Cosmetic agent for care and maintenance of natural hair function, containing 2-furanon derivative

FIELD: medicine; cosmetology.

SUBSTANCE: invention relates to the cosmetic agents, namely cosmetic agent for care and maintenance of the natural hair function; contains the routine cosmetic raw materials, differs in containing the 2-furanon derivative , at least one polymeric compound and at least one compound of protein hydrolysates and their derivatives.

EFFECT: invention efficiently maintains natural hair function.

6 cl, 32 ex, 1 dwg

 

This invention relates to cosmetic products containing certain derivatives of 2-furanone, in particular cosmetic products for the care and maintenance of natural functions of the hair, containing a derivative of 2-furanone at least one compound selected from polymers and at least one compound selected from protein hydrolysates and derivatives thereof.

Cosmetic products for the care and maintenance of natural hair functions are becoming increasingly important. This, among other things, contribute to changing consumer tastes and trends of fashion. So, for example, due to the high attendance tanning hair structure is under persistent harmful effects of UV radiation which is reflected, for example, in the form of loss of elasticity of hair.

Next, strenuous physical activity during leisure leads to frequent intensive wash your hair. Consequently, the fatty protective film, resulting from the continued operation of numerous sebaceous glands, severely damaged or disturbed the formation of transformation products of the sebaceous glands. The result is oily hair.

Development trends in fashion, including modern paint makeup, lipsticks and make and colouring agents for hair and means for Curling, in the case of sensitive skin and wounds the e-treated hair usually harm the natural condition of the hair. It is therefore not surprising that greatly increases the proportion of consumers with the hair difficult to comb, have lost their luster and elasticity, brittle and susceptible to loss.

Consequently, there is no shortage of attempts to eliminate these problems. To clean hair using mild surfactants to avoid additional stress on the hair. Using degreasing agents are trying to eliminate the formation of transformation products of the sebaceous glands during cleaning. UV-protective clothing and vitamins, for example vitamin E, should reduce the negative impact of UV-light. Protein hydrolysates are used to align the internal structure of the hair. Using extracts from plants and algae, for example, affect the moisture balance of the hair.

There is, however, a need for tools which are unwanted decrease of negative effects on the hair. Found that the use of derivatives of 2-furanone as active substances in cosmetic products has unexpectedly resulted in good condition treated hair, in particular, to the best of raschesyvaemost for improved Shine and elasticity.

The objective of the invention is the provision of cosmetics, able to care and maintain the natural functions of hair, is lastnosti to improve raschesyvaemost, Shine and elasticity treated hair.

The problem is solved cosmetic care for and maintain the natural functions of the hair, containing conventional cosmetic raw materials, due to the fact that it contains 2-pornoprovini formula (I)

in which the residues R1and R2mean independently from each other:

- -hydrogen, -HE, methyl-, methoxy-, aminomethyl or hydroclimatology the rest,

is saturated or unsaturated with 1 or 2 double bonds, branched or linear hydrocarbon residue with 2 to 4 carbon atoms,

is saturated or unsaturated with 1 or 2 double bonds, branched or linear mono-, di - or trihydroxyflavanone residue with 2 to 4 carbon atoms,

is saturated or unsaturated with 1 or 2 double bonds, branched or linear mono-, di - or triaminoguanidine residue with 2 to 4 carbon atoms,

group-OR11with R11in the form of saturated or unsaturated with 1 or 2 double bonds, branched or linear hydrocarbon residue with 2 to 4 carbon atoms, saturated or unsaturated with 1 or 2 double bonds, branched or linear mono-, di - or trihydroxyflavanone residue with 2 to 4 carbon atoms,

group-NR12R13while R12and R13respectively of the mean independently from each other hydrogen, methyl-, saturated or unsaturated with 1 or 2 double bonds, branched or linear hydrocarbon residue with 2 to 4 carbon atoms, saturated or unsaturated with 1 or 2 double bonds, branched or linear mono-, di - or trihydroxyflavanone residue with 2 to 4 carbon atoms,

group-COOR14while R14means hydrogen, methyl, saturated or unsaturated with 1 or 2 double bonds, branched or linear hydrocarbon residue with 2 to 4 carbon atoms, saturated or unsaturated with 1 or 2 double bonds, branched or linear mono-, di - or trihydroxyflavanone residue with 2 to 4 carbon atoms, saturated or unsaturated with 1 or 2 double bonds, branched or linear mono-, di - or triaminoguanidine residue with 2 to 4 carbon atoms,

group-COR16while R16means methyl, saturated or unsaturated with 1 or 2 double bonds, branched or linear hydrocarbon residue with 2 to 4 carbon atoms, saturated or unsaturated with 1 or 2 double bonds, branched or linear mono-, di - or trihydroxyflavanone residue with 2 to 4 carbon atoms, saturated or unsaturated with 1 or 2 double bonds, branched or linear mono-, di - or triaminoguanidine residue with 2 to 4 carbon atoms,

group-OCOR17when this is R 17means methyl, saturated and/or mono - or polyunsaturated branched or linear hydrocarbon residue with 2 to 30 carbon atoms, saturated and/or mono - or polyunsaturated branched or linear mono-, di-, tri - or polyhydroxyalkanoates balance with 2-30 carbon atoms, saturated and/or mono - or polyunsaturated branched or linear mono-, di-, tri - or polyaminopropyl balance with 2-30 carbon atoms;

the remains of R3and R4mean independently from each other:

- -HE-, methyl-, methoxy-, aminomethyl-, hydroxymethylene the rest,

is saturated or unsaturated with 1 or 2 double bonds, branched or linear hydrocarbon residue with 2 to 4 carbon atoms,

is saturated or unsaturated with 1 or 2 double bonds, branched or linear mono-, di - or trihydroxyflavanone residue with 2 to 4 carbon atoms,

is saturated or unsaturated with 1 or 2 double bonds, branched or linear mono-, di - or triaminoguanidine residue with 2 to 4 carbon atoms;

the remains of R5and R6mean independently from each other:

- hydrogen, -IT-, methyl-, methoxy-, aminomethyl-, hydroxymethylene the rest,

is saturated or unsaturated with 1 or 2 double bonds, branched or linear hydrocarbon residue with 2 to 4 carbon atoms,

- rich is whether unsaturated with 1 or 2 double bonds, branched or linear mono-, di - or trihydroxyflavanone residue with 2 to 4 carbon atoms,

is saturated or unsaturated with 1 or 2 double bonds, branched or linear mono-, di - or triaminoguanidine residue with 2 to 4 carbon atoms;

at least one compound selected from polymers; and

at least one compound selected from protein hydrolysates and derivatives thereof.

2-Furanones are known compounds and their preparation and use are described, for example, in "Römpps Lexikon Chemie, interactive CD-Rom, version 2.0", keywords dihydro-3-hydroxy-4,4-dimethyl-2(3H)-furanone"and "Ullman''s Encyclopedia, sixth edition, 1999, electronic version" in sections 2.4, 2.7, 3.2, 3.4, 4.6, 6, 11 and 15 and the publications cited therein. In this Chapter and the literature cited therein, specific reference. The compounds of formula (I) and formula (II) are used as intermediates in the synthesis of natural compounds, as well as upon receipt of medicines and vitamins. The active compounds of formulas (I) and (II)may be carried out, for example, through the interaction of primary alcohols with acrylic acid. Further, the compounds of formula (I) can be obtained by reactions on the basis of aldehyde hydroxypivalic acid. Similarly spend carbonylation of Alcina is to substituted 2-furanones of the formula (I) or (II). Finally, it is possible to obtain the compounds of formula (I) or formula (II) intramolecular esterification of the corresponding hydroxycarbonic acids. For example, one of the above-mentioned synthetic methods obtained the following compounds: 2,5-dihydro-5-methoxy-2-furanone, tetrahydro-5-oxo-francebuy acid, dihydro-3-hydroxy-4,4-dimethyl-2(3H)-furanone, or 3,4-dimethyl-5-inteligencija-2(5H)-furanone or 4 hidroxi-2,5-dimethyl-3(2H)-furanone. 2-Furanones according to this invention include, of course, all possible stereoisomers and their mixtures. 2-Furanones according to this invention do not attach a persistent odor cosmetic tool, so the tool should be separately the.

In the preferred form of the present invention uses a compound of formula (I), where the residues R1and R2mean independently from each other:

- hydrogen, -IT-, methyl-, methoxy-, aminomethyl-, hydroxymethylene the rest,

- - 2-C4is saturated or unsaturated with 1 or 2 double bonds, branched or linear mono-, di - or trihydroxyflavanone the rest,

group-OR11with R11as With2-C4is saturated or unsaturated with 1 or 2 double bonds, branched or linear hydrocarbon residue, -C2-C4is saturated or unsaturated with 1 of the 2 double bonds, branched or linear mono-, di - or trihydroxyflavanone balance,

group-COOR14while R14means hydrogen, methyl, -C2-C4is saturated or unsaturated with 1 or 2 double bonds, branched or linear hydrocarbon residue, -C2-C4is saturated or unsaturated with 1 or 2 double bonds, branched or linear mono-, di - or trihydroxyflavanone the rest,

group - COR16while R16means methyl, -C2-C4is saturated or unsaturated with 1 or 2 double bonds, branched or linear hydrocarbon residue, -C2-C4is saturated or unsaturated with 1 or 2 double bonds, branched or linear mono-, di - or trihydroxyflavanone the rest,

group-OCOR17while R17means methyl, -C2-C30- saturated and/or mono - or polyunsaturated branched or linear hydrocarbon residue, -C2-C30- saturated and/or mono - or polyunsaturated branched or linear mono-, di-, tri - or polyhydroxyalkanoates the rest.

Further, in this preferred form of execution of the present invention is preferred when in the compound of formula (I) residues R3and R4mean independently from each other:

- hydrogen, -IT-, methyl-,methoxy-, aminomethyl-, hydroxymethylene the rest,

- - 2-C4is saturated or unsaturated with 1 or 2 double bonds, branched or linear mono-, di - or trihydroxyflavanone the rest,

group-OR11with R11as With2-C4is saturated or unsaturated with 1 or 2 double bonds, branched or linear hydrocarbon residue, -C2-C4is saturated or unsaturated with 1 or 2 double bonds, branched or linear mono-, di - or trihydroxyflavanone balance,

group-COOR14while R14means hydrogen, methyl, -C2-C4is saturated or unsaturated with 1 or 2 double bonds, branched or linear hydrocarbon residue, -C2-C4is saturated or unsaturated with 1 or 2 double bonds, branched or linear mono-, di - or trihydroxyflavanone the rest,

group-OCOR17while R17means methyl, -C2-C30- saturated and/or mono - or polyunsaturated branched or linear hydrocarbon residue, -C2-C30- saturated and/or mono - or polyunsaturated branched or linear mono-, di-, tri - and/or polyhydroxyalkanoates the rest.

In this preferred form of execution of the present invention may be further preferred, when the residues R 5and R6in the compound of formula (I) denote, independently of one another:

- hydrogen, -IT-, methyl-, methoxy-, aminomethyl-, hydroxymethylene the rest,

- - 2-C4is saturated or unsaturated with 1 or 2 double bonds, branched or linear mono-, di - or trihydroxyflavanone the rest,

group-OR11with R11as With2-C4is saturated or unsaturated with 1 or 2 double bonds, branched or linear hydrocarbon residue, -C2-C4is saturated or unsaturated with 1 or 2 double bonds, branched or linear mono-, di - or trihydroxyflavanone balance.

In a particularly preferred form of the present invention, the compounds corresponding to formula (I), use dihydro-3-hydroxy-4,4-dimethyl-2(3H)-furanone.

The active compound of the formula (I) according to this invention is used in cosmetics in an amount of from 0.001 to 10 wt.%, counting means in General, preferably from 0.01 to 5 wt.%, and exceptionally preferably in quantities of from 0.05 to 3 wt.%.

Under the polymers in the sense of the present invention involve both natural and synthetic polymers, which can be anionic, cationic, charged amphoteric or non-ionic.

Under cationic polymers have in mind the polymerase is s, with in the main or side chain groups that can be "temporarily" or "permanently" cationic. As "permanently cationic" called according to this invention such polymers, which have a cationic group, regardless of the pH indicator means. As a rule, polymers containing Quaternary nitrogen atom, for example, in the form of an ammonium group. Preferred cationic groups are Quaternary ammonium groups. In particular, such polymers in which the Quaternary ammonium group is linked via C1-4is a hydrocarbon group to a polymer chain consisting of acrylic acid, methacrylic acid or derivatives thereof, are especially preferred.

The homopolymers of the General formula (III):

in which R18= -H or-CH3, -R19, R20and R21independently from each other selected from C1-4-alkyl, -alkylene or hydroxyalkyl, m=1, 2, 3 or 4, n is a natural number and X-- physiologically compatible organic or inorganic anion, and copolymers consisting mainly of Monomeric units shown in formula (III), and nonionic monomer units, are particularly preferred cationic polymers. Among these polymers preferred according to the invention are those, for to the which is at least one of the following conditions:

- R18means methyl group,

- R19, R20and R21mean metal group,

- m=2.

As physiologically compatible counterion X-discusses, for example, halogenation, sulfation, phosphation, methosulfate, and organic ions, namely lactate, citrate, tartrate and acutation. Preferred are halogenation, in particular chloride.

Especially preferred homopolymer is optionally crosslinked, poly(methacryloxypropyltrimethoxysilane)with the name of polica-emium-37 according to the INCI (international nomenclature of cosmetic ingredients)classification. Stitching may be performed if desired by using polyolefin unsaturated compounds such as divinylbenzene, tetraallyloxyethane, methylenebisacrylamide, dialiawah ether, polyetherpolyols ether or simple allyl ethers of sugars or derivatives of sugars, namely erythritol, pentaerythritol, arabitol, mannitol, sorbitol, sucrose or glucose. Methylenebisacrylamide is the preferred cross-linking agent.

The homopolymer is used preferably in the form of anhydrous polymer dispersion, the polymer of which shall be not less than 30 wt.%. Such polymer dispersions are commercially available under the name Calcare ® SC 9 (about 50% polymer part, further components: mineral oil (INCI-name: Mineral oil) and tridecyl-polyoxypropylene-polyoxyethylene ether (INCI-name: PPG-1-Trideceth-6) and Calcare® SC 96 (about 50% polymer part, other components: mixture of diesters of propylene glycol and a mixture of capril and capric acid (INCI-name: Propylene glycol is dicaprylate/dicaprate) and tridecyl-polyoxypropylene-polyoxyethylene ether (INCI-name: PPG-1-Trideceth-6).

Copolymers with monomer units according to formula (III) contain as nonionic Monomeric residues, preferably acrylamide, methacrylamide, C1-4-alkilany ester of acrylic acid and C1-4-alkilany methacrylic acid. Among these nonionic monomers are particularly preferred acrylamide. These copolymers, as described above homopolymers, can be made. According to this invention, the preferred copolymer is cross-linked acrylamide-methacryloxypropyltrimethoxysilane-copolymer. Such copolymers in which the monomers are represented in a mass ratio of about 20:80, available commercially in the form of a 50%polymer dispersion under the name Calcare® SC 92.

Other preferred cationic polymers are, for example, the following:

- and stereoselectivity derivatives of cellulose, commercially available under the name Celquat® and Polymer JR . Connection Celquat® N 100, Celquat® L 200 and Polymer JR® 400 are preferred stereoselectivity derivatives of cellulose,

- cationic alkylpolyglycoside according to the patent Germany 4413686,

- cationically honey, for example the commercial product Chanicut® 50,

cationic guar derivatives, namely commercially available products under the trademarks of Cosmedia® Guar and Jaguar®,

- polysiloxanes with Quaternary groups, such as the commercially available products Q2-7224 (manufacturer: Dow Corning; a stabilized three-methylselenocysteine), Dow Corning®929 emulsion (containing a hydroxyl -, amino-modified silicone which is also known as amirodemachio), SM-2059 (manufacturer: company General electric), SLM-55067 (manufacturer: company Wacker), as well as the Abil®-Quat 3270 and 3272 (manufacturer: Th. Goldschmidt; dictatorially the polydimethylsiloxane, Quaternium-80),

polymer dimethyldiallylammonium salts and their copolymers with esters and inorganic salts of acrylic acid and methacrylic acid. Commercially available products under the name Marquet ®100 (poly(dimethyldiallylammonium)) and Marquet ®550 (dimethyldiallylammonium-acrylamide copolymer) are examples of such cationic polymers,

copolymers of vinylpyrrolidone with Quaternary derivative di is alkylamino-kilakila and-methacrylate, as for example, Quaternary vinyl pyrrolidone-dimethylaminoethylmethacrylate-copolymer with diethylsulfate. Such compounds are called Rafkat® 734 and Rafkat ®755 are available for sale,

- vinyl pyrrolidone-vinylidenechloride copolymers are available under the names of Lovecat ® FC 370, FC 550, FC 905 and 552 NM,

- Quaternary polyvinyl alcohols,

and also known under the names of

- Polyquaternium 2,

- Polyquaternium 17,

- Polyquaternium 18 and

- Polyquaternium 27 polymers with Quaternary nitrogen atoms in the polymer chain.

As cationic polymers can be used as the polymers known under the names of Polyquaternium -24 (market product, for example, Quatre-soft ® 200 LM). Similarly used in accordance with this invention are copolymers of vinylpyrrolidone, commercially available as market ingredients: Copolymer 845 (manufacturer: ISP), Suffix® VC 713 (manufacturer: ISP), Rafkat® ASCP 1011, Rafkat® HS 110, Lovecat® 8155, Lovecat® MS 370.

Other in accordance with this invention, cationic polymers are the so-called "temporarily cationic" polymers. These polymers usually contain an amino group, which under certain pH indicators exists in the form of Quaternary ammonium groups and thus makes their cation. Preferred is Vlada, for example, chitosan and its derivatives, which are commercially available, for example, under the trade name of Hodgen® CMF, HYDAGEN® HCMF, Cutler® PC and Haolam® NB/101. Chitosan is diacetylpyridine chitin, which with varying degrees of diacetylmorphine and various degrees of decomposition (molecular weight) commercially available. Obtaining them are described, for example, in patent applications Germany 4440625 A1 and 19503465 A1.

Especially suitable chitosans have a degree of diacetylmorphine, at least 80%, and a molecular weight of from 5·105up to 5·106(g/mol).

To obtain compositions according to this invention the chitosan must be converted into the salt form. This is carried out by dissolving in dilute aqueous acids. As suitable acids such as mineral acids, for example hydrochloric acid, sulfuric acid and phosphoric acid, and organic acids, for example low molecular weight carboxylic acids, polycarboxylic acids, hydroxycarbonate acid. Next can also be used high molecular alkylsulfonate acid or alkylene acid or organophosphorus acids that are known as essential physiological compatibility. Suitable acids for transfer of chitosan into the salt form are, for example, acetic sour is a, glycolic acid, tartaric acid, malic acid, citric acid, lactic acid, 2-pyrrolidone-5-carboxylic acid, benzoic acid or salicylic acid. Preferably apply the low-molecular hydroxycarbonate acid, namely glycolic acid or lactic acid.

Under anionic polymers that can activate the action in accordance with this invention the active substances are anionic polymers having carboxylate and/or sulfonatophenyl. Examples of anionic monomers, which can be obtained such polymers are acrylic acid, methacrylic acid, crotonic acid, maleic acid anhydride and 2-acrylamide-2-methylpropanesulfonic acid. When this acid groups may fully or partially be in the form of salts of sodium, potassium, ammonium, mono - or triethanolamine. The preferred monomers are 2-acrylamide-2-methylpropanesulfonic acid and acrylic acid.

Especially high activity are anionic polymers, which contain as a mono - or co monomer of 2-acrylamide-2-methylpropane-sulfonic acid, while the sulfonic group may wholly or partially be in the form of salts of sodium, potassium, ammonium, mono - or triethanolamine.

Especially preferred is a homopolymer acrylamido-2-methylpropane-sulfonic acid, who, for example, is sold under the name Reotic® 11-80.

In the framework of this preferred form may be a copolymer obtained from at least one anionic monomer and at least one non-ionic monomer. As anionic monomers are referred to the above substances. Preferred non-ionic monomers are acrylamide, methacrylamide, ester of acrylic acid, methacrylic acid, vinyl pyrrolidone, simple and complex vinyl ethers.

Preferred anionic copolymers are copolymers of acrylic acid and acrylamide, and, in particular, copolymers of polyacrylamide with monomers containing sulfonic acid group. Particularly preferred anionic copolymer consists of 70 to 55 mol.% acrylamide and 30 to 45 mol.% 2-acrylamide-2-methylpropanesulfonic acid, with sulfonic groups are completely or partially in the form of salts of sodium, potassium, ammonium, mono - or triethanolamine. This copolymer can be crosslinked state, at the same time as cross-linking agents preferably used unsaturated polyolefin compounds, namely, tetraallyloxyethane, allilohreos, allintitle and methylene-bisacrylamide. This polymer contained in the commodity product Sepigel® 305 firm Sappig. Application is the connection, containing, along with the polymer components of the hydrocarbon mixture (C13-C14-ISO) and neinogennye emulsifier (Laureth-7), in the framework of the present invention is especially preferred.

Metriacanthosaurus-copolymer in the form connections with isohexadecane and Polysorbate-80, sold under the name Emulgel® 600, manifests according to this invention is particularly active.

Similarly, the preferred anionic homopolymers are unstitched and stitched polyacrylic acid. While the preferred cross-linking agents may be allyl ethers of pentaerythritol, sucrose and propylene. Such compounds are commercially available, e.g. under the trademark of Carbopol®.

Copolymers of maleic anhydride and methylvinylether ether, in particular blended, are also polymers containing dyes. Copolymer of maleic acid and methylvinylether ether, crosslinked 1,9-decadiene, presented for sale under the name of Stabiles® QM.

Further, as a polymer for improving the efficiency of the active substance according to this invention are used as components amphoteric polymers. Under the term amphoteric polymers are combined as polymers containing in the molecule of free amino groups and free-COOH or SO3N-group, sposobem the matter of the formation of internal salts, and bipolar polymers containing in the molecule Quaternary ammonium groups and-COO-or-SO3-group, and such polymers which contain-COOH or SO3N-group and Quaternary ammonium group.

The example used in accordance with this invention, the amphoteric polymer is a trademark acrylic resin called Infomer®, which is a copolymer of tert-butylmethacrylate, N-(1,1,3,3-TETRAMETHYLBUTYL)-acrylamide and two or more monomers from the group of acrylic acid, methacrylic acid and their esters.

Other used according to this invention the polymers are compounds named lined the patent application in the UK 2104091, tiled applications for European patents 47714, 217274, 283817 and posted in the patent application Germany 2817369.

Preferred amphoteric polymers are those polymers which consist essentially of:

a) monomers with Quaternary ammonium groups of the General formula (IV)

in which R22and R23mean independently from each other hydrogen or methyl group, and R24, R25and R26mean independently from each other alkyl groups with carbon atoms of 1 to 4, Z signifies NH-group or an oxygen atom, n Ravenclaw number from 2 to 5 and a (-)is the anion of an organic or inorganic acid, and

b) Monomeric carboxylic acids of General formula (V),

in which R27and R28are independent from each other hydrogen or methyl groups.

These compounds can be used according to this invention as such or in the form of salts, which are obtained by neutralization of polymerizate, such as alkalis. The details of obtaining these polymerizates are posted in the patent application Germany 3929973. Absolutely preferred are such polymerizate using the monomers of type (a), where R24, R26and R26are methyl groups, Z is an NH group and a(-)is a halide, mexicanhat or amoxicullin-ion; acrylamidoethyl-trimethyl-ammoniate is a particularly preferred monomer (a). As the monomer (b) preferably used are acrylic acid.

The tool in accordance with this invention in the third embodiment can contain further non-ionic polymers.

Suitable nonionic polymers are, for example:

- vinyl pyrrolidone/vinyl ester copolymers sold, for example, under the trademark of Loviscol® (BASF). Loviscol® VA 64 and Luvisol® VA 73, respectively vinylpyrrolidone is/vinyl acetate copolymers, are also preferred non-ionic polymers

- esters of cellulose, such as hydroxypropylcellulose, hydroxyethylcellulose and methylhydroxypropylcellulose sold, for example, under the trademarks of Culminal® and Benecel® (firm Aqualon),

- shellac,

and polyamides. Especially preferred are spherical polymer powders, the diameter of the primary particles of which is less than 1 μm. Such products on the basis of copolymers of polymethacrylate are commercially available, e.g. under the trademark Polytrap® Q5-6603 (manufactured by Dow Corning). Other polymer powders, for example, on the basis of polyamides (Nylon 6, Nylon 12) with a particle size of 2-10 microns (90%) and specific surface area of about 10 m2/g are commercially available under the market name Orgasol® 2002 DU NAT KOs (firm Atochem S.A., Paris). Other spherical polymer powders suitable for the purpose, corresponding to this invention, are, for example, polymethacrylates (Micropearl M) firm SAPPIG or Plastic powder A) firm NICCOLO, copolymers of styrene and divinylbenzene (Plastic powder FP) firm NICCOLO, polyethylene and polypropylene powders (ACCUREL EP 400) manufactured by AKZO, and silicone polymers (Silicone powder x2-1605) of the company Dow Corning or spherical powders of cellulose.

Polymers are used in accordance with this is obreteniyu tool, preferably in quantities from 0.01 to 10 wt.%, considering the vehicle as a whole. Amount of from 0.1 to 5 wt.%, in particular from 0.1 to 3 wt.%, are particularly preferred.

Protein hydrolysates in the sense of this invention are a mixture of products, which is obtained using acidic, basic or enzymatic catalytic cleavage of protein.

According to this invention can be used sources, both vegetable and animal origin.

Animal protein hydrolysates are, for example, protein hydrolysates elastin, collagen, keratin, silk and milk proteins, which may also be in the form of salts. Such products are sold, for example, under the trademarks Dahilan® (firms Cognis), Promos® (firm Interorgan), Kolhapure® (firms Cognis), Nutrilan® (firms Cognis), Gelita-Sol® (German gelatin factory Stoess & Co), Lexein® (firms Inolex) and Kerasol® (company Croda).

Preferred according to this invention is the use of protein hydrolysates of plant origin, for example, protein hydrolysates of soy, almond, rice, pea, potato and wheat. Such products are commercially available, for example, under the trademarks Gluadin® (firms Cognis), Diamine® (firms Diamalt), Lexein® (firms Inolex) and Kratein® (firms Cu is Yes).

Although the use of protein hydrolyzates as such is preferred, instead of them can be used, if necessary, other mixtures containing amino acids, or individual amino acids, such as arginine, lysine, histidine or pirraglia acid. You may also use derivatives of protein hydrolysates, for example, in the form of their condensation products with fatty acids. Such products are sold, for example, under the names Lampon® (firms Cognis), Gluadin® (firms Cognis), Lexein® (firms Inolex), Relastin® (company Croda) or Kratein® (company Croda).

Used according to this invention are also carinsurance protein hydrolysates, while the underlying protein hydrolyzate may belong to an animal, such as collagen, milk or keratin, the plants, such as wheat, maize, rice, potatoes, soy beans, or seafood, such as fish collagen or algae, or protein hydrolysates obtained biotechnology. Cationic derivatives underlying protein hydrolysates can be obtained from the corresponding proteins by chemical, in particular, alkaline or acidic hydrolysis, by enzymatic hydrolysis and/or a combination of both types of hydrolysis. Hydrolysis of proteins gives, as PR is usually protein hydrolysate with a molecular weight distribution from 100 Yes up to more than a few thousand Yes. Preferred such cationic protein hydrolysates, underlying which is the protein part has a molecular weight of from 100 to 25,000 Da, preferably from 250 to 5000 Da. Further, under cationic protein hydrolysates mean Quaternary amino acids and mixtures thereof. The quaternization of protein hydrolysates or amino acids is often carried out with the help of Quaternary ammonium salts, for example N,N-dimethyl-N-(n-alkyl)-N-(2-hydroxy-3-chloro-n-propyl)-ammoniagenes. Further, of the cationic protein hydrolysates can also be obtained and other derivatives. Typical examples of protein hydrolysates and derivatives are listed under the INCI-classification in the "International Cosmetic Ingredient Dictionary and Handbook" (seventeenth edition, 1997, the Association 1101 cosmetics, toiletries and fragrances, 17th street, new York, the kit 300, Washington, DC 20036-4702), and commercially available products: cocodimonium hydroxypropyl hydrolyzed collagen, cocodimonium hydroxypropyl hydrolyzed casein, cocodimonium hydroxypropyl hydrolyzed hair keratin, cocodimonium hydroxypropyl hydrolyzed keratin, cocodimonium hydroxypropyl hydrolyzed rice protein, cocodimonium guide is oksipropil hydrolyzed silk, cocodimonium hydroxypropyl hydrolyzed soy protein, cocodimonium hydroxypropyl hydrolyzed wheat protein, cocodimonium hydroxypropyl silk amino acids, hydroxypropyl arginine lauryl/ministerului ester HCI, hydroxypropyltrimonium gelatin, hydroxypropyltrimonium hydrolyzed casein, hydroxypropyltrimonium hydrolysed collagen, hydroxypropyltrimonium hydrolyzed protein waste cocoa beans, hydroxypropyltrimonium hydrolyzed keratin, hydroxypropyltrimonium hydrolyzed protein rice bran, hydroxypropyltrimonium hydrolyzed silk, hydroxypropyltrimonium hydrolyzed soy protein, hydroxypropyl hydrolyzed vegetable protein, hydroxypropyltrimonium hydrolyzed wheat protein, hydroxypropyltrimonium hydrolyzed wheat protein/selectivley, laurdimonium hydroxypropyl hydrolyzed soy protein, laurdimonium hydroxypropyl hydrolyzed wheat protein, laurdimonium hydroxypropyl hydrolyzed wheat protein/selectivley, laurdimonium hydroxypropyl hydrolyzed casein, laurdimonium hydroxypropyl hydrolyzed collagen, laurdimonium hydroxypropyl hydrolyzed keratin, laurdimonium the hydroxypropyl Hydrometerological, laurdimonium hydroxypropyl hydrolyzed soy protein, stationin hydroxypropyl hydrolyzed keratin, stationin hydroxypropyl hydrolyzed rice protein, stationin hydroxypropyl hydrolyzed silk, stationin hydroxypropyl hydrolyzed soy protein, stationin hydroxypropyl hydrolyzed vegetable protein, stationin hydroxypropyl hydrolyzed wheat protein, stationin hydroxypropyl hydrolyzed collagen, quaternium-76 hydrolyzed collagen, quaternium-79 hydrolyzed collagen, quaternium-79 hydrolyzed milk protein, quaternium-79 hydrolyzed silk, quaternium-79 hydrolyzed soy protein, quaternium-79 hydrolyzed wheat protein. Especially preferred are cationic protein hydrolysates and derivatives from vegetable raw materials.

In applied according to this invention means a protein hydrolysates and derivatives thereof are contained in amounts of from 0.01 to 10 wt.%, considering the vehicle as a whole. Amount of from 0.1 to 5 wt.%, in particular from 0.1 to 3 wt.%, are particularly preferred.

In another preferred form of execution the tool according to this invention contains a surfactant. Under the concept of surfactant refers to a surfactant, comorienne in the molecule anionic or cationic charge. Similarly, the molecule can be present as anionic and cationic charge. These bipolar or amphoteric surfactants also according to this invention can be used. Further, the surfactant can be nonionic.

As the anionic surfactants usable in the compositions according to the invention, anionic surfactants suitable for use on the human body. They are characterized by the presence of anionic groups, making them water-soluble, such as carboxylate, sulfate, sulfonate or fosfato and lipophilic alkyl groups with carbon atoms of 8 to 30. Additionally, the molecule may contain glycol or polyglycolether groups, ester, ether and amide groups, and hydroxyl groups. Examples of suitable anionic surfactants are the surfactants in the form of sodium, potassium and ammonium salts, and mono-, di - and trialkanolamines salts with the number of carbon atoms in alkanones group from 2 to 4

linear and branched fatty acids with the number of carbon atoms from 8 to 30 (soap),

- Abercrombie acid of the formula R-O-(CH2-CH2O)x-CH2-COOH, in which R is a linear alkyl group with the number of carbon atoms from 8 to 30, and x=0 or 1 to 16,

- acylcarnitine with the number of carbon atoms is in the acyl group of 8 to 24,

- aculture with the number of carbon atoms in the acyl group of 8 to 24,

- arylisocyanate with the number of carbon atoms in the acyl group of 8 to 24,

mono - and dialkyl ethers sulfonterol acid with the number of carbon atoms in the alkyl group is from 8 to 24 and mono-alkylpolyoxyethylene ether sulfonterol acid with the number of carbon atoms in the alkyl group is from 8 to 24 and the number oxyethylene groups from 1 to 6,

- linear alkanesulfonyl with the number of carbon atoms from 8 to 24,

linear alpha reincorporate with the number of carbon atoms from 8 to 24,

methyl esters of alpha-califoirnia acids from fatty acids with the number of carbon atoms from 8 to 30,

the alkyl sulphates and sulfates alkylpolyglycoside esters of the formula R-O-(CH2-CH2O)x-OSO3H, in which R is a preferably linear alkyl group with the number of carbon atoms from 8 to 30, and x=0 or from 1 to 12,

- a mixture of surface-active hydroxysulphate according to the patent application Germany And 3725030,

- sulfated hydroxyalkylated and/or hydroxyethylpyrrolidine esters according to the patent application Germany And 3723354,

- sulfonates of unsaturated fatty acids with the number of carbon atoms from 8 to 24 and the number of double bonds from 1 to 6 according to the patent application Germany And 3926344,

- ester of tartaric acid and citric acid with alcohols, which represent aboutproduct accession about 2-15 molecules of ethylene oxide and/or propylene oxide to fatty alcohols with a number of carbon atoms from 8 to 22,

- alkyl - and/or altneratively formula (VI)

in which R29means aliphatic hydrocarbon residue with the number of carbon atoms from 8 to 30, R30means hydrogen, the remainder R29(Och2CH2)nor X, n denotes numbers from 1 to 10 and X is hydrogen, alkali or alkaline-earth metal or NR31R32R33R34with R31-R34meaning independently of each1-4-hydrocarbon residues, sulfated alkalophilicity the fatty acid ester of the formula (VII)

in which R35CO - means linear or branched, aliphatic, saturated and/or unsaturated acyl residue with the number of carbon atoms from 6 to 22, Alk denotes CH2CH2, SNSN3CH2and/or CH2SNSN3n denotes a number from 0.5 to 5 and M stands for a cation, as described in the patent application Germany 19736906.5,

- monoglycerides and monoglycerides formula (VIII),

- which R36CO means a linear or branched acyl residue with the number of carbon atoms from 6 to 22, x, y and z in the sum of mean 0 or numbers from 1 to 30, preferably from 2 to 10, X is an alkaline or alkaline-earth metal. Typical examples in accordance with this image is taneem suitable mono-glycerides(ether)sulfates are the products of interaction of monoglyceride lauric acid, monoglyceride coconut acid, monoglyceride palmitic acid, monoglyceride stearic acid, monoglyceride oleic acid and monoglyceride fatty acids fats and products of their accession to the ethylene oxide with sulfur trioxide or chlorosulfonic acid in the form of their sodium salts. Preferably use monoglycerides formula (VIII)in which R36CO means a linear acyl residue with the number of carbon atoms from 8 to 18. Monoglycerides and monoglycerides described, for example, applications for European patents 0561825, 0561999, the patent application Germany 4204700 or in publications A.K.Bismas and others in J.Am.Oil.Chem.Soc., VIP, str (1990) and F.U.Ahmed in J.Am.Oil.Chem.Soc., VIP, p.8 (1990).

Preferred anionic surfactants are the alkyl sulphates, alkylphenolethoxylate and Abercrombie acid with the number of carbon atoms in the alkyl group of 10 to 18 and up to 12 glycolether groups in the molecule, as well as mono - and dialkyl ethers sulfonterol acid with the number of carbon atoms in the alkyl group is from 8 to 18 and monoacylglycerol esters sulfonterol acid with the number of carbon atoms in the alkyl group is from 8 to 18 and the number of hydroxyethyl groups from 1 to 6.

As zwitterionic surfactants are those surface-active compounds which contain in the molecule at least one chetverin the Yu ammonium group or at least one - COO(-)or-SO3-group. Particularly suitable zwitterionic surfactants are the so-called betaines, namely N-alkyl-N,N-dimethylammonio-glycinate, such as cocoalkyl-dimethylammonium-glycinate, N-acyl-aminopropyl-N,N-dimethylammonio-glycinate, such as chocolatiere-dimethyl-amineptine, and 2-alkyl-3-carboxymethyl-3-hydroxymethylimidazole accordingly with the number of carbon atoms in the alkyl or aryl groups of from 8 to 18, and chocolatechipcookierecipe. Preferred zwitterionic surfactant is omeprozole fatty acids, known by the INCI-classification as cocamidopropyl betaine.

Under apoliticism surfactant understand such surface-active substances which contain in the molecule in addition to the alkyl or aryl groups with the number of carbon atoms from 8 to 24 at least one free amino group and at least one - COOH - or - SO3N-group, which makes possible the formation of an internal salt. Examples of suitable impolitically surfactants are N-allylglycine, N-alkylphosphonate acid, N-acylaminoalkyl acid, N-alkyl-imino-dipropionate acid, N-hydroxyethyl-N-alkylamidoamines, N-alkyltin, N-alkylaromatic, 2-alkylenediamine acid and alkylaminocarbonyl acid, respectively, with the number of carbon atoms is kind alkyl groups of from 8 to 24. Particularly preferred apoliticism surfactants are N-cocoalkylamine, chocolateeeeeeeeeeeeeee and C12-C18-acylcarnitine.

Nonionic surfactants contain as a hydrophilic group, for example, polyol as one group, a group of simple polyalkyleneglycol ether, or a combination of polyglycolic and polyglycolether groups. Such soedineniya, for example, are:

- addition products of 2 to 50 moles of ethylene oxide and/or 0 to 5 moles of propylene oxide to linear and branched fatty alcohols with a number of carbon atoms from 8 to 30, to fatty acids with the number of carbon atoms from 8 to 30 and to alkyl phenols with the number of carbon atoms in the alkyl group is from 8 to 15,

- addition products of 2 to 50 moles of ethylene oxide and/or 0 to 5 moles of propylene oxide to linear and branched fatty alcohols with a number of carbon atoms from 8 to 30, to fatty acids with the number of carbon atoms from 8 to 30 and to alkyl phenols with the number of carbon atoms in the alkyl group is from 8 to 15, with terminal groups, closed methyl - or2-C6-alkyl residues, such as, for example, commercially available products under the trade names Digidol® LS, Digital® LT (company Cognis),

- mono - and diesters With12-C30fatty acids and products of accession from 1 to 30 moles of ethylene oxide to glycerin,

products Pris the unity of from 5 to 60 moles of ethylene oxide to castor oil and otverzhdennom castor oil,

- esters poliklinik acids, as, for example, the commercial product of HYDAGEN® HSP (company Cognis) or products Sovermol-type (firm Cognis),

- alkoxysilane triglycerides,

- alkoxysilane alkylamine fatty acids of the formula (IX),

in which R37CO means a linear or branched, saturated and/or unsaturated acyl residue with the number of carbon atoms from 6 to 22, R38means hydrogen or methyl, R39means a linear or branched alkyl residue with the number of carbon atoms from 1 to 4, and w stands for numbers from 1 to 20,

- aminoxide,

- mixed hydroxyether described, for example, in the patent application Germany 19738866,

- esters sorbitan and fatty acids and addition products of ethylene oxide to esters sorbitan and fatty acids, as for example, Polysorbate,

- esters of sugar and of fatty acids and addition products of ethylene oxide to esters of sugar and of fatty acids,

- addition products of ethylene oxide to alkanolamide fatty acids and fatty amines,

- N-Alkylglucoside fatty acids,

- alkylpolyglycoside corresponding to the General formula RO-(Z)xwhile R means alkyl, Z means sugar and x means the number of units of sugar. Used according to this invention alkylpolyglycoside can contain only l is nil specific alkyl residue R. Usually these connections receive, based on natural fats and oils or mineral oils. In this case, the alkyl residue R is a mixture of the corresponding starting compounds or the corresponding processed products of these compounds.

Particularly preferred such alkylpolyglycoside, in which R consists mainly of:

- C8- and10-alkyl groups,

- C12- and14-alkyl groups,

- C8- and16is an alkyl group or

- C12- and16is an alkyl group or

- C16and C18-alkyl groups.

As a structural element of sugar Z can be any mono - or oligosaccharides. Commonly used sugar with 5 or 6 carbon atoms, and the corresponding oligosaccharides. This sugar is, for example, glucose, fructose, galactose, arabinose, ribose, xylose, Lukasa, allose, altrose, mannose, gulose, idose, talose and sucrose. Preferred sugar structural elements are glucose, fructose, galactose, arabinose and sucrose.

Used according to this invention alkylpolyglycoside contain in the interval from 1.1 to 5 sugar structural elements. Preferred are alkylpolyglycoside with the x-value of from 1.1 to 2.0. Absolutely are preferred Alkylglucoside in which sostavljaet from 1.1 to 1.8.

Can also be used according to this invention alkoxysilane homologues named alkylpolyglycoside. These homologues can contain on average up to 10 ethylene oxide and/or propylenoxide units per unit Alkylglucoside.

The preferred nonionic surfactants are the addition products alkalisation to saturated linear fatty alcohols and fatty acids, respectively from 2 to 30 moles of ethylene oxide per mole of fatty alcohol or fatty acid. Similarly receive composition with excellent properties, when a nonionic surfactant is used, the ester of fatty acid and ethoxylated glycerin.

These compounds are characterized by the following parameters. The alkyl residue R contains from 6 to 22 carbon atoms and may be linear or branched. Preferred are primary, linear and has a 2-position methyl branching aliphatic residues. Such alkyl residues are, for example, 1-octyl, 1-decyl, 1-lauryl, 1-myristyl, 1-cetyl and 1-stearyl. Particularly preferred 1-octyl, 1-decyl, 1-lauryl, 1-myristyl. When applying the so-called "oxo-alcohols as starting substances is dominated by compounds with an odd number of carbon atoms in the alkyl chain.

Regarding the compounds used as the surfactant, it could be the line is the result about homogeneous substances. However, as a rule, it is preferable to use these substances come from vegetable or animal raw materials, so that you get a mixture of substances with different due to raw data, the lengths of the alkyl chains.

In the case of surfactants, representing the addition products of ethylene - and/or propylenoxide to fatty alcohols or derivatives of these accession, can be used as products with a "normal" distribution of homologues, and products with a narrow distribution of homologues. Under "normal" distribution of homologues see a mixture of homologues, which is obtained by the interaction of fatty alcohol and accelerated when using alkali metals, alkali or alkali metal alcoholate as a catalyst. A narrower distribution of homologues compared to this gain, when applied, for example hydrotalcite, salts of alkaline-earth metals aircarbon acids, oxides, hydroxide or alcoholate of alkaline-earth metals. The application of products with a narrow distribution of homologues may be preferable.

These surfactants are used in quantities of from 0.1 to 45 wt.%, preferably from 1 to 30 wt.% and quite preferably from 1 to 15%, considering the vehicle as a whole.

In the preferred form of the preferred implementation can be non-ionic, zwitterionic and/or amp is characteristic of surfactants, as well as mixtures thereof.

According to this invention are also cationic surfactants of the type of Quaternary ammonium compounds, exterkate and amidoamine. Preferred Quaternary ammonium compounds are ammoniaand, in particular chlorides and bromides, namely alkyltrimethylammonium, diallyldimethylammoniumchloride and trialkylamine, such as cetyltrimethylammoniumbromide, steartrimonium, distearyldimethylammonium, lauryldimethylamine, lauryldimethylamine and triethylmethylammonium, and imidazole compounds known by the INCI-classification as Quaternium-27 and Quaternium-83. The long alkyl chains of the above-mentioned surfactants preferably contain from 10 to 18 carbon atoms.

Exterkate are known substances which as structural elements contain at least one ester function and at least one Quaternary ammonium group. The preferred exterkate are Quaternary salts of esters of fatty acids with triethanolamine, Quaternary salts of esters of fatty acids with diethanolamine and Quaternary salts of esters of fatty acids with 1,2-dihydroxyphenylalanine. Such products are sold under the trademarks Stepanek®, DEHYQUART® and Armoir® . Products Armoir® VGH-70, an N,N-bis(2-palmitoleate)dimethylammonio-chloride, and DEHYQUART® F-75, DEHYQUART® C-4046, DEHYQUART® L80 and DEHYQUART® AU-35 are examples of such exterkate.

Alkylamidoamines usually get by amidation of natural or sinteticnih fatty acids and fragments of fatty acids dialkylaminoalkyl. Particularly suitable according to the invention the connection of this group of substances is stearamidopropyl-dimethylamine, commercially available under the name Agamid® S 18.

Cationic surfactants are contained in the applicable according to this invention the tool in quantities from 0.05 to 10 wt.%, considering the vehicle as a whole. Amount of from 0.1 to 5 wt.% are particularly preferred.

In another preferred form of execution of the effectiveness of the active substances according to the invention is promoted by using emulsifiers. Such emulsifiers are, for example:

- addition products of 4 to 30 moles of ethylene oxide and/or 0 to 5 moles of propylene oxide to linear fatty alcohols with a number of carbon atoms from 8 to 22, to fatty acids with the number of carbon atoms from 12 to 22 and to alkyl phenols with the number of carbon atoms in the alkyl groups of from 8 to 15,

- mono - and diesters With12-C22fatty acids and products of accession from 1 to 30 moles of ethyleneoxide the polyol with the number of carbon atoms from 3 to 6, in particular glycerin,

- addition products of ethylene oxide and polyglycerol to the esters methylglucoside acids, alkanolamides fatty acids and glutamicum fatty acids,

- C8-C22-alkylene - and-oligoglycosides and their ethoxylated analogs, the degree of oligomerization ranging from 1.1 to 5, in particular 1.2 to 2.0, and glucose as the sugar component are preferred

- mixtures of alkyl(oligo)glycosides and fatty alcohols, for example a commercially available product Montanov® 68,

- addition products of 5 to 60 moles of ethylene oxide to castor oil and otverzhdennom castor oil,

- poloviny polyols with number of carbon atoms from 3 to 6 and saturated fatty acids with the number of carbon atoms from 8 to 22,

- sterols, which are a group of steroids bearing a hydroxyl group at the third C-atom of the steroid skeleton, and which can be isolated both from animal tissue (tosterone)and from vegetable fats (phytosterols). Examples of sooteriou are cholesterol and lanosterol. Examples of suitable phytosterols are ergosterol, stigmasterol and sitosterol. From fungi and yeasts also produce sterols called nicoteine,

- phospholipids. Under this name first mean glucose phospholipids, which are known as, for example, lecithin is or phosphatidylcholines from, for example, egg yolk or plant seeds (e.g., soybeans),

- esters of fatty acids with sugars or sugar alcohols, namely sorbitol,

- polyglycine and derivatives of polyglycerol, such as polyglyceryl-12-hydroxystearate (commodity product Dehymuls® PGPH),

linear and branched fatty acids with the number of carbon atoms from 8 to 30 and their Na-, K-, ammonium-, CA-, Mg - and Zn-salts.

According to this invention the tool includes an emulsifier in amounts of from 0.1 to 25 wt.%, in particular from 0.5 to 15 wt.%, considering the vehicle as a whole.

Preferably the compositions according to the invention can contain at least one nonionic emulsifier with products HLB-indicator (indicator hydrophilic-lipophilic balance) of from 8 to 18, according to Römpp-Lexikon Chemie (Hrg.J.Falbe, M.Regitz), issue 10, Georg Thieme publishing house Stuttgart, new York (1977), str. Nonionic emulsifiers with products HLB-indicator 10 to 15 are particularly preferred according to the invention.

Among these types of emulsifiers are particularly preferred emulsifiers, not containing in the molecule with ethylene oxide and/or propylene oxide.

In another preferred form of execution of the invention the effect of the active substance according to this invention further optimized with fatty substances. Under fatty substances should pony is the substance of fatty acids, fatty alcohols, natural and synthetic waxes, which are both in solid and in liquid form can exist in water dispersion, and natural and synthetic cosmetic oil components.

As fatty acids can be used in linear and/or branched, saturated and/or unsaturated fatty acids with carbon atoms of 6 to 30. Preferred are fatty acids with the number of carbon atoms from 10 to 22. Among them are, for example, to call isostearamide acid, for example the commercial product Emerson® 871 and Emerson® 875, and isopoliteia acid as commercial products called Edenor® 95 IP, and all other fatty acids, sold under the trademarks of Edenor® (company Cognis). Other typical examples of such fatty acids are Caproic acid, Caprylic acid, 2-ethylhexanoate acid, capric acid, lauric acid, isotridecanol acid, myristic acid, palmitic acid, palmitoleic acid, stearic acid, ezoterikova acid, oleic acid, elaidic acid, Petroselinum acid, linoleic acid, linolenic acid, aleocharinae acid, arahidonova acid, gadolinia acid, Bekenova acid and erucic acid and technical mixtures, which are obtained when rassal the NII under the pressure of natural fats and oils, the oxidation of the aldehydes obtained by oxosynthesis Relena, or the dimerization of unsaturated fatty acids. Particularly preferred are usually commercially available fragments of fatty acids from coconut or palm oils; in particular, it is preferable to use, as a rule, stearic acid.

The amount used amount from 0.1 to 15 wt.%, considering the vehicle as a whole. In a preferred form of execution, the amount is from 0.5 to 10 wt.%, especially preferred amount is from 1 to 5 wt.%.

As fatty alcohols can be used saturated, unsaturated with 1 or more double bonds, branched or unbranched fatty alcohols with C6-C30preferably With10-C22and particularly preferably C12-C22-carbon atoms. Used according to the invention are, for example, decanol, octanol, octenol, dodecanol, decanol, octadecanol, dodecadienol, decadienal, alerby alcohol, arcaloy alcohol, retinology alcohol, stearyl alcohol, isostearoyl alcohol, cetyl alcohol, lauric alcohol, ministerului alcohol, arachidonoyl alcohol, Caprylic alcohol, capric alcohol, linalilovy alcohol, linolenic alcohol and beganovic alcohol and hubertovy alcohols, and this listing is exemplary and should not be limiting in nature. However, the fatty alcohols preferably choose accordingly natural fatty acids, usually getting their conduct recovery of fatty acid esters. Used according to this invention are also such fragments of fatty alcohols, which are obtained by recovery of triglycerides of natural origin such as beef fat, palm oil, peanut oil, rapeseed oil, cottonseed oil, soybean oil, sunflower oil and linseed oil or recovery of fatty acid esters derived from their products interesterification corresponding alcohols and, thus, represents a mixture of different fatty alcohols. Such products have proliferated in the market under the names of Steel®such as Steel® 1618 or Lanette®for example, Lanett® or Lorol®such as Lorol® C8, Lorol® C14, Lorol® C18, Lorol® C8-18, HD-Ocenol®, Crodacol®such as Crodacol® CS, NOVOL®Eutanol® G, Guernica® 16, Guernica® 18, Guernica® 20, Isofol® 12, Isofol® 16, Isofol® 24, Isofol® 36, Isocarb® 12, Isocarb® 16 or Isocarb® 24. Of course can also be used according to this invention, the alcohols of the wax coat, which became widespread in the market under the names of Crown®white Swan®, Coronet® or Fluelen®. Fatty alcohols are used in amounts from 0.1 to 20 wt.%, considering the product processing in General, preferably in quantities of from 0.1 to 10 wt.%.

As natural or synthetic waxes may according to the invention be used paraffin waxes, or ISO, Carnauba wax, beeswax, candelilla wax, ozokerite, ceresin, spermaceti, sunflower wax, fruit wax, as, for example, Apple wax or citrus wax, microvasc of polyethylene or polypropylene. These types of wax, for example, are produced in the selling firm Feces & Co., Trittau.

Natural and synthetic cosmetic oil, which according to this invention can enhance the action of biologically active substances, for example, include:

- vegetable oil. Examples of such oils are sunflower oil, olive oil, soybean oil, rapeseed oil, almond oil, jojoba oil, orange oil, wheat oil, stone fruit oil and the liquid part coconut oil. Suitable are also other triglyceride oils, such as liquid portion of beef fat, and synthetic oils, triglycerides,

liquid paraffin oils, isoparaffin oils and synthetic hydrocarbons, and simple di-n-alkylamine containing generally from 12 to 36 atoms is of Pereda, in particular from 12 to 24 carbon atoms, such as di-n-oktilovom ether, di-n-decroly ether, di-n-nonlevy ether, di-n-undecyloxy ether, di-n-dodecyloxy ether, n-hexyl-n-oktilovom ether, n-octyl-n-decroly ether, n-decyl-n-undecyloxy ether, n-undecyl-n-dodecyloxy ether and n-hexyl-n-undecyloxy ether, and di-tert-butyl ether, di-ISO-pentalogy ether, di-3-ethyl-decroly ether, tert-butyl-n-oktilovom ether, ISO-pentyl-n-oktilovom ether and 2-methyl-pentyl-n-oktilovom ether. Commercially available as commercial products of the compound 1,3-di-(2-ethyl-hexyl)-cyclohexane (Cetiol® S) and di-n-oktilovom ether (Cetiol® OE) may be preferred,

- ester oils, which are the esters With6-C12fatty acids with C2-C30fatty alcohols. Preferred monetary fatty acids with alcohols with the number of carbon atoms from 2 to 24. Examples of fatty acids that are included in the acid component of the esters are Caproic acid, Caprylic acid, 2-ethylhexanoate acid, capric acid, lauric acid, isotridecanol acid, myristic acid, palmitic acid, palmitoleic acid, stearic acid, ezoterikova acid, oleic acid, elaidic acid, Petroselinum acid, linoleic acid, linolenic acid, aleocharinae acids is, arahidonova acid, gadolinia acid, Bekenova acid and erucic acid and technical mixtures which are obtained, for example, by splitting under the pressure of natural fats and oils, the oxidation of the aldehydes obtained by oxosynthesis Roelen, or the dimerization of unsaturated fatty acids. Examples of fatty alcohols included in the alcohol component of the ester oils are isopropyl alcohol, Caproic alcohol, Caprylic alcohol, 2-ethylhexyloxy alcohol, capric alcohol, lauric alcohol, isotridecyl alcohol, ministerului alcohol, cetyl alcohol, Palmolive alcohol, stearyl alcohol, isostearoyl alcohol, alerby alcohol, laidlawii alcohol, petroselinic alcohol, linalilovy alcohol, linalilovy alcohol, beasteallty alcohol, archelogy alcohol, galolery alcohol, beganovic alcohol, aracelly alcohol and passively alcohol and the technical mixtures obtained, for example, when the hydrogenation under high pressure technical methyl esters based on fats and oils or aldehydes obtained by oxosynthesis Roelen, and as monomer fraction in the dimerization of unsaturated fatty alcohols. According to this invention, the most preferred are isopropylmyristate (Ilanit® IPM), isononanoate-C16-C18-alkilany ether (Cetiol ® SN), 2-ating xmlparent (Cegesoft® 24), 2-ethylhexyloxy ester of stearic acid (Cetiol ® 868), atilola, hyperirritability, caucasionizer-karinat/kalimat (Cetiol ® LC), n-butilstearat, realroot (Cetiol ® J 600), isopropyl (Ilanit® IPP), aerolef (Cetiol ®), hexyl ester of lauric acid (Cetiol ® A), di-n-butylacetat (Cetiol ®), myristoleate (Cetiol ® MM), clearlistener (Cetiol ® SN), decroly ester of oleic acid (Cetiol ® V),

- esters of dicarboxylic acids, such as di-n-butylacetat, di(2-ethylhexyl)adipate, di(2-ethylhexyl)succinate and di-isotridecyl, as well as esters of diodes, such as etilenglikolevye, ethylene glycol di isotridecanol, propylene glycol di(2-ethylhexanoate), propylene glycol di isostearate, propylene glycol di pelargonate, butanediol di isostearate, neopentyl-glycol-di-kaprilat,

- symmetrical, asymmetrical or cyclic esters of carbonic acid with fatty alcohols, for example, described in patent application Germany 19756454 clearinterval or disabilitant (Cetiol ® SS)

- mono-, di - and tri-esters of saturated and/or unsaturated linear and/or branched fatty acids with glycerol, such as Monomers® 90-18O, Monomers® 90-L12 or cutin® MD.

The amount used is from 0.1 to 50 wt.%, considered the traveler on the tool as a whole, preferably from 0.1 to 20 wt.% and particularly preferably from 0.1 to 15 wt.%, considering the vehicle as a whole.

The total number of oil and fat components in the tool according to this invention is usually from 6 to 45 wt.%, considering the vehicle as a whole. Number from 10 to 35 wt.% are preferred in accordance with this invention.

Further, it was found that the effect of the active substances according to the invention can be amplified, if you combine it with esters hydroxycarbonic acids. Preferred esters hydroxycarbonic acids are full esters of glycolic acid, lactic acid, malic acid, tartaric acid or citric acid. Other in principle suitable esters hydroxycarbonic acids are esters β-hydroxypropionic acid, Castronovo acid, D-gluconic acid, sugar acids, mucus acid, or glucuronic acid. As the alcohol component of these esters suitable primary, linear and branched aliphatic alcohols with the number of carbon atoms from 8 to 22, i.e., for example, fatty alcohols or synthetic fatty alcohols. It is particularly preferred esters With12-C15fatty alcohols. Ethers of this type are commercially available under the trade mark Comsol® firm Enichem, Augusta Ingest the ial group. The amount of ether hydroxycarbonate acid is from 0.1 to 15 wt.%, counting means in General, preferably from 0.1 to 10 wt.% and quite preferably from 0.1 to 5 wt.%.

Similarly, are the best combination of active substances with vitamins, provitamins and vitamin precursor, as well as their derivatives.

According to this invention are preferred such vitamins, provitamins and their predecessors, who usually belong to groups a, b, C, E, F and H.

To the group of substances referred to in vitamin a include retinol (vitamin A1), a 3,4-delegitimation (vitamin a2). β-carotene is the provitamin of retinol. As components of the vitamin a treated according to this invention, for example, vitamin a acid and its ester, vitamin a aldehyde and vitamin a alcohol and esters, as the palmitate and the acetate. Used according to this invention, the composition comprises vitamin a component preferably in an amount of from 0.05 to 1 wt.%, considering the composition as a whole.

The b vitamins or b-complex vitamins include, among others:

- vitamin B1(thiamine),

- vitamin b2(Riboflavin),

- vitamin b3. Under this name are often compounds such as nicotinic acid amide is ikodinovic acid (Niacinamide). According to this invention, it is preferable amide of nicotinic acid, which is used in accordance with this invention the tool is preferably contained in an amount of from 0.05 to 1 wt.%, counting means in General,

- vitamin B5(Pantothenic acid and panthenol). Within this group are preferably used panthenol. According to this invention applied derivatives of panthenol are, in particular, complex and simple esters of panthenol, as well as cationic derivatives of panthenol. Individual representatives are, for example, antinatriuretic, simple pandenominational ether and its monoacetate, and cationic derivatives of panthenol, described in the international patent application 92/13829. These compounds are vitamin B5in applied according to this invention the means preferred in an amount of from 0.05 to 10 wt.%, considering the vehicle as a whole. Amount of from 0.1 to 5 wt.% especially preferred

- vitamin b6(pyridoxine and pyridoxamine and pyridoxal).

Vitamin C (ascorbic acid). The vitamin C applied in accordance with this invention means are preferred in an amount of from 0.1 to 3 wt.%, considering the vehicle as a whole. Application in the form of an ester of palmitic acid, glucoside or phosphate may be preferable. The use in combination of the Tocopherols is also preferred.

Vitamin E (Tocopherols, in particular α-tocopherol). Tocopherol and its derivatives, among which, in particular, esters, namely (in descending order) the acetate, the nicotinate, the phosphate and the succinate, are applied in accordance with this invention means are preferably in quantities from 0.05 to 1 wt.%, considering the vehicle as a whole.

Vitamin F. Under vitamin F mean usually essential fatty acids, in particular linoleic acid, linolenic acid and arachidonic acid.

Vitamin N. Vitamin H is called the connection (3S,4S,6R)-2-oxohexanoate[3,4-d]-imidazole-4-Valerian acid, which has been recognized temporarily settled trivial name "Biotin". Biotin is used in accordance with this invention the tool is contained preferably in an amount of from 0.0001 to 1.0 wt.%, in particular 0.001 to 0.01 wt.%, considering the vehicle as a whole.

Used according to this invention means preferably contain vitamins, provitamins and vitamin precursor of groups a, b, E and H.

Panthenol and its derivatives, as well as nicotinic acid amide and Biotin are particularly preferred.

Finally, the combined use with plant extracts can improve the action of the active substance.

Typically, these extracts obtained by extraction of the whole plant. However, the CTD is lnyh cases it may be preferred to obtain the extracts exclusively from flowers and/or leaves.

Relatively used according to the invention of plant extracts reference is made in particular to the extracts which are listed in the tables "Edition des Leitfadens zur Inhaltstoffdeklaration kosmetisch Mitell" (p.44, 3 edition), published by the Industrial Union of personal care products and detergents, registered Association (IKW), Frankfurt.

According to this invention, first and foremost, the preferred extracts from green tea, oak bark, nettle, Hamamelis, hops, chamomile, burdock root, horsetail, white thorns, lime blossom, almond, aloe Vera, pine needles, horse chestnut, sandalwood, juniper, coconut, mango, apricot, lemon, wheat, kiwi, melon, orange, grapefruit, sage, rosemary, birch, mallow, core meadow, thyme, yarrow, lemon balm, harrow, mother-and-stepmother, marshmallow, meristem, ginseng and ginger root.

Especially preferred extracts from green tea, oak bark, nettle, Hamamelis, hops, chamomile, burdock root, horsetail, Linden blossom, almond, aloe Vera, coconut, mango, apricot, lemon, wheat, kiwi, melon, orange, grapefruit, sage, rosemary, birch, core meadow, thyme, yarrow, of harrow, meristem, ginseng and ginger root.

Most preferred for use according to this invention are extracts of green tea, m is ndala, aloe Vera, coconut, mango, apricot, lemon, wheat, kiwi and melon.

As an extracting means for obtaining the mentioned plant extracts using water, alcohols and mixtures thereof. Among the preferred alcohols are lower alcohols such as ethanol and isopropanol, and, in particular, polyhydric alcohols such as ethylene glycol and propylene glycol, as an independent extraction means, and in a mixture with water. Especially suitable are plant extracts based on water/propylene glycol in a ratio of from 1:10 to 10:1.

Plant extracts can be used according to the invention in pure form and also in diluted form. If they are used in diluted form, they contain from about 2 to 80 wt.% the active substance and the solvent used when receiving extracting agent or a mixture of extracting agents.

Further, it may be preferable to the tool corresponding to this invention, to introduce a mixture of several, in particular two, different plant extracts.

It was further found that the effect of the active substances according to the invention in cosmetic tool can be further enhanced in combination with substances containing primary or secondary amino group. In the when asked examples of aminecontaining substances can be called ammonia, monoethanolamine, 2-amino-2-methyl-propandiol, as well as basic amino acids, such as lysine, arginine or histidine. Of course, these amines can be used in the form of corresponding salts with inorganic and/or organic acids, for example, in the form of ammonium carbonate, ammonium citrate, ammonium oxalate, ammonium tartrate or hydrochloride lysine. Amines with active substance according to this invention are used in common in the ratio from 1:10 to 10:1, preferably from 3:1 to 1:3, and entirely preferably in stoichiometric quantities.

In addition to the required in accordance with this invention, active substances and other, the above-mentioned preferred components, this composition may contain, in principle, and others known in the art for such cosmetics, components.

Other active auxiliary and additive substances are, for example:

- thickeners, namely gelatin or vegetable gums, such as agar-agar, guar gum, alginate, xanthene gum, Arabic gum, gum of sterculia burning, krupchatka carob, resin Flaxseed, dextrans, cellulose derivatives such as methylcellulose, hydroxyethylcellulose and carboxymethylcellulose, starch fractions and derivatives, namely amylose, amylopectin and dextrin, g the ins and sizing silicates, as, for example, bentonite or fully synthetic hydrocolloids, such as polyvinyl alcohol, CA-, Mg - or Zn-soap,

- structural funds, namely maleic acid and lactic acid,

aromatic oil,

- dimetridazole,

- cyclodextrins,

- solvents and agents of dissolution, for example ethanol, isopropanol, ethylene glycol, propylene glycol, glycerol and diethylene glycol,

- active substances that improve the structure of the fibers, in particular mono-, Li -, and oligosaccharides, such as glucose, galactose, fructose, fruit sugar and lactose,

- Quaternary amines, namely methyl-1-acylaminoacyl-2-alkylimidazole-methosulfate,

- antispyware, namely silicones,

- dyes for coloring tools

- active agents dandruff, namely Piroctone Alamin, Zinc Amadin and Climbazol,

- light stabilizers, in particular benzophenone derivatives, cinnamic acid and triazine,

- other substances for installation of the pH indicator, such as αand β-hydroxy carboxylic acid,

- biologically active substances, namely, allantoin and bisabolol,

- cholesterol,

- complexing agents, namely EDTA (ethylenediaminetetraacetic acid), NTA (nitrilotriacetate acid), β-allindustry acid and phosphonic acid,

- substances for which uhane and penetration, for example glycerin, propilenglikolmonostearata ether, carbonates, hydrogen carbonates, guanidine, urea, and primary, secondary and tertiary phosphates,

- ceramide, which include N-acylsphingosine (fatty acid amides of sphingosine) or synthetic analogues of such lipids (so-called pseudoceramides),

- cloud emulsions glass, such as latex, styrene/polyvinylpyrrolidone and styrene/acrylamide copolymers,

- remedies for pearly luster, namely etilenglikolevye - and-distearate, and polyethylene glycol-3-distearate,

- pigments,

- reducing agents, such as, for example, thioglycolate acid and its derivatives, tomalachka acid, hexamethylenetetramine, diablada acid and α-mercapto-econsultancy acid,

- working gases, such as propane-butane mixture, N2O, dimethyl ether, carbon dioxide and air,

- antioxidants

detoxifer,

plant glycosides,

- polysaccharides, namely fructose and rhamnose.

Information about other optional components, as well as quantities of these components can be found in well-known specialists in the appropriate directory, for example in the monograph by Kh. Schrader, "Grundlagen und Rezepturen der Kosmetika", 2nd edition, publishing house Hüthig Buch, Heidelberg, 1989

Regarding the type of the corresponding izaberete the Oia active substances, applied to the keratin fibers, particularly human hair, there are no restrictions. The quality of the finished product of this composition are suitable, for example, creams, lotions, solutions, water, emulsions, such as b/M, M/ -, DFT-emulsion (water/oil, oil/water-temperature phase transition is named according to the teaching of phase transitions), micro-emulsions and multiplet emulsion, rough, unstable, single or multiphase shake mixes, jellies, sprays, aerosols and foam aerosols. They are, as a rule, water-alcohol-based. As the alcohol component used in this lower alcohols and polyols, such as propylene glycol and glycerin. Ethanol and isopropanol are preferred alcohols. Water and alcohol can exist in water-alcohol-based mass ratio of from 1:10 to 10:1. Water and water-alcohol mixtures, which contain up to 50 wt.%, in particular up to 25 wt.%, alcohol, considering the mixture of alcohol/water, can serve as the preferred basis in accordance with this invention. The pH of these compositions can in principle be from 2 to 11, preferably from 2 to 7, while the pH value from 3 to 5 is preferred. To establish this, the pH indicator can be used any used for cosmetic purposes acids or basis of the project. Usually, the acids used by food acids. Food acids involve such acids, which are usually produced by the food industry and have a positive impact on the human body. Food acids are, for example, acetic acid, lactic acid, tartaric acid, citric acid, malic acid, ascorbic acid and gluconic acid. In the framework of the invention particularly preferred are citric and lactic acids. The preferred bases are ammonia, hydroxides of alkali metals, monoethanolamine, triethanolamine, N,N,N',N'-tetrakis-(2-hydroxypropyl)-Ethylenediamine.

Remaining on the hair composition is particularly active and may therefore represent a preferred form of implementation of the present invention. Under remaining on the hair according to the invention the composition imply such a composition that when processing is not washed off again with the hair for a period of time from several seconds to hours by using water or an aqueous solution. On the contrary, the composition remains until the next wash your hair.

According to a preferred form of execution of these compositions are designed for use on the hair as a remedy for hair or hair conditioner. The relevant data is mu invention compositions according to this form of execution after completion of the exposure can be washed away with water or tool, at least the predominant amount of water; preferably still, as stated above, to remain on the hair. This may be preferable to have developed composition, corresponding to this invention, was applied to the hair before applying the cleanser, styling or other means of treating the hair. In this case, the designed composition according to this invention serves as a protection coating by subsequent treatments.

In accordance with other forms of execution of the invention it may be in the case of tools suitable for the invention, also, for example, detergents for the hair, namely, shampoos, such means of hair care products like mouthwash, or about tonics for hair, as, for example, means for packing, foam stabilizers, styling gels and compositions for cold wave, means long-term preservation of shape, namely, the means for controlling and locking means, and, in particular, used in the process of perming and coloring tools, pre-treatment or follow-up rinsing.

In a particular form of execution of the tool corresponding to this invention, it may be preferable, if it exists in the form of a microemulsion. Under the microemulsions mean the part of the invention also named "DFT-emulsions". In the case of these emulsions it is in principle to systems with three components: water, oil, and emulsifier, which at room temperature are in the form of oil-in-water (M/W)emulsion. When heated to a certain temperature (usually referred to as "temperature phase transformations" or "DFT") of this system form a microemulsion, which upon further heating is transformed into a water-in-oil(W/M)-emulsion. Upon further cooling, again formed M/O emulsion, which, however, at room temperature exists in the form of a microemulsion with an average particle diameter of less than 400 nm, preferably with a particle diameter of about 100-300 nm. Details regarding these very stable, low viscosity systems, under the General title "DFT"-emulsions, can be found in publications, instead of which we have named the replacement of their publication in Angew. Chem., volume 97, str-669 (1985) and Adv. Colloid Interface Sci., volume 58, str-149 (1995).

According to this invention such micro - or "DFT"emulsion with an average particle diameter of about 200 nm may be preferred.

Obtaining this invention microemulsions can, for example, be carried out in such a way that, first determine the temperature of phase transformation system by heating the samples obtained in the usual manner of the emulsion and the temperature determination with the help of the device is to measure specific conductance, when the conductivity is greatly reduced. The specific conductivity of the existing first M/To-emulsion drops, and, as a rule, above the temperature range of from 2 to 8°With a first value greater than 1 MS/cm to values below 0.1 MSM/see This temperature region corresponds in this case, the temperature region of the phase transformation. Thus, after the temperature region of phase transformation is known, can the emulsion obtained in the usual way from the oil component, neinogennye emulsifier, at least part of the water, and, if necessary, other components are first heated to a temperature lying within or above the temperature range of phase transformations, then cool and add, if necessary, other components and the rest of the water. You can spend an alternate receipt microemulsions right at a temperature which lies within or above the temperature range of phase transformations. Thus obtained microemulsion was then cooled below the temperature range of phase transformations, usually to room temperature.

In a particularly preferred form of the active substance is applied in the means for coloring keratin fibers. The tool corresponding to this invention, in principle, can be added to the in nternet dye. Preferably the application of active substances on the painted keratin fibers on a separate stage or in the painting process, or by a separate processing, if necessary, after a few days or weeks after coloring.

The concept of "painting process" includes all well-known specialists of the ways in which on the hair, if necessary, soaked, dye is applied and left on the hair for a period of from several minutes to approximately 45 minutes, and then rinse with water or a medium containing a surfactant, or is left entirely to the hair. In this regard, the relevant information for professionals contained in the famous monograph Kh. Schrader, "Grundlagen und Rezepturen der Kosmetika", 2nd edition, publishing house Hüthig Buch, Heidelberg, 1989

As mentioned before, in the framework of this invention it is also possible, although less preferred, to include the active substance directly into coloring or tinting agent.

The composition of the dye or tonic not subject to fundamental limitations.

As the coloring matter (predecessor) can be used:

the predecessor of oxidative dyes manifested or coupler type,

- natural and synthetic dyes, direct action, and

- before Estonica similar natural dyes, namely indole and indoline-derivatives

as well as mixtures of one or more of these groups.

As precursors of oxidation dyes manifested type are usually primary aromatic amines with another located in the para - or ortho-position, free or substituted amino group, a derivative of diaminopyridine, heterocyclic hydrazones, 4-aminobenzophenone, and 2,4,5,6-tetraaminopyrimidine and its derivatives. Suitable components are manifested, for example, p-phenylenediamine, p-toluylenediamine, p-aminophenol, o-aminophenol, 1-(2'-hydroxyethyl)-2,5-diaminobenzene, N,N-bis-(2-hydroxy-ethyl)-p-phenylenediamine, 2-(2,5-diaminophenoxy)-ethanol, 4-amino-3-METHYLPHENOL, 2,4,5,6-tetraaminopyrimidine, 2-hydroxy-4,5,6-triaminopyrimidine, 4-hydroxy-2,5,6-triaminopyrimidine, 2,4-hydroxy-5,6-diaminopyridine, 2-dimethyl-amino-4,5,6-triaminopyrimidine, 2-hydroxymethylamino-4-aminophenol, bis-(4-AMINOPHENYL)amine, 4-amino-3-terfenol, 2-aminomethyl-4-aminophenol, 2-hydroxy-methyl-4-aminophenol, 4-amino-2-[(diethylamino)-methyl]phenol, bis-(2-hydroxy-5-amino-phenyl)-methane, 1,4-bis-(4-AMINOPHENYL)-disallowable, 1,3-bis-[N-(2-peroxyacyl)-N-(4-amino-phenylamino)]-2-propanol, 4-amino-2-(2-hydroxyethoxy)-phenol, 1,10-bis-(2,5-diaminophenyl)-1,4,7,10-tetraoxalate, and 4,5-diaminobenzophenone according to European patent Ali the application for international patent 94/08970, as, for example, 4,5-diamino-1-(2'-hydroxy-ethyl)pyrazole. Particularly preferred components manifested type are p-phenylenediamine, p-toluylenediamine, p-aminophenol, 1-(2'-hydroxyethyl)-2,5-diaminobenzene, 4-amino-3-METHYLPHENOL, 2-aminomethyl-4-aminophenol, 2,4,5,6-Tetra-amino-pyridine, 2-hydroxy-4,5,6-triaminopyrimidine, 4-hydroxy-2,5,6-triamino-pyridine.

As precursors of oxidation dyes are used, as a rule, derivatives of p-phenylenediamine, naftaly, resorcinol and derivatives of resorcinol, pyrazolones and derivatives of m-aminophenol. Examples of such color-forming components are:

- m-aminophenol and its derivatives, such as 5-amino-2-METHYLPHENOL, 5-(3-hydroxypropylamino)-2-METHYLPHENOL, 3-amino-2-chloro-6-METHYLPHENOL, 2-hydroxy-4-aminophenoxyethanol, 2,6-dimethyl-3-aminophenol, 3-triptorelin-2-chloro-6-METHYLPHENOL, 5-amino-4-chloro-2-METHYLPHENOL, 5-amino-4-methoxy-2-methyl-phenol, 5-(2'-hydroxyethyl)-amino-2-METHYLPHENOL, 3-(diethylamino)-phenol, N-cyclopentyl-3-aminophenol, 1,3-dihydro-5-(methylamino)-benzene, 3-(ethylamino)-4-METHYLPHENOL and 2,4-dichloro-3-aminophenol,

- o-aminophenol and its derivatives,

- m-diaminobenzene and its derivatives, such as 2,4-diaminophenoxyethanol, 1,3-bis-(2,4-diaminophenoxy)propane, 1-methoxy-2-amino-4-(2'-hydroxyethylamino)-benzene, 1,3-bis-(2,4-diaminophenyl)propane, 2,6-bis-(2-hydroxyethylamino)-1-mative the evils and 1-amino-3-bis-(2'-hydroxyethyl)-aminobenzoyl,

- o-aminobenzoyl and its derivatives, such as, for example, 3,4-diaminobenzoic acid and 2,3-diamino-1-methylbenzol,

- derived di - or trihydroxybenzene, as, for example, resorcinol, onomatology ether of resorcinol, 2-methylresorufin, 5-methylresorcinol, 2.5-demetallization, 2-chloro-resorcinol, 4-chloro-resorcinol, pyragollole and 1,2,4-trihydroxybenzene,

- derivative pyridines, such as 2,6-dihydroxypyridine, 2-amino-3-hydroxypyridine, 2-amino-5-chloro-3-hydroxypyridine, 3-amino-2-methylamino-6-methoxypyridine, 2,6-dihydroxy-3,4-dimethylpyridine, 2,6-dihydroxy-4-methylpyridine, 2,6-diaminopyridine, 2,3-diamino-6-methoxypyridine and 3,5-diamino-2,6-dimethoxypyridine,

- derivatives of naphthalene, as, for example, 1-naphthol, 2-methyl-1-naphthol, 2-hydroxy-methyl-1-naphthol, 2-hydroxyethyl-1-naphthol, 1,5-dihydroxynaphthalene, 1,6-dihydro-xington, 1,7-dihydroxynaphthalene, 1,8-dihydroxynaphthalene, 2,7-dihydroxynaphthalene and 2,3-dihydroxynaphthalene,

derivatives of the research as, for example, 6-hydroxybenzomorpholine and 6-amino-benzomorphan,

derivatives finokalia, as, for example, 6-methyl-1,2,3,4-tetrahydroquinoxalin,

- pyrazole derivatives, such as 1-phenyl-3-methylpyrazole-5-he,

- indole derivatives, such as 4-hydroxyindole, 6-hydroxyindole and 7-guide-oxyindole,

derivatives methylenedioxybenzene, as, for example, 1-hydroxy-3,4-methylenedi-oxybenzoyl, 1-amino-3,4-m is silenciosamente and 1-(2'-hydroxyethyl)-amino-3,4-methylenedioxybenzene.

Particularly suitable color-forming components are 1-naphthol, 1,5-, 2,7 - and 1,7-dihydroxynaphthalene, 3-aminophenol, 5-amino-2-METHYLPHENOL, 2-amino-3-hydroxypyridine, resorcinol, 4-chlororesorcinol, 2-chloro-6-methyl-3-aminophenol, 2-methylresorcinol, 5-methylresorcinol, 2,5-dimethylanisole and 2,6-dihydroxy-3,4-dimethylpyridine.

Dyes direct action are usually nitrophenylacetylene, nitrome-Naftali, azo dyes, anthraquinones or indophenol. Particularly suitable are directly applicable dyes are known under the international names or trade names: NA yellow 2, HC yellow 4, HC yellow 5, HC yellow 6, basic yellow 57, dispersion, orange 3, HC red 3, HC red BN, basic red 76, HC blue 2, HC blue 12, dispersion, blue 3, basic blue 99, HC violet 1, dispersion, purple 1, dispersion, purple 4, dispersion, black 9, basic brown 16 and basic brown 17, as well as 1,4-bis-(β-hydroxyethyl)-amino-2-nitrobenzene, 4-amino-2-nitrodiphenylamine-2'-carboxylic acid, 6-nitro-1,2,3,4-tetrahydroquinoxalin, hydroxyethyl-2-nitrotoluene, picramic acid, 2-amino-6-chloro-4-NITROPHENOL, 4-ethylamino-3-nitrobenzoic acid and 2-chloro-6-ethylamino-1-hydroxy-4-nitrobenzene.

Dyes direct action occurring in nature include, for example, x is in the red, henna neutral, henna black, chamomile, sandalwood, black tea, buckthorn, sage, sandal wood tree, the root of moraine, betel, sedre and root alkanna.

It is not mandatory that the precursors of oxidative dye or dyes of direct action are respectively homogeneous connection. In contrast, the dyes corresponding to this invention, may be contained in the dependent quantities of other components, due to the processes of obtaining the individual dyes, as well as components, if they do not have a negative impact on the colour, and should not be excluded for other reasons, such as poison.

Information about coloring substances used in dyeing and tinting tools that are relevant to this invention, can be found in the monograph Ch. Zviak, The Science of Hair Care, Chapter 7 (str-250; dyes direct action), and in Chapter 8 (str-267; forproduct oxidation dyes), published in 7 volumes of the series "Dermatology" (edited by: Ch.Culman and N. Maibach), publisher Varcel Dekker Inc., New York, Basel, 1986, as well as in the European registry of cosmetic raw materials", published by the European society, and is available in the form of diskettes, from the "Federal Association of German industrial and trading enterprises medicines, Ref is armirovannykh goods and personal hygiene" (registered Association).

As precursors of natural analogues of dyes are used, for example, indole and indoline, as well as their physiologically compatible salts. It is preferable to use such indoles and indoline that contain at least one hydroxyl or amino group as a substituent on the six-membered ring. These groups may have other substituents, such as ether and ester groups with a hydroxyl group and an alkyl group at the amino group. Especially preferred properties have 5,6-dihydroxyindoline, N-methyl-5,6-dihydroxyindoline, N-ethyl-5,6-dihydroxyindoline, N-propyl-5,6-dihydroxyindoline, N-butyl-5,6-dihydroxyindoline, 5,6-dihydroxyindoline-2-carboxylic acid, 6-hydroxyindole, 6-aminoindole and 4-aminoindole, and 5,6-dihydroxyindole, N-methyl-5,6-dihydroxyindole, N-ethyl-5,6-dihydroxyindole, N-propyl-5,6-dihydroxyindole, N-butyl-5,6-dihydroxyindole, 5,6-dihydroxyindole-2-carboxylic acid, 6-hydroxyindole, 6-aminoindole and 4-aminoindole.

Particularly prominent within this group are N-methyl-5,6-dihydroxyindoline, N-ethyl-5,6-dihydroxyindoline, N-propyl-5,6-dihydroxyindoline, N-butyl-5,6-dihydroxyindoline and, in particular, 5,6-dihydroxyindoline, and N-methyl-5,6-dihyd-oxyindole, N-ethyl-5,6-dihydroxyindole, N-propyl-5,6-dihydroxyindole, N-butyl-5,6-dihydroxyindole, and, in particular 5,6-dihydroxyindole.

Indolin and abdolrasulnia used dyes in the framework of the method of the invention, are used both as free bases and in the form of their physiologically compatible salts with inorganic or organic acids, such as hydrochloride, sulfates and hydrobromides.

When applying the precursors of dyes of indolin - or indole type, it is preferable to use them in conjunction with at least one amino acid and/or at least one Oligopeptide. Preferred amino acids are aminocarbonyl acid, in particular α-aminocarbonyl acid and ω-aminocarbonyl acid. Among α-aminocarbonyl acids are particularly preferred arginine, lysine, ornithine and histidine. Absolutely the preferred amino acid is arginine, which is used, in particular, both in free form and in the form of hydrochloride.

The dye for the hair, in particular, if the oxidation and staining is oxygen or other oxidants, such as hydrogen peroxide, is usually a composition of from weakly acidic to alkaline, i.e. with a pH in the range from 5 to 11. This dye contains alkalizing agent, usually hydroxides of alkaline or alkaline-earth metals, ammonia or organic AMI the s.

Preferred alkalizing agent are monoethanolamine, mono-isopropanolamine, 2-amino-2-methylpropanol, 2-amino-2-methyl-1,3-propandiol, 2-amino-2-ethyl-1,3-propandiol, 2-amino-2-methylbutanol and triethanolamine, as well as hydroxides of alkaline or alkaline-earth metals. In particular, monoethanolamine, triethanolamine and 2-amino-2-methylpropanol and 2-amino-2-methyl-1,3-propandiol are preferred within this group. You can also use ω-amino acids, namely ω-aminocaproic acid as alkalizing remedies.

If done coloring dye direct action within the oxidation process, it is possible to apply conventional oxidants, in particular, for example, hydrogen peroxide or products of its accession to urea, melamine or sodium borate. Oxidation by air oxygen as the sole oxidant of course is preferred. Further, it is possible to carry out the oxidation with the help of enzymes, while enzymes are used both to generate oxidizing peroxide compounds, and to enhance the effects of smaller amounts of available oxidant, with the help of enzymes is also the transfer of electrons from suitable components "manifest" type (reductants) to the oxygen of the air. Preferred are oxidase, namely ti is osinaga, ascorbicacid and laccase or glucoseoxidase, uricase or privatkredite. Next can be called advantages such as the impact of smaller quantities (e.g., 1% or less, counting on the tool as a whole) of hydrogen peroxide by peroxidase when docked.

It is advisable to mix the composition with an oxidant just before coloring the hair with a composition containing the dye precursor.

The resulting ready-to-use product for hair coloring should preferably have a pH value in the range from 6 to 10. Especially preferred is the use of hair dye in alkaline environment. Used the temperature is from 15 to 40°With a preferred temperature of the scalp. After exposure for about 5 to 45 minutes, in particular from 15 to 30 minutes, the dye is removed by flushing with color-treated hair. Subsequent washing with a shampoo is not done, if you are using contains a strong surfactant base, for example coloring shampoo.

In particular, when highly colored hair you can apply the composition to the hair without pre-mixing of the dye precursor with an oxidizing component. After exposure lasting from 20 to 30 minutes and then, if necessary, after premiato the aqueous washing - cause oxidative component. After further exposure for 10 to 20 minutes, wash off and, if desired, washed with shampoo. In this form of conduct according to the first variant, in which the prior application of the precursor of the dye should call the best hair growth, the appropriate tool is adjusted to the pH value from 4 to 7. According to the second variant, first seek to oxidation by air, the applied solution has preferably a pH value from 7 to 10. Subsequent accelerated additional oxidation may be preferable to use as the oxidizing agent in acid solution peroxydisulfate.

Next, you can contribute to staining and enhance it by adding in the means of certain metal ions. Such metal ions are, for example, Zn2+, Cu2+, Fe2+, Fe3+, Mn2+, Mn4+Li+, Mg2+, CA2+and Al3+. Particularly suitable are Zn2+, Cu2+and Mn2+. Metal ions can be used in any form of physiologically compatible salts. Preferred salts are acetates, sulfates, halides, lactates and tartratami. Through the use of metal salts as possible to speed up the coloring process, and to purposefully influence the nuances of color.

Examples

Su is given amounts, if not noted otherwise, are given in mass units.

1. The latch perms
CompositionChemical nameINCI-nameWt.%
Dehyton® For (firm Cognis)Natural betaine. Aminopropane fatty acids betanova structure (about 32%)Cocamidopropyl betaine6,0
Nutrilan® N (firm Cognis)A partial hydrolysate of protein (about 36%)Hydrolyzed collagen5,0
Limequat® LCationically hydrolyzed protein (about 36%)Laurdimonium hydroxypropyl hydrolyzed collagen3,0
Hydrogen peroxide 35%7,5
Central T (1% swelling)Hantan gum15,0
Water100
(S)-(+)-2-hydroxy-3,3-dimethyl-γ-butyrolactone (firm Aldrich)1,0
PH3,5

2. The latch perms, emulsion form
CompositionChemical nameINCI-nameWt.%
DEHYQUART® 4046 (firm Cognis)A mixture of exterkate, fatty alcohol and a nonionic emulsifierCetearyl alcohol (and) dipalmitoyl ether hydroxyethylmonium methosulfate (and) ceteareth-203,0
Water100
Turbinal® SLHeteronympha acid7,5
Hydrogen peroxide 35%7,5
PLANTACARE® 2000-UP company Cognis)Glycoside With8-C16fatty alcoholsDecyl glucoside1,0
D,L-2-hydroxy-3,3-dimethyl-γ-butyrolactone (firm Aldrich)0,5
Viscosity (MPa· (C), the o'hare Chicago MARRIOTT RVF, 23°C, Sp.TC, 10 Upm3600
PH2,7

3. Spray treatment for hair loss
CompositionChemical nameINCI-nameWt.%
Monomers® 60-35 With (company Cognis)Hydrogenated palm-glyceridesHydrogenated palm glycerides1,24
Emulgin® B1 (firm Cognis)Polyoxyethylene-12-cetylstearyl alcoholCetearate-12was 2.76
Cetiol® S (firm Cognis)HydrocarbonDioctylsebacate9,0
Cetiol® TH (firm Cognis)Di-n-oktilovom etherDicaprylyl ether9,0
Dow Corning DC 345® (the company Dow Corning)Cyclomethicone2,0
2,5-Dihydro-5-methoxy-2-furanone (Merck)2,0
Water100
Gluadin® WQ (firm Cognis)Cationically hydrolyzed wheat protein (about 31%)Laurdimonium hydroxypropyl hydrolyzed wheat protein2,85
PLANTACARE® 2000-UP company Cognis)Glycoside With8-C16fatty alcohols (about 50%)Decyl glikos the water 1,0
Viscosity (MPa·)<100

4. The treatment for hair
CompositionChemical nameINCI-nameWt.%
DEHYQUART® F 75 (firm Cognis)A mixture of exterkate and fatty alcoholDistearoyl hydroxyethylmonium methosulfate (and) Cetearyl alcohol0,7
Dehymuls® PGPH (firm Cognis)Polyglyceryl-12-hydroxystearatePolyglyceryl-2 dipolyhydroxystearate1,0
Lanett® About (company Cognis)Cetylstearyl alcoholCetearyl alcohol3,0
Eutanol® G (firm Cognis)2-Octyldodecanol (Gorbaty alcohol)Octyldodecanol0,2
Cetiol® J 600 (firm Cognis)Liquid ester waxOleyl Erekat0,1
PLANTACARE® 1200 UP (firm Cognis)Glycoside With12-C16fatty alcohols (about 50%)Lauryl glucoside2,5
4-Hydroxy-2,5-dime-Tyl-3(2H)-FSD is a non 1,0
Water100
Gluadin® 40 W (firm Cognis)A partial hydrolysate of wheat (about 40%)Hydrolyzed wheat protein2,0
Panthenol (50%)0,7
Viscosity (MPa· (C), the o'hare Chicago MARRIOTT RVF, 23°C, Sp.5, 10 Upm6800
PH4

5. The treatment for hair
CompositionChemical nameINCI-nameWt.%
Sepigel® 305 (firm Shippig).Polyacrylamide (and) With13-C14isoparaffin (and) Laureth-73,0
Comperlan® KD (firm Cognis)Diethanolamide coconut acidCocamide DEA2,0
Dihydro-3-hydroxy-4,4-dimethyl-2-(3H)-furanone3,0
Water100
PLANTACARE® 1200 UP firms who Cognis) Glycoside C12-C16fatty alcohols (about 50%)Lauryl glucoside0,5
Cetiol® J 600 (firm Cognis)Liquid ester waxOleyl Erekat0,5
Copherol® F 1250 (firm Cognis)RRR-(α)-tocopherylacetateTocopherol0,2
Gluadin® almond (firm Cognis)A partial hydrolysate of almonds (about 20%)Hydrolyzed sweet almond protein3,0
Gluadin® WQ (firm Cognis)Cationically hydrolyzed wheat protein (about 31%)Laurdimonium hydroxypropyl hydrolyzed wheat protein0,8
Ethanol10,0
Viscosity (MPa· (C), the o'hare Chicago MARRIOTT RVF, 23°C, Sp.4, 10 Upm6700
PH7

6. Rinse hair
CompositionChemical nameINCI-nameWt.%
DEHYQUART® 4046 (firm Cognis)A mixture of exterkate, Zhirnov the alcohol and nonionic emulsifier Cetearyl alcohol (and) dipalmitoyl ether hydroxyethylmonium methosulfate (and) ceteareth-204,0
Cetiol® SN (firm Cognis)The ester of branched fatty acids and saturated fatty C16-C18-alcohol : Cetearyl isononanoate1,0
Gluadin® almond (firm Cognis)A partial hydrolysate of almonds (about 22%)Hydrolyzed sweet almond protein2,1
Dihydro-3-hydroxy-4,4-dimethyl-2-(3H)-furanone (firm Aldrich)1,5
Water100
Viscosity (MPa· (C), the o'hare Chicago MARRIOTT RVF, 23°C, Sp.4, 10 Upm4000
PH3,5

7. The treatment for hair
CompositionChemical nameINCI-nameWt.%
DEHYQUART®L 80 (firm Cognis)A mixture of exterkate and propylene glycol (about 75%)DIOXOLANYL hydroxyethylmonium methosulfate (and) propylene GL is Col 0,9
Lanett® O (firm Cognis)Cetylstearyl alcoholCetearyl alcohol3,5
Monomers® 60-35 With (company Cognis)Hydrogenated palm-glyceridesHydrogenated palm glycerides1,0
Emulgin® B2 (firm Cognis)Polyoxyethylene-20-cetylstearyl alcoholCetearate-200,8
Cosmedia® Guar With 261 (firm Cognis)Qualitatsprufer-trimethylammonium chlorideQualitatsprufer trimonium chloride0,3
Tetrahydro-5-oxo-2-francebuy acid Na-salt2,0
Water100
PH3,5

8. Hair mask
CompositionChemical nameINCI-namewt.%
DEHYQUART® F 75 (firm Cognis)A mixture of exterkate and the fat is on alcohol Distearoyl hydroxyethylmonium methosulfate (and) Cetearyl alcohol3,0
Lanett® About (company Cognis)Cetylstearyl alcoholCetearyl alcohol4,0
Cutin® GMS (firm Cognis)GlycerylmonostearateGlyceryl stearate1,0
Emulgin® B2 (firm Cognis)Polyoxyethylene-20-cetylstearyl alcoholCetearate-201,5
4-Hydroxy-2,5-dimethyl-3(2H)-furanone2,0
Nutrilan® Keratin W (firm Cognis)Partial hydrolyzed keratin (about 20%)Hydrolyzed keratin5,0
Panthenol0,8
Aloe Vera gel2,0
Water100
PH3-4

9. Means for intensive hair treatment
CompositionChemical nameINCI-nameMA is.%
DEHYQUART® L 80 (firm Cognis)A mixture of exterkate and propylene glycol (about 75%)DIOXOLANYL hydroxyethylmonium methosulfate (and) propylene glycol2,5
Cutin® GMS (firm Cognis)GlycerylmonostearateGlyceryl stearate0,5
Lanett® OCetylstearyl alcoholCetearyl alcohol4,0
HYDAGEN® HSP (firm Cognis)Trimethylolpropane-hydroxyethylstarch ether0,5
Dihydro-3-hydroxy-4,4-dimethyl-2-(3H)-furanone (firm Aldrich)3,0
Lamesoft® RO 65 (firm Cognis)A mixture of alkylpolyglycoside and monoglyceride fatty acidsCoco-glucoside (and) glyceryl the oleate2,5
Water100
Viscosity (MPa· (C), the o'hare Chicago MARRIOTT RVF, 23°C, Sp.4, 10 Upm4400
PH3,5

10. Hairspray
CompositionThe chemical is some name INCI-nameWt.%
HYDAGEN® HCMF (firm Cognis)Chitosan powderChitosan0,4
Glycolic acid (Merck)Glycolic acid0,2
Glycerol (86%)55,0
Tolosa® H 100.000 YP (firm Xëxart)0,4
(R)-(-)-2-hydroxy-3,3-dimethyl-γ-butyrolactone (firm Aldrich)3,0
Gluadin® R (firms Cognis)A partial hydrolysate of rice (about 40%)Hydrolyzed rice protein (and) hydrolyzed vegetable protein4,0
Panthenol 50%1,0
Ethanol10,0
Water100
PH4,5

11. Jelly for hair
CompositionChemical nameINCI name-the name Wt.%
DEHYQUART®L 80 (firm Cognis)The mixture Avianova tools and propylene glycol (about 75%)DIOXOLANYL Hydroxyethylmonium methosulfate (and) propylene glycol2,0
Lamesoft® RO 65 (firm Cognis)A mixture of alkylpolyglycoside and monoglyceride fatty acidsCoco-glucoside (and) glyceryl the oleate2,0
Tetrahydro-5-oxo-2-francebuy acid, K-Sol2,0
Water100
PH3,5

Glycoside With12-C16fatty alcohols (about 50%)

Cationically hydrolyzed wheat protein (about 31%)
12. Spray fixer
CompositionChemical nameINCI-nameWt.%
HYDAGEN® HCMF (firm Cognis)Chitosan powderChitosan1,0
Glycolic acid (Merck)0,4
2,5-Dihydro-5-methoxy 2-furanone (Merck)0,5
PLANTACARE® 1200 UP (firm Cognis)

Gluadin® WQ (firm Cognis)
Lauryl glucoside

Laurdimonium hydroxypropyl hydrolyzed wheat protein
0,2

1,0
Ethanol40,0
Water100
PH4,0

13. Foam stabilizer
CompositionChemical nameINCI-nameWt.%
HYDAGEN® HCMF (firm Cognis)Chitosan powderChitosan0,4
Glycolic acid (Merck)Glycolic acid0,2
Dihydro-3-hydroxy-4,4-dimethyl-2-(3H)-furanone (firm Aldrich)1,0
DEHYQUART® And (company Cognis)Cetyltrimethylammonium-chloride (about 25%)Cetrimonium chloride1,0
Gluadin® 40 W (firm Cognis)A partial hydrolysate of wheat (about 40%)Gidrolizovat the hydrated wheat protein 2,0
Water100

14. Styling-wax
CompositionChemical nameINCI-nameWt.%
Cutin® MD (firm Cognis)A mixture of mono - and diglycerides of palmitic and stearic acidsGlyceryl stearate5,0
Emulgin® B1 (firm Cognis)Polyoxyethylene-12-cetylstearyl alcoholCetearate-121,0
Cetiol® V (firm Cognis)Decroly ester of oleic acidThe a decyl oleate5,0
Paraffin oil10,0
HYDAGEN® HCMF (firm Cognis)Chitosan powderChitosan0,8
Glycolic acid (Merck)0,4
D,L-2-hydroxy-3,3-dimethyl-γ-butyrolactone (firm Aldri:1,0
Water100

15. Shampoo 2 in 1
CompositionChemical nameINCI-nameWt.%
Texapon® N 70 (firm Cognis)Matricariifolium with 2 mol of EO (about 70%)Sodium Laureth sulfateto 12.0
Dehyton® RK 45 (firm Cognis)Aminopropane fatty acids betanova structure (about 45%)Cocamidopropyl betaine2,5
PLANTACARE® 818 UP company Cognis)Glycoside With8-C16fatty alcohols (about 50%)Coco glucoside3,0
Lamesoft® RO 65 (firm Cognis)Coco-glucoside (and) glyceryl the oleateCoco-glucoside (and) glyceryl the oleate3,0
Cosmedia® Guar With 261 N (firm Cognis)Qualitatsprufer-trimethylammonium chlorideGuar hydroxypropyl trimonium chloride0,3
EUPERLAN® RK 1200 (firm Cognis)Liquid dispersion of substances, giving pearly luster, and adjuvantCoco-glucoside (and) glycol distearate (and) glycerin5,0
Sodium chloride1,2
D,L-4-hydroxymethyl-γ-butyro-the Acton (Merck) 0,3
Auxil® 400 (firm sylke & Maur)and0,1
Water100
Viscosity (MPa· (C), the o'hare Chicago MARRIOTT RFT, 23°C, Sp.4, 10 Upm6300
PH5,5

16. The shampoo-conditioner
CompositionChemical nameINCI-nameWt.%
Texapon® N 70 (firm Cognis)Matricariifolium with 2 mol of EO (about 70%)Sodium Laureth sulfate10,0
PLANTACARE® 818 UP company Cognis)Glycoside With8-C16fatty alcohols (about 50%)Coco glucoside4,0
Dehyton® For (firm Cognis)Derived amide of a fatty acid with betanova structure (about 30%)Cocamidopropyl betaine5,0
Lamesoft® RO 65 (firm Cognis)Coco-glucoside (and) glyceryl the oleateCoco glycoside (s) glyceril the oleate1,5
E. the Perlan® RC AM (firm Cognis)Liquid dispersion of substances, giving pearly luster, and amphoteric surface-active substanceGlycol distearate (and) Laureth 4 (I) cocamidopropyl betaine3,2
Dihydro-3-hydroxy-4,4-dimethyl-2-(3H)-furanone (firm Aldrich)1,5
Polymer JR® 400 (firm Amerchol)Polyquaternium 100,3
Sodium chloride1,5
Water100
Viscosity (MPa· (C), the o'hare Chicago MARRIOTT RVF, 23°C, Sp.4, 10 Upm8500
PH5,5

0,42
17. Cream hair dye
CompositionChemical nameINCI-nameWt.%
Lanett® OCetylstearyl alcoholCetearyl alcoholof 17.0
Cutin ® AGS (firm Cognis)EthylenglykoletherGlycol distearate1,5
Emulgin® B2 (f is RMA Cognis) Polyoxyethylene-20-cetylstearyl alcoholCetearate-203,0
Emulgin® B1 (firm Cognis)Polyoxyethylene-12-cetylstearyl alcoholCetearate-123,0
Emulgin® O5 (firm Cognis)Polyoxyethylene-5-operatively alcoholIG-51,0
Emulgin® O10 (firm Cognis)Polyoxyethylene-10-operatively alcoholIG-101,0
Comperlan® KD (firm Cognis)Diethanolamide coconut fatty acidsCocamide DEA5,0
Water100
DEHYQUART® L 80 (firm Cognis)A mixture of exterkate and propylene glycolDIOXOLANYL hydroxyethylmonium methosulfate (and) propylene glycol2,5
Propylene glycol5,0
p-Aminophenol0,35
p-Commencemen0,85
2-Methylresorcinol0,14
6-Methyl-m-aminophenol
Dihydro-3-hydroxy-4,4-dimethyl-2-(3H)-furanone (firm Aldrich)1,0
The sodium sulfate0,6
EDTA (Ethylenediamine-tetraoxane acid)Tetranitro EDTA0,2
Ammonia, 28%5,0

18. Hair rinse
CompositionWt.%
Emulgin® B210,3
Cetylstearyl alcohol3,3
Isopropylmyristate0,5
Paraffin oil perliquidum 15 cSt/DAB90,3
DEHYQUART® AND-CA22,0
Calcare® SC 9631,0
Citric acid0,4
Gluadin® WQ42,0
Dihydro-3-hydroxy-4,4-dimethyl-2-(3H)-furanone0,5
Phenonip®50,8
Water100
1Cetylstearyl alcohol +20 MA (INCI-name: Ceteareth-20) (company Cognis)
2Trimethyloctadecylammonium (approx 25% active substance; INCI-name: Cetrimonium chloride) (company Cognis)
3N,N,N-trimethyl-2[(methyl-1-oxo-2-propenyl)oxy]ethanaminium-homopolymer (50% active substance; INCI-name: Polyquaternium-37 (and) propylene glycol dicaprylate dicaprate (and) PPG-1 Trideceth-6) (firm Olid Colloids)
4Cationically hydrolyzed wheat protein, about 31% of the active substance (INCI-name: Laurdimonium hydroxypropyl hydrolyzed wheat protein) (company Cognis)
5Methyl ester of hydroxybenzoic acid-ethyl ester of hydroxybenzoic acid propyl ester of hydroxybenzoic acid butyl ester of hydroxybenzoic acid-Phenoxyethanol - mixture (about 28% active substance;

INCI-name: Phenoxyethanol, methylparaben, ethylparaben, propylparaben, butylparaben) (firm nip)

19. Hair rinse
CompositionWt.%
Emulgin® B20,3
Cetylstearyl alcohol3,3
Isopropylmyristate0,5
Paraffin oil perliquidum 15 cSt/DAB9 0,3
DEHYQUART® L 8060,4
Cosmedia guar® 26171,5
Promos® milk-CAQ83,0
Dihydro-3-hydroxy-4,4-dimethyl-2-(3H)-furanone0,5
Citric acid0,4
Phenonip®0,8
Water100
6Bis-(chocolates)-hydroxyethyl-methyl-ammonium-methosulfate (about 76% of the active substance in propylene glycol; INCI-name: decoquinate hydroxyethylmonium methosulfate, propylene glycol) (company Cognis)
7Qualitatsprodudukten chloride; INCI-name: guar hydroxypropyl trimonium chloride (firm Cognis)
8INCI-name: cocodimonium hydroxypropyl hydrolyzed casein (firm Saves Kazei)

20. The treatment for hair
CompositionWt.%
DEHYQUART® F 7594,0
Cetylstearyl alcohol4,0
Paraffin oil perliquidum 15 cSt/DAB91,5
DEHYQUART® AND-SA4,0
Calcare® SC 961,5
Amisah-LMA-60®101,0
Gluadin® W 20113,0
Dihydro-3-hydroxy-4,4-dimethyl-2-(3H)-furanone0,5
Citric acid0,15
Phenonip®0,8
Water100
9Fatty alcohol-methyltrimethylsilyltrifluoroacetamide ether - mixture (INCI-name: distearoyl hydroxyethylmonium methosulfate, Cetearyl alcohol) (company Cognis)
10INCI-nasaaee: hydroxypropyl arginine lauryl/myristyl ester HCI (firm Inomoto)
11Hydrolyzed wheat protein (20% active substance in water; INCI-name: water (and) hydrolyzed wheat protein (and) sodium benzoate (and) Phenoxyethanol (and) methylparaben (and) propylparaben) (company Cognis)

21. The treatment for hair
CompositionWt.%
DEHYQUART® L 802,0
Cetylstearyl alcohol6,0
Paraffin oil perliquidum 15 cSt/DAB92,0
Revocat® W 7 122,0
Dihydro-3-hydroxy-4,4-dimethyl-2-(3H)-furanone0,5
Cosmedia guar® 2610,5
Sepigel® 305133,5
Chanicut® 50141,0
Gluadin® WQ2,5
Gluadin® W203,0
Citric acid0,15
Phenonip®0,8
Water100
121-Methyl-2-portugalky-3-Targ-fatty acid-aminoimidazole-methods-sulfate (about 75% of the active substance in propylene glycol; INCI-name: quaternium 27, propylene glycol) (firm Witco)
13Copolymer of acrylamide and 2-acrylamide-2-methylpropanesulfonic acid (INCI-name: polyacrylamide (and) C13-C14-isoparaffin (and) Laureth-7) (firm seppic)
14INCI-name: hydroxypropyltrimonium honey (firm Brooks)

22. The treatment for hair
CompositionWt.%
DEHYQUART® F 750,3
Calcare® SC 965,0
Gluadin® WQ/td> 1,5
Dow Corning®200 Fluid, 5 cSt.151,5
Dihydro-3-hydroxy-4,4-dimethyl-2-(3H)-furanone0,5
Rafkat® 755N161,5
Biodomes®170,02
Perfume oil0,25
Water100
15The polydimethylsiloxane (INCI-name: Dimethicone) (the company Dow Corning)
16Dimethylaminoethylmethacrylate-vinyl pyrrolidone copolymer, dimethylsulfate Quaternary (19% active substance in water; INCI-name: polyquaternium-11) (company GAF)
173-Iodine-2-propenyl-n-BUTYLCARBAMATE (INCI-name: improper of BUTYLCARBAMATE) (company Milker & Gruning)

23. The treatment for hair
CompositionWt.%
Sepigel® 3055,0
Dow Corning® Q2-5220181,5
Promos® milk Q193,0
Polymer P1 according to the patent Germany 39291730,6
Dihydro-3-hydroxy-4,4-dimethyl-2-(3H)-furanone0,5
the enamine® DSAC200,3
Phenonip®0,8
Perfume oil0,25
Water100
18The silicone-glycol copolymer (INCI-name: Dimethicone copolyol) (the company Dow Corning)
19INCI-name: hydroxypropyltrimonium hydrolyzed casein, about 30% of the active substance (firm Saves Kazei)
20Dimethyldioctadecylammonium (INCI-name: distearyldimonium chloride) (company Clariant)

24. Shampoo
CompositionWt.%
Texapon® NSO21(the firm Cognis)40,0
Dehyton® G22(the firm Cognis)6,0
Polymer JR 400®230,5
Cetiol® NOT240,5
AGU® NL 50251,0
Gluadin® WQT262,5
Dihydro-3-hydroxy-4,4-dimethyl-2-(3H)-furanone0,5
Gluadin® W200,5
Panthenol (50%)0,3
Vitamin E0,1
Vitamins is N 0,1
Citric acid0,5
Sodium benzoate0,5
Perfume oil0,4
Sodium chloride0,5
Water100
21Matricariifolium about 28% of the active substance (INCI-name: sodium Laureth sulfate) (company Cognis)
22INCI-name: sodium cocoamphoacetate about 30% of the active substance (the firm Cognis)
23Kaarniranta hydroxyethyl cellulose (INCI-name: polyquaternium-10) (company Union carbide)
24Polyol fatty acid ester (INCI-name: PEG-7 glyceryl Cocoate) (company Cognis)
25Sodium salt of 2-pyrrolidinone-5-carboxylic acid (firm Inomoto)
2INCI-name: Hydroxypropyltrimonium hydrolyzed wheat protein (company Cognis)

EUPERLAN® RC29
25. Shampoo
CompositionWt.%
Texapon® NSO43,0
Dehyton®2710,0
PLANTACARE® 1200 UP284,0
1,6
Arkad® 316300,8
Polymer® JR 4000,3
Gluadin® WQ4,0
Glutamat® DOE 120310,5
Dihydro-3-hydroxy-4,4-dimethyl-2-(3H)-furanone0,5
Sodium chloride0,2
Water100
27INCI-name: Cocamidopropyl betaine, about 30% of the active substance (the firm Cognis)
28Glycoside With12-C16fatty alcohol, about 50% of the active substance (INCI-name: lauryl glucoside) (company Cognis)
29Liquid dispersion of the substance, giving pearly luster, and amphoteric surfactants (62% of active substance; CTFA-name: glycol distearate (and) glycerin (and) Laureth-4 (and) cocamidopropyl betaine) (company Cognis)
30Three-C16-allylmethylamine (firm Akzo)
31The ethoxylated methylglucoside-dioleate (CTFA-name: PEG-120 methyl glucose dioleate) (firm Amerchol)

26. Shampoo
The composition of Wt.%
Texapon® N 703221,0
PLANTACARE® 1200 UP8,0
Gluadin® WQ1,5
Cutin® EGMS330,6
Chanicut® 50342,0
AGU® NL 502,8
The Antilles® 141351,3
Dihydro-3-hydroxy-4,4-dimethyl-2-(3H)-furanone0,5
Sodium chloride0,2
Magnesium hydroxideto pH 4.5
Water100
32Matricariifolium with 2 mol of MA, about 70% of the active substance (INCI-name: sodium Laureth sulfate) (company Cognis)
33Ethylenglykolether (about 25-35% of monoether, 60-70% of diapir (INCI-name: glycol stearate) (company Cognis)
34INCI-name: hydroxypropyltrimonium honey (about 50% active substance) (firm Brooks)
35Polyoxyethylene-propilenglikolstearat (40% active substance; INCI-name: propylene glycol (and) PEG-55 propylene glycol oleate) (company Goldschmidt)

/tr>
27. Shampoo
CompositionWt.%
Texapon® 14 S3650,0
Dehyton®10,0
PLANTACARE® 818 UP374,5
Polymer P1 according to the patent Germany 39291730,6
Cutin® AGS382,0
D-Panthenol0,5
Glucose1,0
Dihydro-3-hydroxy-4,4-dimethyl-2-(3H)-furanone0,5
Salicylic acid0,4
Sodium chloride0,5
Gluadin® WQ2,0
Water100
36Acryloyldimethyltaurate about 28% of the active substance (INCI-name: sodium Miret sulfate) (company Cognis)
37Glycoside With8-C16fatty alcohol about 50% of the active substance (INCI-name: Coco glucoside) (company Cognis)
38Ethylenglykolether (about 5-15% of monoether, 85-95% of diapir (INCI-name: glycol distearate) (company Cognis)

28. The treatment for hair
CompositionWt.%
Selka the® L 200390,6
Loviscol® 30400,2
D-Panthenol0,5
Polymer P1 according to the patent Germany 39291730,6
DEHYQUART® AND-CA411,0
Gluadin® W 40421,0
Natrosol® 250 HR431,1
Dihydro-3-hydroxy-4,4-dimethyl-2-(3H)-furanone0,5
Gluadin® WQ2,0
Water100
39Stereoselectivity derived cellulose (95% of active substance; CTFA-name: polyquaternium-4) (firm Delft national)
40Polyvinylpyrrolidone (50% active substance; CTFA-name: PVP) (firm BASF)
41Cetyltrimethylammoniumbromide (INCI-name: Cetrimonium chloride) (company Cognis)
42A partial hydrolysate of wheat OC% of the active substance (INCI-name: hydrolyzed wheat gluten hydrolyzed wheat protein) (company Cognis)
43Hydroxyethylcellulose (firm Aqualon)

td align="center"> Composition
29. The cream-paint
Wt.%
With12-C18fatty alcohol1,2
Lanett®444,0
Emulgin® B20,8
Cutin® KD 16452,0
Sodium sulfite0,5
L(+)-Ascorbic acid0,5
Ammonium sulfate0,5
1,2-Propylene glycol1,2
Polymer JR® 4000,3
p-Aminophenol0,35
p-Commencemen0,85
2-Methylresorcinol0,14
6-Methyl-m-aminophenol0,42
Cetiol® TH460,5
Dihydro-3-hydroxy-4,4-dimethyl-2-(3H)-furanone0,5
Chanicut® 501,0
AGU® NL 501,2
Gluadin® WQ1,0
Ammonia1,5
Water100
44Cetylstearyl alcohol (INCI-name: Cetearyl alcohol) (company Cognis)
45Self emulsifiable mixture of mono-/diglycerides of higher saturated fatty acids with article what Arat potassium (INCI-name: glyceryl stearate SE) (company Cognis)
46Di-n-oktilovom ether (INCI-name: dicaprylyl ether) (company Cognis)

30. Revealing variance for the cream-paint 29
CompositionWt.%
Texapon® NSO2,1
Hydrogen peroxide (50%)to 12.0
Turbinal® SL471,7
Latecoll® D48to 12.0
Dihydro-3-hydroxy-4,4-dimethyl-2-(3H)-furanone0,5
Gluadin® WQ0,3
Calcare® SC 961,0
Water100
471-Hydroxyethane-1,1-diphosphonic acid (60% active substance; INCI-name: heteronympha acid) (company Cognis)
48Copolymer of acrylic ester and methacrylic acid (25% active substance) (firm BASF)
The cream color has a pH of 10.0. Colors the hair in intense red tones.

31. Toning shampoo
CompositionWt.%
Texapon® N 7014,0
Dehyton®10,0
Ukipo® RLM 45 NV4914,7
PLANTACARE® 1200 UP4,0
Polymer P1 according to the patent Germany 39299730,3
Cremophor® RH 40500,8
Dye C.I. 12 7190,02
Dye C.I. 12 2510,02
Dye C.I. 12 2500,04
Dihydro-3-hydroxy-4,4-dimethyl-2-(3H)-furanone0,5
Dye C.I. 56 0590,03
Preservative0,25
Perfume oila sufficient quantity
Eutanol® G510,3
Gluadin® WQ1,0
Chanicut® 501,0
Calcare® SC 960,5
Water100
49Lauric alcohol + 4.5 ethylene oxide-acetic acid-sodium salt (20.4% of active substance) (firm hem-Y)
50Castor oil, gidrirovannoe+45 etilenoksida (INCI-name: PEG-40 hydrogenomonas castor oil), BASF)
512-Octyldodecanol (gerberoy alcohol (INCI-name octyldodecanol) (company Cognis)

When washing this hair toning shampoo they get a brilliant light brown color.

32. Cream permanent
CompositionWt.%
Cream perms
PLANTACARE® 810 UP525,0
Thioglycolate acid8,0
Turbinal® SL0,5
Ammonia (25%)7,3
Ammonium carbonate3,0
Cetylstearyl alcohol5,0
Gerberoy alcohol4,0
Dihydro-3-hydroxy-4,4-dimethyl-2-(3H)-furanone0,5
Calcare® SC 963,0
Gluadin® WQ2,0
Perfume oila sufficient quantity
Water100
52C8-C10-Alkylglucoside with a degree of polymerization of 1.6 (OC% active substance) (company Cognis)
Fixative
PLANTACARE® 810 UP5,0
Utverjdenie castor oil2,0
the Romat potassium 3,5
Nitrilotriacetate acid0,3
Citric acid0,2
Dihydro-3-hydroxy-4,4-dimethyl-2-(3H)-furanone0,5
Marquet® 550530,5
HYDAGEN® HCMF540,5
Gluadin® WQ0,5
Perfume oila sufficient quantity
Water100
53Dimethyldiallylammonium-acrylamide copolymer (8% active substance; INCI-name: polyquaternium 7) (company Mobil oil)
54Chitosan powder (INCI-name: chitosan) (company Cognis)

1. Cosmetic care for and maintain the natural functions of the hair, containing conventional cosmetic raw materials, characterized in that it contains

2-pornoprovini formula (I)

in which the residues R1and R2mean independently from each other

hydrogen, - HE, methyl-, methoxy-, aminomethyl or hydroclimatology balance

saturated or unsaturated with 1 or 2 double bonds, branched or linear hydrocarbon residue with 2 to 4 carbon atoms,

on ewenny or unsaturated with 1 or 2 double bonds, branched or linear mono-, di - or trihydroxyflavanone residue with 2 to 4 carbon atoms,

saturated or unsaturated with 1 or 2 double bonds, branched or linear mono-, di - or triaminoguanidine residue with 2 to 4 carbon atoms,

group OR11with R11in the form of saturated or unsaturated with 1 or 2 double bonds, branched or linear hydrocarbon residue with 2 to 4 carbon atoms, saturated or unsaturated with 1 or 2 double bonds, branched or linear mono-, di - or trihydroxyflavanone residue with 2 to 4 carbon atoms,

the group-NR12R13while R12and R13respectively denote independently from each other hydrogen, methyl, saturated or unsaturated with 1 or 2 double bonds, branched or linear hydrocarbon residue with 2 to 4 carbon atoms, saturated or unsaturated with 1 or 2 double bonds, branched or linear mono-, di - or trihydroxyflavanone residue with 2 to 4 carbon atoms,

group-COOR14while R14means hydrogen, methyl, saturated or unsaturated with 1 or 2 double bonds, branched or linear hydrocarbon residue with 2 to 4 carbon atoms, saturated or unsaturated with 1 or 2 double bonds, razwell the config or linear mono-, di - or trihydroxyflavanone residue with 2 to 4 carbon atoms, saturated or unsaturated with 1 or 2 double bonds, branched or linear mono-, di - or triaminoguanidine residue with 2 to 4 carbon atoms,

the group-COR16while R16means methyl, saturated or unsaturated with 1 or 2 double bonds, branched or linear hydrocarbon residue with 2 to 4 carbon atoms, saturated or unsaturated with 1 or 2 double bonds, branched or linear mono-, di - or trihydroxyflavanone residue with 2 to 4 carbon atoms, saturated or unsaturated with 1 or 2 double bonds, branched or linear mono-, di - or triaminoguanidine residue with 2 to 4 carbon atoms,

group-OCOR17while R17means methyl, saturated and/or mono - or polyunsaturated branched or linear hydrocarbon residue with 2 to 30 carbon atoms, saturated and/or mono - or polyunsaturated branched or linear mono-, di-, tri - or polyhydroxyalkanoates residue with 2 to 30 carbon atoms, saturated and/or mono - or polyunsaturated branched or linear mono-, di-, tri - or polyaminopropyl residue with 2 to 30 carbon atoms;

the remains of R3and R4mean independently from each other:

HE METI the-, methoxy-, aminomethyl-, hydroxymethylene balance

saturated or unsaturated with 1 or 2 double bonds, branched or linear hydrocarbon residue with 2 to 4 carbon atoms,

saturated or unsaturated with 1 or 2 double bonds, branched or linear mono-, di - or trihydroxyflavanone residue with 2 to 4 carbon atoms,

saturated or unsaturated with 1 or 2 double bonds, branched or linear mono-, di - or triaminoguanidine residue with 2 to 4 carbon atoms;

the remains of R5and R6mean independently from each other:

hydrogen, - HE, methyl-, methoxy-, aminomethyl-, hydroxymethylene balance

saturated or unsaturated with 1 or 2 double bonds, branched or linear hydrocarbon residue with 2 to 4 carbon atoms,

saturated or unsaturated with 1 or 2 double bonds, branched or linear mono-, di - or trihydroxyflavanone residue with 2 to 4 carbon atoms,

saturated or unsaturated with 1 or 2 double bonds, branched or linear mono-, di - or triaminoguanidine residue with 2 to 4 carbon atoms;

at least one compound selected from polymers;

and

at least one compound selected from the hydrolysates FR is on and their derivatives.

2. Cosmetic according to claim 1, characterized in that the compound of formula (I) is dihydro-3-hydroxy-4,4-dimethyl-2(3H)-furanone.

3. Cosmetic according to claim 1 or 2, wherein the tool further comprises a surfactant.

4. Cosmetic according to claim 1 or 2, wherein the tool further comprises an emulsifier.

5. Cosmetic according to claim 1 or 2, wherein the tool further comprises a fatty substance.

6. Cosmetic according to claim 1 or 2, wherein the tool further comprises a vitamin, a provitamin, a precursor of vitamin a or derivatives thereof.



 

Same patents:

FIELD: medicine; cosmetology.

SUBSTANCE: composition for local application contains: i) anti-dandruff agent; ii) conjugated linoleic acid and iii) cosmetic acceptable dissolvent or carrier.

EFFECT: invention provides increased efficiency in treatment and prevention of dandruff and itching of scalp skin.

14 cl, 1 dwg, 2 ex

Film composition // 2323715

FIELD: medicine, stomatology.

SUBSTANCE: invention relates to film compositions for delivering local and systemic substances, in general, and to slow dissolving or decomposing films, in particular.

EFFECT: provides more efficient delivery of oral agents to teeth and gums.

15 cl, 5 ex

FIELD: chemistry.

SUBSTANCE: invention relates to film compositions, which contain in a single layer: a) at least one water-insoluble polymer; b) at least one debonder from the group, which consists of water-insoluble particles, plastisizer and mixtures thereof; c) optionally, at least one local or system agent, where the film aqueous degradation is possible.

EFFECT: film with barrier characteristics and controlled degradation properties.

14 cl, 7 ex

FIELD: medicine, cosmetology.

SUBSTANCE: invention relates to cosmetics field and applies to cosmetic and/or dermatological preparations, which contain lecithin and essential fatty acids.

EFFECT: maximal skin moistening is provided and healing of injured skin is maintained.

12 cl, 10 ex

FIELD: medicine, stomatology.

SUBSTANCE: composition contains about 10 to 13 weight percent of water and abrasive low-structured precipitated silica dioxide, which has the refraction index about 1.439 to 1.450, index of lipid uptake about 90 to 120 mL/100g, optical transmission more than 60% and Brass Einlehner abrasion value less than 5 mg loss/100 000 rev. In addition, dental care agent has opacity index less than 50 and RDA about 50 to 200, refraction index about 1.439 to 1.450.

EFFECT: abrasive efficiency is increased.

7 cl, 6 tbl, 2 ex, 1 dwg

FIELD: personal hygiene commodities.

SUBSTANCE: invention relates to aqueous fluid compositions and aims at obtaining fluid non-Newton on shear liquefiable composition suitable for use in personal hygiene commodities, which composition is capable of slurring water-insoluble particles and manifests stability under freezing/thawing conditions. Invention provides fluid composition containing, based on the mass of composition, at least one anionic surfactant, 5-30%, at least one alkanolamine, 0.1-10%, at least one electrolyte, and water. Composition may further contain one or several supplemental surfactants. Composition of invention has layered liquid-crystalline structure, has non-Newton on shear liquefaction property, and ability of slurring water-insoluble particles or partially insoluble components, while being stable in at least one freezing/thawing cycle. Proposed are also a method of preparing indicated composition or stable multiphase composition based thereon.

EFFECT: extended choice of practically useful on shear-liquefiable compositions.

54 cl, 11 tbl, 5 ex

FIELD: personal hygiene commodities.

SUBSTANCE: invention relates to aqueous fluid compositions and aims at obtaining fluid non-Newton on shear liquefiable composition suitable for use in personal hygiene commodities, which composition is capable of slurring water-insoluble particles and manifests stability under freezing/thawing conditions. Invention provides fluid composition containing, based on the mass of composition, at least one anionic surfactant, 5-30%, at least one alkanolamine, 0.1-10%, at least one electrolyte, and water. Composition may further contain one or several supplemental surfactants. Composition of invention has layered liquid-crystalline structure, has non-Newton on shear liquefaction property, and ability of slurring water-insoluble particles or partially insoluble components, while being stable in at least one freezing/thawing cycle. Proposed are also a method of preparing indicated composition or stable multiphase composition based thereon.

EFFECT: extended choice of practically useful on shear-liquefiable compositions.

54 cl, 11 tbl, 5 ex

FIELD: organic chemistry, medicine, pharmacy, cosmetology.

SUBSTANCE: invention relates to novel biphenylmethylthiazolidinedions of the general formula (I): , their salts, and to their optical and geometrical isomers possessing agonistic activity with respect to PPARγ receptors, to pharmaceutical and cosmetic compositions based on thereof, and to their using for preparing composition used in treatment of different cutaneous diseases. In compound of the formula (I) R1 means radical of the following formula (a): or (b): ; R2 and R3 mean hydrogen atom; X means binding groups showing the following structures: -CH2-N(R8)-CO-, -N(R8)-CO-N(R9)- that can be read from left to right or vice versa; R4 means phenyl substituted with group R10, pyrrolyl, naphthyl, biphenyl, indenyl, benzothienyl and all these groups can be mono- or di-substituted with group R11 and/or R12, group -(CH2)n-(CO)qR13, adamantyl, cyclopentylethyl, group -(CH2)n-O-R13; R5 means hydroxyl or alkoxyl with 1-19 carbon atoms; R6 means group -OR14. Values R8, R9, R10, R11, R12, R13, n and q are given in the invention claim.

EFFECT: valuable medicinal properties of compounds.

25 cl, 2 dwg, 37 ex

FIELD: organic chemistry, medicine, pharmacy, cosmetology.

SUBSTANCE: invention relates to novel biphenylmethylthiazolidinedions of the general formula (I): , their salts, and to their optical and geometrical isomers possessing agonistic activity with respect to PPARγ receptors, to pharmaceutical and cosmetic compositions based on thereof, and to their using for preparing composition used in treatment of different cutaneous diseases. In compound of the formula (I) R1 means radical of the following formula (a): or (b): ; R2 and R3 mean hydrogen atom; X means binding groups showing the following structures: -CH2-N(R8)-CO-, -N(R8)-CO-N(R9)- that can be read from left to right or vice versa; R4 means phenyl substituted with group R10, pyrrolyl, naphthyl, biphenyl, indenyl, benzothienyl and all these groups can be mono- or di-substituted with group R11 and/or R12, group -(CH2)n-(CO)qR13, adamantyl, cyclopentylethyl, group -(CH2)n-O-R13; R5 means hydroxyl or alkoxyl with 1-19 carbon atoms; R6 means group -OR14. Values R8, R9, R10, R11, R12, R13, n and q are given in the invention claim.

EFFECT: valuable medicinal properties of compounds.

25 cl, 2 dwg, 37 ex

FIELD: medicine, dermatology.

SUBSTANCE: the present innovation deals with applying the preparation to prevent contact allergic dermatitis induced with salts of nickel or other metals under conditions of nickel plating at galvanic manufacturing. The preparation for preventing contact allergic dermatitis induced with nickel salts contains natural zeolite (for example, from Kholinskoe origin at isolated fraction being less than 0.25 mm). It consists of zeolite dispersed in the foundation out of starchy gel at the following ratio of the components, weight%: zeolite 26.0-29.0; 2.0-4.0 weight% starchy gel - the rest. The preparation declared is of good sorption properties, covers the skin steadily and is retained well upon it; it is easily removed with water that in combination enables to decrease the quantity of nickel ions in surface and deep cutaneous layers and, thus, prevents the development of contact dermatosis.

EFFECT: higher efficiency of prophylaxis.

3 ex, 1 tbl

FIELD: medicine; cosmetology.

SUBSTANCE: composition for local application contains: i) anti-dandruff agent; ii) conjugated linoleic acid and iii) cosmetic acceptable dissolvent or carrier.

EFFECT: invention provides increased efficiency in treatment and prevention of dandruff and itching of scalp skin.

14 cl, 1 dwg, 2 ex

Film composition // 2323715

FIELD: medicine, stomatology.

SUBSTANCE: invention relates to film compositions for delivering local and systemic substances, in general, and to slow dissolving or decomposing films, in particular.

EFFECT: provides more efficient delivery of oral agents to teeth and gums.

15 cl, 5 ex

FIELD: chemistry.

SUBSTANCE: invention relates to film compositions, which contain in a single layer: a) at least one water-insoluble polymer; b) at least one debonder from the group, which consists of water-insoluble particles, plastisizer and mixtures thereof; c) optionally, at least one local or system agent, where the film aqueous degradation is possible.

EFFECT: film with barrier characteristics and controlled degradation properties.

14 cl, 7 ex

FIELD: medicine, cosmetology.

SUBSTANCE: invention relates to cosmetics field and applies to cosmetic and/or dermatological preparations, which contain lecithin and essential fatty acids.

EFFECT: maximal skin moistening is provided and healing of injured skin is maintained.

12 cl, 10 ex

FIELD: medicine, stomatology.

SUBSTANCE: composition contains about 10 to 13 weight percent of water and abrasive low-structured precipitated silica dioxide, which has the refraction index about 1.439 to 1.450, index of lipid uptake about 90 to 120 mL/100g, optical transmission more than 60% and Brass Einlehner abrasion value less than 5 mg loss/100 000 rev. In addition, dental care agent has opacity index less than 50 and RDA about 50 to 200, refraction index about 1.439 to 1.450.

EFFECT: abrasive efficiency is increased.

7 cl, 6 tbl, 2 ex, 1 dwg

FIELD: personal hygiene commodities.

SUBSTANCE: invention relates to aqueous fluid compositions and aims at obtaining fluid non-Newton on shear liquefiable composition suitable for use in personal hygiene commodities, which composition is capable of slurring water-insoluble particles and manifests stability under freezing/thawing conditions. Invention provides fluid composition containing, based on the mass of composition, at least one anionic surfactant, 5-30%, at least one alkanolamine, 0.1-10%, at least one electrolyte, and water. Composition may further contain one or several supplemental surfactants. Composition of invention has layered liquid-crystalline structure, has non-Newton on shear liquefaction property, and ability of slurring water-insoluble particles or partially insoluble components, while being stable in at least one freezing/thawing cycle. Proposed are also a method of preparing indicated composition or stable multiphase composition based thereon.

EFFECT: extended choice of practically useful on shear-liquefiable compositions.

54 cl, 11 tbl, 5 ex

FIELD: personal hygiene commodities.

SUBSTANCE: invention relates to aqueous fluid compositions and aims at obtaining fluid non-Newton on shear liquefiable composition suitable for use in personal hygiene commodities, which composition is capable of slurring water-insoluble particles and manifests stability under freezing/thawing conditions. Invention provides fluid composition containing, based on the mass of composition, at least one anionic surfactant, 5-30%, at least one alkanolamine, 0.1-10%, at least one electrolyte, and water. Composition may further contain one or several supplemental surfactants. Composition of invention has layered liquid-crystalline structure, has non-Newton on shear liquefaction property, and ability of slurring water-insoluble particles or partially insoluble components, while being stable in at least one freezing/thawing cycle. Proposed are also a method of preparing indicated composition or stable multiphase composition based thereon.

EFFECT: extended choice of practically useful on shear-liquefiable compositions.

54 cl, 11 tbl, 5 ex

FIELD: organic chemistry, medicine, pharmacy, cosmetology.

SUBSTANCE: invention relates to novel biphenylmethylthiazolidinedions of the general formula (I): , their salts, and to their optical and geometrical isomers possessing agonistic activity with respect to PPARγ receptors, to pharmaceutical and cosmetic compositions based on thereof, and to their using for preparing composition used in treatment of different cutaneous diseases. In compound of the formula (I) R1 means radical of the following formula (a): or (b): ; R2 and R3 mean hydrogen atom; X means binding groups showing the following structures: -CH2-N(R8)-CO-, -N(R8)-CO-N(R9)- that can be read from left to right or vice versa; R4 means phenyl substituted with group R10, pyrrolyl, naphthyl, biphenyl, indenyl, benzothienyl and all these groups can be mono- or di-substituted with group R11 and/or R12, group -(CH2)n-(CO)qR13, adamantyl, cyclopentylethyl, group -(CH2)n-O-R13; R5 means hydroxyl or alkoxyl with 1-19 carbon atoms; R6 means group -OR14. Values R8, R9, R10, R11, R12, R13, n and q are given in the invention claim.

EFFECT: valuable medicinal properties of compounds.

25 cl, 2 dwg, 37 ex

FIELD: organic chemistry, medicine, pharmacy, cosmetology.

SUBSTANCE: invention relates to novel biphenylmethylthiazolidinedions of the general formula (I): , their salts, and to their optical and geometrical isomers possessing agonistic activity with respect to PPARγ receptors, to pharmaceutical and cosmetic compositions based on thereof, and to their using for preparing composition used in treatment of different cutaneous diseases. In compound of the formula (I) R1 means radical of the following formula (a): or (b): ; R2 and R3 mean hydrogen atom; X means binding groups showing the following structures: -CH2-N(R8)-CO-, -N(R8)-CO-N(R9)- that can be read from left to right or vice versa; R4 means phenyl substituted with group R10, pyrrolyl, naphthyl, biphenyl, indenyl, benzothienyl and all these groups can be mono- or di-substituted with group R11 and/or R12, group -(CH2)n-(CO)qR13, adamantyl, cyclopentylethyl, group -(CH2)n-O-R13; R5 means hydroxyl or alkoxyl with 1-19 carbon atoms; R6 means group -OR14. Values R8, R9, R10, R11, R12, R13, n and q are given in the invention claim.

EFFECT: valuable medicinal properties of compounds.

25 cl, 2 dwg, 37 ex

FIELD: medicine, dermatology.

SUBSTANCE: the present innovation deals with applying the preparation to prevent contact allergic dermatitis induced with salts of nickel or other metals under conditions of nickel plating at galvanic manufacturing. The preparation for preventing contact allergic dermatitis induced with nickel salts contains natural zeolite (for example, from Kholinskoe origin at isolated fraction being less than 0.25 mm). It consists of zeolite dispersed in the foundation out of starchy gel at the following ratio of the components, weight%: zeolite 26.0-29.0; 2.0-4.0 weight% starchy gel - the rest. The preparation declared is of good sorption properties, covers the skin steadily and is retained well upon it; it is easily removed with water that in combination enables to decrease the quantity of nickel ions in surface and deep cutaneous layers and, thus, prevents the development of contact dermatosis.

EFFECT: higher efficiency of prophylaxis.

3 ex, 1 tbl

FIELD: medicine; cosmetology.

SUBSTANCE: composition for local application contains: i) anti-dandruff agent; ii) conjugated linoleic acid and iii) cosmetic acceptable dissolvent or carrier.

EFFECT: invention provides increased efficiency in treatment and prevention of dandruff and itching of scalp skin.

14 cl, 1 dwg, 2 ex

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