Agent for pest and acaridae controlling

FIELD: agriculture, organic chemistry.

SUBSTANCE: invention relates to agent for pest and acaridae controlling containing mixture of a) compound of formula I , wherein X represents C1-C4-alkyl; W, Y, and Z are independently hydrogen or C1-C4-alkyl; A and B together with the hydrogen atom to which they are attached form saturated C3-C6-cycloalkyl monosubstituted with (C1-C4-alkoxyl; D represents hydrogen; G represents hydrogen or group , wherein M is oxygen; R2 is C1-C8-alkyl; and b) compound selected from group containing acrinatrin, cypermetrin, alpha-cypermetrin, zeta-cypermetrin, cyflutrin, beta-cyflutrin,, deltametrin, lambda-cyhalotrin, phempropatrin, and biphentrin, wherein a) and b) mass ratio is from 25:1 to 1:1.

EFFECT: agent with synergic effect and increased activity.

3 cl, 12 tbl, 5 ex

 

This invention relates to new combinations of active substances consisting of known cyclic ketoenols, on the one hand, and other known insecticidal active substances, on the other hand, is effective in combating animal pests, such as insects and unwanted acaricides.

It is known that certain cyclic ketoenol have herbicide, insecticide and acaricide properties. The effectiveness of these substances, however, in some cases when used in small quantities insufficient.

Its herbicide, insecticide or acaricide efficiency of the known unsubstituted, bicyclic derivatives of 3-arylpyrimidine-2,4-dione (EP-A 355599 and EP-A 415211)and substituted monocyclic derivatives of 3-arylpyrimidine-2,4-dione (EP-A 377893 and EP-A 442077).

Also known polycyclic derivatives of 3-arylpyrimidine-2,4-dione (EP-A 422073), as well as derivatives of 1H-arylpyrimidine (EP-A 456063, EP-A 521334, EP-A 596298, EP-A 613884, EP-A 613885, WO 94/01997, WO 95/26954, WO 95/20572, EP-A 0668267, WO 96/25395, WO 96/35664, WO 97/01535, WO 97/02243, WO 97/36868, WO 97/43275, WO 98/05638, WO 98/06721, WO 98/25928, WO 99/16748, WO 99/24437, WO 99/43649, WO 99/48869 and WO 99/55673).

In addition, it is known that many compounds, ORGANOTIN compounds, benzoylacetone and pyrethroids possess insecticidal or acaricidal properties (cf WO 93/22297, WO 93/10083, DE-A 2641343, EP-347488, EP-A 210487, U-A 3264177 and EP-A 234045). However, the effectiveness of these substances is not always satisfactory.

Found that the compounds of formula (I)

in which X is halogen, alkyl, alkoxyl, haloalkyl, haloalkoxy or cyano,

W, Y and Z denote, independently of one another, hydrogen, halogen, alkyl, alkoxyl, haloalkyl, haloalkoxy or cyano,

A represents hydrogen, unsubstituted or substituted by halogen alkyl, alkoxy, saturated, optionally substituted cycloalkyl, in which optionally at least one atom in the ring is replaced by a heteroatom,

In the mean hydrogen or alkyl,

A and b together with the carbon atom to which they are attached, form a saturated or unsaturated, unsubstituted or substituted ring optionally containing at least one heteroatom,

D is hydrogen or unsubstituted or substituted radical from the series alkyl, alkenyl, alkoxyalkyl, rich cycloalkyl in which optionally one or several links in the ring are replaced by heteroatoms,

A and D together with the atoms to which they are attached, form a saturated or unsaturated ring, optionally containing at least one heteroatom, unsubstituted or substituted in the A,the D - position of the ring

G means hydrogen (a) or one of the groups

E (e) or

where E means a metal ion or ammonium,

L is oxygen or sulphur,

M stands for oxygen or sulphur,

R1means unsubstituted or substituted by halogen alkyl, alkenyl, alkoxyalkyl, alkylthiomethyl, polyalkoxyalkyl or unsubstituted or substituted by halogen, alkyl or alkoxyl cycloalkyl, which, optionally, contains at least one heteroatom, unsubstituted or substituted phenyl, phenylalkyl, heteroaryl, phenoxyethyl or heteroepitaxial,

R2means unsubstituted or substituted by halogen alkyl, alkenyl, alkoxyalkyl, polyalkoxyalkyl means or unsubstituted or substituted cycloalkyl, phenyl or benzyl,

R3means alkyl, unsubstituted or substituted by halogen, or denotes phenyl, unsubstituted or substituted,

R4and R5denote, independently of one another, unsubstituted or substituted by halogen alkyl, alkoxy, alkylamino, dialkylamino, alkylthio, alkanity, cycloalkylation or means unsubstituted or substituted phenyl, benzyl, phenoxy or phenylthio and

R6and R7denote, independently of one another, hydrogen, unsubstituted or substituted by halogen alkyl, cycloalkyl, and canil, alkoxyl, alkoxyalkyl denote unsubstituted or substituted phenyl, signify unsubstituted or substituted benzyl or together with the N-atom to which they are bound, form an unsubstituted or substituted ring which optionally includes an oxygen or sulphur,

and pyrethroids, preferably the following:

1. Acrinathrin

known from EP-A 048186,

and/or

2. Alpha-cypermethrin

known from EP-A 067461,

and/or

3. Betacyfluthrin

known from EP-A 206149,

and/or

4. Cigalotrin

known from DE-A 2802962,

and/or

5. Cypermethrin

known from DE-A 2326077,

and/or

6. Deltamethrin

known from DE-A 2326077,

and/or

7. Esfenvalerate

known from DE-A 2737297,

and/or

8. Etofenprox

known from DE-A 3117510,

and/or

9. Fenpropathrin

known from DE-A 2231312,

and/or

10. Fenvalerate

known from DE-A 2335347,

and/or

11. Flucythrinate

known from DE-A 2757066,

and/or

12. NML is Yes-cigalotrin

known from EP-A 106469, and/or

13. Permethrin

known from DE-A 2326077,

and/or

14. Teaflavin

known from EP-A 038617,

and/or

15. Tralomethrin

known from DE-A 2742546,

and/or

16. Zeta-cypermethrin

known from EP-A 026542,

and/or

17. Cyfluthrin

known from DE-A 2709264,

and/or

18. Bifenthrin

known from EP-A 049977,

and/or

19. Cicloprofen

known from DE-A 2653189,

and/or

20. Fluient

known from DE-A 3604781,

and/or

21. Tupfenrock

known from DE-A 3708231,

and/or

22. Pyrethrin

R=-CH3or-CO2CH3,

R1=-CH=CH2or-CH3or-CH2CH3,

known from the Pesticide manual, 1977, 11th edition, str, and/or

23. Resmethrin

known from GB-A 1168797,

which have good insecticidal and acaricidal properties.

Unexpectedly, it was found that insecticidal and carecidaaniesy combinations of active substances according to the invention is significantly higher than the sum of the efficacies of the individual active substances. Occurs unpredictable this synergistic effect, not only increase efficiency.

The combination of active substances according to the invention contain, along with at least one active substance of the formula (I), at least one active compound from the compounds 1 to 23.

Preferred combinations of active substances containing the compounds of formula (I)in which the radicals have the following meanings:

W means preferably hydrogen, (C1-C4)-alkyl, (C1-C4-alkoxy, chlorine, bromine or fluorine,

X is preferably (C1-C4)-alkyl, (C1-C4-alkoxy, (C1-C4-haloalkyl, fluorine, chlorine or bromine,

Y and Z denote preferably, independently of one another,

hydrogen, (C1-C4)-alkyl, halogen, (C1-C4-alkoxy or (C1-C4-haloalkyl,

And means preferably hydrogen or unsubstituted or substituted by halogen (C1-C6)-alkyl or (C3-C8-cycloalkyl,

In means preferably hydrogen, methyl or ethyl,

A, b and the carbon atom to which they are attached, preferably by means saturated (C3-C6-cycloalkyl, unsubstituted or substituted once or twice (C1-C4)-alkyl, trifluoromethyl or (C1-C4-alkoxyl, in which, if necessary, the STI, one link in the ring is replaced by oxygen or sulphur,

D means preferably hydrogen, unsubstituted or substituted by fluorine or chlorine (C1-C6)-alkyl, (C3-C4)-alkenyl or (C3-C6-cycloalkyl,

A and D together imply preferably unsubstituted or substituted by stands (3-C4)-alcander in which optionally one methylene group is replaced by sulfur,

G means preferably hydrogen (a) or one of the groups

E (e) or

especially mean (a), (b), (C) or (g), in which

E. means metal ion or ammonium,

L is oxygen or sulphur,

M stands for oxygen or sulphur,

R1means are preferably unsubstituted or substituted by halogen (C1-C10)-alkyl, (C2-C10)-alkenyl, (C1-C4)-alkoxy-(C1-C4)-alkyl, (C1-C4)-alkylthio-(C1-C4)-alkyl or (C3-C6-cycloalkyl, unsubstituted or substituted by fluorine, chlorine, (C1-C4)-alkyl or (C1-C2-alkoxyl,

means phenyl, unsubstituted or substituted by fluorine, chlorine, bromine, cyano-, nitro-group, (C1-C4)-alkyl, (C1-C4and what maxilom, by trifluoromethyl or cryptomaterial,

means pyridyl or thienyl, unsubstituted or substituted by chlorine or stands,

R2means are preferably unsubstituted or substituted by fluorine or chlorine (C1-C10)-alkyl, (C2-C10)-alkenyl, (C1-C4)-alkoxy-(C2-C4)-alkyl,

means (C5-C6-cycloalkyl, nezameshchenny or replaced by stands or metaxylem, or

means phenyl or benzyl, unsubstituted or substituted by fluorine, chlorine, bromine, cyano-, nitro-group, (C1-C4)-alkyl, (C1-C4-alkoxyl, trifluoromethyl or cryptomaterial,

R3means preferably (C1-C4)-alkyl, unsubstituted or substituted by fluorine, or denotes phenyl, unsubstituted or substituted by fluorine, chlorine, bromine, (C1-C4)-alkyl, (C1-C4-alkoxyl, trifluoromethyl, cryptomaterial, cyano - or nitro-group,

R4means preferably (C1-C4)-alkyl, (C1-C4-alkoxy, (C1-C4)-alkylamino-, (C1-C4)-allylthiourea, unsubstituted or substituted by fluorine or chlorine, or denote phenyl, phenoxy or phenylthio, unsubstituted or substituted by fluorine, chlorine, bromine, nitro, cyano, (C1-C4-alkoxyl, cryptomaterial, (C1-C4)-alkylthio-, (Csub> 1-C4-haloalkylthio, (C1-C4)-alkyl or trifluoromethyl,

R5means preferably (C1-C4-alkoxy or (C1-C4-thioalkyl,

R6means preferably (C1-C6)-alkyl, (C3-C6-cycloalkyl, (C1-C6-alkoxy, (C3-C6)-alkenyl, (C1-C4)-alkoxy-(C1-C4)-alkyl,

R7means preferably (C1-C6)-alkyl, (C3-C6)-alkenyl or (C1-C4)-alkoxy-(C1-C4)-alkyl,

R6and R7together means preferably (C3-C6)-alkalinity radical in which optionally one carbon atom is replaced by oxygen or sulphur and which is unsubstituted or substituted by stands or ethyl,

W means particularly preferably hydrogen, methyl, ethyl, chlorine, bromine or methoxy,

X is particularly preferably chlorine, bromine, methyl, ethyl, propyl, isopropyl, methoxy, ethoxyl or trifluoromethyl,

Y and Z mean particularly preferably, independently of one another, hydrogen, fluorine, chlorine, bromine, methyl, ethyl, propyl, isopropyl, trifluoromethyl or methoxy,

And means particularly preferably methyl, ethyl, propyl, isopropyl, butyl, isobutyl, sec-butyl, tert-butyl, cyclopropyl, cyclopentyl or cyclohexyl,

In means especially prepact the positive hydrogen, methyl or ethyl,

A, b and the carbon atom to which they are attached, signify particularly preferably saturated, unsubstituted or once substituted by stands, ethyl, metaxylem, ataxia, propexia or butoxyl6-cycloalkyl, in which, optionally, one link in the ring is replaced by oxygen,

D is particularly preferably hydrogen, methyl, ethyl, propyl, isopropyl, butyl, isobutyl, allyl, cyclopropyl, cyclopentyl or cyclohexyl,

A and D together particularly preferably denote unsubstituted or substituted stands (3-C4)-alcander,

G means particularly preferably hydrogen (a) or one of the groups

or

in which M stands for oxygen or sulphur,

R1means particularly preferably (C1-C8)-alkyl, (C2-C4)-alkenyl, methoxymethyl, ethoxymethyl, ethylthiomethyl, cyclopropyl, cyclopentyl or cyclohexyl,

means phenyl, unsubstituted or substituted by fluorine, chlorine, bromine, cyano-, nitro-group, stands, ethyl, metaxylem, trifluoromethyl or cryptomaterial,

means pyridyl or thienyl, unsubstituted or substituted by chlorine or stands,

R2means particularly preferably (C1-C8)-alkyl, (C2-C4 )-alkenyl, methoxyethyl, ethoxyethyl or denotes phenyl or benzyl,

R6and R7denote, independently of one another, particularly preferably methyl, ethyl or together imply C5-alkalinity radical, in which3-methylene group is replaced by oxygen,

W most preferably means hydrogen or methyl,

X is most preferably means chlorine, bromine or methyl,

Y and Z denote, independently of one another, most preferably hydrogen, chlorine, bromine or methyl,

A, b and the carbon atom to which they are attached most preferably mean a saturated, unsubstituted or once substituted by stands, metaxylem, ataxia, propexia or butoxyl6-cycloalkyl, in which, optionally, one link in the ring is replaced by oxygen,

D is most preferably hydrogen,

G means most preferably hydrogen (a) or one of the groups

or

in which M stands for oxygen or sulphur,

R1means most preferably (C1-C8)-alkyl, (C2-C4)-alkenyl, methoxymethyl, ethoxymethyl, utilmately, cyclopropyl, cyclopentyl, cyclohexyl or

means phenyl, unsubstituted or substituted by fluorine, chlorine, bro is om, the stands, metaxylem, trifluoromethyl, cryptomaterial, cyano - or nitro-group,

means pyridyl or thienyl, unsubstituted or substituted by chlorine or stands,

R2means most preferably (C1-C8)-alkyl, (C2-C4)-alkenyl, methoxyethyl, ethoxyethyl, phenyl or benzyl,

R6and R7denote, independently of one another, most preferably methyl, ethyl or together imply C5-alkalinity radical, in which3-methylene group is replaced by oxygen.

Particularly preferred combinations of active substances containing the compounds of formula (I)

in which W, X, Y, Z, R and G have the meanings given in table 1,

Table 1
Example No.WXYZRGSo pl., °
I - 1HBr5-CH3NOch3WITH-i-C3H7122
I - 2HBr5-CH3NOch3CO2-C2H5140-142
I - 3 HCH35-CH3NOch3N>220
I - 4HCH35-CH3NOch3CO2-C2H5128
I - 5CH3CH33-BrNOch3N>220
I - 6CH3CH33-ClNOch3N219
I - 7HBr4-CH35-CH3Och3WITH-i-C3H7217
I - 8HCH34-Cl5-CH3Och3CO2-C2H5162
I - 9HCH34-CH35-CH3Och3Oil
I - 10CH3CH33-CH34-CH3 Och3N>220
I - 11HCH35-CH3NOC2H5Oil
I - 12CH3CH33-BrNOC2H5WITH-i-C3H7212-214
I - 13HCH34-CH35-CH3OC2H5CO-n-Pr134
I - 14HCH34-CH35-CH3OC2H5CO-i-Pr108
I - 15HCH34-CH35-CH3OC2H5WITH-with-Pr163

and at least one active compound I-23.

The combination of active substances along with this can contain other fungicide, acaricide or insecticide applicable additional components.

In that case, if the active ingredients in the combinations of active substances according to the invention are in particular is of nowych ratios, the synergistic effect is particularly clear. However, the weight ratio of the active substances can vary in a relatively large interval. As a rule, combinations according to the invention contain the active substances of the formula (I) and an additional partner in the preferred and particularly preferred ratio shown in table 2.

Ratio when mixing are weight relationships. The ratio should be understood as the ratio of the active substances of the formula (I) to the additional partner.

Table 2
Additional partnerThe preferred ratio when mixingEspecially preferred ratio when mixing
Acrinathrin20:1 to 1:5010:1 to 1:1
Alpha-cypermethrin50:1 to 1:510:1 to 1:1
Betacyfluthrin50:1 to 1:510:1 to 1:1
Cigalotrin50:1 to 1:510:1 to 1:1
Cypermethrin50:1 to 1:510:1 to 1:1
Deltamethrin50:1 to 1:510:1 to 1:1
Esfenvalerate50:1 to 1:510:1 to 1:1
Etofenprox10:1 to 1:105:1 to 1:5
Fenpropathrin10:1 to 1:105:1 to 1:5
Fenvalerate20:1 to 1:510:1 to 1:1
Flucythrinate50:1 to 1:510:1 to 1:1
Lambda cigalotrin50:1 to 1:510:1 to 1:1
Permethrin10:1 to 1:105:1 to 1:5
Tau-fluvalinate20:1 to 1:510:1 to 1:2
Tralomethrin50:1 to 1:510:1 to 1:1
Zeta-cypermethrin50:1 to 1:510:1 to 1:2
Cyfluthrin50:1 to 1:510:1 to 1:1
Bifenthrin10:1 to 1:1010:1 to 1:1
Cicloprofen10:1 to 1:105:1 to 1:5
Fluient10:1 to 1:105:1 to 1:5
Tupfenrock10:1 to 1:105:1 to 1:5
Pyrethrin50:1 to 1:105:1 to 1:1
Resmethrin50:1 to 1:105:1 to 1:1

The combination of active substances according to the invention are suitable for combating animal pests, preferably with what arthropode and nematodes, especially insects and arachnids, encountered in agriculture, veterinary science, in forests, in the protection of supplies and materials and in the field of hygiene. They are effective against species with normal sensitivity and resistant species and against all or individual stages of development. To the abovementioned pests include the following :

From the order Isopoda, for example Oniscus asellus, Armadillidium vulgare, Porcellio scaber.

From the order Diplopoda, for example Blaniulus guttulatus.

From the order Chilopoda, for example Geophilus carpophagus, Scutigera spp.

From the order Symphyla, for example Scutigerella immaculata.

From the order Thysanura, for example Lepisma saccharina.

From the order Collembola, for example Onychiurus armatus.

From the order Orthoptera, for example, Acheta domesticus, Gryllotalpa spp., Locusta migratoria migratorioides, Melanoplus spp., Schistocerca gregaria.

From the order Blattaria, for example, Blatta orientalis, Periplaneta americana, Leucophaea maderae, Blattella germanica.

From the order Dermaptera, for example Forficula auricularia.

From the order Isoptera, for example Reticulitermes spp.

From the order Phthiraptera, for example, Pediculus humanus corporis, Haematopinus spp., Linognathus spp., Trichodectes spp., Damalinia spp.

From the order Thysanoptera, for example Hercinothrips femoralis, Thrips tabaci, Thrips palmi, Frankliniella accidentalis.

From the order Heteroptera, for example Eurygaster spp., Dysdercus intermedius, Piesma quadrata, Cimex lectularius, Rhodnius prolixus, Triatoma spp.

From the order Homoptera, for example, Aleurodes brassicae, Bemisia tabaci, Trialeurodes vaporariorum, Aphis gossypii, Brevicoryne brassicae, Cryptomyzus ribis, Aphis fabae. Aphis pomi, Eriosoma lanigerum, Hyalopterus arundinis. Phylloxera vastatrix, Pemphigus spp., Macrosiphum avenae, Myzus spp., Phorodn humuli, Rhopalosiphum padi, Empoasca spp., Euscelis bilobatus, Nephotettix cincticeps, Lecanium corni, Saissetia oleae, Laodelphax striatellus, Nilaparvata lugens, Aonidiella aurantii, Aspidiotus hederae, Pseudococcus spp., Psylla spp.

From the order Lepidoptera, for example, Pectinophora gossypiella, Bupalus piniarius, Cheimatobia brumata, Lithocolletis blancardella, Hyponomeuta padella, Plutella xylostella, Malacosoma neustria, Euproctis chrysorrhoea, Lymantria spp., Bucculatrix thurberiella, Phyllocnistis citrella, Agrotis spp., Euxoa spp., Feltia spp., Earias insulana, Heliothis spp., Mamestra brassicae, Panolis flammea, Spodoptera spp., Trichoplusia ni, Carpocapsa pomonella, Pieris spp., Chilo spp., Pyrausta nubilalis, Ephestia kuehniella, Galleria mellonella, Tineola bisselliella, Tinea pellionella, Hoffmannophila pseudospretella, Cacoecia podana, Capua reticulana, Choristoneura fumiferana, Clysia ambiguella, Homona magnanima, Tortrix viridana, Cnaphalocerus spp., Oulema oryzae.

From the order Coleoptera, for example, Anobium punctatum, Rhizopertha dominica, Bruchidius obtectus, Acanthoscelides obtectus, Hylotrupes bajulus, Agelastica alni, Leptinotarsa decemlineata, Phaedon cochleariae, Diabrotica spp., Psylliodes chrysocephala, Epilachna varivestis, Atomaria spp., Oryzaephilus surinamensis, Anthonomus spp., Sitophilus spp., Otiorrhynchus sulcatus, Cosmopolites sordidus, Ceuthorrhynchus assimilis, Hypera postica, Dermestes spp., Trogoderma spp., Anthrenus spp., Attagenus spp., Lyctus spp., Meligethes aeneus, Ptinus spp., Niptus hololeucus, Gibbium psylloides, Tribolium spp., Tenebrio molitor, Agriotes spp., Conoderus spp., Melolontha melolontha, Amphimallon solstitialis, Costelytra zealandica, Lissorhoptrus oryzophilus.

From the order Hymenoptera, for example Diprion spp., Hoplocampa spp., Lasius spp., Monomorium pharaonis, Vespa spp.

From the order Diptera, for example Aedes spp., Anopheles spp., Culex spp., Drosophila melanogaster, Musca spp., Fannia spp., Calliphora erythrocephala, Lucilia spp., Chrysomyia spp., Cuterebra spp., Gastrophilus spp., Hyppobosca spp., Stomoxys spp., Oestrus spp., Hypoderma spp., Tabanus spp., Tannia spp., Bibio hortulanus, Oscinella frit, Phorbia spp., Pegomyia hyoscyami, Ceratitis capitata, Dacus oleae, Tipula paludosa, Hulemyia spp., Liriomyza spp.

Estrada Siphonaptera, for example, Xenopsylla cheopis, Ceratophyllus spp.

Of the class Arachnida, for example Scorpio maurus, Latrodectus mactans, Acarus siro, Argas spp., Ornithodoros spp., Dermanyssus gallinae, Eriophyes ribis, Phyllocoptruta oleivora, Boophilus spp., Rhipicephalus spp., Amblyomma spp., Hyalomma spp., Ixodes spp., Psoroptes spp., Chorioptes spp., Sarcoptes spp., Tarsonemus spp., Bryobia praetiosa, Panonychus spp., Tetranychus spp., Hemitarsonemus spp., Brevipalpus spp.

For nematodes, parasitic plants include, for example, Pratylenchus spp., Radopholus similis, Ditylenchus dipsaci, Tylenchulus semipenetrans, Heterodera spp., Globodera spp., Meloidogyne spp., Aphelenchoides spp., Longidorus spp., Xiphinema spp., Trichodorus spp., Bursaphelenchus spp.

The combination of active substances can be converted in the usual forms, such as solutions, emulsions, powders for spraying, suspensions, powders, tools for pollination, pastes, soluble powders, granules, suspension-emulsion concentrates, natural and synthetic substances impregnated with active substances, as well as fine capsules in polymeric substances.

These forms are prepared by known methods, for example, by mixing the active substances with solvents, that is liquid solvents and/or solid carriers, optionally with the use of surface-active agents, that is emulsifying and/or dispersing funds, and/or foaming of the funds.

In the case of using water as a diluent may, for example, to use organic solvents as auxiliary tools outsideranthony. As solvents in the least significant mean aromatic compounds such as xylene, toluene or alkylnaphthalenes, chlorinated aromatics and chlorinated aliphatic hydrocarbons, such as chlorobenzene, chloroethylene or methylene chloride, aliphatic hydrocarbons, such as cyclohexane or paraffins, for example oils, mineral and vegetable oils, alcohols, such as butanol or glycol and also their ethers and esters, ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, cinnaprarie solvents, such as dimethylformamide and dimethylsulfoxide, and water.

As solid carriers mean, for example, ammonium salts or grinding of natural minerals such as kaolins, alumina, talc, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth, and the grinding of synthetic minerals such as highly disperse silicic acid, alumina and silicates, as solid carriers for granules mean crushed and fractionated natural rocks such as calcite, marble, pumice, sepiola, dolomite, and also synthetic granules of inorganic or organic flour and granules of organic material such as wood sawdust, coconut shell, corn Koch is Reiki and stems of tobacco; as emulsifying and/or foam-forming means mean, for example, nonionic and anionic emulsifiers, such as an ester of polyoxyethylene-fatty acid ester of polyoxyethylene-fatty alcohol, for example, alkylarylsulphonates ether, alkyl sulphonates, alkyl sulphates, arylsulfonate, and also protein hydrolysates; as dispersing means mean, for example, waste lignin-sulfite liquors and methylcellulose.

In recipes using substances that improve adhesion, such as carboxymethylcellulose, natural or synthetic, powder, granular or latex form polymers, such as gum Arabic, polyvinyl alcohol, polyvinyl acetate, and also natural phospholipids, such as Catalina and lecithins, and synthetic phospholipids. Other additives can be mineral and vegetable oils.

Also use colorants such as inorganic pigments, for example iron oxide, titanium oxide, ferrocen blue, and organic dyestuffs, such as alizarin, azo and metallophthalocyanine dyes, and trace amounts of micronutrients, such as iron salts, manganese, boron, copper, cobalt, molybdenum and zinc.

The formulations contain, as a rule, from 0.1 to 95 wt.% the active substance, preferably from 0.5 to 90 wt.%.

The combination of active substances with the according to the invention can be presented in the form of ordinary commercial formulations and made from them are ready to use forms in a mixture with other active substances such as insecticides, attractants, sterilizing agents, bactericides, acaricides, nematicides, fungicides, substances that regulate the growth of plants, or herbicides. The insecticides include, for example, phosphoric esters, carbamates, esters, carboxylic acids, chlorinated hydrocarbons, prilocaine, substances obtained by using microorganisms, and others.

May also be mixed with other active substances, such as herbicides, or with fertilizers and growth regulators.

The combination of active substances according to the invention further can insecticides be used in the form of commercially available formulations and in the prepared from these forms for use in a mixture with synergists. Synergists are compounds which increases the efficiency of the active substances, with the added synergist itself may not be active.

The content of active substance in the form for application, obtained from commercial formulations formulations can vary within wide limits. The concentration of the active substances in the forms for application is from 0.0000001 to 95 wt.% the active substance, preferably from 0.0001 to 1 wt.%.

Application carried out in the usual way, suitable for fo what we use.

When applied against pests that are dangerous for hygiene or for the stored reserves of harvest, the combination of active substances find a very good residual action on wood and on earth, as well as a good stability to alkali on calcareous substrates.

The combination of active substances according to the invention act not only against pests, dangerous for plants, hygiene, or for stored reserves of harvest, but also in veterinary medical practice, against animal parasites (ectoparasites), such as pasture mites, skin mites, mange mites and scabies, krasnoselka, flies (biting and licking), parasitic larvae of flies, lice, ect., hematophagous biting and fleas. Such parasites include the following :

From squad Anoplurida, for example, Haematopinus spp., Linognathus spp., Pediculus spp., Phtirus spp., Solenopotes spp.

From squad Mallophagida and suborders Amblycerina and Ischnocerina, for example, Trimenopon spp., Menopon spp., Trinoton spp., Bovicola spp., Werneckiella spp., Lepikentron spp., Damalina spp., Trichodectes spp., Felicola spp.

From the order Diptera and the suborders Nematocerina and Brachycerina, for example, Aedes spp., Anopheles spp., Culex spp., Simulium spp., Eusimulium spp., Phlebotomus spp., Lutzomyia spp., Culicoides spp., Chrysops spp., H. spp., Atylotus spp., Tabanus spp., Haematopota spp., Philipomyia spp., Braula spp., Musca spp., Hydrotaea spp., Stomoxys spp., Haematobia spp., Morellia spp., Fannia spp., Glossina spp., Calliphora spp., Lucilia spp., Chrysomyia spp., Wohlfahrtia spp., Sarcophaga spp., Oestrus spp., Hypodernia spp., Gasterophilus spp., Hippobosca spp., Lipoptena spp., Melophagus spp.

From squad Siphonapterida, is for example, Pulex spp., Ctenocephalides spp., Xenopsylla spp., Ceratophyllus spp.

From squad Heteropterida, for example, Cimex spp., Triatoma spp., Rhodnius spp., Panstrongylus spp.

From squad Blattarida, for example, Blatta orientalis, Periplaneta americana, Blatella germanica, Supella spp.

From the subclass of the Acaria (Acarida) and the units of Meta-and Mesostigmata, for example Argas spp., Ornithodorus spp., Otobius spp., Ixodes spp., Amblyomma spp., Boophilus spp., Dermacentor spp., Haemophysalis spp., Hyalomma spp., Rhipicephalus spp., Dermanyssus spp., Raillietia spp., Pneumonyssus spp., Sternostoma spp., Varroa spp.

Unit Actinedida (Prostigmata) and Acaridida (Astigmata), for example, Acarapis spp., Cheyletiella spp., Ornithocheyletia spp., Myobia spp., Psorergates spp., Demodex spp., Trombicula spp., Listrophorus spp., Acarus spp., Tyrophagus spp., Caloglyphus spp., Hypodectes spp., Pterolichus spp., Psoroptes spp., Chorioptes spp., Otodectes spp., Sarcoptes spp., Notoedres spp., Knemidocoptes spp., Cytodites spp., Laminosioptes spp.

The combination of active substances according to the invention are suitable for combating blood-sucking arthropods that attack useful farm animals, such as cows, sheep, goats, horses, pigs, donkeys, camels, Buffalo, rabbits, chickens, turkeys, ducks, geese, honeybees, other domestic animals such as dogs, cats, pet birds, aquarium fish and so-called experimental animals such as hamsters, Guinea pigs, rats and mice. In the fight against these blood-sucking arthropods achieve that avoid deaths and reduce production losses (in the production of meat, milk, wool, skins, eggs, honey and so on). Thus, when the change the combinations of active substances according to the invention creates an opportunity for more cost-effective and simple cattle.

The use of combinations of active substances according to the invention occurs in veterinary practice in the usual way with the introduction of the intestine, for example, in the form of tablets, capsules, drinks, impregnations, granules, pastes, pills, food, petals, parenteral, for example, by injections (intramuscularly, with cateora, intravenous, vnutriuretrale and others), in the form of implants, with the introduction of the nose, skin application, for example, dipping or bathing (Dippen), spraying (Spray), pouring over the top (Pour-on and Spot-on), washing, audriana, and by containing the active substance of the bodies of a certain shape, such as collars, ear marks, tail marks, tape on various parts of the body, headbands, marking devices, and so forth.

When applied to livestock, poultry, Pets and the like, you can use combinations of active substances in the form of ready-made forms (e.g., powders, emulsions, liquid assets), which contain the active substance in an amount of from 1 to 80 wt.%, directly or after 100 - to 10,000-fold dilution, or used as a chemical bath.

In addition, it was found that the combination of active substances according to the invention possess high insecticidal activity against insects which destroy technical materials.

As an example, is preferably but not limited to - mention should be made of the following insects:

beetles, such as Hylotrupes bajulus, Chlorophorus pilosis, Anobium punctatum, Xestobium rufovillosum, Ptilinus pecticornis, Dendrobium pertinex, Ernobius mollis, Priobium carpini, Lyctus brunneus, Lyctus africanus, Lyctus planicollis, Lyctus linearis, Lyctus pubescens, Trogoxylon aequale, Minthes rugicollis, Xyleborus spec. Tryptodendron spec. Apate monachus, Bostrychus capucins, Heterobostrychus brunneus, Sinoxylon spec. Dinoderus minutus,

hymenopterans, such as Sirex juvencus, Urocerus gigas, Urocerus gigas taignus, Urocerus augur,

termites, such as Kalotermes flavicollis, Cryptotermes brevis, Heterotermes indicola, Reticulitermes flavipes, Reticulitermes santonensis, Reticulitermes lucifugus, Mastotermes darwiniensis, Zooterroopsis nevadensis, Coptotermes formosanus,

Seinajoki, such as Lepisma saccharina.

Under the technical materials in connection with the foregoing it should be understood materials, such as, preferably, plastics, adhesives, clay, paper and cardboard, leather, wood, wood processing products and paints.

Particularly preferably mean protective materials from attack by insects to protect the wood and of products of wood processing.

Under the timber and wood processing products that can be protected by the means according to the invention, respectively mixtures containing these means, for example, to understand

construction timber, wooden beams, railway sleepers, parts of bridges, ship walls, wooden carts, boxes, pallets, containers, is leonnie posts wood veneer, wooden Windows and doors, plywood, fasteners, plates, millwork and products of wood, which, as a rule, are used in housing construction and in building joiner's works.

The combination of active substances can be used as such in the form of concentrates or generally applicable forms, such as powders, granulates, solutions, suspensions, emulsions or pastes.

These forms can be manufactured by known methods, for example by mixing the active substances with at least one solvent, respectively diluent, emulsifier, dispersant and/or connecting or fixing agent, water repellent, if necessary, by drying or UV stabilizer and, if necessary, dyes and pigments, as well as other assistive technology for processing.

Insecticidal preparations or concentrates used for protection of wood and wood products contain the active substance according to the invention in a concentration of from 0.0001 to 95 wt.%, preferably from 0.001 to 60 wt.%.

The number of the used means, respectively, of the concentrate depends on the type and distribution of insects, and habitat. The optimal applied quantity is determined with the aid of ranks test. As a rule, it is sufficient to apply from 0.0001 to 20 wt.%, preferably from 0.001 to 10 wt.%, the active substance, in terms of the protected material.

The solvent and/or diluent is an organic chemical solvent or solvent mixture and/or oil or oily volatile ingredients organic chemical solvent or solvent mixture and/or a polar organic chemical solvent or solvent mixture and/or water and, if necessary, an emulsifier and/or wetting agent.

As the organic chemical solvent used is preferably an oil or an oily solvent with the ratio of the volatility of above 35 and a flashpoint of above 30°C, preferably above 45°C. as such volatile ingredients, water-insoluble oil and oily solvents used appropriate oils or their fractions containing aromatic compounds, or a mixture of solvents containing oil, preferably testbenching, kerosene and/or alkylbenzene.

Preferred to apply the oil with a boiling point in the range from 170 to 220°, testbenching with a boiling point in the range from 170 to 220°, spun the oil with a boiling point in the range from 250 to 350°, kerosene, respectively, aromatic compounds with a boiling point in the range from 160 to 280°, carpente the ol and the like.

In one of the preferred forms of embodiment of the use of liquid aliphatic hydrocarbons with a boiling point in the range from 180 to 210°or high-boiling mixtures of aromatic and aliphatic hydrocarbons with a boiling point in the range from 180 to 220°and/or spun oil, and/or monochromator, preferably α-monochromation.

Organic volatile ingredients oil or oily solvents factor volatility above 35 and a flash point above 30°C, preferably above 45°may be partially replaced easily and sredneetazhnye organic chemical solvents provided that the solvent mixture also will have a coefficient of volatility is above 35 and a flash point above 30°C, preferably above 45°and that the mixture can be emulsified or dissolved in this solvent mixture.

When one of the preferred forms of embodiment of a part of the organic chemical solvent or solvent mixture substituted aliphatic polar organic chemical solvent or mixture of solvents. Preferably used aliphatic organic chemical solvents containing hydroxyl and/or ether and/or ester groups, such as, for example, glycol ether, ester or the like.

In the operation of organic chemical binders in this invention is used are known in themselves, diluted with water and/or soluble or dispersible, respectively, emulsifiable used organic chemical solvents, synthetic resins and/or binding drying oils. Especially applicable binders consisting of or containing acrylic resin, vinyl resin, for example polyvinyl acetate, polyester resin, polycondensation resin or a resin obtained by polyprionidae, polyurethane resin, alkyd resin, respectively, a modified alkyd resin, phenolic resin, hydrocarbon resin, such as inden-coumarone resin, silicone resin, drying vegetable and/or drying oils and/or physically drying binders based on natural and/or artificial resins.

As the binders used a synthetic resin in the form of an emulsion, dispersion or solution. As the binders used as bitumen or bituminous substances to 10 wt.%. Optionally use the known dyes, pigments, water repellent products, substances corrective smell, and inhibitors, respectively, protection from corrosion and the like.

Preferably according to the invention, the contents of the vehicle or in concentrate as organic, chemical binders, at least one alkyd resin, soo is respectively modified alkyd resin and/or a drying vegetable oil. Preferably used according to the invention alkyd resin with an oil content of more than 45 wt.%, preferably from 50 to 68 wt.%.

Mentioned binder may be completely or partially replaced with a fixing agent (mixture) or plasticizing agent (mixture). These additives should prevent the volatilization of the active substances, as well as crystallization, according to the deposition. Preferably they replace from 0.01 to 30% binders (in recalculation on 100% of the used binders).

The plasticizers are selected from the chemical classes of esters of phthalic acid, such as dibutil, dioctyl or benzylbutylphthalate, esters of phosphoric acid such as tributyl phosphate, esters of adipic acid, such as di(2-ethylhexyl)adipate, stearates, such as butilstearat or amistart, oleates, such as butylurea, glycerol ethers or high molecular weight glycol ethers, glycerol esters and ethers of p-toluensulfonate acid.

The locking means as chemical bases contain polyvinylalcohol ethers, such as, for example, polivinilbutilovy ether, or ketones, such as benzophenone and atelevision.

As solvents and thinners used in features and water, optionally in a mixture with one or several is likemy the above-mentioned organic chemical solvents, respectively, diluents, emulsifying and dispersing agents.

Particularly effective protection of wood is achieved by the means of industrial impregnation, for example, with the help of vacuum, double vacuum or under pressure.

At the same time the combination of active substances according to the invention can be used for protection against fouling of objects, particularly such as ship hulls, screens, nets, buildings, harbour moorings and signaling devices that are in contact with sea or ballast water.

Fouling settled Oligochaete, such as lime pipe makers, and by shells and species group Ledamorpha (filling shells), such as various species of Lepas and Scalpellum, or species group Balanomorpha (marine smallpox), such as Balanus or Pollicipes-Species, increases the frictional resistance of ships, leading to increased energy costs and, in addition, the long stay in dry dock to an increase in operating expenses.

Along with fouling by algae, for example Ectocarpus sp. Ceramium sp., of particular importance fouling settled entomostracous groups, which are United under the name of Cirripedia) (antennal crayfish).

It has been unexpectedly discovered that the combination of active substances according to the invention show very well the good effect against fouling (antifouling).

When using combinations of active substances according to the invention can be ignored or significantly reduce the concentration of compounds containing heavy metals, such as, for example, bis-(triamcinolone)sulphides, tri-n-butylanisole, tri-n-butylalcohol, oxide copper(I), triethylborane, tri-n-butyl(2-phenyl-4-chlorophenoxy)tin, oxide anti, molybdenum sulfide developed for resistance, monoxide arsenic, polymer butylsilane, phenyl-(bis-pyridine)bismuthate, tri-n-butylalcohol, morganization-bis-THIOCARBAMATE, cincinati-dithiocarbamate, zincation-bis-THIOCARBAMATE, zinc and copper salts of 2-pyridinethiol-1-oxide, bis-dimethyldithiocarbamic-zincation-bis-THIOCARBAMATE, zinc oxide, copper(I)-ethylene-bis-dithiocarbamate, copper thiocyanate, copper naphthenate and tributyltinchloride.

Ready to use anti-fouling paint may optionally contain other active substances, preferably algaecides, fungicides, herbicides, molluscicides, respectively other antifouling active substances.

As a partner in combination antifouling means according to the invention preferably fit the following:

algaecides, such as 2-tert-butylamino-4-cyclopropylamino-6-methylthio-1,3,5-triazine, dichlorophen, Diuron, endothal, fentiazac, Isoproturon, methabenzthiazuron, XYplorer, hinkleman or terbutryn;

fungicides, such as SS-dioxide cyclohexylamine benzo[b]thiophencarboxylic acid, dichlofluanid, floortype, 3-iodine-2-propynylbutylcarbamate, tolylfluanid and azoles such as azaconazole, cyproconazole, epoxiconazole, hexaconazole, metconazole, propiconazole and tebuconazole;

molluscicide, such as fentiazac, metaldehyde, methiocarb, niclosamide, thiodicarb and trimeters,

or conventional antifouling active substances, such as 4,5-dichloro-2-octyl-4-isothiazolin-3-one, diiodomethyl-para-trillion, 2-(N,N-dimethylthiocarbamate)-5-nitrothiazole, potassium, copper, sodium and zinc salts of 2-pyridinethiol-1-oxide, pyridinethione, tetramethyldisiloxane, 2,3,5,6-tetrachloro-4-(methylsulphonyl)pyridine, 2,4,5,6-tetrachloroisophthalonitrile, tetramethylthiuramdisulphide and 2,4,6-trichlorotoluene.

Apply antifouling products contain the active substance according to the invention with a concentration of from 0.001 to 50 wt.%, preferably from 0.01 to 20 wt.%.

Antifouling means according to the invention contain, besides the usual components, as described, for example, in Ungerer, Chem. Ind., 1985, 37, 730-732, or Williams, Antifouling Marine Coatings, Noyes, Park Ridge, 1973.

Priobresti coating materials contain, along with algaecidal, fungicidal, molluscicidal and insecticidal active what exectly, in particular, binders.

Examples of commonly used binders are polyvinyl chloride in a solvent system, chlorinated rubber in a solvent system, acrylic resins in a solvent system, especially in an aqueous system, vinyl chloride/vinyl acetate copolymer systems in the form of aqueous dispersions or in the form of systems of organic solvents, butadiene-styrene-Acrylonitrile rubbers, drying oils such as linseed oil, ester resins or modified solid resins in combination with tar or bitumen, asphalt, and epoxysilane, small amounts of chlorinated rubber, chlorinated polypropylene and vinyl resins.

If necessary, coating materials include inorganic pigments, organic pigments or dyes, which are preferably insoluble in sea water. Next, the coating materials may contain kolofonium to create the possibility of controlled release of active substances. In addition, the coating materials may contain softeners, modifying means of influencing the rheological properties, as well as other conventional components. And self polishing antifouling system can be used active substances according to the invention or the above-mentioned mixture.

The combination of active substances is thtat and pest animals, especially insects, arachnids and mites, which live in confined spaces, such as apartments, factories, offices, cabins cars and others. They are used to combat these pests alone or in combination with other active or auxiliary substances in insecticide products for the household. They are effective against susceptible and resistant species and at all stages of development. These pests include the following:

from squad Scorpionidea, for example, Buthus occitanus;

from the order Acarina, for example, Argas persicus, Argas reflexus, Bryobia ssp., Dermanyssus gallinae, Glyciphagus domesticus, Ornithodorus moubat, Rhipicephalus sanguineus, Trombicula alfreddugesi, Neutrombicula autumnalis, Dermatophagoides pteronissimus, Dermatophagoides forinae;

from the order Araneae, for example, Aviculariidae, Araneidae;

from the order Opiliones, for example, Pseudoscorpiones chelifer, Pseudoscorpiones cheiridium, Opiliones phalangium;

from the order Isopoda, for example Oniscus asellus, Porcellio scaber;

from the order Diplopoda, for example Blaniulus guttulatus, Polydesmus spp.;

from the order Chilopoda, for example Geophilus spp.;

from the order Zygentoma, for example, Ctenolepisma spp., Lepisma saccharina, Lepismodes inquilinus;

from the order Blattaria, for example, Blatta orientalies, Blattella germanica, Blatella asahinai, Leucophaea maderae, Panchlora spp., Parcoblatta spp., Periplaneta australasiae, Periplaneta americana, Periplaneta brunnea, Periplaneta fuliginosa, Supella longipalpa;

detachment of Saltatoria, for example, Acheta domesticus;

from the order Dermaptera, for example Forficula auricularia;

from the order Isoptera, for example, Kalotermes spp., Reticulitermes spp.;

from the detachment of the Psocoptera, for example, Lepinatus spp., Liposcelis spp.;

from the order Coleoptera, for example, Anthrenus spp., Attagenus spp., Dermestes spp., Latheticus oryzae, Necrobia spp., Ptinus spp., Rhizopertha dominica, Sitophilus granarius, Sitophilus oryzae, Sitophilus zeamais, Stegobium paniceum;

from the order Diptera, for example Aedes aegypti, Aedes albopictus, Aedes taeniorhynchus, Anopheles spp., Calliphora erythrocephala, Chrysozona pluvialis, Culex quinquefasciatus, Culex pipiens, Culex tarsalis, Drosophila spp., Fannia canicularis, Musca domestica, Phlebotomus spp., Sarcophaga carnaria, Simulium spp., Stomoxys calcitrans, Tipula paludosa;

from the order Lepidoptera, for example, Achroia grisella, Galleria mellonella, Plodia interpunctella, Tinea cloacella, Tinea pellionella, Tineola bisselliella;

from the order Siphonaptera, for example, Ctenocephalides canis, Ctenocephalides felis, Pulex irritans, Tunga penetrans, Xenopsylla cheopis;

from the order Hymenoptera, for example, Camponotus herculeanus, Lasius fuliginosus, Lasius niger, Lasius umbratus, Monomorium pharaonis, Paravespula spp., Tetramorium caespitum;

from the order Anoplura, for example, Pediculus humanus capitis, Pediculus humanus corporis, Phthirus pubis;

from the order Heteroptera, for example, Cimex hemipterus, Cimex lectularius, Rhodinus prolixus, Triatoma infestans.

The application is carried out in the form of aerosols, spray, non-pressurized, for example sprays to spray pump for spraying machines for the formation of mist, humidifiers, foam, gel, in the form of products of evaporation from the plates for evaporation of cellulose or plastic, in the form of evaporation of liquid, gel and membrane evaporators, evaporators with propeller systems, evaporation, not fueled by energy, respectively, in the form of a passive system is eat evaporation, paper for moles, pouches for moths and moth gels, as granules and dust, in the form of loose bait stations with bait.

According to the invention it is possible to treat all plants or plant parts. Under the plant understands all plants and plant populations, as desired and undesired wild or cultivated plants (including naturally occurring crop plants). Cultivated plants are plants obtained by conventional methods of growing and cultivation or biotechnological and gentechnologie methods, or by combinations of these methods, including the transgenic plants and including the plant varieties protected or not protected by the right of protection of the variety. Under parts of plants understand all above the soil surface and below-ground parts and organs of plants, such as seedlings, leaves, flowers and roots, and, for example, are the leaves, needles, stems, trunks, flowers, fruit body, fruits and seeds and also roots, tubers and korenok. The plant parts also include the yield and vegetative and generative material for reproduction, for example seedlings (seedlings), tubers of korenok, cuttings and seeds.

Processing plants and parts of plants according to the invention the active substances according to the invention occurs through direct impact or the impact is and the environment, living space or space where storage, traditional methods, such as dipping, spraying, evaporation, fogging, rubbing, brushing, and in the case of planting material, especially seeds, in addition, a single-layer or multilayer wrapping.

As already mentioned above, in accordance with the invention, it is possible to treat all plants and their parts. In one preferred form of embodiment cultivate wild plants or types of plants and plant varieties obtained by conventional biological methods of cultivation, such as crossing or merging protoplast, as well as parts of plants. In another preferred form of embodiment of the process of transgenic plants and plant varieties that transgenic methods, optionally in combination with conventional methods (genetically modified organisms), and parts thereof. The notion of "part", "parts of plants", explained above.

Especially preferably treated in accordance with the invention of commercial plants or applied plant varieties.

Depending on plant species, respectively varieties of plants, location and growth conditions (soils, climate, vegetation period, diet) as a result of processing in accordance with the invention can watch what I suradditions ("synergistic") effects. So, for example, may decrease the number of used substances and/or expanding the range of actions and/or enhanced activity of substances and agents used according to the invention, better plant growth, increased tolerance to high or low temperatures, increased tolerance to moisture or salt content in water, respectively, in the soil, improved performance when flowering, easier harvesting, accelerated maturation, higher yield, higher quality and/or higher nutritional value of the products of the harvest, the best persistence during storage and/or better processability of the products of the harvest, which extend beyond the expected effects.

To the preferred transgenic (obtained by genetic technologies) plants, respectively varieties of plants to be treated according to the invention include all plants which received the genetic material in the modification of gene technology, which gave these plants are especially preferred securities properties ("Traits"). Examples of such properties are better plant growth, increased tolerance to high or low temperatures, increased tolerance to moisture or salt content in water, respectively, in the soil, produced increased the productivity of the blossom, easier harvesting, accelerated maturation, higher yield, higher quality and/or higher nutritional value of the products of the harvest, the best persistence during storage and/or better processability harvest products. Other especially preferred examples of such properties is the increased resistance of plants to animal pests and microbes, such as insects, mites, pathogens of plants, fungi, bacteria and/or viruses, and also increased tolerance of the plants to certain herbicide active substances. As examples of transgenic plants especially preferably to mention important cultivated plants such as cereals (wheat, rice), maize, rice, soybeans, potatoes, cotton, canola, and also fruit plants (with the fruits apples, pears, citrus fruits and grapes), with corn, soybeans, potatoes, cotton and oilseed rape are particularly preferred. As properties (Traits) particularly prefer the increased resistance of plants to insects in connection with, resulting in plants with toxins, especially those that are created using genetic material from Bacillus Thuringiensis (for example, using the genes CryIA(a), CryIA(b)CryIA(c), CryIIA, CryIIIA, CryIIIB2, Cry9c, Cry2Ab, ry3b and CryIF and also combinations thereof) in plants (hereinafter "Btraction"). As properties ("Traits") more particularly valued the increased tolerance of the plants is in relation to certain herbicide agents, for example, imidazolines, sulfonylureas, glyphosate or phosphinotricin (for example the "PAT"gene). The genes responsible for desirable properties ("Traits"), can occur in transgenic plants and in combinations with each other. As examples of "BT. plants include varieties of corn, cotton varieties, soybean varieties and potato varieties which are supplied under the trade marks YIELD GARD® (for example, corn, cotton, soybeans), Knockout® (for example maize), StarLink® (for example maize), Bollgard® (cotton), Nucotn® (cotton) and NewLeaf® (potatoes). As examples tolerant to herbicides plant should be called varieties of corn, cotton varieties and soybean varieties which are supplied under the trademark Roundup Ready® (tolerance glyphosate, for example, corn, cotton, soybeans), Liberty Link® (tolerance to phosphinotricin, for example, rape), IMI® (tolerance imidazolinones) and STS® (tolerance to sulfonylureas, for example, corn). As herbicide-tolerant (traditionally grown as tolerant to herbicides) plants should be mentioned and included under the name Clearfield® varieties (e.g., corn). It is clear that these statements are true for varieties of plants that will be created in the future, respectively, which in the future will go to market with these or in the future created genetic the properties ("Traits").

The above plants can be particularly preferably processed in accordance with the invention, mixtures of active substances according to the invention. Preferred mixtures of area ratios given above is also valid for the processing of these plants. Particularly preferred processing plant compounds specifically described in this text.

Good insecticidal and acaricidal action of combinations of active substances according to the invention can be seen from the following examples. While the individual active substances find a weak effect, combinations detect an effect that exceeds the simple sum of the effects.

A synergistic effect is present in insecticides and acaricides always the case, if the effect of the combination of active substances is greater than the sum of the effects separately applied active substances.

The expected effect of a given combination of two active substances can, according S.R.Colby, Weeds, 15, (1967), 20-22, calculated as follows:

if X represents the degree of devitalisation (killing) in %, calculated relative to the untreated control, when employing active substances And in the number of m (g/ha) or with a concentration of m (million shares),

Y means the degree of devitalisation in %, calculated relative to the untreated control, when employing active substances In the number n (g/ha) or with n concentration (million shares),

E indicates the degree of devitalisation in %, calculated relative to the untreated control, when employing active substances a and b in the quantities m and n (g/ha) or with a concentration of m and n (million shares),

then we get

If the actual degree of devitalisation more calculated, this means that the combination of her devitalisation of vergadain, i.e. there is a synergistic effect. In this case, we observed degree devitalisation must be greater than calculated by the formula above, the value for the expected degree of devitalisation (E).

After the selected time, determine devitalization %. 100% means that all animals killed; 0% means that no animals are killed.

Examples of the application

Example

Aphis gossypii test

Solvent: 3 weight parts of dimethylformamide.

Emulsifier: 1 weight part alkylarylsulphonates ether.

For a given composition of the active substances are mixed 1 weight part of the active substance with the amounts of solvent and emulsifier and dilute the concentrate with water to the desired concentration.

The leaves of cotton (Gossypium hirsutum), which were subjected to severe attack of lice cotton leaves (Aphis gossypii), dip into the prepared composition of the active substance in the currently selected concentration.

After the selected period of time determine devitalization (the killing) in %. 100% means that all lice leaves killed; 0% means that none of the louse leaves not put to death. The values obtained devitalisation cheated by the formula Colby.

In this test, for example, the following combination of active substances according to this invention was found to synergistically enhanced efficiency compared to the active substances, which were used separately.

Example B

Myzus test

Solvent: 3 weight parts of dimethylformamide. Emulsifier: 1 weight part alkylarylsulphonates ether.

For a given composition of the active substances are mixed 1 weight part of the active substance with the amounts of solvent and emulsifier and dilute the concentrate with water to the desired concentration.

Cabbage leaves (Brassica oleracea), which were subjected to severe attack of lice peach leaves (Myzus persicae), dip into the prepared composition of the active substances selected concentration.

After the selected period of time determine devitalization (the killing) in %. 100% means that all the pests are killed; 0% means that none of the pest is not put to death. The values obtained devitalisation cheated by the formula Colby.

In this test, a voltage is emer, the following combination of active substances according to this invention was found to synergistically enhanced efficiency compared to the active substances, which were used separately.

The example In

Test boundary concentration / soil insects - treatment of transgenic plants

Test insect: Diabrotica balteata larvae in the soil.

Solvent: 7 parts by weight of acetone.

Emulsifier: 1 weight part alkylarylsulphonates ether.

For a given composition of the active substances are mixed 1 weight part of the active substance with the specified amount of solvent, add the specified amount of emulsifier concentrate and diluted with water to a predetermined concentration.

The resulting solution of the active substance is poured on the soil. The concentration of the active substance in prepared solution plays virtually no role in determining weight is the amount of active substance per unit volume of soil, which is given in million shares (mg/l). The soil is placed in pots with a volume of 0.25 l and leave at 20°C.

Immediately after placing the soil in each pot lay 5 naklonivshisya corn varieties YIELD GUARD (trademark of Monsanto company, USA). After 2 days in the treated soil is placed corresponding test nasekomye 7 days determine the effectiveness of the active substance in the calculation of rising corn plants (1 plant = 20% efficiency).

Example D

Heliothis virescens test - treatment of transgenic plants

Solvent: 7 parts by weight of acetone.

Emulsifier: 1 weight part alkylarylsulphonates ether.

For a given composition of the active substances are mixed 1 weight part of the active substance with the specified amounts of solvent and emulsifier and dilute the concentrate with water to the desired concentration.

Soya bean (Glycine max) varieties Roundup Ready (trademark of Monsanto company, USA) are treated by dipping in the solution of active substance specified concentration and placed on the still wet leaves caterpillars tobacco buds Heliothis virescens.

After a time delay determined devitalization insects.

In tables 3-9 shows the results of biological testing of known compounds and means according to the invention. Preparation of test tools, processing affected by plant pests and determine the degree of devitalisation of pests has been shown for sample a and b.

In the preparation of the test tools used the following.

Solvent: 7 parts by weight of DMF (dimethylformamide).

Emulsifier: 2 weight parts alkylarylsulphonates ether one weight part of the active component.

Example D

Tetranychus test (resistance to phosphate)

Solvent: 7 parts by weight of DMF (dimethylformamide).

Emulsifier: 2 weight parts alkylarylsulphonates ether

For a given composition of the active substances are mixed 1 weight part of the active substance with the amounts of solvent and emulsifier and dilute the concentrate with water to the desired concentration.

Bean plant (Phaseolus vulgaris), which was subjected to a severe attack of klasika spider mites (Tetranychus urticae), dip into the prepared composition of the active substances selected concentration.

After the selected period of time determine devitalization (the killing) in %. 100% means that all the pests are killed; 0% means that none of the pest is not put to death.

In this test, for example, the following combinations of active substances according to this invention was found to synergistically enhanced efficiency compared to the active substances, which were used separately.

1. The way to combat insects and acaridae containing CME and from (a) compounds of the formula (I)

in which X means (C1-C4)-alkyl;

W, Y and Z denote, independently of one another, hydrogen or (C1-C4)-alkyl;

A and b together with the carbon atom to which they are attached represent a saturated, singly substituted (C1-C4-alkoxyl (C3-C6-cycloalkyl;

D is hydrogen;

G denotes hydrogen or a group

where M stands for oxygen;

R2means (C1-C8)alkyl

and

(b) one of the following connections:

acrinathrin, cypermethrin, alpha-cypermethrin, Zeta-cypermethrin, cyfluthrin, beta-cyfluthrin, deltamethrin, lambda-cigalotrin, fenpropathrin, bifenthrin, and components (a) and (b) taken in a weight ratio of from 25:1 to 1:1.

2. The tool according to claim 1, containing a compound of the formula (I), in which

X, W, Y, and Z denote methyl,

A and b together with the carbon atom to which they are attached represent a saturated, singly substituted by a methoxy group6-cycloalkyl,

D and G denote hydrogen.

3. The tool according to claim 1, containing as component (a) compound (1-4) of the formula

where X is methyl;

W stands for a hydrogen;

Y oz is achet methyl, in particular, in position 5;

Z denotes hydrogen;

R is methoxy;

G stands for a group



 

Same patents:

FIELD: agriculture.

SUBSTANCE: invention relates to herbicide agent containing at least one herbicidal agent of general formula I , whereon R is hydrogen; R1 is C1-C8-cycloalkyl; R2 is halogens, C1-C4-flkyl, C1-C4-haloalkyl, C1-C4-alkylthio, C1-C4-alkylsulfonyl; q = 2; and at least one antidote compound of formula II , wherein { represents CH or N; R3 represents C1-C6-flkyl, C3-C6-cycloalkyl or C2-C6-alkynyl; R4 represents hydrogen or C2-C6-alkynyl, or R3 and R4 together with nitrogen atom to which they are attached form pyrrolidinyl or piperidinyl rest; R5 represents halogen; R5 represents hydrogen or C1-C4-alkyl; R5 are independently halogen, C1-C4-alkyl, C1-C4-alkoxy, or C1-C4-haloalkoxy; s = 0 or 1; and o = 1 or 2; including stereomers and agriculturally acceptable salts thereof. Effective amount of abovementioned herbicidal agent is applied on harmful plants, cultural plants, plant seeds or areas of cultivation thereof.

EFFECT: agent with decreased phytotoxicity.

11 cl, 7 tbl

FIELD: herbicidal composition.

SUBSTANCE: invention relates to herbicidal composition in form of water-soluble powder containing (mass %): 2-methoxy-3,6-dichlorobenzoic acid or n- or iso-esters thereof, containing up to 10 carbon atoms in etherified groops 20-80; substituted sulfonyl urea 3-6; primary, secondary or tertiary amine 20-38; and balance: surfactant.

EFFECT: herbicidal preparation improved emulsion stability and increased herbicidal activity.

3 cl, 2 tbl, 13 ex

FIELD: agriculture.

SUBSTANCE: claimed stimulator contains (mg/l): 4-chlorophenoxyacetic acid 1-50: succinic acid 10-80; and balance: 50 % monohydric saturated aliphatic alcohols.

EFFECT: increased set-formation and yield.

2 cl, 4 tbl, 2 ex

FIELD: organic chemistry, agriculture, herbicides.

SUBSTANCE: invention describes a herbicide agent containing the effective amount of a mixture of active substances and comprising: (a) substituted arylsulfonylaminocarbonyl-triazolinone of the formula (I): wherein R1 means alkyl comprising up to 6 carbon atoms; R2 means alkoxy-group comprising up to 6 carbon atoms; R3 means alkoxycarbonyl or alkoxy-group substituted with halogen atom and each comprising up to 6 carbon atoms; R4 means hydrogen atom, and also salts formed by compound of the general formula (I) with basic compounds (compound of the group 1), and (b) compound improving the tolerance of crop plants to herbicides effect and chosen from the following group of compound of the general formula (II): wherein m = 1; n = 0; X means alkoxy-group comprising up to 6 carbon atoms; Z means a group , wherein R5 means hydrogen atom; R6 means alkyl comprising from 1 to 6 carbon atom and substituted with (C1-C4)-alkoxy-group (compounds of the group 2) in the weight ratio of compound of the group 1 to compound of the group 2 = (1:12.5)-(1:50), and a method for control of weed plants using the proposed herbicide agent. Invention provides good tolerance of crop plants in their treatment with the proposed herbicide agent.

EFFECT: improved and valuable properties of agent.

8 cl, 5 tbl, 1 ex

Rodenticide agent // 2289925

FIELD: rodenticides.

SUBSTANCE: invention relates to agents used for control of mouse-like rodents. Rodenticide agent comprises an active substance, attractant, dye, repellent agent for humans and domestic animals and a binding component. Thermoplastic is used as a binding component and agent comprises components taken in the following ratio, wt.-%: active substance, 0.002-10; attractant, 40-85; dye, 0.005-0.05, repellent for humans and domestic animals, 0.001-0.02, and a binding agent, the balance. Invention provides enhancing the mechanical strength of agent at increased temperatures and its moisture resistance. Invention can be used for carrying out the deratization of compartments and in agriculture also.

EFFECT: enhanced effectiveness of agent.

3 tbl

FIELD: organic chemistry, chemical technology, medicine, pharmacy.

SUBSTANCE: invention relates to a novel terbinafine salt of the formula (I):

with malic acid possessing an antimycotic activity and to a method for its preparing and pharmaceutical composition used in treatment of fungal infection. L-(-)-bimalate is the most preferable form of salt. Method for preparing salt involves interaction of compound of the formula (I) as a free base with the corresponding form of malic acid. Pharmaceutical composition comprises indicated salt in combination with at least one pharmaceutically acceptable carrier or excipient. Pharmaceutical composition can be prepared as a solution or lacquer for nails. Proposed salt shows improved pharmacokinetic properties that makes its to be preferable in preparing pharmaceutical compositions adopted for systemic and topical using.

EFFECT: improved preparing method, improved and valuable properties of salt and pharmaceutical composition.

8 cl, 6 dwg, 5 ex

FIELD: pesticides, chemical technology.

SUBSTANCE: invention describes a method for preparing copper-containing liquid pesticide. Method involves formation of a hardened water-soluble complex copper-borate, its grinding to form granules and dissolving granules in water to obtain liquid pesticide comprising the copper concentration at least 0.20% but not above 1.00 wt.-%. Also, invention describes liquid pesticide prepared by indicated method and a set comprising granules of hardened water-soluble complex copper-borate and letter instructions for preparing the liquid pesticide. Method provides remaining copper in solution in dissolving the hardened complex copper-borate in water.

EFFECT: improved preparing method.

4 cl, 1 dwg

FIELD: organic chemistry, chemical technology.

SUBSTANCE: invention describes {[1-(ammonio)-3,5,7-triazaadamantyl]methylcarbonyloxypoly-(alkyleneoxy)}-propane chlorides of the general formula: wherein at X+ = Y+ means ; R1 means aliphatic unsaturated hydrocarbon C17-radical; a + c + e = 49; b + d + f = 9; at X+ = Y+ means ; R1 means aliphatic unsaturated hydrocarbon C17-radical; a + c + e = 55; b + d + f = 10; at X+ = Y+ means ; a + c + e = 49; b + d + f = 9; at X+ = Y+ means ; a + c + e = 55; b + d + f = 10; at X+ = Y+ means ; R1 means aliphatic unsaturated hydrocarbon C17-radical; a + c + e = 49; b + d + f = 0; at X+ = Y+ means ; R1 means aliphatic unsaturated hydrocarbon C17-radical; a + c + e = 55; b + d + f = 0; at X+ = Y+ means -RNH2+-; R means aliphatic hydrocarbon (C10-C16)-radical; a + c + e = 49; b + d + f = 9; at X+ = Y+ means -RNH2+-; R means aliphatic hydrocarbon (C10-C16)-radical; a + c + e = 55; b + d + f = 10. Also, invention describes a method for synthesis of abovementioned compounds that possess antibactericidal and fungicide activity and can be used for control of bacterial and fungal damages in medicine, veterinary science and agriculture.

EFFECT: improved method of synthesis, valuable properties of compounds.

7 cl, 2 tbl, 8 ex

FIELD: agriculture.

SUBSTANCE: method involves extracting larch and/or fir wood with organic solvent; distilling extractant for producing of aqueous emulsion of total of biologically active natural compounds. Organic solvent used is aliphatic alcohol with 1, 2, 3 carbon atoms, or acetone containing water not in the excess of 60 wt%, or mixture of these extractants. After distilling of extractant, active substance is produced, said substance being based on total of flavonoids of the following composition, wt%: dihydroquercetinic acid 70-86; dihydrokaempferol 4-12; naringenin 2-6; other compounds being the balance. Claimed preparation is preferably used in the form of aqueous emulsion comprising 2-10 wt% of active substance.

EFFECT: increased biological activity of preparation.

2 cl, 3 ex

FIELD: agriculture.

SUBSTANCE: synergetic herbicide composition contains active substances such as chlorimuron-ethyl (I) and imazetapir (II) and salts thereof, used in the ratio of (I):(II)-10:1, and also contains fillers, diluents, surfactants and other functional additives needed for producing of preparation forms. Method for controlling of weed plants in sown farm crops involves using effective doses of preparations adapted for suppressing weed plants without affecting leguminous crops such as soya, feed beans, pea etc.

EFFECT: wider range of weed plant controlling means and processes.

5 cl, 2 dwg, 7 tbl, 13 ex

FIELD: agriculture.

SUBSTANCE: invention relates to herbicide agent containing at least one herbicidal agent of general formula I , whereon R is hydrogen; R1 is C1-C8-cycloalkyl; R2 is halogens, C1-C4-flkyl, C1-C4-haloalkyl, C1-C4-alkylthio, C1-C4-alkylsulfonyl; q = 2; and at least one antidote compound of formula II , wherein { represents CH or N; R3 represents C1-C6-flkyl, C3-C6-cycloalkyl or C2-C6-alkynyl; R4 represents hydrogen or C2-C6-alkynyl, or R3 and R4 together with nitrogen atom to which they are attached form pyrrolidinyl or piperidinyl rest; R5 represents halogen; R5 represents hydrogen or C1-C4-alkyl; R5 are independently halogen, C1-C4-alkyl, C1-C4-alkoxy, or C1-C4-haloalkoxy; s = 0 or 1; and o = 1 or 2; including stereomers and agriculturally acceptable salts thereof. Effective amount of abovementioned herbicidal agent is applied on harmful plants, cultural plants, plant seeds or areas of cultivation thereof.

EFFECT: agent with decreased phytotoxicity.

11 cl, 7 tbl

FIELD: herbicidal composition.

SUBSTANCE: invention relates to herbicidal composition in form of water-soluble powder containing (mass %): 2-methoxy-3,6-dichlorobenzoic acid or n- or iso-esters thereof, containing up to 10 carbon atoms in etherified groops 20-80; substituted sulfonyl urea 3-6; primary, secondary or tertiary amine 20-38; and balance: surfactant.

EFFECT: herbicidal preparation improved emulsion stability and increased herbicidal activity.

3 cl, 2 tbl, 13 ex

FIELD: agriculture.

SUBSTANCE: claimed stimulator contains (mg/l): 4-chlorophenoxyacetic acid 1-50: succinic acid 10-80; and balance: 50 % monohydric saturated aliphatic alcohols.

EFFECT: increased set-formation and yield.

2 cl, 4 tbl, 2 ex

FIELD: organic chemistry, agriculture, herbicides.

SUBSTANCE: invention describes a herbicide agent containing the effective amount of a mixture of active substances and comprising: (a) substituted arylsulfonylaminocarbonyl-triazolinone of the formula (I): wherein R1 means alkyl comprising up to 6 carbon atoms; R2 means alkoxy-group comprising up to 6 carbon atoms; R3 means alkoxycarbonyl or alkoxy-group substituted with halogen atom and each comprising up to 6 carbon atoms; R4 means hydrogen atom, and also salts formed by compound of the general formula (I) with basic compounds (compound of the group 1), and (b) compound improving the tolerance of crop plants to herbicides effect and chosen from the following group of compound of the general formula (II): wherein m = 1; n = 0; X means alkoxy-group comprising up to 6 carbon atoms; Z means a group , wherein R5 means hydrogen atom; R6 means alkyl comprising from 1 to 6 carbon atom and substituted with (C1-C4)-alkoxy-group (compounds of the group 2) in the weight ratio of compound of the group 1 to compound of the group 2 = (1:12.5)-(1:50), and a method for control of weed plants using the proposed herbicide agent. Invention provides good tolerance of crop plants in their treatment with the proposed herbicide agent.

EFFECT: improved and valuable properties of agent.

8 cl, 5 tbl, 1 ex

Rodenticide agent // 2289925

FIELD: rodenticides.

SUBSTANCE: invention relates to agents used for control of mouse-like rodents. Rodenticide agent comprises an active substance, attractant, dye, repellent agent for humans and domestic animals and a binding component. Thermoplastic is used as a binding component and agent comprises components taken in the following ratio, wt.-%: active substance, 0.002-10; attractant, 40-85; dye, 0.005-0.05, repellent for humans and domestic animals, 0.001-0.02, and a binding agent, the balance. Invention provides enhancing the mechanical strength of agent at increased temperatures and its moisture resistance. Invention can be used for carrying out the deratization of compartments and in agriculture also.

EFFECT: enhanced effectiveness of agent.

3 tbl

FIELD: organic chemistry, chemical technology, medicine, pharmacy.

SUBSTANCE: invention relates to a novel terbinafine salt of the formula (I):

with malic acid possessing an antimycotic activity and to a method for its preparing and pharmaceutical composition used in treatment of fungal infection. L-(-)-bimalate is the most preferable form of salt. Method for preparing salt involves interaction of compound of the formula (I) as a free base with the corresponding form of malic acid. Pharmaceutical composition comprises indicated salt in combination with at least one pharmaceutically acceptable carrier or excipient. Pharmaceutical composition can be prepared as a solution or lacquer for nails. Proposed salt shows improved pharmacokinetic properties that makes its to be preferable in preparing pharmaceutical compositions adopted for systemic and topical using.

EFFECT: improved preparing method, improved and valuable properties of salt and pharmaceutical composition.

8 cl, 6 dwg, 5 ex

FIELD: pesticides, chemical technology.

SUBSTANCE: invention describes a method for preparing copper-containing liquid pesticide. Method involves formation of a hardened water-soluble complex copper-borate, its grinding to form granules and dissolving granules in water to obtain liquid pesticide comprising the copper concentration at least 0.20% but not above 1.00 wt.-%. Also, invention describes liquid pesticide prepared by indicated method and a set comprising granules of hardened water-soluble complex copper-borate and letter instructions for preparing the liquid pesticide. Method provides remaining copper in solution in dissolving the hardened complex copper-borate in water.

EFFECT: improved preparing method.

4 cl, 1 dwg

FIELD: organic chemistry, chemical technology.

SUBSTANCE: invention describes {[1-(ammonio)-3,5,7-triazaadamantyl]methylcarbonyloxypoly-(alkyleneoxy)}-propane chlorides of the general formula: wherein at X+ = Y+ means ; R1 means aliphatic unsaturated hydrocarbon C17-radical; a + c + e = 49; b + d + f = 9; at X+ = Y+ means ; R1 means aliphatic unsaturated hydrocarbon C17-radical; a + c + e = 55; b + d + f = 10; at X+ = Y+ means ; a + c + e = 49; b + d + f = 9; at X+ = Y+ means ; a + c + e = 55; b + d + f = 10; at X+ = Y+ means ; R1 means aliphatic unsaturated hydrocarbon C17-radical; a + c + e = 49; b + d + f = 0; at X+ = Y+ means ; R1 means aliphatic unsaturated hydrocarbon C17-radical; a + c + e = 55; b + d + f = 0; at X+ = Y+ means -RNH2+-; R means aliphatic hydrocarbon (C10-C16)-radical; a + c + e = 49; b + d + f = 9; at X+ = Y+ means -RNH2+-; R means aliphatic hydrocarbon (C10-C16)-radical; a + c + e = 55; b + d + f = 10. Also, invention describes a method for synthesis of abovementioned compounds that possess antibactericidal and fungicide activity and can be used for control of bacterial and fungal damages in medicine, veterinary science and agriculture.

EFFECT: improved method of synthesis, valuable properties of compounds.

7 cl, 2 tbl, 8 ex

FIELD: agriculture.

SUBSTANCE: method involves extracting larch and/or fir wood with organic solvent; distilling extractant for producing of aqueous emulsion of total of biologically active natural compounds. Organic solvent used is aliphatic alcohol with 1, 2, 3 carbon atoms, or acetone containing water not in the excess of 60 wt%, or mixture of these extractants. After distilling of extractant, active substance is produced, said substance being based on total of flavonoids of the following composition, wt%: dihydroquercetinic acid 70-86; dihydrokaempferol 4-12; naringenin 2-6; other compounds being the balance. Claimed preparation is preferably used in the form of aqueous emulsion comprising 2-10 wt% of active substance.

EFFECT: increased biological activity of preparation.

2 cl, 3 ex

FIELD: agriculture.

SUBSTANCE: synergetic herbicide composition contains active substances such as chlorimuron-ethyl (I) and imazetapir (II) and salts thereof, used in the ratio of (I):(II)-10:1, and also contains fillers, diluents, surfactants and other functional additives needed for producing of preparation forms. Method for controlling of weed plants in sown farm crops involves using effective doses of preparations adapted for suppressing weed plants without affecting leguminous crops such as soya, feed beans, pea etc.

EFFECT: wider range of weed plant controlling means and processes.

5 cl, 2 dwg, 7 tbl, 13 ex

FIELD: organic chemistry, insecticides.

SUBSTANCE: invention describes an insecticide agent comprising synergetic mixture of compound of the formula (I): wherein W, X, Z, R and G have values given in the invention claim and one of the following compounds: lufenuron, triflumuron, novaluron, fluphenoxuron, emamectin, methoxyphenozide, endosulfan, fipronil, ciromazin, indoxacarb. Insecticide activity of the proposed agent is higher as compared with sum of activities of individual active substances.

EFFECT: enhanced activity of agent.

2 cl, 23 tbl, 6 ex

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