Plant fungicidal composition and uses thereof

FIELD: agriculture, fungicides.

SUBSTANCE: claimed composition contains two components as active ingredients in synergistically effective amount in combination with respective filler, wherein component 1 represents O-methyloxime of 2-[α-{[(α-methyl-3-fluoromethylbenzyl)imino]oxy7}ortho-tolyl]-glyoxylic acid methyl aster, and component II represents compound selected from group containing II1 4-(2,2-difluoro-1,3-(benzodioxol-4-yl)-pyrrol-3-carbonitrile (fludioxanyl); II2 4-(2,3-dichlorophenyl)-pyrrol-3-carbonitrile (phenpiclonyl); II3 1-methylcyclohexanecarboxylic acid (2,2-dichloro-4-hydroxyphenyl)-amide (phenhexamide); II4 2-{2-[6-(2-cyanophenoxy)-pyrimidine-4-yloxy]phenyl}-3-methoxyacrilic acid methyl ester (azoxystrobin); II5 methoxyimino-(2-ortho-tolyloxymethylphenyl)-acetic acid methyl ester (cresoxymemethyl). Method for controlling and preventing of plant diseases also is disclosed. Claimed method includes application of stricken plant parts with component I and component II on any order or simultaneously in synergistically effective amount.

EFFECT: fungicide of high activity.

3 cl, 6 tbl, 4 ex

 

The present invention relates to novel mixtures of active substances as plant protection products, has increased due to synergism activity and comprising as components at least two active substances, as well as to a method of using such compounds for plant protection, in particular to fight and prevent disease outbreaks.

Component I is a compound

On-methyloxime methyl ester 2-[α-{[(α-methyl-3-trifluoromethyl-benzyl)imino]oxy}ortho-tolyl]Glyoxylic acid (EP-A-460575), a

component II is a compound selected from the group including

IIE) 4-(2,2-debtor-1,3-benzodioxol-4-yl)pyrrole-3-carbonitrile ("fludyoksonil") (The Pesticide Manual, 10th ed., 1994, 326),

G) 4-(2,3-dichlorophenyl)pyrrole-3-carbonitrile ("fenpiclonil") (The Pesticide Manual, 10th ed., 1994, 302),

S) (2,3-dichloro-4-hydroxyphenyl)amide 1-methylcyclohexanecarboxylic acid ("fenhexamid") (EP-A-339418),

I) methyl ester 2-{2-[6-(2-cianfrocca)pyrimidine-4-yloxy] phenyl}-3-ethoxyacrylate acid (AZOXYSTROBIN") (EP-A-382375),

C) methyl ether, methoxamine (2-ortho-tolylacetylene) acetic acid (kresoxim-methyl") (EP-A-398692), or one of the salts or metal complexes of the compounds I and II.

According to the invention it has been unexpectedly found that the mixture of components I and I according to the invention have not only additive activity but significantly higher due to synergism of activity in regard to the prevention and combating plant diseases.

The preferred ratio of the two active compounds I:II in the mixture is from 20:1 to 1:20, and more preferred intervals range from 10:1 to 1:10, from 6:1 to 1:6, 2:1 to 1:10 and 10:1 to 1:2.

The mixture of active ingredients I+II according to the invention possess valuable characteristics in respect of plant protection against outbreaks of various diseases.

In addition, a mixture comprising compound II may activate defense system, which is latent in the plant, in terms of protection from exposure to the pathogen and thus can protect the plant by immunization.

Mixtures of active substances according to the invention can be used to inhibit or destroy the microorganisms which occur on plants or parts of plants (fruits, flowers, leaves, stems, tubers, roots) in different crops of useful plants, while protecting against these microorganisms also applies to those parts of plants, which are formed in the later period. They can also be used as agents for treatment of seeds with the aim of protecting material for breeding plants, particularly seeds (fruit, tubers, grains) and seedlings of plants (e.g. the R, rice), to protect them from fungal and soil pathogenic fungi. Mixtures of active substances according to the invention are compatible with plants and harmless to the environment.

Mixtures of active substances according to the invention are effective against phytopathogenic fungi belonging to the following classes: Ascomycetes (for example Venturia, Podosphaera, Erysiphe, Monilinia, Mycosphaerella, Uncinula), Basidiomycetes (e.g. the genera Hemileia, Rhizoctonia, Puccinia), imperfect fungi (for example Botrytis, Helminthosporium, Rhynchosporium, Fusarium, Septoria, Cercospora, Alternaria, Pyricularia and, in particular, Pseudocercosporella herpotrichoides), Oomycetes (for example, Phytophthora, Peronospora., Bremia, Pythium, Plasmopara).

Be protected against specified in the description of the diseases of cultivated plants falling under the scope of the present invention include, for example, the following species of plants: cereals (wheat, barley, rye, oats, rice, sorghum and the like), beet (sugar beet and fodder beet), pome fruit, stone fruits and berries (apples, pears, plums, peaches, almonds, cherries, strawberries, raspberries and blackberries), leguminous plants (beans, lentils, peas, soybeans), oil plants (rape, mustard, poppy, olives, sunflower, coconut, castor, cocoa beans, groundnuts), cucumber plants (pumpkins, cucumbers, melons), fibre plants (cotton, flax, hemp, jute), citrus crops (oranges, lemons, GRE is Prouty, mandarins), vegetables (spinach, lettuce, asparagus, cabbage, carrots, onions, tomatoes, potatoes, paprika), Lauraceae (Laurel culture) (avocado, cinnamon tree, camphor tree), or plants such as maize, tobacco, nuts, coffee, sugar cane, tea, vines, hops, bananas and natural rubber plants, as well as ornamentals (flowers, shrubs, deciduous trees and evergreen trees such as conifers). However, the scope of the invention is not limited to the above list.

Mixtures of active substances according to the invention have the greatest advantages in the following applications:

I+IIE: on cereals, in particular wheat and barley, and vines and vegetable crops

I+J: for the treatment of seed,

I+Z: vegetable crops and grapes,

I+I: grain and grapes,

I+K: on cereals, in particular wheat and barley.

The mixture of active substances of formula I and II are usually applied in the form of compositions. The active substances of the formulae I and II can be used for processing the cultivated area or plant to be treated, simultaneously or sequentially in the same day, optionally together with further carriers, surfactants or other conducive to the introduction of additives generally used in about the region of the cooking preparative forms.

Appropriate carriers and additives can be solid or liquid and are substances which are suitable for the preparation of preparative forms, for example, natural or regenerated mineral substances, solvents, dispersing agents, wetting agents, adhesives, thickeners, binders or fertilizers.

The preferred method of processing a mixture of active substances containing at least one of these active ingredients I and II, is the processing of above-ground plant parts, in particular sheet system (sheet processing). The frequency of treatments and the rate of application depend on biological and climatic conditions of life of the pathogen. However, the active substances can also penetrate the plant through the root system (systemic action) from the soil or water, if the place of growth of the plant is saturated with liquid drug (for example, when the cultivation of rice), or if the compounds applied to the soil in solid form, for example in the form of granules (soil application). Compounds of formulas I and II can also be applied to seeds by seed treatment (coating), while the tubers or seeds or immersed sequentially in the liquid composition of each active substance or cover them already combined liquid or a dry composition. In addition, in special cases also the possibility of the us other processing methods, for example, selective processing of the kidneys or ovaries of fetuses. In this connection, included in the compositions used in unmodified form or preferably together with inert fillers normally used in the preparation preparative forms, which are prepared in a known manner to give, for example, emulsion concentrates, covering pastes, ready-to-use solutions for spraying or dilutable solutions, diluted emulsions, wettable powders, soluble powders, Farrukh Dustov, granules or encapsulated, for example in polymeric substances, drugs. Processing methods, such as spraying, spraying in the form of a mist, dusting, scattering, coating or irrigation, is chosen depending on the type of composition, and in accordance with the objectives and specific conditions, as well as depending on the choice of the type of the active substance. Preferred norms of flow of the mixture of active substances typically range from 50 g to 2 kg of active ingredient (A.I.) per hectare, preferably from 100 g to 700 g A.I/ha, most preferably from 75 g to 450 g A.I/ha When used for the treatment of seed consumption rates range from 0.5 g to 600 g, preferably from 5 g to 80 g A.I. per 100 kg seed.

Preparative form get in a known manner, for example, by carefully what additional mixing and/or grinding the active substances with solvents, for example with solvents, solid fillers, and optionally with surfactants.

Suitable solvents are aromatic hydrocarbons, preferably8-C12-fractions, such as xiaowei mixtures or substituted naphthalenes, esters of phthalic acid such as dibutyl phthalate or dioctylphthalate, aliphatic hydrocarbons, such as cyclohexane or paraffins, alcohols and glycols and their ethers and esters, such as ethanol, ethylene glycol, onomatology or monotropy ether of ethylene glycol, ketones such as cyclohexanone, highly polar solvents, such as N-methyl-2-pyrrolidone, dimethylsulfoxide or dimethylformamide, as well as optional epoxydecane vegetable oils, such as epoxydecane coconut oil or soybean oil; or water.

Solid fillers, for example, Farrukh Dustov and dispersible powders, are usually natural mineral powder fillers, such as calcite, talc, kaolin, montmorillonite or attapulgite. To improve the physical properties is also possible to add highly dispersed silicic acid or highly dispersed absorbent polymers. Suitable granulated adsorptive fillers carriers are porous types, for example pumice, broken brick, thick or bent the bat, and suitable nearbywe fillers are, for example, calcite or sand. In addition, also can be used a number of pre-granulated materials of inorganic or organic origin, in particular dolomite or crushed into powder residues.

Depending on the nature of the active substances of formula I and II, on the basis of which is made preparative form suitable surfactants are nonionic, cationogenic and/or anionic surfactants having good emulsifying, dispersing and wetting properties. Under surfactants also need to understand the mixture of surface-active substances.

Especially preferred conducive to the application of additives are natural or synthetic phospholipids from the group of cefalino and lecithins, for example, phosphatidylethanolamine, phosphatidylserine, phosphatidylglycerol, lysolecithin.

Agricultural compositions usually contain 0.1 to 99%, preferably from 0.1 to 95% of active ingredients of formulae I and II, from 99.9% to 1%, preferably from about 99.9 to 5% of a solid or liquid additive and 0 to 25%, preferably from 0.1 to 25% surfactant.

While concentrated compositions are more predpochtite lname as marketed products, direct consumer typically uses dilute compositions.

Below the invention is illustrated in the examples, the term "active ingredient" (A.I.) refers to a mixture of compound I and compound II in a certain ratio.

Examples preparative forms

Wettable powder

Componentsa)6)in)
active ingredient [I:II=1:3(and), 1:2(6), 1:1(in)]25%50%75%
sodium lignosulphonate5%5%-
sodium lauryl sulfate3%-5%
diisobutyldimethoxysilane sodium-6%10%
polietilenglikolya ether op (7-8 mol ethylenoxide)-2%-
highly dispersed silicon dioxide5%10%10%
kaolin62%27%-

The active ingredient is thoroughly mixed with the additives and ground in appropriate mills. Get designed for spraying powders which can be diluted with water is with suspensions of any desired concentration.

Emulsion concentrates

active substance (I:II=1:6)10%
polietilenglikolya ether op3%
(4-5 mol ethylenoxide)
dodecylbenzenesulfonate calcium3%
polietilenglikolya ether castor4%
oil (35 mole ethylenoxide)
cyclohexanone30%
Kiselyova mixture50%

Emulsions of any desired concentration can be prepared by dilution of such concentrates with water, and then they can be used for protection of plants.

Granules coated

active substance (I:II=1:10)8%
polyethylene glycol (molecular weight 200)3%
kaolin89%

Finely ground active ingredient is uniformly fed into the mixer, to the kaolin moistened with polyethylene glycol. In this way we obtain a dust free granules coated.

Biological examples

High fungicidal activity of the compositions of the active compounds according to the invention is obvious is C the following example. While the active compounds individually are weak (low) fungicidal activity, combinations thereof have activity that exceeds a simple sum of the activities of the components.

Synergistic effect of fungicides is always observed when the fungicidal activity of combinations of active substances exceeds the total activity of active substances, when they are used separately.

The expected activity for a given combination of two active substances can be calculated as described below (see S.R. Colby Calculating synergistic and antagonistic response of combinations of herbicides, 15, 20-22(1967)).

If

X is the efficacy when applying the active substance And at normal flow rate of n g/ha,

Y denotes the efficacy when applying the active substance In at the normal flow rate of n g/ha,

E is the efficiency when applying the active compounds a and b at the rate of type g/ha,

then E=X+Y-(X×N)/100.

Degree (coefficient) efficiency expressed in %. 0% means that the efficiency in the control, 100% means that the disease is observed.

If the actual fungicidal activity exceeds the calculated value, then the activity of the combination is vergadain, i.e. there is a synergistic effect. In this case, the observed efficiency may be the use than expected, calculated according to the formula above.

The invention is illustrated by the following examples.

Example

Test for protection against Plasmopara viticola (the culture of the vine)

Solvents: 24.5 parts by weight of acetone

24.5 parts by weight of dimethylacetamide

Emulsifier: 1 part by weight alkylarylsulphonates ether

To prepare the drug 1 part by weight of active substance is mixed with the specified amount of solvent and emulsifier, and the resulting concentrate is diluted with water to the desired concentration.

For testing protective activity, young plants are sprayed with the preparation of the active substance at a specified rate of flow. After drying plants infect aqueous spore suspension Plasmopara viticola and placed for one day in an incubation chamber with a temperature of approximately 20°C and a relative atmospheric humidity of 100%. Then the plants are placed for 4 days in a greenhouse with a temperature of approximately 21°C and a relative atmospheric humidity of approximately 90%. Then the plants are sprayed with water and placed for 1 day in an incubation chamber.

Testing is carried out 6 days after infection. 0% means an efficacy in the control, 100% means no signs of illness.

The data below in table 1 clearly show that the observed activity of whom is inali active substances according to the invention above, than the calculated activity, i.e. there is a synergistic effect.

Example

Test for protection against Sphaerotheca fuliginea (culture cucumbers)

Solvents: 24.5 parts by weight of acetone

24.5 parts by weight of dimethylacetamide

Emulsifier: 1 part by weight alkylarylsulphonates ether

To prepare a suitable preparation of 1 part by weight of active substance is mixed with the specified amount of solvent and emulsifier, and the resulting concentrate is diluted with water to the desired concentration or experimental or salesthe composition is diluted with water to the desired concentration.

For testing protective activity, young plants are sprayed with the preparation of the active substance at a specified rate of flow. After drying plants infect aqueous spore suspension Sphaerotheca fuliginea. Then the plants are placed in a greenhouse with a temperature of approximately 23°C and a relative atmospheric humidity of approximately 70%.

Testing is carried out after 7 days after infection. 0% means an efficacy in the control, 100% means no signs of illness.

Data the following tables 2 and 3 clearly show that the observed activity of the combination of active substances according to the invention is higher than the calculated activity, i.e. prisutstvie is no synergistic effect.

Example

Test for protection against Alternaria solani (on the culture of tomatoes)

Solvents: 24.5 parts by weight of acetone

24.5 parts by weight of dimethylacetamide

Emulsifier: 1 part by weight alkylarylsulphonates ether

To prepare the drug 1 part by weight of active substance is mixed with the specified amount of solvent and emulsifier, and the resulting concentrate is diluted with water to the desired concentration.

For testing protective activity, young plants are sprayed with the preparation of the active substance at a specified rate of flow. After drying infect plants with an aqueous suspension of spores Alternaria solani. Then the plants are placed in a greenhouse with a temperature of approximately 20°C and a relative atmospheric humidity of 100%.

Testing is carried out in 3 days after infection. 0% means an efficacy in the control, 100% means no signs of illness.

Data the following tables 4 and 5 clearly show that the observed activity of the combination of active substances according to the invention is higher than the calculated activity, i.e. there is a synergistic effect.

Example

Test for protection against Leptoshaera nodorum (on the culture of wheat)

R is storytell: 25 parts by weight of dimethylacetamide

Emulsifier: 0.6 part by weight alkylarylsulphonates ether

To prepare the drug 1 part by weight of active ingredient or combination of active substances are mixed with the specified amount of solvent and emulsifier, and the resulting concentrate is diluted with water to the desired concentration.

For testing protective activity, young plants are sprayed with the preparation of active substances or combinations of active substances during specified normal flow. After drying plantsinfect aqueous spore suspension Leptoshaera nodorum. Then plants left for 48 hours in an incubation chamber at 20°C and a relative humidity of 100%. Then the plants are placed in a greenhouse with a temperature of 15°C and a relative atmospheric humidity of approximately 80%.

Testing is carried out within 10 days after infection. 0% means an efficacy in the control, 100% means no signs of illness.

Table 6
Test for protection against destruction Leptoshaera nodorum (on the culture of wheat)
Active connectionThe consumption rate g/haEfficiency (%)
Known:

component (I)

methyl ester-O-methyloxime 2-(α{[α-methyl-3-trifloromethyl them is about]oxy]-ortho-tolyl] Glyoxylic acid
2567
component (IIE) (fludyoksonil)2533
according to the invention

(I) + (IN)
12,5+12,583

1. Fungicidal composition for plants, comprising as components at least two active substances in the number of synergistic activity in combination with an appropriate filler, wherein component I is a O-methyloxime methyl ester 2-[α-{[(α-methyl-3-trifluoromethyl-benzyl)imino]oxy}ortho-tolyl]Glyoxylic acid, and component II is a compound selected from the group including

IIE) 4-(2,2-debtor-1,3-(benzodioxol-4-yl)pyrrole-3-carbonitrile ("fludyoksonil"),

G) 4-(2,3-dichlorophenyl)pyrrole-3-carbonitrile ("fenpiclonil"),

S) (2,3-dichloro-4-hydroxyphenyl)amide 1-methylcyclohexanecarboxylic acid ("fenhexamid"),

I) methyl ester 2-{2-[6-(2-cianfrocca)pyrimidine-4-yloxy] phenyl }-3-ethoxyacrylate acid (AZOXYSTROBIN"),

C) methyl ether, methoxamine(2-ortho-tolylacetylene)acetic acid (kresoxim-methyl").

2. The composition according to claim 1, characterized in that the mass ratio of components I:II is from 20:1 to 1:8.

3. The way of the fight against and prevention of diseases of plants, which is eat, the place suffered defeat by the fungus, or which may be subject to defeat by the fungus, processed in any order or simultaneously, component I and component II according to claim 1 in number, showing a synergistic effect.



 

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3 cl, 3 tbl, 10 ex

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3 cl, 3 tbl, 10 ex

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1 tbl, 1 ex

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2 cl, 4 tbl

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2 cl, 8 tbl, 32 ex

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8 cl, 1 ex

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3 cl, 4 tbl, 3 ex

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3 cl, 7 tbl, 2 ex

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3 cl, 46 tbl, 4 ex

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6 cl, 15 ex

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8 cl, 12 ex

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FIELD: organic chemistry, chemical technology, herbicides, agriculture.

SUBSTANCE: invention relates to new sulfonamides of the formula (I):

and their salt wherein A represents substituted or unsubstituted benzene ring or 5-membered, or 6-membered substituted or unsubstituted heteroaromatic ring taken among the group comprising thienyl, pyrazolyl, imidazolyl, pyridyl wherein optional substitutes are taken among the group consisting of halogen atom, substituted or unsubstituted (C1-C4)-alkyl, unsubstituted or substituted (C1-C4)-alkoxy-group, nitro-group, phenyl, phenoxy-group, benzoyl and (C1-C4)-alkylcarboxylate when any alkyl fragment in the latter indicated substituted is substituted with one or some halogen atoms, (C1-C4)-alkoxy-groups, cyano-group and phenyl; Q represents -O-, -S- or group of the formula: -CXX' wherein X and X' can be similar or different and each represents hydrogen atom, halogen atom, cyano-group, alkyl comprising 1-8 carbon atoms, or the group -ORa, -SRa; or one of X and X' represents hydroxy-group and another has values determine above; Ra means (C1-C8)-alkyl, phenyl; Rb means (C1-C8)-alkyl, phenyl; Y means nitrogen atom or the group CR9; R1 means unsubstituted (C1-C8)-alkyl or that substituted with halogen atom, cyano-group, phenyl or (C1-C4)-alkoxycarbonylamino-group, or it represents phenyl; R2 means hydrogen atom (H), (C1-C4)-alkyl; R3 and R4 can be similar or different and each represents (C1-C4)-alkyl, (C1-C4)-alkoxy-group, halogen atom; R9 means hydrogen atom (H) under condition that when Q represents oxygen atom (O) or -S- then ring A represents 5-membered substituted or unsubstituted heteroaromatic ring and determined above. Compounds of the formula (I) possess the herbicide activity that allows their using for eradication of weeds. Also, invention describes a method for preparing compounds of the formula (I).

EFFECT: improved preparing method, valuable properties of compounds.

9 cl, 5 tbl, 18 ex

FIELD: organic chemistry, herbicides, agriculture.

SUBSTANCE: invention elates to novel derivatives of uracil of the formula [I] possessing herbicide activity, a herbicide composition based on thereof and to a method for control of weeds. In derivatives of uracil of the formula [I] the group Q-R3 represents a substituted group taken among:

wherein a heterocyclic ring can be substituted with at least a substitute of a single species taken among the group involving halogen atom, (C1-C6)-alkyl-(C1-C6)-alkoxy; Y represents oxygen, sulfur atom, imino-group or (C1-C3)-alkylimino-group; R1 represents (C1-C3)-halogenalkyl; R2 represents (C1-C3)-alkyl; R3 represents OR7, SR8 or N(R9)R10; X1 represents halogen atom, cyano-group, thiocarbamoyl or nitro-group; X2 represents hydrogen or halogen atom wherein each among R7, R8 and R10 represents independently carboxy-(C1-C6)-alkyl and other substitutes given in the invention claim; R9 represents hydrogen atom or (C1-C6)-alkyl. Also, invention relates to intermediate compounds used in preparing uracil derivatives.

EFFECT: improved preparing method, valuable properties of compounds.

40 cl, 16 sch, 12 tbl, 65 ex

FIELD: organic chemistry, agriculture.

SUBSTANCE: invention relates to selective herbicidal compositions, containing customary auxiliary substances, as well as: a) herbicidal effective amount of compound of formula I or agriculture acceptable salt thereof wherein R are independently C1-C6-alkyl, C1-C6-haloalkyl, C1-C4-alcoxy-C1-C4-alkyl, or C1-C4-alcoxy-C1-C4-alcoxy-C1-C4-alkyl; m = 2; Q is group of formula wherein R23 is hydroxyl and Y is C1-C4-alkylen bridge; and b) synergetically effective amount of one or more herbicides; and methods for controlling of undesired plants in tame cultures using the said composition. Also disclosed is composition containing customary auxiliary substances, as well as herbicidal and synergetically effective amount of 4-hydroxy-3-(2-methyl-6-trifluoromethylpyridine-3-carbonyl)bicyclo[3.2.1]octo-3-ene-2-one of formula 2.2 and herbicidal antagonistically effective amount of antidote of formula 3.1. Compositions based on 4-hydroxy-3-(2-methyl-6-trifluoromethylpyridine-3-carbonyl)bicyclo[3.2.1]octo-3-ene-2-one and herbicidal antagonistically effective amount of antidote, as well as methods for controlling of weeds and cereal grasses in tame cultures also are described.

EFFECT: compositions useful in effective controlling of many weeds both in pre-spring and post-spring phases.

5 cl, 63 tbl, 12 ex

FIELD: organic chemistry.

SUBSTANCE: invention describes C2-phenyl-substituted cyclic ketoenols of the general formula: wherein W means hydrogen atom, alkyl with 1-6 carbon atoms; X means alkyl with 1-6 carbon atoms, alkenyl with 2-6 carbon atoms; Y means hydrogen atom, methyl, ethyl, isopropyl, alkenyl with 2-6 carbon atoms, ethynyl; Z means hydrogen atom, alkyl with 1-6 carbon atoms under condition that at least one of residues W, X, Y or Z means a chain with at least 2 carbon atoms but only one of residues X and Y can mean alkenyl with 2-6 carbon atoms; CKE means one of the following groups: , , and wherein A means hydrogen atom, alkyl with 1-6 carbon atoms; B means hydrogen atom, alkyl with 1-6 carbon atoms; A and B in common with carbon atom to which they are bound mean cycloalkyl with 5-6 carbon atoms wherein the ring carbon atom can be substituted with oxygen atom and can be substituted with alkyl with 1-6 carbon atoms or alkoxyl with 1-6 carbon atoms; A and B in common mean group of the formula: D means hydrogen atom or phenyl substituted with fluorine atom if CKE means group of the formula (4); G means hydrogen atom (a) or one of groups of the formula: or wherein R1 means alkyl with 1-6 carbon atoms, alkoxymethyl with 1-2 carbon atoms; R2 means alkyl with 1-4 carbon atoms; A and Q1 in common mean alkanediyl with 3-4 carbon atoms; Q2 means hydrogen atom. Invention provides preparing compound of the formula (I) possessing with insecticide, acaricide and herbicide activity.

EFFECT: valuable properties of compounds.

2 cl, 8 tbl, 32 ex

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