Composition containing polyorgansiloxane polymer, thickener and at least one volatile alcohol

FIELD: medicine.

SUBSTANCE: invention concerns cosmetology and represents a cosmetic composition containing at least one silicone-polyamide copolymer, at least one volatile alcohol and, at least one thickener, where said copolymer contains at least one fragment (III) or (IV).

EFFECT: invention provides production of lubrication free or lubrication resistant compositions, as well as ensures improvement of keratinised tissue and provides improved by-touch characteristics in application and shows water resistance.

35 cl, 4 ex, 2 tbl

 

The technical field to which the invention relates.

The present invention relates to compositions, such as cosmetic compositions, resistant to smudging, which may also be plastic and/or convenient when applied to keratinous tissue, which contains at least one polyorganosiloxane polymer comprising at least one fragment, containing at least one organopolysiloxane group, including organosiloxane the links in the chain fragment or in the form of grafted chains, and at least two groups capable of establishing hydrogen interactions/communication, at least one volatile alcohol and at least one thickener.

Discussion of the prerequisites of inventions

Many cosmetic compositions, including colored pigment cosmetics, such as base correction/masking tools, lipsticks and mascara and other cosmetic and sunscreen compositions have been developed to achieve the characteristics of a more durable (makeup, coloring, shades) and resistance to smudging. This is usually reached by applying the compositions, which form a film after application. Such compositions typically contain volatile solvents that evaporate upon contact with the skin or other keratinous tissue, the remaining is Yaya layer, including waxes and/or resins, pigments, fillers and active substances. However, these compositions tend to be uncomfortable for whom they are applied, because the composition remains on the skin or other keratinous tissue in the form of brittle or non-elastic film. Such compositions may not be plastic or soft, and they may not be comfortable to wear. Also, such compositions may have a tendency to flake off due to the weak adhesion to the skin or other keratinous tissue. In addition, such compositions tend to be sticky, which leads to poor performance of the application, distribution and durability.

Patent US Pat. No. 5874069, US Pat. No. 5919441, US Pat. No. 6051216, US Pat. No. 6353076, patent applications W/O-A-02/17870 and W/O-A-02/17871 reveal narodnosti (semi-solid, plastic-solid, solid) deodorant gels or pencils containing polyorganosiloxane polymers. Such deodorizing pencils and gels, however, are unacceptable for cosmetic applications, especially for cosmetic applications where it is desirable durability of the color.

Thus, there remains a need for improved persistent (preserving for a long time their properties) cosmetic compositions which are lubricated with little or no smearing, that is "free from masiva the Oia or resistant to lubricating compositions, which also have good cosmetic properties, such as flexibility and convenience. For example, the composition that is resistant to smudging, can form a film on the surface of keratinized tissue, which cannot be done when the surface of keratinized tissue comes into contact with, for example, skin, clothing, Cup, paper, cigarette, or a handkerchief.

Therefore, one aspect of the present invention is a composition for care and/or to create a makeup and/or treatment of the surface of keratinized tissue, such as skin, hair, eyelashes, fingernails and/or lips, which may resolve or respond to at least one of the above-mentioned problems associated with compositions of the prior art.

SUMMARY of the INVENTION

The present invention relates to compositions, preferably cosmetic compositions containing at least one polyorganosiloxane polymer selected from homopolymers and copolymers of at least one volatile alcohol, and at least one thickener. Preferred compositions additionally contain at least one essential oil.

The present invention also relates to colored cosmetic compositions containing at least one polyorganosiloxanes the polymer, preferably the silicone-polyamide copolymer, at least one coloring substance, at least one volatile alcohol and at least one thickener. Preferred compositions additionally contain at least one essential oil. Such colored cosmetic compositions can be an anhydrous composition for the lips (for example, lipstick or liquid coloring tools for lips or database.

The present invention additionally relates to colored cosmetic compositions containing at least one polyorganosiloxane polymer, preferably a silicone-polyamide copolymer, at least one coloring substance, at least one volatile alcohol, at least one thickener and water. Preferred compositions additionally contain at least one essential oil. Such aqueous colored cosmetic composition preferably is a composition for the lips (for example, lipstick or liquid coloring tools for lips), base or ink, and are emulsions or dispersions.

The present invention also relates to a method of treatment, care and/or makeup on the surface of keratinized tissue (e.g. skin or lips) by applying compositions of the present invention to the keratinous TC is Ni in number, sufficient for treatment, care and/or makeup on the surface of the keratinous tissue.

The present invention additionally relates to methods of hiding or correction/masking imperfections on the skin associated with keratinized tissue (e.g. skin or lips) by applying compositions of the present invention on the surface of keratinized tissue in sufficient quantity in order to hide or to correct/to mask these defects on the skin.

The present invention also relates to a method of improving the appearance of keratinous tissue (e.g., skin or lips) by applying compositions of the present invention on the surface of keratinized tissue in sufficient quantity to improve the appearance of keratinous tissue.

The present invention additionally relates to compositions having improved cosmetic properties such as, for example, improved durability (makeup, coloring, shades), resistance to smudging and/or water-resistant properties. The composition may also have improved characteristic to the touch when applied (for example, a more convenient application layer), elasticity, easy to wear, the drying time and/or retention/preservation and reduced stickiness and/or move over time.

The present invention also relates to n the pinery, includes (a) a composition comprising at least one polyorganosiloxane polymer, preferably a silicone-polyamide copolymer, at least one coloring substance, at least one volatile alcohol and at least one thickener; and (b) composition - based coating and/or top coating. Preferably the composition (a) further comprises at least one essential oil.

The present invention also relates to methods for narodnostnej compositions, preferably solid compositions, comprising mixing at least one polyorganosiloxane polymer, preferably a silicone-polyamide copolymer, at least one volatile alcohol and at least one thickener education narodnostnej composition.

It should be understood that both the foregoing General description and the subsequent detailed description are merely illustrative and interpretive and non-limiting of the invention.

DETAILED description of the INVENTION

Used in this description, the expression "at least one" means one or more and thus includes individual components as well as mixtures/combinations.

"Film" or "film-forming substance, which is used in this description, means a polymer or with the Olu, which leaves a film on the surface of the fabric on which it is applied, for example, after the solvent accompanying the film, evaporated, absorbed cloth and/or residuosity on the surface of the fabric.

"Resistance to smudging"as used in this document refers to the quality exhibited by compositions that are not readily removed by contact with another material, such as, for example, glass, piece of clothing or skin, for example, when eat or drink. Resistance to smudging can be assessed by any method known in this area for this assessment. For example, resistance to lubricating compositions can be evaluated by testing the contact method ("kiss" test). Test contact method may include applying the composition to the surface of keratinized tissues such as hair, skin or lips, with subsequent grinding of the material, such as a sheet of paper, to hair, skin or lips after some amount of time after application, for example, 2 minutes after application. Also, resistance to lubricating compositions can be evaluated by the amount of product transferred from the fact who suffered composition, on any other surface, for example, in the lubrication of hair, skin or lips of the man on the collar/neck boards is to, when you wear the clothes after the expiration of a certain period of time after application of the composition to the hair, skin or lips. The amount of composition transferred/grease on the surface (for example, on the collar/neck handkerchief or paper) can then be evaluated and compared. For example, the composition may be resistant to smudging, if the majority of the product remains on the hair, skin or lips who applied composition. In addition, grease quantity can be compared with the number lubricated other compositions, for example, commercially available compositions. In a preferred embodiment of the present invention the composition is smeared on the surface of the hair, skin or lips a little, or not at all smeared.

"Persistent" songs used in this document, refer to compositions in which color/hue remains the same or substantially the same as at the time of application that is visible to the naked eye, after a long period of time. Characteristics resistance can be assessed by any method known in the field to assess such properties. For example, the resistance can be measured by the test, including applying the composition to hair, skin or lips of the person and assess the color/hue of the composition after a long period of time. For example, t is et/tint compositions can be evaluated directly after application to the hair, the skin or lips, and these characteristics can then be re-evaluated and compared over time. In addition, these characteristics can be evaluated relative to other compositions, for example, commercially available compositions.

"Stickiness"as used in this document refers to the adhesion between the two substances. For example, the more stickiness between the two substances, the greater the adhesion between the substances. For a quantitative assessment of "stickiness" is useful to define the "work of adhesion"is defined by IUPAC as correlated with the two substances. Generally speaking, the work of adhesion is measured as the amount of work required to separate two substances from each other. Thus, more than the work of adhesion correlated with the two substances, the greater the adhesion between the substances, which means greater stickiness between the two substances.

The work of adhesion and, thus, stickiness, can be quantified using techniques and methods, usually used to measure adhesion, and is usually given in units of force over time (for example, gramschi ("GS")). For example, the instrument TA-XT2 from Stable Micro Systems, Ltd. can be used to determine the adhesion, following the method described in the publication TA-XT2 Application Study (reference: MATI/PO.25), revised in January 2000, the full content to the th included as references. According to this method, the desired values of work of adhesion for essentially non-sticky substances include values less than approximately 0.5 Gauss, less than about 0.4 Gauss, less than approximately 0.3 HS and less than about 0.2 Gauss. As is well known in this area for adhesion can be used in other similar ways to other similar analytical devices.

"Resistance"used in this document, refers to the ability to repel water and sustainability in relation to water. Water-resistant characteristics can be estimated by a method known in this field to assess such properties. For example, the composition of mascara to the eyelashes and eyebrows can be applied to artificial eyelashes, which can then be placed in water for some time, for example, for 20 minutes. Upon expiration of a predetermined time artificial eyelashes can be removed from the water and held on to the material, such as, for example, a sheet of paper. The degree of residue left on the material, can then be estimated and compared with other compositions, such as, for example, commercially available compositions. Similarly, for example, the composition may be applied on the skin, and the skin can be submerged in water for some time. The amount of composition remaining on the skin after a pre-installed the belts, then can be evaluated and compared. For example, the composition may be water resistant, if most part of it remains on the surface to which it is applied, for example, eyelashes, skin, and so on. In a preferred embodiment of the present invention the composition is smeared with the surface to which applied, little or no smeared.

Cosmetic compositions and methods of the present invention can include, consist of or mainly composed of basic elements and limitations of the invention described in this document, as well as any additional or optional ingredients, components, or limitations described herein or otherwise useful in compositions for personal care, intended for topical application to the hair.

The composition of the present invention may be in any form, or liquid or seidkona (semi-solid, solid plastic, solid and so on). For example, it can represent paste/ointment, solid, gel or cream. It can be an emulsion, such as an emulsion of the type oil-in-water type or water-in-oil multiple emulsion, such as an emulsion of the type oil-in-water-in-oil type or water-in-oil-in-water, or solid, solid/unyielding or soft/pliable gel, including bezvadneho. Also the composition may be in the form selected from the semi-transparent anhydrous gel and a transparent anhydrous gel. The composition of the invention may, for example, contain the external or continuous fatty phase. The composition may be anhydrous. Also the composition may be a molded composition or molding in the form of a pencil or plates. The composition in one embodiment is a solid, such as a molded pencil or cast pencil.

Depending on the intended use, such use as a pencil, may also be taken into account the hardness of the composition. The hardness of the composition, for example, can be expressed in grams-force (GF). The composition of the present invention, for example, may have a hardness, fluctuating in the range of 20 Gauss to 2000 Gauss, for example, from 20 to 900 GS GS, and, in addition, for example, from 20 HS 600 HS.

Such hardness is measured in one of two ways. The first hardness test is carried out in accordance with the method of penetration of the sample into the composition and, in particular, when using the texture analyzer/structures (for example, TA-XT2I from Rheo)equipped with ebonite cylinder with a height of 25 mm and a diameter of 8 mm, the hardness Measurement is carried out at 20°C in the center of the 5 samples of the composition. The cylinder is introduced into each sample of the composition with a pre-installed / min net is using 2 mm/s and then at a rate of 0.5 mm/s and eventually installed after that a speed of 2 mm/s, where the total displacement is 1 mm Recorded the hardness value represents the maximum value of the observed peak. Measurement error is ±50 Gauss.

The second hardness test is a way to "cheese wire", which includes the cutting of the composition of a pencil diameter of 8.1 mm, or preferably 12.7 mm and measuring its hardness at 20°C using a bursting machine from the company Indelco-Chatillon Co. at a speed of 100 mm/minute. The hardness value by this method is expressed in grams as a transverse force required to cut the pencil in the above-mentioned conditions. According to this method, the hardness of the compositions in accordance with the present invention, which may be in the form of a pencil, can vary, for example, in the range from 30 g to 300 g, for example, from 30 g to 250 g for sample pencil diameter of 8.1 mm, and, in addition, for example, from 30 g to 200 g, and, in addition, for example, from 30 g to 120 g for sample pencil diameter of 12.7 mm

The hardness of the composition of the present invention may be such that the tracks were samoderzhavie and could easily be divided into parts with the formation of a satisfactory layer on keratinized tissues. In addition, this hardness can give good impact strength of the compositions of the present invention, which may be molded or cast, in the example, in the form of a pencil or plates.

The specialist may choose to assess the composition using at least one test on the hardness of the above, based on the anticipated use and desired hardness. If you get an acceptable hardness value, from the point of view of the intended application, at least one of these tests, the hardness, the composition refers to preferred variants of the invention.

Obviously, the hardness of the composition according to preferred variants of the invention may be, for example, such that the composition was mainly samoderzhavie and could easily be divided into parts with the formation of a satisfactory layer on keratinized tissues. In addition, with such firmness composition of the invention can have good impact strength.

In accordance with a preferred variant implementation of the present invention the composition is in the form of a pencil can have properties of a deformable, flexible elastic solid, giving noteworthy elastic softness during application.

As defined in this document, the stability of the experience by placing the composition in a chamber with a controlled environment for 8 weeks at 25°C. In this test, carefully study the physical is the condition of the sample, when it is put in the camera. The sample was then examined again after 24 hours, 3 days, 1 week, 2 weeks, 4 weeks and 8 weeks. In each survey, the sample is examined for changes in the composition, such as the separation of the phases, if the composition is in the form of emulsions, flexion or deviation from the vertical, if the composition is in the form of a pencil, melting or syneresis (or wypadanie). Stability additionally experience by re-testing after 8 weeks at 25°C, 37°C, 45°C and in conditions of freezing and thawing. I think that the composition is stable, if in any of these tests mark the change that interferes with the operation of composition. The specialist can easily notice the change, which will interfere with the function and composition, based on the intended application.

Polyorganosiloxane polymer

In accordance with the present invention are compositions containing at least one polyorganosiloxane polymer selected from homopolymers and copolymers, preferably with a mass-average molecular weight, fluctuating in the range of from about 500 g/mol to about 2.5×106g/mol or more, including at least one fragment, containing: at least one organopolysiloxane group,including, preferably, from 1 to about 10000 organosiloxane links in the chain fragment or in the form of grafted chains, and at least two groups capable of establishing hydrogen interactions. Preferably, polyorganosiloxane copolymer is a silicone-polyamide copolymer; the copolymer containing siloxane and amide fragments.

In accordance with a preferred variant implementation of the present invention polyorganosiloxane polymers used in the compositions of the invention may belong to the following two families:

a) polyorganosiloxanes containing at least two groups capable of establishing hydrogen interactions, these two groups are located in the polymer chain; and/or

b) polyorganosiloxanes containing at least two groups capable of establishing hydrogen interactions, these two groups are grafted on the links or branches.

Polyorganosiloxane polymers of the present invention can be liquid or solid at room temperature. Preferably, the polymers are solid. In the case where the polymers are solid, it is preferable that they could be dissolved before use or during use, in a solvent with water is native interactions, able to destroy hydrogen interaction of polymers, for example, in C2-C8the lower alcohols, especially ethanol, n-propanol or isopropanol. It is also possible to use solvents such "destructive" hydrogen interaction, as co-solvents in the compositions of the present invention. These solvents can then be left in the composition or may be removed by selective evaporation, which is well known to specialists in this field.

Polymers containing two groups capable of establishing hydrogen interactions in the polymer chain, can be a polymer containing at least one fragment corresponding to the formula:

in which:

1) R1, R2, R3and R4that may be the same or different, represent a group chosen from:

- a linear, branched or cyclic, saturated or unsaturated, groups based on the C1-C40hydrocarbon, possibly containing in its chain one or more atoms of oxygen, sulfur and/or nitrogen, and possibly being partially or totally substituted by fluorine atoms,

- C6-C10aryl groups, optionally substituted by one or more1-C4alkyl groups,

- polyorganosiloxanes the x circuits possibly containing one or more atoms of oxygen, sulfur and/or nitrogen;

2) the groups X, which may be identical or different, represent a linear or branched C1-C30alkylenediamine group, possibly containing in its chain one or more oxygen atoms and/or nitrogen;

3) Y is a saturated or unsaturated, With1-C50linear or branched divalent alkilinity, Allenova, cycloalkanones, alkylsilanes or arylalkylamines group may containing one or more atoms of oxygen, sulfur and/or nitrogen and/or bearing as substituent one of the following atoms or groups of atoms: fluorine, hydroxyl, C3-C8cycloalkyl,1-C40alkyl, C5-C10aryl, phenyl, optionally substituted from 1 to 3 With1-C3alkyl groups With1-C3hydroxyalkyl and C1-C6aminoalkyl, or

4) Y represents a group corresponding to the formula:

in which

T represents a linear or branched, saturated or unsaturated, trivalent or tetravalent group based on the C3-C24hydrocarbon, optionally substituted organopolysiloxane chain, and possibly containing one or more atoms selected from O, N and S, or T before the hat is trivalent atom, selected from N, P and Al, and

- R5represents a linear or branched C1-C50alkyl group or organopolysiloxane chain may contain one or more ester, amide, urethane, THIOCARBAMATE, urea, timesaving and/or sulfonamidnuyu groups that can be linked to another chain of the polymer;

5) the groups G, which may be identical or different, represent divalent groups chosen from:

;;;

;;;

;;;

;

where R6represents a hydrogen atom or a linear or branched C1-C20alkyl group, provided that at least 50% of the groups R6in the polymer represents a hydrogen atom and that at least two groups G of the polymer are a group other than:

and;

6) n is an integer of at least 1, for example, in the range from 2 to 500 and preferably from 2 to 200, and m is an integer, at least one in the range from 1 to 35,000, for example, from 1 to 10,000 and 1 to 2500, from 1 to 700 and from 6 to 200, including all values and subranges between them.

In accordance with the invention, 80% of the groups R1, R2, R3and R4the polymer is preferably selected from methyl, ethyl, phenyl and 3,3,3-triptoreline groups.

In accordance with the invention, Y may be a number of different divalent group, in addition, optionally containing one or two free valencies to establish links with other fragments of the polymer or copolymer. Preferably, Y represents a group chosen from:

a) linear C1-C20and preferably1-C10alkilinity groups,

(b) (C30-C56extensive alkilinity groups, possibly containing rings and unpaired bonds,

C)5-C6cycloalkenes groups,

d) filinovich groups, optionally substituted by one or more1-C40alkyl groups,

e)1-C20alkilinity groups containing from 1 to 5 amide groups,

f)1-C20alkilinity groups containing one or more substituents selected from hydroxyl, C3-C8cycloalkane,1-C3hydroxyalkyl and C1-C6alkylamine what's groups,

g) organopolysiloxane chain of the formula:

in which R1, R2, R3, R4, T and m are the same as defined above, and

h) organopolysiloxane chain of the formula:

Polyorganosiloxanes of the second family can be a polymer containing at least one fragment corresponding to formula (II):

in which

- R1and R3that may be the same or different, are the same as defined above for formula (I),

- R7represents a group defined above for R1and R3or represents a group of formula-X-G-R9in which X and G are the same as defined above for formula (I), and R9represents a hydrogen atom or a linear, branched or cyclic, saturated or unsaturated group based on the C1-C50hydrocarbon, optionally containing in its chain one or more atoms selected from O, S and N, optionally substituted by one or more fluorine atoms and/or one or more hydroxyl groups, or a phenyl group, optionally substituted by one or more1-C4alkyl groups,

- R8represents a group of formula-X-G-R9in which the Oh X G and R9are the same as defined above,

- m1is an integer, at least one in the range from 1 to 35,000, for example, from 1 to 10,000 and 1 to 2500, from 1 to 700, from 6 to 200, including all values and subranges between them; and

- m2is an integer, at least one in the range from 1 to 35,000, for example, from 1 to 10,000 and 1 to 2500, from 1 to 700, and from 6 to 200, including all values and subranges between them.

In accordance with the invention polyorganosiloxane polymer may be a homopolymer, i.e. a polymer containing several identical fragments, particularly fragments of the formula (I) or formula (II).

In accordance with the invention it is also possible to use a polymer consisting of a copolymer containing several different fragments of the formula (I), that is, a polymer in which at least one of the groups: R1, R2, R3, R4, X, G, Y, m and n is different in one of the fragments. The copolymer may also be formed from multiple pieces of the formula (II), in which at least one of the groups:

R1, R3, R7, R8, m1and m2is excellent, at least one of the fragments.

It is also possible to use a copolymer containing at least one fragment of the formula (I) is, at least one fragment of the formula (II), where fragments of the formula (I) and fragments of the formula (II) may be the same or different from each other.

In accordance with a preferred variant implementation is also possible to use a copolymer containing at least one fragment-based hydrocarbon containing two groups capable of establishing hydrogen interactions, chosen from ester, amide, sulfonamidnuyu, urethane, THIOCARBAMATE, urea and timesaving groups and their combinations.

Such copolymers may be copolymers or grafted copolymers.

In accordance with the first embodiment of the present invention, capable of establishing hydrogen interactions are amide groups of the formula-C(O)NH - and-HN-C(O)-.

In this case, the polymer may contain at least one fragment of the formula (III) or (IV):

or

in which R1, R2, R3, R4X, Y, m and n are the same as defined above.

Such a fragment can be obtained:

or condensation reaction between the end groups siliconsamurai α,ω-carboxylic acid, and one or more diamines, according to the following reaction scheme:

or by reaction of two molecules of α-unsaturated carboxylic acid with a diamine according to the following reaction scheme:

subsequent merger of the siloxane to the ethylene unsaturated fragments in accordance with the following scheme:

in which X1-(CH2)2- corresponds to X defined above, and Y, R1, R2, R3, R4and m are the same as defined above;

or by reaction of the end groups siliconsamurai α,ω-NH2and decollate formula HOOC-Y-COOH in accordance with the following reaction scheme:

In these polyamides of formula (III) or (IV) m is an integer of at least one, as defined above, and preferably in the range from 1 to 700, for example, from 15 to 500 and from 15 to 45, including all values and subranges between them; and n is in particular in the range from 1 to 500, for example, from 1 to 100 and from 4 to 25, including all values and subranges between them; X preferably represents a linear or branched alkylenes chain, containing from 1 to 30 carbon atoms and in particular from 3 to 10 carbon atoms, and Y preferably represents alkylenes chain which is linear or branched or may contain a ring and/or unsaturated fragments, containing from 1 to 40 carbon atoms, including from 1 to 20 carbon atoms and from 2 to 6 carbon atoms, including all values and subranges between them, for example, to 6 carbon atoms.

In formulas (III) and (IV) Allenova group representing X or Y may optionally contain in its alkalinous part, at least one of the following elements:

1) 1-5 amide, urea or urethane groups,

2)5or6cycloalkyl group, and

3) fenelonov group, optionally substituted from 1 to 3 identical or different With1-C3alkyl groups.

In formulas (III) and (IV) alkylene groups can also be substituted by at least one element selected from the group consisting of:

- hydroxyl group,

- C3-C8cycloalkyl group,

- one-three1-C40alkyl groups,

is a phenyl group, optionally substituted one to three With1-C3alkyl groups,

- C1-C3hydroxyalkyl group, and

- C1-C6aminoalkyl group.

In these formulas (III) and (IV) Y can also be represented as:

in which R5is an organopolysiloxane chain and T represents a group of the formula:

or

in which a, b, and C, independently of one another, are integers in the range from 1 to 10, and R10represents a hydrogen atom or a group such as the groups defined for R1, R2, R3and R4.

In formulas (III) and (IV) R1, R2, R3and R4independently from each other, preferably represent a linear or branched C1-C40alkyl group, preferably CH3With2H5the h3H7or ISO-propyl group, an organopolysiloxane chain or a phenyl group, optionally substituted by one to three methyl or ethyl groups.

As was shown above, the polymer may contain the same or different fragments of the formula (III) or (IV).

Thus, the polymer may be a polyamide containing a few fragments of the formula (III) or (IV) with different lengths, i.e. a polyamide corresponding to the formula:

in which X, Y, n and R1-R4have the meanings defined above, m1and m2that are different, determined as above, and preferably is chosen in the range from 1 to 1000, and p is an integer of at least one, for example, in the range from 2 to 500 and preferably from 2 to 200.

In this formula, f is Agency can be made with education or blockcopolymer, or statistical copolymer or alternating copolymer. In this copolymer, the fragments can be not only of different lengths, but also of different chemical structures, for example, contain different groups Y. In this case, the copolymer may correspond to the formula:

in which R1-R4X, Y, m1, m2, n and p have the meanings defined above, and Y1is different from Y, but selected from the groups defined for Y. As discussed above, the various fragments can be composed with the formation or blockcopolymer, or statistical copolymer or alternating copolymer.

In one embodiment of the invention polyorganosiloxane polymer may also contain a grafted copolymer. Thus, the polyamide containing silicon linkages, may be grafted, and optionally crosslinked with silicone chains containing amide groups. Such polymers can be synthesized by trifunctional amines.

In this case, the copolymer may contain at least one fragment of the formula:

in which X1and X2that may be the same or different, have the meanings defined for X in the formula (I), n is the same as defined in formula (I), Y and T are therefore the same, as defined in the formula (I), R11-R18represent a group selected from the group that is identical to R1-R4, m1and m2represent numbers in the range from 1 to 1000, and p is an integer of at least one, for example, R may be in the range from 2 to 500.

In the formula (VII) is preferable that:

- R is in the range from 1 to 25, including from 1 to 7, including all values and subranges between them,

- R11-R18represent a methyl group,

- T corresponds to one of the following formulas:

;;

in which R19represents a hydrogen atom or a group selected from the groups defined for R1-R4and R20, R21and R22independently from each other, are linear or branched alkionovymi groups, and more preferably corresponds to the formula:

where, in particular, R20, R21and R22represent-CH2-CH2-,

- m1and m2range from 15 to 500, including from 15 to 45, and including all values and subranges between them,

- X1and X2represent -(CH2)10-and

- Y represents-sub> 2-.

Such polyamides containing grafted siloxane fragment of the formula (VII)can be copolymerizable with polyamide-silicones of formula (II) with the formation of block copolymers, alternating copolymers or random copolymers. Mass percentage of grafted siloxane fragments (VII) in the copolymer can vary in the range from 0.5% to 30% by mass.

In accordance with the invention, as shown above, siloxane units can be in the principal chain or skeleton of the polymer, but also they may be present in grafted or pendantic circuits. In the main chain siloxane units can be in the form of segments, as described above. In pendantic or grafted chains, siloxane units can enter individually or in segments.

In accordance with the invention, the preferred polyamides based siloxane are:

the polyamides of formula (III)in which m has a value from 15 to 300, for example, 15-100, including all values and subranges between them;

- a mixture of two or more polyamides in which at least one polyamide has a value of m in the range from 15 to 50, including all values and subranges between them, and at least one polyamide has a value of m in the range from 30 to 300, including all values and subranges between them;

the polymers of formula (V), where m1chosen in the range from 15 to 50 and m 2chosen in the range from 30 to 500, where the part corresponding to m1is a 1-99% by weight of the total weight of polyamide, and a part corresponding to m2is a 1-99% by weight of the total weight of polyamide;

- mixture of the polyamide of the formula (III)combining

1) 80-99% by weight of a polyamide in which n equals 2 to 10 and, in particular, 3-6, and

2) 1-20% by weight of a polyamide in which n is in the range from 5 to 500 and in particular from 6 to 100;

- polyamides corresponding to formula (VI), in which at least one of the groups Y and Y1contains at least one hydroxyl Deputy;

the polyamides of formula (III), synthesized by means of at least one part of the activated decollate (acid chloride of decollate, dianhydride or fluids) instead of decollate;

the polyamides of formula (III)in which X represents -(CH2)3- or -(CH2)10; and

the polyamides of formula (III), in which the polyamides end monofunctional chain selected from the group consisting of monofunctional amines, monofunctional acids, monofunctional alcohols, including fatty acids, fatty alcohols and fatty amines number, such as, for example, octylamine, octanol, stearic acid and stearyl alcohol.

In accordance with the invention, the end groups of the polymer chain can end with:

With 1-C50alkyl-ester groups by introducing1-C50monohydroxy alcohol during synthesis,

- C1-C50alkylamino group by using as stopping group monocellate, if the silicone is α,ω-diaminononane, or monoamine, if the silicone is an α,ω-dicarboxylic acid.

In accordance with one embodiment of the invention it is possible to use a copolymer of silicone-polyamide and polyamide-based hydrocarbon, that is, the copolymer containing fragments of the formula (III) or (IV) and fragments of the polyamide-based hydrocarbon. In this case, the polyamide-silicone fragments can be located in the limit positions of the polyamide-based hydrocarbon.

Polymers based on polyamide containing siloxanes can be obtained silyl-amidation of polyamides based on dimer fatty acids. This approach involves the reaction of the free acid sites present in the polyamide as end-centers, with organosiloxane-monoamines and/or organosiloxane-diamines (amidation reaction), or, alternatively, with oligosiloxane alcohols or oligosiloxane dialami (esterification reaction). The esterification reaction requires the presence of acid catalysts that are known in this field. For polyamide containing with the rim of acid centers, used for amidation or esterification reaction, it is desirable to have a relatively large number of acid end groups (for example, the polyamides with large acid numbers, for example, from 15 to 20).

For amidation of free acid sites of polyamides on the basis of the hydrocarbon to react with the polyamide-based hydrocarbon, based on dimer fatty acids, can be used siloxane-diamines with 1-300, in particular from 2 to 50, and, for example, 2, 6, 9,5, 12, 13,5, 23 or 31 siloxane groups. The siloxane-diamines containing 13,5 siloxane groups are preferred, and the best results are obtained with the siloxane-diamine containing 13,5 siloxane groups, and polyamides containing a large number of terminal carboxyl groups.

The reaction can be carried out in xylene to extract water obtained from the solution by azeotropic distillation, or at higher temperatures (approximately 180-200°C) without solvent. Typically, the efficiency of the amidation and the reaction rate is reduced in the case where the siloxane-diamine is longer, i.e. the larger the number of siloxane groups. The free amine centers can be blocked after the initial amidation reaction of diaminocyclohexane by reaction interaction or siloxane acid,or with organic acid, such as benzoic acid.

For the esterification of the free acid sites in the polyamides that can be carried out in boiling xylene with about 1% by weight, relative to the total mass of the reactants, the pair-toluensulfonate acid as a catalyst.

These reactions are performed on the terminal carboxyl groups of the polyamide, lead to the introduction of silicone fragments only in the limit positions of the polymer chain.

It is also possible to obtain a copolymer polyamide-silicone, using polyamide containing free amine groups, the amidation reaction by a siloxane containing acid group.

It is also possible to prepare a gelling agent based on a copolymer between a polyamide-based hydrocarbon and silicone-polyamide, transaminirovania polyamide having, for example, ethylene diamines component, through oligosiloxane-α,ω-diamine, at high temperature (e.g., 200-300°C), in order to perform transaminirovania so that ethylendiamine component of the original polyamide was replaced by oligosiloxane-diamine.

The copolymer polyamide-based hydrocarbon and a polyamide-silicone may also be a graft copolymer containing the main chain of the polyamide-based hydrocarbon pendante oligosiloxane groups.

This may be what Holocene, for example:

the hydrosilation of unsaturated bonds in the polyamides based on dimer fatty acids;

- similarobama amide groups of the polyamide; or

- similarobama unsaturated polyamides by oxidation, that is, by carrying out the oxidation of unsaturated groups to alcohols or diols, in order to form hydroxyl groups that are reactive against the siloxane-carboxylic acids or siloxane alcohols. Olefinic centers unsaturated polyamides can also be epoxydecane, and epoxypropyl can then interact with the siloxane amines or siloxane alcohols.

Polyorganosiloxane polymers used in the compositions of the invention, most preferred are polymers of organopolysiloxane type, such as polymers described in documents US 5874069, US 5919441, US 6051216 and US 5981680, and published patent applications: US patent application publication No. 2004/0170586, the full disclosure of which is included thus by reference.

In accordance with another embodiment of the invention polyorganosiloxane polymer is a homopolymer or copolymer containing urethane or urea groups.

As discussed above, the polymer may contain organopolysiloxane fragments containing the two is whether more urethane and/or urea groups, or in the main polymer chain or in side chains, either in the form pendantic groups.

Polymers containing at least two urethane and/or urea groups in the main chain, may be a polymer containing at least one fragment, corresponding to the following formula:

in which R1, R2, R3, R4X, Y, m and n have the meanings defined above for formula (I), and U represents-O - or-NH-, so:

corresponds to a urethane or urea group.

In this formula (VIII) Y may be linear or branched C1-C40alkalinous group, optionally substituted C1-C15alkyl group or a C5-C10aryl group. Preferably, use the group -(CH2)6-.

Y can also represent a5-C12cycloaliphatic or aromatic group which may be substituted With1-C15alkyl group or a C5-C10aryl group, for example, a radical group selected from methylene-4,4-bicyclohexyl radical groups, radical groups derived from isophorone-diisocyanate, 2,4 - and 2,6-tolylene, 1,5-naphthylene, p-phenylene and 4,4'-biphenylmethane. As a rule, preferably Y represents a linear or osvetleniyu 1-C40alkylenes radical group or4-C12cycloalkenyl radical group.

Y may also represent a block of polyurethane or polyurea, corresponding to the condensation of several molecules of a diisocyanate with one or more molecules of the agents involved in the reaction combinations, diol or diamines of the type. In this case Y contains alkalinous chain multiple urethane or urea groups.

This may correspond to the formula:

in which B1represents a group selected from the groups given above for Y, U represents-O - or-NH - and B2choose from:

linear or branched C1-C40alkilinity groups, which can optionally bear an ionisable group, such as carboxylic acid group or sulfonic acid, or neytralizuya or quaternized tertiary amino group,

With5-C12cycloalkenes groups, optionally bearing alkyl substituents, for example one to three methyl or ethyl groups, or alkylene, for example, of the diol radical groups: cyclohexanedimethanol,

filinovich groups that may not necessarily carry With1-C3alkyl substituents

and

groups of the formula:

in which T is the battle trivalent radical group based on hydrocarbon, possibly containing one or more heteroatoms, such as oxygen, sulfur and nitrogen, and R5is an organopolysiloxane chain or a linear or branched C1-C50the alkyl chain.

T can represent, for example:

or

where w is an integer in the range from 1 to 10, and R5is an organopolysiloxane chain.

In the case when Y is a linear or branched C1-C40alkalinous group, preferred are a group -(CH2)2- and -(CH2)6-.

In the formula given above for Y, d can be an integer in the range from 0 to 5, preferably from 0 to 3 and more preferably equal to 1 or 2.

Preferably, B2is a linear or branched C1-C40alkalinous group, in particular, -(CH2)2- or -(CH2)6or group:

where R5is an organopolysiloxane chain.

As discussed above, polyorganosiloxane polymer can be formed from a silicone-urethane and/or silicone-urea fragments of different length and/or composition, and may be block copolymers or the acceptance of the ski copolymers.

In accordance with the invention, the silicone may also contain urethane and/or urea group is not already in the main chain and in the side branches.

In this case, the polymer may contain at least one fragment of the formula:

in which R1, R2, R3, m1and m2have the meanings defined above for formula (I),

- U represents O or NH,

- R23represents a C1-C40alkylenes group, optionally containing one or more heteroatoms selected from O and N, or fenelonov group, and

- R24choose from linear, branched or cyclic, saturated or unsaturated With1-C50alkyl groups, and phenyl groups, optionally substituted by one to three With1-C3alkyl groups.

The polymers comprising at least one fragment of the formula (X), contain siloxane units and urea or urethane groups, and they can be used, for example, as gelling agents (gelatinosa funds) in the compositions of the invention.

Siloxane polymers can have one urea or urethane group in branching or may have a branch that contains two urea or urethane groups, or, alternatively, they may contain a mixture of branches, containing the one urea or urethane group, and branches, containing two urea or urethane groups.

They can be obtained from branched polysiloxanes containing one or two amino groups in branching, by the reaction of the interaction of these polysiloxanes with monoisocyanates.

As examples of the source of this type of polymer containing amino and diamino-branches, may be mentioned the polymers corresponding to the following formulas:

In these formulas, the symbol "/" indicates that the segments can be of different lengths and in any order, and R represents a linear aliphatic group, preferably containing 1-6 carbon atoms including 1-3 carbon atom.

Such polymers containing branching, can be formed by the reaction of interaction siloxane polymer containing at least three amino groups in the polymer molecule with a compound containing only one monofunctional group (for example, acid, isocyanate or isothiocyanate), with the interaction of this monofunctional group with one of the amino groups and education groups capable of establishing hydrogen interactions. Amino groups can be on the side chains extending from the main chain of the siloxane polymer, so that the group is able at travlemate hydrogen interactions, formed on these side chains, or, alternatively, the amino group can be in the limit positions of the main chain, so that groups capable of hydrogen interaction will be terminal groups of the polymer.

As a method for obtaining a polymer containing siloxane units and groups capable of establishing hydrogen interactions, can be made the reference to the interaction of the siloxane-diamine and diisocyanate in a silicone solvent, in order to provide directly gel. The reaction can be carried out in silicone fluid, resulting in a product that is soluble in the silicone fluid, at high temperature, then the temperature of the system is reduced with the preparation of a gel.

The polymers which are preferred for inclusion in compositions in accordance with the present invention are copolymers of siloxane-urea, which are linear and which contain urea groups as the groups capable of establishing hydrogen interactions in the main polymer chain.

As an illustration, features, ending with four urea groups may be referred to the polymer of the formula:

in which Ph represents a phenyl group, and n is a number greater is 0, which includes at least 1, from 2 to 500, 2 to 200, from 1 to 300, in particular from 1 to 100, and all values and subranges between them, for example, 50.

This polymer is produced by the reaction of interaction next polysiloxane containing amino groups:

with phenylisocyanate.

The polymers of formula (VIII)containing urea or urethane groups in the chain of the silicone polymer can be obtained by reaction between a silicone containing end groups of the α,ω-NH2or is HE the formula:

in which m, R1, R2, R3, R4and X are defined as for formula (I), and a diisocyanate OCN-Y-NCO, in the formula which Y has the meaning defined in formula (I); and, optionally, an agent involved in the reaction combinations, diol or diamines of the type of formula H2N-B2-NH2or HO-B2-OH, in which B2defined as in formula (IX).

In accordance with the stoichiometric proportions between the two reagents, the diisocyanate and the agent of combination reaction, Y can have the formula (IX), where d 0 or d is equal to 1-5.

As in the case of polyamide-silicones of formula (II) or (III), it is possible to use in the invention is a polyurethane - or polyurea-silicone containing fragments of different length and structure, in which lastnosti, fragments, the length of which differ in the number of silicone parts. In this case, the copolymer may correspond to, for example, the formula:

in which R1, R2, R3, R4X, Y and U are defined as for formula (VIII) and m1, m2, n, and p are defined as for formula (V).

Branched polyurethane - or polyurea-silicone can also be obtained by using, instead of the diisocyanate OCN-Y-NCO, triisocyanate formula:

Thus obtained polyurethane - or polyurea-silicone containing branches, including organosiloxane chain with groups capable of establishing hydrogen interactions. Such a polymer includes, for example, a fragment corresponding to the formula:

in which X1and X2that are the same or different, have the meaning given for X in formula (I), n is the same as defined in formula (I), Y and T are the same as defined in formula (I), R11-R18represent a group selected from the group that is identical to R1-R4, m1and m2are the same as defined above.

As in the case of polyamides, such a copolymer may also include a polyurethane-silicone fragments without branching.

Even the bottom of the embodiment of the invention polyurea and polyurethane-based siloxane, which are preferred, are:

the polymers of formula (VIII)in which m has a value from 15 to 300, for example, from 15 to 100, and all values and subranges between them;

- a mixture of two or more polymers in which at least one polymer has a value of m in the range from 15 to 50 and at least one polymer has a value of m in the range from 30 to 300, including all values and subranges between them;

- polymers of the formula (XII) with m1selected in the range from 15 to 50, and m2selected in the range from 30 to 500, where the part corresponding to m1is 1-99% by weight of the total weight of the polymer, and the part corresponding to m2is 1-99% by weight of the total weight of the polymer;

- mixture of the polymer of formula (VIII), combining

1) 80-99% by weight of the polymer, where n is 2-10 and, in particular, 3-6, and

2) 1-20% of a polymer in which n is in the range from 5 to 500 and in particular from 6 to 100,

copolymers, including two fragments of the formula (VIII), in which at least one group Y contains at least one hydroxyl Deputy;

the polymers of formula (VIII), synthesized, at least with one part of the activated decollate (acid chloride of decollate, dianhydride or fluids) instead of decollate;

the polymers of formula (VIII)in which X represents -(CH2)3- or -(CH2 )10-; and

the polymers of formula (VIII), in which the polymer end multifunctional chain selected from the group consisting of monofunctional amines, monofunctional acids, monofunctional alcohols, including fatty acids, fatty alcohols and fatty amines number, such as, for example, octylamine, octanol, stearic acid and stearyl alcohol.

As in the case of polyamides, copolymers, polyurethane - or polyurea-silicone and polyurethane or polyurea-based hydrocarbon can be used in the invention by implementing interaction for synthesizing the polymer in the presence of α,ω-bifunctional block nesulyginamos nature, for example, a polymer of ester, polymer with simple ether or polyolefin.

As was shown above, the homopolymers or copolymers of the invention can contain siloxane fragments in the main chain of the polymer and groups capable of establishing hydrogen interactions, either in the main polymer chain or in its limit positions, or on side chains or branches of the main chain. This may correspond to the following five layouts:

in which the continuous line represents the main chain of the siloxane polymer and agrati represent groups, capable of establishing hydrogen interactions.

In case (1) groups capable of establishing hydrogen interactions, located in the extreme positions of the main chain.

In the case of (2) two groups capable of establishing hydrogen interactions, are located in each end position of the main chain.

In case (3) groups capable of establishing hydrogen interactions, are located within the main chain in the repeating fragments.

In cases (4) and (5) they are copolymers in which the groups capable of establishing hydrogen interactions, are located on branches of the main chain of the first row of fragments that are copolymerizable with fragments that do not contain groups capable of establishing hydrogen interactions. Preferably, the values of n, x and y are such that the polymer had the desired properties from the point of view of the gelation agent for the oily phase, preferably, fatty phases based on silicone oil.

As examples of polymers that may be used may be mentioned silicone polyamides obtained in accordance with the disclosure in the patent application US-A-5981680, the full disclosure of which is thus incorporated by reference.

Additional examples polyorganosiloxane polymers described in patent USpatents 6503632 and 6569955, both of which are thereby incorporated by reference in its entirety.

As noted above, the polymers of the present invention can be solid or liquid at room temperature. In the case where the polymers are solid, they preferably have a softening temperature of 50 to 130°C. Most preferably, they have a softening temperature in the range from 65°C to 150°C, including from 70°C to 130°C. This softening point is below the softening temperature of the other structural polymers that facilitate the use of polymers that are the subject of the invention, and limit the deterioration of the liquid fatty phase.

As noted above, polyorganosiloxane polymers of the present invention contain both siloxane units and at least two groups capable of establishing hydrogen interactions, such as amide linkages. Siloxane units can provide the compatibility with silicone fluid medium, if present, (for example, cyclomethicone), along with the fact that the groups capable of establishing hydrogen interactions, and the distance between them and the choice provisions of the amide linkages can facilitate gelation and the formation of cosmetic products.

In one embodiment, poliorama Olexandria polymer of the present invention is present in a quantity effective in order to ensure the characteristics of resistance to smudging, and may also provide at least one of the following characteristics: flexibility, softness and comfort when wearing. In addition, it is preferable that the compositions of the invention exhibit elasticity and/or good adhesion on rough cloth, on which were deposited composition. In another preferred embodiment, compositions of the present invention when applied to the surface of keratinized tissue are mostly non-sticky.

In the composition of the present invention polyorganosiloxane polymers are preferably present in an amount of from about 1 to about 50 percent by weight, more preferably from 3 to 35 percent by weight and most preferably from 5 to 20 percent by weight of the total weight of the composition.

VOLATILE ALCOHOL

In accordance with the present invention provide compositions containing at least one volatile alcohol. Volatile alcohol may be either linear or branched. The term "volatile linear alcohol", imply a connection with a straight chain containing at least one hydroxyl group, with the ignition temperature is preferably above 0°C, preferably from 0°C. to about 40°C, bol is e preferably from about 10°to about 40°C. The term "branched volatile alcohol" imply a connection with indirect chain containing at least one hydroxyl group, with the ignition temperature is preferably above 0°C, preferably from 0°C. to about 40°C., more preferably from approximately 20°to approximately 40°C.

Preferably, the volatile alcohol has less than 10 carbon atoms, more preferably from 2 to 5 carbon atoms, most preferably 2 to 4 carbon atoms. Suitable examples include ethanol, propanol, butanol, isopropanol, Isobutanol, 2-methyl-1-propanol and 3-methyl-1-butanol, and mixtures thereof, but is not limited to this. In preferred variants of implementation, the composition contains at least two volatile alcohol with different volatility. Thus, for example, the same composition can be relatively volatile and relatively non-volatile alcohol.

Preferably, the volatile(s) alcohol(s) is(are) from about 0.1% to about 30% by weight of the total composition, more preferably from about 0.5% to about 15% by weight of the total composition and most preferably from about 1% to about 10%, including all ranges and subranges between them.

Also preferably, the ratio polyorganosiloxanes on what the iMER volatile alcohol ranges from about 1:3 to about 70:1. In preferred embodiments, the implementation, the compositions contain more polyorganosiloxanes polymer than volatile alcohol, where the ratio polyorganosiloxane polymer to volatile alcohol about 2:1 to about 35:1 are especially preferred.

THICKENER

In accordance with the present invention provide compositions containing at least one thickener. Thickeners are substances that increase the viscosity of the compositions of the invention. Such thickeners may, for example, be chosen from waxes, rheological agents and gelling agents.

Non-limiting examples of acceptable gelling substances include gel-forming substance in a polymeric form and the gel-forming substance in mineral form, such as, for example, elastomeric polyorganosiloxanes, such as elastomeric polyorganosiloxanes, sold or manufactured under the trade names KSG6 from the company Shin-Etsu, Trefil E-505C or Trefil E-506C from Dow-Corning, Gransil from Grant Industries (SR-CYC, SR DMF10, SR-DC556)or elastomeric polyorganosiloxanes, commercially available in the form of pre-formed gels (KSG15, KSG17, KSG16, KSG18, KSG21 from the company Shin-Etsu, gel, Gransil SR 5CYC gel Gransil SR DMF 10 gel, Gransil SR DC556, SF 1204 and JK 113 from General Electric company), or emulsifying elastomers, such the AK emulsifying elastomers, sold under the trade names KSG-210, KSG-30, KSG-31, KSG-32, KSG-33, KSG-40, KSG-41, KSG-42, KSG-43 and KSG-44 from the company Shin-Etsu silicone gum, crystalline silicone compound, asilicone polyamides, bearing in limit positions ester or triamine functional groups, such as compounds described in the patents and patent applications US 5783657, US 6268466, WO 01/95871, WO 00/40216, US 2002/0035237 and EP 1068856, the disclosure of which is incorporated in this document by reference, polyurethanes, and polymers or copolymers resulting from the polymerization or copolymerization of ethylene monomer, in particular, can be used with vinyl, acrylic or methacrylic copolymers, which can be a block copolymers, such as diblock or triblocaltara, or even multiplexability or copolymers Torx type or radial copolymers, but are not limited to this. Such ethylene gel-forming substance may contain, for example, styrene block (S), ancilliary block (AS), ethylene/butylene block (EB), ethylene/propylene block (EP), polybutadiene block (B), isoprene block (I), acrylic block (A), methacrylate block (MA) or a combination of these blocks.

In one embodiment of the present invention as a gel-forming substance or ethylene-rheological substance used is a copolymer containing, at least one styrene block. Can be used tribocorrosion and, in particular, the copolymers of the polystyrene/branch, Rubezhnoe, Ukraine or polystyrene/polybutadiene type, such as block copolymers, sold or manufactured under the trade name "Luvitol HSB" by BASF, the copolymers of the polystyrene/copoly(ethylene-propylene)type type or, alternatively, the polystyrene/copoly(ethylene/butylene)new type, such as copolymers sold or made known under the trademark "Kraton" by Shell Chemical Co. or Gelled Permethyl 99A by the company Penreco. Can also be used a styrene-methacrylate copolymers.

As ethylene gel-forming substances which may be used in compositions of the invention may be mentioned, for example, ethylene gelling substances Kraton G1650 (SEBS), Kraton G1651 (SEBS), Kraton G1652 (SEBS), Kraton G1657X (SEBS), Kraton G1701X (SEP), Kraton G1702X (SEP), Kraton G1726X (SEB), Kraton G1750X (EP) based on multiresolutional copolymer (multiarm), Kraton G1765X (EP) based on multiresolutional copolymer (multiarm), Kraton D-1101 (SBS), Kraton D-1102 (SBS), Kraton D-1107 (SIS), Gelled Permethyl 99A - 750, Gelled Permethyl 99A - 753-58 (a mixture of star-shaped polymer and triblocaltara), Gelled Permethyl 99A - 753-59 (a mixture of star-shaped polymer and triblocaltara), Versagel 5970 and Versagel 5960 from Penreco (a mixture of star-shaped polymer and tablecolor in isododecane), and OS 12880, OS 129881 and OS 84383 from Lubrizol (styrene-methacrylate copolymer).

Di - or triblocaltara, such as polystyrene-copoly(ethylene/propylene) or polystyrene-copoly(ethylene/butylene), such as the copolymers described in patent applications WO 98/38981 and US 2002/0055562, disclosure of which is incorporated so by reference, are also included in the present invention.

As modified clays, which can be used may be mentioned hectorite, modified ammonium chloride10-C22fatty acid, such as hectorite modified distearyldimethylammonium-chloride, also known as quaternium-18 bentonite, such as the products sold or manufactured under the trade names of Bentonite 34 by the company Rheox, laytone XL, Claytone 34 and Claytone 40, sold or manufactured by the company Southern Clay, the modified clays known under the name of quaternium-18-benzalconi-bentonites and sold or made under the trade names Claytone HT, Claytone GR and Claytone PS by the company Southern Clay, the clays modified with stearoylbenzoylmethane-chloride, known as stearalkonium-bentonites, such as the products sold or manufactured under the trade names Claytone APA and Claytone AF by the company Southern Clay, and Baragel 24, sold or manufactured by the company Rheox.

the other mineral gelling substances, which can be used may be mentioned silicon dioxide (silica)such as colloidal silicon dioxide. Colloidal silica may have a particle size that may be nanometric - micrometric, for example ranging from about 5 nm to 200 nm.

Colloidal silica can be obtained by high temperature hydrolysis of a volatile silicon compound in a hydrogen-oxygen flame, producing a finely ground silica. This process makes it possible to obtain hydrophilic silica, which have a large number of silanol groups on its surface. Such hydrophilic silica sell or produce, for example, under the trade names "Aerosil 130®", "Aerosil 200®", "Aerosil 255®", "Aerosil 300®" and "Aerosil 380®" by the company Degussa, and "CAB-O-SIL HS-55®", "CAB-O-SIL EH-5®", "CAB-O-SIL LM-130®", "CAB-O-SIL MS-55®" and "CAB-O-SIL M-5®" by the company Cabot.

Thus, it is possible to chemically modify the surface of the hydrophilic silicon dioxide by chemical reaction, producing a reduction in the number of silanol groups. Silanol groups can be substituted, for example, hydrophobic groups: it then gives you a hydrophobic silicon dioxide. The hydrophobic group can be either (a) trimethylsiloxy groups that receive, in particular, by the OBR is batawana colloidal silicon dioxide in the presence of hexamethyldisilazane. The silica thus treated, known as "silanizing silicon dioxide in accordance with the data of certified trade missions CTFA (6th edition, 1995). They are sold or manufactured, for example, under the trademark "Aerosil R812®" by the company Degussa, and "CAB-O-SIL TS-530®" by the company Cabot; (b) dimethylsiloxane or polydimethylsiloxane groups that receive, in particular by colloidal processing of silicon dioxide in the presence of polydimethylsiloxane or clear. The silica thus treated, known as "dimethylaminovinyl silicon dioxide in accordance with the data of certified trade missions CTFA (6th edition, 1995). They are sold or manufactured, for example, under the trademark "Aerosil R972®" and "Aerosil R974®" by the company Degussa, and "CAB-O-SIL TS-610®and CAB-O-SIL TS-720®" by the company Cabot; and (C) group resulting from the reaction of interaction of colloidal silica with the silane-alkoxides or siloxanes. Such treated silica are, for example, the products sold or manufactured under the trademark "Aerosil R805®" by the company Degussa.

In accordance with the invention, hydrophobic silica, such as colloidal silicon dioxide, can be used as a lipophilic gel is forming substances. The use of colloidal silicon dioxide allows to obtain a translucent or even transparent composition, in particular in the form of a pencil, which does not spread/seeps, in the absence of pomutnela particles, such as waxes, fillers and pigments (including, parametry).

Such thickeners may also include at least one wax. For the purposes of this invention, a wax is a lipophilic compound of the fatty series, which is a solid at room temperature (25°C.) and atmospheric pressure (760 mm RT. Art., that is 101 kPa), which undergoes a reversible change of state solid/liquid having a melting point of more than 40°C and, in addition, for example, more than 55°C and which may be up to 200°C. By bringing the wax to its melting temperature it is possible to make it miscible with oils and to form a microscopically homogeneous mixture, but on the reverse, bringing the temperature of the mixture to room temperature, get the recrystallization of the wax in the oils of the mixture. This is a recrystallization in a mixture, which is responsible for reducing the gloss of the mixture.

For the purposes of the invention, the waxes are waxes commonly used in cosmetics and dermatology; they have, for example, of natural origin, such as beeswax,ozokerite, Carnauba wax, candelilla wax, wax ouricuri, vegetable wax, wax the bark of the cork oak, sugar cane wax, paraffin wax, mineral wax, microcrystalline waxes, lanolin wax, montany wax, maltes and hydrogenated oils such as hydrogenated jojoba oil, and waxes of synthetic origin, for instance polyethylene waxes derived from the polymerization of ethylene, waxes obtained by Fischer-Tropsch synthesis, esters of fatty acids and glycerides that are solid at 40°C, for example, at temperatures above 55°C, waxes based on fatty alcohols, such as waxes based on fatty alcohols sold by Baker Petrolite under the trade name Performacol (Performacol 350, 425 and 550), including With30-C50alcohols, silicone waxes such as alkyl - and alkoxy-poly(di)methylsiloxanes and/or poly(di)methylsiloxane esters that are solid at 40°C, for example, at temperatures above 55°C.

In accordance with the invention, the values of the melting temperature corresponds to the peak of the melting point, measured by way of the method of "Differential Scanning Calorimetry" when the temperature rise of 5 or 10°C/min

Compositions of the present invention can also optionally contain fat-soluble or dispersible real the formed polymers, such as, for example, polyalkylene, in particular polybutene, poly(meth)acrylates, alkylaryl with linear or branched, saturated or unsaturated With1-C8alkyl radical group, such as ethylcellulose and propylethylene, silicone polymers which are compatible with the fatty phase, as well as vinylpyrrolidone (VP) copolymers, and mixtures thereof.

Can be used vinylpyrrolidone copolymers, copolymers With2-C30such as3-C22alkene, and combinations thereof. As examples of copolymers of vinylpyrrolidone, which can be used in the invention may be mentioned vinyl pyrrolidone/vinyl acetate, vinyl pyrrolidone/ethyl methacrylate, bottled polyvinylpyrrolidone (PVP), vinyl pyrrolidone/ethyl methacrylate/methacrylic acid, vinyl pyrrolidone/achozen, vinyl pyrrolidone/hexadecene, vinyl pyrrolidone/triacetin, vinyl pyrrolidone/styrene or a copolymer of vinyl pyrrolidone/acrylic acid/laurenmarie.

To make the film not only strength characteristics, but also characteristics to the touch and texture, can be used polyvinylpyrrolidone/hexadecanoyl copolymer having a mass-average molecular weight of from 7000 to 7500, or, alternatively, polyvinylpyrrolidone/eicosenoic copolymer having a mass-average molecular mA is su from 8000 to 9000.

Preferably, the thickener(s) is(are) from about 1% to about 50% by weight of the total composition, more preferably from about 5% to about 40% by weight of the total composition and most preferably from about 7% to about 30%, including all ranges and subranges between them.

ESSENTIAL OIL

In accordance with a particularly preferred variant implementation of the present invention provide compositions, optionally containing at least one essential oil. Preferably, at least one essential oil is a silicone essential oil, hydrocarbon essential oil or their mixture.

In accordance with a preferred variant implementation, the composition may contain one or more volatile silicone oils. Examples of volatile silicone oils include linear or cyclic silicone oils having a viscosity at room temperature of less than or equal to 6 CST (Centistokes), and having from 2 to 7 silicon atoms, where such silicones are optionally substituted alkyl or alkoxygroup with 1-10 carbon atoms. Specific oils that can be used in the invention include octamethyltetrasiloxane, decamethylcyclopentasiloxane, Dodecamethylcyclohexasiloxane, heptameric ciloxan, hexamethyldisiloxane, decamethylpentasiloxane, Dodecamethylcyclohexasiloxane and mixtures thereof. Other volatile oils that may be used include essential oil KF-96A c with a viscosity of 6 CST, commercially available product from the company Shin Etsu, having a flash point of 94°C. Preferably, the volatile silicone oils have a flash point of at least 40°C.

Non-limiting examples of volatile silicone oils are shown in table 1 below.

td align="center"> 7
Table 1
ConnectionIgnition temperature (°C)Viscosity (cSt)
Actitretin931,2
Existimatio791,2
Decamethylcyclopentasiloxane (Cyclopentasiloxane or D5)724,2
Octamethylcyclotetrasiloxane (cyclotetrasiloxane or D4)552,5
Dodecamethylcyclohexasiloxane (D6)93
Decamethylpentasiloxane (L4)631,7
KF-96 A from Shin Etsu946
PDMS (polydimethylsiloxane) DC 200 (1,5 cSt) from Dow Corning561,5
PDMS DC 200 (2 cSt) from Dow Corning872
PDMS DC 200 (5 cSt) from Dow Corning1345
PDMS DC 200 (3) from Dow Corning1023

Additionally, the compositions of the present invention can be applied essential linear silicone oil. Suitable ether linear silicone oils include essential linear silicone oils described in U.S. patent No. 6338839 and WO 03/042221, the contents of which are incorporated in this document by reference. In one embodiment, the essential linear silicone oil is decamethylpentasiloxane. In yet another embodiment, decamethylpentasiloxane optionally combined with another solvent, which is more essential than decamethylpentasiloxane.

Rela is availa able scientific C with other preferred options for implementation, the composition may contain one or more resiliancy essential oils, and they can be selected from ether, hydrocarbon oils, esters and ethers. Examples of such essential asilicone oils include essential hydrocarbon oils having from 8 to 16 carbon atoms, and their mixtures and in particular branched C8-C16alkanes, such as C8-C16isoalkanes (also known as ISO), isododecane, sodacan, isohexadecane and for example the oils sold under the trade names Isopar or Permethyl,8-C16branched esters, such as isohexyl or Isodecyl-neopentanoate, and mixtures thereof, but is not limited to this. Preferably, the ether asilicone oils have a flash point of at least 40°C.

Non-limiting examples of essential asilicone essential oils are shown in table 2 below.

Table 2
ConnectionIgnition temperature (°C)
Isododecane43
Isohexadecane102
Isodecyl-neopentanoate118
n-butyl ether propylene glycol60
Ethyl-3-ethoxypropionate58
Acetate methyl ether of propylene glycol46
Isopar L (isoparaffin11-C13)62
Isopar H (isoparaffin11-C12)56

The volatile solvents/oils can be determined by using the rate of evaporation, as described in US patent No. 6338839.

Preferably, the ether(s) oil(and), when present(s)is(are) from about 5% to about 90% by weight of the total composition, more preferably from about 10% to about 80% by weight of the total composition and most preferably from about 20% to about 75%, including all ranges and subranges between them.

Also preferably, the ether(s) oil(and)when there is(are)present(s) in an amount greater than the amount present ether-alcohol, preferably in a ratio of at least 2:1 (essential oil: essential alcohol), more preferably in a ratio of at least 3:1, more preferably in a ratio of at least 4:1, more preferred is sustained fashion in the ratio, at least 5:1 and more preferably in a ratio of at least 6:1.

Colorants

In accordance with a particularly preferred variant implementation of the present invention provide compositions, optionally containing at least one coloring substance. Preferably, such colored compositions are cosmetic compositions, such as, for example, compositions for the lips (for example, lipstick or liquid colorants lip), mascara, nail Polish or base.

In accordance with this embodiment, at least one coloring substance is preferably selected from pigments, dyes such as oil-soluble dyes, pearl pigments and substances, giving pearl color/Shine.

Typical oil-soluble dyes that may be used in accordance with the present invention include Sudan red, DC Red 17 (red), DC Green 6 (green), β-carotene, soybean oil, Sudan brown, DC Yellow 11 (yellow), DC Violet 2 (purple), DC Orange 5 (orange), annatto and quinoline yellow. Fat-soluble dye, when present, usually have a concentration in the range up to 20% by weight of the total weight of the composition, for example, from 0.0001% to 6%.

Pearlescent pigments which can be used is according to the present invention, can be chosen from white nacreous pigments such as mica coated with titanium or with bismuth oxychloride, colored nacreous pigments such as titanium mica with iron oxides, titanium mica with glandular blue or chromium oxide, titanium mica with an organic pigment selected from organic pigments mentioned above, and nacreous pigments based on bismuth oxychloride. Pearlescent pigments, if present, are present in the composition with a concentration in the range up to 50% by weight of the total weight of the composition, for example, from 0.1% to 20%, preferably from 0.1% to 15%, including all ranges and subranges between them.

Pigments that may be used in accordance with the present invention, can be selected from white, colored, inorganic, organic, polymer, polimernyh, coated and uncoated pigments. Typical examples of mineral pigments include titanium dioxide, optical surface-treated, zirconium oxide, zinc oxide, cerium oxide, iron oxides, chromium oxides, manganese violet, ultramarine blue, chromium hydrate and ferrous blue. Typical examples of organic pigments include carbon black, pigments of D - and C-type, and replace based cochinilla Carmine, barium, strontium, calcium and aluminium.

what if present, the pigments may be present in the composition with concentration, fluctuating in the range of up to 50% by weight of the total weight of the composition, for example, from 0.5% to 40%, and additionally, for example, from 2% to 30%, including all ranges and subranges between them. In the case of some products, pigments, including pearlescent pigments may, for example, up to 50% by weight of the composition.

Film-forming substance

In accordance with a particularly preferred variant implementation of the present invention provide compositions, optionally containing at least one film-forming agent (foaming agent). Acceptable film-forming substance known in the field and include film-forming substance disclosed in US patent publication pplication publication No. 2004/0170586, the full content of which is thus incorporated by reference, but are not limited to this. Non-limiting typical examples of such film-forming substances include silicone resin, such as, for example, the MQ resin (for example, trimethylchlorosilane) and resin MK (for example, polymethylsilsesquioxane), silicon esters, such as silicone esters disclosed in patent US Pat. No. 6045782, 5334737 and 4725658, disclosure of which is thus incorporated by reference, the polymers comprising the main chain, selected the th of vinyl polymers, methacrylic polymers and acrylic polymers, and at least one chain selected from pendantic siloxane groups and pendantic organofluorine groups, such as the polymers disclosed in the patent US Pat. No. 5209924, 4693935, 4981903, 4981902 and 4972037 and WO 01/32737, the disclosure of which are thereby incorporated by reference, polymers such as the polymers disclosed in the patent US Pat. No. 5468477, the disclosure of which is thus incorporated by reference (non-limiting examples of such polymers is poly(dimethylsiloxane)-g-poly(isobutyronitrile), which is commercially available in the company: 3M Company under the trade name VS 70 IBM).

In accordance with a preferred variant implementation of the foaming agent, when present, is present in the composition in a quantity ranging from 0.1% to 30% by weight relative to the total weight of the composition. Preferably, the foaming agent is present in an amount in the range from 0.5% to 25% by weight relative to the total weight of the composition and more preferably from 2% to 20%, including all ranges and subranges between them. An ordinary person skilled in the art will understand that the foaming agent of the present invention can be which is commercially available and may come from suppliers in the form of a dilute solution. The quantity of foaming agent, disclosed what this document therefore, reflects the mass percentage of the active substance.

In accordance with a particularly preferred variant implementation, when the present film-forming substance, the combined number polyorganosiloxanes(s) polymer(s) and film-forming substances is 20-60% by weight of the total weight of the composition. In particularly preferred embodiments, the implementation polyorganosiloxane polymer is a silicone-polyamide copolymer, and film-forming substance is a silicone resin, in particular trimethylsulfoxonium.

In accordance with a preferred variant implementation of the present invention the compositions of the present invention are anhydrous. The term "anhydrous" means that the composition essentially contains no water (i.e. contains less than about 0.5% by weight of water relative to the composition).

In accordance with other preferred variants of implementation of the composition of the present invention optionally contain water. In this embodiment, water is preferably present in amounts in the range from about 0.6 to about 70%, preferably from about 3.0 to 60% and more preferably from about 5 to about 50% relative on the total weight of the composition. Preferably, such an aqueous cosmetic composition is a composition for the lips (for example, lipstick or liquid painting means for lips), base or carcasses and are emulsions or dispersions.

Additional additives

The composition of the invention may also contain any additive usually used in this field. For example, can be added dispersing agents such as poly(12-hydroxystearate acid), antioxidants, essential oils, sunscreen agents, preservatives, fragrances, fillers, neutralizing agents, cosmetic and dermatological active agents such as, for example, emollients, moisturizers, vitamins, essential fatty acids, surfactants, buttery compounds and their mixtures. A non-exhaustive list of such ingredients can be found in the published patent application US patent application publication No. 2004/0170586, the full content of which is thus incorporated by reference. Additional examples of suitable additional components can be found in other references, which are incorporated by reference in this application. Additional examples of such additional ingredients can be found in the dictionary of International Cosmetic Ingredient Dictionary and Handbook (9th edition 202).

The person skilled in the art will be able to select the optional additional additives and/or their amounts so that the predominant properties of a composition in accordance with the invention were not, or were not significantly affected by the envisaged addition.

Such substances can be chosen in different ways by the person skilled in the art in order to prepare a composition which has the desired properties, such as consistency or texture.

These additives may be present in the composition in a proportion from 0% to 99% (for example, from 0.01% to 90%) relative to the total weight of the composition and, optionally, for example, from 0.1% to 50% (if present), including all ranges and subranges between them.

In accordance with a particularly preferred embodiment of the present invention, compositions of the invention contain less than 25% by weight relative to the total weight of the composition, the powder material (i.e. powder material, such as pigments and fillers, which do not dissolve and/or are insoluble in the compositions of the invention), more preferably less than 20% and most preferably less than 15%.

Needless to say that the composition of the invention should be cosmetically or dermatologically acceptable, i.e. it must contain a non-toxic physiologically acceptable medium and which should be suitable for application to the eyelashes of people.

Non-limiting examples of such additional components include non-volatile oils such as silicone oils (for example, Dimethicone, fenitrothion, trimethyl-pentaphenyl-trisiloxane and so on) or hydrocarbon oils (e.g., esters). In one embodiment of the present invention the compositions of the present invention are essentially free of silicone oils (i.e. contain less than about 0.1% silicone oils). In yet another embodiment, the compositions are essentially free from asilicone oils (i.e. contain less than about 0.1% asilicone oils). In yet another embodiment, the compositions are essentially free from non-volatile oils (i.e. contain less than about 0.1% of non-volatile oils).

Compositions in accordance with the present disclosure may also contain at least one combination of a fatty series, which is buttery at room temperature. Used in this document the expression "buttery fatty substance"is considered to mean fatty substances with a melting point in the range from 20°C to 55°C, for example, from 25°C to 45°C. and/or viscosity at 40°C in the range from 0.1 PA·s to 40 PA·s (1-400 poises), for example, from 0.5 PA·s to 25 PA·s, measured using the of viscosimeter Contraves TV or Rheomat 80, equipped with a spindle rotating at 60 Hz. The person skilled in the art can select the spindle for measuring the viscosity of the spindles MS-r3 and MS-r4, on the basis of publicly available information, in order to be able to perform measurements of the test buttery connection.

These fatty substances may constitute, for example, compounds based on hydrocarbons, optionally of polymeric type; they can also be chosen from silicone compounds; they may also be in the form of a mixture of compounds based on hydrocarbon and/or silicone compounds. In the case of a mixture of different buttery fat, buttery connection-based hydrocarbons (containing mainly hydrogen and carbon atoms and optionally ester groups) can be used, for example, in fixed proportions.

Among buttery compounds which can be used in the compositions in accordance with the present disclosure, may be made of a non-limiting reference to lanolin and lanolin derivatives such as acetylated lanolin or oxyprogesterone lanoline or isopropylene, and mixtures thereof. It is also possible to use esters of fatty acids or of fatty alcohols, for example, esters of fatty acids or of fatty alcohols, containing from 20 to 65 carbon atoms, such as trees stearyl or cetyl-citrate; Arachidyl-propionate; polyvinyl laurate; bis-diglyceryl-polyacyladipate-2; esters of cholesterol, such as triglycerides of vegetable origin, such as hydrogenated plant oils, viscous polyesters such as poly(12-hydroxystearate acid), and mixtures thereof. Additionally may be made of a non-limiting reference to buttery silicone fatty substances, such as polydimethylsiloxane (PDMS), including pendente chain alkyl or alkoxide containing from 8 to 24 carbon atoms, such as sterilisation, for example, sterilisation sold by Dow Corning under the trade names DC2503 and DC25514, and mixtures thereof.

In accordance with a preferred variant of the present invention provide methods of treatment, care and/or use makeup to keratinous tissue, such as skin, lips, hair and mucous membranes, by applying compositions of the present invention on the surface of keratinized tissue in an amount sufficient to treat, care for and/or use makeup to keratinous tissue. Preferably, the "makeup" on keratinized tissue includes applying at least one coloring matter on the surface of keratinized tissue in sufficient quantity to provide the color/shade of keratinized tissue.

ACC is accordance with other preferred options exercise provide ways to hide/camouflage or mask/correction of deficiencies associated with keratinous tissue, such as defects or stains by applying compositions of the present invention on the surface of keratinized tissue in sufficient quantity to conceal or disguise such shortcomings.

In accordance with other preferred options exercise provide ways to improve the appearance of keratinous tissue by applying compositions of the present invention on the surface of keratinized tissue in sufficient quantity to improve the appearance of keratinous tissue.

In accordance with the three preceding preferred variant implementation, the compositions of the present invention containing at least one polyorganosiloxane polymer, preferably polysilicon-polyamide copolymer, at least one volatile alcohol, and at least one thickener is applied topically to the desired area of the skin in sufficient quantity to treatment, care and/or makeup to keratinous tissue, in order to hide or disguise the defects associated with keratinous tissue defects or spots on the skin, or to improve the appearance of keratinous tissue. The composition can be applied on the desired area if needed, preferably once or twice daily, more preferably once a day, and then preferably stavlenikom to exposure to the contact, for example, clothing or other items (for example, glass or coat). Preferably, the composition is allowed to dry for approximately 5 minutes or less, more preferably within about 2 minutes or less. The composition is preferably applied to the desired area that is dry or has been dried prior to application, or which previously was coated-basis. Most preferably, the composition additionally contains at least one coloring substance, at least one film-forming substance and/or at least one essential oil.

In accordance with a preferred embodiment of the present invention provide compositions having improved cosmetic properties such as, for example, improved performance to the touch when applied (for example, when overlaying layer), resistance (makeup), resistance to smudging or water resistance. Improved properties can also be selected from superior elasticity/plasticity, comfort in carrying, drying time or ability to resist, and reduced stickiness or moving/spreading over time.

The present invention also provides for kits and/or pre-Packed substances suitable for use by consumers, the soda is containing one or more compositions in accordance with the description of this document. The packaging and the device applied to any subject invention can be selected and produced by experts in this field, based on publicly available information, and adapted in accordance with the nature of the composition, which must be Packed. Actually the type of device that should be used can be, in particular, is associated with the consistency of the composition, in particular its viscosity; it may also depend on the nature of the constituents present in the composition, for example, from the presence of volatile compounds.

In accordance with a particularly preferred variant of implementation, the kits of the present invention include (a) a composition comprising at least one polyorganosiloxane polymer, at least one thickener and at least one volatile alcohol; and (b) composition-based coating and/or covering.

In accordance with this embodiment, the composition (a) corresponds to the compositions of the invention described above, while composition (b) is a composition(s), damage(s) before and/or after application of the composition of the invention, typically known in the field as cover-base (applied to) and top cover (done once). No special requirements to cover the base and top coatings, which can be used in owani in combination with the compositions of the present invention, and thus, such coatings-base and top coatings can contain ingredients such as ingredients discussed above. However, preferably, such coating-substrate and the top cover should not be too harmful effects on the properties of the compositions of the invention (for example, coating the base or the top coating should not unacceptably affect the properties of resistance to lubricating compositions of the invention).

For example, in accordance with a particularly preferred variant implementation of the present invention provides kits comprising (a) composition-based coating containing at least one polyorganosiloxane polymer, at least one thickener and at least one volatile alcohol; and (b) the composition of the top coating containing non-volatile solvent. In accordance with a particularly preferred variant implementation of the composition of the upper cover further comprises at least one volatile oil, preferably ether hydrocarbon oil, and the composition of the top coating contains at least one non-terrestrial silicone oil. In accordance with a particularly preferred variant implementation of such sets are usually used for application of makeup on the skin or lips, especially on the lips.

In a preferred is ariante implementation kits of the present invention include two or more solid compositions. For example, the kit may include (a) a solid composition comprising at least one polyorganosiloxane polymer, at least one thickener and at least one volatile alcohol; and (b) a solid composition-based coating and/or covering.

In a particularly preferred embodiment, the kits of the present invention include (a) a solid composition comprising at least one silicone-polyamide copolymer, at least one coloring substance, at least one thickener and at least one volatile alcohol; and (b) a solid composition of the top coating containing at least one oil and/or at least one wax.

In accordance with other variants of implementation of the present invention provide methods of obtaining narodnostnej composition, preferably a solid composition, comprising mixing together at least one polyorganosiloxane polymer, preferably a silicone-polyamide copolymer, at least one thickener and at least one volatile alcohol, and at least one thickener, with the formation of narodnostnej composition. In accordance with such a preferred variant implementation, at least one volatile alcohol makes possible a more rapid dissolution of reorganization.instead polymer during preparation narodnostnej composition. In accordance with a particularly preferred variant implementation is faster dissolution allows the use of lower temperature/lower the amount of time during cooking narodnostnej composition.

Unless otherwise indicated, all numbers expressing quantities of ingredients, reaction conditions, and so henceforth used in the description and in the claims, should be understood as being variable in all examples by the term "approximately". Accordingly, unless otherwise stated to the contrary, the numerical parameters set forth in the following description and in the accompanying claims, are approximate values that may vary depending on the desired desired properties, which must be obtained by the present invention.

Notwithstanding that the numerical ranges and parameters that define the broad scope of the invention, are approximate values, the numerical values set forth in the specific examples are reported as precisely as possible. Any numerical values, however, inherently contain certain errors resulting from the standard deviation found in their respective dimensions. The following examples are intended to illustrate the invention, does not exhaust anesiva as a result of its volume. The percentage given in terms of mass.

28,24
Example 1 - Hard coating-substrate (lipstick or base)
Name INCI (international nomenclature of cosmetic ingredients)Concentration
LAUROYL-LYSINE0,90
The IRON OXIDES1,7830
The IRON OXIDES0,0310
TITANIUM DIOXIDE1,6650
DISTEARDIMONIUM-HECTORITE (and) propylene carbonate8,68
FLAVOURING SUBSTANCE0,20
MICA4,0210
POLYETHYLENE WAX8,91
TRIMETHYLSULFOXONIUM21,55
COPOLYMER NYLON-611/DIMETHICONE13,90
ISOPROPYL ALCOHOL5
ISODODECANE
With30-50ALCOHOLS5,12

Example 2 - Solid upper floor
Name INCI USAConcentration
TRIMETHYL-PENTAPHENYL-TRISILOXANE (DOW CORNING PH-1555 HRI COSMETIC FLUID MEDIUM)90,0
OZOKERITE5,5
BEESWAX4,5
The TOTAL NUMBER of100,0

Example 3 - Solid upper floor
The INCI nameConcentration
TRIMETHYL-PENTAPHENYL-TRISILOXANE (DOW CORNING PH-1555 HRI COSMETIC FLUID MEDIUM)92,50
OZOKERITE3,25
BEESWAX4,25
The TOTAL NUMBER of100,0

Example 4 - Solid upper floor
Name INCI USAConcentration
TRIMETHYL-PENTAPHENYL-TRISILOXANE (DOW CORNING PH-1555 HRI COSMETIC FLUID MEDIUM)95,0
OZOKERITE2,0
BEESWAX3,0
The TOTAL NUMBER of100,0

1. Cosmetic composition comprising at least one silicone-polyamide copolymer, at least one volatile alcohol and at least one thickener, where the specified copolymer includes at least one fragment (III) or (IV)

or

where 1) R1, R2, R3and R4that may be the same or different, represent a group chosen from:
linear, branched or cyclic, saturated or unsaturated, groups based on C1-C40hydrocarbon, possibly containing in its chain one or more atoms of oxygen, sulfur and/or nitrogen, and possibly being partially or totally substituted by fluorine atoms,
With6-C10aryl groups, it is certainly substituted by one or more C 1-C4alkyl groups,
organopolysiloxane chains possibly containing one or more atoms of oxygen, sulfur and/or nitrogen;
groups X, which may be identical or different, represent a linear or branched C1-C30alkylenediamine group, possibly containing in its chain one or more oxygen atoms and/or nitrogen;
Y is a saturated or unsaturated, C1-C50linear or branched divalent alkilinity, Allenova, cycloalkanones, alkylsilanes or arylalkylamines group may containing one or more atoms of oxygen, sulfur and/or nitrogen and/or bearing as substituent one of the following atoms or groups of atoms: fluorine, hydroxyl, C3-C8cycloalkyl, C1-C40alkyl, C5-C10aryl, phenyl, optionally substituted from 1 to 3 C1-C3alkyl groups, C1-C3hydroxyalkyl and C1-C6aminoalkyl, or
Y represents a group corresponding to the formula

in which T represents a linear or branched, saturated or unsaturated, trivalent or tetravalent group based on the C3-C24hydrocarbon, optionally substituted organopolysiloxane chain, and possibly containing one or the more atoms, selected from O, N and S, or
T represents a trivalent atom chosen from N, P and Al, and
R5represents a linear or branched C1-C50alkyl group or organopolysiloxane chain may contain one or more ester, amide, urethane,
THIOCARBAMATE, urea, timesaving and/or sulfonamidnuyu groups that can be linked to another chain of the polymer;
p is an integer of at least 1, for example, in the range from 2 to 500 and preferably from 2 to 200, and m is an integer of at least one in the range from 1 to 35,000;
where the value of the specified silicone-polyamide copolymer to the specified volatile alcohol is in the range from about 2:1 to about 70:1.

2. The composition according to claim 1, where the ratio of the specified silicone-polyamide copolymer to the specified volatile alcohol is in the range from about 2:1 to about 35:1.

3. The composition according to claim 1, additionally comprising at least one film-forming substance.

4. The composition according to claim 3, where the film-forming substance is trimethylsulfoxonium.

5. The composition according to claim 1, additionally comprising at least one coloring substance.

6. The composition according to claim 1, further including, what about the least one essential oil.

7. Composition according to claims 1-6, where the composition is a solid.

8. The composition according to claim 1, where the silicone-polyamide copolymer constitutes at least, nylon 611/Dimethicone copolymer.

9. The composition according to claim 7, where the thickening agent is a wax.

10. The composition according to claim 7, where the thickening agent is a gelling agent.

11. The composition according to claim 7, where the thickener is a rheological polymer.

12. The composition according to claim 11, where the rheological polymer is a vinyl pyrrolidone/hexadecene.

13. The composition according to claim 6, where the essential oil is an essential hydrocarbon oil.

14. The composition according to claim 1, comprising at least two volatile alcohol.

15. The composition according to claim 1, where the volatile alcohol is a branched volatile alcohol.

16. The composition according to item 15, where the branched volatile alcohol selected from the group consisting of isopropanol, Isobutanol and mixtures thereof.

17. The composition according to PP or 8-16, where the value of the specified essential oil to the specified volatile alcohol at least 2:1, more preferably in a ratio of at least 3:1, more preferably in a ratio of at least 4:1, more preferably in a ratio of at least 5:1 and more preferably in a ratio of at least 6:1.

18. The composition according to claim 1, where composers who Oia is waterless.

19. The kit includes (a) a cosmetic composition is a Foundation according to claim 1 for coating containing at least one silicone-polyamide copolymer, at least one volatile alcohol, at least one thickener and at least one coloring substance; and (b) the composition for top coating containing at least one oil.

20. Set according to claim 19, where the composition is the basis for the coating further comprises at least one film-forming substance.

21. Set according to claim 19 or 20, where the thickening agent is a wax.

22. Set according to claim 19 or 20, where the thickening agent is a gelling agent.

23. Set according to claim 19 or 20, where the thickener is a rheological polymer.

24. Set according to claim 20, where the film-forming substance is trimethylsulfoxonium.

25. Set according to claim 19 or 20 additionally comprising at least one essential oil.

26. Set according to claim 19 or 20, where the silicone-polyamide copolymer constitutes at least, nylon 611/Dimethicone copolymer.

27. Set according to claim 19 or 20, where at least one volatile alcohol in the composition is the basis for coverage represents a branched volatile alcohol.

28. Set in item 21, where the branched volatile alcohol selected from the group consisting of isopropanol, Isobutanol and mixtures thereof.

29. Set according to claim 19 or 20, where the song for top coating further comprises, at least one pasty fatty substance.

30. Set according to claim 19 or 20, where the composition for top coating contains at least one non-terrestrial silikonovoe oil.

31. A method of obtaining a non-liquid cosmetic composition according to claim 1, comprising mixing together at least one silicone-polyamide copolymer, at least one thickener and at least one branched volatile alcohol, with formation of a non-liquid composition.

32. The method according to p, comprising mixing together at least one silicone-polyamide copolymer, at least one branched volatile alcohol, at least one coloring substance and at least one thickener, with the formation of a solid composition.

33. The method according to p or 32, where the silicone-polyamide copolymer constitutes at least, nylon 611/Dimethicone copolymer.

34. The cosmetic method of applying the coloring matter in the skin or lips, comprising applying the composition according to any one of pp.5-18 on the skin or lips in a quantity sufficient to dye the skin or lips.

35. The method according to clause 34, further comprising applying the composition for top coating on the skin or lips.



 

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FIELD: medicine.

SUBSTANCE: claimed invention relates to field of cosmetology, namely to cosmetic composition for care and make-up of lips, method of lip make-up of and application of copolymer in said composition. Claimed cosmetic composition contains one copolymer in form of block-copolymer, which contains, first block and second block, one non-volatile oil, one oil with glitter effect. First block is obtained from one acrylate monomer of formula CH2=CH-COOR2, where R2 - represents cycloalkyl group, which has 4-12 carbon atoms, and from one methacrylate monomer of formula CH2=C(CH2)-COOR'2, where R'2 represents cycloalkyl group, which has 4-12 carbon atoms. Second block is obtained from monomer of acrylic acid and from one other monomer with temperature of vitrifying less or equal 20°C. Non-volatile oil has hydrocarbon (polymeric) chain, which contains 16 atoms of carbon and has molar weight less than 650 g/mole. Oil with glitter effect has molar weight, more or equal 650 g/mol.

EFFECT: composition insures novel cosmetic product and has good properties of comfort, good stability and glitter effect.

26 cl, 2 ex

FIELD: medicine.

SUBSTANCE: invention concerns pharmacology and dentistry and covers the method and composition for prevention and/or reduction of dental deposit and/or gingivitis. There are offered bioactive glass compositions which prevent or reduce dental deposit and/or gingivitis development owing to application of traces of small particles of bioactive glass in amount approximately 0.25 to 10 wt % in nonaqueous compounds.

EFFECT: produced nonaqueous compositions are effective in preparations for tooth brushing; they are stable and meet ISO standards (International Organisation for Standardisation), moreover the nonaqueous compositions containing bioactive glass exhibit unexpectedly high antimicrobic activity in relation to oral pathogens.

18 cl, 3 ex, 3 tbl

FIELD: medicine.

SUBSTANCE: invention refers to pharmaceutical industry, and to production of a product with regenerative, stimulatory and anti-aging effect. There is offered bath containing pantohematogen and water. In addition it contains sea salt, glycerine, hydrogenated castor oil, an aromatiser and a preserving agent.

EFFECT: invention ensures stimulation of metabolic processes and blood circulation and does not cause allergic reaction.

2 cl, 1 ex

FIELD: medicine.

SUBSTANCE: invention refers to medicine, particularly to cosmetics. Water-in-oil antiperspirant or deodorant emulsion applied by means of a ball dispenser contains a continuous aqueous phase, preferentially contains an active ingredient of antiperspirant or deodorant, an emulsifier in the form of ethoxylated ether or a mixture with the average HLB 7 to 9, and a disperse oil phase containing vegetable oil, such as fatty acid triglyceride, and particles of colloid silicon dioxide and especially hydrophobic colloid silicon dioxide. Herewith in the method of for making the composition, hydrophobic colloid silicon dioxide is dispersed in the aqueous phase.

EFFECT: invention provides excellent quality, fast drying and absence of oiliness.

32 cl, 2 tbl, 4 dwg, 4 ex

FIELD: cosmetology.

SUBSTANCE: invention relates to cosmetology and is represented by a cleansing compound consisting from approximately 2.6% to approximately 3% (weight) of an aqueous emulsion of an acrylate copolymer, from approximately 7.7% to approximately 10.2% (weight) of an anionic surfactant and from approximately 1.4% to approximately 1.7% (weight) of an amphoteric surfactant, an effective quantity of balls of shea butter and seeds, the diametre of each ball varying within the range from 100 to 1200 micron; and additional ingredients required to bring the compound composition to 100%.

EFFECT: invention enables improvement of cleansing properties, is characterised by high translucency and improved stability.

15 cl, 3 ex, 1 dwg

FIELD: medicine.

SUBSTANCE: invention concerns cosmetic industry, particularly to an oral care composition. The oral care composition containing propolis extract, a nonionic antibacterial substance representing halogenated diphenyl ester, an active compound for oral care chosen from: a cationic antibacterial substance, an adhesion preventing substance, a substance decomposing biological films or an antiinflammatory substance, and a fluorine ion source.

EFFECT: composition effectively prevents development of oral diseases.

24 cl, 1 ex

FIELD: medicine.

SUBSTANCE: invention refers to cosmetology and concerns a surfactant composition containing at least one sorbitan ester and at least one sorbite ester where average of carbon atoms of sorbitan ester hydrofuge exceeds that of sorbite ester.

EFFECT: development of the composition to be applied for stabilisation of emulsions, especially personal hygiene or cosmetic products.

19 cl, 8 ex

FIELD: medicine.

SUBSTANCE: invention refers to cosmetology and concerns a surfactant composition containing at least one sorbitan ester and at least one sorbite ester where average of carbon atoms of sorbitan ester hydrofuge exceeds that of sorbite ester.

EFFECT: development of the composition to be applied for stabilisation of emulsions, especially personal hygiene or cosmetic products.

19 cl, 8 ex

FIELD: medicine.

SUBSTANCE: invention concerns medicine, namely dentistry, and can be used for microorganism control in oral cavity. That is ensured by introduction in the oral cavity of a composition that creates active particles under exposure to light, and then using of an electric tooth brush with a head comprising a light-emitting element. Said light-emitting element is located on a back surface of the tooth brush head, and its back surface contains one or more flanges. An output signal from the light-emitting element is directed to the part of oral soft tissues during a period of time sufficient to create active particles of said composition.

EFFECT: invention allows for effective oral care with simultaneous clearing and microorganism control.

11 cl, 7 dwg

FIELD: medicine.

SUBSTANCE: invention concerns an oligodynamic composite material representing a layer of polymer material with electret properties wherein there is one first discrete element coming on one working surface of the electret material and made of metal particles of various electronic work function and able to show oligodynamic action. The composite material can also contain the other discrete elements representing a drug dispenser or absorption aids.

EFFECT: composite material distinguishes itself with high efficiency ensured by synergy effect of the electret material and the metal showing oligodynamic action.

17 cl, 4 dwg, 1 tbl, 18 ex

FIELD: medicine.

SUBSTANCE: claimed invention relates to field of cosmetology, namely to cosmetic composition for care and make-up of lips, method of lip make-up of and application of copolymer in said composition. Claimed cosmetic composition contains one copolymer in form of block-copolymer, which contains, first block and second block, one non-volatile oil, one oil with glitter effect. First block is obtained from one acrylate monomer of formula CH2=CH-COOR2, where R2 - represents cycloalkyl group, which has 4-12 carbon atoms, and from one methacrylate monomer of formula CH2=C(CH2)-COOR'2, where R'2 represents cycloalkyl group, which has 4-12 carbon atoms. Second block is obtained from monomer of acrylic acid and from one other monomer with temperature of vitrifying less or equal 20°C. Non-volatile oil has hydrocarbon (polymeric) chain, which contains 16 atoms of carbon and has molar weight less than 650 g/mole. Oil with glitter effect has molar weight, more or equal 650 g/mol.

EFFECT: composition insures novel cosmetic product and has good properties of comfort, good stability and glitter effect.

26 cl, 2 ex

FIELD: medicine.

SUBSTANCE: invention concerns pharmacology and dentistry and covers the method and composition for prevention and/or reduction of dental deposit and/or gingivitis. There are offered bioactive glass compositions which prevent or reduce dental deposit and/or gingivitis development owing to application of traces of small particles of bioactive glass in amount approximately 0.25 to 10 wt % in nonaqueous compounds.

EFFECT: produced nonaqueous compositions are effective in preparations for tooth brushing; they are stable and meet ISO standards (International Organisation for Standardisation), moreover the nonaqueous compositions containing bioactive glass exhibit unexpectedly high antimicrobic activity in relation to oral pathogens.

18 cl, 3 ex, 3 tbl

FIELD: medicine.

SUBSTANCE: invention refers to pharmaceutical industry, and to production of a product with regenerative, stimulatory and anti-aging effect. There is offered bath containing pantohematogen and water. In addition it contains sea salt, glycerine, hydrogenated castor oil, an aromatiser and a preserving agent.

EFFECT: invention ensures stimulation of metabolic processes and blood circulation and does not cause allergic reaction.

2 cl, 1 ex

FIELD: medicine.

SUBSTANCE: invention refers to medicine, particularly to cosmetics. Water-in-oil antiperspirant or deodorant emulsion applied by means of a ball dispenser contains a continuous aqueous phase, preferentially contains an active ingredient of antiperspirant or deodorant, an emulsifier in the form of ethoxylated ether or a mixture with the average HLB 7 to 9, and a disperse oil phase containing vegetable oil, such as fatty acid triglyceride, and particles of colloid silicon dioxide and especially hydrophobic colloid silicon dioxide. Herewith in the method of for making the composition, hydrophobic colloid silicon dioxide is dispersed in the aqueous phase.

EFFECT: invention provides excellent quality, fast drying and absence of oiliness.

32 cl, 2 tbl, 4 dwg, 4 ex

FIELD: cosmetology.

SUBSTANCE: invention relates to cosmetology and is represented by a cleansing compound consisting from approximately 2.6% to approximately 3% (weight) of an aqueous emulsion of an acrylate copolymer, from approximately 7.7% to approximately 10.2% (weight) of an anionic surfactant and from approximately 1.4% to approximately 1.7% (weight) of an amphoteric surfactant, an effective quantity of balls of shea butter and seeds, the diametre of each ball varying within the range from 100 to 1200 micron; and additional ingredients required to bring the compound composition to 100%.

EFFECT: invention enables improvement of cleansing properties, is characterised by high translucency and improved stability.

15 cl, 3 ex, 1 dwg

FIELD: medicine.

SUBSTANCE: invention concerns cosmetic industry, particularly to an oral care composition. The oral care composition containing propolis extract, a nonionic antibacterial substance representing halogenated diphenyl ester, an active compound for oral care chosen from: a cationic antibacterial substance, an adhesion preventing substance, a substance decomposing biological films or an antiinflammatory substance, and a fluorine ion source.

EFFECT: composition effectively prevents development of oral diseases.

24 cl, 1 ex

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