Composition containing nano-composite as gas barrier and articles made of it |
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IPC classes for russian patent Composition containing nano-composite as gas barrier and articles made of it (RU 2340639):
      
Epoxy binding agent for fiberglass / 2339662
Invention concerns epoxy binding agent for obtaining fiberglass on the basis of reinforcing filler for glass fiber cloth, glass fiber blanket, glass fiber roving etc, applied mainly in construction reinforcement applied under effect of aggressive media, and in obtaining high-strength fiberglass for various engineering, shipbuilding industries etc. Binding agent includes the following components, wt %: 56.11-56.42 of ED-22 epoxy resin, 42.10-42.29 of isomethyltetrahydrophthalic anhydride, 0.79 of UP-606/2 2,4,6-tris(dimethyl)phenol, 0.50-1.00 of polytriphenyl ether of boric acid.
 Binding substance for reinforced plastics / 2338762
Invention pertains to a binding substance for reinforced plastics, which can be used as construction coating or protecting concrete, reinforced concrete, metallic and other surfaces from aggressive media and abrasive wearing, as well as making general use moulding products, used in chemically aggressive media. The binding substance consists of the following components, in wt %: 4.5-70 epoxy-diane resin, 1-30 chlorinated polyvinylchloride solution in an organic solvent, 8-25 reactive diluent, and amine type hardener constitutes the remaining wt %. The reactive diluent used is epoxy rubber adduct, obtained through co-condensation of functional groups of epoxide resin and liquid nitrile rubber, and if necessary glycidyl ether of phosphorous acids with general formula:
Polymer composition for radionuclide fixation / 2337118
Invention relates to polymer composition for radionuclide fixation, including 133Ba, 134Eu, and 36Cl, which can be applied in nuclear technology to prevent radionuclide release to environment, causing its contamination. The composition contains ingredients proportion as follows, in parts by weight: diane epoxide resin 100, furan thinner 100-150, nitrogen-containing hardener 10-65, alumimium phosphate 20-70, orthophosphoric acid 4-12, filler 0-400.
Epoxy binding agent for prepregs, prepreg based on it, and article made thereof / 2335515
Binding agent includes components at the following ratio, weight parts: epoxy diane resin or its mix with diglycidyl diethyleneglycol ether 18-50, polyfunctional epoxy resin 18-60, bromine-containing epoxy diane resin 18-34, bis-N,N-(dimethylcarbamido)diphenylmetane as solidifier 3-6, alcohol and acetone mix as organic solvent 70-105. Bromine-containing epoxy diane resin is an oligomer product of tetrabromdiphenylolpropane and epychlorhydrine condensation in 600-1500 mol mass amount in the form of diglycidyl tetrabromdiphenylolpropane ether mix with its dimmer and trimer at the component ratio of (3-4):1:(0.2-0.8) or diglycidyl tetrabromdiphenylolpropane ether mix with its dimmer, trimer and chlorhydrine ether at the component ratio of (3-4):1:(0.2-0.8):(0.5-0.6). Prepreg includes components at the following ratio, wt %: epoxy binding agent described above 30.0-42.0, and fiber filler 58.0-70.0. An article is produced by prepreg modelling.
 Composition of epoxybismaleimide binding agent for prepregs (versions), method of obtaining epoxybismaleimide binding agent (versions), prepreg and article / 2335514
First version of invention claims composition of the following component ratio, wt %: N,N,N',N'-tetraglycidyl-4,4'-diamino-3,3'-dichlordiphenylmethane 24.8÷42.1 and triglycidyl-aminophenol as polyfunctional epoxy resins 11.5÷25.8, polycrystalline powder of N,N'-hexamethylenebismaleimide as bismaleimide 25.8÷41.3, polycrystalline powder of 4,4'-diaminodiphenylsulfone as solidifier 17.4÷22.6. Second version of invention claims composition of the following component ratio, wt %: N,N,N',N'-tetraglycidyl-4,4'-diamino-3,3'-dichlordiphenylmethane 21.6÷49.5 and triglycidyl bisphenol-A ether as polyfunctional epoxy resins 16.1÷32.4, polycrystalline powder of N,N'-hexamethylenebismaleimide as bismaleimide 3.5÷27.0, polycrystalline powder of 4,4'-diaminodiphenylsulfone as solidifier 19.0÷25.8. Method of obtaining the claimed compositions involves addition of polycrystalline 4,4'-diaminodiphenylsulfone powder to homogenous polyfunctional epoxy resin melt during stirring at 120÷130°C in minimum time sufficient for its complete dissolution. Then the temperature of obtained homogenous melt is lowered to 90÷100°C. By further stirring polycrystalline powder of N,N'-hexamethylenebismaleimide is added to the melt in minimum time sufficient for its complete dissolution. Prepreg includes components at the following ratio, wt %: the claimed epoxybismaleimide binding agent 20-48 and fiber filler 52-80. An article is produced by the claimed prepreg modelling.
Epoxide moulding composition for armor plating set-in grain of composite solid propellant / 2330832
Invention relates to missilery and applies to the production of the epoxide molding composition from the composite solid propellant by filling that is valid in a broad range of temperatures; the invention is aimed at armor planting of set-in grains, diameter of which varies from 300 to 700 mm. The composition includes the following proportion of the components, mass %: 27-36 of epoxy-diane resin ED-20, 3-5 of plasticiser-modifier of low-viscous epoxy diethyleneglycolic aliphatic resin DEG-1, 30-40 of amine hardening agent of low viscous polyamineimidozaline resin PO-300, 30-35 of alkylphenol interaction product gr. C9-C12 with chloromethyl oxirane.
Method of obtaining antifriction moulding materials / 2330051
Invention concerns production of antifriction epoxy moulding materials used in manufacturing of inserts for bearing bushings with binary friction surface, i.e. greases, as well as construction material and electric insulator in electrical engineering and other technical fields. The method involves forge rolling of solid pre-polymer with fluorine rubber capable of curing by an amine, in the ratio of 90:10 to 60:40 at the temperature of 60-90°C for 5-30 minutes. Here pre-polymer is a product of interaction of epoxidised novolac (A) with epoxy diane resin of molecular mass 360 to 540 (B) and with 3,3'-dichlor-4,4'-diaminodiphenylmethane (C) in the A:B:C ratio of 85:10:5 to 5:80:15, obtained by heating at 60-130°C for 30-120 minutes. Further to 100 mass parts of forge-rolled mix 15.0-50.0 mass parts of arylamine as curative, 5.0-50.0 mass parts of polytetrafluoretylene and 10.0-100.0 mass parts of chopped fiber as filler, and 2.0-6.0 mass parts of antiadhesive are added. The composition is additionally forge-rolled at 40-80°C for 5-15 minutes, then the resulting mass is cooled and crushed.
Sealing compound / 2329280
Invention pertains to a composition based on an epoxide resin, designed for sealing semiconductor devices. The compound consists of the following components in the given mass ratios: 100 epoxide resin "ЭД-22" with 22% content of epoxide groups for formation of a more compact and tough polymer network, 50 oligoester acrylates "МГФ-9", 20 metaphenylene diamine, 35 filler, 0.5 nigrosine as black dye and a catalyst of the solidification reaction of the epoxy groups. The filler is a mixture of 6.0 mass ratio of boron nitride, 4.0 mass ratio of talc and 0.8 mass ratio of aerosil.
 Epoxy binder for composite materials / 2327718
Epoxy binder consists of the following components in the given mass ratios: 100 epoxy diane resin, 60-80 iso-methyltetrahydrophtalic anhydride, 1.0-2.0 hardener. The hardener used is an alkanolamine with general formula
 Method of obtaining polymer composite materials / 2327717
Method involves putting filler into a polymer matrix and subsequent hardening. The filler is a ferromagnetic material in powdered form. Hardening is carried out in a cyclic magnetic field.
 Methods of production of the copolymers from nonsaturated monocarboxylic acid and the derivative of the monounsaturated carboxylic acid and the material produced by the given methods / 2292363
The invention is pertaining to the bulk polymetric compounds gained by the casting method. The invention presents the versions of the method of production of copolymers from the nonsaturated monocarboxylic acid and the derivative of monounsaturated carboxylic acid by the casting method, at which the polymerization is conducted at the phase of the syrup produced by addition of the polymetric compounds dissolvable in the mixture of the initial monomers. At that as the nonsaturated monocarboxylic acid they use the methacrylic acid, and as the derivative of the monounsaturated carboxylic acid use the metacrylonitrile. The produced material can contain up to 400 mass shares of the parts of the additives in terms of the total mass capable to polymerization groups, which are insoluble in the reaction mixture necessary for production of the material.
Composition for making polishing round disk / 2263125
Invention relates to making cotton round disks. The composition for making polishing round disk involves a binding agent aqueous solution wherein a mixture of aqueous emulsion of polymer prepared by emulsion polymerization of butyl acrylate, ethyl acrylate, methyl methacrylate and acrylic acid amide with the content of basic substance from 15 to 50 mas. p. p. and water glass is used in the following ratio of components, mas. p. p.: copolymer of (meth)acrylic esters and amide of acrylic acid, 15-50; liquid sodium glass, 3-12, and water, 50-85. Invention provides enhancing the stability of polishing round disks and to reduce the cost in their making. Invention can be used in polishing table dishware and their components made of stainless steel, devices used in stomatology, jewelry articles, watches and so on.
 Thermoplastic polymer composition / 2089569
The invention relates to the qualitative and quantitative composition of the thermoplastic polymer compositions which are intended for processing in filament or staple fiber and the subsequent use of the obtained fibers as adhesives (binders) in the manufacture of composite materials, for example:
glue tissue or preferably, adhesive Jersey used in the manufacture of multilayer, mainly flexible sheet materials of the type redundant heat, sound or heat and sound insulation, or reinforcing materials, fabrics, knitted fabrics, leather or faux leather for clothing or shoes, upholstery and finishing and/or heat, sound and thermal insulation salons passenger cars or passenger aircraft or for use in the interiors of residential and public buildings; non-woven bulk isotropic mainly insulating lining materials of the type "padding" for clothes or heat and sound insulation materials for construction needs; filled with dispersed waste wood (sawdust, shavings, etc.,) or other predominantly plant materials isotropic composite material is
Stretchable packing film / 2340635
Film is made from polymer mixture, which contains (wt %): 50-90% composition of the ethylene polymer and 10-50% polymer component on ethylene basis, having a density in the range from 0.9 to 0.930 g/ml and molten flow-rate till 4 g/10 min. Composition of the ethylene polymer contains a recurring unit, obtained from an ester, selected from (1) ethylene-unsaturated organic monomer in the form of esters unsaturated C3-C20 monobasic carboxylic acids and C1-C24 univalent aliphatic or alicyclic alcohols, (2) vinyl esters saturated C2-C18 carboxylic acids, where the content of esters is in the range from 2.5-8 wt %. Composition of the ethylene polymer has a density in the range from 0.920 to 0.94 g/ml. Stretchable packing film has a relation between the value of tear resistance longitudinally and the vale of tear resistance transversely, which exceeds 0.3 and the value of ultimate tensile strength lengthwise 30% in the range from 6.5 to 15 N.
 Amorphous perfluorated polymers / 2339656
Invention claims application of amorphous perfluorated polymers in obtaining transparent films with transparency over 50% at 157 nm width, where the perfluorated polymers do not contain ion end groups and consist of cyclic units obtained from perfluorodioxols of formula:
 Method of film receiving from aromatic polyamide / 2338759
Invention concerns method of high-strength film material receiving, used in radio and electrical engineering, and also used as polymeric membrane for chemical industry. Method of film receiving is in further: by method of electrochemical deposition it is implemented formation from solution aromatic heterocyclic polyamide in organic amide solvent, with soluted in it haloid salt of alkaline-earth metals or lithium chloride. In the capacity of aromatic heterocyclic polyamide it is used polyamide, containing in chain benzimidazole or sewage-limed or thiazol cycles. In the capacity of solvent there are used dimethyl acetamide or N-methylpyrrolidone. Electrochemical deposition is implemented on rotating anode by continuous shaping method.
 Thermoplastic composition suitable for making items, method of making it and items made from it / 2338758
Invention pertains to thermoplastic compositions, to the method of making it and to items, made from the composition. The composition consists of the following components: polyester, substituted cyclic anhydride or a mixture of substituted cyclic anhydrides forming a resin, and an additive. The substituted cyclic anhydride, used in the invention as a reactive carrier, has melting point closer to ambient temperature or lower than ambient temperature. The method of obtaining the composition involves mixing substituted cyclic anhydride with an additive and further reaction of the resulting mixture with polyester. From the compositions items like sheets, films, fibres, work pieces and containers can be made.
 Thin-film material and method of thin-film material production / 2336941
Invention may be used for development of new nano-structured thin-film materials applied in systems of controlled transport and delivery of micron, submicron and molecular objects in liquid phase, in technologies of bioengineering, in nano-metrical assembly technologies, in analytic, sensor, biomedical, cosmetic, catalytic, membrane technologies. Thin-film material is made in the form of free thin film in liquid phase that includes colloidal particles, which are chemically connected between each other in the film plane, at that components of material separately are able to form solutions in liquid phase. Material is formed by the method on the basis of self-assembly and self-organisation effects of low-dimensional structures directly in the volume of liquid phase. Initial solutions of material individual components are prepared, and liquid phase that contains prepared thin-film material is formed. Processes of binding and creation of chemical links are carried out between colloidal particles by means of single or multiple addition of solution that contains one or several reagents or components into solution of another component or other components of prepared thin-film material. Formation of material thin-film structure is performed in the volume of liquid phase for the time sufficient for processes of material components binding and creation of free thin-film structure. Thin-film material is applied as a layer on the surface of extended articles - threads, wire, rods, etc.
 Barrier layered film / 2334767
Invention refers to production technique of barrier layered polymer films. Single- or laminate film consists of, at least, one gaseous oxygen proof barrier layer. Layer is basically laminated with mixed ethylene copolymer and vinyl alcohol and, at least, one multipolyamide. Film is applied for packaging of perishable, outgassing products, such as foodstuffs. Packing made of this film for perishable, outgassing products represents first of all a package for cheese making its aging. The film possesses is minimum possible permeability almost independent of moisture content in packed product and/or in environment, thus ratio of carbon dioxide permeability and oxygen permeability is not less 3:1.
 Polymer film containing random copolymer of propylene / 2334766
Group of inventions refers to polymer film containing random copolymer of propylene with ethylene or α-olefin and used mainly for the packages. In the first version this invention concerns polymer film made of the composition containing random copolymer of polyethylene with comonomer which is ethylene or α-olefin, having at least four carbon atoms at total comonomer content within 4.5 to 12 mole%, and the film has relative reduction of random friction (intra-intra) within period from one to four days by 35% or more, however it is preferable by 40% or more. The second version concerns polymer film made of the composition containing random copolymer of propylene with comonomer which is ethylene or α-olefin, having at least four carbon atoms at total comonomer content within 4.5 to 12 mass %, and comonomer distribution in random copolymer, defined by TREF method, is multimodal, preferably bimodal, and if necessary, the composition contains common additives. Some versions of polymer film are presented in addition. Good optical, sealing and sliding properties, as well as high softness of film and low content of soluble xylenes are provided.
Flat or sleeve-type cover or film suitable for smoking and packaging food and associated method of its production / 2333652
Invention relates to flat or sleeve-type cover or film suitable for smoking and intended for packaging of food products such as sausage cover, shrink film wrapper and etc., on polymer basis. This cover or film was first produced by air exhausting from homogenous plastic melt consisting of plastics mixture. This melt includes, at least, polyamide, PVAL (polyvinyl alcohol) and PEBAX (polyetherblockamide). Food cover or film is characterized by permeability factor by water steam being at least 1 kg/m2 in 24 hours. Oxygen permeability at 30 μm thickness of film is less 2.1 sm3/m2 in 24 hours. Besides, method of such items production is proposed in this invention for the first time.
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FIELD: chemistry. SUBSTANCE: composition is made from mixing 30-95 mass parts of polyolefin resin, 0.5-60 mass parts of molten resin mixture with protective properties and nanocomposite with protective properties and 1-30 mass parts of the substance which ensures the compatibility of components. Resins with protective properties are the copolymer of ethylene with vinyl alcohol polyamide, ionomer, polyvinyl alcohol. Nanocomposite is chosen from a group consisting of copolymer of ethylene with vinyl alcohol/nanocomposite from intercalated clay, polyamide/nanocomposite from intercalated clay, ionomer/nanocomposite from intercalated clay and polyvinyl alcohol/nanocomposite from intercalated clay. EFFECT: good protecting properties and pliability. 18 cl, 2 dwg, 2 tbl, 37 ex
The technical field The present invention relates to compositions containing nanocomposite as a gas barrier, and products made from it, and, in particular, to compositions containing nanocomposite with excellent protective properties and plasticity, which is obtained by dry mixing the polyolefin resin with a melt mixture of the resin having barrier properties, and nanocomposites nanocomposite having barrier properties, as well as substances, ensuring the compatibility of the components, and the manufacture of its products. The level of technology General purpose resins such as polyethylene and polypropylene, are used in many fields due to their excellent ductility, mechanical and waterproofing properties. However, use of these resins in packaging material or containers for food products and agrochemicals limited, because these products need packaging materials with very high chemical resistance and good protivogololednye protective properties. The copolymer of ethylene-vinyl alcohol (EMU) and the polyamide resin are transparent and have a high protective properties. However, due to the higher cost of these resins in comparison with the resin General purpose their content in products is limited. Thus, to reduce stand the STI was offered a mixture of resin with protective properties, such as EMU and polyamide resins, and inexpensive polyolefin. However, a satisfactory protective properties were not achieved. To improve the protective properties was used fully stratified, partially stratified, intercalated or partially intercalated nanocomposite obtained by dispersion of nanorazmernyh particles of intercalated clay in the polymer matrix. Disclosure of inventions In the manufacture of injection molded articles of the above nanocomposites nanocomposite nanocomposite should retain their morphology, providing protective properties even after molding, and its plasticity must be high for a simple manufacture of sheets or films, as well as containers. The aim of the present invention is a composition comprising a nanocomposite with excellent mechanical strength, excellent protivogololednye protective properties, resistance to organic solvents, waterproofing properties, excellent ductility. The aim of the present invention is also the manufacturer of the products obtained from the compositions containing the nanocomposite having barrier properties. In accordance with one aspect of the present invention dry mix composition is prepared, containing 30-95 wt. parts p is linoleinovoy resin; 0.5-60 wt. parts of the melt mixture comprising at least one resin protective properties selected from the group consisting of a copolymer of ethylene-vinyl alcohol (EMU), polyamide, ionomer and polyvinyl alcohol (PVA) and at least one nanocomposite with protective properties selected from the group consisting of a copolymer of EMU with intercalated clay, polyamide with intercalated clay, ionomer with intercalated clay and polyvinyl alcohol with intercalated clay and 1-30 wt. parts of substances, ensuring the compatibility of the components. In one of the embodiments of the present invention, the resin protective properties and nanocomposite with protective properties can be mixed in the melt in a mass ratio of from 25:75 to 75:25. In another embodiment of the present invention, the resin protective properties and nanocomposite with protective properties can be mixed in the melt with the application of the jointly rotating twin-screw extruder or single screw extruder at a melting temperature or at higher temperatures. In accordance with another aspect of the present invention, the invention provides for the fabrication of the nanocomposite composition with. In one of the embodiments of the present invention, the product can be manufactured PU is eat pneumaturia, extrusion molding, molding under pressure or injection molding. In another embodiment of the present invention the product may be a container, a sheet, tube or film having protective properties. The present invention will be described hereinafter in more detail. Korean patent application No. 2002-76575, previously filed by the authors of this application, discloses a composition with a nanocomposite comprising 1-97 wt. parts of the polyolefin resin; 1-95 wt. parts nanocomposites nanocomposite with protective properties selected from the group consisting of a copolymer of ethylene-vinyl alcohol (EMU) with intercalated clay, polyamide with intercalated clay, ionomer with intercalated clay and polyvinyl alcohol (PVA) with intercalated clay; and 1-95 wt. parts of substances, ensuring the compatibility of the components. It complements the present invention. When carrying out the present invention the composition of the nanocomposite having barrier properties, get dry mixing of the melt mixture of the resin with protective properties and nanocomposites nanocomposite having barrier properties, with a polyolefin resin and substance ensuring the compatibility of the components. That is, the composition of the nanocomposite is a composition prepared by dry mixing, comprising 30-95 wt. parts of polio einevoll resin; 0.5-60 wt. parts of the melt mixture comprising at least one resin protective properties selected from the group consisting of a copolymer of ethylene-vinyl alcohol (EMU), polyamide, ionomer and polyvinyl alcohol (PVA) and at least one nanocomposite with protective properties selected from the group consisting of EMU copolymer intercalated with clay, polyamide with intercalated clay, ion meter with intercalated clay and polyvinyl alcohol with intercalated clay; and 1-30 wt. parts of substances, ensuring the compatibility of the components. The polyolefin resin may be at least one selected from the group consisting of high density polyethylene (HDPE), low density polyethylene (LDPE), linear low density polyethylene (LLDPE), ethylene-propylene copolymer and polypropylene. The polypropylene may be at least one compound selected from the group consisting of homopolymer polypropylene, copolymer polypropylene, polypropylene and composite resin with improved physical properties by adding talc, flame retardant, etc. to homopolymer or copolymer of polypropylene. The preferred content of the polyolefin resin 30-95 wt. parts and most preferably 70-90 wt. parts. If the content of the polyolefin resin is lower than 30 wt. parts, formula the s difficult. If the content of the polyolefin resin is more than 90 wt. portions, the protective properties of the low. The molten mixture of resin/nanocomposite can be obtained by first forming a stratified or partially layered nanocomposites nanocomposite with protective properties of the resin protective properties and intercalated clay and mixing in the melt nanocomposites nanocomposite resin with protective properties. More specifically, the molten mixture of resin/nanocomposite can be obtained by mixing in the melt, at least one resin protective properties selected from the group consisting of EMU copolymer, polyamide, ionomer and polyvinyl alcohol (PVA) and at least one nanocomposites nanocomposite with protective properties selected from the group consisting of EMU copolymer/nanocomposite of intercalated clay, polyamide/nanocomposite of intercalated clays, ion meter/nanocomposite of intercalated clay and polyvinyl alcohol/nanocomposite of the intercalated clay. The resin protective properties add to the intercalated clay for the formation of nanoscale stratified or partially layered nanocomposites nanocomposite. Due to this morphology of the nanocomposites nanocomposite path of passage of gas and liquid in the resin is lengthened and thus water-resistant and protective against the fluid properties of the resin are improved, and the resistance of the floor is of the olefin increases due to the intercalated clay, which prevents the falling of the workpiece when pneumatomachi. The mass ratio of the resin protective properties to the intercalated clay in the nanocomposite is from 58.0:42.0 to 99.9:0.1, and preferably from 85.0:15.0 to 99.0:1.0. If the mass ratio of the resin protective properties to the intercalated clay less than 58.0:42.0, intercalated clay aglomerated and homogenization difficult. If the mass ratio of the resin protective properties to the intercalated clay above 99.0:0.1, improving the protective properties of the minor. Through the application of the melt blend and nanocomposites nanocomposite resin with protective properties, temperature molding can be extended. It is possible to choose the components of the mixture, and the mixing ratio can be adjusted in accordance with temperature conditions of the process required for product formation. To obtain molten mixture of resin with protective properties/nanocomposite homogenization of the melt is preferably carried out at a temperature 175-270°C. Intercalated clay is preferably clay, intercalated in the organic matrix. The preferred content of organic material in the intercalated clay 1-45 wt.%. When the content of organic material is less than 1 wt.%, compatible intercalated clay and resin to protect time properties low. When the content of organic material more than 45 wt.%, intercalation resin with protective properties difficult. Intercalated clay contains at least one material selected from montmorillonite, bentonite, kaolinite, mica, hectorite, forgetit, saponite, beidellite, nontronite, stevensite, vermiculite, callosity, volkonskoit, saconit, magarita, geniality, and organic material preferably contains a functional group selected from primary to Quaternary ammonium, phosphonium, maleate, succinate, acrylate, benzyl hydrogen, oxazoline and dimethyldodecylamine. The resin protective properties and nanocomposite with protective properties preferably are mixed in the melt in a mass ratio of from 25:75 to 75:25. If the amount of resin with protective properties too high protective properties are not improved. If the amount of resin with protective properties too low, the impact strength of the final product is lowered. If the copolymer of ethylene-vinyl alcohol introduced in the nanocomposite, the ethylene content in the copolymer of ethylene-vinyl alcohol is preferably from 10 to 50 mol.%. If the ethylene content is less than 10 mol.%, the melt molding is difficult because of low machinability. If the ethylene content exceeds 50 mol.%, the protective properties attributed the Yu oxygen and fluids insufficient. If the polyamide is included in the nanocomposite, the polyamide may be nylon 4.6, nylon 6, nylon 6.6, nylon 6.10, nylon 7, nylon 8, nylon 9, nylon 11, nylon 12, nylon 46, MXD6, amorphous polyamide, copolymerizable polyamide containing at least two of them or a mixture of at least two of them. Amorphous polyamide refers to the polyamide having insufficient crystallinity, i.e. no endothermic melting peak of the crystalline phase in the measurement by the method of differential scanning calorimetry (DSC) (ASTM D-3417, 10°C/min). In General, the polyamide can be prepared using a diamine and a dicarboxylic acid. Examples of the diamine include hexamethylenediamine were 2-methylpentylamine, 2,2,4-trimethylhexamethylenediamine, 2,4,4-trimethylhexamethylenediamine, bis(4-aminocyclohexane)methane, 2,2-bis(4-aminocyclohexane)isopropylidene, 1,4-diaminocyclohexane, 1,3-diaminocyclohexane, meta Cialdini 1,5-diaminopentane, 1,4-diaminobutane, 1,3-diaminopropane, 2-ethyldiamine, 1,4-diaminomethylene, meta Cialdini, alkyl substituted or unsubstituted meta-phenylenediamine and para-phenylenediamine, etc. Examples of dicarboxylic acids include alkyl substituted or unsubstituted isophthalic acid, terephthalic acid, adipic acid, sabotinova acid, balancecarbon acid, etc. Poly the Ministry of foreign Affairs, obtained by using aliphatic diamines and aliphatic dicarboxylic acids, is usually a semicrystalline poliamida (with respect to the crystalline nylon) and is not an amorphous polyamide. The polyamide obtained by the use of aromatic diamine and aromatic dicarboxylic acid, with hardly treated in the usual way melting. Thus, the amorphous polyamide is preferably get when one of the used substances - diamine or dicarboxylic acid is an aromatic compound, and the other aliphatic. Aliphatic group, an amorphous polyamide preferably C1-C15aliphatic or C4-C8alicyclic alkali. Aromatic groups of the amorphous polyamide is preferably C1-C6substituted mono - or bicyclic aromatic group. However, all the above-mentioned amorphous polyamides are preferred in the present invention. For example, meta-Cialdini dipyramid easily crystallized when heated during the process of thermoforming or when ordering, therefore, is undesirable. Examples of preferred amorphous polyamides include hexamethylenediamine were isophthalamide, isophthalamide/terephthalamide terpolymer related isophthalic acid/terephthalic to the slot from 99/1 to 60/40, a mixture of 2,2,4 - and 2,4,4-trimethylhexamethylenediamine of terephthalamide, copolymer of hexamethylenediamine were or 2-methylpentylamine and isophthalic acid, terephthalic acid or mixtures thereof. While the basis of polyamide is hexamethylenediamine were isophthalamide/terephthalamide, in which a high content of terephthalic acid, so that he was smashin with another diamine such as 2-meterdiameter, to obtain an amorphous polyamide, which can be recycled. The above amorphous polyamide containing only the above-mentioned monomer may contain a small amount of lactam, such as caprolactam or laurolactam as co monomer. It is important that the polyamide was amorphous. Consequently, it can be applied to any comonomer, which is not crystallized polyamide. About 10 wt.% or less liquid or solid plasticizer, such as glycerol, sorbitol, or toluensulfonate (Santicizer 8 monsato), can also be included in the composition of the amorphous polyamide. For most applications the glass transition temperature Tg(measured in the dry state, i.e. with a water content of about 0.12 wt.% or less) of the amorphous polyamide is about 70-170°C, preferably about 80-160°C. Amorphous polyamide, which has not been mixed with other components, has Tgapproximately 125°in the dry state. N the life boundary of T gnot very clear, but approximately equal to 70°C. Upper bound Tgalso fuzzy. However, when using polyamide with Tgapproximately 170°With or higher, thermal molding is difficult. Therefore, the polyamide with acid and amine with aromatic groups, may not be used for thermoforming due to a too high Tgand, therefore, unsuitable for the purposes of the present invention. The polyamide may also be semi-crystalline polyamide. Semi-crystalline polyamide in General get by using a lactam, such as nylon 6 or nylon 11, or amino acids, or obtained by condensation of a diamine such as hexamethylenediamine were, with a dibasic acid such as succinic acid, adipic acid or sabotinova acid. The polyamide may be a copolymer or terpolymer, such as a copolymer of hexamethylenediamine were/adipic acid and caprolactam (nylon 6,66). Can be used a mixture of two or more crystalline polyamides. Semi-crystalline and amorphous polyamides get well-known condensation polymerization. If ion meter is part of the nanocomposites nanocomposite, ion meter is preferably a copolymer of acrylic acid and ethylene with a melt index from 0.1 to 10 g/10 min (190°, 2, 160 g). Content of the melt mixture, preferred the nutrient is 0.5-60 wt.% and more preferably 8 to 30 wt.%. If the content of the melt mixture is less than 0.5 wt.% improving the protective properties of the minor. If the content of the melt mixture above 60 wt.%, the processing is complicated. A substance that improves the compatibility of the polyolefin resin with the resin protective properties/nanocomposite, used for the formation of a stable composition. Substance, compatibility may be a hydrocarbon polymer with polar groups. When using hydrocarbon polymer with polar groups of part of the hydrocarbon polymer increases the affinity substance, to ensure compatibility, to the polyolefin resin and the resin protective properties/nanocomposite, thus forming a stable composition. Substance, compatibility, may include a compound selected from epoxy-modified copolymer of polystyrene, copolymer of ethylene-ethylene anhydride-acrylic acid copolymer, ethylene-ethyl acrylate, copolymer of ethylene-alkylacrylate-acrylic acid, high density polyethylene, modified (grafted) anhydride of maleic acid, linear low density polyethylene, modified (grafted) anhydride maleic acid copolymer alkylation-methacrylate-methacrylic acid copolymer, ethylene-butyl acrylate, copolymer of ethylene-vinyl acetate copolymer is ethylene-vinyl acetate modified, the anhydride of maleic acid and their modifications. The substance that provides compatibility is mainly 1-30 wt.% and more preferably 2-20 wt.%. If the substance, compatibility, less than 1 wt.% the mechanical properties of the articles obtained by molding, worse. If the substance, compatibility, more than 30 wt.%, molding is difficult. When the epoxy-modified copolymer of polystyrene is used as the substance compatible, preferably, the copolymer includes a main chain containing 70-99 wt.% styrene and 1-30 wt.% epoxysilane represented by formula 1, and the branching contain 1-80 wt.% acrylic monomers represented by formula 2.
where each R and R' are independently C1-C20aliphatic group, or C5-C20aromatic group having a double bond at the ends of the chain.
Each of the copolymers, high density polyethylene, modified (grafted) anhydride of maleic acid, linear low density polyethylene, modified (grafted) anhydride of maleic acid, ethylene-vinyl acetate modified (grafted) anhydride of maleic acid, preferably includes side C is PI containing 0.1-10 wt.% maleic anhydride relative to the main chain. When the content of maleic anhydride is less than 0.1 wt.%, the copolymer does not function as substances for compatibility. The content of maleic anhydride is more than 10 wt.% unacceptable because of the unpleasant smell. A container having barrier properties, can be produced in accordance with the present invention by molding the composition with the nanocomposite having protective properties. Because of the dry mix composition with nanocomposite, the morphology of the nanocomposites nanocomposite having barrier properties, can be saved to obtain molded products having good protective properties. The molded product may be obtained in the usual way of forming, including pneumotropica, extrusion molding, molding under pressure and injection molding. In addition to the container with protective properties, can be made of a sheet or film having protective properties. The container or sheet with protective properties, can be multi-layered container or film, which has an additional adhesive layer and a layer of polyolefin. For example, sheet or container with protective properties, can be made from 5-layer film HDPE/adhesive/composition with a nanocomposite in accordance with the present invention/adhesive/HDPE. The composition of the nanocomposite in accordance with the embodiment of the present invention has a high protective properties and formability, and thus made the product possesses a wonderful performance as a container, a sheet or film having protective properties.While the present invention has been disclosed in detail using variants of its implementation, to a person skilled in this field it is obvious that various changes in form and details of the invention may be made without departing from the scope of the claims of the present invention defined by the claims. Brief description of drawings Disclosed earlier signs and symptoms, which will be disclosed hereinafter, and advantages of the present invention will be more apparent when the detailed description of examples of its implementation on the basis of the appended drawings, in which figure 1 - electron microscopic photograph (×200) cross-section of the product obtained by pneumoperitoneum from the composition with a nanocomposite in accordance with the embodiment of the present invention; figure 2 - electron microscopic photograph (×5000) cross-section of the product obtained by pneumoperitoneum from the composition with a nanocomposite in accordance with the option assests the of the present invention. The implementation of the invention Examples In the following examples used the following materials: EMU (EVOH):E105B (Kuraray, Japan) Amorphous nylon: SELAR 2072 (Dupont, USA) Nylon 6,12: Zytel 158L(Dupont, USA) Nylon 6: EN500 (KP Chemicals) HDPE-g-MAH: substance ensuring the compatibility of the components, RV (CRAMP-TON) HDPE: ME (LG CHEM) Ion meter: SURLYN 8527 (Dupont, USA) Clay: (Closite) 30V (SCP) Thermal stabilizer: IR 1098 (Songwon Inc.) Example obtain 1 (getting EMU/nanocomposite with intercalated clay) 97 wt.% copolymer of ethylene-vinyl alcohol (EMU); E105 (ethylene content of 44 mol.%; Kuraray, Japan; the melt index of 5.5 g/10 min; a density of 1.14 g/cm3) are placed in the main feeder double screw extruder (SM Platek, co rotating twin screw extruder; ϕ 40). Then, 3 wt.% organic montmorillonite (Southern Intercalated Clay Products, USA; C2OA) as an intercalated clay and 0.1 wt.% IR 1098 as a thermal stabilizer, counting for 100 wt.% the amount of EMU copolymer and organic montmorillonite, separately put in the side feeder of the twin screw extruder to obtain EMU/nanocomposite with intercalated clay in the form of granules. The temperature conditions of extrusion 180-190-200-200-200-200-200°C, the speed of screw rotation 300 rpm, capacity 15 kg/hour. Example of getting 2 (getting the Nylon 6/nanocomposite Internet is kalirani clay) 97 wt.% polyamide (nylon 6) are placed in the main feeder double screw extruder (SM Platek, co rotating twin screw extruder; ϕ 40). Then, 3 wt.% organic montmorillonite as an intercalated clay and 0.1 wt.% IR 1098 as a thermal stabilizer, counting for 100 wt.% the amount of polyamide and organic montmorillonite, separately put in the side feeder of the twin screw extruder to obtain a nylon 6/nanocomposite with intercalated clay in the form of granules. The temperature conditions of extrusion 220-225-245-245-245-245-245°C, the speed of screw rotation 300 rpm and a capacity of 40 kg/hour. Example for the preparation of 3 (getting the Nylon 6,12/nanocomposite with intercalated clay) 95 wt.% polyamide (nylon 6,12) placed in the main feeder double screw extruder (SM Platek, co rotating twin screw extruder; ϕ 40). Then, 5 wt.% organic montmorillonite as an intercalated clay and 0.1 wt.% IR 1098 as a thermal stabilizer, counting for 100 wt.% the amount of polyamide and organic montmorillonite, separately put in the side feeder of the twin screw extruder to obtain nylon 6,12/nanocomposite with intercalated clay in the form of granules. The temperature conditions of extrusion 225-245-245-245-245-245-240°C, the speed of screw rotation 300 rpm and productive is to be 40 kg/hour. Example 4 (obtaining Amorphous Nylon/nanocomposite with intercalated clay) 95 wt.% polyamide (amorphous nylon) placed in the main feeder double screw extruder (SM Platek, co rotating twin screw extruder; ϕ 40). Then, 5 wt.% organic montmorillonite as an intercalated clay and 0.1 wt.% ER. 1098 as a thermal stabilizer, counting for 100 wt.% the amount of polyamide and organic montmorillonite, separately put in the side feeder of the twin screw extruder to obtain an amorphous nylon/nanocomposite with intercalated clay in the form of granules. The temperature conditions of extrusion 215-225-235-235-235-235-230°C, the speed of screw rotation 300 rpm and a capacity of 40 kg/hour. Example of getting 5 (getting the ion meter/nanocomposite with intercalated clay) 95 wt.% ion meter is placed in the main feeder double screw extruder (SM Platek, co rotating twin screw extruder; ϕ 40). Then, 5 wt.% organic montmorillonite as an intercalated clay and 0.1 wt.% IR 1098 as a thermal stabilizer, counting for 100 wt.% the amount of ionomer and organic montmorillonite, separately put in the side feeder of the twin screw extruder to obtain ion meter/nanocomposite with intercalated clay in the form of granules. Temperature is haunted conditions of extrusion 220-230-235-235-235-235-230° With the speed of screw rotation 300 rpm and a capacity of 40 kg/hour. Example 1 40 wt. parts nanocomposites nanocomposite with EMU obtained in the Example of a 1 and 60 wt. parts of the EMU are mixed in the melt in the temperature conditions 190-200-210-210-210-200°to obtain a melt mixture nanocomposites nanocomposite with EMU/EMU. 20 wt. parts of the melt mixture is subjected to dry blending 70 wt. parts of HDPE and 10 wt. parts of substances, ensuring the compatibility of the components (high-density polyethylene modified (grafted) anhydride of maleic acid (HDPE-g-MAN, uniroyal chemical, USA, PB3009 (content IAS 1%), melt index of 5 g/10 min, a density of 0.95 g/cm3). Then by pneumaturia made container with a capacity of 1000 ml temperature conditions was 180-195-195-195-195-190°when the speed of rotation of the auger 22 rpm Also dry mixture was extrudible to obtain a film thickness of 30 μm. When this temperature was 185-195-195-195-195-190°when the rotation speed of the screw 16 rpm Example 2 40 wt. parts nanocomposites nanocomposite with EMU obtained in the Example of a 1 and 60 wt. parts of nylon 6 are mixed in the melt in the temperature conditions 215-220-210-210-210-200°to obtain a melt mixture nanocomposites nanocomposite with EMU/nylon 6. 20 wt. parts of the melt mixture is subjected to dry mixing 70 wt. parts HDPE and 10 wt. parts of the substance ensuring the compatibility of the components. Then by pneumaturia made container with a capacity of 1000 ml temperature conditions was 190-225-225-220-210°when the speed of rotation of the screw 23 rpm Also dry mixture was extrudible to obtain a film thickness of 30 μm. When this temperature was 220-235-235-235-235-235°when the rotation speed of the screw 16 rpm Example 3 40 wt. parts nanocomposites nanocomposite with EMU obtained in the Example of a 1 and 60 wt. parts of nylon 6,12 mixed in the melt in the temperature conditions 225-235-245-245-245-240°to obtain a melt mixture nanocomposites nanocomposite with EMU/nylon 6,12. 20 wt. parts of the melt is subjected to dry mixing 70 wt. parts of HDPE and 10 wt. parts of substances, ensuring the compatibility of the components. Then by pneumaturia made container with a capacity of 1000 ml temperature conditions was 200-220-230-225-210°and a screw rotation speed of 21 rpm Also dry mixture was extrudible to obtain a film thickness of 30 μm. When this temperature was 220-235-235-235-235-235°when the speed of rotation of the auger 14 Rev/min Example 4 40 wt. parts nanocomposites nanocomposite with EMU obtained in the Example of a 1 and 60 wt. parts of amorphous nylon mixed in the melt in the temperature conditions 225-235-245-245-245-240°to obtain a melt mixture nanocomposite with EMU/amorphous nylon. 20 mA is. parts of the melt mixture is subjected to dry mixing 70 wt. parts of HDPE and 10 wt. parts of substances, ensuring the compatibility of the components. Then by pneumaturia made container with a capacity of 1000 ml temperature conditions was 185-200-210-200-190°and a screw rotation speed of 22 rpm Also dry mixture was extrudible to obtain a film thickness of 30 μm. When this temperature was 220-235-235-235-235-235°when the rotation speed of the screw 16 rpm Example 5 40 wt. parts nanocomposites nanocomposite with EMU obtained in the Example of a 1 and 60 wt. parts of ionomer mixed in the melt in the temperature conditions 225-235-245-245-245-240°to obtain a melt mixture nanocomposite with EMU/ion meter. 20 wt. parts of the melt mixture is subjected to dry mixing 70 wt. parts of HDPE and 10 wt. parts of substances, ensuring the compatibility of the components. Then by pneumaturia made container with a capacity of 1000 ml temperature conditions was 190-210-225-220-210°and the speed of rotation of the screw 23 rpm Also dry mixture was extrudible to obtain a film thickness of 30 μm. When this temperature was 220-235-235-235-235-235°when the speed of rotation of the auger 14 Rev/min Example 6 40 wt. parts nanocomposites nanocomposite with nylon 6 obtained in Example getting 2, and 60 wt. parts of the EMU is peremeshivayte in the melt in the temperature conditions 220-235-245-245-245-240° To obtain molten mixture nanocomposites nanocomposite with nylon 6/EMU. 20 wt. parts of the melt is subjected to dry mixing 70 wt. parts of HDPE and 10 wt. parts of substances, ensuring the compatibility of the components. Then by pneumaturia made container with a capacity of 1000 ml temperature conditions was 185-195-225-215-200°and the speed of rotation of the auger 14 rpm Also dry mixture was extrudible to obtain a film thickness of 30 μm. When this temperature was 220-235-235-235-235-235°when the speed of rotation of the screw 13 rpm Example 7 40 wt. parts nanocomposites nanocomposite with the nylon 6 obtained in Example getting 2, and 60 wt. parts of nylon 6 are mixed in the melt in the temperature conditions 220-235-245-245-245-240°to obtain a melt mixture nanocomposites nanocomposite with nylon 6/nylon 6. 20 wt. parts of the melt mixture is subjected to dry mixing 70 wt. parts of HDPE and 10 wt. parts of substances, ensuring the compatibility of the components. Then by pneumaturia made container with a capacity of 1000 ml temperature conditions was 195-215-220-215-200°and screw rotation speed 24 rpm Also dry mixture was extrudible to obtain a film thickness of 30 μm. When this temperature was 220-245-245-245-245-240°when the speed of rotation of the screw 13 rpm Example 8 40 wt. parts of the nano is composite with nylon 6, received in the Sample receiving 2, and 60 wt. parts of nylon 6,12 mixed in the melt in the temperature conditions 230-240-245-245-245-235°to obtain a melt mixture nanocomposites nanocomposite with nylon 6/nylon 6,12. 20 wt. parts of the melt mixture is subjected to dry mixing 70 wt. parts of HDPE and 10 wt. parts of substances, ensuring the compatibility of the components. Then by pneumaturia made container with a capacity of 1000 ml temperature conditions was 195-225-225-215-200°and screw rotation speed 24 rpm Also dry mixture was extrudible to obtain a film thickness of 30 μm. When this temperature was 220-235-235-245-245-245°With screw rotation speed 12 rpm Example 9 40 wt. parts nanocomposites nanocomposite with nylon 6 obtained in Example getting 2, and 60 wt. parts of amorphous nylon mixed in the melt in the temperature conditions 230-240-245-245-245-235°to obtain a melt mixture nanocomposites nanocomposite with nylon 6/amorphous nylon. 20 wt. parts of the melt mixture is subjected to dry mixing 70 wt. parts of HDPE and 10 wt. parts of substances, ensuring the compatibility of the components. Then by pneumaturia made container with a capacity of 1000 ml temperature conditions was 185-220-220-215-200°when the speed of rotation of the auger 24 rpm Also dry mixture was extrudible for receiving the Oia film thickness of 30 μm. When this temperature was 220-235-235-235-235-235°and a screw rotation speed of 15 rpm Example 10 40 wt. parts nanocomposites nanocomposite with nylon 6 obtained in Example getting 2, and 60 wt. parts of ionomer mixed in the melt in the temperature conditions 210-225-235-235-235-230°to obtain a melt mixture nanocomposite with nylon 6/ion meter. 20 wt. parts of the melt mixture is subjected to dry mixing 70 wt. parts of HDPE and 10 wt. parts of substances, ensuring the compatibility of the components. Then by pneumaturia made container with a capacity of 1000 ml temperature conditions was 185-235-235-235-235-230°and a screw rotation speed of 21 rpm Also dry mixture was extrudible to obtain a film thickness of 30 μm. When this temperature was 220-235-235-235-240-240°when the speed of rotation of the auger 12 rpm Example 11 40 wt. parts nanocomposites nanocomposite with nylon 6,12 received in the Sample receiving 3, and 60 wt. parts of the EMU are mixed in the melt in the temperature conditions 220-235-245-245-245-240°to obtain a melt mixture nanocomposite with nylon 6,12/EMU. 20 wt. parts of the melt mixture is subjected to dry mixing 70 wt. parts of HDPE and 10 wt. parts of substances, ensuring the compatibility of the components. Then by pneumaturia made container with a capacity of 1000 ml At this rate the temperature conditions were 185-225-225-215-200° And screw rotation speed of 21 rpm Also dry mixture was extrudible to obtain a film thickness of 30 μm. When this temperature was 215-225-235-235-235-240°when the speed of rotation of the auger about 15/min Example 12 40 wt. parts nanocomposites nanocomposite with nylon 6,12 received in the Sample receiving 3, and 60 wt. parts of nylon 6 are mixed in the melt in the temperature conditions 220-235-245-245-245-240°to obtain a melt mixture nanocomposites nanocomposite with nylon 6,12/nylon 6. 20 wt. parts of the melt mixture is subjected to dry mixing 70 wt. parts of HDPE and 10 wt. parts of substances, ensuring the compatibility of the components. Then by pneumaturia made container with a capacity of 1000 ml temperature conditions was 185-245-245-245-240°and a screw rotation speed of 23 rpm Also dry mixture was extrudible to obtain a film thickness of 30 μm. When this temperature was 205-225-235-240-240-245°when the speed of rotation of the auger 12 rpm Example 13 40 wt. parts nanocomposites nanocomposite with nylon 6,12 received in the Sample receiving 3, and 60 wt. parts of nylon 6,12 mixed in the melt in the temperature conditions 220-235-245-245-245-240°to obtain a melt mixture nanocomposites nanocomposite with nylon 6,12/nylon 6,12. 20 wt. parts of the melt mixture is subjected to dry mixing 70 wt. parts of HDPE and 10 wt. parts of the substance, obespechivayuschego compatibility of components. Then by pneumaturia made container with a capacity of 1000 ml temperature conditions was 190-215-230-230-225-210°and screw rotation speed 24 rpm Also dry mixture was extrudible to obtain a film thickness of 30 μm. When this temperature was 210-225-245-245-245-245°when the rotation speed of the screw 13 rpm Example 14 40 wt. parts nanocomposites nanocomposite with nylon 6,12 received in the Sample receiving 3, and 60 wt. parts of amorphous nylon mixed in the melt in the temperature conditions 220-235-235-235-235-230°to obtain a melt mixture nanocomposites nanocomposite with nylon 6,12/amorphous nylon. 20 wt. parts of the melt mixture is subjected to dry mixing 70 wt. parts of HDPE and 10 wt. parts of substances, ensuring the compatibility of the components. Then by pneumaturia made container with a capacity of 1000 ml temperature conditions was 190-220-225-215-200°and screw rotation speed 24 rpm Also dry mixture was extrudible to obtain a film thickness of 30 μm. When this temperature was 220-235-235-235-235-235°when the speed of rotation of the auger 12 rpm Example 15 40 wt. parts nanocomposites nanocomposite with nylon 6,12 received in the Sample receiving 3, and 60 wt. parts of ionomer mixed in the melt in the temperature conditions 215-235-245-245-245-240°to obtain a melt mixture of NAS the composite with nylon 6,12/ion meter. 20 wt. parts of the melt mixture is subjected to dry mixing 70 wt. parts of HDPE and 10 wt. parts of substances, ensuring the compatibility of the components. Then by pneumaturia made container with a capacity of 1000 ml temperature conditions was 195-225-225-225-200°and a screw rotation speed of 22 rpm Also dry mixture was extrudible to obtain a film thickness of 30 μm. When this temperature was 225-235-235-235-235-240°when the speed of rotation of the screw 13 rpm Example 16 40 wt. parts nanocomposites nanocomposite amorphous nylon obtained in Example 4, and 60 wt. parts of the EMU are mixed in the melt in the temperature conditions 205-215-215-215-215-210°to obtain a melt mixture nanocomposites nanocomposite amorphous nylon/EMU. 20 wt. parts of the melt mixture is subjected to dry mixing with 70 mascectomy HDPE and 10 wt. parts of substances, ensuring the compatibility of the components. Then by pneumaturia made container with a capacity of 1000 ml temperature conditions was 185-205-215-210-200°and the speed of rotation of the auger 20 rpm Also dry mixture was extrudible to obtain a film thickness of 30 μm. When this temperature was 220-235-235-235-235-235°when the speed of rotation of the screw 13 rpm Example 17 40 wt. parts nanocomposites nanocomposite amorphous nylon, obtained When the ore receiving 4, and 60 wt. parts of nylon 6 are mixed in the melt in the temperature conditions 225-235-235-235-235-230°to obtain a melt mixture nanocomposites nanocomposite amorphous nylon/nylon 6. 20 wt. parts of the melt mixture is subjected to dry mixing 70 wt. parts of HDPE and 10 wt. parts of substances, ensuring the compatibility of the components. Then by pneumaturia made container with a capacity of 1000 ml temperature conditions was 195-215-220-215-200°and a screw rotation speed of 23 rpm Also dry mixture was extrudible to obtain a film thickness of 30 μm. When this temperature was 220-235-235-235-235-240°when the speed of rotation of the screw 13 rpm Example 18 40 wt. parts nanocomposites nanocomposite amorphous nylon obtained in Example 4, and 60 wt. parts of nylon 6,12 mixed in the melt in the temperature conditions 225-240-240-240-240-235°to obtain a melt mixture nanocomposites nanocomposite amorphous nylon/nylon 6,12. 20 wt. parts of the melt mixture is subjected to dry mixing 70 wt. parts of HDPE and 10 wt. parts of substances, ensuring the compatibility of the components. Then by pneumaturia made container with a capacity of 1000 ml temperature conditions was 200-220-225-215-205°and a screw rotation speed of 22 rpm Also dry mixture was extrudible to obtain a film thickness of 30 μm. While the temperature conditions were 215-225-235-235-235-240° When the speed of rotation of the auger 12 rpm Example 19 40 wt. parts nanocomposites nanocomposite amorphous nylon obtained in Example 4, and 60 wt. parts of amorphous nylon mixed in the melt in the temperature conditions 225-240-240-240-240-235°to obtain a melt mixture nanocomposites nanocomposite amorphous nylon/amorphous nylon. 20 wt. parts of the melt mixture is subjected to dry mixing 70 wt. parts of HDPE and 10 wt. parts of substances, ensuring the compatibility of the components. Then by pneumaturia made container with a capacity of 1000 ml temperature conditions was 190-205-215-205-195°and screw rotation speed 24 rpm Also dry mixture was extrudible to obtain a film thickness of 30 μm. When this temperature was 200-215-215-215-215-220°when the rotation speed of the screw 13 rpm Example 20 40 wt. parts nanocomposites nanocomposite amorphous nylon obtained in Example 4, and 60 wt. parts of ionomer mixed in the melt in the temperature conditions 225-240-240-240-240-235°to obtain a melt mixture nanocomposites nanocomposite amorphous nylon/ion meter. 20 wt. parts of the melt mixture is subjected to dry mixing 70 wt. parts of HDPE and 10 wt. parts of substances, ensuring the compatibility of the components. Then by pneumaturia made container with a capacity of 1000 ml At this temperature the cultural conditions were 190-215-220-215-205° And screw rotation speed of 22 rpm Also dry mixture was extrudible to obtain a film thickness of 30 μm. When this temperature was 220-235-235-235-235-240°With screw rotation speed 12 rpm Example 21 40 wt. parts nanocomposites nanocomposite with ionomers received in the Sample receiving 5 and 60 wt. parts of the EMU are mixed in the melt in the temperature conditions 225-235-235-240-240-235°to obtain a melt mixture nanocomposites nanocomposite with ionomers/EMU. 20 wt. parts of the melt mixture is subjected to dry mixing 70 wt. parts of HDPE and 10 wt. parts of substances, ensuring the compatibility of the components. Then by pneumaturia made container with a capacity of 1000 ml temperature conditions was 190-215-220-215-200°and screw rotation speed 24 rpm Also dry mixture was extrudible to obtain a film thickness of 30 μm. When this temperature was 210-225-235-235-235-240°when the speed of rotation of the auger 14 Rev/min Example 22 40 wt. parts nanocomposites nanocomposite with ionomers received in the Sample receiving 5 and 60 wt. parts of nylon 6 are mixed in the melt in the temperature conditions 225-240-245-245-245-240°to obtain a melt mixture nanocomposites nanocomposite with ionomers/nylon 6. 20 wt. parts of the melt mixture is subjected to dry mixing 70 wt. parts of HDPE and 10 wt. parts of the substance, providing with the compatibility of the components. Then by pneumaturia made container with a capacity of 1000 ml temperature conditions was 195-215-225-220-210°and a screw rotation speed of 23 rpm Also dry mixture was extrudible to obtain a film thickness of 30 μm. When this temperature was 220-235-235-235-235-240°when the speed of rotation of the screw 13 rpm Example 23 40 wt. parts nanocomposites nanocomposite with ionomers received in the Sample receiving 5 and 60 wt. parts of nylon 6,12 mixed in the melt in the temperature conditions 225-245-245-245-245-240°to obtain a melt mixture nanocomposites nanocomposite with ionomers/nylon 6,12. 20 wt. parts of the melt mixture is subjected to the dry mixed with 70 wt. parts of HDPE and 10 wt. parts of substances, ensuring the compatibility of the components. Then by pneumaturia made container with a capacity of 1000 ml temperature conditions was 225-245-245-245-245-240°and a screw rotation speed of 23 rpm Also dry mixture was extrudible to obtain a film thickness of 30 μm. When this temperature was 220-235-235-235-235-240°when the speed of rotation of the auger 14 Rev/min Example 24 40 wt. parts nanocomposites nanocomposite with ionomers received in the Sample receiving 5 and 60 wt. parts of amorphous nylon mixed in the melt in the temperature conditions 215-230-235-235-235-230°to obtain a melt mixture of nanocomposites ionomers/amorphous nylon. 20 wt. parts of the melt mixture is subjected to dry mixing 70 wt. parts of HDPE and 10 wt. parts of substances, ensuring the compatibility of the components. Then by pneumaturia made container with a capacity of 1000 ml temperature conditions was 185-215-220-215-200°and screw rotation speed 24 rpm Also dry mixture was extrudible to obtain a film thickness of 30 μm. When this temperature was 215-235-235-235-235-240°when the speed of rotation of the auger about 15/min Example 25 40 wt. parts nanocomposites nanocomposite with ionomers received in the Sample receiving 5 and 60 wt. parts of ionomer mixed in the melt in the temperature conditions 215-235-235-235-235-240°to obtain a melt mixture nanocomposites nanocomposite with ionomers/ion meter. 20 wt. parts of the melt mixture is subjected to dry mixing 70 wt. parts of HDPE and 10 wt. parts of substances, ensuring the compatibility of the components. Then composition with the nanocomposite is subjected to pneumoperitoneum a 5-layer structure (HDPE/adhesive/composition nanocomposite/adhesive/HDPE) for the manufacture of a container with a capacity of 1000 ml temperature conditions was 195-225-225-225-215°and a screw rotation speed of 23 rpm Also dry mixture was extrudible a 5-layer structure (HDPE/adhesive/composition nanocomposite/adhesive/HDPE) to obtain a thick film is 30 μm. When this temperature was 220-235-235-235-235-240°when the speed of rotation of the auger 12 rpm Example 26 40 wt. parts nanocomposites nanocomposite with nylon 6 obtained in Example getting 2, and 60 wt. parts of amorphous nylon mixed in the melt in the temperature conditions 230-240-245-245-245-235°to obtain a melt mixture nanocomposites nanocomposite with nylon 6/amorphous nylon. 4 wt. part of the melt mixture is subjected to dry mixing with 94 wt. parts of HDPE and 2 wt. parts of substances, ensuring the compatibility of the components, to obtain a composition with the nanocomposite. Then composition with the nanocomposite is subjected to pneumoperitoneum a 5-layer structure (HDPE/adhesive/composition nanocomposite/adhesive/HDPE) for the manufacture of a container with a capacity of 1000 ml temperature conditions was 195-225-225-225-215°and a screw rotation speed of 23 rpm Also the composition with the nanocomposite was extrudible a 5-layer structure (HDPE/adhesive/composition nanocomposite/adhesive/HDPE) to obtain a film thickness of 30 μm. When this temperature was 220-235-235-235-235-240°when the speed of rotation of the auger 12 rpm Example 27 40 wt. parts nanocomposites nanocomposite with nylon 6 obtained in Example getting 2, and 60 wt. parts of amorphous nylon mixed in the melt in the temperature conditions 230-240-245-245-245-235°for the floor is to be placed melt mixture nanocomposites nanocomposite with nylon 6/amorphous nylon. 60 wt. parts of the melt mixture is subjected to dry mixing with 35 wt. parts of HDPE and 5 wt. parts of substances, ensuring the compatibility of the components, to obtain a composition with the nanocomposite. Then composition with the nanocomposite is subjected to pneumoperitoneum a 5-layer structure (HDPE/adhesive/composition nanocomposite/adhesive/HDPE) for the manufacture of a container with a capacity of 1000 ml temperature conditions was 195-225-225-225-215°and a screw rotation speed of 23 rpm Also the composition with the nanocomposite was extrudible a 5-layer structure (HDPE/adhesive/composition nanocomposite/adhesive/HDPE) to obtain a film thickness of 30 μm. When this temperature was 220-235-235-235-235-240°when the speed of rotation of the auger 12 rpm Comparative example 1 70 wt. parts HDPE, 10 wt. parts of substances, ensuring the compatibility of the components 20 wt. parts copolymer EMU mix and by pneumaturia made container with a capacity of 1000 ml temperature conditions was 180-190-190-185-180°and a screw rotation speed of 22 rpm the mixture was extrudible to obtain a film thickness of 30 μm. When this temperature was 220-235-235-235-235-240°when the speed of rotation of the auger 14 Rev/min Comparative example 2 70 wt. parts HDPE, 10 wt. parts of the substance, obespechivaya what about the compatibility of components, 20 wt. parts of nylon 6 mixed by pneumaturia made container with a capacity of 1000 ml temperature conditions was 210-220-225-215-200°and the rotation speed of the screw 21 Rev/min. the mixture was extrudible to obtain a film thickness of 30 μm. When this temperature was 220-235-235-235-235-240°when the speed of rotation of the screw 13 rpm Comparative example 3 70 wt. parts HDPE, 10 wt. parts of substances, ensuring the compatibility of the components 20 wt. parts of nylon 6,12 mix and by pneumaturia made container with a capacity of 1000 ml temperature conditions was 215-225-230-215-205°and a screw rotation speed of 22 rpm the mixture was extrudible to obtain a film thickness of 30 μm. When this temperature was 220-235-240-240-240-245°and screw rotation speed 12 rpm Comparative example 4 70 wt. parts HDPE, 10 wt. parts of substances, ensuring the compatibility of the components 20 wt. parts of ionomer mix and by pneumaturia made container with a capacity of 1000 ml temperature conditions was 205-215-225-220-215°and the speed of rotation of the auger 14 Rev/min the mixture was extrudible to obtain a film thickness of 30 μm. When this temperature was 220-235-235-235-235-240°when the speed of rotation of the auger 14 Rev/min p> The containers and films obtained by the method of pneumaturia described in examples 1-27 and comparative examples 1-4 were tested protective properties, the results are presented in tables 1 and 2.Experimental example Toluene and M15 (a mixture of 85% toluene/isooctane (50/50) and 15% methanol) were placed in containers of examples 1-27 and comparative examples 1-4. Then define the change of weight in 15 days in a drying Cabinet at 50°C. Films prepared by the method described in examples 1-27 and in comparative examples 1-4, was kept at a temperature of 23°C and 50% relative humidity for 1 day. Then measured the speed of gas diffusion (Mocon OX-TRAN 2/20, USA). td align="center"> 0.0921255.66
As shown in tables 1 and 2, containers and films obtained by the method described in examples 1-27 using the prepared dry mix composition comprising polyolefin resin, a substance that allows compatibility between components, and the melt mixture of the resin with protective properties/nanocomposite, have a very good protective properties against liquids and gases in comparison with containers and films obtained by the method described in comparison examples 1-4, which are obtained using a composition comprising polyolefin resin, a substance that allows compatibility between components, and the resin having barrier properties. Electron microscopic photographs of the cross-section of the container obtained by pneumoperitoneum in example 7, as shown in figure 1 (×200) and figure 2 (×5000). As can be seen from figures 1 and 2, the container made from the composition with a nanocomposite having protective properties, includes nanocomposite dispersed throughout the volume of the polyolefin resin, which provides a good protective properties. 1. Mixed dry composition with a nanocomposite including 30-95 parts by weight of a polyolefin resin; 0.5-60 parts by weight of the melt mixture comprising at least the bottom of the resin protective properties, selected from the group consisting of a copolymer of ethylene-vinyl alcohol (EMU), polyamide, ionomer and polyvinyl alcohol (PVA) and at least one nanocomposites nanocomposite having barrier properties, selected from the group consisting of a copolymer EMU/nanocomposite with intercalated clay, polyamide/nanocomposite with intercalated clay, ionomer/nanocomposite with intercalated clay and polyvinyl alcohol/nanocomposite with intercalated clay; and 1-30 parts by weight of substances, ensuring the compatibility of the components, in which the substance ensuring the compatibility of the components, represented by one or more compounds selected from the group consisting of a copolymer of ethylene-ethylene anhydride acrylic acid; a copolymer of ethylene-ethyl acrylate; copolymer of ethylene-alkyl acrylate-acrylic acid; high-density polyethylene, modified (grafted) anhydride of maleic acid; linear low density polyethylene, modified (grafted) maleic acid anhydride; a copolymer of ethylene-alkyl (meth)acrylate-(meth)acrylic acid; a copolymer of ethylene-butyl acrylate; copolymer of ethylene-vinyl acetate; copolymer of ethylene-vinyl acetate modified (grafted) anhydride of maleic acid. 2. The composition according to claim 1, in which the resin protective properties and nanocomposite with for animi properties are mixed in the melt in a mass ratio of from 25:75 to 75:25. 3. The composition according to claim 1, in which the polyolefin resin is at least one of the compounds selected from the group consisting of high density polyethylene (HDPE), low density polyethylene (LDPE), linear low density polyethylene (LLDPE), polypropylene, and copolymer ethylene-propylene. 4. The composition according to claim 1, in which the intercalated clay is at least one of the compounds selected from the group consisting of montmorillonite, bentonite, kaolinite, mica, hectorite, forgetit, saponite, beidellite, nontronite, stevensite, vermiculite, callosity, volkonskoit, saconit, magarita, geniality. 5. The composition according to claim 1, in which the intercalated clay contains 1-45 wt.% organic material. 6. The composition according to claim 5, in which the organic material contains at least one functional group selected from the group consisting of ammonium from the primary to the Quaternary, phosphonium, maleate, succinate, acrylate, benzyl hydrogen, oxazoline and dimethisterone. 7. The composition according to claim 1 in which the copolymer of ethylene-vinyl alcohol contains 10-50 mol.% of ethylene. 8. The composition according to claim 1, in which the polyamide is nylon 4.6, nylon 6, nylon 6.6, nylon 6.10, nylon 7, nylon 8, nylon 9, nylon 11, nylon 12, nylon 46, MXD 6, amorphous polyamide, copolymerizable polyamide, soda is official at least two of them, or a mixture of at least two of them. 9. The composition according to claim 1, in which the ion meter is characterized by a melt index of 0.1-10 g/10 min (190°, 2, 160 g). 10. The composition according to claim 1, in which the resin protective properties and nanocomposite with protective properties are mixed in the melt with the application of the jointly rotating twin-screw extruder or single screw extruder at a melting temperature or at higher temperatures. 11. The composition according to claim 1, in which the mass ratio of the resin protective properties to the intercalated clay in the nanocomposite is from 58.0:42.0 to 99.9:0.1 12. The product produced by molding the composition with the nanocomposite according to any one of claims 1 to 11. 13. The product is indicated in paragraph 12, the received pneumoperitoneum, extrusion molding, the molding pressure, molding compression. 14. The product according to item 12, which is a container with protective properties. 15. The product according to item 12, which is a pipe with protective properties. 16. The product according to item 12, which represents a sheet with protective properties. 17. Product 14, which is a multilayered container, further containing an adhesive layer and a layer of polyolefin resin. 18. The product according to item 16, which is a multilayered sheet, further containing an adhesive layer and a layer of polyolefin is th resin.
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