Cationic polymeric composition for using as conditioner, method for its preparing, composition for conditioning of surfaces, composition of household chemistry agent, composition of personal hygiene agent

FIELD: chemistry of polymers.

SUBSTANCE: invention describes a composition for using as a conditioner and comprising water and at least one cationic polygalactomannan or derivative of cationic polygalactomannan. A lower limit of average molecular mass of these cationic substances is 5000 Da and the upper limit is 200000 Da, transparency value of 10% aqueous solution is above 80% at wavelength 600 nm. The protein content is less 1.0% as measured for polysaccharide mass and the content of aldehyde groups is at least 0.01 ml-eqiv./g. Residue for modification of cationic derivative of polygalactomannan is chosen from group comprising alkyl, hydroxyalkyl, alkylhydroxyalkyl and carboxymethyl wherein alkyl comprises in chain from 1 to 22 carbon atoms, Hydroxyalkyl is chosen from group comprising hydroxyethyl, hydroxypropyl and hydroxybutyl, and cation residue is chosen from compounds of quaternary ammonium but with exception of hydroxypropyl trimethyl ammonium chloride. Proposed compositions are used for preparing a clear final product, for example, for personal hygiene agent and household chemistry agent.

EFFECT: improved preparing method, improved and valuable properties of composition.

55 cl, 11 tbl, 14 ex

 

The text descriptions are given in facsimile form.

1. The composition for use as an air conditioner, comprising water and at least one cationic polygalacturonase or derivative of cationic polygalacturonase, the lower limit of the mass-average molecular mass (MM) which is 5,000 and an upper limit of 200,000, the transmittance of a 10%aqueous solution is more than 80% at a wavelength of 600 nm, and the protein content is less than 1.0% calculated on the weight of the polysaccharide and the content of aldehyde groups of at least 0.01 mlaku./g, where the remainder for modification of the cationic derivative of polygalacturonase selected from the group including alkyl, hydroxyalkyl, alkylhydroxylamines and carboxymethyl, where alkyl contains in the chain from 1 to 22 carbon atoms, and hydroxyalkyl selected from the group including g proxetil, hydroxypropyl and hydroxybutyl, and the rest of the cation is selected from Quaternary ammonium compounds, with the exception of the hydroxypropyl ammonium chloride.

2. The composition according to claim 1, in which the lower limit of the degree of substitution (Sz) cationic groups is approximately 0,001, and the upper limit is approximately 2.0.

3. The composition according to claim 2, in which the lower limit of the degree of substitution (Sz) cationic groups is about 0.01.

4. The composition according to claim 2, in which the upper limit of the degree of substitution (Sz) cationic substituents is approximately 1.0,

5. The composition according to claim 1, in which polyglutamine chosen from the group comprising guar gum and locust beans.

6. The composition according to claim 1, in which the connection Quaternary ammonium compounds are selected from the group comprising chloride 3-chloro-2-hydroxypropyltrimethylammonium, chloride 2,3-epoxypropyltrimethylammonium, bromide, 3-chloro-2-hydroxypropyltrimethylammonium, bromide, 2,3-epoxypropyltrimethylammonium, chloride of glycidylmethacrylate, chloride of glycidylmethacrylate, chloride of glycidaldehyde, chloride of glycidylmethacrylate, chloride of glycidylmethacrylate and their corresponding bromides and iodides; chloride 3-chloro-2-hydroxypropyltrimethylammonium, chloride 3-chloro-2-hydroxypropyltrimethylammonium, chloride 3-chloro-2-hydroxypropyltrimethylammonium, chloride is 3-chlorine is-2-hydroxypropyltrimethylammonium and their corresponding bromides and iodides;

and halide derivatives of imidazole.

7. The composition according to claim 1, in which the value of transmittance is more than 90%.

8. The composition according to claim 1, in which the amount of light transmission is more than 95%.

9. The composition according to claim 1, in which the protein content is less than about 0.5% based on the weight of polysaccharide.

10. The composition according to claim 1, in which the lower limit MM is 20000.

11. The composition according to claim 1, in which the lower limit MM is 35,000.

12. The composition according to claim 1, in which the lower limit MM is 50,000.

13. The composition according to claim 1, in which the upper limit MM is 100,000.

14. The composition according to claim 1, in which the upper limit MM is 70000.

15. The composition according to claim 1, additionally comprising a component selected from the group comprising a dye, a preservative, an antioxidant, alpha - or beta-hydroxy acids, power activity, emulsifier, functional polymer, thickener, alcohol, fat or fatty compound, an antimicrobial compound, pyrithione zinc, silicon material, a hydrocarbon polymer, a softening tools, oil, surfactant, suspendresume agents and mixtures thereof.

16. The composition according to item 15, in which the functional polymer is chosen from the group comprising anionic, hydrophobizated and amphoteric copolymers of acrylic acid, homopolymers and copolymers of vinylpyrrolidone; cationic FOSS is emery vinylpyrrolidone, nonionic, cationic, anionic and amphoteric polymers based on cellulose, the homopolymers of acrylamide, cationic, anionic, amphoteric and hydrophobizated copolymers of acrylamide, polymers and copolymers of polyethylene glycol, hydrophobizated polyethers, hydrophobizated (easy polyester) acetals, hydrophobizated (easy polyester) urethanes, an associative polymer, hydrophobizated polymers based on cellulose, copolymers of polyethylene oxide and propylene oxide, and nonionic, anionic, hydrophobizated, amphoteric and cationic polysaccharides, chitosan, and mixtures thereof.

17. The composition according to item 16, in which the nonionic, cationic, anionic and amphoteric polymers based on cellulose selected from the group comprising hydroxyethyl cellulose, hydroxypropylcellulose, hypromellose, carboxymethylcellulose, gidrofobizirovannogo carboxymethylcellulose, cationic hydroxyethyl cellulose, cationic gidrofobizirovannogo hydroxyethyl cellulose, gidrofobizirovannogo hydroxyethyl cellulose, gidrofobizirovannogo hydroxypropylcellulose, cationic gidrofobizirovannogo hydroxypropylcellulose, the cationic karboksimetiltselljuloza and the cationic hydroxypropylcellulose.

18. The composition according to item 16, in which the nonionic, anionic, hydrophobizated, amphoteric, Katie the major polysaccharides are selected from the group including carboxitherapy polymer, alginates, hydroxypropylmethyl polymer gidrofobizirovannym guar polymer, hydroxypropyltrimethylammonium karboksimetilovogo polymer, hydroxypropyltrimethylammonium guar polymer, hydroxypropyltrimethylammonium hydroxypropylcellulose polymer.

19. The composition according to item 15, in which the thickener is chosen from the group comprising NaCl, NH4Cl, KCl and fatty alcohols, esters of fatty acids, amides of fatty acids, ethers of fatty alcohols and glycol ethers of sorbitol and polyethylene glycol, cocamidopropylbetaine, clay, silica, polymers based on cellulose, xanthan gum and mixtures thereof.

20. The composition according to item 15, in which the silicone material selected from the group including cyclosiloxane, linear siloxane, comb or graft structure of siloxane-containing polyol as one group, amino groups or other functional groups, and mixtures thereof.

21. The composition according to claim 20, in which other functional groups are selected from the group including polietilenoksidy and/or polypropyleneoxide, optional contains6-C24alkyl groups, substituted or unsubstituted amino group, tirinya group, alkoxysilane group, hydroxyl group, aryloxyalkyl group.

22. The composition according to p, in which silicone material selected from the group including polyalkyloxy, polyacrilamide, polyalkylacrylate and mixtures thereof.

23. The composition according to item 22, in which polyalkyloxy selected from the group including polydimethylsiloxane, polydimethylsiloxane containing terminal fragment chain hydroxyl groups, and mixtures thereof.

24. The composition according to item 15, in which the surfactant is anionic, amphoteric or nonionic.

25. A method of obtaining a composition according to claim 1, comprising (a) interaction of at least one cation of polygalacturonase or derivative of cationic polygalacturonase with at least one reagent in the aquatic environment, which reduces MM to less than 200000, where the reagent is an oxidizing agent selected from the group comprising peroxides, persulfates, permanganates, perchlorates, sodium hypochlorite, oxygen and biochemical oxidants, with specified polymer include water-soluble colored particles and water-insoluble material, with the formation of aqueous dispersions treated polygalacturonase, and (b) removing water-insoluble material to form a clarified solution composition.

26. The method according A.25, in which the peroxide is hydrogen peroxide.

27. The method according A.25, in which biochemical oxidant is oxygenase.

28. The method according to item 27, in which the hydroxy what ensoy is galactosaminidase.

29. The method according A.25, in which the reagent also includes a hydrolytic reagent.

30. The method according to clause 29, in which the aforementioned hydrolytic reagent selected from the group including hydrolytic enzymes.

31. The method according to item 30, in which the aforementioned hydrolytic enzyme selected from the group comprising hemicellulase.

32. The method according to p in which hemicellulose is mannanase.

33. The method according to clause 29, in which the aforementioned hydrolytic reagent is an organic or mineral acid.

34. The method according A.25, moreover, including the removal of the water-soluble colored particles.

35. The method according A.25, moreover, including the removal of the water-soluble colored particles with the formation of bleached colorless aqueous solution.

36. The method according to p, in which water-soluble colored particles can be removed by adding sodium metabisulfite, sodium bisulfite, sodium hypochlorite or sodium chlorite.

37. The method according to p, in which water-soluble colored particles removed by the addition of activated carbon with its branch at the next stage.

38. The method according to p, in which water-soluble colored particles can be removed by adding molecular sieves to their office at the next stage.

39. The method according A.25, in addition, includes derivatization of polygalacturonase in dry form from the underwater solution.

40. The method according A.25, in which the cationic polygalacturonase or derived polygalacturonase is in powder form, powder or crushed particles.

41. Composition for conditioning surfaces, including composition according to claim 1, whereby the surface is chosen from the group comprising skin, hair and textile substrates.

42. Composition of household chemical goods, including composition according to claim 1.

43. Composition of household chemical goods by 42, comprising at least one other active ingredient used in household products.

44. Composition of household chemicals on p.43, in which the active ingredient of household chemicals selected from the group including agent to deter insects, deodorant for animals, an active agent for washing animals, active agent for liquid and solid technical Soaps, active agent for funds for dishwashing, universal detergent, disinfecting agent, active agent for cleaning carpets and upholstery, active agent for softening the washing means, the active agent for washing tools, agent for cleaning toilet bowls, agent for impregnation of fabrics, dust collecting agent, an agent to prevent re-deposition agent for cleaning fabrics and softener.

45. Composition of household chemicals on p.43, and the composition is e includes at least one additional ingredient, selected from the group comprising a colorant, preservative, antioxidant, bleach, power activity, emulsifier, functional polymer, thickener, alcohol, fat or fatty compound, oil, surfactant, flavor, suspendisse agent, a silicone material, or a mixture thereof.

46. The composition of personal hygiene, including composition according to claim 1.

47. The composition of the personal care products according to 46, additionally comprising at least one other active ingredient for personal care products.

48. The composition of personal hygiene on p, in which the active ingredient for personal care products are selected from the group including odorants, means for skin cooling, softeners, deodorants, active agents against sweat, moisturizers, detergents, active agents from sunburn, agents, hair care agents for oral hygiene, bonding agents for dentures, active agents for shaving, cosmetics and agents for care of nails.

49. The composition of personal hygiene item 46 or 47, which is a product selected from the group comprising a means for hair care, skincare, anti-sunburn tool for nail care and oral hygiene.

50. The composition according to 49, in which the product for hair care includes private balcony is ner, selected from the group comprising silicone materials, hydrocarbon oils, panthenol and its derivatives, Pantothenic acid and its derivatives and mixtures thereof.

51. The composition according to 49, in which the product skin care includes air conditioning, selected from the group comprising silicone materials, hydrocarbon oils, panthenol and its derivatives, Pantothenic acid and its derivatives and mixtures thereof.

52. The composition according to 49, in which the product for hair care or care product skin includes up to 5 wt.% the composition according to claim 1 and characterized by the value of light transmission of more than 95%.

53. The composition of personal hygiene on p, additionally comprising at least one ingredient selected from the group comprising a dye, a preservative, an antioxidant, alpha - or beta-hydroxy acids, power activity, emulsifier, functional polymer, thickener, alcohol, fat or fatty compound, an antimicrobial compound, pyrithione zinc, silicon material, a hydrocarbon polymer, emollient, oil, surfactant, flavor, perfume, pharmaceuticals, anti-aging agents, suspendresume agents, and mixtures thereof.

54. The composition according to claim 1, further comprising water in an amount from 50 to 95%, based on the total weight of the composition.

55. The composition according to item 54, additionally comprising at least one more is the extra ingredient, selected from the group comprising stabilizing biocides, fragrances, perfumes, dyes, and mixtures thereof.



 

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