Insecticide composition

FIELD: organic chemistry, insecticides.

SUBSTANCE: invention describes insecticide composition comprising the active amount of one pyridine compound of the formula (I)

or its salt wherein Y represents halogenalkyl group comprising from 1 to 2 carbon atoms and halogen atoms from 1 to 5; m = 0; Q represents compound of the formula:

wherein X represents oxygen atom; R1 and R2 represent independently hydrogen atom, alkyl group comprising from 1 to 6 carbon atoms and substituted with cyan-group, and one insecticide taken among carbofuran, carbosulfan, cipermethrin, bifentrin, acetamiprid, chlorfauazuron, fluphenoxuron, piriproxiphen, spinosad, emamectine benzoate, avermectin, buprophezin and fipronil taken in the weight ratio of compound of the formula (I) and other insecticide = from 1:2 to 100:1. The composition provides stable and strong effect and eradicates insects.

EFFECT: strong insecticide effect of composition.

4 cl, 11 tbl, 5 ex

 

The technical FIELD

The present invention relates to applicable in agriculture pesticide composition comprising a combination of a pyridine compound of the formula (I)below, or salts thereof with other insecticides, fungicides, etc.

PRIOR art

Up to the present time as an effective ingredient of the insecticide was applied organophosphorus compound, compound carbamate, PYRETHROID compound, etc. that has led to the fact that in recent years, some insects have become resistant to these insecticides. Therefore there was a need for the development of insecticide effective for these resistant insects. The pyridine compound of the formula (I) or its salt described in Japanese patent No. 2994182, JP-A-10-195072, JP-A-11-180957, WO 98/57969, WO 00/35285, WO/35912, WO 00/35913, WO 01/9104, WO 01/14373 etc.

Known pesticides are, respectively, characteristic spectra and action, however, their use raises some problems, namely that: sometimes their effect on some pests unsatisfactory; their residual activity is sometimes low and they do not have the necessary action within a certain period of time; satisfactory pesticide action can not be achieved and depends on the application. In addition, in spite of the popularity of nectariniidae with a strong pesticide action need improvement in the safety of fish, crustaceans and Pets, and there is a need to ensure a strong pesticide action at low doses.

The INVENTION

The authors of the present invention have been actively looking for solutions to the above problems, and studies have found that the combination of the pyridine compounds of the following formula (I) or its salt with another pesticide is able to simultaneously provide unexpected, stronger action for the destruction of pests in any place used at lower dosage than when using, respectively, only one effective component. This discovery was the subject of the present invention.

I.e. the present invention provides a pesticidal composition comprising at least one pyridine compound of the formula (I) or its salt and at least one other pesticide:

where Y represents halogenating group, m is 0 or 1, Q represents

or substituted or unsubstituted heterocyclic group (in which X represents an oxygen atom or a sulfur atom, R1and R2, respectively, independently represent a hydrogen atom, substituted or unsubstituted Alky is inuu group, substituted or unsubstituted alkenylphenol group, substituted or unsubstituted alkylamino group, substituted or unsubstituted cycloalkyl group, -C(W1R3group, -OR4group, -S(O)nR5group-other6group

-C(R8)=NO-R9group or a substituted or unsubstituted aryl group,

or R1and R2can form a =C(R10R11the group, or may form a C4-C55-membered or 6-membered heterocyclic group which may contain a nitrogen atom or an oxygen atom, together with the adjacent nitrogen atom,

R3represents a substituted or unsubstituted alkyl group, substituted or unsubstituted alkenylphenol group, substituted or unsubstituted alkylamino group, substituted or unsubstituted cycloalkyl group, substituted or unsubstituted aryl group, alkoxygroup, allylthiourea or mono - or dialkylamino,

R4represents a hydrogen atom, substituted or unsubstituted alkyl group, substituted or unsubstituted alkenylphenol group, substituted or unsubstituted alkylamino group, substituted or unsubstituted cycloalkyl group, substituted or unsubstituted aryl group, a substituted or unsubstituted heterocyclic group, or-COR3groups is,

R5represents an alkyl group or dialkylamino,

R6represents alkyl group or aryl group,

Z represents N or C-R7group

R7represents a hydrogen atom, halogen atom, substituted or unsubstituted alkyl group, alkoxygroup, allylthiourea or nitrogroup,

R8and R9, respectively, independently represent a hydrogen atom, substituted or unsubstituted alkyl group, substituted or unsubstituted alkenylphenol group, substituted or unsubstituted alkylamino group, substituted or unsubstituted aryl group, a substituted or unsubstituted heterocyclic group,

R10and R11, respectively, independently represent a hydrogen atom, substituted or unsubstituted alkyl group, substituted or unsubstituted alkenylphenol group, a substituted or unsubstituted heterocyclic group, -N(R12R13group, substituted or unsubstituted alkoxygroup, substituted or unsubstituted allylthiourea,

R12and R13, respectively, independently represent a hydrogen atom, substituted or unsubstituted alkyl group, substituted or unsubstituted alkenylphenol group, substituted or unsubstituted alkylamino group, substituted or unsubstituted aryl group or a substituted or unsubstituted g is teracycline group,

W1represents an oxygen atom or a sulfur atom, and n is 1 or 2).

PREFERRED embodiments of the INVENTIONS

In the above formula (I) Y includes halogenating group, such as CF3, CHF2CH2F, CF2Cl, CFCl2, CCl3CH2CF3, CF2CF3, CHBr2CH2Br, etc. Among them, preferred is allogeneically group having the number of carbon atoms from 1 to 2, and halogen atoms from 1 to 5, and particularly preferred is triptorelin group.

In the formula (I) examples of the secondary substituent of substituted or unsubstituted alkyl group, designated as R1, R2, R3, R4, R7, R8, R9, R10, R11, R12or R13; substituted or unsubstituted alkenylphenol groups designated as R1, R2, R3, R4, R8, R9, R10, R11, R12or R13; substituted or unsubstituted alkenylphenol groups designated as R1, R2, R3, R4, R8, R9, R12or R13; and substituted or unsubstituted cycloalkyl groups designated as R1, R2, R3or R4included in the group expressed Q:

(hereinafter called the "Q1group"), include halogen atom; alcox the group; allylthiourea; trialkylsilyl group; phenyl group; a phenyl group substituted with halogen, alkyl, alkoxy, nitro or halogenoalkanes group; a phenyl group substituted by phenoxypropane, which may be substituted by alkoxy or alkylthiol; fenoxaprop; phenylthiourea; an amino group; an amino group substituted by one or two alkyl groups; C2-6the cyclic amino group; morpholinopropan; morpholinopropan, substituted alkyl group; 1-piperazinilnom group; 1-piperazinilnom group, substituted alkyl, phenyl, pyridium or cryptomaterial group; heterocyclic group which may be substituted with halogen, alkyl, alkoxyl, halogenation, alkylthio, phenyl (which may be in turn substituted with halogen, alkyl, alkoxy, nitro, halogenation or fenoxaprop), phenoxy, phenylthio, cycloalkyl or cycloalexie; a hydroxy-group, cyano, cycloalkyl group, aminogroup; -With(W2R14group (W2represents a hydrogen atom or a sulphur atom, R14represents a hydrogen atom; an amino group; an amino group substituted by one or two alkyl groups; alkyl group; alkoxygroup; allylthiourea or aryl group); -OS(W2R15group (R15represents an aryl group, a substituted alkyl or g is legendkilla group); or alkylsulfonyl group. If the above Deputy is aminogroup, it can also form amidinopropane or imidate group with the amino group or alkoxygroup.

Other examples of a substituent of substituted or unsubstituted alkyl group, designated as R1or R2included in Q1group in formula (I)include 4-halogenated-3-pyridinecarboxamide, N-methyl-4-halogenated-3-pyridine-carboxamide, 4-halogenated-3-pyridinecarboxamide-N-accelerograph etc. the Chemical structure of formula (I), including the specified substituents, is presented below:

(where R2have the above values, And represents -(CH2)l- group or a -(CH2)q-O-(CH2)qgroup, l is an integer from 1 to 4, and q is 1 or 2).

Thus, the above compound is a dimer compound of formula (I)connected alkalinous chain. In the same way effective component of a composition in accordance with the present invention includes a trimer.

Examples of the secondary substituent of substituted or unsubstituted aryl group, designated as R1, R2, R3, R4, R8, R9, R12or R13included in Q1a group of the formula (I)include the

p> halogen atom; alkyl group; halogenation group; alkoxygroup; halogenlampe; alkylthiols; cycloalkyl group; cycloalkanes; alkoxycarbonyl group; alkylcarboxylic group; alkylcarboxylic; aryl group; alloctype; killigrew; amino group; amino group, substituted by 1 or 2 alkyl groups; a cyano; a nitro-group; a hydroxy-group, etc.

Examples of the secondary substituent of substituted or unsubstituted heterocyclic group, designated as R4, R8, R9, R10, R11, R12or R13included in Q1a group of the formula (I)include halogen atom; alkyl group; alkoxygroup; halogenlampe; alkylthiols; phenyl group which may be substituted with halogen, alkyl, alkoxy, nitro, halogenation or fenoxaprop; fenoxaprop; phenylthiourea; cycloalkyl group; cycloalkanes etc.

Examples of alkyl residue or an alkyl group, a member of Q1a group of the formula (I)include a group having the number of carbon atoms from 1 to 6 such as methyl group, ethyl group, through the group, bucilina group, pencilina group, exilda group, etc. and a group having the number of carbon atoms is at least 3, may include an isomer with a linear or branched structure Taipei alkenylphenol group, a member of Q1a group of the formula (I)include a group having the number of carbon atoms from 2 to 6, such as Attila group, propylaniline group, bucinellina group, penttila group, hexeline group, etc. and a group having the number of carbon atoms is at least 3, may include an isomer with a linear or branched chain structure. Examples alkenylphenol group, a member of Q1a group of the formula (I)include a group having the number of carbon atoms from 2 to 6, such as etinilnoy group, proponila group, Butyrina group, puntinella group, hexylamine group and a group having the number of carbon atoms is at least 4, may include an isomer with a linear or branched chain structure. Examples cycloalkyl group, a member of Q1a group of the formula (I)include a group having the number of carbon atoms from 3 to 8, such as cyclopropyl group, cyclobutyl group, cyclopentenone group or tsiklogeksilnogo group.

Examples4-C55-membered or 6-membered heterocyclic group, which may include a nitrogen atom or an oxygen atom, formed by R1and R2together with the neighboring nitrogen atom within Q1formula (I)include morpholinopropan, pyrrolidinone, piperidine, 1-imidazolidinyl group, 2-cyanoimino-3-methyl-1-imidazolidinyl group, 1-p is personilnya group or 4-methyl-1-piperazinilnom group.

Examples of the aryl group that is a member of Q1a group of the formula (I)include phenyl group, thienyl group, fornillo group, pyridyloxy group, naftalina group, benzothiazoline group, benzofuranyl group, hyalinella group, etc.

Examples of the heterocyclic residue of a substituted or unsubstituted heterocyclic group, a member of Q1a group of the formula (I)include a 5-7-membered monocyclic or phenylcarbonylamino cyclic group containing 1-3 heteroatoms selected from nitrogen atom, oxygen atom and sulfur atom, such as Peregrina group, thienyl group, furilla group, piratininga group, pyrimidinyl group, tetrahydrofuranyl group, thiazolidine group, isooxazolyl group, kinolinna group, pyrazolidine group, oxazoline group, oxadiazolyl group, thiadiazolyl group, thiazolidine group, etc.

Examples of the heterocyclic residue of a substituted or unsubstituted heterocyclic group, denoted as Q1in the formula (I)preferably include a 5-7-membered monocyclic group containing 2-3 heteroatoms selected from nitrogen atom, oxygen atom and sulfur atom, such as 5-membered monocyclic group comprising pyrazolidine group, oxazolidinyl group, thiazolidine group, oxadiazolyl group, t is diazolidinyl group, triazolyl group and the like; 6-membered monocyclic group, such as:

Examples of the secondary substituent of substituted or unsubstituted heterocyclic group, designated as Q in formula (I)include a halogen atom, a nitro-group, a substituted or unsubstituted alkyl group, substituted or unsubstituted alkenylphenol group, substituted or unsubstituted alkylamino group, substituted or unsubstituted aryl group, a substituted or unsubstituted heterocyclic group, substituted or unsubstituted cycloalkyl group, hydroxyl group, substituted or unsubstituted alkoxygroup, substituted or unsubstituted alkenylacyl, substituted or unsubstituted alkyloxy, substituted or unsubstituted, aryloxy group, substituted or unsubstituted geterotsiklicheskikh, substituted or unsubstituted cycloalkanes, mercapto group, substituted or an unsubstituted allylthiourea, substituted or unsubstituted killigrew, substituted or unsubstituted altertekhnogrupp, substituted or unsubstituted alinytjara, substituted or unsubstituted killigrew, substituted or unsubstituted heterocyclic tigroup, substituted or unsubstituted cycloalkenyl, substituted or unsubstituted carbonyl group, a substituted or what zameshannuu alkoxycarbonyl group, substituted or unsubstituted arylcarbamoyl group, substituted or unsubstituted carbonyloxy, formyl group, substituted or unsubstituted ester group, a substituted or unsubstituted acyl group, substituted or unsubstituted sulfonyloxy group, substituted or unsubstituted Solferino group, substituted or unsubstituted sulfonyloxy, substituted or unsubstituted alkylsulfonyl group, substituted or unsubstituted sulfonyloxy group, a substituted or an unsubstituted amino group, substituted or unsubstituted isocyanate group, a substituted or unsubstituted arylalkyl group, a substituted or unsubstituted heterocyclic alkyl group, etc.

Among these secondary substituents some substituents may also be substituted tertiary Deputy, such as halogen atom; cyano; alkyl group which may be substituted with halogen, halogenation, cyan, alkoxyl or aryl; alkoxygroup, which may be substituted with halogen or aryl; hydroxyl group; amino group which may be substituted by alkylsulfonyl, arylalkyl, heterocyclic alkyl, alkyl, aryl, alkylaryl, alkylperoxyl, cyanoacrylat, quinil, alkenyl, or cycloalkyl; carbonyl group which may be substituted by alkoxyl, Alki is amino or alkyl; allylthiourea; alloctype; aristocrata; aryl group which may be substituted with halogen, halogenation, alkyl or aryl; the nitro-group; arylcarboxylic, which may be substituted with halogen or nitro; cycloalkyl group; alkylsulfonates; alkylcarboxylic; isocyanate group which may be substituted by alkyl, halogenation, alkenyl, quinil, heterocyclic alkyl, aryloxy, aryloxyalkyl, alkoxyl, alkoxycarbonyl, hydroxyalkyl, cyanoacrylat, alkoxyalkyl, alkenyl, arylalkyl or alkoxycarbonyl; arylalkylamine group which may be substituted by arylalkyl, halogen, alkyl or alkoxyl; cycloalkylcarbonyl group; cycloalkylcarbonyl group, which may be substituted by halogenation; alkylalkoxysilane group; arylisocyanate group which may be substituted by alkyl, alkoxyl, alkylthio, a halogen, a hydroxyl group, halogenation, nitro, halogen-substituted, aryloxy or aryloxy; heterocyclic group which may be substituted by alkyl, alkoxyl, aryl or a complex ester; alkoxysilanes etc.

Examples of alkyl radicals or alkyl groups in the secondary Deputy or tertiary Deputy substituted or unsubstituted Goethe is acyclically group, designated as Q in formula (I)include a group having the number of carbon atoms from 1 to 6 such as methyl group, ethyl group, through the group, bucilina group, pencilina group or exilda group, the group containing at least 3 carbon atoms, may represent an isomer having a structure with a linear or branched chain. Examples alkenylphenol group include a group having the number of carbon atoms from 2 to 6, such as atenolol group, propenyloxy group, butenyloxy group, pantanillo group or hexenyl group, the group containing at least 3 carbon atoms, may represent an isomer having a structure with a linear or branched chain. Examples alkenylphenol group include a group having the number of carbon atoms from 2 to 6, such as etinilnoy group, propenyloxy group, butenyloxy group, pantanillo group or hexylamino group, the group containing at least 3 carbon atoms, may represent an isomer having a structure with a linear or branched chain. Examples cycloalkyl group include a group having a carbon number from 3 to 8, such as cyclopropyl group, cyclobutyl group, cyclopentyl group or tsiklogeksilnogo group. Examples of aryl groups include phenyl group, tienluugu, fornillo group, pyridyloxy group, naftalina group, benzothiazoline group, benzofuranyl group or hyalinella group. Examples of heterocyclic groups include 5-membered or 6-membered monocyclic or phenyl-condensed cyclic group, containing 1 to 3 heteroatoms selected from nitrogen atom, oxygen atom and sulfur atom, such as Peregrina group, thienyl group, furilla group, piratininga group, thiazolidine group, isooxazolyl group and kinolinna group.

The compound of formula (I) may form a salt with an acid or a basic compound, with examples of salts with acidic compound include salts of inorganic acids such as hydrochloride, hydrobromide, phosphate, sulfate or nitrate, and examples of the salt with a basic compound include inorganic salt or organic base, such as sodium salt, potassium salt, calcium salt, ammonium salt or dimetilaminovogo salt.

The compound of formula (I) or its salt can be obtained in accordance with the method described in Japanese patent No. 2994182, JP-A-10-195072, JP-A-11-180957, WO 98/57969, WO 00/35285, WO 00/35912, WO 00/35913, WO 01/9104, WO 01/14373 etc.

Examples of pyridine compounds or salts thereof, preferred as an effective component of the pesticide composition in accordance with the present invention, CR is illustrated below, however, the present invention is not limited to them.

(1) a Pyridine compound represented by the following formula (I)or its salt:

where Y, m and Q have the above values.

(2) the Compound of the above formula (I) or its salt,

where Q is

where X represents an oxygen atom or a sulfur atom, R1and R2, respectively, independently represent a hydrogen atom, substituted or unsubstituted alkyl group, substituted or unsubstituted alkenylphenol group, substituted or unsubstituted alkylamino group, substituted or unsubstituted cycloalkyl group, -C(W1R3group, -S(O)nR5group-other6group

or-C(R8)=NO-R9group, or R1and R2can form a =C(R10R11the group, or may form a C4-C55-membered or 6-membered heterocyclic group which may contain a nitrogen atom or an oxygen atom, together with the adjacent nitrogen atom, and R3, R5, R6, Z, R7, R8, R9, R10, R11, W1and n have the above values.

(3) the Compound of the above formula (I) or its salt,

where Q is

(where X represented yet an oxygen atom or a sulfur atom, R1and R2, respectively, independently represent a hydrogen atom, substituted or unsubstituted alkyl group, substituted or unsubstituted alkenylphenol group, substituted or unsubstituted alkylamino group, substituted or unsubstituted cycloalkyl group, -C(W1R3group, -S(O)nR5group-other6group, or R1and R2can form a =C(R10R11the group, or may form a C4-C55-membered or 6-membered heterocyclic group which may contain a nitrogen atom or an oxygen atom, together with the adjacent nitrogen atom, and R3, R5, R6, W1and n have the above significance, and R10and R11, respectively, independently represent alkoxygroup or allylthiourea.

(4) the Compound of the above formula (I) or its salt,

where Q is

where X represents an oxygen atom or a sulfur atom, R1represents a hydrogen atom, substituted or unsubstituted alkyl group, substituted or unsubstituted alkenylphenol group, substituted or unsubstituted alkylamino group, substituted or unsubstituted cycloalkyl group, substituted or unsubstituted aryl group, or-C(W1R3group, and R3, R4and W1have the above values.

<> (5) the Compound or its salt of the above p.(2) or (3)where X represents the oxygen atom.

(6) the Compound according to the above p.(3) or its salt,

where R1and R2, respectively, independently represent a hydrogen atom, substituted or unsubstituted alkyl group, or

-With(W1R3group, or R1and R2can form a =C(R10R11group, W1represents an oxygen atom or a sulfur atom, R3represents a substituted or unsubstituted alkyl group, substituted or unsubstituted aryl group, or alkoxygroup, and R10and R11, respectively, independently represent alkoxygroup or allylthiourea.

(7) the Compound or its salt of the above p.(2), where R1represents a hydrogen atom, R2represents-C(R8)=NO-R9group, and R8and R9have the above values.

(8) the Compound or its salt of the above p.(2), in which R1and R2form =C(R10)-N(R12R13group, R10represents a hydrogen atom, substituted or unsubstituted alkyl group, substituted or unsubstituted alkenylphenol group or a substituted or unsubstituted heterocyclic group, and R12and R13have the above values.

(9) the Compound or its salt of the above p.(2), in the cat the rum R 1represents a hydrogen atom, and R2is

(where Z and R7have the above values).

(10) the Compound or its salt of the above p.(3),

where X represents an oxygen atom, R1and R2, respectively, independently represent a hydrogen atom, alkyl group, alkoxyalkyl group, acylaminoalkyl group2-6cyclic aminoalkyl group, hydroxyalkyl group, cyanoaniline group, thiocarbamoylation group, alkylcarboxylic group, alkylcarboxylic group, arylcarbamoyl group, triftormetilfosfinov arylcarbamoyl group, alkoxyaryl group or alkoxycarbonyl group, or R1and R2can form a =C(R10R11group, and R10and R11, respectively, represent alkoxygroup or allylthiourea.

(11) the Compound or its salt of the above p.(1), in which the compound of formula (I) represents at least one compound selected from the group including

N-cyanomethyl-4-trifluoromethyl-3-pyridinecarboxamide (compound No. 1), N-ethyl-4-trifluoromethyl-3-pyridinecarboxamide (compound No. 2), 4-trifluoromethyl-3-pyridinecarboxamide 1-oxide (compound No. 3), 4-trifluoromethyl-3-pyridinecarboxamide (compound No. 4),

N-Tikaram ylmethyl-4-trifluoromethyl-3-pyridinecarboxamide,

N-ethoxymethyl-4-trifluoromethyl-3-pyridinecarboxamide,

N-isopropylaminomethyl-4-trifluoromethyl-3-pyridinecarboxamide,

N-cyanomethyl-N,N-bis(4-triftormetilfosfinov)amine,

N-acetyl-N-cyanomethyl-4-trifluoromethyl-3-pyridinecarboxamide,

N-cyanomethyl-N-methyl-4-triptorelin-3-carboxyamide,

O-methyl N-(4-triftormetilfosfinov)THIOCARBAMATE,

N-methyl-4-triptorelin-3-carboxyamide,

N-(N',N'-dimethylaminomethyl)-4-triptorelin-3-carboxyamide,

N-(1-piperidinylmethyl)-4-triptorelin-3-carboxyamide,

N-cyanomethyl N-(4-triftormetilfosfinov)aminomethylphenol,

O,S-dimethyl N-(4-triftormetilfosfinov)aminoformic,

N-hydroxymethyl-4-trifluoromethyl-3-pyridinecarboxamide,

N-acetyl-4-trifluoromethyl-3-pyridinecarboxamide and

methyl N-(4-triftormetilfosfinov)carbamate or their 1-oxides.

(12) the Compound or its salt of the above p.(1), in which the compound of formula (I) represents at least one compound selected from the group comprising N-cyanomethyl-4-trifluoromethyl-3-pyridinecarboxamide, N-ethyl-4-trifluoromethyl-3-pyridinecarboxamide, 4-trifluoromethyl-3-pyridine-carboxamide 1-oxide and 4-trifluoromethyl-3-pyridinecarboxamide.

(13) the Compound or its salt of the above p.(1), in which the compound of formula (I) represents the N-cyanomethyl-4-trifluoromethyl-3-Piri is incarnational and/or 4-trifluoromethyl-3-pyridinecarboxamide.

(14) the Compound or its salt of the above p.(1), in which the compound of formula (I) represents the N-cyanomethyl-4-trifluoromethyl-3-pyridinecarboxamide.

(15) the Compound or its salt of the above p.(1), in which the compound of formula (I) is 4-trifluoromethyl-3-pyridinecarboxamide.

(16) the Compound or its salt of the above p.(1), in which Q represents a substituted or unsubstituted heterocyclic group.

(17) the Compound or its salt of the above p.(16), in which the residue of the heterocyclic group represents a 5-7-membered monocyclic group containing from 2 to 3 heteroatoms selected from the group comprising a nitrogen atom, an oxygen atom and a sulfur atom.

(18) the Compound or its salt of the above p.(16), in which the residue of the heterocyclic group is a 5-membered monocyclic group containing from 2 to 3 heteroatoms selected from the group comprising a nitrogen atom, an oxygen atom and a sulfur atom.

(19) the Compound or its salt of the above p.(18), in which 5-membered monocyclic group is pyrazolidine group, oxazolidinyl group, thiazolidine group, oxadiazolyl group, thiadiazolyl group or triazolyl group.

(20) the Compound or its salt of the above p.(16), in which the heterocyclic residue which group represents a 6-membered monocyclic group, containing from 2 to 3 heteroatoms selected from the group comprising a nitrogen atom, an oxygen atom and a sulfur atom.

(21) the Compound or its salt of the above p.(20), in which 6-membered monocyclic group represents:

(where R16represents alkyl group).

(22) the Compound or its salt of the above p.(21), in which R16represents a methyl group or an isopropyl group.

In accordance with this invention the compound of formula (I) or its salt is used in combination with other pesticides, examples of which include insecticides, fungicides, bactericide agricultural chemicals, such as V.T. and insect viruses, however, preferably the use of insecticides and/or fungicides, and even more preferably the use of insecticides. Preferred examples of the insecticides applied as an effective component of the pesticide composition in accordance with the present invention, is illustrated below.

(A) Organophosphorus compounds

(A-1) Profenofos

(A-2) Dichlorvos

(A-3) Fenamiphos

(A-4) Fenitrothion

(A-5) EPN

(A-6) Diazinon

(A-7) chlorpyrifos

(A-8) Acetat

(A-9) Prothiofos

(A-10) Fosthiazate

(A-11) Cadusafos

(A-12) Disulfoton

(A-13) Isoxathion

(A-14) Isofenphos

(A-16) Etrimfos

(A-17) Finalpos

(A-18) Dimethylene

(A-19) Dimethoate

(A-20) Sulprofos

(A-21) Thiometon

(A-22) Amidation

(A-23) Pyraclofos

(A-24) Predatation

(A-25) Pirimphos-methyl

(A-26) Propafol

(A-27) Fosalan

(A-28) Formation

(A-29) Malathion

(A-30) Tetrachlorvinphos

(A-31) Chlorfenvinphos

(A-32) Cyanophos

(A-33) Trichlorfon

(A-34) Mitigation

(A-35) Pintout

(A-36) Dimethylaminoisopropyl thiophosphate

(common name: ESP)

(A-37) Azinphos-methyl

(A-38) Fenthion

(A-39) Heptenophos

(A-40) Methamidophos

(A-41) Parathion

(C) Compounds carbamate

(B-1) Carbaryl

(B-2) Propoxur

(B-3) Aldicarb

(B-4) Carbofuran

(B-5) Thiodicarb

(B-6) Methomyl

(B-7) Oxamyl

(B-8) Ethiofencarb

(B-9) Pirimicarb

(10) Fenobucarb

(B-11) Carbosulfan

(B-12) Benfuracarb

(B-13) Bendiocarb

(B-14) Furathiocarb

(B-15) Isoprocarb

(B-16) Metolcarb

(B-17) Xiller

(B-18) 3.5-Killmail carbamate (common name:

CMS)

(C) a PYRETHROID compound

(C-1) Fenvalerate

(2) Permethrin

(C-3) Cypermethrin

(C-4) Deltamethrin

(C-5) Cigalotrin

(C-6) Tefluthrin

(C-7) Etofenprox

(C-8) Cyfluthrin

(C-9) Fenpropathrin

(C-10) Flucythrinate

(C-11) Fluvalinate

(C-12) Cicloprofen

(C-13) Lambda cigalotrin

(the -14) Pyrethrins

(C-15) Esfenvalerate

(C-16) Tetramethrin

(C-17) Resmethrin

(C-18) Protrient

(C-19) Bifenthrin

(C-20) S-Cyano(3-phenoxyphenyl)methyl(±)CIS/TRANS 3-(2,2-

dichloroethenyl)-2,2-dimethylcyclopropane carboxylate

(D) Neonicotinoids connection

(D-1) Imidacloprid

(D-2) Nitenpyram

(D-3) Acetamiprid

(D-4) Thiacloprid

(D-5) Thiamethoxam

(D-6) Clothianidin

(D-7) Dinotefuran

(D-8) 1-(6-Chloro-3-pyridylmethyl)-2-(1-nitro-2-

allylthiourea)imidazolidin (ERA)

(E) Compounds of benzoylacetone

(E-1) Diflubenzuron

(E-2) Chlorfluazuron

(E-3) Teflubenzuron

(E-4) Flufenoxuron

(E-5) Triflumuron

(E-6) Hexaflumuron

(E-7) Lufenuron

(E-8) Novaluron

These compounds act as IGR agent (the agent regulating the growth of insects).

(F) Derivatives delicatessen

(F-1) Cartap

(F-2) Thiocyclam

(G) Compounds of hydrazine

(G-1) Tebufenozide

(G-2) Chromafenozide

(G-3) Methoxyfenozide

(G-4) N'-tert-butyl-N' - for 3,5-dimethylbenzoyl-N-4,5,6,7-

tetrahydrobenzo[b]thiophene-2-carbohydrazide (ERA)

(G-5) N'-tert-butyl-N' - for 3,5-dimethylbenzoyl-N-5,6-dihydro-

4H-cyclopent[b]thiophene-2-carbohydrazide (ERA)

(G-6) Halogenized

These compounds act as IGR agent (the agent regulating the growth of insects).

(H) Compounds, such juvenile hormone

(N-1) Methoprene

(N-2)Pyriproxifen

(H-3) Fenoxycarb

The specified connection type benzoylacetone act as IGR agent (the agent regulating the growth of insects).

(I) Antibiotics

(I-1) Spinosad

(I-2) Emamectin-benzoate

(I-3) Avermectin

(I-4) Milbemycin

(J) Compounds of the pyrrole

(J-1) Chlorfenapyr

(K) Compounds thiadiazine

(K-1) Buprofezin

These compounds act as IGR agent (the agent regulating the growth of insects).

(L) Compounds of silane

(L-1) Selflove

(M) Organochlorine compounds

(M-1) Dicofol

(M-2) Tetradifon

(M-3) Endosulfan

(N) Compounds of pyrazole

(N-1) Fenpyroximate

(N-2) Fipronil

(N-3) Tebufenpyrad

(N-4) Ethiprole

(N-5) Elfenberg

(N-6) Acetool

(O) ORGANOTIN compounds

(O-1) Fenbuconazole oxide

In addition, other insecticides, applicable as a pesticide include connection type dinitro, organic sulfur compound, connection type urea, compound of triazine type, connection type hydrazone; IGR agent (the agent regulating the growth of insects, such as cyromazine; IGR agent for ticks, such as hexythiazox or etoxazole; pyridaben, amitraz, Chlordimeform, triazamate, pymetrozine, pyrimidifen, indoxacarb, achiezer, 1,3-dichloropropene, flociprin, spirodiclofen, bifenazate etc. or crystalline protein toxin derived from their use is the group etc.

Among the above-mentioned insecticides preferably the application of IGR agent. As IGR agent preferably use at least one compound selected from the group comprising (E) connection type benzoylacetone, (G) connection type hydrazine, (N) connection, such juvenile hormone (K) connection type thiadiazine, hexythiazox, etoxazole and cyromazine.

Among pesticide compositions in accordance with the present invention, including the compound of formula (I) or its salt and IGR agent as effective components, the pesticide composition comprising a compound of formula (I) or its salt and the compound type benzoylacetone as an effective component provides a particularly strong pesticide action. As the connection type benzoylacetone preferably use at least one compound selected from the group comprising compounds listed in the above subgroups (E-1)to(E-8), however, it is preferable to use at least one compound selected from the group comprising diflubenzuron, chlorfluazuron, teflubenzuron and flufenoxuron, and most preferably the use of chlorfluazuron and/or flufenoxuron.

Examples of preferred types of insecticide applicable as an effective component pesticide is oppozitsii in accordance with the present invention, also include the following cases.

(1) the Insecticide represents at least one compound selected from the group comprising (A) organophosphorus compounds (In) carbamate compounds, (C) a PYRETHROID compound, (D) neonicotinoid compounds, (E) compounds of benzoylacetone, (F) derivatives delicatessen, (G) compounds of hydrazine, (H) compounds, such juvenile hormone, (I) antibiotics, (J) compounds of the pyrrole, (K) compounds thiadiazine, (L) compounds of silane, (M) organochlorine compounds, (N) the pyrazole compounds, and (O) ORGANOTIN compounds.

(2) the Insecticide represents at least one compound (1)selected from the group comprising (A) organophosphorus compounds (In) carbamate compounds, (C) a PYRETHROID compound, (D) neonicotinoid compounds, (E) compounds of benzoylacetone, (F) derivatives delicatessen, (G) compounds of hydrazine, (H) compounds, such juvenile hormone, (I) antibiotics, (J) compounds of the pyrrole, (K) compounds thiadiazine, (L) compounds of silane and (M) organochlorine compounds.

(3) Insecticide represents at least one compound (2)selected from the group including dichlorvos, diazinon, chlorpyrifos, Arafat, fosthiazate, isoxathion, mitigation, ESP, methomyl, ethiofencarb, pirimicarb, fenoxycarb, fenvalerate, cypermethrin, deltamethrin, who halotron, etofenprox, fluvalinate, acetamiprid, diflubenzuron, chlorfluazuron, teflubenzuron, flufenoxuron, cartap, tebufenozide, pyriproxifen, spinosad, abamectine, chlorfenapyr, buprofezin and selflove.

Further, preferred examples of the fungicide applicable as an effective component of the pesticide composition in accordance with the present invention, is presented below.

(R) Postreorganization connection

(P-1) Fosetyl-A1

(P-2) Tolkienites

(P-3) Aluminum acylhydrolase

(P-4) Iprobenfos

(R-5) Edifenphos

(R-6) Fosterb

(Q) Antibiotics

(Q-1) Validamycin

(Q-2) Kasugamycin

(R) Organochlorine compounds

(R-1) Phtalic

(R-2) CHLOROTHALONIL

(R-3) Chitosan

(R-4) Declomycin

(S) Compounds benzanilide

(S-1) Flutolanil

(S-2) Mepronil

(S-3) Zoxamide

(T) Condensed heterocyclic compounds,

containing a nitrogen atom or a sulfur atom

(T-1) Tricyclazole

(T-2) Missile. benzol

(U) ORGANOTIN compounds

(U-1) Panilova hydroxide

(U-2) Panilova acetate

Next, examples of effective component fungicide, applicable as another pesticide, include compounds of pyrimidinamine, such as mepanipyrim, Pyrimethanil and cyprodinil;

connection of asola, such as triadimefon, bitertanol, triflumizole, itaconate, propion is angry penconazole, flusilazol, myclobutanil, tsyprokonazolu, tebuconazol, hexaconazole, vorconizole-CIS, prochloraz, metconazole, epoxiconazole, tetraconazole, Expocentr and ipconazole;

connection finokalia, such as chinomethionat;

connection of dithiocarbamate, such as MANEB, zineb, MANCOZEB, polycarbamate and propineb;

- imidazole compounds, such as benomyl, thiophanate, carbendazim and cyazofamid;

connection pyridinoline such fluazinam;

connection cyanoacetamide, such as having cymoxanil;

connection phenylamide, such as metalaxyl, oxadixyl, operas, benalaxyl, parallaxes and zeroforum; - connect sultanovoy acid, such as dichlofluanid;

- copper compounds such as copper hydroxide(2) and Okinawa copper;

connection isoxazol such as hydroxyethoxy;

connection N-halogenoalkane, such as Captan, captafol and folpet;

connection dicarboximide, such as procymidone, iprodion and vinclozolin;

connection piperazine, such as triforine;

connection of pyridine, such as pirivenas;

connection carbinol, such as fenarimol and flutriafol;

- piperidine compounds, such as fenpropidin;

connection of the research, such as fenpropimorph;

connection of urea, such as pencycuron;

connection cinnamic acid, such as is dimethomorph;

connection phenylcarbamate, such as dietphenterm;

connection cyanoferrate, such as fludyoksonil and fenpiclonil;

compounds strobilurin, such as AZOXYSTROBIN, kresoxim-methyl, etaminophen, Trifloxystrobin and picoxystrobin; connection oxazolidinone, such as famoxadone, connection thiazolecarboxamide, such as ethaboxam;

connection silylamine, such as silthiofam; connection amicarbalide amino acids, such as iprovalicarb; connection imidazolidine, such as fenamidone; connection hydroxyanisole, such as fenhexamid; connection benzosulfimide, such as glucolipid; anthraquinone compounds; compounds crotonic acid; isoprothiolane, pyroxylin, jenoxifen, propamocarb hydrochloride, spiroxamine, chlorpicrin, dazomet, metamatrix etc.

Examples of preferred types of fungicide applicable as an effective component of the pesticide composition in accordance with the present invention include the following cases.

(1) the Fungicide represents at least one compound selected from the group comprising (B) organophosphorus compounds (Q) antibiotics, (R) organochlorine compounds, (S) compounds benzanilide, (T) condensed heterocyclic compounds containing a nitrogen atom or a sulfur atom, and (U) olovoorganichyesikh the e connection.

(2) Fungicide represents at least one compound (1)selected from the group comprising validamycin, kasugamycin, phtalic, dilamtin, flutolanil, tricyclazole and about. benzol.

In pesticide compositions in accordance with the present invention, the mixing proportion of at least one of the compounds of formula (I) or their salts and at least one active ingredient other pesticides ranges from 1:100 to 100:1, preferably from 1:50 to 50:1.

The pesticide composition in accordance with the present invention can be prepared together with agricultural adjuvants in various forms such as emulsifiable concentrates, powders, granules, wettable powders, dispersible in water, granules, suspension concentrates, soluble concentrates, aerosols or paste, etc. in the same way as known agricultural chemicals. Such compositions typically comprise from 0.001 to 99 weight parts, preferably from 0.01 to 80 parts by weight of active ingredient and from 1 to 99,999 weight parts, preferably from 5 to 99.99 weight parts, more preferably from 20 to 99.99 parts by weight of agricultural adjuvants. When applying such compositions, they can be used as such or after dilution with suitable diluents, such as water, to serene the prescribed concentration.

As agricultural adjuvants can be mentioned carriers, emulsifiers, suspendresume agents, dispersing agents, fillers, penetrants (substances that contribute to permeability), humectants, thickeners, defoamers, stabilizing agents or antifreeze. They can be added if necessary. Media can be divided into solid carriers and liquid carriers. As solid carriers may be mentioned powders of animal and vegetable origin, such as starch, activated carbon, soybean flour, wheat flour, wood flour, flour from fish or milk powder; or mineral powders, such as talc, kaolin, bentonite, calcium carbonate, zeolite, diatomaceous earth, white carbon black, clay or alumina, sulfur powder, anhydrous sodium sulfate, etc. as liquid carriers may be mentioned water, alcohols such as methyl alcohol or ethylene glycol; ketones, such as acetone, methyl ethyl ketone or N-methyl-2-pyrrolidone; ethers, such as dioxane or tetrahydrofuran; aliphatic hydrocarbons such as kerosene, gas oil and the like; aromatic hydrocarbons such as xylene, trimethylbenzene, tetramethylbenzene, cyclohexane or solvent-naphtha; halogenated hydrocarbons such as chloroform or chlorobenzene; acid amides such as dimethylformamide; challenging the esters, such as ethyl acetate or an ester of glycerin fatty acid; NITRILES such as acetonitrile; sulfur-containing compounds such as dimethyl sulfoxide; vegetable oils such as soybean oil or corn oil, etc.

The pesticide composition in accordance with the present invention can be obtained by mixing the respective effective components, and then preparation of a ready mix or can be obtained in the preparation of appropriate and effective components, and then mixing the obtained compositions.

The pesticide composition in accordance with the present invention provides pesticidal activity against a variety of pests, including anthropogy, such as harmful agricultural insects, mites, etc.; nematodes; and soil insects; or against various diseases.

Thus, the pesticide composition in accordance with the present invention is applicable as pesticides, for example insecticides, miticides, nematicides, soil pesticides and fungicides. For example, it is effective against plant parasitic mites such as dvuperistye spider mite (Tetranychus urticae), Carmine spider mite (Tetranychus cinnabarinus), citrus red mite (Panonychus citri) or bulb mite (Rhizoglyphus echinopus); aphids such as the green peach aphid(Myzus persicae) or cotton aphid (Aphis gossypii); agricultural insect pests, such as cabbage moth (Plutella xylostella), cabbage worm (armyworm) (Mamestra brassicae), the usual winter worm (Spodoptera litura), Colorado potato beetle (Leptinotarsa decemlineata), Codling moth (Laspeyresia pomonella), boxed worm (Heliothis zea), tobacco Packed (Heliothis virescens), a boxed weevil (Anthonomus grandis), Gypsy moth (Lymantria dispar), cucurbit leaf (Aulacophora femoralis), planthoppers, cycatki (leafhoppers, mealy bugs, bugs, whiteflies, thrips, grasshoppers, flies damaging Antonii (anthomyiid flies), scarabs, black winter worm (Argotis ipsilon), fall cankerworm (Argotis segetum) or ants; sanitary insect pests, such as cockroaches or fly room (Musca domestica); insect pests of stored grain, such as angoumois grain moth (Sitotroga cerealella), the weevil azuki beans (Callosobruchus chinensis), mixed khruschak flour (Tribolium confusum) or flour worms; anthropogy, including insect pests of household goods, such as clothes moth (Tinea pellionella), black carpet beetle (Anthrenus scrophularidae) or subterranean termites; it is also effective against parasites of nematodes of plants, such as nematodes, harmful cysts, root nodes, roots, white tops of the shoots of rice (Aphelenchoides besseyi), nematodes that damage the kidneys strawberry (Nothotylenchus acris) or nematodes damaging the wood is pine (Bursaphelenchus lignicolus). In addition, it is also effective against soil hurting is her including Gastropoda, such as slugs or snails, or isopods, such as woodlice collapsing (pillbugs) or lice (sowbugs). Further, it is effective against insects that have acquired resistance to organophosphorus, urethane and/or synthetic PYRETHROID insecticides. Moreover, the composition in accordance with the present invention has a good system properties, so use this song for tillage allows you to control not only of soil insect pests, plant parasitic harmful mites, harmful nematodes, harmful gastropods and harmful isopods in the soil, and pests, damaging the foliage.

The concentration of the applied active ingredient the compounds of formula (I) or its salt pesticide compositions in accordance with the present invention is from 1 to 100,000 ppm, preferably from 1 to 50,000 ppm, more preferably from 10 to 20,000 ppm, and the concentration of the active ingredient of another pesticide is from 1 to 100,000 ppm, preferably from 1 to 50,000 ppm, more preferably from 10 to 20000 h/million Concentration of the active ingredient may be optionally changed depending on the composition, destination, or time of application, and the state insect pest. For example, control over water harmful insects may be is carried out by application of the composition, with the above concentration, the place of their mass occurrence and, thus, the concentration of active ingredient in water is less than the above interval.

The amount of active ingredient applied per unit surface area, is usually from about 1 to 50,000 g, preferably from 10 to 10,000 g per hectare in the form of the active ingredient the compounds of formula (I) or its salt, and from about 1 to 50000, preferably from 10 to 10,000 g per hectare in the form of the active ingredient of another pesticide. However, in special cases, the number of the applied compounds may exceed the above interval. Various formulations containing compounds in accordance with the present invention or their diluted composition can be applied using a known, commonly used methods, such as sputtering (e.g., spraying, injection, dispersion, atomization, spreading a powder or granules or dispersion in water), soil (e.g., mixing or wetting), surface application (for example, the application of the coating layer, rubbing proskomide - coating or impregnation with the purpose of getting poisoned bait. In addition, you can feed the pet food containing the above active ingredient, and to control the mass emergence or growth is of becomig, especially insect pests, in their excrement. Moreover, the active ingredient can also be applied using the so-called method of using ultra-low volume. In accordance with this method, the composition may include 100% of the active ingredient.

EXAMPLES

Further, the present invention is described with reference to examples of formulations of the pesticide composition. However, it should be noted that the present invention is in no way limited to these specific examples, the compositions of the active ingredient and auxiliary agricultural chemicals, mixing ratios, compositions, etc.

EXAMPLE COMPOSITION 1

(A) Compound No. 120 weight. parts
(C) Compound D-310 weight. parts
(C) Kaolin42 weight. part
(D) Sodium ligninsulfonate8 weight. parts
(E) White black20 weight. parts

The above components are uniformly mixed, getting a wettable powder.

EXAMPLE COMPOSITION 2

(A) Compound No. 13 weight. part
(In) Connection L-11.5 weight. part
(C) Talc95.5 weight. parts

The above components are uniformly mixed, getting a wettable powder.

An example of a STRUCTURE of 3

(A) Compound No. 110 weight. parts
(In) Connection-850 weight. parts
(C) N-methyl-2-pyrrolidone10 weight. parts
(D) a Simple ether polyoxyalkylene10 weight. parts
(E) Xylene20 weight. parts

The above components are uniformly mixed and dissolved, getting emulsifiable concentrate.

EXAMPLE of PART 4

(A) Kaolin83 weight. part
(C) Sodium ligninsulfonate2 weight. part
(C) Polyoxyethyleneglycol sulfate5 weight. parts
(D) a Fine powder of silica10 weight. parts

A mixture of the above components, the compound No. 1 and compound D-3 are mixed in a weight ratio of 7:2:1, receiving a wettable powder.

EXAMPLE of PART 5

10 weight. parts
(A) Compound No. 120 weight. parts
(C) Compound E-2
(C) Atsilirovannye polyalkylphenol phosphatidylethanolamine2 weight. part
(D) a Silicone0.2 weight. part
(E) Xanthan gum0.1 weight. part
(F) ethylene Glycol5 weight. parts
(G) Water62,7 weight. parts

The above components are uniformly mixed and pulverized to a powder receiving aqueous suspension.

EXAMPLE of compound 6

(A) Compound No. 125 weight. parts
(B) Compound B-950 weight. parts
(C) Sodium polycarboxylate13.5 weight. parts

(D) Anhydrous sodium sulfate10 weight. parts
(E) Dextrin0,5 weight. parts
(F) Sodium alkylsulfonate1 weight. part

The above components are placed in a high speed mixing granulator and add to it 20% of water, and the resulting mixture granularit getting wettable granules.

EXAMPLE of compound 7

(A) Compound No. 15 weight. parts
(C) Obedinenie a-8 5 weight. parts
(C) Bentonite33 weight. part
(D) Kaolin52 weight. part
(E) Sodium ligninsulfonate5 weight. parts

To the above components, water is added in the quantity required for granulation, and the resulting mixture granularit, receiving granules.

EXAMPLE of compound 8

(A) Compound No. 12 weight. part
(In) Connection-30,5 weight. parts
(C) N-methyl-2-pyrrolidone2,5 weight. parts
(D) Soybean oil95 weight. parts

The above components are uniformly mixed and dissolved, receiving the composition of ultra-low volume.

EXAMPLE of compound 9

(A) Compound No. 110 weight. parts
(C) Compound a-3410 weight. parts
(C) N-methyl-2-pyrrolidone5 weight. parts

(D) a Simple ether polyoxyethyleneglycol10 weight. parts
(E) Xylene65 weight. parts

The above components are uniformly mixes the t, getting emulsifiable concentrate.

An example of a COMPOSITION of 10

(A) Compound No. 110 weight. parts
(C) Compound G-110 weight. parts
(C) Corn oil67 weight. parts
(D) Utverjdenie a polyoxyethylene castor oil12 weight. parts
(E) Organic bentonite1 weight. part

The above components are uniformly mixed and pulverized, receiving a suspension.

EXAMPLE of compound 11

(A) Compound No. 13 weight. part
(In) Connection S-12 weight. part
(C) Talc95 weight. parts

The above components are uniformly mixed, receiving the dust.

An example of a STRUCTURE of 12

(A) Compound No. 13 weight. part
(In) Connection T-11 weight. part
(C) Clay96 weight. parts

The above components are uniformly mixed, receiving the dust.

EXAMPLE of compound 13

(A) Compound No. 13 weight. cha is t
(In) Connection L-10,5 weight. parts
(C) Talc96,5 weight. parts

The above components are uniformly mixed, receiving the dust.

EXAMPLE of compound 14

(A) Compound No. 13 weight. part
(C) Compound R-12 weight. part
(C) Clay95 weight. parts

The above components are uniformly mixed, receiving the dust.

EXAMPLE of compound 15

(A) Compound No. 13 weight. part
(C) the Compound Q-10.3 weight. part
(C) Talc96.7 weight. parts

The above components are uniformly mixed, receiving the dust.

EXAMPLE TEST 1

Insecticidal test (1) Thrips palmi

Agrochemical liquid, diluted to a predetermined concentration, is applied using a hand sprayer to plant eggplant with 10-12 in pot leaves pest Thrips palmi thus, to fully hydrate the plant agrochemical liquid, and the pot is placed in the greenhouse. The number of parasitic insects count before treatment and three days after the treatment, determining the value of the control percentage is in accordance with the following formula; the results are presented in the following table 1.

% Control = 100-((x-Cb)/(Tb x Ca) x 100)

TA: the number of insects on the treated plants after processing

Tb: the number of insects on the treated plants before processing

Sa: the number of insects on untreated plants after processing

Cb: the number of insects on untreated plants before processing

Calculate theoretical value % of control in accordance with the following formula Colby. If value % of control higher than theoretical value (%) (in accordance with the Colby formula), it is assumed that the pesticide composition in accordance with the present invention provides a synergistic pesticidal action. Theoretical values of the percent control was calculated according to the Colby formula, are shown in parentheses in the table below 1.

theoretical value % of control = 100 - (X x Y)/100

X: 100-(% of control when processing only compound No. 1)

Y: 100-(% of control when processing only flufenoxuron)

Table 1
Flufenoksuron (E-4)Connection # 1
0 ppm25 ppm50 ppm
0 ppm04324
12,5 ppm7073,784(77)
25 ppm6785(81)86(75)

Number of repetitions: 2

SAMPLE TEST 2

Insecticidal test (2) Thrips palmi

Agrochemical liquid, diluted to a predetermined concentration, is applied using a hand sprayer to plant eggplant with 10-12 leaves in the pot pest Thrips palmi thus, to fully hydrate the plant agrochemical liquid, and the pot is placed in the greenhouse.

The number of insect pests count before treatment and 7 days after treatment, determining the percentage value of the control in the same manner as in example test 1; the results are presented in the following table 2.

Calculate theoretical value of mortality (%) control in accordance with the following formula Colby. If value % of control higher than theoretical value % of control (in accordance with the Colby formula), it is assumed that the pesticide composition in accordance with the present invention provides a synergistic pesticidal action. Theoretical values of the percent control was calculated according to the Colby formula, are shown in parentheses in the table below 2.

theoretical value % of control = 100 - (X x Y)/100

X: 100-(% of control when processing only with what Association No. 1)

Y: 100-(% of control when processing only chlorfluazuron)

Table 2
Chlorfluazuron (E-2)Connection # 1
0 ppm25 ppm50 ppm
0 ppm04855
12,5 ppm5577(76)74
25 ppm5292(75)85(78)

Number of repetitions: 2

EXAMPLE TEST 3

Insecticidal test thrips

western flower Frankliniella occidentalis

Agrochemical liquid, diluted to a predetermined concentration, is applied using a hand sprayer to plant eggplant with 10-12 leaves in a pot with parasites thrips Frankliniella occidentalis thus, to fully hydrate the plant agrochemical liquid, and the pot is placed in the greenhouse. The number of insect pests count before treatment and 2 days after treatment, determining the percentage value of the control in the same manner as in example test 1; the results are presented in the following table 3.

Calculate theoretical value % of control in accordance with the Colby formula in the same manner as example test 1; the obtained result is you are in parentheses in the table below 3.

Table 3
Concentration

(h/m)
Mortality

(%)
Connection # 1+ flufenoxuron (E-4)50+2593(90)
Connection # 15086
Flufenoksuron (E-4)2531

Number of repetitions: 2

EXAMPLE TEST 4

Insecticidal test Thrips palmi

(test in a vinyl greenhouse)

Agrochemical liquid, diluted to a predetermined concentration, is applied using a rucksack spray on the plant eggplant with 6-8 leaves in the pot pest Thrips palmi in the amount of 100 l / 10, ar. The number of insect pests count before treatment and 12 days after treatment, determining the percentage value of the control in the same manner as in example test 1; the results are presented in table 4.

Theoretical values of the percent control calculated according to the Colby formula in the same manner as example test 2, also shown in brackets in the table below 4.

Table 4
Concentration (ppm)Smartest the (%)
Connection # 1+ chlorfluazuron (E-2)50+2591 (79)
Connection # 15051
Chlorfluazuron (E-2)2558

The number of times: 2, 5 plants/pot

The example tests And

Test insecticidal action on Thrisps palmi

Agrochemical liquid, diluted up to a preset concentration, was applied using a spray gun to plant eggplant with 10-12-leaves infected Thrisps palmi, in the pot so to completely soak the eggplant agrochemical liquid, and the pot was placed in a greenhouse. The number of insect pests were counted before treatment and after 7 or 14 days after treatment and the percentage of control was calculated as described in test Example 1 of the present description. The results are presented below in Tables 1-3. The test was carried out in three repetitions.

It was also calculated theoretical value of the percentage of control in accordance with the Colby formula, as described in test Example 1 of the present description, and the results are presented in brackets in Tables 1-3.

Table 1
Connection # 150 ppm25 h/m is n 0 ppm
Acetamiprid (D-3)
25,0 ppm99,6 (96,5)98,8 (95,0)94,5
12,5 ppm97,5 (95,0)97,2 (92,9)to 92.1
0 ppm36,39,8

7 days after processing

Table 2
Connection # 125 ppm0 ppm
Pyriproxifen (N-2)
50,0 ppm91,5 (85,8)74,0
0 ppmto 45.4

14 days after processing

Table 3

Connection # 150 ppm0 ppm
Fipronil (N-2)
5,0 ppm98,8 (87,9) 86,7
2.5 h/million88,9 (75,3)73,0
0 ppm8,7

7 days after processing

Sample tests

Test insecticidal action on ordinary well

Cabbage leaves were dipped in the chemical solution prepared at a predetermined concentration, for about 10 seconds and then dried in the air. A sheet of moistened filter paper was placed in a plastic Petri dish having a diameter of 9 cm, and dried cabbage leaves were placed on filter paper. Larvae scoops ordinary (Spodoptera litura) in the second stage of growth were released on the leaves and the Petri dish was closed and kept in a thermostatic chamber for removing at 26°C. On the 6th day after release were counting the number of dead larvae. The test was carried out in two iterations and death was determined as an average value. The results are presented below in Tables 4-10.

It was also calculated theoretical value of the percentage loss in accordance with the Colby formula, and the results are presented in brackets in Tables 4-10.

85 (60)
Table 4
Connection50 h/ml, the 25 ppm0 ppm
No. 1
The carbofuran (4)
50 ppm80 (75)90 (75)75
25,0 ppm70 (50)80 (50)50
12,5 ppm75 (50)80 (50)50
0 ppm000
Table 5
Connection # 150 ppm25 ppm0 ppm
Carbosulfan (11)
50 ppm6585 (70)70
25 ppm90 (60)85 (60)60
0 ppm000
Table 6
Connection # 150 ppm25 ppm
Cypermethrin (C-3)
at 6.25 ppm90 (70)75 (70)70
3,13 ppm85 (55)75 (55)55
and 1.56 ppm75 (45)60 (45)45
0 ppm000
Table 7
Connection # 150 ppm25 ppm0 ppm
Bifenthrin (C-19)
2.5 h/million100 (90)90 (90)90
1,25 ppm100 (45)90 (45)45
0 ppm000
Table 8
Connection # 150 ppm25 ppm0 ppm
Spinosad (I-1)
at 6.25 ppm 100 (75)90 (75)75
3,13 ppm70 (40)90 (40)40
and 1.56 ppm45 (15)40 (15)15
0 ppm000
Table 9
Connection # 150 ppm25 ppm0 ppm
Amaneciendo (I-2)
0,31 ppm100 (90)90 (90)90
of 0.15 ppm55 (35)70 (35)35
0,078 ppm60 (25)30 (25)25
0 ppm000
Table 10
Connection # 150 ppm25 ppm0 ppm
Avermectin (1-3)
12,5 ppm85 (60)60
3,12 ppm2545 (30)30
0 ppm000

Example test

Test insecticidal action on small brown delgaldo

Seedlings of rice dipped in a chemical solution prepared at a predetermined concentration, for about 10 seconds and then dried in the air. Then a sprout from his roots wrapped in moist absorbent cotton wool was placed in a test tube. After the seedlings have lost 10 larvae of the little brown delphacidae (Laodelphax striatellus), the test tube was covered with gauze and kept in a thermostatic chamber for removing at 26°C. On the 6th day after release were counting the number of dead larvae. The test was carried out in two iterations and death was determined as an average value. The results are presented below in Table 11.

It was also calculated theoretical value of the percentage loss in accordance with the Colby formula, and the results are presented in parentheses in Table 11.

Table 11
Connection # 125 ppm0 ppm
Buprofezin (K-1)
12,5 ppm100 (95)100 (95)95
3,12 ppm100100100
0,78 ppm100 (85)100 (85)85
to 0.19 ppm65 (35)55 (35)35
0 ppm000

The pesticide composition in accordance with the present invention provides a stable, strong pesticide action, destroying harmful insects and other organisms.

1. Insecticidal composition comprising insecticide active amount of one pyridine compounds of formula (I) or its salt

where Y represents halogenating group having the number of carbon atoms from 1 to 2 halogen atoms of 1 to 5, m is 0, Q is

in which X represents an oxygen atom, R1and R2, respectively, independently represent a hydrogen atom, alkylen the th group, having the number of carbon atoms from 1 to 6, substituted by cyano, and one insecticide selected from carbofuran, carbosulfan, cypermethrin, bifenthrin, acetamiprid, chlorfluazuron, flufenoxuron, pyriproxifen, spinosad, amaneciendo, embryo death, buprofezin and fipronil at a weight ratio of the compounds of formula (I) and another insecticide is 1:2 to 100:1.

2. Insecticidal composition according to claim 1, in which the other insecticide is a compound selected from the group including cypermethrin, acetamiprid, chlorfluazuron, flufenoxuron, pyriproxifen, spinosad, amamantando and buprofezin.

3. Insecticidal composition according to claim 1, in which the insecticide is an agent that regulates the growth of insects selected from chlorfluazuron, flufenoxuron, buprofezin, pyriproxyfen.

4. Insecticidal composition according to claim 3, in which the agent regulating the growth of insects, is a connection - derived benzoylacetone selected from chlorfluazuron and flufenoxuron.



 

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EFFECT: increased stability of formulations.

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EFFECT: improved herbicide activity of composition.

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