Agent for controlling of plant pathogen fungi and agent for insect controlling

FIELD: agriculture, organic chemistry.

SUBSTANCE: invention relates to agent for controlling of plant pathogen fungi containing compound of general formula I as active ingredient, wherein X represents =N-; E represents NO2 or CN; R representsthiazolulmethyl or pyridylmethyl substituted with halogen; A represents hydrogen; Z represents C1-C4-alkylamino group; or A and Z together with atoms bonded thereon form thiazolidine, imidazolidine, hexahydro-1,3,5-triazine, N2- and N5-substituted with two C1-C4-alkyl in alkyl group, 6-membered saturated heterocycle fragment including additionally oxygen and N-(C1-C4)alkyl heterogroup; and fungicide compound selected from group containing cyproconazole, triadimenol, methalaxide, azoxistrobin, kresoximmethyl, etc., in weight ratio compound of formula I/fungicidal agent of 1:(0.1-10). Also disclosed is insecticide agent containing compound of formula I and compound selected from group containing cyproconazole, azoxistrobin, kresoximmethyl, biterthanol, tiram, methalaxide, etc. in ratio of 1:(0.1-10).

EFFECT: enhanced assortment of agents for controlling of plant pathogen fungi and agents for insect controlling.

4 cl, 15 tbl, 15 ex

 

The invention relates to a means for plant protection, in particular to the means of combating phytopathogenic fungi and insects.

Known means for protection of plants, containing as active substance agonists or antagonists nicotinergic acetylcholine receptors in insects (see application EP№.№.464830, 428941, 425978, 386565, 383091, 375907, 364844, 315826, 254859, 235725, 212600, 192060, 163855, 154178,136626, 303570, 302833, 306696, 189972, 455000, 135956, 471371, 302389; application Germany No. no..3639877, 3712307; Japan№.№.03220176, 02207083, 63307857, 63287764, 03246283, 049371, 03279359, 03255072; U.S. patents№.№.5034524, 4948798, 4918086, 5039686, 5034404; application WO No..no.91/17659, 91/4965; France application No. .2611114; the application of Brazil No. .8803621).

Known means of combating phytopathogenic fungi and insects, containing agonist or antagonist nicotinergic acetylcholine receptors in insects as a first active substance and tebuconazole, propiconazole, bitertanol or pencycuron as a second active substance (see J.P. 05017311, EP 0511541, Chemical Patents Index, Dokumentation Abstracts Journal, Week 8907, AN 89-050297 and Week 9309, AN 93-070992).

Object of the invention is the expansion of the range of means of combating phytopathogenic fungi and insects, which contain two active substances, each of which has at least one nitrogen atom.

The problem is solved by the proposed means of combating phytopathogenic fungi, containing to the operation of the first active substance a compound of General formula (I)

in which

E - NO2or CN,

R - thiazolyl-methyl or pyridyl-methyl, substituted with halogen,

A - hydrogen

Z - alkylamino-group with the number of carbon atoms from 1 to 4 or a and Z together with the atoms to which they are linked, form thiazolidin, imidazolidin, hexahydro-1,3,5-triazine, which have nitrogen atoms in the 3 and 5-position is substituted by an alkyl group with 1-4 carbon atoms in the alkyl group, 6-membered saturated heterocyclic fragment which further includes oxygen and heterogroup N-alkyl, while the alkyl N-alkyl group contains 1-4 carbon atoms, and

a compound selected from the group comprising tsyprokonazolu, triadimenol, walkable, metalaxyl, AZOXYSTROBIN, kresoximmethyl, triazoxide, tolylfluanid, fenpiclonil and fludyoksonil

when the weight ratio of compounds of General formula (I) to the compound of the specified group, equal 1: (0,1-10).

As the compounds of formula (I) means of combating phytopathogenic fungi preferably contains a compound of the formula

The task is also solved by the proposed means of combating insects comprising as a first active substance a compound of General formula (I)

in which

E - NO2or CN,

R - thiazolyl-m is l or pyridyl-methyl, substituted with halogen,

A - hydrogen

Z - alkylamino-group with the number of carbon atoms from 1 to 4 or

A and Z together with the atoms to which they are linked, form thiazolidin, imidazolidin, hexahydro-1,3,5-triazine, which have nitrogen atoms in the 3 and 5-position is substituted by an alkyl group with 1-4 carbon atoms in the alkyl group, 6-membered saturated heterocyclic fragment which further includes oxygen and heterogroup N-alkyl, while the alkyl N-alkyl group contains 1-4 carbon atoms, and

a compound selected from the group comprising tsyprokonazolu, bitertanol, thiram, metalaxyl, AZOXYSTROBIN, kresoximmethyl, tolylfluanid, fenpiclonil, fludyoksonil and triadimenol,

when the weight ratio of compounds of General formula (I) to the compound of the specified group, equal 1: (0,1-10).

As the compounds of formula (I) means of combating insects preferably contains a compound of the formula

Contained in the proposed means of a second active agent has the following structural formula:

The invention is illustrated by the following examples in which to explore products containing as the first active substances the following compounds are indicated by letters A-D.

And:

B:

In:

G:

D:

Specified in the tables below the expected degree calculated by the well-known equation Colby

where X is expressed in percentage relative to the untreated control plants, the degree of action when using the active substance And the number of m,

Y means expressed as a percentage relative to the untreated control plants, the degree of action when using the active substance B in the amount of n

E. means expressed as a percentage relative to the untreated control plants, the degree of action when using the active substance and the active substance B in the amount of respectively m and n.

If experimentally set the action higher than expected, i.e. calculated, the activity funds swered ituna means, what we are dealing with synergies. In this case, observed in the experiment, the degree must be higher than calculated by the above equation is the expected degree of validity (see Colby, S.R., "Calculating Senergistic and Antogonistic Responses of Combination", Weeds 15, p.20-22, 1967).

Example 1

Experience with Puccinia on wheat: protective action

1 parts specified in table 1 of the active substance is mixed with 25 parts of N,N-dimethylacetamide as a solvent and 6 parts alkylarylsulphonates ether as an emulsifier, and the resulting concentrate is diluted with water to the desired concentration.

To test the protective effects of spray young plants obtained by means of up until it starts to drip off the leaves.

After drying caused as specified in table 1, the amount of plants inoculant dusting conidia Puccinia recondita. Plants left in the incubation chamber at a temperature of 20°C and 100% relative humidity for 48 hours.

Then the plants are set in a greenhouse with a temperature of about 20°C and a relative humidity of about 80%.

10 days after inoculation to assess the condition of the plants. 0% means that the degree of action of the product corresponds to the test of experience, whereas the level of 100% means that the lesion is not observed.

The result is s experience summarized in table 1.

Table 1
The active ingredientThe amount of active substance (g/haThe expected degree of action in %Defined degree of action in %
Connection # And1,8750
Connection # of 18.750
AZOXYSTROBIN1,87575
Triadimenolof 18.7513
Connection # And+AZOXYSTROBIN0,9375

+

0,9375
7594
Connection # In+triadimenol9,375

+

9,375
1363

Example 2

Experience with Botrvtis on beans: protective action

1 parts specified in table 2 of the active substance is mixed with 47 parts of acetone as solvent and 3 parts alkylarylsulphonates ether as an emulsifier, and the resulting concentrate is diluted with water to the desired concentration.

To test the protective effects of spray young plants obtained by means of up until it starts to drip off the leaves.

To test the protective effects of opressive the t young plants obtained by means until until he begins to drain from the leaves.

After drying caused as specified in table 2 the amount on each sheet is placed on two small pieces of agar, sprouted Botrytis cinerea. Inoculated plants set in a darkened chamber with a temperature of about 20°and a humidity of 100%.

Two days after inoculation to determine the size of the affected areas on the leaves. 0% means that the degree of action of the product corresponds to the test of experience, whereas the level of 100% means that the lesion is not observed.

The results of the experiment are summarized in table 2.

Table 2
The active ingredientThe amount of active substance (g/haThe expected degree of action in %Defined degree of action in %
Connection # And500

40
0

0
Connection # B10

40

100
0

0

0
Connection # 100

10
4

0
Connection # G10

40
0

0
500Ȋ 0
Connection # D10

40

500
0

0

0
Fludyoksonil1040
AZOXYSTROBIN4042
Connection # And+AZOXYSTROBIN40

+

40
4250
Connection # B+fludyoksonil10

+

10
4070
Connection # B+AZOXYSTROBIN40

+

40
4250
Connection # In+fludyoksonil10

+

10
4083
Connection # G+fludyoksonil10

+

10
4071
Connection # G+AZOXYSTROBIN40

+

40
4250
Connection # D+fludyoksonil10

+

10
4061
Connection # D+AZOXYSTROBIN40

+

40
4256

Example 3

Experience with Pyrenophora teres on barley: protective action

1 parts specified in table 3 of the active substance is mixed with 25 parts of N,N-DIMET is faceted as solvent and 6 parts alkylarylsulphonates ether as an emulsifier, and the resulting concentrate is diluted with water to the desired concentration.

To test the protective effects of spray young plants obtained by means of up until it starts to drip off the leaves.

After drying caused as specified in table 3 the amount of plants inoculant dusting conidia Pyrenophora teres. Plants left in the incubation chamber at a temperature of 20°C and 100% relative humidity for 48 hours.

Then the plants are set in a greenhouse with a temperature of about 20°and a humidity of about 80%.

7 days after inoculation to assess the condition of the plants. 0% means that the degree of action of the product corresponds to the test of experience, whereas the level of 100% means that the lesion is not observed.

The results of the experiment are summarized in table 3.

Table 3
The active ingredientThe amount of active substance (g/haThe expected degree of action in %Defined degree of action in %
Connection # And18,75

62,5
20

40
Connection # B18,75

62,5
0

20
Connection # 62,5

of 18.75
20

0
Connection # G62,5

of 18.75
20

0
Connection # D62,5

of 18.75
40

20
Triazoxide62,540
AZOXYSTROBINof 18.750
Kresoxim-methyl62,50
Triadimenolof 18.7540
Connection # And+AZOXYSTROBIN9,375

+

9,375
2070
Connection # And+kresoxim-methyl31,25

+

31,25
4060
Connection # B+triazoxide31,25

+

31,25
5060
Connection # B+AZOXYSTROBIN9,375

+

9,375
070

Table 3 (Continued)
The active ingredientThe amount of active substance (g/haThe expected frame the action in % Defined degree of action in %
Connection # In+AZOXYSTROBIN9,375

+

9,375
060
Connection # In+triazoxide31,25

+

31,25
3670
Connection # G+triadimenol9,375

+

9,375
4060
Connection # G+AZOXYSTROBIN9,375

+

9,375
080
Connection # D+AZOXYSTROBIN9,375

+

9,375
2070
Connection # D+kresoxim-methyl31,25

+

31,25
2060

Example 4

Experience with Erysiphe on wheat: protective action

1 parts specified in table 4 of the active substance is mixed with 25 parts of N,N-dimethylacetamide as solvent and 6 parts alkylarylsulphonates ether as an emulsifier, and the resulting concentrate is diluted with water to the desired concentration.

To test the protective effects of spray young plants obtained by means of up until it starts to drip off the leaves.

After drying caused as specified in table 4 the amount of plants inoculant dusting with conidia of Erysiphe.

Plants is set in an incubation chamber with a temperature of 20° C and a humidity of about 80%.

7 days after inoculation to assess the condition of the plants. 0% means that the degree of action of the product corresponds to the test of experience, whereas the level of 100% means that the lesions are not observed.

The results of the experiment are summarized in table 4.

Table 4
Active substance No.The amount of active substance g/haThe expected degree of action in %Defined degree of action in %
Connection # B6,25

62,5
0

0
Connection # G62,5

of 18.75
0

0
Connection # Dof 18.750
AZOXYSTROBIN62,557
Kresoxim-methyl18,75

62,5
43

79
Connection # G+kresoxim-methyl31,25

+

31,25
7993
Connection # D+BAP Taksim-methyl9,375

+

9,375
4371
Connection # B+AZOXYSTROBIN 31,25

+

31,25
5779

Example 5

Experience with Erysiphe on barley; protective action

1 parts specified in table 5 of the active substance is mixed with 25 parts of N,N-dimethylacetamide as solvent and 6 parts alkylarylsulphonates ether as an emulsifier, and the resulting concentrate is diluted with water to the desired concentration.

To test the protective effects of spray young plants obtained by means of up until it starts to drip off the leaves.

After drying caused as specified in table 5 the amount of plants inoculant dusting with conidia of Erysiphe.

Plants set in a greenhouse with a temperature of about 20°and a humidity of about 80%.

7 days after inoculation to assess the condition of the plants. 0% means that the degree of action of the product corresponds to the test of experience, whereas the level of 100% means that the lesions are not observed.

The results of the experiment are summarized in table 5.

Table 5
Active substance No.The amount of active substance (g/haThe expected degree of action in %Defined degree of action in %
Connection # And18,75br>
62,5
0

33
Connection # B62,517
Connection # 62,50
Connection # G62,50
Kresoxim-methyl62,50
Connection # And+kresoxim-methyl31,25

+

31,25
3367
Connection # B+kresoxim-methyl31,25

+

31,25
1767
Connection # In+kresoxim-methyl31,25

+

31,25
075
Connection # G+kresoxim-methyl31,25

+

31,25
067

Example 6

Experience with Phvtophthora on tomatoes: protective action

1 parts specified in table 6 of the active substance is mixed with 47 wesc acetone as solvent and 1 parts alkylarylsulphonates ether as an emulsifier, and the resulting concentrate is diluted with water to the desired concentration.

To test the protective effects of spray young plants obtained by means of up until it starts to drip off the leaves.

After drying n is worn as shown in table 6 the amount of plants inoculant with an aqueous suspension of Phytophthora infestans and then plants installed in an incubation chamber with a temperature of about 20° C and 100%relative humidity.

3 days after inoculation assess the damage. 0% means that the degree corresponds to the degree of action of the control experiment, and 100%degree of validity means that the lesions are not observed.

The results of the experiment are summarized in table 6.

Table 6
Active substance No.The amount of active substance (g/haThe expected degree of action in %Defined degree of action in %
Connection # And10

50

500
0

33

41

Table 6 (Continued)
Active substance No.The amount of active substance (g/haThe expected degree of action in %Defined degree of action in %
Connection # B10

50

500
0

4

55
Connection # 50

500
19

51
Connection # G10

50

500
0

11

46
Connection # D10

50
1

25
AZOXYSTROBIN1074
Tolylfluanid5034
Metalaxyl5042
Walkable1061
Triadimenol5000
Connection # And+walkable10

+

10
6189
Connection # And+tolylfluanid50

+

50
5670
Connection # B+walkable10

+

10
6178
Connection # B+AZOXYSTROBIN10

+

10
7484

Table 6 (Continued)
Active substance No.The amount of active substance (g/haThe expected degree of action in %Defined degree of action in %
Connection # B+tolylfluanid50

+

50
71 87
Connection # B+metalaxyl50

+

50
4465
Connection # In+metalaxyl50

+

50
5368
Connection # In+triadimenol500

+

500
5563
Connection # G+tolylfluanid50

+

50
4151
Connection # G+walkable10

+

10
6196
Connection # G+AZOXYSTROBIN10

+

10
7486
Connection # D+walkable10

+

10
6591
Connection # D+AZOXYSTROBIN10

+

10
7488
Connection # D+tolylfluanid50

+

50
5177

Example 7

Experience with Spharotheca on cucumbers; protective action

1 parts specified in table 7 of the active substance is mixed with 47 parts of acetone as solvent and 1 parts alkylarylsulphonates ether as an emulsifier, and the resulting concentrate is diluted with water to the desired concentration.

To check casinostyle spray young plants obtained by means until until it starts to drip off the leaves.

After drying caused as specified in table 7 the amount of plants inoculant aqueous spore suspension Spharotheca fuliginea. Then the plants are set in a greenhouse with temperatures around 23°C and relative humidity about 70%.

10 days after inoculation assess the damage. 0% means that the degree of action, appropriate to the degree of action of the control experiment, and 100%degree of validity means that the lesions are not observed.

The results of the experiment are summarized in table 7.

Table 7
Active substance No.The amount of active substance (g/haThe expected degree of action in %Defined degree of action in %
Connection # And10

500
0

0
Connection # B10

500
0

0
Connection # 10

500
0

0
Connection # G100
Connection # D10

500
0

0
Ciproxan is angry 1070
Fenpiclonil50050
Fludyoksonil50070
Connection # And+tsyprokonazolu10

+

10
7090
Connection # And+fenpiclonil500

+

500
5073
Connection # And+fludyoksonil500

+

500
7085
Connection # B+fenpiclonil500

+

500
5095
Connection # B+fludyoksonil500

+

500
7093

td align="center"> 10

+

10
Table 7 (Continued)
Active substance No.The amount of active substance (g/haThe expected degree of action in %Defined degree of action in %
Connection # In+tsyprokonazolu10

+

10
7080
Connection # In+fenpiclonil500

+

500
5083
Connection # G+tsyprokonazolu7090
Connection # D+tsyprokonazolu10

+

10
7090
Connection # D+fenpiclonil500

+

500
5063
Connection # D+fludyoksonil500

+

500
7087

Example 8

Experience with Fusarium culmorium on wheat: protective action

Specified in table 8 of the active substance used in the form of tools for dry etching. It is prepared by appropriate dilution of the active substance crushed rock with the formation of finely dispersed mixture, which ensures a uniform distribution of the fungicide on the seed surface.

Treatment of infected seed is carried out by shaking with crickets for three minutes in a closed glass bottle. While the crickets used in the amount of 75 mg/kg of seeds.

Wheat planted in standard soil to a depth of 1 cm 2×100 grains and cultivated in a greenhouse at a temperature of about 18°C and a relative humidity of about 95%, illuminating them daily for 15 hours.

About three weeks after sowing to inspect plants for signs and symptoms of defeat. P and 0% means that the degree of action, the appropriate degree of action of the control experiment, and 100%degree of validity means that the lesions are not observed.

The results of the experiment are summarized in table 8.

Table 8
Active substance No.The amount of active substance (g/haThe expected degree of action in %Defined degree of action in %
Connection # And750,5
Connection # B750
Connection # 750
Connection # G750
Connection # D750,5
Tsyprokonazolu751

Table 8 (Continued)
Active substance No.The amount of active substance (g/haThe expected degree of action in %Defined degree of action in %
Triadimenol7513,5
Fludyoksonil750
Connection # And+tsyprokonazolu37,5

+

37,5
1,522
Connection # B+tsyprokonazolu37,5

+

37,5
134,5
Connection # In+triadimenol37,5

+

37,5
13,530,5
Connection # In+fludyoksonil37,5

+

37,5
0a 38.5
Connection # G+triadimenol37,5

+

37,5
13,526,5
Connection # G+fludyoksonil37,5

+

37,5
025,5
Connection # G+tsyprokonazolu37,5

+

37,5
151,5
Connection # D+triadimenol37,5

+

37,5
13,526
Connection # D+fludyoksonil37,5

+

37,5
024,5

Comparison data table 1-8 shows the proposed means of combating phytopathogenic fungi synergies.

Example 9

Experience with Myzus

1 parts specified in table 9 of the active substance is mixed with 7 wesc dimetilan the amide as solvent and 1 parts alkylarylsulphonates ether as an emulsifier, and the resulting concentrate is diluted with water to the desired concentration listed in table 9.

Heavily infected peach aphid (Myzus persicae), cabbage leaves (Brassica oleracea) are treated by immersion in a received tool.

After 6 days to determine the percentage of the death of insects. 100% means all the insects were killed, 0% means that none of the insect was not alone.

The results of the experiment are summarized in table 9.

Table 9
Active substance No.The concentration of active substance in the vehicle, %The expected degree of mortification %Defined degree of mortification %
Connection # And0,00460
Fludyoksonil0,020
AZOXYSTROBIN0,00080
Connection # And+flu-dioxanes0,004

+

0,02
60100
Connection # And+AZOXYSTROBIN0,004

+

0,0008
60100

Example 10

Experience with larvae of Phaedon

1 parts specified in the tables of the 10 active substances are mixed with 7 wesch of dimethylformamide as solvent and 1 parts alkylarylsulphonates ether as an emulsifier, and the resulting concentrate is diluted with water to the desired concentration listed in table 10.

Cabbage leaves (Brassica oleracea) are treated by immersion in the received vehicle and even on wet leaves carry the larvae of the rape of the leaf (Phaedon cochleariae).

After 7 days to determine the percentage loss of larvae. 100% means that all larvae were killed, 0% means that no larvae was not put to death.

The results of the experiment are summarized in table 10.

Table 10
Active substance No.The concentration of active substance in the vehicle, %The expected degree of mortification %Defined degree of mortification %
Connection # And0,000810
1,2570
Connection # G2,500

Table 10 (continued)
Active substance No.The concentration of active substance in the vehicle, %The expected degree of mortification %The installed power of the ü killing, %
Connection # D0,000845
Tsyprokonazolu0,00410
Triadimenol20,000
Connection # And+tsyprokonazolu0,0008

+

0,004
10100
Connection # G+triadimenol2,50

+

20,00
090
Connection # D+tsyprokonazolu0,0008

+

0,004
50100

Example 11

Experience with Spodoptera frugiperda

1 parts specified in table 11 of the active substance is mixed with 7 wesch of dimethylformamide as solvent and 1 parts alkylarylsulphonates ether as an emulsifier, and the resulting concentrate is diluted with water to the desired concentration listed in table 11.

Cabbage leaves (Brassica oleracea) are treated by immersion in the received vehicle and even on wet leaves endure caterpillars Spodoptera frugiperda.

After 7 days to determine the percentage loss of caterpillars. 100% means that all caterpillars have been killed and 0% means that none of the caterpillar was not put to death.

The results of the experiment are summarized in table 11.

Table 11
Active substance No.The concentration of active substance in the vehicle, %The expected degree of mortification %Defined degree of mortification %
Connection # And0,00445
Fludyoksonil0,020
Connection # And+fludyoksonil0,004+0,0245100

Example 12

Experience with Spodoptera frugiperda

1 wescast specified in table 12 active compound is mixed with 4 westcastle acetone as solvent and 1 westcastle alkylarylsulphonates ether as an emulsifier and the concentrate is diluted with water to the desired concentration.

The resulting tool is mixed with soil in the amount indicated in table 12.

Pots fill-treated soil and the top serves 3 sprouted wheat grains. Then the pots are placed in a greenhouse at 20°C.

After 9 days the plants add experimental insects.

After a further 5 days to determine the effectiveness of protection by defining the number of plants in % of the control experiment in which the soil was not treated with the active compounds.

0% means that the protection corresponds to the test of experience, and 100% means full for the ITU from insects.

The results of the experiment are summarized in table 12.

Table 12
Active substance No.The concentration of the active substance h/mil. (mg/l soil)The expected effectiveness of the protection in %Installed the effectiveness of protection, %
Connection # G10,000 50
Connection # D2,5060
Triadimenol20,000
Fenpiclonil20,000
Metalaxyl20,000
Tsyprokonazolu20,000
Connection # G+metalaxyl10,00

+

20,00
5070
Connection # D+triadimenol2,50

+

20,00
6080
Connection # D+fenpiclonil2,50

+

20,00
6090
Connection # D+tsyprokonazolu2,50

+

20,00
6080

Example 13

Experience with Heliothis virescns

1 parts specified in table 13 of the active substance is mixed with 7 parts of dimethylformamide as solvent and 1 parts alkylarylsulphonates ether as an emulsifier, and the resulting concentrate is diluted with water to the desired concentration listed in table 13.

Shoots of soybean (Glycine max) are treated by immersion in the received vehicle and even on wet leaves carry larvae of Heliothis virescens.

After 7 days to determine the percentage loss of caterpillars. 100% means that all caterpillars have been killed and 0% means that none of the caterpillar was not put to death.

The results of the experiment are summarized in table 13.

Table 13
Active substance No.The concentration of active substance in the vehicle, %The expected degree of mortification %Defined degree of mortification %
Connection # 0,0001650
AZOXYSTROBIN0,00080
Connection # In+AZOXYSTROBIN0,00016

+

0,0008
50100

Example 14

Experience with larvae of Diabrotica balteata

1 wescast specified in table 15 active compound is mixed with 4 weight. parts of Aceto is and as a solvent and 1 weight. part alkylarylsulphonates ether as an emulsifier and the concentrate is diluted with water to the desired concentration.

The resulting tool is mixed with soil in the amount indicated in table 14.

Pots fill-treated soil and the top serves 5 germinating corn seed. Then move pots in a greenhouse at a temperature of 20°C.

After 2 days add experimental insects.

After 7 days to determine the effectiveness of protection by counting the number of emerged plants of maize and determination of the result in % of the control experiment in which the soil was not treated with the active compounds.

0% means that the protection corresponds to the test of experience, and 100% means full protection from insects.

The results of the experiment are summarized in table 14.

Table 14
Active substance No.The concentration of the active substance h/mil. (mg/l soil)The expected effectiveness of the protection in %Installed the effectiveness of protection in %
Connection # G5,0090
2,5040
Tolylfluanid20,000
Fenpiclonil20,000
AZOXYSTROBIN20,000
Metalaxyl20,000
Tsyprokonazolu20,000
Kresoxim-methyl20,000
Thiram20,000
Bitertanol20,000
5,00
+90100
Connection # 20,00
G+tolylfluanid2,50
+40100
20,00
5,00
+90100
Connection # 20,00
G+fenpiclonil 2,50
+40100
20,00

+
Table 14 (continued)
Active substance No.The concentration of the active substance h/mil. (mg/l soil)The expected effectiveness of the protection in %Installed the effectiveness of protection in %
5,00
+90100
Connection # 20,00
G+AZOXYSTROBIN2,50
+40100
20,00
Connection # G+2,50
metalaxyl+4090
20,00
5,00
90100
Connection # G+20,00
bitertanol2,50
+4090
20,00
2,50
Connection # +
G+tsyprokonazolu20,004070
5,00
+90100
Connection # 20,00
G+kresoximmethyl2,50
+40100
20,00
50,00
+90100
Connection # 20,00
G+thiram2,50
+4090
20,00

Example 15

Experience with larvae of Phaedon cochleariae

1 wescast specified in table 16 active compound is mixed with 4 westcastle acetone as solvent and 1 weight. part alkylarylsulphonates ether as an emulsifier and the concentrate is diluted with water to the desired concentration.

The resulting tool is mixed with soil in the amount indicated in table 15.

Pots fill-treated soil and plant cabbage (Brassica oleracea). After 7 days the plants add experimental insects.

After a further 3 days, determine the effectiveness of protection by defining the number of cabbage plants in % of the control experiment in which the soil was not treated with the active compounds.

0% means that the protection corresponds to the test of experience, and 100% means full protection from insects.

The results of the experiment are summarized in table 15.

Table 15
Active substance No.The concentration of the active substance h/mil. (mg/l soil)The expected effectiveness of the protection in %The us is set out in effektivnosti, %
Connection # G2,50

5,00

10,00
0

80

95
Triadimenol20,000
Connection # G+triadimenol10,00

+

20,00

5,00

+

20,00

2,50

+

20,00
95

80

0
100

100

90

Comparison data table 9-16 shows the means of combating insects synergies.

1. Means of combating phytopathogenic fungi that contains two active substances, wherein the active substance contains a compound of General formula (I)

in which

E. means NO2or CN,

R means thiazolyl-methyl or pyridyl-methyl, substituted with halogen,

A represents hydrogen,

Z means alkylamino with the number of carbon atoms from 1 to 4 or

A and Z together with the atoms to which they are linked, form thiazolidin, imidazolidin, hexahydro-1,3,5-triazine, which have nitrogen atoms in the 3 and 5-position is substituted by an alkyl group with 1-4 carbon atoms in the alkyl group, 6-membered saturated heterocyclic fragment which further includes oxygen and heterogroup N-alkyl, while the alkyl in N-alkylene the group contains 1-4 carbon atoms, and

a compound selected from the group comprising tsyprokonazolu, triadimenol, walkable, metalaxyl, AZOXYSTROBIN, kresoximmethyl, triazoxide, tolylfluanid, fenpiclonil and fludyoksonil

when the weight ratio of compounds of General formula (I) to the compound of the specified group, equal 1:(0,1-10).

2. Means of combating phytopathogenic fungi according to claim 1, characterized in that compounds of General formula (I) contains a compound of the formula

3. Means of combating insects that contains two active substances, wherein the active substance contains a compound of General formula (I)

in which

E. means NO2or CN,

R means thiazolyl-methyl or pyridyl-methyl, substituted with halogen,

A represents hydrogen,

Z means alkylamino with the number of carbon atoms from 1 to 4 or a and Z together with the atoms to which they are linked, form thiazolidin, imidazolidin, hexahydro-1,3,5-triazine, which have nitrogen atoms in the 3 and 5 position is replaced by akilina group with 1-4 carbon atoms in the alkyl group, 6-membered saturated heterocyclic fragment which further includes oxygen and heterogroup N-alkyl, while the alkyl N-alkyl group contains 1-4 atom of plastics technology : turning & the Yes, and

a compound selected from the group comprising tsyprokonazolu, bitertanol, thiram, metalaxyl, AZOXYSTROBIN, kresoximmethyl, tolylfluanid, fenpiclonil, fludyoksonil and triadimenol,

when the weight ratio of compounds of General formula (I) to the compound of the specified group, equal 1:(0,1-10).

4. Means of combating insects according to claim 3, characterized in that compounds of General formula (I) contains a compound of the formula



 

Same patents:

FIELD: agricultural chemistry.

SUBSTANCE: invention relates to herbicidal composition containing (A) mesotrion and (B) the second herbicide selected from amicarbazone, metribuzine, flumetsulfam, trifloxysulfuron, pyriphthalide, prosulfocarb or herbicidically active salts thereof in (A):(B) ratio from 32:1 to 1:3. Disclosed is method for controlling of undesired plants which includes application of herbicidically effective amount of said composition into locus with such plants.

EFFECT: composition of high herbicidal activity.

8 cl, 6 tbl

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SUBSTANCE: claimed method includes application in environments of pests of germinal calls thereof effective amount at least one vicinal diol of formula R(OH)2 selected from group containing diols, wherein R represents aliphatic hydrocarbon chain with the proviso that carbon atom in the chain adjacent to diol functional group is not substituted with ethyl and chain skeleton contains 8-20 carbon atoms. Composition for insecticidal and arachnicidal application containing abovementioned diol of formula R(OH)2 also is disclosed. Methods for controlling of sucking lice, flies, mites, cockroaches, and pests from group comprising Pediculus humanus, Dermatophagoides pteronyssinus, and Musca domestica.

EFFECT: death or non-vitality of pests after treatment.

26 cl, 4 tbl, 4 ex

FIELD: method for controlling of arthropod pests.

SUBSTANCE: claimed method includes application in environments of pests of germinal calls thereof effective amount at least one vicinal diol of formula R(OH)2 selected from group containing diols, wherein R represents aliphatic hydrocarbon chain with the proviso that carbon atom in the chain adjacent to diol functional group is not substituted with ethyl and chain skeleton contains 8-20 carbon atoms. Composition for insecticidal and arachnicidal application containing abovementioned diol of formula R(OH)2 also is disclosed. Methods for controlling of sucking lice, flies, mites, cockroaches, and pests from group comprising Pediculus humanus, Dermatophagoides pteronyssinus, and Musca domestica.

EFFECT: death or non-vitality of pests after treatment.

26 cl, 4 tbl, 4 ex

FIELD: organic chemistry, nematocides.

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10 cl, 2 tbl, 19 ex

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6 ex

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9 cl, 1 tbl

FIELD: organic chemistry, agriculture.

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20 cl, 16 tbl, 33 ex

FIELD: organic chemistry, agriculture.

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15 cl, 21 tbl, 9 ex

FIELD: chemistry of organophosphorus compounds, agriculture, pesticides.

SUBSTANCE: invention describes bis-(diethylammonium)-dihydrogen-1-hydroxyethyl-1,1diphosphonate monohydrate of the formula (I) showing properties of stimulator of growth o agricultural root crop plants. Invention provides enhancing productivity of root crops beet and carrot and expanding assortment of agents for this designation.

EFFECT: valuable agricultural properties of agent.

1 tbl, 2 ex

FIELD: agricultural chemistry.

SUBSTANCE: invention relates to herbicidal composition containing (A) mesotrion and (B) the second herbicide selected from amicarbazone, metribuzine, flumetsulfam, trifloxysulfuron, pyriphthalide, prosulfocarb or herbicidically active salts thereof in (A):(B) ratio from 32:1 to 1:3. Disclosed is method for controlling of undesired plants which includes application of herbicidically effective amount of said composition into locus with such plants.

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8 cl, 6 tbl

FIELD: method for controlling of arthropod pests.

SUBSTANCE: claimed method includes application in environments of pests of germinal calls thereof effective amount at least one vicinal diol of formula R(OH)2 selected from group containing diols, wherein R represents aliphatic hydrocarbon chain with the proviso that carbon atom in the chain adjacent to diol functional group is not substituted with ethyl and chain skeleton contains 8-20 carbon atoms. Composition for insecticidal and arachnicidal application containing abovementioned diol of formula R(OH)2 also is disclosed. Methods for controlling of sucking lice, flies, mites, cockroaches, and pests from group comprising Pediculus humanus, Dermatophagoides pteronyssinus, and Musca domestica.

EFFECT: death or non-vitality of pests after treatment.

26 cl, 4 tbl, 4 ex

FIELD: method for controlling of arthropod pests.

SUBSTANCE: claimed method includes application in environments of pests of germinal calls thereof effective amount at least one vicinal diol of formula R(OH)2 selected from group containing diols, wherein R represents aliphatic hydrocarbon chain with the proviso that carbon atom in the chain adjacent to diol functional group is not substituted with ethyl and chain skeleton contains 8-20 carbon atoms. Composition for insecticidal and arachnicidal application containing abovementioned diol of formula R(OH)2 also is disclosed. Methods for controlling of sucking lice, flies, mites, cockroaches, and pests from group comprising Pediculus humanus, Dermatophagoides pteronyssinus, and Musca domestica.

EFFECT: death or non-vitality of pests after treatment.

26 cl, 4 tbl, 4 ex

FIELD: organic chemistry, nematocides.

SUBSTANCE: invention relates to compounds of the formula (I): wherein Ar1 and Ar2 mean independently of one another unsubstituted phenyl or mono- or multi-substituted phenyl with substitutes having independent of one another values and chosen from the group including halogen atom, (C1-C6)-alkyl or halo-(C1-C6)-alkyl; Q1 means -OCH2 or -C(O); Q2 means a direct bond or -C(O); R3 means hydrogen atom; R4, R5 and R6 mean independently of one another hydrogen atom or (C1-C6)-alkyl; W means O or S atom; a means 1, 2, 3 or 4; b means 0; n means 0 or 1. Also, method proposes a method for synthesis of compound of the formula (I) and carriers and/or dispersers also. Also, invention proposes using compound of the formula (I) for control of nematodes. Invention provides preparing derivatives of benzamidoacetonitrile used in control of nematodes.

EFFECT: improved preparing method, valuable properties of compounds.

10 cl, 2 tbl, 19 ex

FIELD: agriculture, herbicides.

SUBSTANCE: invention relates to agent for reducing of toxic action of hormonal herbicidal 2,4-dichlorophenoxyacetic acid on sunflower sprouts. Claimed agent contains 2-(2-furil)-1,3-dioxolane of formula I .

EFFECT: herbicide with decreased toxic action on sunflower.

FIELD: agriculture.

SUBSTANCE: invention relates to preparations obtained by pharmacopoeia method from overground and underground parts of calamus (Acorus calamus L.) for controlling of freshwater mollusk.

EFFECT: enhanced assortment of effective agents for controlling of freshwater mollusk.

6 ex

FIELD: agriculture.

SUBSTANCE: claimed composition contains a) one or more insecticide, in particular parathyroid: b) one or more solvents selected from group comprising aliphatic monocarboxylic acid esters, aromatic monocarboxylic acid esters, aromatic dicarboxylic acid esters, and tri-n-alkyl phosphates; c) emulsion system including one or more anionic surfactants and two or more nonionic surfactants, wherein one surfactant has HLB of 4-12; d) one or more film-forming agents/thickeners; and e) water. Method for insect pest controlling includes application of claimed composition onto insects or plants.

EFFECT: composition of reduced toxicity.

9 cl, 1 tbl

FIELD: organic chemistry, agriculture.

SUBSTANCE: invention relates to anthranylamide derivative selected from compound of formula I or N-oxides thereof, wherein R1 represents methyl, F, Cl, Br; R2 represents F, Cl, Br, I, CF3; R3 represents CF3, Cl, Br, OCH2CF3; R4a represents C1-C4-alkyl; R4b represents H, CH3; and R5 represents Cl, Br, and agriculturally acceptable salt thereof. Also disclosed are composition for pest controlling containing biologically effective amount of formula I and at least one additional component selected from group comprising surfactants, solid and liquid diluents; composition for invertebrate insect controlling containing biologically effective amount of formula I and at least one additional biologically active compound or agent. Also disclosed are method for insect controlling as well as intermediates such as benzoxazinone and parasolocarboxylic acid derivatives.

EFFECT: compounds with insecticide activity, useful in insect controlling.

20 cl, 16 tbl, 33 ex

FIELD: organic chemistry, agriculture.

SUBSTANCE: invention relates to ortho-substituted arylamides of formula I , wherein J represents phenyl ring or pyrazole ring each substituted with one or two substitutes independently selected from R5; K represents -NR1C(=A)- or -NR1SO2-; L represents -C(=B)NR2-, -SO2NR2- or -C(=B)-; A and B represent O; R1 and R2 represent H; R3 represents C1-C6-alkyl optionally substituted with one or more substitutes, independently selected from group containing CN, NO2, C1-C4-alkylsulfonyl and C2-C6-alkoxycarbonyl; each R4 independently represents C1-C6-alkyl, halogen or CN; each R5 independently represents C1-C6-alkyl, halogen or C1-C4-haloalkoxy or pyridinyl optionally substituted with one substitute independently selected from R9; wherein R9 represents halogen; n = 1-2; with the proviso, that when K represents -NR1C(=A)- L is not -C(=B)NR2-, and salts thereof, method for insect controlling by using abovementioned compounds. Intermediate for synthesis of target compounds having formula 2 also is disclosed.

EFFECT: compounds with insecticide activity, useful in insect controlling.

15 cl, 21 tbl, 9 ex

FIELD: chemistry of organophosphorus compounds, agriculture, pesticides.

SUBSTANCE: invention describes bis-(diethylammonium)-dihydrogen-1-hydroxyethyl-1,1diphosphonate monohydrate of the formula (I) showing properties of stimulator of growth o agricultural root crop plants. Invention provides enhancing productivity of root crops beet and carrot and expanding assortment of agents for this designation.

EFFECT: valuable agricultural properties of agent.

1 tbl, 2 ex

FIELD: organic chemistry, agriculture.

SUBSTANCE: invention relates to pest controlling agents containing compound of formula I in mixture with active fungicidal material selected from azoxystrobin, tebuconazol, prothioconazol etc., in mass ratio of formula I/active fungicidal material providing marked synergic action.

EFFECT: enhanced assortment of pest controlling agents based on nitromethylene derivatives.

2 cl, 15 tbl, 9 ex

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