the above context, in particular, in the proportions and chemical composition described above in the case makeup of the lips, to improve the color stability over time.

The object of the present invention is a method of cosmetic treatment of keratin surfaces, in particular the skin of the body or of the face, lips, nails, hair and/or re is SIC, including the application of the above-mentioned surface of the cosmetic compositions, such as the above.

This method according to the invention allows, in particular, a cosmetic care or makeup case lip by applying a composition in the form of a lipstick or lip gloss (Shine) according to the invention.

The invention also relates to the use of the above compositions makeup lip.

The object of the present invention is also a cosmetic package including:

- capacity limiting at least one branch, and the above-mentioned container is closed by a positive fastening element; and

- the composition, such as the above, inside the above branch.

The capacity can be in any appropriate manner. In particular, it may be in the form of bottles, tubes, jars, boxes, bottle, sachet or pouch.

The locking element may be in the form of removable plugs, cap, blasting cap detonator, torn tape or capsule, especially of the type comprising a body, fixed on the container, and articulated with the body of the cap. It can also be in the form of item, provide selective closure of the container, in particular a pump, valve or valve.

Capacity may be associated with an applicator, in particular, in the form of a brush comprising an arrangement of hairs, p is deriveth twisted wire. This twisted brush is described in particular in U.S. patent 4887622. The applicator may also be in the form of combs, with many damaging elements obtained, in particular by casting. Such combs are described, for example, in French patent 2796529. The applicator may be in the form of brushes, such as are described, for example, in French patent 2722380. The applicator may be in the form of a block of foam or elastomer, felt or in the form of a spatula. The applicator can be free (powder puff or sponge) or interconnected with the rod which carries the locking element, as described, for example, in U.S. patent 5492426. The applicator may be correlated with the capacity, as described, for example, in French patent 2761959.

The product may be contained directly in the tank, or not directly in the tank. As an example, the product may be impregnowana media, in particular, in the form of flannel or swab, and can be placed (in the form of one unit or more) in a box or sachet. This includes the product carrier is described, for example, in International application WO 01/03538.

The locking element can be connected to the container by screwing. Alternatively, the connection between the locking element and the container is made otherwise than by screwing, in particular, via a bayonet mechanism, with OSU locking mechanism, clamp, weld, adhesive bonding or magnetic attraction. The term "locking mechanism" see, in particular, any system that leads to overcoming thickening or roll of material by elastic deformation part, in particular a locking element, followed by return to the elastically't stress position above the part after overcoming thickening or roller.

The capacity can be at least a part made of thermoplastic material. As examples of thermoplastic materials can be called polypropylene or polyethylene.

Alternatively, the capacity of the carry out from neuroplastic material, in particular of glass or of metal (or alloy).

The capacity can be from the hard walls or with deformable walls, in particular in the form of a tube or bottle tubes.

Capacity may include funds that are intended to implement or facilitate the distribution of the composition. As an example, the capacity can be with deformable walls to call "exit" composition in response to increased pressure inside the tank, and high pressure is generated due to elastic or not elastic) deformation under compression of the vessel wall. Alternatively, particularly when the product is in the form of a cosmetic pencil, this pic the front can be set in motion the piston mechanism. Always in the case of a cosmetic pencil, in particular, means of makeup (lipstick, liquid Foundation, etc), the capacity can include a mechanism, in particular, with rack-and-pinion drive or a rod with a screw thread or helical inclined plane and is able to move the cosmetic pencil in the direction of the above-mentioned holes. Such a mechanism is described, for example, in French patent 2806273 or in French patent 2775566. Such a mechanism for the liquid product is described in the French patent 2727609.

The capacity can be formed by a casing with a bottom limiting, at least, the branch containing the composition, and cover, in particular, articulated to the bottom, and are able to overlap, at least partially, above the bottom. This casing is described, for example, in International application WO 03/018423 and in French patent 2791042.

The container may be provided with a desiccant (utimately), located near the openings of the containers. This dryer allows you to dry the applicator and, if necessary, the rod with which he may be interrelated. This dehumidifier is described, for example, in French patent 2792618.

The composition may be at atmospheric pressure inside the tank (at room temperature) or at elevated pressure, in particular, at the expense of the propellant (aerosol). In this case, the placenta is eaten if the tank is provided with a valve (type any, used for aerosols).

The invention is illustrated in more detail in the following examples.

Method of measuring the viscosity

The viscosity at a temperature of 80°C. or at a temperature of 110°C. the polymer is determined using a cone-plate type viscometer BROOKFIELD CAP 1000+.

Adapted cone-plane determined by the person skilled in the art on the basis of its knowledge, in particular:

- from 50 MPa·s to 500 MPa·s, you can use the cone 02;

from 500 MPa·s to 1000 MPa·s: cone 03;

from 1000 MPa·s to 4000 MPa·s: cone 05;

from 4000 MPa·s to 10,000 MPa·s: cone 06.

Example 1

Synthesis of pentaerythritoltetranitrate/isophthalate/isostearate

In a reactor equipped with mechanical stirring, the input of argon and system for distillation, load 20 g of benzoic acid, 280 g ezoterikovou acid and 100 g of pentaerythritol, then gradually heated in a light current of argon, to a temperature of 110-130°C. to obtain a homogeneous solution. Then the temperature is gradually increased up to 180°C and maintain it for approximately 2 hours. Again increase the temperature up to 220°C and maintain it until an acid number of less than or equal to 1, which is about 11 hours. Cooled to a temperature in the range from 100°C to 130°C, then enter 100 g of isophthalic acid and again gradually heated up to 220°C in t is an increase of approximately 11 hours. Receive, therefore, 405 g of polycondensate of pentaerythritoltetranitrate/isophthalate/isostearate in the form of a very thick oil.

Polycondensate has the following characteristics:

- soluble in the amount of 50 wt.% at 25°C in Parléam;

acid number = 3,7;

- hydroxyl number = 72;

- MW=59400;

- η110°C=1510 MPa·s;

the ratio between the number of moles of aromatic monocarboxylic acid to the number of mol nonaromatic branched monocarboxylic acid: 0,16.

Example 2

Synthesis of pentaerythritoltetranitrate/isophthalate/isostearate

In a reactor equipped with mechanical stirring, the input of argon and system for distillation, load 35 g of benzoic acid, 270 g ezoterikovou acid and 80 g of pentaerythritol, then gradually heated in a light current of argon, to a temperature of 110-130°C. to obtain a homogeneous solution. Then the temperature is gradually increased up to 180°C and maintain it for approximately 2 hours. Again increase the temperature up to 220°C and maintain it until an acid number of less than or equal to 1, which is about 11 hours. Cooled to a temperature in the range from 100°C to 130°C, then give 65 g of isophthalic acid and again gradually heated up to 220°C for about 5 hours. Receive, therefore, 380 g of polycondensate the Penta is retrytimeout/isophthalate/isostearate in the form of oil.

Polycondensate has the following characteristics:

- soluble in the amount of 50 wt.% at 25°C in Parléam;

acid number = 5,5;

- hydroxyl number = 103;

- MW=7200;

- η80°C=700 MPa·s;

the ratio between the number of moles of aromatic monocarboxylic acid to the number of mol nonaromatic branched monocarboxylic acid: 0,30.

Example 3

Synthesis of pentaerythritoltetranitrate/isophthalate/stearate

In a reactor equipped with mechanical stirring, the input of argon and system for distillation, load 10 g of benzoic acid, 370 g of stearic acid and 95 g of pentaerythritol, then gradually heated in a light current of argon, to a temperature of 110-130°C. to obtain a homogeneous solution. Then the temperature is gradually increased up to 180°C and maintain it for approximately 2 hours. Again increase the temperature up to 220°C and maintain it until an acid number of less than or equal to 1, which is about 11 hours. Cooled to a temperature in the range from 100°C to 130°C, then enter 90 g of isophthalic acid and again gradually heated up to 220°C for about 11 hours. Receive, therefore, 430 g of polycondensate of pentaerythritoltetranitrate/isophthalate/stearate in the form of a very thick oil.

Polycondensate has the following characteristics:

- RAS is work in the amount of 50 wt.% at 70°C in Parléam;

acid number = 10, 8mm;

- MW=8800;

- η80°C=360 MPa·S.

Examples A-R

Similar to the previous examples given the following polycondensate (%) mean mass percent).

Polyol (% nature)Aromatic acid (% nature)Polycarboxylic acid or anhydride (% nature)Nah acid (% nature)Solubility*
Example a21.6 pentaerythritol3,9 benzoic19,5 isophthalic acid27.5% of ezoterikova + 27,5% isononanoateat 25°C
Example B16,8 pentaerythritol1,8 benzoic15,9 isophthalic acid65,5 Baganovaat 70°C
Example C20 pentaerythritol4 tert-butylbenzene20 isophthalic acid56 isostearyl the at 25°C
Example D17,4 glycerin8,6 benzoic16 isophthalic acid58 ezoterikovaat 25°C
Example E20,7 glycerin8,5 tert-butylbenzene15,9 adipic acid54,9 isononanoateat 25°C
Example F25.5 diglycerin2 benzoic13,7 isophthalic acid58,8 isononanoateat 25°C
Example G28 detromethorphan2 1-naphthoic14 isophthalic acid56 ezoterikovaat 25°C
Example H25.2 trimethylolpropane5,8 benzoic12,6 isophthalic acid56,3 isononanoateat 25°C
Example I25 trimethylolpropane2.1 m-Truelove14,6 phthalic anhydride58,3 ezoterikovaat 25°C
Example J21.9 aritra6,3 tert-butylbenzene13,5 sabotinova acid58,3 isooctanolat 25°C
Example K20,4 dipentaerythritol6,1 benzoic20,4 PRIPOL 1009**53,1 ezoterikovaat 25°C
Example L28 detromethorphan2 1-naphthoic14 isophthalic acid40% ezoterikova + 16% 2-ethylhexanoateat 25°C
Example M21,3 pentaerythritol6,4 benzoic17 succinic acid27,7% novanova + 27,6% Sagatovaat 25°C
Example N 17,4 glycerin8,6 benzoic16 isophthalic acid58 stearicat 70°C
Example O25.5 diglycerin2 benzoic13,7 isophthalic acid58,8 myristicat 70°C
Example P25.5 diglycerin3,9 benzoic15,7 sabotinova acid54,9 lauricat 70°C
Example Q20,4 dipentaerythritol6,1 benzoic20,4 PRIPOL 1009**53,1 Baganovaat 70°C
Example R25.2 trimethylolpropane5,8 benzoic12,6 isophthalic acid31,1% stearic + 25.3% of Baganovaat 70°C
* "25°C" means that the polymer is soluble in the amount of 50 wt.% at 25°C in Parléam; who at 70°C" means, the polymer is soluble in the amount of 50 wt.% at 70°C in Parléam;
** PRIPOL 1009 d Uniqema: dimer of oleic acid

Example 4

Synthesis of pentaerythritoltetranitrate/isophthalate/isostearate/stearate

In a reactor equipped with mechanical stirring, the input of argon and system for distillation, load 20 g of benzoic acid, 210 g of stearic acid, 70 g ezoterikovou acid and 100 g of pentaerythritol, then gradually heated in a light current of argon, to a temperature of 110-130°C. to obtain a homogeneous solution. Then the temperature is gradually increased up to 180°C and maintain it for approximately 2 hours. Again increase the temperature up to 220°C and maintain it until an acid number of less than or equal to 1, which is about 11 hours. Cooled to a temperature in the range from 100°C to 130°C, then enter 100 g of isophthalic acid and again gradually heated up to 220°C for about 11 hours. Receive, therefore, 450 g of polycondensate of pentaerythritoltetranitrate/isophthalate/isostearate/stearate in the form of a very thick oil.

Polycondensate has the following characteristics:

- soluble in the amount of 50 wt.% at 70°C in Parléam;

acid number = 7,1;

- η110°C=850 MPa·s;

- MW=28500;

- zootoxin the e between the number of moles of aromatic monocarboxylic acid to the number of moles of non-aromatic monocarboxylic acids: 0,166.

Example 5

Synthesis of pentaerythritoltetranitrate/benzoate/isophthalate/isostearate

In a reactor equipped with mechanical stirring, the input of argon and system for distillation, load 20 g of benzoic acid, 140 g of beganovi acid, 140 g ezoterikovou acid and 100 g of pentaerythritol, then gradually heated in a light current of argon, to a temperature of 110-130°C. to obtain a homogeneous solution. Then the temperature is gradually increased up to 180°C and maintain it for approximately 2 hours. Again increase the temperature up to 220°C and maintain it until an acid number of less than or equal to 1, which is about 11 hours. Cooled to a temperature in the range from 100°C to 130°C, then enter 100 g of isophthalic acid and again gradually heated up to 220°C for about 11 hours. Receive, therefore, 440 g of polycondensate of pentaerythritoltetranitrate/benzoate/isophthalate/isostearate in the form of a very thick oil.

Polycondensate has the following characteristics:

- soluble in the amount of 50 wt. at 70°C in Parléam;

acid number = 4,2;

- η110°C=2050 MPa·s;

the ratio between the number of moles of aromatic monocarboxylic acid to the number of moles of non-aromatic monocarboxylic acids: 0,181.

Examples a-j

Similar to the previous examples given, after which existing polycondensate (%) mean mass percent).

Polyol (% nature)Aromatic acid (% nature)Polycarboxylic acid or anhydride (% nature)Nah acid (% nature)Solubility*
Example a20,4 pentaerythritol4,1 benzoic18,3 isophthalic acid28,6% ezoterikova + 14,3% isononanoate + 14,3% stearicat 25°C
Example b20 pentaerythritol4 benzoic20 isophthalic acid18% ezoterikova + 38% stearicat 70°C
Example20 pentaerythritol4 benzoic20 isophthalic acid28% ezoterikova + 28% stearicat 25°C
Example d19,8 pentaerythritol4 benzoic 19,8 isophthalic acid40.6% of ezoterikova + 15.8% of stearicat 25°C
Example e19,8 pentaerythritol4 benzoic19,8 isophthalic acid48,5% ezoterikova + 7,9% stearicat 25°C
Example f19,8 pentaerythritol4 benzoic19,8 isophthalic acid52,4% ezoterikova + 4% stearicat 25°C
Example g25.5 diglycerin3,9 benzoic15,7 sabotinova acid34,9% ezoterikova + 20% lauricat 25°C
Example h25 trimethylolpropane2.1 m-Truelove14,6 phthalic anhydride18,3% ezoterikova + 40% Baganovaat 70°C
Example I21.9 aritra6,3 tert-Buti is benzoic 13,5 sabotinova acid8.3% of isooctane + 50% stearicat 70°C
Example j20,7 glycerin8,5 tert-butylbenzene15,9 adipic acid45.9% of isononanoate + 9% Baganovaat 25°C
* "25°C" means that the polymer is soluble in the amount of 50 wt.% at 25°C in Parléam;"at 70°C" means that the polymer is soluble in the amount of 50 wt.% at 70°C in Parléam;

Example 6

Synthesis of pentaerythritoltetranitrate/isophthalate/lowrate/polydimethylsiloxane (PDMS)

In a reactor equipped with mechanical stirring, the input of argon and system for distillation, charged 150 g of benzoic acid, 165 g of lauric acid and 110 g of pentaerythritol, then gradually heated in a light current of argon, to a temperature of 110-130°C. to obtain a homogeneous solution. Then the temperature is gradually increased up to 180°C and maintain it for approximately 2 hours. Again increase the temperature up to 220°C and maintain it until an acid number of less than or equal to 1, which takes approximately 15 hours. Cooled to a temperature in the range from 00°C to 130°C, then enter 90 g of isophthalic acid and 50 g of silicone-α,ω-diol H-160AS company Snin-Etsu and again gradually heated up to 220°C for about 11 hours. Receive, therefore, 510 g of polycondensate of pentaerythritoltetranitrate/isophthalate/lowrate/PDMS in the form of a thick oil which solidifies at room temperature.

Polycondensate has the following characteristics:

acid number = 28,7;

- hydroxyl number = 85;

- η110°C=2.1 poise (or 210 MPa·s);

the ratio between the number of moles of aromatic monocarboxylic acid to the number of mol nonaromatic branched monocarboxylic acid: 1,49.

Take 500 g videolooking of polycondensate, is heated to a temperature of 70°C. and slowly poured with stirring 215 g of ethyl acetate, then clarify by filtration while hot through a porous glass filter No. 2. After cooling to room temperature receive 705 g of a 70%aqueous solution of polycondensate in ethyl acetate, in the form of a viscous liquid pale yellow color and has a viscosity at 25°To about 165 centipoise (MPa·s).

Example 7

Synthesis of pentaerythritoltetranitrate/isophthalate/laurate

In a reactor equipped with mechanical stirring, the input of argon and system for distillation, load 165 g of benzoic acid, 160 g of lauric acid I g of pentaerythritol, then gradually heated in a light current of argon, to a temperature of 110-130°C. to obtain a homogeneous solution. Then the temperature is gradually increased up to 180°C and maintain it for approximately 2 hours. Again increase the temperature up to 220°C and maintain it until an acid number of less than or equal to 1, which takes approximately 15 hours. Cooled to a temperature in the range from 100°C to 130°C, then enter 100 g of isophthalic acid and again gradually heated up to 220°C for about 12 hours. Receive, therefore, 510 g of polycondensate of pentaerythritoltetranitrate/isophthalate/laurate in the form of a thick oil which solidifies at room temperature.

Polycondensate has the following characteristics:

acid number = 20,4;

- hydroxyl number = 66;

- η110°C=4.7 poises (or 470 MPa·s);

the ratio between the number of moles of aromatic monocarboxylic acid to the number of mol nonaromatic branched monocarboxylic acid: 1,69.

Take 500 g videolooking of polycondensate, is heated to a temperature of 70°C. and slowly poured with stirring 215 g of ethyl acetate, then clarify by filtration while hot through a porous glass filter No. 2. After cooling to room temperature to obtain 700 g of a 70%aqueous solution of polycondensate in ethyl is cetate, in the form of a viscous liquid pale yellow color and has a viscosity at 25°To about 310 centipoise (MPa·s).

Example 8

Synthesis of pentaerythritoltetranitrate/phthalate/laurate

In a reactor equipped with mechanical stirring, the input of argon and system for distillation, load 185 g of benzoic acid, 174 g of lauric acid and 114,6 g of pentaerythritol, then gradually heated in a light current of argon, to a temperature of 110-130°C. to obtain a homogeneous solution. Then the temperature is gradually increased up to 180°C and maintain it for approximately 2 hours. Again increase the temperature up to 220°C and maintain it until an acid number of less than or equal to 1, which takes about 18 hours. Cooled to a temperature in the range from 100°C to 130°C, then enter 80 g of phthalic anhydride and again gradually heated up to 220°C for approximately 8 hours. Add 15 g of pentaerythritol and incubated for 8 hours at 220°C. Receive, thus, 512 g of polycondensate of pentaerythritoltetranitrate/phthalate/laurate in the form of a thick oil which solidifies at room temperature.

Polycondensate has the following characteristics:

acid number = 13,0;

- hydroxyl number = 60;

- η110°C=0.9 poise (or 90 MPa·s);

the ratio between the number of the om moles of aromatic monocarboxylic acid to the number of mol nonaromatic branched monocarboxylic acid: 1,74.

Example 9

Lipstick in pencil

Ingredient (named according to INCI)wt.%
Andtrimethylenetrinitramine57,55
polycondensate according to example 116,00
Inmicrocrystalline wax4,55
beeswax1,95
polycondensate according to example 31,00
modiglianimiller-212
Dtitanium dioxide (rutile), treated with aluminum oxide/silicon dioxide/trimethylolpropane0,20
aluminium painted bright blue FCF based on aluminium oxide0,20
yellow, brown micaceous iron dyes0,95
terrainability lacquer on the basis of aluminum oxide 0,85
calcium salt of licola In red color0,45
Emica-titanium oxide2,80
mica-titanium oxide1,00
mica-titanium oxide0,50
Total:100,00

1. Cosmetic composition for the lips, including:
at least one first complex polyester, which can be obtained by reaction:
at least one polyol containing from 3 to 12 carbon atoms and 3 to 6 hydroxyl groups, in an amount of from 10 wt.% up to 30 wt.% in relation to the total weight of the final complex polyester;
at least one nonaromatic branched monocarboxylic acid selected from 2-ethylhexanoic acid, isooctanol acid, isoheptane acid, isononanoic acid, ezoterikovou acid and mixtures thereof in an amount of from 30 wt.% up to 80 wt.% in relation to the total weight of the final complex polyester;
at least one aromatic monocarboxylic acid chosen from benzoic acid, 4-tert-butylbenzoyl the Oh of the acid, on-Truelove acid, m-Truelove acid, 1-naphthoic acid, individually or as mixtures, in quantities of from 0.1 wt.% up to 10 wt.% in relation to the total weight of the final complex polyester;
and
at least one polycarboxylic acid containing at least 2 carboxyl groups COOH and/or a cyclic anhydride of such a polycarboxylic acid containing from 3 to 18 carbon atoms, in an amount of 5 wt.% up to 40 wt.% in relation to the total weight of the final complex polyester;
at least one second complex polyester, which can be obtained by reaction:
at least one polyol containing from 3 to 12 carbon atoms and 3 to 6 hydroxyl groups, in an amount of from 10 wt.% up to 30 wt.%;
at least one nonaromatic linear monocarboxylic acid selected from lauric acid, myristic acid, nonnovel acid, palmitic acid, stearic acid, beganovi acid and mixtures thereof, in an amount of from 30 wt.% up to 80 wt.% in relation to the total weight of the final complex polyester;
at least one aromatic monocarboxylic acid chosen from benzoic acid, 4-tert-butylbenzoic acid, o-Truelove acid, m-Truelove acid, 1-naphthoic acid, individually or as mixtures, in quantities of from 0.1 wt.% up to 10 wt.% with respect to the total mass to echnolo complex polyester;
and
at least one polycarboxylic acid containing at least 2 carboxyl groups COOH and/or a cyclic anhydride of such a polycarboxylic acid containing from 3 to 18 carbon atoms, in an amount of 5 wt.% up to 40 wt.% in relation to the total weight of the final complex polyester;
in which the total amount of the first complex of the polyester ranges from 1 wt.% up to 50 wt.% and
in which the total amount of the second complex of the polyester comprises from 0.1 wt.% up to 20 wt.%.

2. The composition according to claim 1 in which the polyol is selected from glycerol, pentaerythritol, diglycerin, sorbitol and mixtures thereof; and, even better, he is pentaerythritol.

3. The composition according to claim 1, in which the aromatic monocarboxylic acid chosen among benzoic acid, 4-tert-butylbenzoic acid, o-Truelove acid, m-Truelove acid, 1-naphthoic acid, individually or as mixtures; and, more preferably, one of benzoic acid.

4. The composition according to claim 1, in which the aromatic monocarboxylic acid, or a mixture of the above acids, ranges from 0.5 wt.% to 9.95 wt.% better, from 1 wt.% up to 9.5 wt.% and even from 1.5 wt.% up to 8 wt.% in relation to the total weight of the final complex polyester.

5. The composition according to claim 1, in which the polycarboxylic acid or its anhydride choose among adipic acid, phthalic anhydride and/or isophthalic sour the s and preferably, one isophthalic acid.

6. The composition according to claim 1, in which the amount of polycarboxylic acid and/or its cyclic anhydride is from 10 wt.% up to 30 wt.% and, better, from 14 wt.% up to 25 wt.% with respect to the total mass of the complex polyester.

7. Composition according to any one of the preceding paragraphs, in which polyesters can be obtained by reacting:
at least one polyol chosen, individually or in a mixture of glycerol, pentaerythritol, sorbitol and mixtures thereof; in an amount of from 10 wt.% up to 30 wt.% in particular, from 12 wt.% up to 25 wt.% and, better, from 14 wt.% to 22 wt.% in relation to the total weight of the final complex polyester;
at least one non-aromatic monocarboxylic acid, in an amount of from 30 wt.% up to 80 wt.% in particular, from 40 wt.% up to 75 wt.% and, better, from 45 wt.% up to 70 wt.% in relation to the total weight of the final complex polyester;
at least one aromatic monocarboxylic acid chosen, individually or as a mixture, from benzoic acid, o-Truelove acid, m-Truelove acid, 1-naphthoic acid; in an amount of from 0.1 wt.% up to 10 wt.% in particular, from 1 wt.% up to 9.5 wt.% even from 1.5 wt.% up to 8 wt.% in relation to the total weight of the final complex of the polyester; and
at least one polycarboxylic acid or one of its anhydrides chosen(ICDO), the individual is the social or in the form of a mixture, from phthalic anhydride and isophthalic acid present(ing) in an amount of from 5 wt.% up to 40 wt.% in particular, from 10 wt.% up to 30 wt.% and, better, from 14 wt.% up to 25 wt.% in relation to the total weight of the final complex polyester.

8. The composition according to claim 1, in which the total amount of the first complex of the polyester ranges from 1 wt.% up to 50 wt.% in particular, from 10 wt.% up to 45 wt.% even from 10 wt.% up to 20 wt.% in relation to the total weight of the composition.

9. The composition according to claim 1, in which the total amount of the second complex of the polyester comprises from 0.1 wt.% up to 20 wt.% in particular, from 0.2 wt.% up to 10 wt.% even from 0.5 wt.% up to 2 wt.% in relation to the weight of the composition.

10. Cosmetic composition for the lips, containing:
the first complex polyester benzoic acid/isophthalic acid/ezoterikovou acid/pentaerythritol, and
the second complex polyester benzoic acid/isophthalic acid/stearic acid/pentaerythritol, in which the first complex of the polyester and the second complex polyester are in a weight ratio of from 50:1 to 2:1, in particular from 30:1 to 20:1.



 

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