Insecticide agent comprising synergetic mixture of two active substances

FIELD: organic chemistry, insecticides.

SUBSTANCE: invention describes an insecticide agent comprising synergetic mixture of compound of the formula (I): wherein W, X, Z, R and G have values given in the invention claim and one of the following compounds: lufenuron, triflumuron, novaluron, fluphenoxuron, emamectin, methoxyphenozide, endosulfan, fipronil, ciromazin, indoxacarb. Insecticide activity of the proposed agent is higher as compared with sum of activities of individual active substances.

EFFECT: enhanced activity of agent.

2 cl, 23 tbl, 6 ex

 

This invention relates to means for combating animal pests, and more particularly to insecticidal means containing a synergistic mixture of two active substances.

A known number of active substances insecticidal action. For example, it is known that certain cyclic ketoenol have herbicide, insecticide and acaricide properties. The effectiveness of these substances is good, but in some cases when used in small quantities insufficient.

Its herbicide, insecticide or acaricide efficiency of the known unsubstituted, bicyclic derivatives of 3-aryl-pyrrolidin-2,4-dione (EP-A 355599 and EP-A 415211)and substituted monocyclic derivatives of 3-arylpyrimidine-2,4-dione (EP-A 377893 and EP-A 442077).

Also known polycyclic derivatives of 3-aryl-pyrrolidin-2,4-dione (EP-A 422073), as well as derivatives of 1H-aryl-pyrrolidin-dione (EP-A 456063, EP-A 521334, EP-A 596298, EP-A 613884, EP-A 613885, WO 94/01997, WO 95/26954, WO 95/20572, EP-A 0668267, WO 96/25395, WO 96/35664, WO 97/01535, WO 97/02243, WO 97/36868, WO 97/43275, WO 98/05638, WO 98/06721, WO 98/25928, WO 99/16748, WO 99/24437, WO 99/43649, WO 99/48869 and WO 99/55673).

In addition, it is known that numerous phosphoric esters, carbamates, heterocyclic compounds, tin-organic compounds, benzoylacetone and pyrethroids possess insecticidal or acaricidal properties (cf US 2758115, US 3309266, EP-A 004334, GB-A 1181657, WO 93/2227, WO 93/10083, DE-A 2641343, EP-347488, EP-A 210487, US-A 3264177 and EP-A 234045). However, the effectiveness of these substances is not always satisfactory.

The objective of the invention is the development of insecticide, containing a synergistic mixture of two active substances.

The problem is solved, we offer insecticidal product containing a synergistic mixture of compounds of formula (I)

in which W, X, Y, Z, R and G have the values shown in the table,

WXYZRG
NBr5-CH3NOch3(ISO-C3H7)
HBr5-CH3HOch3CO2-C2H5
HCH35-CH3HOch3H
HCH35-CH3HOch3CO2-C2H5
CH3CH33-BrHOch3H
MV 3CH33-ClHOch3H
NBr4-CH35-CH3Och3(ISO-C3H7)
NCH34-Cl5-CH3Och3CO2-C2H5
NCH34-CH35-CH3Och3
CH3CH33-CH34-CH3Och3N
NCH35-CH3NOS2H5
CH3CH33-BrNOC2H5(ISO-C3H7)
NCH34-CH35-CH3OS2H5CO-(n-C3H7)
NCH34-CH35-CH3sub> 2H5(ISO-C3H7)
NCH34-CH35-CH3OS2H5WITH-(cyclo-C3H7)

and one of the following connections:

lufenuron, triflumuron, novaluron, flufenoxuron, emamectin, methoxyfenozide, endosulfan, fipronil, cyromazine, indoxacarb.

Lufenuron known from EP-A 179022 and has the following structural formula

triflumuron known from DE-A 2601780 and has the following structural formula

novaluron known from US 4980376 and has the following structural formula

flufenoksuron known from EP-A 161019 and has the following structural formula

emamectin known from EP-A 089202,

methoxyfenozide known from EP-A 639559 and has the following structural formula

endosulfan is known from DE-a 1015797 and has the following structural formula

fipronil is known from EP-A 295117 and has the following structural formula

cyromazine known from DE-A 2736876 and has the following structural formula

indoxacarb known from WO 92/11249 and has the following structural formula

It was unexpectedly found that the insecticidal activity of the combinations of active substances according to the invention was significantly higher than the sum of the activities of the individual active substances. Thus there is a synergy.

The active substance of the above formula (I) have the physical characteristics listed in table 1.

Table 1

Example No.WXYZRGThe pace. Sq. °
I-1NBr5-CH3NOch3CO(ISO-C3H7)122
I-2NBr5-CH3HOch3CO2-C2H5140-142
I-3NCH35-CH3HOch3N>220
I-4NCH35-CH3 HOch3CO2-C2H5128
I-5CH3CH33-BrHOch3N>220
I-6CH3CH33-ClHOch3H219
I-7NBr4-CH35-CH3Och3CO(ISO-C3H7)217
I-8NCH34-Cl5-CH3Och3CO2-C2H5162
I-9NCH34-CH35-CH3Och3Oil
I-10CH3CH33-CH34-CH3Och3H>220
I-11NCH35-CH3NOC2H5 Oil
I-12CH3CH33-BrNOS2H5(ISO-C3H7)212-214
I-13NCH34-CH35-CH3OS2H5CO-(n-C3H7)134
I-14NCH34-CH35-CH3OS2H5(ISO-C3H7)108
I-15NCH34-CH35-CH3OC2H5WITH-(cyclo-C3H7)163

In that case, if the active substance in insecticide tool according to the invention, are in certain weight ratios, the synergistic effect is particularly clear. However, the weight ratio of the active substances can vary in a relatively large interval. As a rule, insecticide, according to the invention contains the active substance of the formula (I) and specified additional component in the preferred and particularly preferred zootoxin and, are shown in table 2.

Table 2
An additional componentThe preferred weight ratioParticularly preferred weight ratio
Lufenuron20:1 to 1:510:1 to 1:2
Triflumuron10:1 to 1:105:1 to 1:5
Novaluron10:1 to 1:105:1 to 1:5
Flufenoksuron10:1 to 1:105:1 to 1:5
Emamectin50:1 to 1:510:1 to 1:1
Methoxyfenozide10:1 to 1:105:1 to 1:5
Endosulfan10:1 to 1:105:1 to 1:5
Fipronil10:1 to 1:105:1 to 1:5
Cyromazine10:1 to 1:105:1 to 1:5
Indoxacarb50:1 to 1:520:1 to 1:2

The tool according to the invention are suitable for combating animal pests, preferably with arthropode and nematodes, especially insects and arachnids, encountered in agriculture, veterinary science, in forests, in the protection of supplies and materials and in the field of hygiene. They are effective on is the compared to species with normal sensitivity and resistant species, and against all or individual stages of development. To the abovementioned pests include:

From the order Isopoda, for example Oniscus asellus, Armadillidium vulgare, Porcellio scaber.

From the order Diplopoda, for example Blaniulus guttulatus. From the order Chilopoda, for example Geophilus carpophagus, Scutigera spp. From the order Symphyla, for example Scutigerella immaculata. From the order Thysanura, for example Lepisma saccharina. From the order Collembola, for example Onychiurus armatus. From the order Orthoptera, for example, Acheta domesticus, Gryllotalpa spp., Locusta migratoria migratorioides, Melanoplus spp., Schistocerca gregaria. From the order Blattaria, for example, Blatta orientalis, Periplaneta americana, Leucophaea maderae, Blattella germanica.

From the order Dermaptera, for example Forficula auricularia. From the order Isoptera, for example Reticulitermes spp. From the order Phthiraptera, for example, Pediculus humanus corporis, Haematopinus spp., Linognathus spp., Trichodectes spp., Damalinia spp. From the order Thysanoptera, for example Hercinothrips femoralis, Thrips tabaci, Thrips palmi, Frankliniella accidentalis.

From the order Heteroptera, for example Eurygaster spp., Dysdercus intermedius, Piesma quadrata, Cimex lectularius, Rhodnius prolixus, Triatoma spp. From the order Homoptera, for example, Aleurodes brassicae, Bemisia tabaci, Trialeurodes vaporariorum, Aphis gossypii, Brevicoryne brassicae, Cryptomyzus ribis, Aphis fabae, Aphis pomi, Eriosoma lanigerum, Hyalopterus arundinis, Phylloxera vastatrix, Pemphigus spp., Macrosiphum avenae, Myzus spp., Phorodon humuli, Rhopalosiphum padi, Empoasca spp., Euscelis bilobatus, Nephotettix cincticeps, Lecanium corni, Saissetia oleae, Laodelphax striatellus, Nilaparvata lugens, Aonidiella aurantii, Aspidiotus hederae, Pseudococcus spp., Psylla spp. From the order Lepidoptera, for example, Pectinophora gossypiella, Bupalus piniarius, Cheimatobia brumata, Lithocolletis blancardella, Hyponomeuta padella, Plutella xylostella, Malacosoma neustria, Euproctis chrysorrhoea, Lymantria spp., Bucculatrix thurberiella, Phyllocnistis citrella, Agrois spp., Euxoa spp., Feltia spp., Earias insulana, Heliothis spp., Mamestra brassicae, Panolis flammea, Spodoptera spp., Trichoplusia ni, Carpocapsa pomonella, Pieris spp., Chilo spp., Pyrausta nubilalis, Ephestia kuehniella, Galleria mellonella, Tineola bisselliella, Tinea pellionella, Hoffmannophila pseudospretella, Cacoecia podana, Capua reticulana, Choristoneura fumiferana, Clysia ambiguella, Homona magnanima, Tortrix viridana, Cnaphalocerus spp., Oulema oryzae.

From the order Coleoptera, for example, Anobium punctatum, Rhizopertha dominica, Bruchidius obtectus, Acanthoscelides obtectus, Hylotrupes bajulus, Agelastica aini, Leptinotarsa decemlineata, Phaedon cochleariae, Diabrotica spp., Psylliodes chrysocephala, Epilachna varivestis, Atomaria spp., Oryzaephilus surinamensis, Anthonomus spp., Sitophilus spp., Otiorrhynchus sulcatus, Cosmopolites sordidus, Ceuthorrhynchus assimilis, Hypera postica, Dermestes spp., Trogoderma spp., Anthrenus spp., Attagenus spp., Lyctus spp., Meligethes aeneus, Ptinus spp., Niptus hololeucus, Gibbium psylloides, Tribolium spp., Tenebrio molitor, Agriotes spp., Conoderus spp., Melolontha melolontha, Amphimallon solstitialis, Costelytra zealandica, Lissorhoptrus oryzophilus.

From the order Hymenoptera, for example Diprion spp., Hoplocampa spp., Lasius spp., Monomorium pharaonis, Vespa spp. From the order Diptera, for example Aedes spp., Anopheles spp., Culex spp., Drosophila melanogaster, Musca spp., Fannia spp., Calliphora erythrocephala, Lucilia spp., Chrysomyia spp., Cuterebra spp., Gastrophilus spp., Hyppobosca spp., Stomoxys spp., Oestrus spp., Hypoderma spp., Tabanus spp., Tannia spp., Bibio hortulanus, Oscinella frit, Phorbia spp., Pegomyia hyoscyami, Ceratitis capitata, Dacus oleae, Tipula paludosa, Hulemyia spp., Liriomyza spp. From the order Siphonaptera, for example Xenopsylla cheopis, Ceratophyllus spp. Of the class Arachnida, for example Scorpio maurus, Latrodectus mactans, Acarus siro, Argas spp., Ornithodoros spp., Dermanyssus gallinae, Eriophyes ribis, Phyllocoptruta oleivora, Boophilus spp., Rhipicephalus spp., Amblyomma spp., Hyalomma spp., Ixodes spp., Psoroptes spp., Chorioptes spp., Sarcoptes spp., Tarsonemus spp., Bryobia praetiosa, Panonychus spp., Tetranychus spp., Hemitarsonemus spp., Brevipalpus spp.

For nematodes, you do not cause the existing plants, include, for example, Pratylenchus spp., Radopholus similis, Ditylenchus dipsaci, Tyienchulus semipenetrans, Heterodera spp., Globodera spp., Meloidogyne spp., Aphelenchoides spp., Longidorus spp., Xiphinema spp., Trichodorus spp., Bursaphelenchus spp.

The combination of active substances can be translated in the usual forms, such as solutions, emulsions, powders for spraying, suspensions, powders, means for spraying, pastes, soluble powders, granules, suspension-emulsion concentrates, natural and synthetic materials impregnated with active substances, as well as very small capsules in polymeric substances.

These forms are prepared by known methods, for example, by mixing the active substances with solvents, that is liquid solvents and/or solid carriers, optionally with the use of surface-active agents, that is emulsifying means and/or dispersing funds, and/or foaming of the funds.

In the case of using water as a diluent can be used, for example, organic solvents as auxiliary means of improving the dissolution. As liquid solvents materially mean: aromatics, such as xylene, toluene or alkylnaphthalenes, chlorinated aromatics and chlorinated aliphatic hydrocarbons, such as chlorobenzene, chloroethylene or methylene chloride, Alif the political hydrocarbons, such as cyclohexane or paraffins, for example, oils, mineral and vegetable oils, alcohols, such as butanol or glycol and also their ethers and esters, ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, cinnaprarie solvents, such as dimethylformamide and dimethylsulfoxide, and water.

As solid carriers are: for example ammonium salts and grinding of natural minerals such as kaolins, alumina, talc, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth, and the grinding of synthetic minerals such as highly disperse silicic acid, alumina and silicates, as solid carriers for granules mean: crushed and fractionated natural rocks such as calcite, marble, pumice, sepiola, dolomite, and also synthetic granules of inorganic or organic flour and granules of organic material such as wood sawdust, coconut shell, corn cobs and stalks of tobacco; as emulsifying and/or foam-forming means mean: for example nonionic and anionic emulsifiers, such as an ester of polyoxyethylene-fatty acid ester of polyoxyethylene-fatty alcohol, for example, alkylaryl-polyglycolic ether, alkyl sulphonates, alkylsulfate is s, arylsulfonate, and also protein hydrolysates; as dispersing funds mean: for example, waste lignin-sulfite liquors and methylcellulose.

Ready-made forms using substances that improve adhesion, such as carboxymethylcellulose, natural or synthetic, powder, granular or latex form polymers, such as gum Arabic, polyvinyl alcohol, polyvinyl acetate, and also natural phospholipids, such as Catalina and lecithins, and synthetic phospholipids. Other additives can be mineral and vegetable oils.

Also use colorants such as inorganic pigments, for example iron oxide, titanium oxide, ferrocen blue, and organic dyestuffs, such as alizarin, azo and metallophthalocyanine dyes, and trace amounts of micronutrients, such as iron salts, manganese, boron, copper, cobalt, molybdenum and zinc.

Forms that contain, as a rule, from 0.1 to 95 wt.% the active substance, preferably from 0.5 to 90 wt.%.

The combination of active substances according to the invention, can be presented in the form of the usual commercial form, and made from them are ready to use forms in a mixture with other active substances such as insecticides, attractants, sterilizing agents, bactericides, acaricides, it is the pesticides, fungicides, nutrients, growth regulators or herbicides. The insecticides include, for example, phosphoric esters, carbamates, esters, carboxylic acids, chlorinated hydrocarbons, prilocaine, substances obtained by using microorganisms, and others.

It is also possible mixing with other known active substances, such as herbicides, or with fertilizers and growth regulators.

The combination of active substances according to the invention, moreover, can be used as insecticides in the form of a commercially available form or in the form prepared from them forms for use in a mixture with synergistic agents. Synergistic substances are those substances, which increases the efficiency of active substances, with the added synergistic substance may itself not be active.

The content of active substance in the form for application, prepared from the compositions of commercial forms, can vary within wide limits. The concentration of the active substances in the forms for application is from 0.0000001 to 95 wt.%, preferably from 0.0001 to 1 wt.%.

Application carried out in the usual way appropriate for the application.

When applied against pests, dangerous for hygiene or for the stored reserves of harvest, the combination of active substances find a very good residual de is the effect on the wood and on the ground, as well as a good stability to alkali on calcareous substrates.

The combination of active substances according to the invention act not only against pests, dangerous for plants, hygiene, or for stored reserves of harvest, but also in veterinary medical practice, against animal parasites (ectoparasites), such as pasture mites, skin mites, mange mites and scabies, krasnoselka, flies (biting and licking), parasitic larvae of flies, lice, ect., hematophagous biting and fleas. Such parasites include:

From squad Anoplurida, for example, Haematopinus spp., Linognathus spp., Pediculus spp., Phtirus spp., Solenopotes spp.

From squad Mallophagida and suborders Amblycerina and Ischnocerina, for example, Trimenopon spp., Menopon spp., Trinoton spp., Bovicola spp., Werneckiella spp., Lepikentron spp., Damalina spp., Trichodectes spp., Felicola spp. From the order Diptera and the suborders Nematocerina and Brachycerina, for example, Aedes spp., Anopheles spp., Culex spp., Simulium spp., Eusimulium spp., Phlebotomus spp., Lutzomyia spp., Culicoides spp., Chrysops spp., H. spp., Atylotus spp., Tabanus spp., Haematopota spp., Philipomyia spp., Braula spp., Musca spp., Hydrotaea spp., Stomoxys spp., Haematobia spp., Morellia spp., Fannia spp., Glossina spp., Calliphora spp., Lucilia spp., Chrysomyia spp., Wohlfahrtia spp., Sarcophaga spp., Oestrus spp., Hypoderma spp., Gasterophilus spp., Hippobosca spp., Lipoptena spp., Melophagus spp.

From squad Siphonapterida, for example, Pulex spp., Ctenocephalides spp., Xenopsylla spp., Ceratophyllus spp.

From squad Heteropterida, for example, Cimex spp., Triatoma spp., Rhodnius spp., Panstrongylus spp.

From squad Blattarida, for example, Blatta orientalis, Periplaneta americana, Blatella germanica, Supella spp.

From the subclass of the Acaria (Acarida) and the army eta-, and Mesostigmata, for example Argas spp., Ornithodorus spp., Otobius spp., Ixodes spp., Amblyomma spp., Boophilus spp., Dermacentor spp., Haemophysalis spp., Hyalomma spp., Rhipicephalus spp., Dermanyssus spp., Raillietia spp., Pneumonyssus spp., Sternostoma spp., Varroa spp.

Unit Actinedida (Prostigmata) and Acaridida (Astigmata), for example, Acarapis spp., Cheyletiella spp., Ornithocheyletia spp., Myobia spp., Psorergates spp., Demodex spp., Trombicula spp., Listrophorus spp., Acarus spp., Tyrophagus spp., Caloglyphus spp., Hypodectes spp., Pterolichus spp., Psoroptes spp., Chorioptes spp., Otodectes spp., Sarcoptes spp., Notoedres spp., Knemidocoptes spp., Cytodites spp., Laminosioptes spp.

The active substances according to the invention, suitable for the fight against blood-sucking arthropods that attack useful agricultural animals such as cows, sheep, goats, horses, pigs, donkeys, camels, Buffalo, rabbits, chickens, turkeys, ducks, geese, honeybees, other domestic animals such as dogs, cats, pet birds, aquarium fish and so-called experimental animals such as hamsters, Guinea pigs, rats and mice. In the fight against these blood-sucking arthropods achieve that avoid deaths and reduce production losses (in the production of meat, milk, wool, skins, eggs, honey and so on), so when using a combination of active substances according to the invention, creates the opportunity for a more cost-effective and simple cattle.

The use of combinations of active substances according to the invention, occurs in veterinarymedicine usual way with the introduction of the intestine, for example, in the form of tablets, capsules, drinks, impregnations, granules, pastes, pills, food, petals, parenteral, for example, with injections (intramuscularly, with cateora, intravenous, vnutriuretrale and others), in the form of implants, with the introduction of the nose, skin application, for example, in the form of dipping or bathing (Dippen), spraying (Spray), watering from the top (Pour-on and Spot-on), washing, audriana, and by containing the active substance of the bodies of a certain shape, such as collars, ear marks, tail marks, tape on various parts of the body, headbands, marking devices, and so forth.

When applied to livestock, poultry, Pets and the like can be used active substances in the form of ready-made forms (e.g., powders, emulsions, liquid assets), which contain the active substance in an amount of from 1 to 80 wt.%, directly or after 100 to 10,000-fold dilution, or used as a chemical bath.

In addition, it was found that the means according to the invention, has a high insecticidal activity against insects which destroy technical materials.

As an example, and preferably but not limited to - mention should be made of the following insects:

beetles, such as

Hylotrupes bajulus, Chlorophorus pilosis, Anobium punctatum, Xestobium rufovillosum, Ptilinus pecticornis, Dendrobium ertinex, Ernobius mollis, Priobium carpini, Lyctus brunneus, Lyctus africanus, Lyctus planicollis, Lyctus linearis, Lyctus pubescens, Trogoxylon aequale, Minthes rugicollis, Xyleborus spec. Tryptodendron spec. Apate monachus, Bostrychus capucins, Heterobostrychus brunneus, Sinoxylon spec. Dinoderus minutus, hymenopterans, such as

Sirexjuvencus, Urocerus gigas, Urocerus gigas taignus, Urocerus augur,

termites, such as

Kalotermes flavicollis, Cryptotermes brevis, Heterotermes indicola, Reticulitermes flavipes, Reticulitermes santonensis, Reticulitermes lucifugus, Mastotermes darwiniensis, Zootermopsis nevadensis, Coptotermes formosanus,

Seinajoki, such as Lepisma saccharina.

Under the technical materials in connection with the foregoing it should be understood inanimate materials, such as plastics, adhesives, clay, paper and cardboard, leather, wood, wood processing products and paints.

Particularly preferably mean protective materials from attack by insects to protect the wood and of products of wood processing.

Under the timber and wood processing products that can be protected by means of, according to the invention, respectively mixtures containing these means, for example, to understand: construction timber, wooden beams, railway sleepers, parts of bridges, ship walls, wooden carts, boxes, pallets, containers, telephone poles, wood veneer, wooden Windows and doors, plywood, fasteners, plates, millwork and products of wood, which, as a rule, find PR is the change in housing construction and in building joiner's works.

The combination of active substances can be used as such in the form of concentrates or generally applicable forms, such as powders, granulates, solutions, suspensions, emulsions or pastes.

These forms can be manufactured by known methods, for example, by mixing the active substances with at least one solvent, respectively, diluent, emulsifier, dispersant and/or binder or fixing agent, water repellent, if necessary, by drying or UV stabilizer and, if necessary, dyes and pigments, as well as other assistive technology for processing.

Insecticidal preparations or concentrates used for protection of wood and wood products contain active substance according to the invention in a concentration from 0.0001 to 95 wt.%, preferably, from 0.001 to 60 wt.%.

The number of the used means, respectively, of the concentrate depends on the type and distribution of insects, and habitat. The optimal applied quantity is determined with the aid of ranks test. As a rule, it is sufficient to apply from 0.0001 to 20 wt.%, preferably, from 0.001 to 10 wt.% the active substance, in terms of the protected material.

The solvent and/or diluent is an organic chemical solvent or solvent mixture and/or oil or oily volatile ingredients organic chemical solvent or solvent mixture, and/or polar organic chemical solvent or solvent mixture and/or water and, if necessary, an emulsifier and/or wetting agent.

As the organic chemical solvent used is preferably an oil or an oily solvent with the ratio of the volatility of above 35 and a flashpoint of above 30°C, preferably above 45°C. as such volatile ingredients, water-insoluble oil and oily solvents used appropriate oils or their fractions containing aromatic compounds, or a mixture of solvents containing oil, preferably testbenching, kerosene and/or alkylbenzene.

Preferred to apply the oil with a boiling point in the range from 170 to 220°, testbenching with a boiling point in the range from 170 to 220°, spun the oil with a boiling point in the range from 250 to 350°, kerosene, respectively, aromatic compounds with a boiling point in the range from 160 to 280°, terpentine and the like.

In one of the preferred forms of embodiments use liquid Lam-political hydrocarbons with a boiling point in the range from 180 to 210°or high-boiling mixtures of aromatic and aliphatic hydrocarbons with a boiling point in the range from 180 to 220°and/or spun oil, and/or the MES shall chloronaphthalene, preferably, α-monochromation.

Organic volatile ingredients oil or oily solvents factor volatility above 35 and a flash point above 30°C, preferably above 45°may be partially replaced easily and sredneetazhnye organic chemical solvents provided that the solvent mixture also will have a coefficient of volatility is above 35 and a flash point above 30°C, preferably above 45°and that the mixture can be emulsified or dissolved in this solvent mixture.

When one of the preferred forms of embodiment of a part of the organic chemical solvent or solvent mixture substituted aliphatic polar organic chemical solvent or mixture of solvents. Preferably used aliphatic organic chemical solvents containing hydroxyl and/or ether and/or difficult ester group, such as, for example, glycol ether, ester or the like.

As organic chemical binders in this invention, use is known in themselves, diluted with water and/or soluble or dispersible, respectively, emulsifiable organic chemical solvents, synthetic resins and/or binding drying oils. Persons who NGOs applicable binder, consisting of or containing acrylic resin, vinyl resin, for example polyvinyl acetate, polyester resin, polycondensation resin or a resin obtained by polyprionidae, polyurethane resin, alkyd resin, respectively, modified alkyd resin, phenolic resin, hydrocarbon resin, such as inden-coumarone resin, silicone resin, drying vegetable and/or drying oils and/or physically drying binders based on natural and/or artificial resins.

As a binder used synthetic resin in the form of an emulsion, dispersion or solution. As the binders used as bitumen or bituminous substances to 10 wt.%. Optionally use the known dyes, pigments, water repellent products, substances corrective smell and inhibitors, respectively, protection from corrosion and the like.

Preferably, according to the invention, the contents in the vehicle or in concentrate as organic, chemical binder, at least one alkyd resin, respectively, of a modified alkyd resin and/or a drying vegetable oil. Preferably used according to the invention, the alkyd resin with an oil content of more than 45 wt.%, preferably, from 50 to 68 wt.%.

Mentioned binder may be the floor of the awn or partially replaced with a fixing agent (mixture) or plasticizing agent (mixture). These additives should prevent the volatilization of the active substances, as well as crystallization, respectively, settling them. Preferably they replace from 0.01 to 30% binder (in recalculation on 100% of the used binder).

The plasticizers are selected from the chemical classes of esters of phthalic acid, such as dibutil, dioctyl or benzylbutylphthalate, esters of phosphoric acid such as tributyl phosphate, esters of adipic acid, such as di(2-ethylhexyl)adipate, stearates, such as butilstearat or amistart, oleates, such as butylurea, glycerol ethers or high molecular weight glycol ethers, glycerol esters and ethers of p-toluensulfonate acid.

The locking means as chemical bases contain polyvinylalcohol simple esiri, as, for example, polivinilbutilovy ether, or ketones, such as benzophenone and atelevision.

As solvents and thinners used in features and water, optionally in a mixture with one or more of the above-mentioned organic chemical solvents, respectively, diluents, emulsifying and dispersing agents.

Particularly effective protection of wood is achieved by the means of industrial impregnation, for example, with the help of vacuum, double vacuum or ways is as under pressure.

At the same time the combination of active substances according to the invention can be applied to protect against fouling of objects, in particular, such as ship hulls, screens, nets, buildings, harbour moorings and signaling devices that are in contact with sea or ballast water.

Fouling settled oligochaetae, such as lime pipe makers, and by shells and species group Ledamorpha (filling shells), such as various species of Lepas and Scalpellum, or species group Balanomorpha (marine smallpox), such as Balanus or Pollicipes-Species, increases the frictional resistance of ships and as a result leads to higher energy costs and, in addition, the long stay in dry dock to an increase in operating expenses.

Along with fouling by algae, for example Ectocarpus sp. Ceramium sp. particular importance fouling settled entomostracous groups, which are United under the name of Cirripedia) (antennal crayfish).

Unexpectedly, it was found that the means according to the invention, has a very good effect against fouling.

When using combinations of active substances according to the invention, it is possible to eliminate or significantly reduce the concentration of compounds containing heavy metals, such as, for example, bis-(triamcinolone)sulphides, tri-n-butylanisole, tri-n-outrolled, oxide copper(1), triethylborane, tri-n-butyl(2-phenyl-4-chlorophenoxy)tin, oxide anti, molybdenum sulfide developed for resistance, monoxide arsenic, polymer butylsilane, phenyl-(bis-pyridine)bismuthate, tri-n-butylalcohol, morganization-bis-THIOCARBAMATE, cincinati-dithiocarbamate, zincation-bis-THIOCARBAMATE, zinc and copper salts of 2-pyridinethiol-1-oxide, bis-dimethyldithiocarbamic-zincation-bis-THIOCARBAMATE, zinc oxide, copper(1)-ethylene-bis-dithiocarbamate, copper thiocyanate, copper naphthenate and tributyl-olowokandi.

Ready to use anti-fouling paint may optionally contain other active substances, preferably, algaecides, fungicides, herbicides, molluscicides, respectively, other anti-fouling, of the active substance.

As a partner in combination antifouling means according to the invention, preferably fit:

algaecides, such as

2-tert-butylamino-4-cyclopropylamino-6-methylthio-1,3,5-triazine, dichlorophen, Diuron, endothal, fentiazac, Isoproturon, methabenzthiazuron, oxyfluorfen, hinkleman or terbutryn;

fungicides, such as

SS-dioxide cyclohexylamine benzo[b]thiophencarboxylic acid, daloglu-and, floortype, 3-iodine-2-PROPYNYL-BUTYLCARBAMATE, tolylfluanid and azoles such as azaconazole, cyproconazole, epoxiconazole, hexaconazole met-conazole, propiconazole and tebuconazole;

molluscicide, such as

fentiazac, metaldehyde, methiocarb, niclosamide, thiodicarb and trimeters;

or conventional antifouling active substances, such as

4,5-dichloro-2-octyl-4-isothiazolin-3-one, iodmethylenetrialkyl, 2-(N,N-dimethylthiocarbamate)-5-nitrothiazole, potassium, copper, sodium and zinc salts of 2-pyridinethiol-1-oxide, pyridinethione, tetrabutyl-distannoxane, 2,3,5,6-Tetra-chloro-4-(methylsulphonyl)pyridine, 2,4,5,6-tetrachloroethane-nitrile, tetramethylthiuramdisulphide and 2,4,6-trichloranisole-imide.

Apply antifouling products contain combinations of active substances according to the invention, with a concentration of from 0.001 to 50 wt.%, preferably, from 0.01 to 20 wt.%.

Antifouling means according to the invention contain, besides the usual component parts, as described, for example, Lingerer, Chem. Ind., 1985, 37, 730 - 732 or Williams, Antifouling Marine Coatings, Noyes, Park Ridge, 1973.

Antifouling paints contain, along with algaecidal, fungicidal, molluscicidal and insecticidal active substances according to the invention, in particular, binders.

Examples of commonly used binders are polyvinyl chloride in a solvent system, chlorinated rubber in a solvent system, acrylic resins in a solvent system, obinna in the aqueous system, the vinyl chloride/vinyl acetate copolymer systems in the form of aqueous dispersions or in the form of systems of organic solvents, butadiene/styrene/Acrylonitrile rubbers, drying oils such as linseed oil, ester resins or modified solid resins in combination with tar or bitumen, asphalt, and epoxysilane, small amounts of chlorinated rubber, chlorinated polypropylene and vinyl resins.

If necessary, coating materials include inorganic pigments, organic pigments or dyes, which are preferably insoluble in sea water. Next, the coating materials may contain colophonium, to create the possibility of controlled release of active substances. In addition, the coating materials may contain plasticizers, modifying means of influencing the rheological properties, as well as other conventional components. And self polishing Pro-teleopathy system can be used active substances according to the invention, or the above-mentioned mixture.

The means according to the invention, suitable for combating animal pests, especially insects, arachnids and mites, which live in confined spaces, such as apartments, factories, offices, cabins cars and others. They are used for Orby with these pests alone or in combination with other active or auxiliary substances in insecticide products for the household. They are effective against susceptible and resistant species and at all stages of development. These pests include:

from squad Scorpionidea, for example, Buthus occitanus;

from the order Acarina, for example, Argas persicus, Argas reflexus, Bryobia ssp., Dermanyssus gallinae, Glyciphagus domesticus, Ornithodorus moubat, Rhipicephalus sanguineus, Trombicula alfreddugesi, Neutrombicula autumnalis, Dermatophagoides pteronissimus, Dermatophagoides forinae;

from the order Araneae, for example, Aviculariidae, Araneidae;

from the order Opiliones, for example, Pseudoscorpiones chelifer, Pseudoscorpiones cheiridium, Opiliones phalangium;

from the order Isopoda, for example Oniscus asellus, Porcellio scaber;

from the order Diplopoda, for example Blaniulus guttulatus, Polydesmus spp.;

from the order Chilopoda, for example Geophilus spp.;

from the order Zygentoma, for example, Ctenolepisma spp., Lepisma saccharina, Lepismodes inquilinus;

from the order Blattaria, for example, Blatta orientalies, Blattella germanica, Blatella asahinai, Leucophaea maderae, Panchlora spp., Parcoblatta spp., Periplaneta australasiae, Periplaneta americana, Periplaneta brunnea, Periplaneta fuliginosa, Supella longipalpa;

detachment of Saltatoria, for example, Acheta domesticus;

from the order Dermaptera, for example Forficula auricularia;

from the order Isoptera, for example, Kalotermes spp., Reticulitermes spp.;

from the order Psocoptera, for example, Lepinatus spp., Liposcelis spp.;

from the order Coleoptera, for example, Anthrenus spp., Attagenus spp., Dermestes spp., Latheticus oryzae, Necrobia spp., Ptinus spp., Rhizopertha dominica, Sitophilus granarius, Sitophilus oryzae, Sitophilus zeamais, Stegobium paniceum;

from the order Diptera, for example Aedes aegypti, Aedes albopictus, Aedes taeniorhynchus, Anopheles spp., Calliphora erythrocephala, Chrysozona pluvialis, Culex quinquefasciatus, Culex pipiens, Culex tarsalis, Drosophila spp., Fannia canicularis, Musca domestica, Phlebotomus spp., Sarcophaga carnaria, Simulium spp., Stomoxys calcitrans, Tipul paludosa;

from the order Lepidoptera, for example, Achroia grisella, Galleria mellonella, Plodia interpunctella, Tinea cloacella, Tinea pellionella, Tineola bisselliella;

from the order Siphonaptera, for example, Ctenocephalides canis, Ctenocephalides felis, Pulex irritans, Tunga penetrans, Xenopsylla cheopis;

from the order Hymenoptera, for example, Camponotus herculeanus, Lasius fuliginosus, Lasius niger, Lasius umbratus, Monomorium pharaonis, Paravespula spp., Tetramorium caespitum;

from the order Anoplura, for example, Pediculus humanus capitis, Pediculus humanus corporis, Phthirus pubis;

from the order Heteroptera, for example, Cimex hemipterus, Cimex lectularius, Rhodinus prolixus, Triatoma infestans.

The application is carried out in the form of aerosols, spray, non-pressurized, for example, sprays for spraying by means of pumps and spraying machines for the formation of mist, humidifiers, foam, gel, in the form of products of evaporation from the plates for evaporation of cellulose or plastic, in the form of evaporation of liquid, gel and membrane evaporators, evaporators with propeller systems, evaporation, not fueled by energy, respectively, in the form of passive systems evaporation, paper for moles, pouches for moths and moth gels, as granules and dust, in the form of loose bait stations with bait.

According to the invention it is possible to treat all plants or plant parts. Under the plant understands all plants and plant populations, as desired and undesired wild or cultivated plants (including the natural the public occurring crop plants). Cultivated plants are plants obtained by conventional methods of breeding and optimization of simulation or biotechnological and gentechnologie methods, or by combinations of these methods, including the transgenic plants and including the plant varieties protected or not protected by the right of protection of the variety. Under parts of plants understand all above the soil surface and below-ground parts and organs of plants, such as seedlings, leaves, flowers and roots, and, for example, are the leaves, needles, stems, trunks, flowers, fruit body, fruits and seeds and also roots, tubers and korenok. The plant parts also include the yield and vegetative and generative material for reproduction, for example seedlings (seedlings), tubers of korenok, cuttings and seeds.

Treatment of plants and plant parts with the active compounds according to the invention, there is a direct effect or impact on the environment, living space or space where storage, traditional methods, such as dipping, spraying, evaporation, fogging, rubbing, brushing, and in the case of planting material, especially seeds, in addition, a single-layer or multilayer wrapping.

As already mentioned above, in accordance with the invention, it is possible to treat all plants and their frequent the. In one preferred form of embodiment cultivate wild plants or types of plants and plant varieties obtained by conventional biological methods of selection, such as crossing or merging protoplast and process plants. In another preferred form of embodiment of the process of transgenic plants and plant varieties which are obtained by gene technology, if necessary, in combination with conventional methods (genetically modified organisms), and parts thereof. The notion of "part", "parts of plants" explained above.

Especially preferably treated in accordance with the invention of commercial plants or applied plant varieties.

Depending on plant species, respectively, plant varieties, location and growth conditions (soils, climate, vegetation period, diet) as a result of processing in accordance with the invention may be suradditions ("synergistic") effects. So, for example, may decrease the number of used substances and/or expanding the range of actions and/or enhanced activity of substances and agents used according to the invention, better plant growth, increased tolerance to high or low temperatures, increased tolerance to moisture or salt content in the de, accordingly, in the soil, improved performance when flowering, easier harvesting, accelerated maturation, higher yield, higher quality and/or higher nutritional value of the products of the harvest, the best persistence during storage, and/or better processability harvest products that extend beyond the expected effects.

To the preferred transgenic (obtained by genetic technologies) plants, respectively, plant varieties, which should be treated according to the invention include all plants which received the genetic material in the modification of gene technology, which gave these plants are especially preferred securities properties ("Traits"). Examples of such properties is the best plant growth, increased tolerance to high or low temperatures, increased tolerance to moisture or salt content in water, respectively, in the soil, improved performance when flowering, easier harvesting, accelerated maturation, higher yield, higher quality and/or higher nutritional value of the products of the harvest, the best persistence during storage, and/or better processability harvest products. Other especially preferred examples of such properties is increased resistance RA the plants to animal pests and microbes, such as insects, mites, pathogens of plants, fungi, bacteria and/or viruses, and also increased tolerance of the plants to certain herbicide active substances. As examples of transgenic plants especially preferably to mention important cultivated plants such as cereals (wheat, rice), maize, rice, soybeans, potatoes, cotton, rape and also fruit plants (with the fruits apples, pears, citrus fruits and grapes), with corn, soybeans, potatoes, cotton and oilseed rape is particularly preferred. As properties (Traits) especially prefer the increased resistance of plants to insects in connection with, resulting in plants with toxins, especially those that are created using genetic material from Bacillus Thuringiensis (for example, using gene CrylA(a), CrylA(b), CrylA(c), CryllA, CrylllA, CrylllB2, Cry9c, Cry2Ab, Cry3Bb and CrylF, as well as their combinations) in plants (hereinafter "Btraction"). As properties ("Traits") more particularly valued the increased tolerance of the plants in relation to certain herbicide active substances, for example, imidazolium, sulfo-nimodipine, glyphosate or phosphinotricin (for example the "PAT"gene). The genes responsible for desirable properties ("Traits"), can occur in transgenic plants and in combinations with each other. As examples of "Btrittany" can be called varieties of corn, cotton varieties, the ORT soybean and potato varieties, supplied under the trade marks YIELD GARD® (for example, corn, cotton, soybeans), KnockOut® (for example maize), StarLink® (for example maize), Bollgard® (cotton), Nucotn® (cotton) and NewLeaf® (potatoes). As examples tolerant to herbicides plant should be called varieties of corn, cotton varieties and soybean varieties which are supplied under the trademark Roundup Ready® (tolerance glyphosate, for example,

maize), StarLink® (for example maize), Bollgard® (cotton), Nucotn® (cotton) and NewLeaf® (potatoes). As examples tolerant to herbicides plant should be called varieties of corn, cotton varieties and soybean varieties which are supplied under the trademark Roundup Ready® (tolerance glyphosate, for example, corn, cotton, soybeans), Liberty Link® (tolerance to phosphinotricin, for example, pane), IMI® (tolerance imidazolinones) and STS® (tolerance to sulfonylureas, for example, corn). As herbicide-tolerant (traditionally grown as tolerant to herbicides) plants should be mentioned and included under the name Clearfield® varieties (e.g., corn). It is clear that these statements are true for varieties of plants that will be created in the future, respectively, which in the future will go to market with these or in the future created genetic properties ("Traits").

The above plants can be particularly preferably processed according to the invention, combinations of active substances according to the invention. Preferred combinations of area ratios given above is also valid for the processing of these plants. Particularly preferred processing plant combinations that are specifically described in this text.

Good insecticidal activity and the presence of a synergistic effect of the combinations of active substances according to the invention can be seen from the following examples. While the individual active substances find a weak effect, combinations detect an effect that exceeds the simple sum of the effects.

Experimental part

A synergistic effect is present in insecticides is always the case if the effect of the combination of active substances is greater than the sum of the effects separately applied active substances.

The expected effect of a given combination of two active substances can, according S.R.Colby, Weeds, 15, (1967), 20 - 22, be calculated as follows:

if

X indicates the degree of devitalisation (killing) in %, calculated relative to the untreated control, when employing active substances And in the number of m g/ha or in a concentration of m million shares,

Y means the degree of devitalisation in %, calculated in relation to neobarb the determined control when applying the active substance In the number of n g/ha or in a concentration n million shares,

E indicates the degree of devitalisation in %, calculated relative to the untreated control, when employing active substances a and b in amounts of type g/ha or in a concentration type million shares, we obtain

If the actual degree of devitalisation more calculated, this means that the combination of her devitalisation of vergadain, i.e. there is a synergistic effect. In this case, we observed degree devitalisation must be greater than calculated by the formula above, the value for the expected degree of devitalisation (E).

Used in examples mixtures were prepared as follows: 1 parts listed in the table of active substance is mixed with 7 parts of dimethylformamide as solvent and 2 parts alkylarylsulphonates ether as an emulsifier, and the resulting concentrate is diluted with water to the indicated in the tables below the desired concentration.

Example 1. Experience with Heliothis armigera

Shoots of soybean (Glycine max) are treated by immersion in the received vehicle and even on wet leaves endure caterpillars of Heliothis armigera.

After 3 days, determine the percentage loss of caterpillars. 100% means that all caterpillars have been killed and 0% of oznacza is t, none of the caterpillar was not put to death.

The results of the experiment are summarized in table 1.

Table 1
The active substanceThe concentration of active substances in MLNDSThe degree of devitalisation(%), after 3 days
detectedcalculated
Compound I-41000-
methoxyfenozide200-
Compound I-4 + methoxyfenozide (5:1), according to the invention100+201000

Example 2. Experience with Myzus persicae

Heavily infected peach aphid (Myzus persicae), cabbage leaves (Brassica oleracea) are treated by immersion in a received tool.

Through these tables 2A-2 d intervals to determine the percentage of the death of the insect. 100% means that all aphids have been killed and 0% means that no aphids was not put to death.

The experimental results are summarized in tables 2A-g

Table 2A
The active substanceThe concentration of active substances in MLNDSThe degree of devit the implementation (%), after 6 days
detectedcalculated
Compound I-4465-
cyromazine200-
Compound I-4 + cyromazine (1:5), according to the invention4+208565

Table 2B
The active substanceThe concentration of active substances in MLNDSThe degree of devitalisation in (%)after 7 days
detectedcalculated
Compound I-4460-
endosulfan0,80-
Compound I-4+ endosulfan (5:1), according to the invention4+0,88060
Table 2B
The active substanceThe concentration of active substances in MLNDS The degree of devitalisation (%), after 6 days
detectedcalculated
Compound I-4475-
flufenoksuron10010-
Compound I-4 + flufenoxuron (1: 25), according to the invention4+1009877,5

Table 2G
The active substanceThe concentration of active substances in MLNDSThe degree of devitalisation (%), after 6 days
detectedcalculated
Compound I-4485-
triflumuron1005-
Compound I-4+ triflumuron (1: 25), according to the invention4+1009085,5

Example 3. Experience with larvae of Phaedon cochleariae

Cabbage leaves (Brassica oleracea) are treated by immersion in the received vehicle and even on wet leaves carry larvae rape if the Toyoda (Phaedon cochleariae).

Through these tables 3A-3G intervals to determine the percentage loss of larvae. 100% means that all larvae were killed, 0% means that no larvae was not put to death.

The results of the experiment are summarized in tables 3A-g

Table 3A
The active substanceThe concentration of active substances in MLNDSThe degree of devitalisation (%), after 4 days
detectedcalculated
Compound I-42025-
cyromazine1005-
Compound I-4+cyromazine (1:5), according to the invention20+1004028,75
Table 3b
The active substanceThe concentration of active substances in MLNDSThe degree of devitalisation (%), after 6 days
detectedcalculated
Compound I-40,80-
fipronil 0-
Compound I-4+ fipronil (25:1), according to the invention0,8+0,032200

novaluron
Table 3b
The active substanceThe concentration of active substances in millions of sharesThe degree of devitalisation (%), after 6 days
detectedcalculated
Compound I-4205-
flufenoksuron460-
Compound I-4 + flufenoxuron (5:1), according to the invention20+49562
Table 3G
The active substanceThe concentration of active substances in MLNDSThe degree of devitalisation (%), after 4 days
detectedcalculated
Compound I-42025-
0,830-
Compound I-4 + novaluron (25:1), according to the invention20+0,88547,5

Example 4. Experience with Plutella xylostella (normal line)

Cabbage leaves (Brassica oleracea) are treated by immersion in the received vehicle and even on wet leaves carry the larvae of Plutella xylostella.

Via listed in tables 4A-4D intervals to determine the percentage loss of caterpillars. 100% means that all caterpillars have been killed and 0% means that none of the caterpillar was not put to death.

The experimental results are summarized in tables 4A-4D.

Table 4A
The active substanceThe concentration of active substances in MLNDSThe degree of devitalisation (%), after 6 days
detectedcalculated
Compound I-40,80-
fipronilto 0.03220-
Compound I-4 + fipronil (25: 1), according to the invention0,8+0,0326520

Table 4B
The active substanceThe concentration of active substances in millions of sharesThe degree of devitalisation (%), after 6 days
detectedcalculated
Compound I-40,80-
flufenoksuron0,1670-
Compound I-4 + flufenoxuron (5:1), according to the invention0,8+0,169070
Table 4B
The active substanceThe concentration of active substances in millions of sharesThe degree of devitalisation (%), after 6 days
detectedcalculated
Compound I-4420-
flufenoksuron0,1625-
Compound I-4 + flufenoxuron (25:1), according to the invention4+0,166040

Table 4G
The active substanceThe concentration of active substances in m is N. sharesThe degree of devitalisation (%), after 3 days
detectedcalculated
Compound I-4420-
lufenuron0,1635-
Compound I-4 + lufenuron (25:1), according to the invention4+0,167548
Table 4D
The active substanceThe concentration of active substances in MLNDSThe degree of devitalisation (%), after 4 days
detectedcalculated
Compound I-40,80-
novaluronto 0.0320-
Compound I-4 + novaluron (25:1), according to the invention0,8+0,032550

Example 5. Experience with Plutella xylostella (resistant line)

Cabbage leaves (Brassica oleracea) are treated by immersion in the received vehicle and even on wet leaves carry the larvae of Plutella xylostella.

Through these tables 5A-5B intervals to determine the percentage loss of caterpillars. 100% means that all caterpillars have been killed and 0% means that h is about no one larva was not put to death.

The results of the experiment are summarized in tables 5A-5B.

Table 5A
The active substanceThe concentration of active substances in MLNDSThe degree of devitalisation (%), after 3 days
detectedcalculated
Compound I-440-
indoxacarb0,160-
Compound I-4 + indoxacarb (25: 1), according to the invention4+0,16600

Table 5B
The active substanceThe concentration of active substances in MLNDSThe degree of devitalisation (%), after 3 days
detectedcalculated
Compound I-4420-
lufenuron0,165-
Compound I-4 + lufenuron (25:1), according to the invention4+0,16 5024
Table 5B
The active substanceThe concentration of active substances in MLNDSThe degree of devitalisation (%), after 3 days
detectedcalculated
Compound I-4495-
triflumuron200-
Compound I-4 + triflumuron (1:5), according to the invention4+2010095

Example 6. Experience with Spodoptera frugiperda

Cabbage leaves (Brassica oleracea) are treated by immersion in the received vehicle and even on wet leaves endure caterpillars Spodoptera frugiperda.

Via listed in tables 6A-6b intervals to determine the percentage loss of caterpillars. 100% means that all caterpillars have been killed and 0% means that none of the caterpillar was not put to death.

The results of the experiment are summarized in tables 6A-6C.

The degree of devitalisation (%), after 3 days
Table 6A
The active substanceThe concentration of active substances in MLNDS
detectedcalculated
Compound I-440-
emamectin0,006470-
Compound I-4 + emamectin (625: 1), according to the invention4+0,00649570

Table 6b
The active substanceThe concentration of active substances in MLNDSThe degree of devitalisation (%), after 6 days
detectedcalculated
Compound I-440-
indoxacarb0,1670-
Compound I-4 + indoxacarb (25: 1), according to the invention4+0,168570
Table 6b
The active substanceThe concentration of active substances in MLNDS The degree of devitalisation (%), after 3 days
detectedcalculated
Compound I-42015-
methoxyfenozide450-
Compound I-4 + methoxyfenozide (5:1), according to the invention20+485of 57.5

The mixture according to the invention containing the compounds of formula (I) compounds I-1 to I-3 and I-5 to I-15, show a similar synergistic effects.

Insecticide containing a synergistic mixture of compounds of formula (I)

in which W, X, Y, Z, R and G have the values shown in the table,

and one of the following connections:

lufenuron, triflumuron, novaluron, flufenoxuron, emamectin, methoxyfenozide, endosulfan, fipronil, cyromazine, indoxacarb.



 

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18 cl, 24 tbl, 106 ex

FIELD: agriculture, in particular method for increasing of beet yield and sugar content.

SUBSTANCE: seeds are treated by spraying in leaf clamping step with titanium tetrachloride diluted in dimethylsulfoxide (DMSO). Concentration of DMSO is 0.1-2 %; titanium tetrachloride consumption is up to 50 g per 1 hectare of seeds. Ratio of titanium tetrachloride:dimethylsulfoxide is 100-200 l per 1 hectare. Treatment is carried out twice in vegetation period, namely the first treatment is carried out in leaf clamping step and the second one in 15-20 days before harvesting of root crops.

EFFECT: increased beet yield and sugar content.

1 tbl, 1 ex

FIELD: agriculture, organic chemistry.

SUBSTANCE: invention relates to agent for controlling of plant pathogen fungi containing compound of general formula I as active ingredient, wherein X represents =N-; E represents NO2 or CN; R representsthiazolulmethyl or pyridylmethyl substituted with halogen; A represents hydrogen; Z represents C1-C4-alkylamino group; or A and Z together with atoms bonded thereon form thiazolidine, imidazolidine, hexahydro-1,3,5-triazine, N2- and N5-substituted with two C1-C4-alkyl in alkyl group, 6-membered saturated heterocycle fragment including additionally oxygen and N-(C1-C4)alkyl heterogroup; and fungicide compound selected from group containing cyproconazole, triadimenol, methalaxide, azoxistrobin, kresoximmethyl, etc., in weight ratio compound of formula I/fungicidal agent of 1:(0.1-10). Also disclosed is insecticide agent containing compound of formula I and compound selected from group containing cyproconazole, azoxistrobin, kresoximmethyl, biterthanol, tiram, methalaxide, etc. in ratio of 1:(0.1-10).

EFFECT: enhanced assortment of agents for controlling of plant pathogen fungi and agents for insect controlling.

4 cl, 15 tbl, 15 ex

FIELD: agriculture, organic chemistry.

SUBSTANCE: invention relates to agent for controlling of plant pathogen fungi containing compound of general formula I as active ingredient, wherein X represents =N-; E represents NO2 or CN; R representsthiazolulmethyl or pyridylmethyl substituted with halogen; A represents hydrogen; Z represents C1-C4-alkylamino group; or A and Z together with atoms bonded thereon form thiazolidine, imidazolidine, hexahydro-1,3,5-triazine, N2- and N5-substituted with two C1-C4-alkyl in alkyl group, 6-membered saturated heterocycle fragment including additionally oxygen and N-(C1-C4)alkyl heterogroup; and fungicide compound selected from group containing cyproconazole, triadimenol, methalaxide, azoxistrobin, kresoximmethyl, etc., in weight ratio compound of formula I/fungicidal agent of 1:(0.1-10). Also disclosed is insecticide agent containing compound of formula I and compound selected from group containing cyproconazole, azoxistrobin, kresoximmethyl, biterthanol, tiram, methalaxide, etc. in ratio of 1:(0.1-10).

EFFECT: enhanced assortment of agents for controlling of plant pathogen fungi and agents for insect controlling.

4 cl, 15 tbl, 15 ex

FIELD: agricultural chemistry.

SUBSTANCE: invention relates to herbicidal composition containing (A) mesotrion and (B) the second herbicide selected from amicarbazone, metribuzine, flumetsulfam, trifloxysulfuron, pyriphthalide, prosulfocarb or herbicidically active salts thereof in (A):(B) ratio from 32:1 to 1:3. Disclosed is method for controlling of undesired plants which includes application of herbicidically effective amount of said composition into locus with such plants.

EFFECT: composition of high herbicidal activity.

8 cl, 6 tbl

FIELD: agricultural chemistry.

SUBSTANCE: invention relates to herbicidal composition containing (A) mesotrion and (B) the second herbicide selected from amicarbazone, metribuzine, flumetsulfam, trifloxysulfuron, pyriphthalide, prosulfocarb or herbicidically active salts thereof in (A):(B) ratio from 32:1 to 1:3. Disclosed is method for controlling of undesired plants which includes application of herbicidically effective amount of said composition into locus with such plants.

EFFECT: composition of high herbicidal activity.

8 cl, 6 tbl

FIELD: agriculture.

SUBSTANCE: claimed fungicide composition contains iprodione and vegetable-origin oil having increased drying ability and iodine number of above 90. Weight ratio of oil/iprodione is from 0.15 to 1.6. Treatment method includes application of effective and non-phytotoxic amount of composition onto plant overground parts.

EFFECT: composition of decreased phytotoxicity.

8 cl

FIELD: agriculture, organic chemistry.

SUBSTANCE: invention relates to herbicidal compositions based on arylsulfonylaminocarbonyl triazolines of general formula I 1, representing flucarbazine, propoxycarbazone and compound selected from group containing amycarbazone, cinidonethyl, florasulam, fluphenacet, iodosulfuronemethyl, mesosulfurone and optionally mephenpyrdiethyl antidote. Composition of present invention are useful in selective weed control in various cultural plants.

EFFECT: effective herbicidal compositions for selective weed control.

3 cl, 67 tbl, 1 ex

FIELD: organic chemistry, herbicides.

SUBSTANCE: invention describes a synergetic composition with the effective content of components (A) and (B) wherein (A) means herbicide chosen from the group of compounds of the formula (I): wherein R1, R2, R, X, Y and Z have values given in the invention claim or their salts; (B) means one or some herbicides among the following groups: (B1) selective herbicides with activity in some dicotyledonous cultures against monocotyledonous and dicotyledonous weeds; (B2) selective herbicides with activity in some dicotyledonous cultures against dicotyledonous weeds; (B3) selective herbicides with activity in some dicotyledonous cultures with preferable effect against monocotyledonous weeds. Also, invention describes a method for control against weeds using the proposed composition. Using the combination of proposed herbicides results to the synergetic effect.

EFFECT: valuable herbicide properties of composition.

3 cl, 7 tbl, 2 ex

Herbicidal agent // 2266648

FIELD: organic chemistry, agriculture.

SUBSTANCE: invention relates to herbicidal agent containing effective amount of active compound mixture including a) 2-(2-methoxycarbonylsulfonyl aminocarbonyl)-4-methyl-5-propoxy-2,4-dihydro-3H-1,2,4-triazole-3-one of general formula I 1 or sodium salt thereof; and b) one compound improving resistance of agriculture plants, namely diethyl-1-(2,4-dichlorophenyl)-4,5-dihydro-5-methyl-1H-pyrazole-3,5-licarboxylate in ratio a/b of 1:0.025-25 pts.

EFFECT: herbicidal agent reducing damage of agriculture plants, in particular cereals.

1 cl, 24 tbl, 2 ex

Herbicidal agent // 2260948

FIELD: organic chemistry, agriculture.

SUBSTANCE: invention relates to herbicidal agent containing 2,6-disubstituted pyridine derivative of general formula I wherein R1 is phenyl radical monosubstituted with halogen; R2 is phenoxy radical monosubstituted with C1-C3-haloalkyl, as well as herbicidal compound selected from group comprising N-isopropyl-N-(4-fluorophenyl)-amide of (5-trifluoromethyl-1,3,4-thiadiazole-2-yl-oxy)-acetic acid (fluphenacete), 2-(2-methoxycarbonyl-phenylsulfonylaminocarbonyl)-4-methyl-5-n-propoxy-2,4-dihydro-3H-1,2,4-triazole-3-one (propoxycarbazone) and sodium propoxycarbazone wherein weight ratio of pyridine derivative to compound from said group is 1:0.5-15.

EFFECT: effective agent useful in selective controlling of weeds, in particular in grain crops.

5 cl, 17 tbl, 3 ex

FIELD: organic chemistry, agriculture, herbicide composition.

SUBSTANCE: invention relates to herbicide composition, containing conventional inert additives and mixture of a) herbicidically effective amount of substance satisfying the formula I [in formula R1 and R3 are the same or different C1-C4-alkyl; R4 and R5 together form groups of formulae: -C-R6(R7)-O-C-R8(R9)-C-R10(R11)-C-R12(R13)-(Z1), -C-R14(R15)-C-R16(R17)-O-C-R18(R19)-C-R20(R21)-(Z2), or -C-R22(R23)-C-R24(R25)-C-R26(R27)-O-C-R28(R29)-(Z3), wherein each R6-R29 is hydrogen; G is hydrogen or -C(X2)-X3-R31; X2 and X3 independently are oxygen; R31 is C1-C10-alkyl]; b) herbicidic synergic amount of at least one herbicide selected from group containing sulfonylureas, phenoxyacetic acids, as well as florsulam, tralcoxidim, klodinafol-propargil, phenoxaprop-P-ethyl, trifluramine, pendimethaline, picolinafen, etc. Composition also may contain safety effective amount of protective agent, such as chloquintocet-mexyl and additive (e.g., mineral oil or C8-C22-fat acid alkyl esters) in amount of 0-2 mass %. Also disclosed is method for selective controlling of weeds and grassy plants in cultural plants by treatment of cultural plants, seeds or seedlings thereof, or vegetation area thereof with claimed composition.

EFFECT: effective composition and method for weed controlling.

5 cl, 11 tbl, 7 ex

FIELD: agriculture, plant science.

SUBSTANCE: it is suggested a herbicide preparation for selective weed control in cereals containing 2-(2-trifluoromethoxyphenylsulfonylaminocarbonyl)-4-methyl-5-methoxy-2.4-dihydro-3H-1,2,4-triazole-3-on or its salt in efficient quantity and method for selective weed control. The innovation provides efficient weed suppression in cereals, wheat, in particular.

EFFECT: higher efficiency.

6 cl, 4 ex, 6 tbl

FIELD: agriculture, organic chemistry.

SUBSTANCE: invention relates to agent for controlling of plant pathogen fungi containing compound of general formula I as active ingredient, wherein X represents =N-; E represents NO2 or CN; R representsthiazolulmethyl or pyridylmethyl substituted with halogen; A represents hydrogen; Z represents C1-C4-alkylamino group; or A and Z together with atoms bonded thereon form thiazolidine, imidazolidine, hexahydro-1,3,5-triazine, N2- and N5-substituted with two C1-C4-alkyl in alkyl group, 6-membered saturated heterocycle fragment including additionally oxygen and N-(C1-C4)alkyl heterogroup; and fungicide compound selected from group containing cyproconazole, triadimenol, methalaxide, azoxistrobin, kresoximmethyl, etc., in weight ratio compound of formula I/fungicidal agent of 1:(0.1-10). Also disclosed is insecticide agent containing compound of formula I and compound selected from group containing cyproconazole, azoxistrobin, kresoximmethyl, biterthanol, tiram, methalaxide, etc. in ratio of 1:(0.1-10).

EFFECT: enhanced assortment of agents for controlling of plant pathogen fungi and agents for insect controlling.

4 cl, 15 tbl, 15 ex

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