Substituted iron phthalocyanines and method of obtaining chlor-derivatives of aromatic hydrocarbons |
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IPC classes for russian patent Substituted iron phthalocyanines and method of obtaining chlor-derivatives of aromatic hydrocarbons (RU 2340589):
                               
 Method of production of mevalonic acid derivatives inhibiting hmg-coa reductase / 2335500
Invention concerns improved method of obtaining mevalonic acid derivatives of the general formula I
 Basic iron (iii) acetate producing method / 2314285
Method is realized by relation of metallic iron with acetic acid at presence of oxidizing agent; using molecular iodine, iron oxides such as Fe2O3, Fe3O4 and oxygen of air as oxidizing agent for converting impurity of iron (II) acetate to basic iron (III) acetate. Process is performed in beads mill at temperature 80°Cand at mass relation of liquid charge and glass beads 1 : 1. Iron is used in the form of shell abutted to lateral surface of reactor housing. Initial molar relation of iron oxide and iodine is 10 : 1. Molar relation of acetic acid, its anhydride and iron oxide is in range 100 : (2 - 5.99) : (2 - 2.5). In time moment of practically complete consumption of iron oxide, solid phase of reaction mixture is taken off by filtering. Simultaneously consumed reagents are replenished and filtrate is returned to reactor for repeating process. Number of processes to be repeated is no more than 5. At second stage residues of iron (II) salt are after-oxidized to basic iron (III) acetate due to drying up taken off solid phase of product in filter by means of blowing air at environmental temperature. Preferably, hematite, γ-oxide or minimum is used as Fe2 O 3 and magnetite and Fe3O4 x 4H2Ois used asFe3 O4.
 Methods for preparing ferric complexes with one salicylic acid anion / 2307118
Invention relates to technology of complexes of iron with salicylic acid suitable for use in a variety of technical areas and in medicine. Title complex is obtained via interaction of metal with acid using air oxygen as oxidant. Salicylic acid is used in butyl acetate or n-butyl alcohol solution with dissolved molecular iodine or potassium iodide. Iron is provided in the form of steel or cast iron shell, shaft, and blade of mechanical mixer as well as, agitated by the mixer, reduced iron powder fractions, broken cast iron or broken steel cuttings, cast iron or steel filings. Process is carried out at stirring with high-speed mechanical stirrer and air bubbling allowing self-heating of reaction mixture to 70-80°C until 1.72-1.85 mole/kg iron compounds is accumulated in reaction mixture in the form of suspension, whereupon mixing is stopped. Suspension is freed of unreacted fine iron and/or alloy(s) thereof and subjected to hot filtration, Filtrate is warmed to eliminate precipitated solid phase and then slowly cooled to ambient temperature. Precipitated solid phase is filtered off, dried, and recrystallized, while filtrate is recycled.
 Method of production of iron (iii) complex with three anions of salicylic acid / 2304575
Proposed iron (III) complex with three anions of salicylic acid is produced due to interaction of iron and its alloys with salicylic acid dissolved in dimethyl formamide in vertical bead-type mill provided with high-speed mechanical blade-type agitator at bubbling of air and spontaneous heating of reaction mixture to 80-90C. Iron is presented in form of steel or cast-iron ferrule over entire height of bead-type mill, steel shaft and blade of mechanical agitator, as well as in form of iron powder, fraction of broken cast iron, broken steel chips or cast-iron shot. Process is completed at accumulation of iron salts in reaction mixture of 1.12-1.30 mole/kg; 95% of these salts are in target compounds of iron (III). Hot suspension is filtered immediately and filtrate is cooled down for crystallization of main mass of iron (III) complex. Precipitated product is filtered and is directed for re-crystallization, if necessary. Filtrate is returned for repeated process.
Water-soluble iron-carbohydrate complexes, method for their preparing, medicinal agent, using / 2303039
Invention describes water-soluble iron-carbohydrate complexes containing 10-40 wt.-% of iron. Complexes can be prepared from ferric (III) salt aqueous solution and oxidation product aqueous solution of one or more maltodextrins with hypochlorite aqueous solution at alkaline pH value. In using one maltodextrin its dextrose equivalent is from 5 to 20, and in using mixture of maltodextrins the dextrose equivalent is from 5 to 20 and dextrose equivalent of each maltodextrin as component of mixture is from 2 to 40. Also, invention describes a method for preparing this complex and medicinal agents used in treatment and prophylaxis of states associated with iron deficiency.
 Method of preparing supported olefin polymerization catalysts / 2302292
Invention relates to an area of supported olefin polymerization organometallic catalysts containing organometallic complex LMX2, wherein L represents bic(imido)pyridine, M period IV transition metal (Ti, V, Cr. Fe. Co), X halogen, alkoxy or alkyl group, deposited on oxide support, namely large-pore silica gel with pore volume no greater than 1.3 cm3/g and specific surface not exciding 250 m2/g, which, prior to deposition of complex LMX2, is treated with trialkylaluminum AlR3 (R = Et or i-Bu) followed by heating SiO2/AlR3 product and dehydroxylation of support obtained.
 Method of preparing iron(iii) formate in presence of hydrogen peroxide / 2296745
Invention relates to preparation of salts of transition metals with organic acids, in particular to formic acid ferric salt. Method is accomplished via oxidation of ferrous formate with hydrogen peroxide in presence of formic acid and in absence of any dorm of iron as reducer in order to prevent reduction of ferric salt into original ferrous salt. As reducer, ferrous formate is used preliminarily recrystallized and dried or filtered off from reaction mixture suspension. Process is carried out in upright bead mill in two steps. In the first step, ferrous formate powder or precipitate is combined, stepwise or in one go, with 85% formic acid or mixture of filtrate with wash water formed during isolation of desired product to form pasty slurry ensuring stable functioning of bead mill. Second-step operation is effected in bead mill functioning mode involving forced cooling through side surfaces of reactor and continuous introduction of 12.5-25% hydrogen peroxide solution at a rate of 3.25-4.24 g H2O2 per 1 kg starting charge until degree of Fe(II) salt conversion achieves 85-90%. Supply velocity is then lowered until complete conversion is reached. Resulting product slurry is separated from beads and filtered. Filter cake is washed with 85% formic acid and recrystallized in saturated ferric formate solution containing 20-30% of formic acid. Wash liquid is combined with filtrate and used in the first step as described above.
 Method of preparing iron(ii) formate in presence of hydrogen peroxide as oxidant / 2296744
Invention relates to preparation of salts of transition metals with organic acids, in particular to formic acid ferric salt. Method is accomplished in bead mill provided with mechanical blade-type stirrer in aqueous formic acid solution (5-10 mole/kg). Iron is used in the form of steel sidewall across the height of reactor and also as particles of reduced iron stirred with stirrer together with glass beads, and/or as broken steel cuttings, and/or yet as split cast iron in any weight proportions. Method is accomplished by continuously introducing 10-20% hydrogen peroxide solution at a rate of 0.015-0,030 mole peroxide/min per 1 kg liquid phase (salt slurry) in presence of stimulating additive, in particular iodine, bromine, alkali metal or ferrous iodides or bromides in amounts (on conversion to halogens) 0.1-0.15 vole per 1 kg reaction mixture. When 1,2-1,5 mole/kg of ferrous salt is accumulated in reaction mixture, stirring and addition of hydrogen peroxide solution are stopped, product slurry is separated from unreacted iron and/or its alloys as well as from glass beads and filtered. Filtrate is recycled into process and precipitate is recrystallized from saturated iron formate solution of aqueous formic acid solution (1-2 mole/kg).
 Method of production of the ferric formiate (ii) / 2292331
The invention is pertaining to the field of chemical industry, in particular, to the method of production of the salts of iron and the organic acids, in particular, to production of the salt of the ferrous iron and the formic acid. The method is realized by the direct interaction of the acid with the iron, its alloys and the ferric oxides. The crumber with the beads and the backflow condenser is loaded with the organic solvent, the formic acid and the water in the mass ratio of 100:(85÷100): (15÷0). As the organic solvent they use ethylcellosolve, butyl acetate, butyl and amyl alcohols, ethylene glycol. The mass ratio of the beads and the liquid phase is 1:1. Ferric oxideFe2O3 orFe3O4 and the iodine are loaded in the amount of 0.40-0.56 or 0/21-0.42 and 0.03-0.1 mole/kg of the liquid phase accordingly. The iron is introduced in the form of the steel shell along the whole height of the reactor and additionally in form of the reduced iron, the fractions of the broken cast iron with dimensions of up to 5 mm and the steel chips in any ratio among themselves at total amount of 20 % from the mass of the liquid phase. The process is conducted at the temperature of 35-55°С practically till the complete consumption of the ferric oxide. The gained suspension is separated from the beads and the metal particles of the greater dimensions and subjected to centrifuging or sedimentation. The clarified liquid phase is returned to the repeated process, and the solid phase is dissolved at stirring action and warming up to 85-95°С in the water solution of the formic acid saturated by the ferric formiate (II) up to 1-2 mole/kg. The present solid impurities are removed at the hot filtration process and the filtrate is cooled and the salt crystals are separated. The technical result of the invention is simplification of the technology of the production process with utilization of the accessible raw.
Method of production of the ferric formiate (ii) in the water medium / 2292330
The invention is pertaining to the field of chemical industry, in particular, to the method of production of the salts of the metals of the organic acids, in particular, to production of the salt of the ferrous iron and the formic acid. The method is realized by the direct interaction of the formic acid water solution with the iron and/or its alloys and the ferric oxidesFe2O3 and Fe3O4 in the bead crumber of the vertical type along the whole its height with the steel shell, with the heat supply and equipped with the mechanical stirrer and the backflow condenser-refrigerator. The apparatus is loaded with 23-46 % water solution of the formic acid as the liquid phase in the mass ratio with the glass beads as 1:1.25 and then introduce the oxide - Fe3O4 orFe2O3 in amount of 0.27-0.49 or 0.48-0.64 mole/kg of the liquid phase accordingly, and besides in amount of 18 % from the mass of the liquid phase they add the powder of the reduced iron and-or the crushed cast iron, and-or the crushed steel chips in any mass ratios. Switch on the mechanical stirring and heating and keep the temperature in the reaction zone within the limits of 55-75°С. The process is terminated, when practically the whole loaded oxide is completely consumed. The suspension of the salt is separated from the non-reacted iron, its alloy and the beads and dilute with the water up to the contents of the formic acid within the limits of 1-2 mole/kg. The gained mass at stirring action is slowly heated up to temperature of 85-95°С, controlling transformation of the solid phase into the solution. The gained solution is subjected to the hot filtration, evaporation, cooling and separation of the salt crystals. The filtrate and the earlier the gained distillate are sent back to the repeated process. The technical result of the invention is simplification of the technology of the production process with utilization of the accessible raw.
The way to obtain diphenyl-(2-chlorophenyl)methane / 2180655
The invention relates to a method for producing diphenyl-(2-chlorophenyl)methane to synthesis of 1-(2-chlorophenyl)diphenylmethyl-1H-imidazole having antifungal activity
 The method of chemical recycling of polychlorinated biphenyls / 2175964
The invention relates to a method for the chemical treatment of polychlorinated biphenyls (PCBs) by the interaction of technical PCB General formula
 < / BR>where n+m=3-5, with polyethylene glycol (PEG) in the presence of potassium hydroxide and/or sodium in an open system at elevated temperatures  The way dechlorination substituted compounds chloroaromatics / 2152921
The invention relates to a method dechlorination substituted chloroaromatics compounds by the action of a reducing agent (zinc, magnesium or aluminum) and catalytic amounts generated in situ complex compounds of Nickel with bidentate nitrogen-containing ligands (2,2'-BIPYRIDILIUM or 1,10 - phenanthroline) in the bipolar solvent in the presence of a source of protons at a temperature of 70-150°C.
 The method of obtaining dichloro-di-p-xylylene / 2101272
The invention relates to organic chemistry, in particular the production of intermediate for the synthesis of poly-n-xylylene used for surface treatment of metal parts in electronics
 Method for the chemical treatment of polychlorinated biphenyls / 2087458
The invention relates to the field of organic chemistry, in particular to a method for the chemical treatment of polychlorinated biphenyls, which until recently was used in electrotechnical products as an insulating and heat transfer materials
 The way to obtain di(p-anisyl)-ideaware of halide / 2033990
The invention relates to the pharmaceutical industry, specifically to a method for producing di-(p-anisyl)-yedoniah halide of General formula
 H3CO I OCH Hal where Hal is Br, I
Method for ecologically pure synthesis of bromobenzene / 2321576
Invention relates to a method for ecologically pure synthesis of bromobenzene. Method involves substitution of one C-H-protons in benzene ring with hypobromous acid generated in situ by effect of mineral acid on a brominating agent comprising a mixture of sodium bromide and sodium bromate wherein this process is carried out at temperature 50-80°C under atmosphere pressure. Invention provides increasing yield of the end product and insignificant formation of polybromo-compounds and simple inorganic salts as by-side products.
Method for production of alkane, cycloalkane and arylalkane monobromoderivatives / 2282611
Claimed method includes reaction between corresponding hydrocarbons with tetra bromomethane at 150-180°C in liquid phase in presence of copper chloride or copper bromide complex with nitrogen-containing substance, wherein as nitrogen-containing substance amine of general formula Ph-CH(OH)-Q-NHR' is used. In formula: Q is group -CH(CH3)- or -(CH2)n, wherein n = 1-3; R' is lower alkyl.
 Connection for use as a binder for mineral fibers and method thereof / 2209203
The invention relates to a method for producing water-soluble resin, is suitable as a binder for mineral wool, by reacting a cyclic anhydride and alkanolamine at a molar ratio of anhydride and alkanolamine below about 2:1 at a temperature of from 20 to 100oSince, in the presence of water with the formation of a number of reaction products that form the components of the binder resin
The way dechlorination substituted compounds chloroaromatics / 2152921
The invention relates to a method dechlorination substituted chloroaromatics compounds by the action of a reducing agent (zinc, magnesium or aluminum) and catalytic amounts generated in situ complex compounds of Nickel with bidentate nitrogen-containing ligands (2,2'-BIPYRIDILIUM or 1,10 - phenanthroline) in the bipolar solvent in the presence of a source of protons at a temperature of 70-150°C.
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FIELD: chemistry. SUBSTANCE: as catalyst substituted iron phthalocyanines of general formula where R=[CH2N+(CH3)2CH2CH2OH]Cl-, L=(CH3)2NCH2CH2OH (I); R=[CH2N+(CH3)2CH2CH2N(CH3)2]Cl-, L=(CH3)2NCH2CH2N(CH3)2 (III);
EFFECT: simplification of technology of obtaining chlor-derivatives of aromatic hydrocarbons with good yield and quality of product. 2 cl, 19 ex
The invention relates to organic chemistry, in particular, it relates to substituted iron phthalocyanines (PcFe) and method of producing chlorinated aromatic hydrocarbons using these substituted PcFe as catalysts. Chlorinated aromatic hydrocarbons belong to an important class of intermediates of organic synthesis, which can be obtained by the action of the common environmentally harmful gloriously agents, such as chlorine, hypochlorites, chlorine Sulfuryl. In the natural environment they are formed under the action of H2About2and Cl-in the presence of chloroperoxidase. Some of chlorinated aromatic hydrocarbons possess biological activity and therefore are of interest for the pharmaceutical industry. Known substituted cationic phthalocyanines metals (Zn, Al) [RF Patent 2282646, SW 47/32, 27.08.2005,], which do not show catalytic activity in the process of obtaining chlorinated aromatic hydrocarbons by oxidative chlorination of a mixture of N2O2and HCl. The objective of the invention is the synthesis of such compounds of a number of substituted phthalocyanines metals that possess catalytic properties in the process of obtaining chlorinated aromatic hydrocarbons. To solve this problem were with nasirovna substituted PcFe the following structure:
where
These substituted PcFe get chlorotoluene α,α'-dichloromethylene ether unsubstituted PcFe and subsequent interaction octakis(chloromethyl)PcFe with various amines. A method of obtaining chlorinated aromatic hydrocarbons by oxidation of aromatic hydrocarbons by hydrogen peroxide in hydrochloric acid solution of 2,2,2-triptoreline, duration of response 15 h (Revital Ben-Daniel, Samuël P. Visser, Sason Shaik, Ronny Neumann. // J. Amer. Chem. Soc. 125 (2003) 12116-12117). The disadvantage of this method is the use of hard-to-solvent - triptoreline. The elimination of this disadvantage is provided in a known way by oxidative chlorination of substituted aromatic hydrocarbons with boiling methyl alcohol, duration of response of 6 h (Nivrutti Century Barbate, Anil S. Gajare, Radhika D. Wakharkar, Ashutosh V. Bedekar. // Tetrahedron Letters 39 (1998) 6349-6350) prototype. When using as the oxidant hydrogen peroxide, this method leads to the formation of only dichloropropionic (anisole, 1,4-dimethoxybenzene and N,N-dimethyl-(3,4,5-trimetoksi)benzamide). A significant disadvantage of this method is the low reaction rate, leading to a large long is a major process and holding it at an elevated temperature (boiling solvent). The objective of the invention is to increase the speed of the process and simplify technology. To achieve this task is carried out catalytic oxidative chlorination of aromatic hydrocarbons by hydrogen peroxide in the solution containing hydrochloric acid, using as catalysts the above derivatives of phthalocyanine iron. The reaction is carried out at a temperature of 20-25°C for 15-20 min, the solvent used lower aliphatic alcohols, water, or mixtures thereof. The following examples illustrate the invention. Example 1. Getting octakis(2-hydroxyethylaminomethyl)iron phthalocyanine. To 40 g of aluminum chloride added with stirring, 12 ml of triethylamine, and then at a temperature of 70-80°With 30 ml α,α' dichlorodifluoro ether and 3 g (0,00527 M) of iron phthalocyanine. The mixture is heated at a temperature of 90°With, then unload on the ice. The precipitate is filtered off, washed with water, methanol and dried. Output octakis(chloromethyl)phthalocyanine iron 2,63 g (52,1%). To 0.65 g (0,00068 mol) octakis(chloromethyl)phthalocyanine iron add 5 ml of 2-(dimethylamino)ethanol and heated the mixture at a temperature of 90°C. the Precipitate is filtered off, washed with acetone, periostat of methanol with acetone and dried. Obtain 0.52 g (46,0%) complex (I). E-the special is Tr absorption, λmax=673 nm (N2About). Found, %: Cl 15,07; N 13,40. Calculated for C80H134N18O10Cl8Fe %: Cl 15,35; N 13,64. Example 2. Getting octakis(pyridiniomethyl)iron phthalocyanine. To 0,49 g (0,00051 mol) octakis(chloromethyl)phthalocyanine iron add 5 ml of pyridine and heated the mixture at a temperature of 90°C. the Precipitate is filtered off, washed with acetone, periostat of methanol with acetone and dried. Get 0,43 g (53%) of the complex (II). Electronic spectrum, λmax=670 nm (H2O). Found, %: Cl 15,85; N 14,07. Calculated for C90H74N18Cl8Fe %: Cl 16,23; N 14,43. Example 3. Getting octakis(N-(2-dimethylamino)ethyl)-N,N-dimethyl-ammoniated)iron phthalocyanine. To 0.06 g (mol) octakis(chloromethyl)phthalocyanine iron add 1 ml of tetramethylethylenediamine and heat the mixture at a temperature of 80-90°C. the Precipitate is filtered off, washed with acetone, periostat of methanol with acetone and dried. Get 0.083 g (62.4 per cent) of complex (III). Electronic spectrum, λmax=670 nm H2O). Found, %: Cl 13,10; N 18,08. Calculated for C100H184N28Cl8Fe %: Cl 13,38; N 18,51. Example 4. Getting octakis(N-methylmorpholinium)iron phthalocyanine. To 0.1 g (mol) octakis(chloromethyl)phthalocyanine iron add 1 ml of methylmorpholine and heat the mixture at a temperature of 80-90°C. the Precipitate is filtered off, washed with acetone, pareos the support from methanol-acetone and dried. Obtain 0.14 g (63,6%) complex (IV). Electronic spectrum, λmax=670 nm (N2O). Found, %: Cl 14,08; N 12,59. Calculated for C90H134N18Cl8O10Fe %: Cl 14,4; N 12,82. Example 5. Obtain 1-chloro-2-methylnaphthalene. To 0.25 ml (0,148 M) solution of 2-methylnaphthalene in ethanol was added 1.65 ml of ethanol, 0.5 ml (2.25 M) hydrochloric acid solution and 0.05 ml (2,2·10-3M) aqueous solution PcFe (I). To the obtained mixture under stirring was added 0.05 ml (2.25 M) aqueous solution of N2About2. After 15-20 min spend HPLC-analysis of the oxidized reaction mixture (LC HP 1100 with UV detector, column bond Eclipse XDB-C8 4,6×1500 mm, 5 μm, eluent acetonitrile (60%)-water (40%), 1 ml/min, internal standard naphthalene). Output 1-chloro-2-methylnaphthalene 94%. Found, %: C 74,57; N, 5.22; Cl 20.07. C11H9Cl. Calculated, %: C 74,80; H 5.14; Cl 20.07. Mass spectrum, m/z: 167 [M+], 141 [M-Cl]+. The product is identical to that obtained by the known method with the SO2Cl2(A.Fozard, C.K.Bradsker // J. Org. Chem. 31 (1966) 3683-3685). Example 6. Obtain 1-chloro-2-methylnaphthalene. The reaction is carried out analogously to example 5 using 0,028 ml (2,2·10-3M) aqueous solution PcFe (I). Output 1-chloro-2-methylnaphthalene 80%. Example 7. Obtain 1-chloro-2-methylnaphthalene. The reaction is carried out analogously to example 5 using 0,17 ml (2,2·10-3M) aqueous solution PcFe (II) and methyl with the IRTA. Output 1-chloro-2-methylnaphthalene 95%. Example 8. Obtain 1-chloro-2-methylnaphthalene. The reaction is carried out analogously to example 5 using 0.1 ml (2,4·10-3M) aqueous solution PcFe (III) and isopropyl alcohol. Output 1-chloro-2-methylnaphthalene 97%. Example 9. Obtain 1-chloro-2-methylnaphthalene. The reaction is carried out analogously to example 5 using 0.6 ml (1,2·10-3M) aqueous solution PcFe (IV). Output 1-chloro-2-methylnaphthalene 80%. Example 10. Obtain 1-chloro-2-methoxynaphthalene. The reaction is carried out analogously to example 5 using 2-methoxynaphthalene and 0.05 ml (2,2·10-3M) aqueous solution PcFe (II). Output 1-chloro-2-methoxynaphthalene 99%. So pl. 65-66°C. Found, %: C 68,28; N. Of 4.44; Cl 18,10. C11H9ClO. Calculated, %: C 68,58; N 4,71; Cl Is 18.40. Mass spectrum, m/z: 192 [M+], 177 [M-CH3]+, 161 [M-och3]+. Example 11. Obtain 1-chloro-2,3-dimethylnaphthalene. The reaction is carried out analogously to example 5 using 2,3-dimethylnaphthalene and 0.1 ml (2,2·10-3M) aqueous solution PcFe (II). Output 1-chloro-2,3-dimethylnaphthalene 80%. Found, %: C 75,30; N 5,64; Cl Is 18.40. C12H11Cl. Calculated, %: C 75,59; N. Of 5.82; Cl 18,59. Mass spectrum, m/z: 190 [M+], 155 [M-Cl]+, 139 [M-Cl-CH3]+. Example 12. Obtaining 1,4-dichloro-2,3-dimethylnaphthalene. The reaction is carried out analogously to example 5 using 1-chloro-2,3-dimethylnaphthalene and 0.1 ml (2,2· 10-3M) aqueous solution PcFe (II). The yield of 1,4-dichloro-2,3-dimethylnaphthalene 95%. So pl. 152-153°C. Found, %: C 64,26; N 4,25; Cl 31,28. With12H10Cl2. Calculated, %: C 64,03; N 4,48; Cl 31,50. Mass spectrum, m/z: 224 [M+-1], 189 [M-Cl]+, 152 [M-2Cl-2]+, 139 [M-2Cl-CH3]+. Example 13. Obtain 1-chloro-2,6-dimethylnaphthalene. The reaction is carried out analogously to example 5 using 2,6-dimethylnaphthalene and 0.1 ml (2,2·10-3M) aqueous solution PcFe (II). Output 1-chloro-2,6-dimethylnaphthalene 99%. Found, %: C 75,66; N 6,10; Cl 18,85. C12H11Cl. Calculated, %: C 75,59; N. Of 5.82; Cl 18,59. Mass spectrum, m/z: 190 [M+]. Example 14. Obtaining 1,5-dichloro-2,6-dimethylnaphthalene. The reaction is carried out analogously to example 5 using 1-chloro-2,6-dimethylnaphthalene and 0.1 ml (2,2·10-3M) aqueous solution PcFe (II). The output of 1,5-dichloro-2,6-dimethylnaphthalene 95%. So pl. 133-134°C. Found, %: C 64,25; N 4,29; Cl 31,29. With12H10Cl2. Calculated, %: C 64,03; N 4,48; Cl 31,50. Mass spectrum, m/z: 224 [M+-1], 189 [M-Cl]+, 152 [M-2Cl-2]+, 139 [M-2Cl-CH3]+. Example 15. Getting 2-chloro-1-methoxybenzene and 4-chloro-1-methoxybenzene. The reaction is carried out analogously to example 5 using anisole and 0.1 ml (2,2·10-3M) aqueous solution PcFe (II). Get 2-chloro-1-methoxybenzyl and 4-chloro-1-methoxybenzo in the ratio of 1:3.3, the output of a mixture of 99%. The identical products obtained from the Irma "Aldrich". Example 16. Getting 2-chloro-1-methoxybenzene and 4-chloro-1-methoxybenzene. The reaction is carried out analogously to example 5 using anisole and 0.1 ml (2,4·10-3M) aqueous solution PcFe (III). Get 2-chloro-1-methoxybenzyl and 4-chloro-1-methoxybenzo in the ratio of 1:3, a mixture of 99%. Example 17. Getting 2-chloro-1-methoxybenzene and 4-chloro-1-methoxybenzene. The reaction is carried out analogously to example 5 using anisole and 0.6 ml (1,2·10-3M) aqueous solution PcFe (IV). Get 2-chloro-1-methoxybenzyl and 4-chloro-1-methoxybenzo in the ratio of 1:3, a mixture of 50%. Example 18. Getting 5-chloro-3,4-dimethoxytoluene. The reaction is carried out analogously to example 5 using 3,4-dimethoxytoluene and 0.05 ml (2,2·10-3M) aqueous solution PcFe (II). The yield of 2-chloro-3,4-dimethoxytoluene 99%. So pl. 33-34°C. Found, %: C 58,19; N 5,91; Cl 18,76. C11H9Cl. Calculated, %: C 57,92; N 5,94; Cl 19,0. Mass spectrum, m/z: 186 [M+], 171 [M-CH3]+, 143 [M-CH3-Och3+3]+, 93 [M-2CH3-Och3-Cl+3]+, 11 [M-CH3-ON3-Cl+3]+. Example 18. Getting 2-chloro-phenol and 4-chlorophenol. The reaction is carried out in aqueous solution as in example 5 using phenol, 0.1 ml of HCl solution (2.25 M) and 0.1 ml (2,2·10-3M) solution PcFe (II). Get 2-chlorophenol and 4-chlorophenol in the ratio of 1:1,15, yield 90%. Thus, pre the proposed substituted iron phthalocyanines are effective catalysts for the process of oxychlorination process of aromatic hydrocarbons, the way their application provides reception of chlorinated aromatic hydrocarbons with high speed (within 15-20 min; prototype - 6 h) in good yield and product quality. 1. Substituted iron phthalocyanines of General formula
where
2. A method of obtaining a chlorinated aromatic hydrocarbons by oxychlorination process of aromatic hydrocarbons with a mixture of hydrogen peroxide and hydrochloric acid in aqueous-alcoholic medium, wherein the process is carried out in the presence of substituted iron phthalocyanines according to claim 1 as a catalyst. 3. The method according to claim 2, characterized in that the catalyst and the source of the aromatic compound taken in a molar ratio of 1:100÷600.
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