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Slip for obtainment of glaze coating

IPC classes for russian patent Slip for obtainment of glaze coating (RU 2346900):
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FIELD: chemistry.

SUBSTANCE: invention can be applied in manufacturing of porcelain and faience goods. Glaze slip includes components at the following ratio, wt %: frit 100.0; clay 0.5-1.5; zircon 4.0-5.0; water 40.0-50.0; silica gel 4.0-5.0; barium carbonate 0.7-1.7; sodium chloride 0.1-0.2; sodium tripolyphosphate 0.1-0.2; calcium borate 3.0-4.0. Frit has the following composition, wt %: SiO2 47.0-50.0; ZrO2 4.0-8.0; B2O3 18.0-22.0; MgO 2.0-4.0; K2O 2.8-3.8; F' 0.1-0.2; TiO2 8.0-10.0; BaO 2.0-4.0; ZnO 4.0-8.0.

EFFECT: enhanced thermal stability and shine of glaze coating.

2 cl, 1 tbl

 

The invention relates to the field of technology of silicates, namely the composition of the slurry to obtain a glaze coating used in the manufacture of porcelain, earthenware.

Known slip to obtain a glaze coating comprising a Frit, clay, water /1/.

Known slip to obtain a glaze coating containing, in wt.%: the Frit 100,0; clay 8,0-10,0; zircon 2,0-4,0; water 40,0-45,0; Krempel 5,0-10,0 /2/.

The purpose of the invention is the improvement of heat resistance and gloss glaze coating.

The objective is achieved by the fact that the composition of the slurry, containing the Frit, clay, Zirconia, water, Krempel, impose additional carbon dioxide barium, sodium chloride, sodium tripolyphosphate, calcium borate in the following ratio, wt.%: the Frit 100,0; clay 0.5 to 1.5; zircon 4,0-5,0; water 40,0-50,0; Krempel 4,0-5,0; barium carbonate 0,7-1,7; sodium chloride 0.1 to 0.2; sodium tripolyphosphate 0,1-0,2; borate of calcium 3,0-4,0.

The table shows the composition of the slip.

Table
Composition Components, wt.%
The Frit clay zircon water Krempel /waste production of cryolite/ carbon dioxide barium sodium chloride sodium tripolyphosphate oral cal tion
1 100,0 0,5 5,0 40,0 4,0 0,7 0,1 0,2 4,0
2 100,0 1,0 4,5 45,0 4,5 1,3 0,2 0,1 8,5
3 100,0 1,5 4,0 50,0 5,0 1,7 0,1 0,2 3,0

The Frit glaze of one of the trains /1 composition: SiO247,0; ZrO28,0; B2O318,0; MgO 4,0; K2O 2,8; F' 0,2; TiO210,0; BaO 2,0; ZnO 8,0; 2nd composition: SiO248,0; ZrO28,0; B2O320,0; MgO 3,5; K2O 2,9; F' 0,1; TiO28,0; BaO 3,0; ZnO 6,0; 3rd composition: SiO250,0; ZrO24,0; B2O322, 0mm; MgO 2,0; K2O 3,8; F' 0,2; TiO210,0; BaO 4,0; ZnO 4,0/ cook at 1300°followed by granulation in water. The Frit with the addition of clay, zircon, water, silica gel, barium carbonate, sodium chloride, sodium tripolyphosphate, calcium borate grind until the residue is not more than 0.2% on mesh No. 005. The obtained slurry is applied onto the surface of the products and calcined at 1000°in an oxidizing atmosphere. Temperature resistant glaze coating shall be not less than 12 thermal cycles, gloss 85%.

Sources of information

1. Berdichevsky, I.M. and al Reference mA the tera-farvorite. - M.: Legprombytizdat, 1992. - P.60.

2. USSR author's certificate No. 1000432, SS 9/00, 1983.

1. The slip to obtain a glaze coating containing the Frit, clay, zircon, water, Krempel, characterized in that it further comprises barium carbonate, sodium chloride, sodium tripolyphosphate, calcium borate in the following ratio, wt.%: the Frit 100,0; clay 0.5 to 1.5; zircon 4,0-5,0; water 40,0-50,0; Krempel 4,0-5,0; barium carbonate 0,7-1,7; sodium chloride 0.1 to 0.2; sodium tripolyphosphate 0,1-0,2; borate of calcium 3,0-4,0.

2. The slip to obtain a glaze coating according to claim 1, wherein the Frit has a composition, wt.%: SiO247,0-50,0; ZrO24,0-8,0;2O318,0-22,0; MgO 2,0-4,0; K2O 2,8-3,8; F' 0,1-0,2; TiO28,0-10,0; BaO 2,0-4,0; ZnO 4,0-8,0.

 

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