Herbicide treatment based arilsulfonilglitsinov

 

(57) Abstract:

Describes the herbicide agent containing the derivative of allconvertertoiphone General formula (I)

where R1is alkyl with 1-6 carbon atoms, R2- alkoxy with 1-6 carbon atoms, R3- alkoxy substituted by halogen, alkoxycarbonyl, each with 1-6 carbon atoms, or its salt with alkali metals (active start group 1) and one herbicide compound from the group comprising amidosulfuron, bromoxynil, carfentrazone-ethyl, clodinafop-propargyl, 2,4-D, dichlorprop-R, diclofop-methyl, diflufenican, fluroxypyr, flurtamone, glyphosat (-isopropylammonium salt), imazamethabenz methyl ester, imazamox, Isoproturon, metosulam, metribuzin, metsulfuron-methyl, sulfosulfuron, thifensulfuron-methyl, tribenuron-methyl (active start group 2), and the active principle of group 1 and the active group 2 taken in synergistically effective weight ratio of 1: 0.05 to 500. 5 C.p. f-crystals, 215 table.

The present invention relates to a new herbicide, synergistic combinations of active principles, consisting of well-known arilsulfonilglitsinov, on the one hand, and f is ardakani in various crops of useful plants.

Sulfonamidophenylhydrazine as herbicides with a broad range of actions are subject to a number of patent applications (see European application no EP 341489, 422469. 425948, 431291, 507171, 534266, the international application number WO 96/11188, application DE No. 19508118). Known sulfonamidophenylhydrazine are, however, a number of gaps in the action.

It has been unexpectedly found that the number of known active principles from a number arilsulfonilglitsinov in a joint application with the known compounds with herbicide action of different classes of substances are expressed synergistic effects in relation to action against weeds and can be used particularly mainly as combined preparations with a wide range of actions for selective weed control in crops of useful plants, such as wheat.

The object of the invention are selective herbicide means differing effective content combinations of active principles, consisting of

and allconvertertoiphone General formula (I)

where R1is hydrogen, hydroxyl, amino, alkylamino or unsubstituted or zamestnanci, cycloalkenyl, cycloalkenyl, aryl and arylalkyl,

R2is hydrogen, hydroxyl, mercapto, amino, cyano, halogen or unsubstituted or substituted residue from the group comprising alkyl, alkoxy, alkylthio, alkylamino, dialkylamino, alkenyl, quinil, alkenylacyl, alkyloxy, alkanity, alkylthio, alkenylamine, alkynylamino, cycloalkyl, cycloalkane, cycloalkene, cyclooctylamine, cycloalkenyl, aryl, aryloxy, aaltio, arylamino and arylalkyl,

R3- nitro, cyano, halogen or unsubstituted or substituted residue from the group comprising alkyl, alkylaryl, alkoxy, alkoxycarbonyl, alkylthio, alkylsulfonyl, alkylsulfonyl, alkylamino, alkenyl, alkenylacyl, alkanity, alkenylamine, quinil, alkyloxy, alkylthio, cycloalkyl, cycloalkane, cycloalkene, cycloalkenyl, aryl, aryloxy, aaltio, arylsulfonyl, arylsulfonyl, arylamino, and

R4is hydrogen, nitro, cyano, halogen or unsubstituted or substituted residue from the group comprising alkyl, alkylaryl, alkoxy, alkoxycarbonyl, alkylthio, alkylsulfonyl, alkylsulfonyl, alkylamino, alkenyl, alkenylacyl, alkanity, alkenylamine, quinil, alkyloxy, alkylthio, cycloalkyl, LASS="ptx2">and/or salts of the compounds of formula (I) (active start group 1”) and

(b) at least one compound of the second group of herbicides containing the following active start:

2-chloro-N-(ethoxymethyl)-N-(2-ethyl-6-methyl-phenyl)-ndimethylacetamide (acetochlor), 2-chloro-6-nitro-3-phenoxy-aniline (klonipin), 2-chloro-N-(methoxymethyl)-N-(2,6-diethyl-phenyl)-ndimethylacetamide (alachlor), N-(4,6-dimethoxy-pyrimidine-2-yl)-N'-(N-methyl-N-methylsulphonyl-sulfamoyl)-urea (amidosulfuron), 6-chloro-4-ethyl-amino-2-isopropylamino-1,3,5-triazine (atrazine), 4-chloro-2-oxo-3(2H)-benzothiazolinone acid (benazolin), complex ethyl ester of N-benzoyl-N-(3,4-dichloro-phenyl)-DL-alanine (benzoylperoxy, complex ethyl ester), 3-isopropyl-1H-2,1,3-benzothiadiazin-4(3H)he (bentazon), methyl-5-(2,4-dichloro-phenoxy)-2-nitrobenzoate (bifenox), 2-bromo-3,3-dimethyl-N-(1-methyl-1-phenyl-ethyl)-butanamide (bambuti), 3,5-dibromo-4-hydroxy-benzaldehyde-O-(2,4-dinitrophenyl)-oxime (bromophenoxy), 3,5'-dibromo-4-hydroxy-benzonitrile (bromoxynil), N-butoxymethyl-2-chloro-N-(2,6-diethyl-phenyl)-ndimethylacetamide (butachlor), S-ethyl-bis-(2-methyl-propyl)-THIOCARBAMATE (butyl), 2-(4-chloro-2-fluoro-5-(2-chloro-2-etoxycarbonyl-ethyl)-phenyl)-4-deformity-5-methyl-2,4-dihydro-3H-1,2,4-triazole-3-one (carfentrazone-ethyl, F-8426), 2,4-dichloro-1-(3-methoxy-4-nitrobenzol (chlornitrofen), N-(4-methoxy-6-methyl-1,3,5-triazine-2-yl)-N'-(2-chloro-phenylsulphonyl)-urea (chlorsulfuron), N'-(3-chloro-4-methyl-phenyl)-N,N-dimethyl-urea (chlortoluron), N-(4,6-dimethoxy-1,3,5-triazine-2-yl)-N'-(2-(2-methoxy-ethoxy)-phenylsulphonyl)-urea (chinaculture), (R)-(2-PROPYNYL)-2-[4-(5-chloro-3-fluoro-pyridine-2-yl-oxy)-phenoxy-propanoic (clodinafop-propargyl), 3,6-dichloro-pyridine-2-carboxylic acid (clopyralid), N-(4,6-dimethoxy-pyrimidine-2-yl)-N'-(3-chloro-4-methoxycarbonyl-1-methyl-pyrazole-5-yl-sulfonyl)-urea (cloperastine, halosulfuron, NC-319), methyl ester 3-chloro-2-[(5-ethoxy-7-fluoro[1,2,4]triazolo[1,5-C]pyrimidine-2-yl-sulfonyl)-amino]-benzoic acid (caruncula, methyl ester), 2-chloro-4-ethylamino-6-(1-cyano-1-methyl-ethylamino)-1,3,5-triazine(cyanazine), N-(4,6-dimethoxy-pyrimidine-2-yl)-N'-(2-cyclopropanecarbonyl-phenyl-sulfonyl)-urea (cycloaliphatic, AU-322140), 2,4-dichloro-phenoxy-acetic acid (2,4-D), 3,6-dichloro-2-methoxy-benzoic acid (dicamba), (R)-2-(2,4-dichloro-phenoxy)-propanoic acid (dichlorprop-R), methyl-2-[4-(2,4-dichloro-phenoxy)-phenoxy]-propanoate (diclofop-methyl), methyl sulfate 1,2-dimethyl-3,5-diphenyl-1H-pyrazole (difenzoquat), N-(2,4-debtor-phenyl)-2-(3-trifluoromethyl-phenoxy)-pyridine-3-carboxamide (diflufenican), 2-chloro-N-(2,4-dim the Teal-phenoxy)-ethylamino)-1,3,5-triazine (Dimexidum, IDH-1105), N3,N3-diethyl-2,4-dinitro-6-trifluoromethyl-1,3-diamino-benzene (dinitramine), sodium salt of N-(4,6-dimethoxy-pyrimidine-2-yl)-N'-(3-methoxycarbonyl-6-trifluoromethyl-pyridin-2-yl-sulfonyl-urea (DPX-KE-459), 6,7-dihydro-dipyrido[1,2-a:2',1'-]pyrazine (Diquat), S,S-dimethyl-2-deformity-4-isobutyl-6-Cryptor-methyl-pyridine-3,5-dikaryotic (dithiopyr), sodium salt of N-(4,6-dimethoxy-pyrimidine-2-yl)-N'-(3-methoxycarbonyl-6-trifluoromethyl-pyridin-2-yl-sulfonyl)-urea (DPX-KE-459), S-ethyl-dipropylthiocarbamate ERTS), S-(phenylmethyl)N-ethyl-N-(1,2-dimethyl-propyl)-THIOCARBAMATE (asbroker), ethyl-[2-chloro-5-(4-chloro-5-deformedarse-1-methyl-1H-pyrazole-3-yl)-4-fluoro-phenoxy]-acetate (ET-751), (S)-(2-ethoxy-1-methyl-2-oxo-ethyl)-2-chloro-5-(2-chloro-4-trifluoromethyl-phenoxy)-benzoate (amoxifen), N-(4,6-dimethoxy-pyrimidine-2-yl)-N'-(2-ethoxy-phenoxycarbonyl)-urea (ethoxysulfuron, HOE-095404), ethyl-2-[4-(6-chloro-benzoxazol-2-yl-oxy)-phenoxy]-propanoate (fenoxaprop-ethyl), isopropyl-N-benzoyl-N-(3-chloro-4-fluoro-phenyl)-DL-alaninate (planrep-isopropyl), isopropyl-N-benzoyl-N-(3-chloro-4-fluoro-phenyl)-L-alaninate (planrep-isopropyl-L), methyl-N-benzoyl-N-(3-chloro-4-fluoro-phenoxy)-DL-alaninate (planrep-methyl), N-(2,6-debtor-phenyl)-5-methyl-1,2,4-triazolo[1,5-a]-pyrimidine-2-sulfonamide (flumetsulam, DE-498), pentyl-[2-chloro-4-fluoro-5-(1,3,4,)-oxy]-phenyl]-4,5,6,7-tetrahydro-1H-isoindole-1,3(2H)-dione (flubiprofen), complex ethoxycarbonylmethyl ester 5-(2-chloro-4-trifluoromethyl-phenoxy)-2-nitrobenzoic acid (fluoroglycofen, complex ethyl ester), 1-(4-chloro-3-(2,2,3,3,3-pendaftar-propoxymethyl)-phenyl)-5-phenyl-1H-1,2,4-triazole-3-carboxamide (flupoxam), 1-isopropyl-2-chloro-5-(3,6-dihydro-3-methyl-2,6-dioxo-4-trifluoromethyl-1(2H)-pyrimidyl)-benzoate (flourophenyl), 9-hydroxy-N-fluoren-9-carboxylic acid (Florina), (4-amino-3,5-dichloro-6-fluoro-pyridin-2-yl-oxy)-acetic acid (fluroxypyr), 5-methylamino-2-phenyl-4-(3-Cryptor-methyl-phenyl)-3(2H)-furanone (floortime), methyl-[(2-chloro-4-fluoro-5-(tetrahydro-3-oxo-1H,3H-[1,3,4]-thiadiazolo-[3,4-a]-pyridazin-1-ilidene)-amino-phenyl]-thio-acetate (fluthiacet-methyl, CN-9201), ammonium salt of 2-amino-4-(hydroxymethylfurfural)-butane acid (glufosinate, ammonium salt), isopropylammonium salt of N-phosphonomethyl-glycine (glyphosate, isopropyl-ammonium salt), methyl ester of 2-(4,5-dihydro-4-methyl-4-isopropyl-5-oxo-1H-imidazol-2-yl)-4-methyl-benzoic acid (mazamet-Benz, methyl ester), 2-(4,5-dihydro-4-methyl-4-isopropyl-5-oxo-1H-imidazol-2-yl)-5-methyl-pyridine-3-carboxylic acid (imazamethabenz), 2-(4,5-dihydro-4-methyl-4-isopropyl-5-oxo-1H-imidazol-2-yl)-5-methoxymethyl-pyridine-3-carboxylic acid (imazamox), 2-(4,5-dihydro-4--5-oxo-1H-imidazol-2-yl)-5-ethyl-Piri-Dean-3-carboxylic acid (imazethapyr), N-(4,6-dimethoxy-pyrimidine-2-yl)-N'-(2-chloro-imidazo[1,2-a]-pyridine-3-yl-sulfonyl)-urea (imazosulfuron), 4-hydroxy-3,5-Diod-benzonitrile (ioxynil), N,N-dimethyl-N'-(4-isopropyl-phenyl)-urea (Isoproturon), N-(3-(1-ethyl-1-methyl-propyl)-isoxazol-5-yl)-2,6-dimethoxy-benzamide (isoxaben), (5-cyclopropyl-isoxazol-4-yl)-(2-methylsulphonyl-4-trifluoromethyl-phenyl)-methanon (isoxaflutole, RPA-201772), 2-[2-[4-[3,5-dichloro-2-pyridinyl)-oxy]-phenoxy]-1-oxo-propyl]-isoxazolidine (saxapella), N'-(3,4-dichloro-phenyl)-N-methoxy-N-methyl-urea (linuron), (4-chloro-2-methyl-phenoxy)-acetic acid (MSRA), 2-(4-chloro-2-methyl-phenoxy)-propionic acid (mecoprop), 2-chloro-N-2,6-dimetilfenil)-N-(1H-pyrazole-1-yl-methyl)-ndimethylacetamide (metazachlor), N'-(4-(3,4-dihydro-2-methoxy-2,4,4-trimethyl-2H-1-benzopyran-7-yl-oxy)-phenyl)-N-methoxy-N-methyl-urea (metaventure, UMP-488), N'-(4-bromo-phenyl-N-meth-oxy-N-methyl-urea (metobromuron), 2-chloro-N-(2-ethyl-6-methyl-phenyl)-N-(2-methoxy-1-methyl-ethyl)-ndimethylacetamide (metolachlor), N-(2,6-dichloro-3-methyl-phenyl)-5,7-dimethoxy-1,2,4-triazolo[1,5-a]-pyrimidine-2-sulfonamide (metosulam, DE-511), N'-(3-chloro-4-methoxy-phenyl)-N,N-dimethyl-urea (metoxuron), 4-amino-6-tert-butyl-3-methylthio-1,2,4-triazine-5(4H)-he (metribuzin), N-(4-methoxy-6-methyl-1,3,5-triazine-2-yl)-N'-(2-methoxycarbonyl-panels the)-N-methyl-urea (neuron), N-(4,6-dimethoxy-pyrimidine-2-yl)-N'-(3-dimethylcarbamoyl-pyridine-2-yl-sulfonyl)-urea (nicosulfuron), S-(2-chloro-benzyl)-N,N-diethyl-THIOCARBAMATE (arrancars), N-(4,6-dimethyl-pyrimidine-2-yl)-N'-(2-oxetan-3-yl-oxycarbonyl-phenylsulphonyl)-urea (oxasulfuron), 1,1'-dimethyl-4,4'-bipyridine (paraquat), 1-amino-N-(1-ethyl-propyl)-3,4-dimethyl-2,6-dinitrobenzene (pendimethalin), N-(4,6-bis-deformedarse-pyrimidine-2-yl)-N'-(2-meloxicam-bonyl-phenylsulphonyl)-urea (primisulfuron-methyl), S-phenyl N-methyl-N,N-dipropyl-THIOCARBAMATE (prosulfocarb), N-(4-methoxy-6-methyl-1,3,5-triazine-2-yl)-N'-(2-(3,3,3-Cryptor-propyl)-phenylsulphonyl)-urea (prosulfuron), 2-chloro-N-(2,6-diethyl-phenyl)-N-(2-propoxy-ethyl)-ndimethylacetamide (pretilachlor), 2-chloro-N-isopropyl-N-phenyl-ndimethylacetamide (propachlor), O-(6-chloro-3-phenyl-pyridazin-4-yl)-S-octyl-thiocarbonate (peridot), 4-(2,4-dichloro-benzoyl)-1,3-dimethyl-5-(4-methyl-phenylsulfonyl)-pyrazole (pyrazolate), 4-(2,4-dichloro-benzoyl)-1,3-dimethyl-5-(phenylcarbonylamino)-pyrazole (paradoxien), N-(4,6-dimethoxy-pyrimidine-2-yl)-N-(4-etoxycarbonyl-1-methyl-pyrazole-5-yl-sulfonyl)-urea (pyrazosulfuron-ethyl), 7-chloro-3-methyl-quinoline-8-carboxylic acid (quinmerac), N-(4,6-dimethoxy-pyrimidine-2-yl)-N'-(3-ethylsulfonyl-pyridine-2-yl-sulfonyl)-urea (Ramalho is he), 2-(2,4-dichloro-5-methylsulfonylamino-phenyl)-4-deformity-5-methyl-2,4-dihydro-3H-1,2,4-triazole-3-one (sulfentrazone, F-6285), N-phosphonomethyl-glycine-trimethylsulfonium (sulfosate), N-(4,6-dimethoxy-pyrimidine-2-yl)-N'-(2-ethylsulfonyl-imidazo[1,2-a]pyridine-3-sulfonamide (sulfosulfuron, MON 37500), 6-chloro-4-ethylamino-2-tert-butylamino-1,3,5-triazine (TERBUTHYLAZINE), 2-tert-butylamino-4-ethylamino-6-methylthio-1,3,5-triazine (terbutryne), 2-chloro-N-(2,6-dimethyl-phenyl)-N-(3-methoxy-2-thienyl-methyl)-ndimethylacetamide (tanishlar), 6-(6,7-dihydro-6,6-dimethyl-3H,5H-pyrrolo[2,1-C]-1,2,4-thiadiazole-3-ylideneamino)-7-fluoro-4-(2-PROPYNYL)-2H-1,4-benzoxazin-3(4H)-he (thidiazuron), N-(4-methoxy-6-methyl-1,3,5-triazine-2-yl)-N'-(2-methoxycarbonyl-Tien-3-yl-sulfonyl)-urea (thifensulfuron-methyl), 2-(amoxiline-propyl)-3-hydroxy-5-(2,4,6-trimethyl-phenyl)-2-cyclohexen-1-he (tralkoxydim), S-(2,3,3-trichloro-2-propenyl)-diisopropylcarbodiimide (triallate), N-(4-methoxy-6-methyl-1,3,5-triazine-2-yl)-N'-[2-(2-chlorine-ethoxy)-phenylsulfonyl]-urea (triasulfuron), N-methyl-N-(4-methoxy-6-methyl-1,3,5-triazine-2-yl)-N'-(2-methoxycarbonyl-phenyl-sulfonyl)-urea (tribenuron-methyl), 2-(3,5-dichloro-phenyl)-2-(2,2,2-trichloroethyl)-oxiran (tridian), 1-amino-2,6-dinitro-N,N-dipropyl-4-trifluoromethyl-benzene (trifluralin) - (“active start group 2”),

Of particular interest are the proposed selective herbicide means which contains a combination of active principles, consisting of

and allconvertertoiphone General formula (I), where

R1is hydrogen, hydroxyl, amino, alkylamino with 2-6 carbon atoms, unsubstituted or substituted ceanography, halogen or alkoxyl with 1-4 carbon atoms in the remainder of the group, including alkyl, alkenyl, quinil, alkoxy, alkenylacyl, alkylamino, dialkylamino, each with 1-6 carbon atoms, unsubstituted or substituted by cyano, halogen or alkyl with 1-4 carbon atoms in the remainder of the group, including cycloalkyl, cycloalkenyl, cycloalkenyl, each with 3-6 carbon atoms in cycloalkyl groups and optionally 1 to 4 carbon atoms in the alkyl part, or unsubstituted or substituted by cyano, nitrogroup, halogen, alkyl with 1-4 carbon atoms, halogenation with 1-4 carbon atoms, alkoxyl with 1-4 carbon atoms or halogenation with 1-4 carbon atoms in the remainder of the group, including phenyl and phenylalkyl with 1-4 carbon atoms in the alkyl part,

R2is hydrogen, hydroxyl, mercapto, amino, cyano, halogen, resumes what she alkyl, alkoxy, alkylthio, alkylamino, dialkylamino, alkenyl, quinil, alkenylacyl, alkyloxy, alkanity, alkylthio, alkenylamine, alkynylamino, each with 1-6 carbon atoms, unsubstituted or substituted by cyano, halogen or alkyl with 1-4 carbon atoms in the remainder of the group, including cycloalkyl, cycloalkane, cycloalkene, cyclooctylamine and cycloalkenyl, each with 3-6 carbon atoms in cycloalkyl groups and optionally 1 to 4 carbon atoms in the alkyl part, or unsubstituted or substituted by a cyano, a nitro-group, halogen, alkyl with 1-4 carbon atoms, halogenation with 1-4 carbon atoms, arcoxia with 1-4 carbon atoms or halogenation with 1-4 carbon atoms in the remainder of the group comprising phenyl, phenoxy, phenylthio, phenylamino and phenylalkyl with 1-4 carbon atoms in the alkyl part,

R3- nitro, cyano, halogen, unsubstituted or substituted by cyano, halogen or alkoxyl with 1-4 carbon atoms in the remainder of the group, including alkyl, alkylaryl, alkoxy, alkoxycarbonyl, alkylthio, alkylsulfonyl, alkylsulfonyl, alkylamino, alkenyl, alkenylacyl, alkanity, alkenylamine, quinil, alkyloxy, alkylthio, each with 1-6 carbon atoms, sesame cycloalkyl, cycloalkane, cycloalkene, cyclooctylamine, each with 3-6 carbon atoms in cycloalkyl groups, or unsubstituted or substituted by a cyano, a nitro-group, halogen, alkyl with 1-4 carbon atoms, halogenation with 1-4 carbon atoms, alkoxyl with 1-4 carbon atoms or halogenation with 1-4 carbon atoms in the remainder of the group comprising phenyl, phenoxy, phenylthio, phenylsulfinyl, phenylsulfonyl, phenylamino, and

R4is hydrogen, nitro, cyano, halogen, unsubstituted or substituted by cyano, halogen or alkoxyl with 1-4 carbon atoms in the remainder of the group, including alkyl, alkylaryl, alkoxy, alkoxycarbonyl, alkylthio, alkylsulfonyl, alkylsulfonyl, alkylamino, alkenyl, alkenylacyl, alkanity, alkenylamine, quinil, alkyloxy, alkylthio, each with 1-6 carbon atoms, unsubstituted or substituted by cyano, halogen or alkyl with 1-4 carbon atoms in the remainder of the group, including cycloalkyl, cycloalkane, cycloalkene. cyclooctylamino, each with 3-6 carbon atoms in cycloalkyl groups, or unsubstituted or substituted by a cyano, a nitro-group, halogen, alkyl with 1-4 carbon atoms, halogenation with 1-4 carbon atoms, alkoxyl with 1-4 atoti, phenylsulfinyl, phenylsulfonyl or phenylamino,

and/or salts of the compounds of formula (I) (active start group 1”) and

(b) 1 or 2 compounds of the second group of herbicides containing the following active start:

2-chloro-N-(ethoxymethyl)-N-(2-ethyl-6-methyl-phenyl)-ndimethylacetamide (acetochlor), 2-chloro-6-nitro-3-phenoxy-aniline (klonipin), 2-chloro-N-(methoxymethyl)-N-(2,6-diethyl-phenyl)-ndimethylacetamide (alachlor), N-(4,6-dimethoxy-pyrimidine-2-yl)-N'-(N-methyl-N-methylsulphonyl-sulfamoyl)-urea (amidosulfuron), 6-chloro-4-ethyl-amino-2-isopropylamino-1,3,5-triazine (atrazine), complex ethyl ester of N-benzoyl-N-(3,4-dichloro-phenyl)-DL-alanine (benzoylperoxy, complex ethyl ester), 3-isopropyl-1H-2,1,3-benzothiadiazin-4(3H)-he (bentazon), methyl-5-(2,4-dichloro-phenoxy)-2-nitro-benzoate (bifenox), 2-bromo-3,3-dimethyl-N-(1-methyl-1-phenyl-ethyl)-butanamide (bambuti), 3,5-dibromo-4-hydroxy-benzaldehyde-O-(2,4-dinitro-phenyl)-oxime (bromophenoxy), 3,5-dibromo-4-hydroxy-benzonitrile (bromoxynil), N-butoxymethyl-2-chloro-N-(2,6-diethyl-phenyl)-ndimethylacetamide (butachlor), S-ethyl-bis-(2-methyl-propyl)-THIOCARBAMATE (butyl), 2-(4-chloro-2-fluoro-5-(2-chloro-2-etoxycarbonyl-ethyl)-phenyl)-4-deformity-5-methyl-2,4-dihydro-3H-1,2,4-triazole-3-one (carfentrazone-ethyl, F-8426), 2,4-dichloro-1-(3-methoxy-4-nitro-phenoxy-benzene (x-(4-methoxy-6-methyl-1,3,5-triazine-2-yl)-N'-(2-chloro-phenylsulphonyl)-urea (chlorsulfuron), N'-(3-chloro-4-methyl-phenyl)-N,N-dimethyl-urea (chlortoluron), N-(4,6-dimethoxy-1,3,5-triazine-2-yl)-N'-(2-(2-methoxy-ethoxy)-phenylsulphonyl)-urea (chinaculture), (R)-(2-PROPYNYL)-2-(4-(5-chloro-3-fluoro-pyridine-2-yl-oxy)-phenoxy-propanoic (clodinafop-propargyl), 3,6-dichloro-pyridine-2-carboxylic acid (clopyralid), N-(4,6-dimethoxy-pyrimidine-2-yl)-N'-(3-chloro-4-methoxycarbonyl-1-methyl-pyrazole-5-yl-sulfonyl)-urea (cloperastine, halosulfuron, NC-319), methyl ester of 3-chloro-2-[(5-ethoxy-7-fluoro[1,2,4]triazolo[1,5-C]pyrimidine-2-yl-sulfonyl)-amino]-benzoic acid (caruncula, methyl ester), 2-chloro-4-ethylamino-6-(1-cyano-1-methyl-ethylamino)-1,3,5-triazine (cyanazine), N-(4,6-dimethoxy-pyrimidine-2-yl)-N'-(2-cyclopropanecarbonyl-phenylsulphonyl)-urea (cycloaliphatic, AU-322140), 3,6-dichloro-2-methoxy-benzoic acid (dicamba), (R)-2-(2,4-dichloro-phenoxy)-propanoic acid (dichlorprop-R), methyl ester 2-[4-(2,4-dichloro-phenoxy)-phenoxy]-propanoic acid (diclofop, methyl ester), methyl sulfate 1,2-dimethyl-3,5-diphenyl-1H-pyrazole (difenzoquat), N-(2,4-debtor-phenyl)-2-(3-trifluoromethyl-phenoxy)-pyridine-3-carboxamide (diflufenican), 2-chloro-N-(2,4-dimethyl-3-thienyl)-N-(2-methoxy-1-methyl-ethyl)-ndimethylacetamide (dimethenamid, SAN 582), 2,4-dichloro-tenoxicam IDH-1105), 6,7-dihydro-dipyrido[1.2-a:2',1'-with]pyrazine (Diquat), S,S-dimethyl-2-deformity-4-isobutyl-6-trifluoromethyl-pyridine-3,5-dikaryotic (dithiopyr), sodium salt of N-(4,6-dimethoxy-pyrimidine-2-yl)-N'-(3-methoxycarbonyl-6-trifluoromethyl-pyridin-2-yl-sulfonyl)-urea (DPX-KE-459), S-ethyl-dipropylthiocarbamate ERTS), S-(phenylmethyl)-N-ethyl-N-(1,2-dimethyl-propyl)-THIOCARBAMATE (asbroker), ethyl-[2-chloro-5-(4-chloro-5-deformedarse-1-methyl-1H-pyrazole-3-yl)-4-fluoro-phenoxy]-acetate (ET-751), (S)-(2 ethoxy-1-methyl-2-oxo-ethyl)-2-chloro-5-(2-chloro-4-trifluoromethyl-phenoxy)-benzoate (amoxifen), N-(4,6-dimethoxy-pyrimidine-2-yl)-N'-(2-ethoxy-phenoxycarbonyl)-urea (ethoxysulfuron, NOAH-095404), complex ethyl ester 2-[4-(6-chloro-benzoxazol-2-yl-oxy)-phenoxy]-propanoic acid (fenoxaprop, complex ethyl ester), complex isopropyl ester of N-benzoyl-N-(3-chloro-4-fluoro-phenyl)-DL-alanine (planrep, complex isopropyl ether), complex isopropyl ester of N-benzoyl-N-(3-chloro-4-fluoro-phenyl)-L-alanine (planrep-L, complex isopropyl ether), methyl-N-benzoyl-N-(3-chloro-4-fluoro-phenoxy)-DL-alanine (planrep, methyl ester), N-(2,6-debtor-phenyl)-5-methyl-1,2,4-triazolo[1,5-a]-pyrimidine-2-sulfonamide (flumetsulam, DE-498), pentyl-[2-chloro-4-fluoro-5-(1,3,4,5,6,7-hexahydro-1,3-dioxo-2H-isoindole-2-yl)-phenoxy]-ACET imipramin), complex ethoxycarbonylmethyl ester 5-(2-chloro-4-trifluoromethyl-phenoxy)-2-nitrobenzoic acid (fluoroglycofen, complex ethyl ester), 1-(4-chloro-3-(2,2,3,3,3-pendaftar-propoxymethyl)-phenyl)-5-phenyl-1H-1,2,4-triazole-3-carboxamide (flupoxam), 1-isopropyl-2-chloro-5-(3,6-dihydro-3-methyl-2,6-dioxo-4-trifluoromethyl-1 (2H)-pyrimidyl)-benzoate (flourophenyl), 9-hydroxy-N-fluoren-9-carboxylic acid (Florina), (4-amino-3,5-dichloro-6-fluoro-pyridin-2-yl-oxy)-acetic acid (fluroxypyr), 5-methylamino-2-fennel-4-(3-trifluoromethyl-phenyl)-3(2H)-furanone (floortime), methyl-[(2-chloro-4-fluoro-5-(tetrahydro-3-oxo-1H, 3H-[1,3,4]-thiadiazolo-[3,4-a]-pyridazin-1-ilidene)-amino-phenyl]-thio-acetate (fluthiacet-methyl, CN-9201), ammonium salt of 2-amino-4-(hydroxymethylfurfural)-butane acid (glufosinate, ammonium salt), isopropylammonium salt of N-phosphonomethyl-glycine (glyphosate, Isopropylamine salt), methyl ester of 2-(4,5-dihydro-4-methyl-4-isopropyl-5-oxo-1H-imidazol-2-yl)-4-methyl-benzoic acid (imazamethabenz, methyl ester), 2-(4,5-dihydro-4-methyl-4-isopropyl-5-oxo-1H-imidazol-2-yl)-5-methyl-pyridine-3-carboxylic acid (imazamethabenz), 2-(4,5-dihydro-4-methyl-4-isopropyl-5-oxo-1H-imidazol-2-yl)-5-methoxymethyl-pyridine-3-carboxylic acid (imazamox), 2-(4,5-dihydro-4-methyl-4-in-imida-Zol-2-yl)-5-ethyl-pyridine-3-carboxylic acid (imazethapyr), N-(4,6-dimethoxy-pyrimidine-2-yl)-N'-(2-chloro-imidazo[1,2-a]-pyridine-3-yl-sulfonyl)-urea (imazosulfuron), 4-hydroxy-3,5-Diod-benzonitrile (ioxynil), N,N-dimethyl-N'-(4-isopropyl-phenyl)-urea (Isoproturon), N-(3-(1-ethyl-1-methyl-propyl)-isoxazol-5-yl)-2,6-dimethoxy-benzamide (isoxaben), (5-cyclopropyl-isoxazol-4-yl)-(2-methylsulphonyl-4-trifluoromethyl-phenyl)-methanon (isoxaflutole, RPA-201772), 2-[2-[4-[3,5-dichloro-2-pyridinyl)-oxy]-phenoxy]-1-oxo-propyl]-isoxazolidine (saxapella), N'-(3,4-dichloro-phenyl)-N-methoxy-N-methyl-urea (linuron), (4-chloro-2-methyl-phenoxy)-acetic acid (MSRA), 2-(4-chloro-2-methyl-phenoxy)-propionic acid (mecoprop), 2-chloro-N-(2,6-dimetilfenil)-N-(1H-pyrazole-1-yl-methyl)-ndimethylacetamide (metazachlor), N'-(4-(3,4-dihydro-2-methoxy-2,4,4-trimethyl-2H-1-benzopyran-7-yl-oxy)-phenyl)-N-methoxy-N-methyl-urea (metaventure, UMP-488), N'-(4-bromo-phenyl)-N-methoxy-N-methyl-urea (metobromuron), 2-chloro-N-(2-ethyl-6-methyl-phenyl)-N-(2-methoxy-1-methyl-ethyl)-ndimethylacetamide (metolachlor), N-(2,6-dichloro-3-methyl-phenyl)-5,7-dimethoxy-1,2,4-triazolo[1,5-a]-pyrimidine-2-sulfonamide (metosulam, DE-511), N'-(3-chloro-4-methoxy-phenyl)-N,N-dimethyl-urea (metoxuron), 4-amino-6-tert-butyl-3-methylthio-1,2,4-triazine-5(4H)-he (metribuzin), N-(4-methoxy-6-methyl-1,3,5-triazine-2-yl)-N'-(2-methoxycarbonyl-phenyl-Multil-urea (neuron), N-(4,6-dimethoxy-pyrimidine-2-yl)-N'-(3-dimethylcarbamoyl-pyridine-2-yl-sulfonyl)-urea (nicosulfuron), S-(2-chloro-benzyl)-N,N-diethyl-THIOCARBAMATE (arrancars), N-(4,6-dimethyl-pyrimidine-2-yl)-N'-(2-oxetan-3-yl-oxycarbonyl-phenylsulphonyl)-urea (oxasulfuron), 1,1'-dimethyl-4,4'-bipyridine (paraquat), 1-amino-N-(1-ethyl-propyl)-3,4-dimethyl-2,6-dinitrobenzene (pendimethalin), N-(4,6-bis-deformedarse-pyrimidine-2-yl)-N'-(2-methoxycarbonyl-phenylsulphonyl)-urea (primisulfuron-methyl), S-phenyl N-methyl-N,N-dipropyl-THIOCARBAMATE (prosulfocarb), N-(4-methoxy-6-methyl-1,3,5-triazine-2-yl)-N'-(2-(3,3,3-Cryptor-propyl)-phenylsulphonyl)-urea (prosulfuron), 2-chloro-N-(2,6-diethyl-phenyl)-N-(2-propoxy-ethyl)-ndimethylacetamide (pretilachlor), 2-chloro-N-isopropyl-N-phenyl-ndimethylacetamide (propachlor), O-(6-chloro-3-phenyl-pyridazin-4-yl)-S-octyl-thiocarbonate (peridot), 4-(2,4-dichloro-benzoyl)-1,3-dimethyl-5-(4-methyl-phenylsulfonyl)-pyrazole (pyrazolate), 4-(2,4-dichloro-benzoyl)-1,3-dimethyl-5-(phenylcarbonylamino)-pyrazole (paradoxien), N-(4,6-dimethoxy-pyrimidine-2-yl)-N'-(4-etoxycarbonyl-1-methyl-pyrazole-5-yl-sulfonyl)-urea (pyrazosulfuron-ethyl), 7-chloro-3-methyl-quinoline-8-carboxylic acid (quinmerac), N-(4,6-dimethoxy-pyrimidine-2-yl)-N'-(3-ethylsulfonyl-pyridine-2-yl-sulfonyl)-urea (rimsulfuron), 6 - 2-(2,4-dichloro-5-methylsulfonylamino-phenyl)-4-deformity-5-methyl-2,4-dihydro-3H-1,2,4-triazole-3-one (sulfentrazone, F-6285), N-phosphonomethyl-glycine-trimethylsulfonium (sulfosate), N-(4,6-dimethoxy-pyrimidine-2-yl)-N'-(2-ethylsulfonyl-imidazo[1,2-a]pyridine-3-sulfonamide (sulfosulfuron, MON 37500), 6-chloro-4-ethylamino-2-tert-butylamino-1,3,5-triazine (TERBUTHYLAZINE), 2-tert-butylamino-4-ethylamino-6-methylthio-1,3,5-triazine (terbutryne), 2-chloro-N-(2,6-dimethyl-phenyl)-N-(3-methoxy-2-thienyl-methyl)-ndimethylacetamide (tanishlar), 6-(6,7-dihydro-6,6-dimethyl-3H,5H-pyrrolo[2,1-C]-1,2,4-thiadiazole-3-ylideneamino)-7-fluoro-4-(2-PROPYNYL)-2H-1,4-benzoxazin-3(4H)-he (thidiazuron), N-(4-methoxy-6-methyl-1,3,5-triazine-2-yl)-N'-(2-methoxycarbonyl-Tien-3-yl-sulfonyl)-urea (thifensulfuron-methyl), 2-(amoxiline-propyl)-3-hydroxy-5-(2,4,6-trimethyl-phenyl)-2-cyclohexen-1-he (tralkoxydim), S-(2,3,3-trichloro-2-propenyl)-diisopropylcarbodiimide (triallate), N-(4-methoxy-6-methyl-1,3,5-triazine-2-yl)-N'-[2-(2-chlorine-ethoxy)-phenylsulfonyl]-urea (triasulfuron), N-methyl-N-(4-methoxy-6-methyl-1,3,5-triazine-2-yl)-N'-(2-methoxycarbonyl-phenyl-sulfonyl)-urea (tribenuron-methyl), 2-(3,5-dichloro-phenyl)-2-(2,2,2-trichloroethyl)-oxiran (tridian), 1-amino-2,6-dinitro-N,N-dipropyl-4-trifluoromethyl-benzene (trifluralin) - (“active start group 2”).

Instead of the pure active principles of formula (I) in the proposed combinations of active principles can also COI is whether compounds of formula (I) with alkali metals, such as, for example, lithium, sodium, potassium, rubidium or cesium, in particular sodium or potassium, alkaline-earth metals such as, for example, magnesium, calcium or barium, in particular with calcium, or earth metals, such as, for example, aluminum.

Further preferred compounds of formula (I) with ammonia, alkylamines followed with 1-6 carbon atoms, such as, for example, methylamine, ethylamine, n - or Isopropylamine, n-, ISO-, sec - or tert-butylamine, n-, ISO-, sec - or tert-pentylamine, dialkylamino with 1-6 carbon atoms in the alkyl part, such as, for example, dimethylamine, dieterlen, dipropylamine, Diisopropylamine, dibutylamine, diisobutylamine, di-sec-butylamine, dimentianon, diisobutylamine, di-sec-pentylamine and digoxigenin, trialkylamine with 1-6 carbon atoms in each alkyl part, such as, for example, trimethylamine, triethylamine, Tripropylamine, tributylamine and N-ethyl-Diisopropylamine, cyclooctylamine with 3-6 carbon atoms, such as cyclopentylamine or cyclohexylamine, dicyclohexylamine with 3-6 carbon atoms in each cycloalkenes parts, such as, for example, Dicyclopentadiene or dicyclohexylamine, N-alkyl-cycloalkenyl with 1-4 carbon atoms in the alkyl part and 3-6 atomic-cyclohexylamine or N-ethyl-cyclohexylamine, N,N-dialkylhydroxylamines with 1-4 carbon atoms in the alkyl part and 3-6 carbon atoms in cycloalkyl parts, such as, for example, N,N-dimethyl-cyclopentylamine, N,N-diethyl-cyclopentylamine, N,N-dimethyl-cyclohexylamine or N,N-diethyl-cyclohexylamine, N-alkyl-dicyclohexylamine with 1-4 carbon atoms in the alkyl part and 3-6 carbon atoms in each cycloalkenes parts, such as, for example, N-methyl-Dicyclopentadiene, N-ethyl-Dicyclopentadiene, N-methyl-dicyclohexylamine or N-ethyl-cyclohexylamine, phenyl-alkylamines followed with 1-4 carbon atoms in the alkyl part, such as, for example, benzylamine, 1-phenyl-ethylamine or 2-phenyl-ethylamine, N-alkyl-phenyl-alkylamines followed with 1-4 carbon atoms in each alkyl part, such as, for example, N-methyl-benzylamine or N-ethyl-benzylamine, or N,N-dialkyl-phenyl-alkyl-amines with 1 to 4 carbon atoms in each alkyl part, for example N,N-dimethyl-benzylamine or N,N-diethyl-benzylamine, or unsubstituted or substituted bellerophone and/or substituted by alkyl with 1-4 carbon atoms with the azines, such as, for example, pyridine, quinoline, 2-methyl-pyridine, 3-methyl-pyridine, 4-methyl-pyridine, 2,4-dimethyl-pyridine, 2,5-dimethyl-pyridine, 2,6-dimethyl-pyridine or 5-ethyl-2-methyl-pyridine.

As osnovno>

acetates, amides, carbonates, bicarbonates, hydrides, hydroxides or alkanoate alkaline or alkaline-earth metals, for example sodium acetate, potassium or calcium, lithium amide, sodium, potassium or calcium, sodium carbonate, potassium or calcium, bicarbonate of sodium, potassium or calcium, lithium hydride, sodium, potassium or calcium hydroxide of lithium, sodium, potassium or calcium, methanolic sodium or potassium, ethanolic sodium or potassium, n - or ISO-propanol sodium or potassium, n-, ISO-, sec - or tert-butanolate sodium or potassium.

As examples of compounds of formula (I) used according to the invention as a blend component, include the following:

2-(2-chloro-vinylsulfonylacetamido)-, 2-(2-bromo-vinylsulfonylacetamido)-, 2-(2-methyl-vinylsulfonylacetamido)-, 2-(2-ethyl-vinylsulfonylacetamido)-, 2-(2-n-propyl-vinylsulfonylacetamido)-, 2-(2-isopropyl-vinylsulfonylacetamido)-, 2-(2-trifluoromethyl-vinylsulfonylacetamido)-, 2-(2-methoxy-vinylsulfonylacetamido)-, 2-(2-ethoxy-vinylsulfonylacetamido)-, 2-(2-n-propoxy-vinylsulfonylacetamido)-, 2-(2-ISO-propoxy-vinylsulfonylacetamido)-, 2-(2-deformedarse-vinylsulfonylacetamido)-, 2-(2-triftormetilfullerenov)-, 2-(2-n-propoxycarbonyl-vinylsulfonylacetamido)-, 2-(2-ISO-propoxycarbonyl-vinylsulfonylacetamido)- 2-(2-chloro-6-methyl-vinylsulfonylacetamido)-4-methyl-5-methoxy-2,4-dihydro-3H-1,2,4-triazole-3-he-4-methyl-5-ethoxy-2,4-dihydro-3H-1,2,4-triazole-3-one, -4-methyl-5-n-propoxy-2,4-dihydro-3H-1,2,4-triazole-3-he-4-methyl-5-ISO-propoxy-2,4-dihydro-3H-1,2,4-triazole-3-he-4-methyl-5-triptoreline-2,4-dihydro-3H-1,2,4-triazole-3-he-4-methyl-5-methylthio-2,4-dihydro-3H-1,2,4-triazole-3-one, -4-methyl-5-ethylthio-2,4-dihydro-3H-1,2,4-triazole-3-he-4-methoxy-5-methyl-2,4-dihydro-3H-1,2,4-triazole-3-he-4-methoxy-5-ethyl-2,4-dihydro-3H-1,2,4-triazole-3-he-4-methoxy-5-n-propyl-2,4-dihydro-3H-1,2,4-triazole-3-one, -4-cyclopropyl-5-methoxy-2,4-dihydro-3H-1,2,4-triazole-3-he-4-cyclopropyl-5-ethoxy-2,4-dihydro-3H-1,2,4-triazole-3-he-4-cyclopropyl-5-n-propoxy-2,4-dihydro-3H-1,2,4-triazole-3-one, -4-cyclopropyl-5-ISO-propoxy-2,4-dihydro-3H-1,2,4-triazole-3-one and 4-cyclopropyl-5-triptoreline-2,4-dihydro-3H-1,2,4-triazole-3-one, and sodium and potassium salts of these compounds.

Compounds 2-(2-methoxycarbonyl-vinylsulfonylacetamido)-4-methyl-5-n-propoxy-2,4-dihydro-3H-1,2,4-triazole-3-one (I-1) and 2-(2-triptoreline-vinylsulfonylacetamido)-4-methyl-5-methoxy-2,4-dihydro-3H-1,2,4-triazole-3-one (I-2) and its sodium salt - (I-1), in the above applications and patents.

As compounds of a number of active principles of group 2 it should be particularly noted: amidosulfuron, bentazon, bromoxynil, carfentrazone (complex ethyl ester), clodinafop (complex propargilovyh ether), clopyralid, chlorsulfuron, chlortoluron, cycloaliphatic, 2,4-D, diclofop (methyl ester), difenzoquat, diflufenican, DPX-KE459, ET-752, idoxifene, fenoxaprop (complex ethyl ester), fluoroglycofen (complex ethyl ester), flourophenyl, fluroxypyr, Isoproturon, mecoprop, metosulam, metribuzin, metsulfuron (methyl ester), pendimethalin, prosulfocarb, peridot, sulfosulfuron, thifensulfuron(-methyl), tralkoxydim, triasulfuron, tribenuron(-methyl), trifluralin. From this group of metribuzin is a particularly interesting connection as a component of the mixture.

It has been unexpectedly found that videopreteen combination of active principles, consisting of arilsulfonilglitsinov formula (I) and the above-mentioned active principles of group 2, with a very good tolerability active principles useful plants show a very high herbicide activity and can be used for selective weed control in various crops, in particular wheat, and cucci active principles of the compounds of the above groups 1 and 2 significantly higher than the sum of the activity of the individual active principles. Therefore, there is an unpredictable synergies, and not the sum of the effects. New combinations of active principles are well tolerated in many cultures, while using new combinations of active principles may well have to deal with those weeds that are usually hard to fight. Therefore, a new combination of active principles are a valuable extension of the range of selective herbicides.

The proposed combination of active principles can be applied, for example, in respect of the following plants.

Dicotyledonous weeds of the genera Sinapis, Lepidium, Galium, Stellaria, Natricaria, Anthemis, Galinsoga, Chenopodium, Urtica, Senecio, Amaranthus, Portulaca, Xanthium, Convolvulus, Ipomoea, Polygonum, Sesbania, Ambrosia, Cirsium, Carduus, Sonchus, Solanum, Rorippa, Rotala, Lindernia, Lamium, Veronica, Abutilon, Emex, Datura, Viola, Galeopsis, Papaver, Centaurea, Trifolium, Ranunculus, Taraxacum.

Dicotyledonous crops of the genera Gossypium. Glyciine, Beta, Daucus, Phaseolus, Pisum, Solanum, Linum, Ipomoea, Vicia, Nicotiana, Lycopersicon, Arachis, Brassica, Lactuca, Cucumis, Cuburbita.

Monocotyledonous weeds of the genera Echinochloa, Setaria, Panicum, Digitaria, Phleum, Poa, Festuca, Eleusine, Brachiaria, Lolium, Bromus, Avena, Cyperus, Sorghum, Agropyron, Cynodon, Monochoria, Fimbristylis, Sagittaria, Eleocharis, Scirpus, Paspalum, Ischaemum, Sphenoclea, Dactyloctenium, Agrostis, Alopecurus, Apera, Phalaris.

Monocotyledonous crops of the genera Oryza, Zea, Triticum, Hordeum, Avena, Secale, Sorghum, Panicum, Saccharum, Ananas,DAMI, but equally applies to other plants.

The synergistic effect of the proposed combinations of active principles is especially pronounced at certain concentration ratios. But the weight ratio of the active principles in the combinations of active principles can be verheiratet in a relatively wide range. In General on 1 weight part of the active principle of formula (I) are from 0.01 to 1000 weight parts, preferably 0.05 to 500 weight parts and particularly preferably 0.1 to 100 parts by weight of the active agent group 2.

The combination of active principles can be translated into the standard preparations, for example solutions, emulsions, sprayable powders, suspensions, powders, means for dusting, pastes, soluble powders, granules, suspension-emulsion concentrates, impregnated with active beginning natural and synthetic substances, as well as polymeric microcapsules. These drugs get well-known manner, for example by mixing the active started with extenders, that is liquid solvents and/or solid carriers, optionally with the use of surfactants, that is emulsifiers and/or dispersing agents and/or blowing agents.

While drinking water in solvents. As liquid solvents can mainly be used aromatic hydrocarbons like xylene and toluene or alkylnaphthalenes, hlorirovanii aromatic hydrocarbons and chlorinated aliphatic hydrocarbons such as chlorobenzene, chloroethylene or methylene chloride, aliphatic hydrocarbons like cyclohexane or paraffins, for example petroleum fractions, mineral and vegetable oils, alcohols like butanol or glycol and also their ethers and esters, ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar solvents such as dimethylformamide and dimethylsulfoxide, and water.

As solid carriers can be used, for example, ammonium salts and natural flour rocks as kaolin, alumina, talc, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth and synthetic flour rocks as highly dispersed silicic acid, alumina and silicates;

as solid carriers for granules can be used, for example, crushed and fractionated natural rocks as calcite, marble, pumice, thick, dolomite and synthetic granules of inorganic and organic flours, and gra cobs and stalks of the tobacco plants;

as emulsifiers and/or blowing agents can be used, for example, nonionic and anionic emulsifiers as complex polyoxyethylene esters of fatty acids, simple polyoxyethylene esters of fatty alcohol series, for example, a simple alkylarylsulphonate ethers, alkyl sulphonates, alkyl sulphates, arylsulfonate, and also protein hydrolysates;

as dispersing agents can be used, for example, spent sulfite liquor, and methylcellulose.

In products, it is possible to use adhesives as carboxymethylcellulose, natural and synthetic powdered, granular or Latecoere polymers such as, for example, gum-Arabicas, polyvinyl alcohol, polyvinyl acetate, and also natural phospholipids, such as Catalina and lecithins and synthetic phospholipids. Further additives can be mineral and vegetable oils.

As dyes can be used inorganic pigments, for example iron oxide, titanium oxide, Prussian blue (hexacyanoferrate (II) iron (III)), and organic dyes such as alizarin, azo and metallophthalocyanine dyes and micronutrients as, for example, iron salts, margaretpascual 0.5 to 90%.

The proposed combination of active principles are in General used in the form of finished products. The active agent contained in the combinations of active principles may also be available as separate preparations, cooked in the tank immediately before use.

New combinations of active principles can be applied as such or in the form of their preparations are also in a mixture with other known herbicides, and again there are ready-made drugs or medications prepared in the tank before use. It is then possible to mixture with other known active principles, such as fungicides, insecticides, acaricides, nematicides, protective substances from vyklevyvanija birds, growth regulators, nutrients for plants and soil amendments. For certain applications, in particular for post-harvest processing, it may be preferential to add to the drugs tolerated by plants, mineral or vegetable oils (e.g., vending drug Ol DuPont 11E) or ammonium salts such as ammonium sulphate or ammonium thiocyanate.

New combinations of active principles can be applied as such, in preparations or in the form received from the enzie, emulsions, powders, pastes and granulates. Drugs used in the standard manner, for example by pouring, spraying/sprinkling, spraying, dusting or scattering.

The proposed combination of active principles can be applied before emergence of the plants, and after him, that is, pre - and post-harvest way. You can also before sowing obrabatyvati them into the soil.

On a good weed-killing activity of new combinations of active principles are shown in the examples below. While the individual active early show deficiencies in herbicide activity, all proposed combinations have very good activity against weeds, which is higher than the sum of the activity of the individual active principles.

Synergistic effect of herbicides has always when herbicide activity of the combination of active principles is higher than the activity of separate active principles are applied.

The estimated activity of a given combination of two herbicides can be calculated as follows (see COLBY, SR.: "Calculating synergistic and antagonistic responses of herbicide combinations", Weeds 15, pages 20-22, 1967):

If X = % damage by herbicide A (the active principle of formula (I) when, over the x2">and E = expected % damage by herbicide a and B at a flow rate p and q kg/ha,

then E=X+Y-(X·Y/100).

If the actual damage is greater than the calculated damage, the combination has vergadain activity, i.e. it exhibits a synergistic effect.

The following examples show that the resulting herbicide activity proposed combinations of active principles in relation to weeds higher than calculated, i.e. new combinations of active principles have a synergistic effect.

Example

Post-harvest processing

Solvent: 5 parts by weight of acetone Emulsifier: 1 weight part of a simple alkylarylsulphonates ether

To obtain the composition of the active principle one weight part of the active principle is mixed with the specified amount of solvent to the mixture add the specified amount of emulsifier, and the resulting concentrate is diluted with water to the desired concentration.

The composition of the active agent are sprayed with experimental plant growth 5-15 cm, with the aim of drawing the desired amounts of active principle per unit area. The concentration of the working solution are chosen so that the desired number of active with the untreated control. 0% = no activity (as untreated control); 100% = complete destruction.

Active start, expenses, experimental plants and the results are listed in the following tables a-1 and a-2, and used in tables abbreviations have the following meanings:

(I-1, Na-salt = sodium salt of 2-(2-methoxycarbonyl-vinylsulfonylacetamido)-4-methyl-5-n-propoxy-2,4-dihydro-3H-1,2,4-triazole-3-one (I-1);

(I-2, Na-salt = sodium salt of 2-(2-triptoreline-vinylsulfonylacetamido)-4-methyl-5-methoxy-2,4-dihydro-3H-1,2,4-triazole-3-one (I-2);

neid. = found value of the damage or activity (%);

the expect. = damage or activity (in %), calculated by the COLBY equation.

Data on post-harvest processing receive similar shown in the application example And a way with the only difference that the concentration of the working solution are chosen so that the desired amount of active principle nameslist in 500 l of water per hectare, and that these solutions usually contain additional surfactant (trade product "Renex 36") in an amount of 0.1%.

Used active principle of group 2 in the form of the following commercially available pH tables A3-215.

Regarding the weight ratio of the active compounds of groups 1 and 2, the applicant notes the following. Specialist in the art it is known that if two compounds together have a synergistic action in General, this synergistic effect is achieved in a wide range of ratios of these compounds.

Thus, based on these additional data, the applicant believes that other herbicide funds, subject to specified amended claims, will have a similar synergistic herbicide activity.

1. Herbicide agent, containing a derivative of allconvertertoiphone General formula (I)

where R1is alkyl with 1-6 carbon atoms;

R2- alkoxy with 1-6 carbon atoms;

R3- alkoxy substituted by halogen, alkoxycarbonyl, each with 1-6 carbon atoms,

or its salt with alkali metals (“active start group 1”) and one herbicide compound of group

N-(4,6-dimethoxy-pyrimidine-2-yl)-N'-(N-methyl-N-methylsulphonyl-sulfamoyl)-maclar-2-etoxycarbonyl-ethyl)-phenyl)-4-deformity-5-methyl-2,4-dihydro-3H-1,2,4-triazole-3-one (carfentrazone-ethyl),

(R)-(2-PROPYNYL)-2-[4-(5-chloro-3-fluoro-pyridine-2-yl-oxy)-phenoxy-propanoic (clodinafop-propargyl),

2,4-dichloro-Phenoxyethanol acid (2,4-D),

(R)-2-(2,4-dichloro-phenoxy)-propanoic acid (dichlorprop-R),

methyl-2-[4-(2,4-dichloro-phenoxy)-phenoxy]-propanoate (diclofop-methyl),

N-(2,4-debtor-phenyl)-2-(3-trifluoromethyl-phenoxy)-pyridine-3-carboxamide (diflufenican),

(4-amino-3,5-dichloro-6-fluoro-pyridin-2-yl-oxy)-acetic acid (fluroxypyr),

5-methylamino-2-phenyl-4-(3-trifluoromethyl-phenyl)-3(2H)-furanone(floortime),

N-phosphonomethyl-glycine (isopropylammonium salt,

(glyphosat(-isopropylammonium salt,

methyl ester of 2-(4,5-dihydro-4-methyl-4-isopropyl-5-oxo-1H-imidazol-2-yl)-4-methyl-benzoic acid (imazamethabenz, methyl ester),

2-(4,5-dihydro-4-methyl-4-isopropyl-5-oxo-1H-imidazol-2-yl)-5-methoxymethyl-pyridine-3-carboxylic acid (imazamox),

N,N-dimethyl-N'-isopropyl-phenyl)-urea (Isoproturon),

N-(2.6-dichloro-3-methyl-phenyl)-5,7-dimethoxy-1.2,4-triazolo[1,5-a]-pyrimidine-2-sulfonamide (metosulam),

4-amino-6-tert-butyl-3-methylthio-1,2,4-triazine-5(4H)-he(metribuzin),

N-(4-methoxy-6-methyl-1,3,5-Triin-2-yl)-N'-(2-ethylsulfonyl-imidazo[1,2-a]pyridine-3-sulfonamide (sulfosulfuron),

N-(4-methoxy-6-methyl-1,3,5-triazine-2-yl)-N'-(2-methoxycarbonyl-Tien-3-yl-sulfonyl)-urea (Typen-sulfuron-methyl),

N-methyl-N'-methoxy-6-methyl-1,3,5-triazine-2-yl)-N'-(2-methoxycarbonyl-phenyl-sulfonyl)-urea (tribenuron-methyl)-("active start group 2"),

moreover, the active principle of group 1 and the active group 2 taken in synergistically effective weight ratio of 1:0.05 to 500.

2. Herbicide remedy under item 1, characterized in that the active agent group 1 contains 2-(2-methoxycarbonyl-phenylcarbonylamino-carbonyl)-4-methyl-5-n-propoxy-2,4-dihydro-3H-1,2,4-triazole-3-one (I-1), or 2-(2-triptoreline-vinylsulfonylacetamido)-4-methyl-5-methoxy-2,4-dihydro-3H-1,2,4-triazole-3-one (1-2), or sodium salt of these compounds.

3. Herbicide remedy under item 1, characterized in that the active agent group 2 contains the active principle from the following group of compounds: amidosulfuron, bromoxynil, carfentrazone(-ethyl), clodinafop(-propargyl), 2,4-D, diclofop(-methyl), diflufenican, fluroxypyr, Isoproturon, metosulam, metribuzin, sulfosulfuron, thifensulfuron(-methyl) tribenuron(-methyl).

4. Herbicide remedy under item 1, characterized in that as an active e tool under item 1, characterized in that the active agent group 1 contains 2-(2-methoxycarbonyl-vinylsulfonylacetamido)-4-methyl-5-n-propoxy-2,4-dihydro-3H-1,2,4-triazole-3-one (I1-1) or 2-(2-triptoreline-vinylsulfonylacetamido)-4-methyl-5-methoxy-2,4-dihydro-ZN-1,2.4-triazole-3-one (I-2), or sodium salt of these compounds, as the active agent of the group 2 contains 4-amino-6-tert-butyl-3-methylthio-1,2,4-triazine-5(4H)-he (metribuzin).

6. Herbicide tool for PP.1-5, characterized in that at 1 weight.h. active start group 1 come 0.1 to 100 weight.h. active start 2.



 

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